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Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO2. Residual methane in sediments at both sites usually exceeded 10 mll-1 of wet sediment. Carbon isotopic compositions of methane, CO2, and ??CO2 followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments. ?? 1984.

Marine and Petroleum Geology↗

Giant subtidal stromatolites forming in normal salinity waters

We report here the discovery of giant lithified subtidal columnar stromatolites (>2 m high) growing in 7-8 m of clear oceanic water in current-swept channels between the Exuma Islands on the eastern Bahama Bank. They grow by trapping ooid and pelletal carbonate sand and synsedimentary precipitation of carbonate cement within a field of giant megaripples. The discovery is important to geologists and biologists because similar organo-sedimentary structures built by a combination of cementation and the trapping of sediment by microbes were the dominant fossil types during the Precambrian. Stromatolites are thought to have been responsible for the production of free oxygen and thus the evolution of animal life1,2. Until the discovery of small lithified subtidal columnar stromatolites in the Bahamas3, the only subtidal marine examples known to be living while undergoing lithification were in the hypersaline waters of Hamelin Pool at Shark Bay, Western Australia4-7. Shark Bay stromatolites range from intertidal to the shallow subtidal with the larger columns reaching 1 m in height. The Shark Bay stromatolites have strongly influenced geological interpretation; by analogy, many ancient stromatolites have been considered to have grown in intertidal and/or hypersaline conditions8, although hypersalinity was not a necessity for growth during the Precambrian because grazing metazoan life had not then evolved. ?? 1986 Nature Publishing Group.

Nature↗

Cretaceous biostratigraphy in the Wyoming thrust belt.

In the Cretaceous section of the thrust belt, fossils are especially useful for dating and correlating repetitive facies of different ages in structurally complex terrain. The biostratigraphic zonation for the region is based on megafossils (chiefly ammonites) , which permit accurate dating and correlation of outcrop sections, and which have been calibrated with the radiometric time scale for the Western Interior. Molluscan and vertebrate zone fossils are difficult to obtain from the subsurface, however, and ammonites are restricted to rocks of marine origin. Palynomorphs (plant microfossils) have proven to be the most valuable fossils in the subsurface because they can be recovered from drill cuttings. Palynomorphs also are found in both marine and nonmarine rocks and can be used for correlation between facies. Stratigraphic ranges of selected Cretaceous marine and nonmarine palynomorphs in previously designated reference sections in Fossil Basin, Wyoming are correlated with the occurrence of ammonites and other zone fossils in the same sections. These correlations can be related to known isotopic ages, and they contribute to the calibration of palynomorph ranges in the Cretaceous of the Western Interior. -from Authors

Mountain Geologist↗

Invertebrate assemblages in the lower Klamath River, with reference to Manayunkia speciosa

The freshwater polychaete, Manayunkia speciosa Leidy (Canalipalpata Sabellidae), is the intermediate host for two myxozoan pathogens (Ceratomyxa shasta and Parvicapsula minibicornis) that cause substantial mortalities of juvenile salmon in the Pacific Northwest, particularly in the Klamath River below Iron Gate Dam in California. Information on the distribution of M. speciosa in the Klamath River may facilitate targeted control of polychaete populations to disrupt the parasites that affect fish populations. We sampled invertebrate assemblages in the lower Klamath River in the summer and fall of 2005 and 2006 to estimate distribution patterns of M. speciosa and to characterize assemblage structure of invertebrates in reaches where the polychaete was both collected and not collected. The polychaete was most often found in a reach of river extending 100 km downstream from the Shasta River (river km 185-287). The reach in which it was found supported high taxonomic richness of invertebrates and a high abundance of filtering collectors including marine relicts such as sponges, unioinid mussels, and bryozoans. We suggest that the large, stable substrate on which these were found represents primary, optimal habitat for the polychaete, also a marine relict. Reaches above and below the zone where we collected polychaetes showed a general trend of reduced taxonomic richness as distance away from the polychaete zone increased, and also showed differing relative abundances of non-insect taxa and functional feeding groups. Differences in invertebrate assemblages between years were coincident with large differences in water flows. We suggest flows and food resources may play important roles in invertebrate distribution patterns.

