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USGS2005

Trends in surface-water quality at selected National Stream Quality Accounting Network (NASQAN) stations, in Michigan

To demonstrate the value of long-term, water-quality monitoring, the Michigan Department of Environmental Quality (MDEQ), in cooperation with the U.S. Geological Survey (USGS), initiated a study to evaluate potential trends in water-quality constituents for selected National Stream Quality Accounting Network (NASQAN) stations in Michigan. The goal of this study is to assist the MDEQ in evaluating the effectiveness of water-pollution control efforts and the identification of water-quality concerns. The study included a total of nine NASQAN stations in Michigan. Approximately 28 constituents were analyzed for trend tests. Station selection was based on data availability, land-use characteristics, and station priority for the MDEQ Water Chemistry Monitoring Project. Trend analyses were completed using the uncensored Seasonal Kendall Test in the computer program Estimate Trend (ESTREND), a software program for the detection of trends in water-quality data. The parameters chosen for the trend test had (1) at least a 5-year period of record (2) about 5 percent of the observations censored at a single reporting limit, and (3) 40 percent of the values within the beginning one-fifth and ending one-fifth of the selected period. In this study, a negative trend indicates a decrease in concentration of a particular constituent, which generally means an improvement in water quality; whereas a positive trend means an increase in concentration and possible degradation of water quality. The results of the study show an overall improvement in water quality at the Clinton River at Mount Clemens, Manistee River at Manistee, and Pigeon River near Caseville. The detected trend for these stations show decreases in concentrations of various constituents such as nitrogen compounds, conductance, sulfate, fecal coliform bacteria, and fecal streptococci bacteria. The negative trend may indicate an overall improvement in agricultural practices, municipal and industrial wastewater-treatment processes, and effective regulations. Phosphorus data for most of the study stations could not be analyzed because of the data limitations for trend tests. The only station with a significant negative trend in total phosphorus concentration is the Clinton River at Mount Clemens. However, scatter-plot analyses of phosphorus data indicate decreasing concentrations with time for most of the study stations. Positive trends in concentration of nitrogen compounds were detected at the Kalamazoo River near Saugatuck and Muskegon River near Bridgeton. Positive trends in both fecal coliform and total fecal coliform were detected at the Tahquamenon River near Paradise. Various different point and nonpoint sources could produce such positive trends, but most commonly the increase in concentrations of nitrogen compounds and fecal coliform bacteria are associated with agricultural practices and sewage-plant discharges. The constituent with the most numerous and geographically widespread significant trend is pH. The pH levels increased at six out of nine stations on all the major rivers in Michigan, with no negative trend at any station. The cause of pH increase is difficult to determine, as it could be related to a combination of anthropogenic activities and natural processes occurring simultaneously in the environment. Trends in concentration of major ions, such as calcium, sodium, magnesium, sulfate, fluoride, chloride, and potassium, were detected at eight out of nine stations. A negative trend was detected only in sulfate and fluoride concentrations; a positive trend was detected only in calcium concentration. The major ions with the most widespread significant trends are sodium and chloride; three positive and two negative trends were detected for sodium, and three negative and two positive trends were detected for chloride. The negative trends in chloride concentrations outnumbered the positive trends. This result indicates a slight improvement in surface-water quality because chloride as a point source in natural water comes from deicing salt, sewage effluents, industrial wastes, and oil fields. For other major ions, such as magnesium and potassium, both positive and negative trends were detected. These changes in trends indicate changes in surface-water quality caused by a variety of point and non-point sources throughout Michigan, as well as natural changes in the environment.

Michigan↗

USGS2008

Potential Chemical Effects of Changes in the Source of Water Supply for the Albuquerque Bernalillo County Water Utility Authority

