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Simulation of ground-water flow in an unconfined sand and gravel aquifer at Marathon, Cortland County, New York

The Village of Marathon, in Cortland County, N.Y., has three municipal wells that tap a relatively thin (25 to 40 feet thick) and narrow (less than 0.25 mile wide) unconfined sand and gravel aquifer in the Tioughnioga River valley. Only one of the wells is in use because water from one well has been contaminated by petroleum chemicals from a leaking storage tank, and water from the other well contains high concentrations of manganese. The operating well pumps about 0.1 million gallons per day and supplies about 1,000 people. A three-dimensional, finite-difference ground-water-flow model was used to (1) compute hydraulic heads in the aquifer under steady-state conditions, (2) develop a water budget, and (3) delineate the areas contributing recharge to two simulated wells that represent two of the municipal wells: one 57 feet east of the Tioughnioga River, the other 4,000 feet to the south and 75 feet from a man-made pond. The water budget for simulated long-term average, steady-state conditions with two simulated pumping wells indicates that the principal sources of recharge to the unconfined aquifer are unchanneled runoff and ground-water inflow from the uplands (41 percent of total recharge), precipitation that falls directly on the aquifer (34 percent), and stream leakage (23 percent). Only 2 percent of the recharge to the aquifer is from ground-water underflow into the northern end of the modeled area. Most of the simulated groundwater discharge from the modeled area (78 percent of total discharge) is to the Tioughnioga River; the rest discharges to the two simulated wells (19 percent) and as underflow at the southern end of the modeled area (3 percent). Results of a particle-tracking analysis indicate that the aquifer contributing area of the northern (simulated) well is 0.10 mile wide and 0.15 mile long and encompasses 0.015 square miles; the contributing area of the southern (simulated) well is 0.20 mile wide and 0.11 mile long and encompasses 0.022 square miles. The average traveltime of ground water from the valley wall to either simulated well is about 1.5 years, calculated on the basis of an assumed aquifer porosity of 0.3. The flowpath analysis indicates that both contributing areas contain surface-water sources of recharge; the Tioughnioga River and Hunts Creek contribute water to the northern well, and a pond and a small tributary contribute water to the southern well. Ground-water temperature in an observation well between the Tioughnioga River and the municipal well fluctuated several degrees Fahrenheit in response to pumping of the municipal well. This temperature fluctuation, in conjunction with the pumping well causing a ground-water gradient from the Tioughnioga River to the pumping well (ground-water levels in the pumping well were generally greater than 3 ft lower than that of the Tioughnioga River), indicate that there is a hydraulic connection between the river and aquifer at this site.

Water-Resources Investigations Report↗

Effects of land use on recharge potential of surficial and shallow bedrock aquifers in the upper Illinois River basin

The upper Illinois River Basin (UIRB) is the 10,949-square-mile drainage area upstream from Ottawa, Illinois on the Illinois River and is one of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program study units. To assist in the interpretation of groundwater data that will be collected during the course of the UIRB study, the study-unit team designed a spatial model to describe recharge potential of surficial and shallow bedrock aquifers. The following factors, identified as having an effect on recharge potential, were incorporated into the model: land use, soil permeability, type and thickness of surficial deposits, and uppermost bedrock geology. Other models designed to simulate recharge potential and the potential for contamination that were examined during the preparation of this model included factors similar to those included in this model, with the exception of land use. Land use and changes in land use over time, however, can affect recharge potential. The UIRB model was used to simulate recharge potential with and without incorporating land use. A comparison of the simulation results showed that recharge potential was overestimated in some areas and underestimated in other areas when land use was not included in the model. Comparisons of simulations that used 1970 and estimated 1990 land use showed changes in recharge potential over time.

