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At least 577 records · Page 32Linked to original sources

Groundwater/surface-water interactions in the Partridge River Basin and evaluation of hypothetical future mine pits, Minnesota

The Partridge River Basin (PRB) covers 156 square miles in northeastern Minnesota with headwaters in the Mesabi Iron Range. The basin is characterized by extensive wetlands, lakes, and streams in poorly drained and often thin glacial material overlying Proterozoic bedrock. To better understand the interaction between these extensive surface water features and the groundwater system, a three-dimensional, steady-state, groundwater-flow model of the PRB was developed by the U.S. Geological Survey in cooperation with the Great Lakes Indian Fish & Wildlife Commission using the finite-difference computer code MODFLOW-NWT. The model simulates steady-state base flow in streams and groundwater interactions using the streamflow routing (SFR2) package. Existing mining features including tailings basins, stockpiles, pumped mine pits, and flooded mine pits were simulated using either high hydraulic conductivity zones or the drain (DRN) package. The unsaturated zone flow (UZF) package was used to better represent the groundwater system in areas with a high water table and for wetlands often associated with such areas. UZF typically is used to represent unsaturated zone processes but also can simulate the rejection of recharge and groundwater discharge to the land surface when the water table is near land surface. The steady-state model used data from the 2011 to 2013 period when 2011 high-resolution land surface (light detecting and ranging [lidar]) data were available that reflected land-surface and water elevations from mining activity in the basin. The parameter-estimation software suite PEST_HP was used to obtain a best fit of the modeled to measured groundwater levels, streamflow, pit inflow rates, and mapped peat deposits. The PEST calibration used the target residuals from two models with the same model parameters and targets from two separate periods: (1) a 1995–2015 calibration model, which provided a larger number of calibration targets, and (2) a 2011–2013 mining conditions model, which included calibration targets that reflected conditions consistent with the modeled mine-workings topography. Calibration of the PRB model resulted in ranges of glacial horizontal hydraulic conductivity parameters that generally agreed with literature values and other models of the region. Horizontal hydraulic conductivity of the bedrock was higher in the upper bedrock layers where numerous and continuous fractures have been observed and lower in the deeper bedrock layers. Average basin-wide calibrated infiltration was 5.3 inches per year. An average of 4.6 inches per year of infiltration crosses the water table and becomes recharge and 0.7 inch per year is rejected by UZF due to saturated conditions at the land surface. Simulated groundwater runoff (the sum of rejected recharge and groundwater seepage to the land surface) can either be routed to streams or removed from the model as evapotranspiration. The calibrated model indicates relatively shallow groundwater-flow paths dominating and approximately 50 percent of the stream base flow coming from groundwater runoff. The 2011–2013 mining conditions model was then used to develop five model scenarios simulating the response of the groundwater and surface-water system to potential hydrologic stress. The purpose of these mine pit scenarios is to present a possible workflow to quantify a model’s uncertainty for a given model forecast and serve as a possible guide for initial data collection that may improve a future model’s ability to make such a forecast. The scenarios included one scenario with the currently existing Peter Mitchell pit at final buildout and flooded to an elevation of 1,500 feet, and four scenarios with a hypothetical, new mine pit plus the flooded Peter Mitchell at final buildout. The five model scenarios were used to forecast streamflow at six locations in the PRB, pit inflow rates for the new mine pits and the flooded Peter Mitchell pit, and the average depth to water in 12 wetlands. A linear uncertainty analysis was performed using information from the PEST calibration and tools in the PyEMU python package to assess model uncertainty propagation to the model forecasts. Streamflows generally were reduced with future mining and the greatest streamflow reductions occurred from the flooded Peter Mitchell Pit, probably due to its large size. Average depth to groundwater in wetlands was most affected the closer the wetland was to a new mine pit. Linear uncertainty methods were also used to evaluate data worth, which is the ability for potential new groundwater elevation observations to reduce the uncertainty in scenario forecasts. Data worth was performed for a grid of new hydraulic head observations. Overall, areas with nonnegligible data worth generally corresponded to wetland areas with no groundwater seepage to land surface from UZF. These model behaviors indicated that the land-surface boundary condition simulated by the UZF package was pinning the groundwater elevations to the land surface in areas with groundwater seepage (33 percent of the 2011–2013 base conditions model) such that the sensitivity to new observations in these areas was minimal. Therefore, representing wetlands as boundary conditions minimized the usefulness of data worth calculations because wetland areas were present over a large part of the model domain. Probabilistic capture zones were estimated for each of the mines in the model scenarios. A capture zone represents the area contributing recharge to a model feature, like a well or a mine pit, and can be calculated by forward tracking particles from the water table. By using Monte Carlo techniques, it is possible to generate estimated capture zones that include the probability of recharge capture given the uncertainty present in the model. Monte Carlo techniques use randomly generated model parameter sets sampled from a plausible parameter range to create many possible realizations. The resulting capture zone arrays were calculated by tallying the total number of realizations in which a particle from a model cell was captured by the feature. Probabilities from the Monte Carlo runs ranged from 1 (captured in 100 percent of the runs) near the pits to 0 (captured in 0 percent of the runs) at the edges of the capture zone. Capture zones were not always spatially continuous; for example, the capture zone for the proposed mine pits south of the flooded Peter Mitchell pit was discontinuous with capture surrounding the proposed mine pit and north of the flooded Peter Mitchell pit. This northern section represents deeper groundwater flow paths that originate in the topographic high, move under the flooded pit, and discharge into the proposed pit. This pattern of capture indicates the possibility of some deeper flow through the upper fractured bedrock when the shallow groundwater flow system is modified. These results underscore that future site-specific applications of the base condition model require the input of site-specific data and recalibration to focus on the site of interest.