California Fish and Game↗

Thermal stability of ladderane lipids as determined by hydrous pyrolysis

Anaerobic ammonium oxidation (anammox) has been recognized as a major process resulting in loss of fixed inorganic nitrogen in the marine environment. Ladderane lipids, membrane lipids unique to anammox bacteria, have been used as markers for the detection of anammox in marine settings. However, the fate of ladderane lipids after sediment burial and maturation is unknown. In this study, anammox bacterial cell material was artificially matured by hydrous pyrolysis at constant temperatures ranging from 120 to 365 ??C for 72 h to study the stability of ladderane lipids during progressive dia- and catagenesis. HPLC-MS/MS analysis revealed that structural alterations of ladderane lipids already occurred at 120 ??C. At temperatures >140 ??C, ladderane lipids were absent and only more thermally stable products could be detected, i.e., ladderane derivatives in which some of the cyclobutane rings were opened. These diagenetic products of ladderane lipids were still detectable up to temperatures of 260 ??C using GC-MS. Thus, ladderane lipids are unlikely to occur in ancient sediments and sedimentary rocks, but specific diagenetic products of ladderane lipids will likely be present in sediments and sedimentary rocks of relatively low maturity (i.e., C31 hopane 22S/(22S + 22R) ratio <0.2 or ????/(???? + ???? + ????) ratio of >0.5). ?? 2008 Elsevier Ltd.

Organic Geochemistry↗

A new probabilistic seismic hazard assessment for greater Tokyo

Tokyo and its outlying cities are home to one-quarter of Japan's 127 million people. Highly destructive earthquakes struck the capital in 1703, 1855 and 1923, the last of which took 105 000 lives. Fuelled by greater Tokyo's rich seismological record, but challenged by its magnificent complexity, our joint Japanese-US group carried out a new study of the capital's earthquake hazards. We used the prehistoric record of great earthquakes preserved by uplifted marine terraces and tsunami deposits (17 M???8 shocks in the past 7000 years), a newly digitized dataset of historical shaking (10 000 observations in the past 400 years), the dense modern seismic network (300 000 earthquakes in the past 30 years), and Japan's GeoNet array (150 GPS vectors in the past 10 years) to reinterpret the tectonic structure, identify active faults and their slip rates and estimate their earthquake frequency. We propose that a dislodged fragment of the Pacific plate is jammed between the Pacific, Philippine Sea and Eurasian plates beneath the Kanto plain on which Tokyo sits. We suggest that the Kanto fragment controls much of Tokyo's seismic behaviour for large earthquakes, including the damaging 1855 M???7.3 Ansei-Edo shock. On the basis of the frequency of earthquakes beneath greater Tokyo, events with magnitude and location similar to the M??? 7.3 Ansei-Edo event have a ca 20% likelihood in an average 30 year period. In contrast, our renewal (time-dependent) probability for the great M??? 7.9 plate boundary shocks such as struck in 1923 and 1703 is 0.5% for the next 30 years, with a time-averaged 30 year probability of ca 10%. The resulting net likelihood for severe shaking (ca 0.9g peak ground acceleration (PGA)) in Tokyo, Kawasaki and Yokohama for the next 30 years is ca 30%. The long historical record in Kanto also affords a rare opportunity to calculate the probability of shaking in an alternative manner exclusively from intensity observations. This approach permits robust estimates for the spatial distribution of expected shaking, even for sites with few observations. The resulting probability of severe shaking is ca 35% in Tokyo, Kawasaki and Yokohama and ca 10% in Chiba for an average 30 year period, in good agreement with our independent estimate, and thus bolstering our view that Tokyo's hazard looms large. Given $1 trillion estimates for the cost of an M???7.3 shock beneath Tokyo, our probability implies a $13 billion annual probable loss. ?? 2006 The Royal Society.