Water-Resources Investigations Report↗

A precipitation-runoff model for analysis of the effects of water withdrawals on streamflow, Ipswich River basin, Massachusetts

Water withdrawals from the 155-square-mile Ipswich River Basin in northeastern Massachusetts affect aquatic habitat, water quality, and recreational use of the river. To better understand the effects of these withdrawals on streamflow, particularly low flow, the Hydrological Simulation Program-FORTRAN (HSPF) was used to develop a watershed-scale precipitation-runoff model of the Ipswich River to simulate its hydrology and complex water-use patterns.An analytical solution was used to compute time series of streamflow depletions resulting from ground-water withdrawals at wells. The flow depletions caused by pumping from the wells were summed along with any surface-water withdrawals to calculate the total withdrawal along a stream reach. The water withdrawals, records of precipitation, and streamflow records on the Ipswich River at South Middleton and at Ipswich for the period 1989?93 were used to calibrate the model. Model-fit analysis indicates that the simulated flows matched observed flows over a wide range of conditions; at a minimum, the coefficient of model-fit efficiency indicates that the model explained 79 percent of the variance in the observed daily flow.Six alternative water-withdrawal and land-use scenarios were simulated with the model. Three scenarios were examined for the 1989?93 calibration period, and three scenarios were examined for the 1961?95 period to test alternative withdrawals and land use over a wider range of climatic conditions, and to compute 1-, 7-, and 30-day low-flow frequencies using a log-Pearson Type III analysis. Flow-duration curves computed from results of the 1989?93 simulations indicate that, at the South Middleton and Ipswich gaging stations, streamflows when no water withdrawals are being made are nearly identical to streamflows when no ground-water withdrawals are made. Streamflow under no water withdrawals at both stations are about an order of magnitude larger at the 99.8 percent exceedence probability than simulations with only ground-water withdrawals. Long-term simulations indicate that the differences between streamflow with no water withdrawals and average 1989?93 water withdrawals is similar to the difference between simulations for the same water-use conditions made for the 1989?93 period at both sites. The 7-day, 10-year low-flow (7Q10, a widely used regulatory statistic) at the South Middleton station was 4.1 cubic feet per second (ft3/s) with no water withdrawals and 1991 land use, 5.8 ft3/s no withdrawals and undeveloped land, and 0.54 ft3/s with average 1989?93 water withdrawals and 1991 land use. The 7Q10 at the Ipswich station was about 8.3 ft3/s for simulations with no water withdrawals for both the 1991 land use and the undeveloped land conditions, and 2.7 ft3/s for simulations with average 1989?93 water withdrawals and 1991 land use. Simulation results indicate that surface-water withdrawals have little effect on the duration and frequency of low flows, but the cumulative ground-water withdrawals substantially decrease low flows.

Water-Resources Investigations Report↗

Hydrogeologic setting, water budget, and preliminary analysis of ground-water exchange at Lake Starr, a seepage lake in Polk County, Florida