Chemical modeling was used by the U.S. Geological Survey, in cooperation with the Albuquerque Bernalillo County Water Utility Authority (henceforth, Authority), to gain insight into the potential chemical effects that could occur in the Authority's water distribution system as a result of changing the source of water used for municipal and industrial supply from ground water to surface water, or to some mixture of the two sources. From historical data, representative samples of ground-water and surface-water chemistry were selected for modeling under a range of environmental conditions anticipated to be present in the distribution system. Mineral phases calculated to have the potential to precipitate from ground water were compared with the compositions of precipitate samples collected from the current water distribution system and with mineral phases calculated to have the potential to precipitate from surface water and ground-water/surface-water mixtures. Several minerals that were calculated to have the potential to precipitate from ground water in the current distribution system were identified in precipitate samples from pipes, reservoirs, and water heaters. These minerals were the calcium carbonates aragonite and calcite, and the iron oxides/hydroxides goethite, hematite, and lepidocrocite. Several other minerals that were indicated by modeling to have the potential to precipitate were not found in precipitate samples. For most of these minerals, either the kinetics of formation were known to be unfavorable under conditions present in the distribution system or the minerals typically are not formed through direct precipitation from aqueous solutions. The minerals with potential to precipitate as simulated for surface-water samples and ground-water/surface-water mixtures were quite similar to the minerals with potential to precipitate from ground-water samples. Based on the modeling results along with kinetic considerations, minerals that appear most likely to either dissolve or newly precipitate when surface water or ground-water/surface-water mixtures are delivered through the Authority's current distribution system are carbonates (particularly aragonite and calcite). Other types of minerals having the potential to dissolve or newly precipitate under conditions present throughout most of the distribution system include a form of silica, an aluminum hyroxide (gibbsite or diaspore), or the Fe-containing mineral Fe3(OH)8. Dissolution of most of these minerals (except perhaps the Fe-containing minerals) is not likely to substantially affect trace-element concentrations or aesthetic characteristics of delivered water, except perhaps hardness. Precipitation of these minerals would probably be of concern only if the quantities of material involved were large enough to clog pipes or fixtures. The mineral Fe3(OH)8 was not found in the current distribution system. Some Fe-containing minerals that were identified in the distribution system were associated with relatively high contents of selected elements, including As, Cr, Cu, Mn, Pb, and Zn. However, these Fe-containing minerals were not identified as minerals likely to dissolve when the source of water was changed from ground water to surface water or a ground-water/surface-water mixture. Based on the modeled potential for calcite precipitation and additional calculations of corrosion indices ground water, surface water, and ground-water/surface-water mixtures are not likely to differ greatly in corrosion potential. In particular, surface water and ground-water/surface-water mixtures do not appear likely to dissolve large quantities of existing calcite and expose metal surfaces in the distribution system to substantially increased corrosion. Instead, modeling calculations indicate that somewhat larger masses of material would tend to precipitate from surface water or ground-water/surface-water mixtures compared to ground water alone.

Scientific Investigations Report↗

USGS2019

Spatial and temporal variability of fish assemblages in acidified streams: Implications for long-term monitoring

Numerous studies have established strong linkages between acid deposition, soil and surface-water acidification, and toxicity to aquatic biota. Little is known however, about the effects of acidification on fish assemblages in headwater streams because they are highly variable, and pre-acidification data are often lacking. The primary purpose of this study was to describe spatial and interannual (temporal) variability of fish assemblages in headwater streams affected by acidification so that future recovery targets and monitoring strategies can be established. Fish communities and water chemistry were sampled at 48 headwater streams in the Western Adirondack Mountains of New York during the summers of 2014 to 2016 to characterize the present-day condition of water quality and local fish assemblages. Additionally, data from six Adirondack streams that were sampled annually from 2014-16 were combined with data from seven streams in the Catskill Mountain region sampled annually for three or more years for an analysis of temporal variability. Inorganic monomeric aluminum concentrations (Ali, the toxic form of Al) were less than 1.0 µmol L-1, between 1 and 2 µmol L-1, and greater than 2 µmol L-1 in 79%, 13%, and 8% of the 48 Adirondack streams. Richness, abundance, and biomass of fish assemblages were negatively related to Ali concentrations. In streams with Ali concentrations less than 1.0 µmol L-1, species richness, density, and biomass averaged 2.0 species, 444.2 fish/0.1 ha, and 1924.4 g/0.1 ha, respectively, and the density and biomass of Brook Trout populations averaged 280.8 fish/0.1 ha and 1384.0 g/0.1 ha. These values may provide a reasonable approximation of fish community condition prior to anthropogenic acidification and can be used as targets for assessing future recovery of acidified streams. A power analysis that considered 21 fish metrics indicated a strong negative relationship between interannual metric variability and statistical power for detecting change over time. Large differences were identified in the sample size necessary to achieve adequate power (0.8) depending on the metric utilized. In general, greater statistical power was obtained from metrics based on entire fish communities and from metrics standardized by reach length or sampling effort. Given the variability observed in our dataset, most metrics could detect a change of 30% with moderate effort, suggesting this may be an appropriate goal for future monitoring. Together, knowledge of biological recovery targets and the statistical power obtained from various fish metrics can be used to develop the most effective strategies for monitoring and assessing biological recovery in New York streams.