Minnesota↗

RAINFALL-LOSS PARAMETER ESTIMATION FOR ILLINOIS.

The U. S. Geological Survey is currently conducting an investigation to estimate values of parameters for two rainfall-loss computation methods used in a commonly used flood-hydrograph model. Estimates of six rainfall-loss parameters are required: four for the Exponential Loss-Rate method and two for the Initial and Uniform Loss-Rate method. Multiple regression analyses on calibrated data from 616 storms at 98 gaged basins are being used to develop parameter-estimating techniques for these six parameters at ungaged basins in Illinois. Parameter-estimating techniques are being verified using data from a total of 105 storms at 35 uncalibrated gaged basins.

Conference Paper↗

GCLAS: a graphical constituent loading analysis system

The U. S. Geological Survey has developed a program called GCLAS (Graphical Constituent Loading Analysis System) to aid in the computation of daily constituent loads transported in stream flow. Due to the relative paucity with which most water-quality data are collected, computation of daily constituent loads is moderately to highly dependent on human interpretation of the relation between stream hydraulics and constituent transport. GCLAS provides a visual environment for evaluating the relation between hydraulic and other covariate time series and the constituent chemograph. GCLAS replaces the computer program Sedcalc, which is the most recent USGS sanctioned tool for constructing sediment chemographs and computing suspended-sediment loads. Written in a portable language, GCLAS has an interactive graphical interface that permits easy entry of estimated values and provides new tools to aid in making those estimates. The use of a portable language for program development imparts a degree of computer platform independence that was difficult to obtain in the past, making implementation more straightforward within the USGS' s diverse computing environment. Some of the improvements introduced in GCLAS include (1) the ability to directly handle periods of zero or reverse flow, (2) the ability to analyze and apply coefficient adjustments to concentrations as a function of time, streamflow, or both, (3) the ability to compute discharges of constituents other than suspended sediment, (4) the ability to easily view data related to the chemograph at different levels of detail, and (5) the ability to readily display covariate time series data to provide enhanced visual cues for drawing the constituent chemograph.

