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Parameterizing an aeolian erosion model for rangelands

Aeolian processes are fundamental to arid and semi-arid ecosystems, but modeling approaches are poorly developed for assessing impacts of management and environmental change on sediment transport rates over meaningful spatial and temporal scales. For model estimates to provide value, estimates of sediment flux that encapsulate intra- and inter-annual and spatial variability are needed. Further, it is important to quantify and communicate transparent estimates of model uncertainty to users. Here, we present a wind erosion and dust emission model parameterized for rangelands using a Generalized Likelihood Uncertainty Estimation framework. Modeled horizontal sediment flux was calibrated using data from five diverse grassland and shrubland sites from the USDA National Wind Erosion Research Network. Observations of wind speed, vegetation height, length of gaps between vegetation, and percent bare ground were used as model inputs. Horizontal sediment flux estimates from 10,000 independently selected parameter sets were compared to flux observations from 44 ∼ month-long collection periods to calculate a likelihood measure for each model. Results show good agreement for individual sampling periods across sites with few observations falling outside prediction bounds and a one-to-one relationship between median predictions and observations. Additionally, combined distributions of sediment flux estimates from all sample periods for a given site closely approximated the probability of observing a given flux at that site. These results suggest AERO effectively represents temporal variability in aeolian transport rates at rangeland sites and provides robust assessments suitable for assessing land health and better predicting changes in air quality and the impacts of land management activities.

Aeolian Research

Genetic structure of Mycoplasma ovipneumoniae informs pathogen spillover dynamics between domestic and wild Caprinae in the western United States

Spillover diseases have significant consequences for human and animal health, as well as wildlife conservation. We examined spillover and transmission of the pneumonia-associated bacterium Mycoplasma ovipneumoniae in domestic sheep, domestic goats, bighorn sheep, and mountain goats across the western United States using 594 isolates, collected from 1984 to 2017. Our results indicate high genetic diversity of M. ovipneumoniae strains within domestic sheep, whereas only one or a few strains tend to circulate in most populations of bighorn sheep or mountain goats. These data suggest domestic sheep are a reservoir, while the few spillovers to bighorn sheep and mountain goats can persist for extended periods. Domestic goat strains form a distinct clade from those in domestic sheep, and strains from both clades are found in bighorn sheep. The genetic structure of domestic sheep strains could not be explained by geography, whereas some strains are spatially clustered and shared among proximate bighorn sheep populations, supporting pathogen establishment and spread following spillover. These data suggest that the ability to predict M. ovipneumoniae spillover into wildlife populations may remain a challenge given the high strain diversity in domestic sheep and need for more comprehensive pathogen surveillance.

Arizona, California, Colorado, Idaho, Kansas, Mont

Genetic diversity of infectious hematopoietic necrosis virus from Feather River and Lake Oroville, California, and virulence of selected isolates for Chinook salmon and rainbow trout

Infectious hematopoietic necrosis virus (IHNV) is a significant pathogen of young salmonid fishes worldwide but particularly within the historical range of the Pacific Northwest and California. In the Sacramento and San Joaquin River drainages of California, IHNV outbreaks in juvenile Chinook salmon Oncorhynchus tshawytscha have been observed regularly at large production hatcheries, including Coleman National Fish Hatchery (established in 1941) and Feather River State Fish Hatchery (FRH; established in 1967), since facility operations began. Recent severe epidemics at the FRH in 1998 and 2000-2002 prompted investigations into the characteristics and potential sources of virus at this facility. Both phylogenetic analyses of a variable portion of the glycoprotein gene and serologic comparisons based on neutralization with three polyclonal rabbit sera were used to characterize 82 IHNV isolates from the Feather River watershed between 1969 and 2004. All isolates examined were in the L genogroup and belonged to one of three serologic groups typical of IHNV from California. The IHNV isolates from the Feather River area demonstrated a maximum nucleotide sequence divergence of 4.0%, and new isolates appeared to emerge from previous isolates rather than by the introduction of more diverse subgroups from exogenous sources. The earliest isolates examined from the watershed formed the subgroup LI, which disappeared coincidently with a temporal shift to new genetic and serologic types of the larger subgroup LII. Experimental challenges demonstrated no significant differences in the virulence for juvenile Chinook salmon and rainbow trout O. mykiss from selected isolates representing the principal types of IHNV found historically and from recent epidemics at FRH. While most isolates were equally virulent for both host species, one isolate was found to be more virulent for Chinook salmon than for rainbow trout. ?? Copyright by the American Fisheries Society 2007.

Journal of Aquatic Animal Health

Ferricrete, manganocrete, and bog iron occurrences with selected sedge bogs and active iron bogs and springs in the upper Animas River watershed, San Juan County, Colorado