New York↗

USGS2022

Laboratory simulation of groundwater along uranium-mining-affected flow paths near the Grand Canyon, Arizona, USA

Mining of volumetrically small, but relatively enriched (average 0.6% U 3 O 8 ) breccia pipe uranium (BPU) deposits near the Grand Canyon, Arizona, USA has the potential to affect groundwater and springs in the area. Such deposits also contain base metal sulfides that can oxidize to generate acid mine drainage and release trace metals. In this study, sequential batch experiments were conducted to simulate the geochemistry of local shallow groundwater that contacts BPU ore and then moves downgradient through sedimentary strata. The experiments simulated shallow groundwater in a carbonate aquifer followed by contact with BPU ore. The experiments subsequently simulated contact with sedimentary rocks and changing oxygen availability. Concentrations of several contaminants of potential concern became substantially elevated in the waters exposed to BPU ore, including As, Co, Ni, U, and Zn, and to a lesser extent, Mo. Of these, Co, Mo, Ni, and U were minimally attenuated by downgradient processes, whereas Zn was partially attenuated. Sb and Tl concentrations were more moderately elevated but also generally minimally attenuated. Although the mixture of elements is particular to these BPU ore deposits, sulfide oxidation in the ore and carbonate buffering of pH by sedimentary rocks generates patterns of water chemistry common in acid mine drainage settings. Ultimately, downgradient concentrations of elements sourced from BPU ore will also be strongly influenced by non-geochemical factors such as the quantities of water contacting BPU materials, heterogeneity of materials along flow paths, and mixing with waters that have not contacted BPU materials.

Arizona↗

USGS2020

Fish growth rates and lake sulphate explain variation in mercury levels in ninespine stickleback (Pungitius pungitius) on the Arctic Coastal Plain of Alaska

Mercury concentrations in freshwater food webs are governed by complex biogeochemical and ecological interactions that spatially vary and are often mediated by climate. The Arctic Coastal Plain of Alaska (ACP) is a heterogeneous, lake-rich landscape where variability in mercury accumulation is poorly understood. Earlier research indicated that the level of catchment influence on lakes varied spatially on the ACP, and affected mercury accumulation in lake sediments. This work sought to determine drivers of spatial variation in mercury accumulation in lake food webs on the ACP. Three lakes that were a priori identified as “high catchment influence” (Reindeer Camp region) and three lakes that were a priori identified as “low catchment influence” (Atqasuk region) were sampled, and variability in water chemistry, food web ecology, and mercury accumulation was investigated. Among-lake differences in ninespine stickleback ( Pungitius pungitius ) length-adjusted methylmercury concentrations were significantly explained by sulphate concentration in lake water, a tracer of catchment runoff input. This effect was mediated by fish growth, which had no pattern between regions. Together, lake water sulphate concentration and fish age-at-size (proxy for growth) accounted for nearly all of the among-lake variability in length-adjusted methylmercury concentrations in stickleback (R 2 adj = 0.94, p < 0.01). The percentage of total mercury as methylmercury (a proxy for net Hg methylation) was higher in sediments of more autochthonous, “low catchment influence” lakes ( p < 0.05), and in the periphyton of more allochthonous, “high catchment influence” lakes (p < 0.05). The results indicate that dominant sources of primary production (littoral macrophyte/biofilm vs. pelagic phytoplankton) and food web structure (detrital vs. grazing) are regulated by catchment characteristics on the ACP, and that this ultimately influences the amount of methylmercury in the aquatic food web. These results have important implications for predicting future mercury concentrations in fish in lakes where fish growth rates and catchment inputs may change in response to a changing climate.

Alaska↗

USGS1963

Chemical character of streams in the Delaware River basin

The water chemistry of streams in the Delaware River basin falls into eight general groups, when mapped according to the prevalent dissolved-solids content and the predominant ions normally found in the water. The approximate regions representing each of these iso-chemical quality groups are shown on the accompanying base map of the drainage basin.