Lake Starr, a 134-acre seepage lake of multiple-sinkhole origin on the Lake Wales Ridge of central Florida, was the subject of a detailed water-budget study from August 1996 through July 1998. The study monitored the effects of hydrogeologic setting, climate, and ground-water pumping on the water budget and lake stage. The hydrogeologic setting of the Lake Starr basin differs markedly on the two sides of the lake. Ground water from the surficial aquifer system flows into the lake from the northwest side of the basin, and lake water leaks out to the surficial aquifer system on the southeast side of the basin. Lake Starr and the surrounding surficial aquifer system recharge the underlying Upper Floridan aquifer. The rate of recharge to the Upper Floridan aquifer is determined by the integrity of the intermediate confining unit and by the downward head gradient between the two aquifers. On the inflow side of the lake, the intermediate confining unit is more continuous, allowing ground water from the surficial aquifer system to flow laterally into the lake. Beneath the lake and on the southeast side of the basin, breaches in the intermediate confining unit enhance downward flow to the Upper Floridan aquifer, so that water flows both downward and laterally away from the lake through the ground-water flow system in these areas. An accurate water budget, including evaporation measured by the energy-budget method, was used to calculate net ground-water flow to the lake, and to do a preliminary analysis of the relation of net ground-water fluxes to other variables. Water budgets constructed over different timeframes provided insight on processes that affect ground-water interactions with Lake Starr. Weekly estimates of net ground-water flow provided evidence for the occurrence of transient inflows from the nearshore basin, as well as the short-term effects of head in the Upper Floridan aquifer on ground-water exchange with the lake. Monthly water budgets showed the effects of wet and dry seasons, and provided evidence for ground-water inflow generated from the upper basin. Annual water budgets showed how differences in timing of rainfall and pumping stresses affected lake stage and lake ground-water interactions. Lake evaporation measurements made during the study suggest that, on average, annual lake evaporation exceeds annual precipitation in the basin. Rainfall was close to the long-term average of 51.99 inches per year for the 2 years of the study (50.68 and 54.04 inches, respectively). Lake evaporation was 57.08 and 55.88 inches per year for the same 2 years, making net precipitation (rainfall minus evaporation) negative during both years. If net precipitation to seepage lakes in this area is negative over the long-term, then the ability to generate net ground-water inflow from the surrounding basin plays an important role in sustaining lake levels. Evaporation exceeded rainfall by a similar amount for both years of the study, but net ground-water flow differed substantially between the 2 years. The basin contributed net ground-water inflow to the lake in both years, however, net ground-water inflow was not sufficient to make up for the negative net precipitation during the first year, and the lake fell 4.9 inches. During the second year, net ground-water inflow exceeded the difference between evaporation and rainfall and the lake rose by 12.7 inches. The additional net ground-water inflow in the second year was due to both an increase in the amount of gross ground-water inflow and a decrease in lake leakage (ground-water outflow). Ground-water inflow was greater during the second year because more rain fell during the winter, when evaporative losses were low, resulting in greater ground-water recharge. However, decreased lake leakage during this year was probably at least as important as increased ground-water inflow in explaining the difference in net ground-water flow to the lake between the 2 years. Estimates of lake leakage based on a relation between net ground-water flow and head in the Upper Floridan aquifer could easily account for the differences in net ground-water exchange with the lake in the 2 years of the study. The relation between net ground-water flow and head in the Upper Floridan aquifer implied that an estimated 1-foot increase in the average Upper Floridan aquifer head from the first to the second year could account for reduced leakage of about 8.5 million cubic feet of water from Lake Starr, or an additional 17 inches of lake stage over a year. The first year of the study was representative of typical rainfall patterns, where most of the rainfall occurs during the summer. If rainfall and lake evaporation in the first year reflect long-term average conditions, the stage of Lake Starr will decrease unless ground-water inflow increases, or leakage decreases, compared to that year.

Florida↗

Effects of a Cattail Wetland on Water Quality of Irondequoit Creek near Rochester, New York

A 6-year (1990-96) study of the Ellison Park wetland, a 423-acre, predominantly cattail ( Typha glauca ) marsh in Monroe County, N.Y., was conducted to document the effect that this wetland has on the water quality of Irondequoit Creek, which flows through it. Irondequoit Creek drains 151 square miles of mostly urban and suburban land and is the main tributary to Irondequoit Bay on Lake Ontario. The wetland was a sink for total phosphorus and total suspended solids (28 and 47 percent removal efficiencies, respectively, over the 6-year study period). Sedimentation and vegetative filtration appear to be the primary mechanisms for the decrease in loads of these constituents. Total nitrogen loads were decreased slightly by the wetland; removal efficiencies for ammonia-plus-organic nitrogen and nitrate-plus-nitrite were 6 and 3 percent, respectively. The proportions of total phosphorus and total nitrogen constituents were altered by the wetland. Orthophosphate and ammonia nitrogen were generated within the wetland and represented 12 percent of the total phosphorus output load and 1.8 percent of total nitrogen output load, respectively. Conservative chemicals, such as chloride and sulfate, were littleaffected by the wetland. Concentrations of zinc, lead, and cadmium showed statistically significant decreases, which are attributed to sedimentation and filtration of sediment and organic matter to which these elements adsorb. Sediment samples from open-water depositional areas in the wetland contained high concentrations of (1) trace metals, including barium, manganese, strontium, zinc (each of which exceeded 200 parts per million), as well as chromium, copper, lead, and vanadium, and (2) some polycyclic aromatic hydrocarbons. Persistent organochlorine pesticides, such as chlordane, dieldrin, DDT and its degradation products (DDD and DDE), and polychlorinated biphenyls (PCB's), also were detected, but concentrations of these compounds were within the ranges often found in depositional environments in highly urbanized areas. Cattail shoots attained a maximum height of 350 centimeters, a density of more than 30 shoots per square meter, and total biomass of more than 5,600 grams per square meter (46 percent of which was in above-ground tissues during the growing season). Nitrogen and potassium were three times more abundant in above-ground tissues (2.4 and 1.5 percent by dry weight, respectively) than in below-ground tissues (0.8 and 0.5 percent, respectively). Concentrations of phosphorus, molybdenum, and manganese in above-ground tissues were similar to those in below-ground tissues, but the concentrations of all other constituents were considerably higher in below-ground tissues. Concentrations of several elements exceeded those typically found in natural wetlands; these included manganese (417 ppm, parts per million) and sodium (3,600 ppm) in above-ground tissues, and aluminum (1,540 ppm), iron (15,400 ppm), manganese (433 ppm), and sodium (10,000 ppm) in below-ground tissues. Large quantities of nutrients are assimilated by wetland vegetation during the growing season, but neither tissue production nor microbial metabolic processes appeared to play a significant role in the observed patterns of surface-water chemical input-to-output relations on a seasonal basis. Presumably, internal cycling of nutrients sequestered in the sediments and detritus, combined with a summer increase in microbially mediated chemical transformations, obscured the effects of vegetative assimilation during the summer on surface-water chemical loads. Additionally, the natural confinement of most flows within the banks of Irondequoit Creek, which resulted in passage of stormwater through the wetland with little dispersion or detention in the cattail and backwater areas, diminished the capability of the wetland to improve water quality. Additional factors that probably affected the chemical-removal efficiency of the wetland included chemical inflow loading rates, storage and release mechanisms of the sediments (sedimentation, adsorption, filtration, precipitaton, dissolution, and resuspension), and accretion and burial of organic matter. Measurements of chlorophyll_ a concentrations, and calculations of potential phosphorus concentrations, since the 1970’s indicate an improvement in the trophic state of Irondequoit Bay. Estimated average annual loads (1990-96) of selected constituents entering Irondequoit Bay indicate that, since 1980, the loads of all major forms of nitrogen have decreased, chloride loads have increased, and sulfate loads have changed little. Inputs of total phosphorus and suspended solids to the wetland have increased since 1980, possibly as a result of increased erosion by stormflows from an increasingly developed watershed. The wetland decreases the loads of these constituents, but the trends of these loads entering Irondequoit Bay cannot be reliably defined because the removal efficiencies during the two earlier study periods (1980–81 and 1984–88) are known.