Philosophical Transactions of the Royal Society A:↗

Field guide to geologic excursions in southwestern Utah and adjacent areas of Arizona and Nevada

This field guide contains road logs for field trips planned in conjunction with the 2002 Rocky Mountain Section meeting of the Geological Society of America held at Southern Utah University in Cedar City, Utah. There are a total of eight field trips, covering various locations and topics in southwestern Utah and adjacent areas of Arizona and Nevada. In addition, the field guide contains a road log for a set of Geological Engineering Field Camp Exercises run annually by the University of Missouri at Rolla in and around Cedar City. Two of the field trips address structural aspects of the geology in southwestern Utah and northwestern Arizona; two trips deal with ground water in the region; and along with the Field Camp Exercises, one trip, to the Grand Staircase, is designed specifically for educators. The remaining trips examine the volcanology and mineral resources of a large area in and around the Tusher Mountains in Utah; marine and brackish water strata in the Grand Staircase-Escalante National Monument; and the Pine Valley Mountains, which are cored by what may be the largest known laccolith in the world. The "Three Corners" area of Utah, Arizona, and Nevada is home to truly world-class geology, and I am confident that all of the 2002 Rocky Mountain Section meeting attendees will find a field trip suited to their interests.

Arizona, Nevada, Utah↗

Attenuation and scattering tomography of the deep plumbing system of Mount St. Helens

We present a combined 3-D P wave attenuation, 2-D S coda attenuation, and 3-D S coda scattering tomography model of fluid pathways, feeding systems, and sediments below Mount St. Helens (MSH) volcano between depths of 0 and 18 km. High-scattering and high-attenuation shallow anomalies are indicative of magma and fluid-rich zones within and below the volcanic edifice down to 6 km depth, where a high-scattering body outlines the top of deeper aseismic velocity anomalies. Both the volcanic edifice and these structures induce a combination of strong scattering and attenuation on any seismic wavefield, particularly those recorded on the northern and eastern flanks of the volcanic cone. North of the cone between depths of 0 and 10 km, a low-velocity, high-scattering, and high-attenuation north-south trending trough is attributed to thick piles of Tertiary marine sediments within the St. Helens Seismic Zone. A laterally extended 3-D scattering contrast at depths of 10 to 14 km is related to the boundary between upper and lower crust and caused in our interpretation by the large-scale interaction of the Siletz terrane with the Cascade arc crust. This contrast presents a low-scattering, 4&ndash;6 km 2 &ldquo;hole&rdquo; under the northeastern flank of the volcano. We infer that this section represents the main path of magma ascent from depths greater than 6 km at MSH, with a small north-east shift in the lower plumbing system of the volcano. We conclude that combinations of different nonstandard tomographic methods, leading toward full-waveform tomography, represent the future of seismic volcano imaging.

Washington↗

Sand wave fields beneath the Loop Current, Gulf of Mexico: Reworking of fan sands

Extensive fields of large barchan-like sand waves and longitudinal sand ribbons have been mapped by deep-towed SeaMARC IA sidescan sonar on part of the middle and lower Mississippi Fan that lies in about 3200 m of water. The area is beneath the strongly flowing Loop Current. The bedforms have not been adequately sampled but probably consist of winnowed siliciclastic-foraminiferal sands. The size (about 200 m from wingtip to wingtip) and shape of the large barchans is consistent with a previously observed peak current speed of 30 cm/s, measured 25 m above the seabed. The types of small-scale bedforms and the scoured surfaces of chemical crusts, seen on nearby bottom photographs, indicate that near-bed currents in excess of 30 cm/s may sometimes occur. At the time of the survey the sand transport direction was to the northwest, in the opposite direction to the Loop Current but consistent with there being a deep boundary current along the foot of the Florida Escarpment. Some reworking of the underlying sandy turbidites and debris flow deposits is apparent on the sidescan sonar records. Reworking by deep-sea currents, resulting in erosion and in deposits characterised by coarsening upwards structures and cross-bedding, is a process that has been proposed for sand found in cores in shallower parts of the Gulf of Mexico. This process is more widespread than hitherto supposed.