During 1996 to 2000, the Bureau of Land Management, National Park Service, Environmental Protection Agency, United States Department of Agriculture (USDA) Forest Service, and the U.S. Geological Survey (USGS) developed a coordinated strategy to (1) study the environmental effects of historical mining on Federal lands, and (2) remediate contaminated sites that have the greatest impact on water quality and ecosystem health. This dataset provides information that contributes to these overall objectives and is part of the USGS Abandoned Mine Lands Initiative. Data presented here represent ferricrete occurrences and selected iron bogs and springs in the upper Animas River watershed in San Juan County near Silverton, Colorado. Ferricretes (stratified iron and manganese oxyhydroxide-cemented sedimentary deposits) are one indicator of the geochemical baseline conditions as well as the effect that weathering of mineralized rocks had on water quality in the Animas River watershed prior to mining. Logs and wood fragments preserved in several ferricretes in the upper Animas River watershed, collected primarily along streams, yield radiocarbon ages of modern to 9,580 years B.P. (P.L. Verplanck, D.B. Yager, and S.E. Church, work in progress). The presence of ferricrete deposits along the current stream courses indicates that climate and physiography of the Animas River watershed have been relatively constant throughout the Holocene and that weathering processes have been ongoing for thousands of years prior to historical mining activities. Thus, by knowing where ferricrete is preserved in the watershed today, land-management agencies have an indication of (1) where metal precipitation from weathering of altered rocks has occurred in the past, and (2) where this process is ongoing and may confound remediation efforts. These data are included as two coverages-a ferricrete coverage and a bogs and springs coverage. The coverages are included in ArcInfo shapefile and ArcInfo interchange file format.

Colorado

Comparability among four invertebrate sampling methods, Fountain Creek Basin, Colorado, 2010-2012

The U.S. Geological Survey, in cooperation with Colorado Springs City Engineering and Colorado Springs Utilities, designed a study to determine if sampling method and sample timing resulted in comparable samples and assessments of biological condition. To accomplish this task, annual invertebrate samples were collected concurrently using four sampling methods at 15 U.S. Geological Survey streamflow gages in the Fountain Creek basin from 2010 to 2012. Collectively, the four methods are used by local (U.S. Geological Survey cooperative monitoring program) and State monitoring programs (Colorado Department of Public Health and Environment) in the Fountain Creek basin to produce two distinct sample types for each program that target single-and multiple-habitats. This study found distinguishable differences between single-and multi-habitat sample types using both community similarities and multi-metric index values, while methods from each program within sample type were comparable. This indicates that the Colorado Department of Public Health and Environment methods were compatible with the cooperative monitoring program methods within multi-and single-habitat sample types. Comparisons between September and October samples found distinguishable differences based on community similarities for both sample types, whereas only differences were found for single-habitat samples when multi-metric index values were considered. At one site, differences between September and October index values from single-habitat samples resulted in opposing assessments of biological condition. Direct application of the results to inform the revision of the existing Fountain Creek basin U.S. Geological Survey cooperative monitoring program are discussed.

Colorado

Effects of highway-deicer application on ground-water quality in a part of the Calumet Aquifer, northwestern Indiana

The effects of highway-deicer application on ground-water quality were studied at a site in northwestern Indiana using a variety of geochemical indicators. Site characteristics such as high snowfall rates; large quantities of applied deicers; presence of a high-traffic highway; a homogeneous, permeable, and unconfined aquifer; a shallow water table; a known ground-water-flow direction; and minimal potential for other sources of chloride and sodium to complicate source interpretation were used to select a study area where ground water was likely to be affected by deicer application. Forty-three monitoring wells were installed in an unconfined sand aquifer (the Calumet aquifer) near Beverly Shores in northwestern Indiana. Wells were installed along two transects that approximately paralleled groundwater flow in the Calumet aquifer and crossed US–12. US–12 is a highway that receives Indiana’s highest level of maintenance to maintain safe driving conditions. Ground-water quality and water-level data were collected from the monitoring wells, and precipitation and salt-application data were compiled from 1994 through 1997. The water-quality data indicated that chloride was the most easily traced indicator of highway deicers in ground water. Concentration ratios of chloride to iodide and chloride to bromide and Stiff diagrams of major element concentrations indicated that the principal source of chloride and sodium in ground water from the uppermost one-third to one-half of the Calumet aquifer and downgradient from US–12 was from a halite highway-deicer source. Borehole logs of relative electromagnetic conductivity defined a distinct plume of deicer-affected water in the uppermost 8 feet of aquifer at about 9 feet horizontally from the paved roadway edge and a zone of higher conductivity than background in the lower one-third of the aquifer. Chloride and sodium in the deep parts of the aquifer originated from natural sources. Chloride and sodium from highway deicers were present in the aquifer throughout the year. The highest concentrations of chloride and sodium in ground water were determined in samples collected during the spring and summer from wells open to the water table within about 9 feet of the highway. Chloride concentrations in ground water that were attributable to highway deicers also were found in tested wells about 400 feet downgradient from US–12 during the fall and winter and at greater depths than in wells closer to US–12. Chloride concentrations exceeded the U.S. Environmental Protection Agency’s (USEPA) secondary maximum contaminant level of 250 milligrams per liter for drinking water at seven wells downgradient from the highway during late winter, spring, and summer samplings. The chloride standard was exceeded only in water from wells with total depths that are less than about 10 feet below land surface. Sodium concentrations in water periodically exceeded the USEPA drinking-water equivalency level of 20 milligrams per liter in both the uppermost (deicer 2 Effects of Highway-Deicer Application on Ground-Water Quality in a Part of the Calumet Aquifer, Northwestern Indiana affected) and lower one-thirds of the aquifer. Sodium concentrations in ground water downgradient from US–12 and in the upper 5 feet of the aquifer also occasionally exceeded drinking-water standards for sodium (160 milligrams per liter) as set by the State of Florida and a standard for taste (200 milligrams per liter) as set by the World Health Organization. Dispersion was identified by analysis of aquifer-test data, isotopic dating of ground water, and water-quality data to be the process most responsible for reducing concentrations of highway deicers in the aquifer. Chemical analyses of the sand composing the aquifer indicated that cation exchange decreased the mass of deicerrelated sodium in ground water, although the sand has a limited capacity to sustain the process. Automated daily measurements of specific conductance, correlated to chloride concentrations, indicated that some deicer is retained in the aquifer near the highway throughout the entire year and acts as a continuous chloride source for ground water. Peak concentrations of deicerrelated constituents occasionally were detected by the daily, automated measurements of specific conductance that were made between the monthly samplings of ground water. Data analysis indicated that more frequent sampling than monthly intervals would be necessary if maximum chloride concentrations were to be measured. Some deicer may be retained in the aquifer and unsaturated zone between annual salt-application periods. Chloride concentrations at wells 1-DG-WT and 2-DG-WT remained greater than background through much or all of the year. The estimated masses of chloride transported in ground water past 2-DG in 1995 and 1996 were either slightly greater than (1995) or less than (1996) the masses of chloride applied to US–12 during the study.