Delaware↗

USGS2012

Evaluating lake stratification and temporal trends by using near-continuous water-quality data from automated profiling systems for water years 2005-09, Lake Mead, Arizona and Nevada

The U.S. Geological Survey, in cooperation with the National Park Service and Southern Nevada Water Authority, collected near-continuous depth-dependent water-quality data at Lake Mead, Arizona and Nevada, as part of a multi-agency monitoring network maintained to provide resource managers with basic data and to gain a better understanding of the hydrodynamics of the lake. Water-quality data-collection stations on Lake Mead were located in shallow water (less than 20 meters) at Las Vegas Bay (Site 3) and Overton Arm, and in deep water (greater than 20 meters) near Sentinel Island and at Virgin and Temple Basins. At each station, near-continual depth-dependent water-quality data were collected from October 2004 through September 2009. The data were collected by using automatic profiling systems equipped with multiparameter water-quality sondes. The sondes had sensors for temperature, specific conductance, dissolved oxygen, pH, turbidity, and depth. Data were collected every 6 hours at 2-meter depth intervals (for shallow-water stations) or 5-meter depth intervals (for deep-water stations) beginning at 1 meter below water surface. Data were analyzed to determine water-quality conditions related to stratification of the lake and temporal trends in water-quality parameters. Three water-quality parameters were the main focus of these analyses: temperature, specific conductance, and dissolved oxygen. Statistical temporal-trend analyses were performed for a single depth at shallow-water stations [Las Vegas Bay (Site 3) and Overton Arm] and for thermally-stratified lake layers at deep-water stations (Sentinel Island and Virgin Basin). The limited period of data collection at the Temple Basin station prevented the application of statistical trend analysis. During the summer months, thermal stratification was not observed at shallow-water stations, nor were major maxima or minima observed for specific-conductance or dissolved-oxygen profiles. A clearly-defined thermocline and well-defined maxima and minima in specific-conductance and dissolved-oxygen profiles were observed at deep-water stations during the summer months. Specific-conductance maxima were likely the result of inflow of water from either the Las Vegas Wash or Muddy/Virgin Rivers or both, while the minima were likely the result of inflow of water from the Colorado River. Maxima and minima for dissolved oxygen were likely the result of primary productivity blooms and their subsequent decay. Temporal-trend analyses indicated that specific conductance decreased at all stations over the period of record, except for Las Vegas Bay (Site 3), where specific conductance increased. Temperature also decreased over the period of record at deep-water stations for certain lake layers. Decreasing temperature and specific conductance at deep-water stations is the result of decreasing values in these parameters in water coming from the Colorado River. Quagga mussels (Dreissena rostriformis bugensis), however, could play a role in trends of decreasing specific conductance through incorporation of calcite in their shells. Trends of decreasing turbidity and pH at deep-water stations support the hypothesis that quagga mussels could be having an effect on the physical properties and water chemistry of Lake Mead. Unlike other stations, Las Vegas Bay (Site 3) had increasing specific conductance and is interpreted as the result of lowering lake levels decreasing the volume of lake water available for mixing and dilution of the high-conductance water coming from Las Vegas Wash. Dissolved oxygen increased over the period of record in some lake layers at the deep-water stations. Increasing dissolved oxygen at deep-water stations is believed to result, in part, from a reduction of phosphorus entering Lake Mead and the concomitant reduction of biological oxygen demand.

Arizona;California;Nevada;Utah↗

USGS2023

Hydrologic framework and characterization of the Little Colorado River alluvial aquifer near Leupp, Arizona

The Little Colorado River alluvial aquifer near Leupp, Arizona, was investigated as a possible source of irrigation water for the Leupp and Birdsprings Chapters of the Navajo Nation. The physical, chemical, and hydraulic characteristics of the alluvial aquifer were studied using geophysical surveys, installation of observation wells, water-level measurements, chemical analyses, groundwater pumping simulations, and review of previous investigations. Geophysical surveys and well borings revealed that the aquifer ranges in thickness from near 0 feet around its periphery to about 100 feet in its thickest parts. Water levels were monitored in nine alluvial wells within the study area and compared with earlier measurements collected in 1998 and 1999. Comparison of those earlier water levels with water levels collected as part of this study showed a decline of between about 5 and 12 feet has occurred in the last 23 years. The water chemistry of the aquifer was analyzed for salinity hazard, sodium-adsorption hazard, and specific-ion toxicity. The sodium-adsorption hazard and specific-ion toxicity of alluvial aquifer water were found to be low. However, the salinity hazard was high enough in most areas that it could negatively affect salt-sensitive crops. Well-field pumping scenarios conducted for this study demonstrated that using groundwater from the alluvial aquifer for irrigated agriculture is theoretically possible but may be economically challenging owing to the hydraulic properties of the aquifer.