Marine Geology↗

Morphology and evolutionary significance of Adoneis pacifica gen. et sp. Nov. (Fragilariaceae, Bacillariophyta), a marine araphid diatom from Chile

A new marine diatom genus and species, Adoneis pacifica G.W. Andrews and P. Rivera, has been identified in Chilean coastal waters. This taxon shows obvious affinities to the genera Rhaphoneis and Delphineis , but cannot be classified in either, as they are currently construed. Adoneis pacifica resembles Rhaphoneis in outline and to some degree in the pseudocelli, whereas it resembles Delphineis in the structure of the vela and the positioning of the apical rimoportulae. However, distinctive characters of this new monotypic genus are: (1) the usual positioning of a single rimoportula near the centre of each lateral margin of the valve, and (2) the occurrence of well organized apical pore fields (pseudocelli), in which the pores are much smaller than elsewhere on the valve. These appear to be primitive traits for the araphid diatom family Fragilariaceae, and they suggest that Adoneis pacifica may be a conservative species important in the study of the evolution of the family.

Diatom Research↗

Trace fossils from Jurassic lacustrine turbidites of the Anyao Formation (Central China) and their environmental and evolutionary significance

The Lower Jurassic Anyao Formation crops out near Jiyuan city, western Henan Province, central China. It is part of the infill of the nonmarine early Mesozoic Jiyuan‐Yima Basin. In the Jiyuan section, this unit is about 100 m thick and consists of laterally persistent, thin and thick‐bedded turbidite sandstones and mudstones displaying complete and base‐or top‐absent Bouma sequences, and thick‐bedded massive sandstones. The Anyao Formation records sedimentation within a lacustrine turbidite system developed in a pull‐apart basin. Processes involved include high and low density turbidity currents, sometimes affected by liquefaction or fluidization. Facies analysis suggests that this succession is formed by stacked aggradational turbidite lobes. The absence of thick mudstone packages indicates that background sedimentation was subordinate to high frequency turbidite deposition. The Anyao Formation hosts a moderately diverse ichnofauna preserved as hypichnial casts on the soles of thin‐bedded turbidite sandstones. The ichnofauna consists of Cochlichnus anguineus, Hel‐minthoidichnites tenuis, Helminthopsis abeli, H. hieroglyphica, Mono‐morphichnus lineatus, Paracanthorhaphe togwunia, Tuberculichnus vagans, Vagorichnus anyao, tiny grazing trails, and irregularly branching burrows. Vagorichnus anyao occurs not only as a discrete trace, but also as a compound ichnotaxon intergrading with Gordia marina and Tuberculichnus vagans. Both predepositional and post‐depositional traces are present on the soles of turbidites. This ichnofauna comprises both feeding and grazing traces produced by a deposit‐feeding lacustrine benthic biota. Crawling traces are rare. Although certain ichnofossils (e.g. V. anyao, P. togwunia) show overall similarities with deep‐sea agrichnia, they differ in reflecting remarkably less specialized feeding strategies, displaying overcrossing between specimens (and to a lesser extent, self‐crossing), and in the case of V’ anyao recording post‐turbidite burrowing activity. The development of less specialized strategies than those displayed by deep‐marine ichnofaunas may be related to less stable conditions, typical of lake settings. Oxyenation, energy, sedimentation rate (both event and background), food supply, soft‐sediment deformation and erosion rate have mainly influenced trace‐fossil distribution. Turbidity currents would have ensured oxygen (as well as food) supply to deep lake settings, thus allowing the establishment of a moderately diverse biota. Biogenic structures were mostly confined to the outer, low energy areas. High sedimentation rates and strong erosion precluded preservation of ichnofossils in inner lobe settings. The Anyao ichnofauna is of significance in furthering knowledge of the colonization of deep lakes throughout the stratigraphie record and in identification of additional nonmarine ichnofacies. The ana‐lyzed ichnofauna resembles late Paleozoic lacustrine assemblages described from different localities around the world and is regarded as a Mesozoic example of the Mermia ichnofacies. However, when compared with Paleozoic assemblages, the Anyao ichnofauna shows a clear dominance of burrows over surface trails, deeper burrowing penetration, larger size, and presence of relatively more complex structures. The high burrow/surface trail ratio may be indicative of lower preservation potential in the latter, thus reflecting a tap‐honomic overprint. In contrast to the Paleozoic examples, the establishment of a relatively well‐developed lacustrine infauna may have precluded preservation of surface trails. Burrower activity probably obliterated biogenic structures formed close to the sediment‐water interface.