Indiana

Occurrence of anthropogenic organic compounds in ground water and finished water of community water systems in Eagle and Spanish Springs Valleys, Nevada, 2002-2004

As a part of the U.S. Geological Survey's National Water-Quality Assessment Program, an effort to characterize the quality of major rivers and aquifers used as a source of supply to some of the largest community water systems (CWSs) in the United States has been initiated. These studies, termed Source Water-Quality Assessments (SWQAs), consist of two sampling phases. Phase 1 was designed to determine the frequency of detection and concentrations of about 260 volatile organic compounds (VOCs), pesticides and pesticide degradates, and other anthropogenic organic compounds in source water of 15 CWS wells in each study. Phase 2 monitors concentrations in the source water and also the associated finished water of CWSs for compounds most frequently detected during phase 1. One SWQA was completed in the Nevada Basin and Range area in Nevada. Ten CWS wells in Eagle Valley and five CWS wells in Spanish Springs Valley were sampled. For phase 2, two wells were resampled in Eagle Valley. Samples were collected during 2002-2004 for both phases. Water use in Eagle Valley is primarily for domestic purposes and is supplied through CWSs. Ground-water sources provide about 55 percent of the public-water supply, and surface-water sources supply about 45 percent. Lesser amounts of water are provided by domestic wells. Very little water is used for agriculture or manufacturing. Spanish Springs Valley has water-use characteristics similar to those in Eagle Valley, although there is more agricultural water use in Spanish Springs Valley than in Eagle Valley. Maximum contaminant concentrations were compared to two human-health benchmarks, if available, to describe the water-quality data in a human-health context for these findings. Measured concentrations of regulated contaminants were compared to U.S. Environmental Protection Agency and Nevada Maximum Contaminant Level (MCL) values. Measured concentrations of unregulated contaminants were compared to Health-Based Screening Levels, which are not regulatory standards and are not legally enforceable values. All of the contaminants detected in this study were found at concentrations less than available human-health benchmarks. In the source waters sampled in phase 1, 10 contaminants of the approximately 260 measured were detected in samples collected from Eagle Valley, and 4 contaminants were detected in samples from Spanish Springs Valley. The most frequently detected compounds in the Eagle Valley source water were chloroform (a disinfection by-product), which was detected in samples from four wells, and deethylatrazine (a degradation product of the herbicide atrazine), which was detected in samples from three wells. Each of the four contaminants detected in the Spanish Springs Valley source waters was detected in samples from one well. The detection frequencies of VOCs and pesticides in samples from the SWQA wells were similar to those in samples from both shallow and deep monitoring wells in Carson City, Reno, and Spanish Springs. This indicates that the SWQA sampling is representative of the organic chemical compounds likely to be detected in the aquifers sampled. However, more organic compounds were detected at low frequencies and concentrations in samples from the monitoring wells than in samples from SWQA wells. Three contaminants were detected in one finished-water sample collected from Eagle Valley. Comparison of SWQA results in the Nevada Basin and Range Study Unit to results of an SWQA in the larger urban area of Salt Lake City showed that fewer anthropogenic compounds were detected in Eagle and Spanish Springs Valleys and generally at lower concentrations than in the Salt Lake City study.

Scientific Investigations Report

Water resources and the urban environment, lower Charles River watershed, Massachusetts, 1630-2005