Conference Paper↗

Documentation of a computer program to simulate lake-aquifer interaction using the MODFLOW ground water flow model and the MOC3D solute-transport model

Heads and flow patterns in surficial aquifers can be strongly influenced by the presence of stationary surface-water bodies (lakes) that are in direct contact, vertically and laterally, with the aquifer. Conversely, lake stages can be significantly affected by the volume of water that seeps through the lakebed that separates the lake from the aquifer. For these reasons, a set of computer subroutines called the Lake Package (LAK3) was developed to represent lake/aquifer interaction in numerical simulations using the U.S. Geological Survey three-dimensional, finite-difference, modular ground-water flow model MODFLOW and the U.S. Geological Survey three-dimensional method-of-characteristics solute-transport model MOC3D. In the Lake Package described in this report, a lake is represented as a volume of space within the model grid which consists of inactive cells extending downward from the upper surface of the grid. Active model grid cells bordering this space, representing the adjacent aquifer, exchange water with the lake at a rate determined by the relative heads and by conductances that are based on grid cell dimensions, hydraulic conductivities of the aquifer material, and user-specified leakance distributions that represent the resistance to flow through the material of the lakebed. Parts of the lake may become "dry" as upper layers of the model are dewatered, with a concomitant reduction in lake surface area, and may subsequently rewet when aquifer heads rise. An empirical approximation has been encoded to simulate the rewetting of a lake that becomes completely dry. The variations of lake stages are determined by independent water budgets computed for each lake in the model grid. This lake budget process makes the package a simulator of the response of lake stage to hydraulic stresses applied to the aquifer. Implementation of a lake water budget requires input of parameters including those representing the rate of lake atmospheric recharge and evaporation, overland runoff, and the rate of any direct withdrawal from, or augmentation of, the lake volume. The lake/aquifer interaction may be simulated in both transient and steady-state flow conditions, and the user may specify that lake stages be computed explicitly, semi-implicitly, or fully-implicitly in transient simulations. The lakes, and all sources of water entering the lakes, may have solute concentrations associated with them for use in solute-transport simulations using MOC3D. The Stream Package of MODFLOW-2000 and MOC3D represents stream connections to lakes, either as inflows or outflows. Because lakes with irregular bathymetry can exist as separate pools of water at lower stages, that coalesce to become a single body of water at higher stages, logic was added to the Lake Package to allow the representation of this process as a user option. If this option is selected, a system of linked pools (sublakes) is identified in each time step and stages are equalized based on current relative sublake surface areas.

Water-Resources Investigations Report↗

Computation of bromide concentrations at the Kansas River at De Soto, Kansas, January 2021 through October 2023

The Kansas River is an essential water resource that provides drinking water to more than 950,000 people in northeastern Kansas. Water suppliers that rely on the Kansas River as a water-supply source use physical and chemical water-treatment strategies to remove contaminants before distribution. Water District No. 1 of Johnson County, Kansas (WaterOne), is the largest water supplier in the State and uses the Kansas and Missouri Rivers as water-supply sources to provide drinking water to the Kansas City metropolitan area. WaterOne has been using ozone disinfection as a primary water-treatment strategy since the summer of 2020. Water suppliers that rely on ozone disinfection have become increasingly concerned with the presence of elevated dissolved bromide (the negatively charged form of bromine; hereafter referred to as “bromide”) concentrations in their water-supply source. Ozone disinfection of source water containing elevated concentrations of bromide can lead to the formation of bromate, a regulated disinfection byproduct and probable carcinogen. Real-time computations of bromide concentrations upstream from the WaterOne source-water intake in the Kansas River can be used to assist WaterOne with proactive adjustment of water-treatment strategies. These computations can also be used to advance understanding of hydrologic processes affecting ozone disinfection and formation of bromate. This report documents the development of the surrogate-regression model that computes bromide concentrations in real time at De Soto, Kansas, and characterizes daily and monthly bromide concentrations at this location during the study period. The U.S. Geological Survey (USGS), in cooperation with WaterOne, collected specific conductance and discrete bromide sample data at the USGS streamgage Kansas River at De Soto, Kans. (06892350; hereafter referred to as “De Soto”), during January 2021 through October 2023 to develop a surrogate-regression model using ordinary least-squares regression that computes bromide concentrations at De Soto, which is about 15 miles upstream from the WaterOne source-water intake in the Kansas River. Specific conductance explained about 85 percent of the variance in bromide concentrations at De Soto during the study period. The surrogate-regression model documented in this report estimated that bromide concentrations at De Soto were likely to exceed the WaterOne water-treatment level of concern (150 micrograms per liter [μg/L]) when specific conductance was greater than or equal to about 930 microsiemens per centimeter at 25 degrees Celsius. Surrogate-regression model computations of bromide concentrations documented in this report are available at the USGS National Real-Time Water-Quality website ( https://nrtwq.usgs.gov/ ). Bromide concentrations in discrete samples ranged from 31.9 to 251 μg/L and exceeded the water-treatment level of concern in about 34 percent of the 41 samples collected at De Soto during January 2021 through October 2023. Computed daily bromide concentrations ranged from 38.2 to 277 μg/L and exceeded the water-treatment level of concern about 46 percent of the time during January 2021 through October 2023. Generally, an inverse relation was observed between bromide and streamflow during the study period. Higher bromide concentrations were observed during September through February, and lower bromide concentrations were observed during March through August. Seasonal median bromide concentrations were significantly different in all pairwise seasonal combinations, except for summer versus spring. Computed median bromide concentrations were highest during winter, followed by fall, then spring and summer.