Ichnos: An International Journal for Plant and Ani↗

A new ichnospecies of Nereites from carboniferous tidal-flat facies of eastern Kansas, USA: Implications for the Nereites-Neonereites debate

Predominantly horizontal, gently curved to slightly sinuous traces constituting uniserial rows of imbricated, subspherical sediment pads occur in Pennsylvanian tidal-flat facies of eastern Kansas. These traces exhibit a complex, actively filled internal structure. The presence of a median tunnel enveloped by overlapping pads of reworked sediment indicates that these biogenic structures should be included in the ichnogenus Nereites MacLeay in Murchison, 1839. A new ichnospecies, N. imbricata , is erected. Externally, Nereites imbricata differs from the other Nereites ichnospecies by the large, tightly packed, imbricated pads that commonly result in an annulated appearance on bedding-planes. Internally, obliquely arranged, arcuate laminae envelope the median tunnel and tend to follow the outline of the external semispherical pads. Additionally, the behavioral pattern reflected by N. imbricata is less specialized than that of the other Nereites ichnospecies. Eione monoliformis Tate, 1859 resembles N. imbricata in general appearence, but lack the diagnostic Nereites internal structure, and is invariably preserved as positive epireliefs. Occurrence of Nereites imbricata as both median tunnels surrounded by reworked sediment ( Nereites preservation) and uniserial rows of imbricated sediment pads ( Neonereites preservation) supports the notion that Neonereites Seilacher, 1960 is a preservational variant of Nereites . The ichnogenus Nereites is an eurybathic form and is a common component of Paleozoic shallow-marine facies.

Kansas↗

A phylogeny based on cytochrome-c oxidase gene sequences identifies sympatric Ichthyophonus genotypes in the NE Pacific Ocean

ABSTRACT: In recent decades, evidence has accumulated to suggest that the widespread and highly variable parasite Ichthyophonus hoferi is actually a species complex. Highly plastic morphology and a general lack of defining structures has contributed to the likely underestimate of biodiversity within this group. Molecular methods are a logical next step in the description of these parasites, but markers used to date have been too conserved to resolve species boundaries. Here we use mitochondrial encoded cytochrome-c oxidase (MTCO1) gene sequences and phylogenic analysis to compare Ichthyophonus spp. isolates from several marine and anadromous fish hosts. The resulting phylogeny displays lineage separation among isolates and possible host/niche segregation not previously described. The parasite type that infects Pacific herring Clupea pallasii , Atlantic herring C. harengus , Atlantic salmon Salmo salar , and Pacific staghorn sculpin Oligocottus maculosus (Clade A) is different from that which infects Chinook salmon Oncorhynchus tshawytscha, walleye pollock Gadus chalcogrammus , Greenland halibut Reinhardtius hippoglossoides , and Pacific halibut Hippoglossus stenolepsis (Clade B). MTCO1 sequences confirmed the presence of a more divergent Ichthyophonus sp. isolated from American shad Alosa sapidissima in rivers of eastern North America (Clade C), while American shad introduced to the Pacific Ocean are infected with the same parasite that infects Pacific herring (Clade A). Currently there are no consensus criteria for delimiting species within Ichthyophonidae , but MTCO1 sequences hold promise as a potential species identifying marker and useful epizootiological tool.