The Charles River, one of the Nation’s most historically significant rivers, flows through the center of the Boston metropolitan region in eastern Massachusetts. The lower Charles River, downstream of the original head of tide in Watertown, was originally a productive estuary and important source of fish and shellfish for the Native Americans of the region. This portion of the river has an exceptionally long and colorful human history. In 1615, the explorer Captain John Smith gave the river its modern name, in honor of young Prince Charles of England. In 1617–18, the Native American community of the watershed was decimated by an epidemic, after having continuously occupied the area for the previous 4,000 years. In 1630, the first large group of English settlers, led by John Winthrop, set foot on the Shawmut Peninsula at the mouth of the river, and established the town of Boston. In the 1630s, the first printing press, public park, public school, and college in the English colonies were all established on the banks of the Charles River. Almost immediately, the settlers of Boston and adjacent towns also began to modify the landscape and water resources of the watershed. Perhaps the most important type of landscape alteration in the watershed was the filling of the extensive salt marshes and tidal flats of the estuary downstream of Watertown. This landmaking activity along the lower Charles River began in the mid-1600s, and did not conclude until the 1950s. In the early 20th century, the estuary mouth was dammed, creating a freshwater basin in the lower 9.5 miles of the river. A system of parks and parkways was built along the banks of the impounded river. In addition to the mainstem river, virtually all of the remaining water resources in the watershed have also been altered. Most of the river’s tributaries, for example, were culverted, or placed into tunnels, and many of the ponds and freshwater wetlands in the watershed were filled to facilitate urban development. One additional legacy of the river’s long human history is pollution from industry and sewage. By 1875, a total of 43 mills were operating along the lower Charles River between Watertown Dam and Boston Harbor. Thousands of gallons of untreated sewage and industrial wastewater entered the river daily through gravity drains, posing a major threat to public health. Concerted efforts to address the sewage problem began in the late 1870s. By the 1960s, the water quality of the river was significantly improved, yet still not suitable for swimming, fishing, or even boating under most conditions. In 1965, the Charles River Watershed Association was organized and the call to restore the environmental quality of the river and its parklands was heard anew. Passage of the Federal Clean Water Act in 1972 and the subsequent court-ordered reconstruction of the region’s sewage-treatment infrastructure in the 1980s and 1990s (the “Boston Harbor Cleanup”) provided additional impetus to address the river’s remaining pollution problems. In 1995, the U.S. Environmental Protection Agency launched the Clean Charles 2005 Initiative, which brought together government agencies, private-sector institutions, and environmental organizations to focus on restoring the river to fishable and swimmable conditions by Earth Day 2005. This initiative has achieved substantial improvements in water quality; sewage discharges to the river, for example, have been largely eliminated. Nevertheless, it is now widely acknowledged that full attainment of water-quality standards will likely depend upon improved public understanding of the watershed, continued efforts to eliminate illicit sewage discharges to the river, and better management of the urban runoff that enters the river both directly and from its many tributary streams.

Massachusetts

Assessment of interim flow water-quality data of the San Joaquin River restoration program and implications for fishes, California, 2009-11

After more than 50 years of extensive water diversion for urban and agriculture use, a major settlement was reached among the U.S. Departments of the Interior and Commerce, the Natural Resources Defense Council, and the Friant Water Users Authority in an effort to restore the San Joaquin River. The settlement received Federal court approval in October 2006 and established the San Joaquin River Restoration Program, a multi-agency collaboration between State and Federal agencies to restore and maintain fish populations, including Chinook salmon, in the main stem of the river between Friant Dam and the confluence with the Merced River. This is to be done while avoiding or minimizing adverse water supply effects to all of the Friant Division contractors that could result from restoration flows required by the settlement. The settlement stipulates that water- and sediment-quality data be collected to help assess the restoration goals. This report summarizes and evaluates water-quality data collected in the main stem of the San Joaquin River between Friant Dam and the Merced River by the U.S. Bureau of Reclamation for the San Joaquin River Restoration Program during 2009-11. This summary and assessment consider sampling frequency for adequate characterization of variability, sampling locations for sufficient characterization of the San Joaquin River Restoration Program restoration reach, sampling methods for appropriate media (water and sediment), and constituent reporting limits. After reviewing the water- and sediment-quality results for the San Joaquin River Restoration Program, several suggestions were made to the Fisheries Management Work Group, a division of the San Joaquin River Restoration Program that focuses solely on the reintroduction strategies and health of salmon and other native fishes in the river. Water-quality results for lead and total organic carbon exceeded the Surface Water Ambient Monitoring Program Basin Plan Objectives for the San Joaquin Basin, and results for copper exceeded the U.S. Environmental Protection Agency Office of Pesticide Programs' aquatic-life chronic and acute benchmarks for invertebrates. One sediment sample contained detections of pyrethroid pesticides bifenthrin, lambda-cyhalothrin, and total permethrin at concentrations above published chronic toxicity thresholds.