Kansas↗

Colorado River Basin Actionable and Strategic Integrated Science and Technology (ASIST) pilot project progress toward an information management and technology plan

Executive Summary The U.S. Geological Survey carries out a wide variety of multidisciplinary science projects through the Bureau’s regions, mission areas, programs, and science centers. However, this structure can limit interactions among individual scientists, segregate data holdings, and make it difficult to apply holistic, interdisciplinary science. In addition, technological advances in sensors, data storage and analysis, computing power, and networking have resulted in an exponential growth in the volume, variety, and complexity of data. To address some of these challenges, the U.S. Geological Survey initiated the Colorado River Basin Actionable and Strategic Integrated Science and Technology (ASIST) pilot project to facilitate interdisciplinary science in the drought-stricken basin and apply information management and technology (IMT) resources that can be used to deliver actionable science efficiently and effectively. In fiscal year 2021, the Data Management and Advanced Technology subgroup of the ASIST pilot project worked toward developing an IMT plan that includes several advanced IMT solutions that are being implemented Bureau-wide by the Office of the Associate Chief Information Officer. This plan identifies applications, opportunities, and steps to leverage new and existing technologies, data, models, and knowledge to support integrated science projects across the Colorado River Basin. The subgroup also created an inventory of available IMT resources and their locations. The Colorado River Basin ASIST pilot project also developed a multiyear approach to build capacity for supporting integrated science projects in the Colorado River Basin, which provides an advanced IMT framework for expediting the production of interdisciplinary science related to the basin.

Colorado River basin↗

Methods for Processing and Summarizing Time-Series Temperature Data Collected as Part of the National Water-Quality Assessment Program Studies on the Effects of Urbanization on Stream Ecosystems

Temperature data and summary statistics are presented for 256 sites in 9 metropolitan areas as part of the U.S. Geological Survey National Water-Quality Assessment Program studies of the effects of urbanization on stream ecosystems. The computer program (GRAN) that was developed to derive uniform data granularity and calculate temperature statistics (means, standard deviations, rates of change, degree days) is described, as are the methods used to estimate missing daily mean temperatures, degree days (annual and summer periods), and 7-day running averages of daily mean temperatures.

Data Series↗

Williston Basin groundwater availability, United States and Canada

The Williston Basin contains important oil and gas resources for the Nation. Freshwater supplies are limited in this semiarid area, and oil and gas development can require large volumes of freshwater. Groundwater is the primary source of water for many water users in the Williston Basin, so to better understand these resources, the U.S. Geological Survey (USGS) assessed the groundwater availability in this area. The final phase of this assessment included a computer model that simulates how groundwater flows in the aquifer systems and simulates how changes in water use and natural conditions may affect the water resources. These results provide a tool for land and water-resource managers to determine how water can be used for multiple purposes in the Williston Basin. For additional information about this assessment and more in-depth descriptions and results, see Long and others (2018).