Diseases of Aquatic Organisms↗

An open-water electrical geophysical tool for mapping sub-seafloor heavy placer minerals in 3D and migrating hydrocarbon plumes in 4D

A towed-streamer technology has been developed for mapping placer heavy minerals and dispersed hydrocarbon plumes in the open ocean. The approach uses induced polarization (IP), an electrical measurement that encompasses several different surface-reactive capacitive and electrochemical phenomena, and thus is ideally suited for mapping dispersed or disseminated targets. The application is operated at sea by towing active electrical geophysical streamers behind a ship; a wide area can be covered in three dimensions by folding tow-paths over each other in lawn-mower fashion. This technology has already been proven in laboratory and ocean settings to detect IP-reactive titanium- and rare-earth (REE) minerals such as ilmenite and monazite. By extension, minerals that weather and accumulate/concentrate by a similar mechanism, including gold, platinum, and diamonds, may be rapidly detected and mapped indirectly- even when dispersed and covered with thick, inert sediment. IP is also highly reactive to metal structures such as pipelines and cables. Currently, the only means for mapping an oil-spill plume is to park a large ship in the ocean and drop a sampling string over the side, requiring hours of time per sampling point. The samples must then be chemically analyzed, adding additional time and expense. We believe that an extension of the marine IP technology could also apply to rapidly mapping both seafloor- blanket and disseminated hydrocarbon plumes in the open ocean, as hydrocarbon droplets in conductive seawater are topologically equivalent to a metal-plates-and-dielectric capacitor. Because the effective capacitance would be frequency-dependent on droplet size, the approach we advocate holds the potential to not only map, but also to characterize the evolution and degradation of such a plume over time. In areas where offshore oil field development has been practiced for extended periods, making IP measurements from a towed streamer may be useful for locating buried - nd exposed pipelines, as well as pipeline leaks. We believe this technique will be a more cost-effective method than drop-sampling to map and monitor hydrocarbon plumes in open ocean settings. A marine induced polarization system was used successfully to map a 15 km &times; 45 km swath of the ocean floor off eastern South Africa with 3-meter sampling along 200-meter-separated profiles. The survey detected titanium-bearing sands up to 15 meters below the seafloor. From preliminary laboratory work it is apparent that we can extend this technology to monitor significant environmental problems including anthropogenic and industrial waste washed into sensitive estuaries and sounds during storm-water runoff episodes, and also to map and characterize dispersed oil plumes in the seawater column in three dimensions, as well as movement and dispersal of both over time.

Conference Paper↗

Petroleum geology and total petroleum systems of the Widyan Basin and Interior Platform of Saudi Arabia and Iraq