Water-Resources Investigations Report↗

Hydrogeology of the Beaver Kill Basin in Sullivan, Delaware, and Ulster Counties, New York

The hydrogeology of the 299-square-mile Beaver Kill basin in the southwestern Catskill Mountains of southeastern New York is depicted in a surficial geologic map and five geologic sections, and is summarized through an analysis of low-flow statistics for the Beaver Kill and its major tributary, Willowemoc Creek. Surficial geologic data indicate that the most widespread geologic units within the basin are ablation and lodgment till. Large masses of ablation till as much as 450 feet thick were deposited as lateral embankments within the narrow Beaver Kill and Willowemoc Creek valleys and have displaced the modern stream courses by as much as 1,000 feet from the preglacial bedrock-valley axis. Low-flow statistics for the Beaver Kill and Willowemoc Creeks indicate that the base flows (discharges that are exceeded 90 percent of the time) of these two streams—0.36 and 0.39 cubic feet per square mile,respectively—are the highest of 13 Catskill Mountain streams studied. High base flows elsewhere in the glaciated northeastern United States are generally associated with large stratified-drift aquifers, however, stratified drift in these two basins accounts for only about 5 percent and 4.4 percent of their respective surface areas, respectively. The high base flows in these two basins appear to correlate with an equally high percentage of massive sandstone members of the Catskill Formation, which underlies the entire region. Ground-water seepage from these sandstone members may be responsible for the high base flows of these two streams.

Water-Resources Investigations Report↗

Use of a ground-penetrating radar system to detect pre- and post-flood scour at selected bridge sites in New Hampshire, 1996-98