Williston Basin↗

A compendium of P- and S-wave velocities from surface-to-borehole logging; summary and reanalysis of previously published data and analysis of unpublished data

For over 28 years, the U.S. Geological Survey (USGS) has been acquiring seismic velocity and geologic data at a number of locations in California, many of which were chosen because strong ground motions from earthquakes were recorded at the sites. The method for all measurements involves picking first arrivals of P- and S-waves from a surface source recorded at various depths in a borehole (as opposed to noninvasive methods, such as the SASW method [e.g., Brown et al., 2002]). The results from most of the sites are contained in a series of U.S. Geological Survey Open-File Reports (see References). Until now, none of the results have been available as computer files, and before 1992 the interpretation of the arrival times was in terms of piecemeal interval velocities, with no attempt to derive a layered model that would fit the travel times in an overall sense (the one exception is Porcella, 1984). In this report I reanalyze all of the arrival times in terms of layered models for P- and for S-wave velocities at each site, and I provide the results as computer files. In addition to the measurements reported in the open-file reports, I also include some borehole results from other reports, as well as some results never before published. I include data for 277 boreholes (at the time of this writing; more will be added to the web site as they are obtained), all in California (I have data from boreholes in Washington and Utah, but these will be published separately). I am also in the process of interpreting travel time data obtained using a seismic cone penetrometer at hundreds of sites; these data can be interpreted in the same way of those obtained from surface-to-borehole logging. When available, the data will be added to the web site (see below for information on obtaining data from the World Wide Web (WWW)). In addition to the basic borehole data and results, I provide information concerning strong-motion stations that I judge to be close enough to the boreholes that the borehole velocity models can be used as the velocity models beneath the stations.

California↗

Volcanogenic Massive Sulfide Deposits of the World - Database and Grade and Tonnage Models

Grade and tonnage models are useful in quantitative mineral-resource assessments. The models and database presented in this report are an update of earlier publications about volcanogenic massive sulfide (VMS) deposits. These VMS deposits include what were formerly classified as kuroko, Cyprus, and Besshi deposits. The update was necessary because of new information about some deposits, changes in information in some deposits, such as grades, tonnages, or ages, revised locations of some deposits, and reclassification of subtypes. In this report we have added new VMS deposits and removed a few incorrectly classified deposits. This global compilation of VMS deposits contains 1,090 deposits; however, it was not our intent to include every known deposit in the world. The data was recently used for mineral-deposit density models (Mosier and others, 2007; Singer, 2008). In this paper, 867 deposits were used to construct revised grade and tonnage models. Our new models are based on a reclassification of deposits based on host lithologies: Felsic, Bimodal-Mafic, and Mafic volcanogenic massive sulfide deposits. Mineral-deposit models are important in exploration planning and quantitative resource assessments for two reasons: (1) grades and tonnages among deposit types vary significantly, and (2) deposits of different types occur in distinct geologic settings that can be identified from geologic maps. Mineral-deposit models combine the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Globally based deposit models allow recognition of important features and demonstrate how common different features are. Well-designed deposit models allow geologists to deduce possible mineral-deposit types in a given geologic environment and economists to determine the possible economic viability of these resources. Thus, mineral-deposit models play a central role in presenting geoscience information in a useful form to policy makers. The foundation of mineral-deposit models is information about known deposits. The purpose of this publication is to present the latest geologic information and newly developed grade and tonnage models for VMS deposits in digital form. This publication contains computer files with information on VMS deposits from around the world. It also presents new grade and tonnage models for three subtypes of VMS deposits and a text file allowing locations of all deposits to be plotted in geographic information system (GIS) programs. The data are presented in FileMaker Pro and text files to make the information available to a wider audience. The value of this information and any derived analyses depends critically on the consistent manner of data gathering. For this reason, we first discuss the rules used in this compilation. Next, we provide new grade and tonnage models and analysis of the information in the file. Finally, the fields of the data file are explained. Appendix A gives the summary statistics for the new grade-tonnage models and Appendix B displays the country codes used in the database.