Two total petroleum systems are associated with the Widyan Basin - Interior Platform Province in northern Saudi Arabia and western Iraq. In the Paleozoic Qusaiba/Akkas/Abba/ Mudawwara Total Petroleum System, which consists of one assessment unit - the Horst/Graben-Related Oil and Gas Assessment Unit - high-gravity, low-sulfur crude oil, as well as natural gas, occurs in horst/graben-related traps that formed prior to, during, and after Hercynian deformation (Carboniferous). The source of oil and gas is from organic-rich marine shale at the base of the Silurian sedimentary sequence (Qusaiba, Akkas, Mudawwara, and Abba Formations) that was deposited under dysoxic to anoxic conditions in an intra-shelf basin located north of the Central Arabian Arch. Onset of oil generation in Iraq began about 250 million years ago (Ma) and in eastern Saudi Arabia about 160 Ma, reaching peak generation, expulsion, migration, and entrapment during the Jurassic Period. In Saudi Arabia, petroleum migrated into fluvial and eolian quartzose sandstones of the Carboniferous-Early Permian Unayzah Formation that overlies the Hercynian unconformity, filling in rifts and half-grabens to thicknesses ranging to more than 400 meters. Combined stratigraphic-structural traps exist where the Unayzah Formation is the reservoir, as is the case in central Saudi Arabia. Oil and gas are sealed in those reservoirs by overlying tight carbonate- evaporite strata, and by subunconformity pinchouts of Pre-Unayzah clastic reservoir units against impermeable facies. In Iraq, reservoirs are sandstones of the Ordovician Upper Khabour and Silurian Akkas Formations. Over most of the Southwestern Desert of Iraq, Lower Silurian shale is a seal for hydrocarbons in the underlying Ordovician Khabour Formation. The Jurassic Gotnia/Barsarin/Sargelu/Najmah Total Petroleum System has two assessment units: the Platform Horst/Graben- Related Oil Assessment Unit and the Basinal Oil and Gas Assessment Unit. All reservoirs are in the Upper Jurassic Najmah Limestone and Gotnia Formation in Iraq, and the correlative Arab Formation in Saudi Arabia, occurring as lenses of marine bar or shelf-margin calcarenites, calcarenitic limestone, and dolomite. These strata grade eastward into organic-rich source rocks that were deposited under anoxic and dysoxic conditions in three restricted intra-shelf basins - from north to south, the Gotnia, Arabian, and Southern Arabian Gulf Basins. Maturation of the Upper Jurassic source-rock formations (Sargelu and Naokelekan Formations in Iraq) began around 90 Ma; peak generation took place from 85 to 13 Ma. With time, the oil migrated updip and was trapped in calcarenite lenses. Later, oil remigrated and was trapped in anticlines that began to form in Early Cretaceous time. Younger Jurassic shale and anhydrite seal rocks are distributed throughout the total petroleum system. The Widyan Basin-Interior Platform Province (2023) ranks 17th in the world, exclusive of the United States, with 62.5 billion barrels of oil equivalent of total petroleum endowment (cumulative production plus remaining petroleum plus estimated mean undiscovered volumes). Mean estimates of undiscovered petroleum for the province, which includes both Paleozoic and Jurassic petroleum systems as well as portions of three additional total petroleum systems from adjacent provinces, are 21.22 billion barrels of oil, 94.75 trillion cubic feet of gas (15.8 billion barrels of oil equivalent), and 6.85 billion barrels of natural gas liquids. The Paleozoic total petroleum system is dominantly gas prone, whereas the volumetrically larger Jurassic total petroleum system is oil prone - resulting in the characterization of the province as an oil province. The discovery maturity for the province is a relatively low 31 percent, meaning that much of the province petroleum potential lies in the future.

Arabian Peninsula↗

Aquaculture disturbance impacts the diet but not ecological linkages of a ubiquitous predatory fish

Aquaculture operations are a frequent and prominent cause of anthropogenic disturbance to marine and estuarine communities and may alter species composition and abundance. However, little is known about how such disturbances affect trophic linkages or ecosystem functions. In Puget Sound, Washington, aquaculture of the Pacific geoduck clam ( Panopea generosa ) is increasing and involves placing nets and polyvinyl chloride (PVC) tubes in intertidal areas to protect juvenile geoducks from predators. Initial studies of the structured phase of the farming cycle have documented limited impacts on the abundance of some species. To examine the effect of geoduck aquaculture on ecological linkages, the trophic relationships of a local ubiquitous consumer, Pacific staghorn sculpin ( Leptocottus armatus ), to its invertebrate prey were compared between geoduck aquaculture sites and nearby reference areas with no aquaculture. Mark-recapture data indicated that sculpin exhibit local site fidelity to cultured and reference areas. The stomach contents of sculpin and stable isotope signatures of sculpin and their prey were examined to study the trophic ecology of cultured and reference areas. Results showed that the structured phase of geoduck aquaculture initiated some changes to staghorn sculpin ecology, as reflected in sculpin diet through stomach content analysis. However, carbon and nitrogen stable isotopes revealed that the general food web function of sculpin remained unchanged. The source of carbon at the base of the food web and the trophic position of sculpin were not impacted by geoduck aquaculture. The study has important implications for geoduck aquaculture management and will inform regulatory decisions related to shellfish aquaculture policy.