Ground-penetrating radar was used to measure the depth and extent of existing and infilled scour holes and previous scour surfaces at seven bridges in New Hampshire from April 1996 to November 1998. Ground-penetrating-radar survey techniques initially were used by the U.S. Geological Survey to study streambed scour at 30 bridges. Sixteen of the 30 bridges were re-surveyed where floods exceeded a 2-year recurrence interval. A 300-megahertz signal was used in the ground-penetrating radar system that penetrated through depths as great as 20 feet of water and as great as 32 feet of streambed materials. Existing scour-hole dimensions, infilled thickness, previous scour surfaces, and streambed materials were detected using ground-penetrating radar. Depths to riprap materials and pier footings were identified and verified with bridge plans. Post data-collection-processing techniques were applied to assist in the interpretation of the data, and the processed data were displayed and printed as line plots. Processing included distance normalization, migration, and filtering but processing was kept to a minimum and some interference from multiple reflections was left in the record. Of the 16 post-flood bridges, 22 ground-penetrating-radar cross sections at 7 bridges were compared and presented in this report. Existing scour holes were detected during 1996 (pre-flood) data collection in nine cross sections where scour depths ranged from 1 to 3 feet. New scour holes were detected during 1998 (post-flood) data collection in four cross sections where scour depths were as great as 4 feet deep. Infilled scour holes were detected in seven cross sections, where depths of infilling ranged from less than 1 to 4 feet. Depth of infilling by means of steel rod and hammer was difficult to verify in the field because of cobble and boulder streambeds or deep water. Previous scour surfaces in streambed materials were identified in 15 cross sections and the depths to these surfaces ranged from 1 to 10 feet below the streambed. Riprap materials or pier footings were identified in all cross sections. Calculated record depths generally agree with bridge plans. Pier footings were exposed at two bridges and steel pile was exposed at one bridge. Exposures were verified by field observations.

New Hampshire↗

Organochlorine compounds in streambed sediment and in biological tissue from streams and their relations to land use, central Arizona

Streambed-sediment samples from 13 sites and biological-tissue samples from 11 sites in the Gila River Basin in central Arizona were analyzed for 32 organochlorine compounds in streambed sediment and 28 compounds in biological tissue during 1996 as part of the U.S. Geological Survey's National Water-Quality Assessment program. The objectives of the study were to determine the occurrence and distribution of organochlorine compounds and their relation to land use. Sampling sites were categorized on the basis of major land uses in the basin or the source of water in the stream. Because land uses were mixed or had changed over time, some land-use categories were combined. Sites were categorized as forest/rangeland (6), forest/urban (1), urban (4), or agricultural/urban (2). Thirteen organochlorine compounds were detected in streambed-sediment samples, and 10 were detected in tissue samples. The number of compounds found in streambed-sediment samples from individual sites ranged from 0 to 10, and the range for individual tissue samples was 0 to 7. Comparison of the number of detections in streambed-sediment samples to the number of detections in tissue samples from particular sites where both were sampled yielded five instances where more compounds were detected in streambed sediment, six instances where more compounds were detected in tissue, and five instances where the number of detections in streambed sediment and tissue were equal. The frequency of detection of particular compounds for sites where both streambed sediment and tissue were sampled resulted in five compounds being detected more frequently in streambed sediment, five more frequently in tissue, and three compounds that were equally frequent in streambed sediment and in tissue. Few contaminants were detected in samples from the forest/rangeland sites; greater numbers of compounds were detected at the urban sites and at the forest/urban site. The greatest number of compounds and the highest concentrations of many contaminants were detected at agriculture/urban sites. The compound detected most frequently in streambed-sediment and tissue samples was p,p'-DDE. Streambed-sediment guideline values for the protection of aquatic life for p,p'-DDE and total DDT were exceeded at both agricultural/urban sites, The streambed-sediment guideline value for the protection of aquatic life for total chlordane was exceeded at one agricultural/urban site, one urban site, and the forest/urban site. The streambed-sediment guideline value for the protection of aquatic life for total PCB’s was exceeded at one agricultural/urban site. Guideline values for the protection of fish-eating wildlife for total DDT and for toxaphene were exceeded only in samples from the two agricultural/urban sites. The guideline value for the protection of fish-eating wildlife for total PCB’s was equaled or exceeded in samples from two sites—one urban and one agricultural/urban site. Screening values established by the U.S. Environmental Protection Agency for the protection of human health for edible portions of fish were exceeded by total DDT and by toxaphene in fish-tissue samples from both agricultural/urban sites. The human-health criterion for total PCB’s was exceeded in two fish-tissue samples from an agricultural site and from an urban site. Tissue samples analyzed in this study were for whole fish, and thus, concentration data are not entirely comparable to the screening values of the U.S. Environmental Protection Agency. Because these exceedences were an order of magnitude above the criteria, however, it is possible that concentrations in the edible portions of fish from these locations could present a human- health risk. Analyses of samples of edible portions of fish from these locations would be needed to adequately assess the presence or absence of a human-health risk. The similarity of the results of this study to the results of other studies of organochlorine compounds in the environment suggests that there is a correlation between contaminants in sediment and biological-tissue samples and land uses. As with other studies of the occurrence and distribution of organochlorine contaminants in streambed sediments and biological tissue, this study shows that many organochlorine compounds continue to persist in the environment and thus could pose a threat to aquatic life, fish-eating wildlife, and possibly to humans who consume contaminated fish.