Open-File Report↗

Geographic information system programs for use in the water-supply-allocation permitting process

Computer programs designed for use in a geographic information system as an aid in the water-supply- allocation permitting process are described. These programs were developed by the U.S. Geological Survey during a project conducted in cooperation with the New Jersey Department of Environmental Protection. The programs enable a user to display proposed water-supply-allocation sites in a defined area together with present sites and important hydrologic and geographic features on a computer screen or on hardcopy plots. The programs are menu-driven and do not require familiarity with geographic information systems. Source codes for the programs are included in appendixes.

Open-File Report↗

Comparison of peak-flow estimation methods for small drainage basins in Maine

Understanding the accuracy of commonly used methods for estimating peak streamflows is important because the designs of bridges, culverts, and other river structures are based on these flows. Different methods for estimating peak streamflows were analyzed for small drainage basins in Maine. For the smallest basins, with drainage areas of 0.2 to 1.0 square mile, nine peak streamflows from actual rainfall events at four crest-stage gaging stations were modeled by the Rational Method and the Natural Resource Conservation Service TR-20 method and compared to observed peak flows. The Rational Method had a root mean square error (RMSE) of -69.7 to 230 percent (which means that approximately two thirds of the modeled flows were within -69.7 to 230 percent of the observed flows). The TR-20 method had an RMSE of -98.0 to 5,010 percent. Both the Rational Method and TR-20 underestimated the observed flows in most cases. For small basins, with drainage areas of 1.0 to 10 square miles, modeled peak flows were compared to observed statistical peak flows with return periods of 2, 50, and 100 years for 17 streams in Maine and adjoining parts of New Hampshire. Peak flows were modeled by the Rational Method, the Natural Resources Conservation Service TR-20 method, U.S. Geological Survey regression equations, and the Probabilistic Rational Method. The regression equations were the most accurate method of computing peak flows in Maine for streams with drainage areas of 1.0 to 10 square miles with an RMSE of -34.3 to 52.2 percent for 50-year peak flows. The Probabilistic Rational Method was the next most accurate method (-38.5 to 62.6 percent). The Rational Method (-56.1 to 128 percent) and particularly the TR-20 method (-76.4 to 323 percent) had much larger errors. Both the TR-20 and regression methods had similar numbers of underpredictions and overpredictions. The Rational Method overpredicted most peak flows and the Probabilistic Rational Method tended to overpredict peak flows from the smaller (less than 5 square miles) drainage basins and underpredict peak flows from larger drainage basins. The results of this study are consistent with the most comprehensive analysis of observed and modeled peak streamflows in the United States, which analyzed statistical peak flows from 70 drainage basins in the Midwest and the Northwest.

Maine↗

PRMS-IV, the precipitation-runoff modeling system, version 4

Computer models that simulate the hydrologic cycle at a watershed scale facilitate assessment of variability in climate, biota, geology, and human activities on water availability and flow. This report describes an updated version of the Precipitation-Runoff Modeling System. The Precipitation-Runoff Modeling System is a deterministic, distributed-parameter, physical-process-based modeling system developed to evaluate the response of various combinations of climate and land use on streamflow and general watershed hydrology. Several new model components were developed, and all existing components were updated, to enhance performance and supportability. This report describes the history, application, concepts, organization, and mathematical formulation of the Precipitation-Runoff Modeling System and its model components. This updated version provides improvements in (1) system flexibility for integrated science, (2) verification of conservation of water during simulation, (3) methods for spatial distribution of climate boundary conditions, and (4) methods for simulation of soil-water flow and storage.

Techniques and Methods↗

Development and Application of Watershed Regressions for Pesticides (WARP) for Estimating Atrazine Concentration Distributions in Streams