Arizona↗

USGS2006

Diatom diversity in chronically versus episodically acidified adirondack streams

The relationship between algal species richness and diversity, and pH is controversial. Furthermore, it is still unknown how episodic stream acidification following atmospheric deposition affects species richness and diversity. Here we analyzed water chemistry and diatom epiphyton dynamics and showed their contrasting behavior in chronically vs. episodically acidic streams in the Adirondack region. Species richness and diversity were significantly higher in the chronically acidic brown water stream, where organic acidity was significantly higher and the ratio of inorganic to organic monomeric aluminum significantly lower. Conversely, in the episodically acidic clear water stream, the inorganic acidity and pH were significantly higher and the diatom communities were very species-poor. This suggests that episodic acidification in the Adirondacks may be more stressful for stream biota than chronic acidity. Strong negative linear relationships between species diversity, Eunotia exigua, and dissolved organic carbon against pH were revealed after the influence of non-linear temporal trends was partialled out using a novel way of temporal modeling. ?? 2006 WILEY-VCH Verlag GmbH & Co. KGaA.

International Review of Hydrobiology↗

USGS2002

Structural instability, multiple stable states, and hysteresis in periphyton driven by phosphorus enrichment in the Everglades

Periphyton is a key component of the Everglades ecosystems. It is a major primary producer, providing food and habitat for a variety of organisms, contributing material to the surface soil, and regulating water chemistry. Periphyton is sensitive to the phosphorus (P) supply and P enrichment has caused dramatic changes in the native Everglades periphyton assemblages. Periphyton also affects P availability by removing P from the water column and depositing a refractory portion into sediment. A quantitative understanding of the response of periphyton assemblages to P supply and its effects on P cycling could provide critical supports to decision making in the conservation and restoration of the Everglades. We constructed a model to examine the interaction between periphyton and P dynamics. The model contains two differential equations: P uptake and periphyton growth are assumed to follow the Monod equation and are limited by a modified logistic equation. Equilibrium and stability analyses suggest that P loading is the driving force and determines the system behavior. The position and number of steady states and the stability also depend upon the rate of sloughing, through which periphyton deposits refractory P into sediment. Multiple equilibria may exist, with two stable equilibria separated by an unstable equilibrium. Due to nonlinear interplay of periphyton and P in this model, catastrophe and hysteresis are likely to occur.

Florida↗

USGS1997

Environmental geochemistry of shale-hosted Ag-Pb-Zn massive sulfide deposits in northwest Alaska: Natural background concentrations of metals in water from mineralized areas

Red Dog, Lik and Drenchwater are shale-hosted stratiform Ag-Pb-Zn massive sulfide deposits in the northwestern Brooks Range. Natural background concentrations of metals in waters from the undisturbed (unmined) Drenchwater prospect and Lik deposit were compared to pre-mining baseline studies conducted at Red Dog. The primary factors affecting water chemistry are the extent of exposure of the deposits, the grade of mineralization, the presence of carbonate reeks in the section, and the proportion of Fe-sulfide in the ore. Surface water samples from the Drenchwater prospect, which has pyrite-dominant mineralization exposed in outcrop, have pH values as low as 2.8 and high dissolved concentrations of metals including as much as 95 mg 1-1 Al, 270 mg 1-1 Fe, 8 ??1-1 Cd, 10 ??1-1 Pb, and 2600 ??1-1 Zn, with As up to 26 ??g1-1. Surface waters from the Red Dog deposit prior to mining were also acidic and metal-rich, however, dissolved metal concentrations in Red Dog waters were many times greater. The higher metal concentrations in Red Dog waters reflect the high Zn grades and the abundant sphalerite, pyrite, and galena that were present in outcrop prior to mining. In contrast, despite significant mineralization at the Lik deposit, carbonate rocks in the section buffer the system, resulting in less acidic, mostly near-neutral pH values with low concentrations of most metals except Zn.