Arizona↗

Analysis of nitrate and volatile organic compound data for ground water in the Great Salt Lake Basins, Utah, Idaho, and Wyoming, 1980-98

In 1995, ground water was the source of drinking water to about 52 percent of the population served by public drinking water systems in the Great Salt Lake Basins study unit, which includes parts of Utah, Idaho, and Wyoming. Existing nitrate and volatile organic compound data for ground water collected in the study unit were compiled and summarized as part of the National Water-Quality Assessment Program’s objective to describe water-quality conditions in the Nation’s aquifers. Prerequisites for the inclusion of nitrate and volatile organic compound data into this retrospective analysis are that the data set is available in electronic form, the data were collected during 1980-98, the data set is somewhat regional in coverage, and the locations of the sampled sites are known. Ground-water data stored in the U.S. Geological Survey’s National Water Information System and the Idaho and Utah Public Drinking Water Systems databases were reviewed. Only the most recent analysis was included in the data sets if more than one analysis was available for a site. The National Water Information System data set contained nitrate analyses for water from 480 wells. The median concentration of nitrate was 1.30 milligrams per liter for the 388 values above minimum reporting limits. The maximum contaminant level for nitrate as established by the U.S. Environmental Protection Agency was exceeded in water from 10 of the 200 wells less than or equal to 150 feet deep and in water from 3 of 280 wells greater than 150 feet deep. The Public Drinking Water Systems data set contained nitrate analyses for water from 587 wells. The median concentration of nitrate was 1.12 milligrams per liter for the 548 values above minimum reporting limits. The maximum contaminant level for nitrate was exceeded at 1 site and 22 sites had concentrations equal to or greater than 5 milligrams per liter. The types of land use surrounding a well and the well depth were related to measured nitrate concentrations in the sampled ground water. Overall, water sampled from wells in rangeland areas had a lower median measured nitrate concentration (0.76 milligrams per liter) than water from areas with an agricultural or urban/residential land use (1.41 and 1.20 milligrams per liter, respectively). In the National Water Information System data set, the median measured nitrate concentration in water from urban/residential areas varied from 1.00 milligrams per liter for wells greater than 150 feet deep to 1.84 milligrams per liter for wells less than or equal to 150 feet deep. The Public Drinking Water Systems and the National Water Information System data sets contained analyses for most of the State and Federally regulated volatile organic compounds in water from about 368 and 74 wells, respectively. Fifteen different volatile organic compounds were detected at least once in ground water sampled from the Great Salt Lake Basins study unit. Water from 21 wells contained at least 1 volatile organic compound at detectable concentrations. About 68 percent of the volatile organic compounds detected were in water sampled from wells in Salt Lake County, Utah. Tetrachloroethylene was the most commonly detected volatile organic compound in ground water sampled from the study unit, present in 8 out of 442 samples. Maximum contaminant levels for tetrachloroethylene and 1,1-dichloroethylene as established by the U.S. Environmental Protection Agency were exceeded in water from one well each.

Idaho,Utah, Wyoming↗

Hydrogeologic setting and potential for denitrification in ground water, Coastal Plain of southern Maryland