Regression models were developed for predicting atrazine concentration distributions in rivers and streams, using the Watershed Regressions for Pesticides (WARP) methodology. Separate regression equations were derived for each of nine percentiles of the annual distribution of atrazine concentrations and for the annual time-weighted mean atrazine concentration. In addition, seasonal models were developed for two specific periods of the year--the high season, when the highest atrazine concentrations are expected in streams, and the low season, when concentrations are expected to be low or undetectable. Various nationally available watershed parameters were used as explanatory variables, including atrazine use intensity, soil characteristics, hydrologic parameters, climate and weather variables, land use, and agricultural management practices. Concentration data from 112 river and stream stations sampled as part of the U.S. Geological Survey's National Water-Quality Assessment and National Stream Quality Accounting Network Programs were used for computing the concentration percentiles and mean concentrations used as the response variables in regression models. Tobit regression methods, using maximum likelihood estimation, were used for developing the models because some of the concentration values used for the response variables were censored (reported as less than a detection threshold). Data from 26 stations not used for model development were used for model validation. The annual models accounted for 62 to 77 percent of the variability in concentrations among the 112 model development stations. Atrazine use intensity (the amount of atrazine used in the watershed divided by watershed area) was the most important explanatory variable in all models, but additional watershed parameters significantly increased the amount of variability explained by the models. Predicted concentrations from all 10 models were within a factor of 10 of the observed concentrations at most model development and model validation stations. Results for the two sets of seasonal models were similar. Concentration distributions derived from the seasonal-model predictions provided additional information compared to distributions derived from the annual models.

Water-Resources Investigations Report↗

Mineral resource of the month: iron oxide pigments

The article discusses iron oxide pigments, which have been used as colorants since human began painting as they resist color change due to sunlight exposure, have good chemical resistance and are stable under normal ambient conditions. Cyprus, Italy and Spain are among the countries that are known for the production of iron oxide pigments. Granular forms of iron oxides and nano-sized materials are cited as developments in the synthetic iron oxide pigment industry which are being used in computer disk drives and nuclear magnetic resonance imaging.

Earth↗

Two-dimensional steady-state dispersion in a saturated porous medium

A previously developed analytical solution for two-dimensional dispersion is computed for various conditions. These results were then compared with solution of previously developed approximate models of transverse dispersion which were used to analyze experimentally derived concentration distribution. Comparison established that, whenever steady state was reached, the values of dispersion coefficient computed using the approximate expression agreed with values derived from exact expression and in addition allowed a quick computation of the parameter.

Journal of Research of the U.S. Geological Survey↗

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper↗

Groundwater and surface-water interaction, water quality, and processes affecting loads of dissolved solids, selenium, and uranium in Fountain Creek, near Pueblo, Colorado, 2012–2014