California

Assessment of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Operation of a coal-tar distillation and wood-preserving facility in St. Louis Park, Minnesota, during 1918-72 contaminated ground water with coal-tar derivatives and inorganic chemicals. Coal-tar derivatives entered the groundwater system through three major paths: (1) Spills and drippings that percolated to the water table, (2) surface runoff and plant process water that was discharged to wetlands south of the former plant site, and (3) movement of coal tar directly into bedrock aquifers through a multiaquifer well on the site. In the drift, Platteville, and St. Peter aquifers, ground water flows laterally from west to east and vertically downward. Near the former plant site, creosote-like organic fluids have migrated vertically downward through the drift and are being partially dissolved by ground water. Ground water has preferentially mobilized low-molecular-weight compounds such as phenolic compounds, alkyl-benzenes, and naphthalene, although polynuclear aromatic hydrocarbons as heavy as benzo(a)pyrene have been mobilized at low concentrations. Sorption of high-molecular-weight compounds has retarded their migration down the hydraulic gradient compared to low-molecular-weight compounds in the plume. Some simple phenolic compounds are being degraded to methane and carbon dioxide by bacteria under anaerobic conditions in the drift-PlattevilleSt. Peter aquifer system. Other low-molecular-weight aromatic compounds are apparently being degraded by aerobic bacteria at the periphery of the plume where oxygen is available. Intermediate degradation products such as volatile fatty acids are likely present, but complete conversion of the organic contaminants to innocuous inorganic substances has not been demonstrated. Near and south of 36th and Wooddale Avenues, contaminants enter the St. Peter aquifer where the Glenwood confining unit has been eroded in a buried bedrock valley. Contaminants previously entered the Prairie du Chien-Jordan aquifer through at least one multiaquif er well (W38). Other sources of contaminants and the low concentrations of contaminants hamper delineation of the maximum areal extent of contaminants that are resistant to biologic degradation. These biorefractory compounds will probably continue to migrate down the hydraulic gradients in the drift and Platteville and St. Peter aquifers. Of particular concern with respect to the health risk to humans are the polynuclear aromatic hydrocarbons, which are a major constituent of coal tar and are found in municipal wells near the site that are completed in the Prairie du Chien-Jordan aquifer. The Prairie du Chien-Jordan aquifer lies 250 to 500 feet below land surface and is relatively well protected from nearsurface sources of contamination by overlying rocks. However, the aquifer has been contaminated since at least 1932 because coal-tar derivatives have entered the aquifer through multiaquifer wells. The most significant single source of contamination in the aquifer is a well drilled on the site in 1917 (well W23) that has contained liquid coal-tar since at least 1958. The introduction, dissolution, and movement of this coal-tar in ground water has contaminated nearby municipal wells. The composition of the tar in well W23, and the ratio of concentrations of individual compounds in water from well W23 to those in municipal well SLP15, are consistent with known hydrologic, chemical, and biologic processes, and the conclusion that contaminants in well SLP15 are due primarily to contaminants introduced at well W23. Most of the major polynuclear aromatic hydrocarbons in the tar, although slightly soluble in water and strongly sorbed by aquifer materials, have moved greater distances at higher concentrations than have the lower-molecular-weight, more soluble compounds such as phenolic compounds and naphthalene. The latter are apparently being degraded by bacteria. The direction and rate of contaminant movement within the Prairie du Chien-Jordan aquifer changes with time because the ground-water-flow system continually adjusts to hydraulic stresses caused by ground-water withdrawals and flow through multiaquifer wells. Contaminants can move rapidly through the Prairie du Chien-Jordan because the upper part of the aquifer is a carbonate rock having fracture and solution-channel permeability, low effective porosity, and relatively small surface area for sorption. Consequently, the concentration and composition of contaminants in water pumped from individual industrial and municipal wells completed in the aquifer fluctuate with time. Although contaminants have been in the aquifer for at least 50 years and their spatial distribution is complex, concentrations remain highest near their points of introduction through multiaquifer wells near and on the site of the former plant. Contaminants reached the Ironton-Galesville aquifer through at least two deep multiaquifer wells (W23 and W38), but the extent of contamination in this aquifer, and in the underlying Mount Simon-Hinckley aquifer, is not known.

Minnesota

Zirconium and hafnium

Zirconium and hafnium are corrosion-resistant metals that are widely used in the chemical and nuclear industries. Most zirconium is consumed in the form of the main ore mineral zircon (ZrSiO 4 , or as zirconium oxide or other zirconium chemicals. Zirconium and hafnium are both refractory lithophile elements that have nearly identical charge, ionic radii, and ionic potentials. As a result, their geochemical behavior is generally similar. Both elements are classified as incompatible because they have physical and crystallochemical properties that exclude them from the crystal lattices of most rock-forming minerals. Zircon and another, less common, ore mineral, baddeleyite (ZrO 2 ), form primarily as accessory minerals in igneous rocks. The presence and abundance of these ore minerals in igneous rocks are largely controlled by the element concentrations in the magma source and by the processes of melt generation and evolution. The world’s largest primary deposits of zirconium and hafnium are associated with alkaline igneous rocks, and, in one locality on the Kola Peninsula of Murmanskaya Oblast, Russia, baddeleyite is recovered as a byproduct of apatite and magnetite mining. Otherwise, there are few primary igneous deposits of zirconium- and hafnium-bearing minerals with economic value at present. The main ore deposits worldwide are heavy-mineral sands produced by the weathering and erosion of preexisting rocks and the concentration of zircon and other economically important heavy minerals, such as ilmenite and rutile (for titanium), chromite (for chromium), and monazite (for rare-earth elements) in sedimentary systems, particularly in coastal environments. In coastal deposits, heavy-mineral enrichment occurs where sediment is repeatedly reworked by wind, waves, currents, and tidal processes. The resulting heavy-mineral-sand deposits, called placers or paleoplacers, preferentially form at relatively low latitudes on passive continental margins and supply 100 percent of the world’s zircon. Zircon makes up a relatively small percentage of the economic heavy minerals in most deposits and is produced primarily as a byproduct of heavy-mineral-sand mining for titanium minerals. From 2003 to 2012, world zirconium mineral concentrates production increased by more than 40 percent, and Australia and South Africa were the leading producers. Global consumption of zirconium mineral concentrates generally increased during the same time period, largely as a result of increased demand in developing economies in Asia and the Middle East. Global demand weakened in 2012, causing a decrease in world production of zirconium mineral concentrates and delaying the development of several new mining projects. Global consumption is expected to increase in the future, however, as demand from the ceramics, chemicals, and metals industries increases (driven by renewed growth in developing economies) and demand for zirconium and hafnium metal increases (driven by the construction and operation of new nuclear powerplants). The behaviors of zirconium and hafnium in the environment are very similar to one another in that most zirconium- and hafnium-bearing minerals have limited solubility and reactivity. Anthropogenic sources of zirconium, and likely hafnium, are from industrial zirconium-containing byproducts and emissions from the processing of sponge zirconium, and exposure to the general population from these sources is small. Zirconium and hafnium are likely not essential to human health and generally are considered to be of low toxicity to humans. The main exposure risks are associated with industrial inhalation and dermal exposure. Because of the low solubility of zirconium and hafnium, ecological health concerns in the aquatic environment and in soils are minimal. Heavy-mineral-sand mining may lead to increased erosion rates when the mining is managed improperly. In addition, surface mining requires removal of the overlying organic soil layer and produces waste material that includes tailings and slimes. The soil removal and mining activity disturbs the surrounding ecosystem and alters the character of the landscape. Dry mineral separation processes create high amounts of airborne dust, whereas wet mineral separation processes do not. In operations that restore the landscape to pre-mining conditions, the volume of waste and the impact on the landscape may be relatively temporary.