The types and distribution of Coastal Plain sediments in the Patuxent River Basin may contribute to relatively low concentrations of nitrate (typically less than 1 milligram per liter) in stream base flow because of the chemical reduction of dissolved nitrate (denitrification) in ground water. Water chemistry data from synoptic stream base-flow surveys in the Patuxent River Basin show higher dissolved nitrate concentrations in the Piedmont than in the Coastal Plain section of the watershed. Stream base flow reflects closely the chemistry of ground water discharging from the surficial (unconfined) aquifer to the stream. Because land use in the sampled subbasins is virtually the same in each section, differences in the physical and geochemical characteristics of the surficial aquifer may explain the observed differences in water chemistry. One possible cause of lower nitrate concentrations in the Coastal Plain is denitrification within marine sediments that contain chemically reduced compounds. During denitrification, the oxygen atoms on the nitrate (N0 3 -) molecule are transferred to a reduced compound and N gas is produced. Organic carbon and ferrous iron (Fe 2+ ), derived from the dissolution of minerals such as pyrite (FeS 2 ) and glauconite (an iron aluminosilicate clay), can act as reducing substrates; these reduced chemical species are common in the marine and estuarine deposits in Southern Maryland. The spatial distribution of geologic units and their lithology (sediment type) has been used to create a map of the potential for denitrification of ground water in the surficial aquifer of the Coastal Plain in Southern Maryland.

Maryland↗

Effects of alternative Missouri River management plans on ground-water levels in the lower Missouri River flood plain

In 1998, the U.S. Army Corps of Engineers (USACE) proposed eight Alternative River Management Plans (ARMPs) for managing reservoir levels and water-release rates for the Missouri River. The plans include the Current Water Control Plan (CWCP), Conservation 18, 31, and 44 (C18, C31, and C44) that provide different levels of water conservation in the reservoirs during droughts, Fish and Wildlife 10, 15, and 20 (FW10, FW15, and FW20) that vary water-release rates to provide additional fish and wildlife benefits, and Mississippi River 66 (M66) that maintains a 66,000 cubic feet per second discharge at St. Louis to provide navigation support for the Mississippi River. Releases from Gavin?s Point Dam affect both the lower 1,305 kilometers of the Missouri River and ground-water levels in the lower Missouri River flood plain. Changes in the magnitude and timing of ground-water-level fluctuations in response to changes in river management could impact agriculture, urban development, and wetland hydrology along the lower Missouri River flood plain. This study compared simulated ground-water altitude and depth to ground water for the CWCP in the Missouri River alluvial aquifer near the Kansas City area between 1970 and 1980 with each ARMP, determined the average change in simulated ground-water level for selected river-stage flood pulses at selected distances from the river, and compared simulated flood pulse, ground-water responses with actual flood pulse, and ground-water responses measured in wells located at three sites along the lower Missouri River flood plain.For the model area, the percent total shallow ground-water area (depth to ground water less than 0.3048 meter) is similar for each ARMP because of overall similarities in river flow between ARMPs. The percent total shallow ground-water area for C18 is the most similar to CWCP followed by C31, M66, C44, FW10, FW15, and FW20. ARMPs C18, C31, C44, and M66 do not cause large changes in the percent shallow ground-water area when compared to CWCP. FW10 and FW15 each cause a spring increase and a summer decrease in the shallow ground-water area. FW20 has a larger spring increase in the shallow ground-water area, but the largest decrease is delayed into November. Analysis of daily changes between the ARMPs indicate large differences can exist in both duration and extent of shallow ground-water areas.A series of 12 flood pulses of 0.5-, 1-, and 3-meters in magnitude and 1-, 8-, 32-, and 128-days in duration were simulated using the ground-water flow model. A ground-water response factor (GWRF, defined as the change in ground-water level at a known distance from the river, at a specified time after the beginning of a flood pulse divided by the magnitude of the flood pulse) was determined daily for selected distances from the river. The GWRF multiplied by the magnitude of the flood pulse can be used to estimate the change in ground-water level at a known time after the beginning of a flood pulse for a known distance from the river. Flood-pulse simulation results indicate the relatively small impact on ground-water levels of small river-stage fluctuations of short duration as might occur daily or weekly. The larger impact on ground-water levels from larger river-stage increases of longer duration indicate the importance of river management flow releases, seasonal changes in river flow, and the effects of continuous high-river stage for long periods on ground-water levels of the lower Missouri River flood plain.A comparison of model results to well hydrographs from three areas along the lower Missouri River flood plain was used to determine how closely the simulated GWRFs matched the measured GWRFs for similar flood pulses and the transferability of GWRFs to other parts of the lower Missouri River flood plain. The comparison between the measured and simulated ground-water responses indicate that the simulated ground-water responses can provide a reasonable estimate of the ground-water resp

Water-Resources Investigations Report↗