In 2012, the U.S. Geological Survey, in cooperation with the Arkansas River Basin Regional Resource Planning Group, initiated a study of groundwater and surface-water interaction, water quality, and loading of dissolved solids, selenium, and uranium to Fountain Creek near Pueblo, Colorado, to improve understanding of sources and processes affecting loading of these constituents to streams in the Arkansas River Basin. Fourteen monitoring wells were installed in a series of three transects across Fountain Creek near Pueblo, and temporary streamgages were established at each transect to facilitate data collection for the study. Groundwater and surface-water interaction was characterized by using hydrogeologic mapping, groundwater and stream-surface levels, groundwater and stream temperatures, vertical hydraulic-head gradients and ratios of oxygen and hydrogen isotopes in the hyporheic zone, and streamflow mass-balance measurements. Water quality was characterized by collecting periodic samples from groundwater, surface water, and the hyporheic zone for analysis of dissolved solids, selenium, uranium, and other selected constituents and by evaluating the oxidation-reduction condition for each groundwater sample under different hydrologic conditions throughout the study period. Groundwater loads to Fountain Creek and in-stream loads were computed for the study area, and processes affecting loads of dissolved solids, selenium, and uranium were evaluated on the basis of geology, geochemical conditions, land and water use, and evapoconcentration. During the study period, the groundwater-flow system generally contributed flow to Fountain Creek and its hyporheic zone (as a single system) except for the reach between the north and middle transects. However, the direction of flow between the stream, the hyporheic zone, and the near-stream aquifer was variable in response to streamflow and stage. During periods of low streamflow, Fountain Creek generally gained flow from groundwater. However, during periods of high streamflow, the hydraulic gradient between groundwater and the stream temporarily reversed, causing the stream to lose flow to groundwater. Concentrations of dissolved solids, selenium, and uranium in groundwater generally had greater spatial variability than surface water or hyporheic-zone samples, and constituent concentrations in groundwater generally were greater than in surface water. Constituent concentrations in the hyporheic zone typically were similar to or intermediate between concentrations in groundwater and surface water. Concentrations of dissolved solids, selenium, uranium, and other constituents in groundwater samples collected from wells located on the east side of the north monitoring well transect were substantially greater than for other groundwater, surface-water, and hyporheic-zone samples. With one exception, groundwater samples collected from wells on the east side of the north transect exhibited oxic to mixed (oxic-anoxic) conditions, whereas most other groundwater samples exhibited anoxic to suboxic conditions. Concentrations of dissolved solids, selenium, and uranium in surface water generally increased in a downstream direction along Fountain Creek from the north transect to the south transect and exhibited an inverse relation to streamflow with highest concentration occurring during periods of low streamflow and lowest concentrations occurring during periods of high streamflow. Groundwater loads of dissolved solids, selenium, and uranium to Fountain Creek were small because of the small amount of groundwater flowing to the stream under typical low-streamflow conditions. In-stream loads of dissolved solids, selenium, and uranium in Fountain Creek varied by date, primarily in relation to streamflow at each transect and were much larger than computed constituent loads from groundwater. In-stream loads generally decreased with decreases in streamflow and increased as streamflow increased. In-stream loads of dissolved solids and selenium increased between the north and middle transects but generally decreased between the middle and south transects. By contrast, uranium loads generally decreased between the north and middle transects but increased between the middle and south transects. In-stream load differences between transects appear primarily to be related to differences in streamflow. However, because groundwater typically flows to Fountain Creek under low-flow conditions, and groundwater has greater concentrations of dissolved solids, selenium, and uranium than surface water in Fountain Creek, increases in loads between transects likely are affected by inflow of groundwater to the stream, which can account for a substantial proportion of the in-stream load difference between transects. When loads decreased between transects, the primary cause likely was decreased streamflow as a result of losses to groundwater and flow through the hyporheic zone. However, localized groundwater inflow likely attenuated the magnitude by which the in-stream loads decreased. The combination of localized soluble geologic sources and oxic conditions likely is the primary reason for the occurrence of high concentrations of dissolved solids, selenium, and uranium in groundwater on the east side of the north monitoring well transect. To evaluate conditions potentially responsible for differences in water quality and redox conditions, physical characteristics such as depth to water, saturated thickness, screen depth below the water table, screen height above bedrock, and aquifer hydraulic conductivity were compared by using Wilcoxon rank-sum tests. Results indicated no significant difference between depth to water, screen height above bedrock, and hydraulic conductivity for groundwater samples collected from wells on the east side of the north transect and groundwater samples from all other wells. However, saturated thickness and screen depth below the water table both were significantly smaller for groundwater samples collected from wells on the east side of the north transect than for groundwater samples from other wells, indicating that these characteristics might be related to the elevated constituent concentrations found at that location. Similarly, saturated thickness and screen depth below the water table were significantly smaller for groundwater samples under oxic or mixed (oxic-anoxic) conditions than for those under anoxic to suboxic conditions. The greater constituent concentrations at wells on the east side of the north transect also could, in part, be related to groundwater discharge from an unnamed alluvial drainage located directly upgradient from that location. Although the quantity and quality of water discharging from the drainage is not known, the drainage appears to collect water from a residential area located upgradient to the east of the wells, and groundwater could become concentrated in nitrate and other dissolved constituents before flowing through the drainage. High levels of nitrate, whether from anthropogenic or natural geologic sources, could promote more soluble forms of selenium and other constituents by affecting the redox condition of groundwater. Whether oxic conditions at wells on the east side of the north transect are the result of physical characteristics or of groundwater inflow from the alluvial drainage, the oxic conditions appear to cause increased dissolution of minerals from the shallow shale bedrock at that location. Because ratios of hydrogen and oxygen isotopes indicate evaporation likely has not had a substantial effect on groundwater, constituent concentrations at that location likely are not the result of evapoconcentration.

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