Professional Paper

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California

Status and understanding of groundwater quality in the Klamath Mountains study unit, 2010: California GAMA Priority Basin Project

Groundwater quality in the Klamath Mountains (KLAM) study unit was investigated as part of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in Del Norte, Humboldt, Shasta, Siskiyou, Tehama, and Trinity Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA Priority Basin Project was designed to provide a spatially unbiased, statistically robust assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality data and explanatory factors for groundwater samples collected in 2010 by the USGS from 39 sites and on water-quality data from the California Department of Public Health (CDPH) water-quality database. The primary aquifer system was defined by the depth intervals of the wells listed in the CDPH water-quality database for the KLAM study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study included two types of assessments: (1) a status assessment , which characterized the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds, pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements, and (2) an understanding assessment , which evaluated the natural and human factors potentially affecting the groundwater quality. The assessments were intended to characterize the quality of groundwater resources in the primary aquifer system of the KLAM study unit, not the quality of treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentrations divided by the health- or aesthetic-based benchmark concentrations) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration less than or equal to a benchmark. Relative-concentrations of organic constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). For inorganic constituents, the boundary between low and moderate relative-concentration was set at 0.5. Aquifer-scale proportion was used in the status assessment as the primary metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifer system with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentages of the primary aquifer system with moderate and low relative-concentrations, respectively. The KLAM study unit includes more than 8,800 square miles (mi 2 ), but only those areas near the sampling sites, about 920 mi 2 , are included in the areal assessment of the study unit. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. To confirm this methodology, 90 percent confidence intervals were calculated for the grid-based high aquifer-scale proportions and were compared to the spatially weighted results, which were found to be within these confidence intervals in all cases. Grid-based results were selected for use in the status assessment unless, as was observed in a few cases, a grid-based result was zero and the spatially weighted result was not zero, in which case, the spatially weighted result was used. The status assessment showed that inorganic constituents with human-health benchmarks were detected at high relative-concentrations in 2.6 percent of the primary aquifer system and at moderate relative-concentrations in 10 percent of the system. The high aquifer-scale proportion for inorganic constituents mainly reflected the high aquifer-scale proportions of boron. Inorganic constituents with secondary maximum contaminant levels were detected at high relative-concentrations in 13 percent of the primary aquifer system and at moderate relative-concentrations in 10 percent of the system. The constituents present at high relative-concentrations included iron and manganese. Organic constituents with human-health benchmarks were not detected at high relative-concentrations, but were detected at moderate relative-concentrations in 1.9 percent of the primary aquifer system. The 1.9 percent reflected a spatially weighted moderate aquifer-scale proportion for the gasoline additive methyl tert-butyl ether. Of the 148 organic constituents analyzed, 14 constituents were detected. Only one organic constituent had a detection frequency of greater than 10 percent—the trihalomethane, chloroform. The second component of this study, the understanding assessment , identified the natural and human factors that may have affected the groundwater quality in the KLAM study unit by evaluating statistical correlations between water-quality constituents and potential explanatory factors. The potential explanatory factors evaluated were aquifer lithology, land use, hydrologic conditions, depth, groundwater age, and geochemical conditions. Results of the statistical evaluations were used to explain the occurrence and distribution of constituents in the KLAM study unit. Groundwater age distribution (modern, mixed, or pre-modern), redox class (oxic, mixed, or anoxic), and dissolved oxygen concentration were the explanatory factors that best explained occurrence patterns of the inorganic constituents. High concentrations of boron were found to be associated with groundwater classified as mixed or pre-modern with respect to groundwater age. Boron was also negatively correlated to dissolved oxygen and positively correlated to specific conductance. Iron and manganese concentrations were strongly associated with low dissolved oxygen concentrations, anoxic and mixed redox classifications, and pre-modern groundwater. Specific conductance concentrations were found to be related to pre-modern groundwater, low dissolved oxygen concentrations, and high pH. Chloroform was selected for additional evaluation in the understanding assessment because it was detected in more than 10 percent of wells sampled in the KLAM study unit. Septic tank density was the only explanatory factor that was found to relate to chloroform concentrations.