Washington↗

40Ar/39Ar age of the Manson impact structure, Iowa, and correlative impact ejecta in the Crow Creek member of the Pierre Shale (Upper Cretaceous), South Dakota and Nebraska

A set of 34 laser total-fusion 40 Ar/ 39 Ar analyses of sanidine from a melt layer in crater-fill deposits of the Manson impact structure in Iowa has a weighted-mean age of 74.1 ± 0.1 Ma. This age is about 9.0 m.y. older than 40 Ar/ 39 Ar ages of shocked microcline from the Manson impact structure reported previously by others. The 74.1 Ma age of the sanidine, which is a melt product of Precambrian microcline clasts, indicates that the Manson impact structure played no part in the Cretaceous-Tertiary (K-T) mass extinction at 64.5 Ma. Moreover, incremental-heating 40 Ar/ 39 Ar ages of the sanidine show that it is essentially free of excess 40 Ar and has not been influenced by postcrystallization heating or alteration. An age spectrum of the matrix of the melt layer shows effects of 39 Ar recoil, including older ages in the low-temperature increments and younger ages in the high-temperature increments. At 17 places in eastern South Dakota and Nebraska, shocked quartz and feldspar grains are concentrated in the lower part of the Crow Creek Member of the Pierre Shale (Upper Cretaceous). The grains are largest (3.2 mm) in southeastern South Dakota and decrease in size (0.45 mm) to the northwest, consistent with the idea that the Manson impact structure was their source. The ubiquitous presence of shocked grains concentrated in a thin calcarenite at the base of the Crow Creek Member suggests it is an event bed recording an instant of geologic time. Ammonites below and above the Crow Creek Member limit its age to the zone of Didymoceras nebrascense of earliest late Campanian age. Plagioclase from a bentonite bed in this zone in Colorado has a 40 Ar/ 39 Ar age of 74.1 ± 0.1 Ma commensurate with our sanidine age of 74.1 Ma for the Manson impact structure. 40 Ar/ 39 Ar ages of bentonite beds below and above the Crow Creek are consistent with our 74.1 ± 0.1 Ma age for the Manson impact structure and limit its age to the interval ±74.5 0.1 to 73.8 ± 0.1 Ma. Recently, two origins for the Crow Creek have been proposed—eastward transgression of the Late Cretaceous sea and a Manson impact-triggered tsunami. We conclude that most data are in accord with an impact origin for the Crow Creek Member and are at odds with the marine transgression hypothesis.

Iowa, Nebraska, South Dakota↗

Subsurface geology of the upper Cretaceous Kirtland and Fruitland formations of the San Juan Basin, New Mexico and Colorado

The San Juan Basin is an asymmetrical structural basin in northwestern New Mexico and southwestern Colorado. The basin contains sedimentary rocks ranging from Cambrian through Recent in age and attaining a maximum thickness between 14,000 and 15,000 feet. The Upper Cretaceous sedimentary rocks exceed 8,000 feet in thickness and can be divided into two groups: the lower Upper Cretaceous which is composed of the non marine and non-marine rocks and the upper Upper Cretaceous which is composed of the non-marine Kirtland and Fruitland Formations. The Kirtland Shale is subdivided into the lower shale, Farmington Sandstone, and upper shale members. The rocks of the Kirtland and Fruitland Formations consist of fluviatile and flood plain deposits and range in thickness from 1750 feet in the northwest part of the basin to 0 feet on the eastside of the basin. The thinning of the Kirtland and Fruitland Formations from west to east is primarily the result of erosion following tilting of the San Juan Basin area toward the west after either part or all of the upper shale member had been deposited. The overlying Ojo Alamo Sandstone rests on progressively older rocks across the basin overstepping the under lying upper shale member, Farmington Sandstone Member, Fruitland Formation, and finally resting on the Lewis Shale on the east side of the basin. The source area for the rocks of the Kirtland and Fruitland Formations was probably to the north or northwest of the San Juan Basin area. The Kirtland and Fruitland rocks have produced minor amounts of oil and gas. The Fruitland Formation contains large coal deposits some of which are currently being strip mined near Fruitland, New Mexico

Colorado, New Mexico↗