California

Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane. Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic concentrations were higher than the Health Advisory level of 2 µg/L in 27 of 89 samples (30 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 µg/L in 9 of 89 samples (10 percent). The pH ranged from 5.4 to 9.3 and did not meet the SMCL range of greater than 6.5 to less than 8.5 in 27 samples (30 percent); 22 samples had pH values less than 6.5, and 5 samples had pH values greater than 8.5. Total coliform bacteria were detected in 22 of 89 samples (25 percent); Escherichia coli were detected in only 2 of those 22 samples. Radon-222 activities ranged from 25 to 7,400 picocuries per liter (pCi/L), with a median of 2,120 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 86 of 89 samples (97 percent); radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 12 of 89 samples (13.5 percent). Water from 8 of the 89 wells (9 percent) had concentrations of methane greater than the reporting level of 0.24 milligrams per liter (mg/L) with the detectable methane concentrations ranging from 0.74 to 9.6 mg/L. Of 16 replicate samples submitted to another laboratory with a lower reporting level of 0.0002 mg/L, 15 samples had detectable methane concentrations that ranged from 0.0011 to 9.7 mg/L. Of these 15 samples, low levels of ethane (0.00032 to 0.0017 mg/L) were detected in 6 of 7 samples with methane concentrations greater than 0.75 mg/L. The isotopic composition of methane in 6 of 8 samples with sufficient dissolved methane (about 1 mg/L) for isotopic analysis is consistent with a predominantly thermogenic methane source (sample carbon isotopic ratio δ13C CH4 values ranging from -56.36 to -45.97 parts per thousand (‰) and hydrogen isotopic ratio δD CH4 values ranging from -233.1 to -141.1 ‰). However, the low levels of ethane relative to methane indicate that the methane may be of microbial origin and subsequently underwent oxidation. Isotopic compositions indicated a possibly mixed thermogenic and microbial source (carbon dioxide reduction process) for the methane in 1 of the 8 samples (δ 13 C CH4 of -63.72 and δD CH4 of -192.3 ‰) and potential oxidation of microbial and (or) thermogenic methane in the remaining sample (δ 13 C CH4 of -46.56 and δD CH4 of -79.7 ‰). Groundwater samples with relatively elevated methane concentrations (near or greater than 1 mg/L) had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with relatively low methane concentrations (less than 0.75 mg/L). The seven well-water samples with the highest methane concentrations (from about 1 to 9.6 mg/L) also had among the highest pH values (8.1 to 9.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less, by volume) similar in composition to that reported for gas and oil well brines in Pennsylvania. Most other samples with low methane concentrations (less than about 1 mg/L) had chloride/bromide ratios that indicate predominantly man-made sources of chloride, such as road salt, septic systems, and (or) animal waste. Although naturally occurring brines may originate from deeper parts of the aquifer system, the man-made sources are likely to affect shallow groundwater. Geochemical modeling showed that the water chemistry of samples with elevated pH, sodium, lithium, bromide, and alkalinity could result from dissolution of calcite (calcium carbonate) combined with cation exchange and mixing with a small amount of brine. Through cation exchange reactions (which are equivalent to processes in a water softener) calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. The spatial distribution of groundwater compositions generally shows that (1) relatively dilute, slightly acidic, oxygenated, calcium-carbonate type waters tend to occur in the uplands along the western border of Wayne County; (2) waters of near neutral pH with the highest amounts of hardness (calcium and magnesium) generally occur in areas of intermediate altitudes; and (3) waters with pH values greater than 8, low oxygen concentrations, and the highest arsenic, sodium, lithium, bromide, and methane concentrations can occur in deep wells in uplands but most frequently occur in stream valleys, especially at low elevations (less than about 1,200 ft above North American Vertical Datum of 1988) where groundwater may be discharging regionally, such as to the Delaware River. Thus, the baseline assessment of groundwater quality in Wayne County prior to gas-well development shows that shallow (less than about 1,000 ft deep) groundwater is generally of good quality, but methane and some constituents present in high concentrations in brine (and produced waters from gas and oil wells) may be present at low to moderate concentrations in some parts of Wayne County.

Pennsylvania

Perceptions of volcanic air pollution and exposure reduction practices on the Island of Hawai‘i: Working towards socially relevant risk communication

Kīlauea volcano, on the Island of Hawai‘i, is one of the most active volcanoes in the world. Over the past four decades it has released large amounts of volcanic gases and aerosols which form volcanic air pollution known as ‘vog’. Communities downwind of Kīlauea have been chronically or episodically exposed to this potentially harmful air pollution and have raised concerns about the hazards of vog exposure. Public health and civil protection agencies have offered a range of advice, information, and mitigation strategies for living with vog. In this mixed-methods social study, we investigate the translation of official advice into practice in Island of Hawai‘i communities and assess how risk communication could be improved by considering public input, preferences, and community relevance. Given the paucity of information on the long-term effects of chronic vog exposure, assessing the effectiveness of public health and risk communication is vital.

Hawaii

Evaluating the potential role of bioactive chemicals on the distribution of invasive Asian carp upstream and downstream from river mile 278 in the Illinois waterway

Two non-native carp species have invaded the Illinois Waterway and are a threat to Great Lakes ecosystems. Poor water quality in the upper Illinois Waterway, may be a factor contributing to the stalling of the carp population front near river mile 278. In 2015, the U.S. Geological Survey collected 4 sets of water samples from two sites upstream and 4 sites downstream from river mile 278, and one tributary. Each sample was analyzed for up to 649 unique parameters of which 287 were detected including 96 pesticides, 62 pharmaceuticals, 39 wastewater indicator compounds, 29 metals, 19 volatile organic compounds (VOCs), six disinfection by-products (DBPs), five hormones, and five carboxylic acids. Potential for bioactivity was estimated by comparing chemical concentrations to aquatic life or human health criteria and to in-vitro bioactivity screening results in the U.S EPA ToxCast™ database. The resulting hazard quotients and exposure-activity ratios (EARs) are toxicity indexes, that can be used to rank potential bioactivity of individual chemicals and chemical mixtures. This analysis indicates that several bioactive chemicals (BCs) including: carbendazim, 2,4-D, metolachlor, terbuthylazine, and acetochlor (pesticides); 1,4-dioxane (VOC); metformin, diphenhydramine, sulfamethoxazole, tramadol, fexofenadine, and the anti-depressants (pharmaceuticals); bisphenol A, 4-nonylphenol, galaxolide, 4-tert-octylphenol (wastewater indicator chemical); lead and boron (metals); and estrone (hormone) all occur in the upper Illinois Waterway at concentrations that produce elevated EARs values and may be adversely affecting carp reproduction and health. The clear differences in water quality upstream and downstream from river mile 278 with higher contaminant concentrations and potential bioactivity upstream could represent a barrier to carp range expansion.

Illinois

Geochemical legacies and the future health of cities: A tale of two neurotoxins in urban soils

The past and future of cities are inextricably linked, a linkage that can be seen clearly in the long-term impacts of urban geochemical legacies. As loci of population as well as the means of employment and industry to support these populations, cities have a long history of co-locating contaminating practices and people, sometimes with negative implications for human health. Working at the intersection between environmental processes, communities, and human health is critical to grapple with environmental legacies and to support healthy, sustainable, and growing urban populations. An emerging area of environmental health research is to understand the impacts of chronic exposures and exposure mixtures&mdash;these impacts are poorly studied, yet may pose a significant threat to population health. Acute exposure to lead (Pb), a powerful neurotoxin to which children are particularly susceptible, has largely been eliminated in the U.S. and other countries through policy-based restrictions on leaded gasoline and lead-based paints. But the legacy of these sources remains in the form of surface soil Pb contamination, a common problem in cities and one that has only recently emerged as a widespread chronic exposure mechanism in cities. Some urban soils are also contaminated with another neurotoxin, mercury (Hg). The greatest human exposure to Hg is through fish consumption, so eating fish caught in urban areas presents risks for toxic Hg exposure. The potential double impact of chronic exposure to these two neurotoxins is pronounced in cities. Overall, there is a paradigmatic shift from reaction to and remediation of acute exposures towards a more nuanced understanding of the dynamic cycling of persistent environmental contaminants with resultant widespread and chronic exposure of inner-city dwellers, leading to chronic toxic illness and disability at substantial human and social cost.

Indiana

USGS global change science strategy: A framework for understanding and responding to climate and land-use change

This U.S. Geological Survey (USGS) Global Change Science Strategy expands on the Climate Variability and Change science component of the USGS 2007 Science Strategy, “Facing Tomorrow’s Challenges: USGS Science in the Coming Decade” (U.S. Geological Survey, 2007). Here we embrace the broad definition of global change provided in the U.S. Global Change Research Act of 1990 (Public Law 101–606,104 Stat. 3096–3104)—“Changes in the global environment (including alterations in climate, land productivity, oceans or other water resources, atmospheric chemistry, and ecological systems) that may alter the capacity of the Earth to sustain life”—with a focus on climate and land-use change. There are three major characteristics of this science strategy. First, it addresses the science required to broadly inform global change policy, while emphasizing the needs of natural-resource managers and reflecting the role of the USGS as the science provider for the Department of the Interior and other resource-management agencies. Second, the strategy identifies core competencies, noting 10 critical capabilities and strengths the USGS uses to overcome key problem areas. We highlight those areas in which the USGS is a science leader, recognizing the strong partnerships and effective collaboration that are essential to address complex global environmental challenges. Third, it uses a query-based approach listing key research questions that need to be addressed to create an agenda for hypothesis-driven global change science organized under six strategic goals. Overall, the strategy starts from where we are, provides a vision for where we want to go, and then describes high-priority strategic actions, including outcomes, products, and partnerships that can get us there. Global change science is a well-defined research field with strong linkages to the ecosystems, water, energy and minerals, natural hazards, and environmental health components of the USGS Science Strategy (2007). When science strategies that cover these other components are developed, coordinated implementation will be necessary to achieve Bureau-level synergies and optimize capabilities and expertise. In October 2010, USGS realigned its management and budget structure to implement its 2007 Science Strategy. The new organizational structure, in which “Global Change” is one of seven key mission areas, lends itself to the advancement of the established six strategic goals. USGS global change science is formally represented by the “Climate and Land-Use Change” Mission Area in the FY 2012 budget (USGS, 2011). This plan was developed by the USGS Global Change Science Strategy Planning Team (SSPT) appointed by the USGS Director on March 4, 2010 and charged with developing a Global Change Science Strategy for the coming decade (McNutt, 2010). USGS managers and science staff are the main audience for this science strategy. This document is also intended to serve as the foundation for consistent USGS collaboration and communication with partners and stakeholders.

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