Applied Geochemistry↗

USGS2010

Use of regression‐based models to map sensitivity of aquatic resources to atmospheric deposition in Yosemite National Park, USA

An abundance of exposed bedrock, sparse soil and vegetation, and fast hydrologic flushing rates make aquatic ecosystems in Yosemite National Park susceptible to nutrient enrichment and episodic acidification due to atmospheric deposition of nitrogen (N) and sulfur (S). In this study, multiple linear regression (MLR) models were created to estimate fall‐season nitrate and acid neutralizing capacity (ANC) in surface water in Yosemite wilderness. Input data included estimated winter N deposition, fall‐season surface‐water chemistry measurements at 52 sites, and basin characteristics derived from geographic information system layers of topography, geology, and vegetation. The MLR models accounted for 84% and 70% of the variance in surface‐water nitrate and ANC, respectively. Explanatory variables (and the sign of their coefficients) for nitrate included elevation (positive) and the abundance of neoglacial and talus deposits (positive), unvegetated terrain (positive), alluvium (negative), and riparian (negative) areas in the basins. Explanatory variables for ANC included basin area (positive) and the abundance of metamorphic rocks (positive), unvegetated terrain (negative), water (negative), and winter N deposition (negative) in the basins. The MLR equations were applied to 1407 stream reaches delineated in the National Hydrography Data Set for Yosemite, and maps of predicted surface‐water nitrate and ANC concentrations were created. Predicted surface‐water nitrate concentrations were highest in small, high‐elevation cirques, and concentrations declined downstream. Predicted ANC concentrations showed the opposite pattern, except in high‐elevation areas underlain by metamorphic rocks along the Sierran Crest, which had relatively high predicted ANC (>200 μ eq L −1 ). Maps were created to show where basin characteristics predispose aquatic resources to nutrient enrichment and acidification effects from N and S deposition. The maps can be used to help guide development of water‐quality programs designed to monitor and protect natural resources in national parks.

Yosemite Nataional Park↗

USGS2014

Bouse Formation in the Bristol basin near Amboy, California, USA

Limestone beds underlain and overlain by alluvial fan conglomerate near Amboy, California, are very similar in many respects to parts of the Bouse Formation, suggesting that an arm of the Pliocene Bouse water body extended across a wide part of the southern Mojave Desert. The deposits are north of the town of Amboy at and below an elevation of 290 m, along the northern piedmont of the Bristol “dry” Lake basin. The Amboy outcrops contain the Lawlor Tuff (4.83 Ma), which is also found in an outcrop of the Bouse Formation in the Blythe basin near Buzzards Peak in the Chocolate Mountains, 180 km southeast of Amboy. Bouse exposures near Amboy are &sim;3.4 m thick, white, distinctly bedded, with limestone and calcareous sandstone as well as stromatolite mounds; we interpret these as nearshore deposits. The Bouse at Amboy contains ostracodes, diatoms, and mollusks that indicate saline lake or estuarine environments with an admixture of fresh-water forms. Along with wading bird tracks and a spine from a marine fish, these fossils suggest that the deposits formed in saline waters near a fresh-water source such as a perennial stream. Beds of the outcrop dip southward and are 113 m above the surface of Bristol Playa, where similar age sediments are buried 270+ m deep, indicating significant faulting and vertical tectonics in this part of the Eastern California Shear Zone during the past 5 m.y. Confirmation of the Bouse Formation at Amboy strengthens previous assignments to the Bouse Formation for mudstones in driller logs at Danby “dry” Lake, California, and suggests that areally extensive arms of the Bouse water body were west of the Blythe basin. The Bristol basin arm of the lower Bouse basin probably was restricted from the main water body by narrow passages, but Bouse sediment there is similar to that in the Blythe basin, suggesting generally similar water chemistry and environmental conditions. Examining the degree to which Bouse deposits in the western arms differed from Bouse deposits in the Blythe basin offers an approach to test whether the southernmost Bouse water body was deposited in an estuarine or lacustrine setting.

California↗

USGS2014

Hydrogeologic framework and occurrence, movement, and chemical characterization of groundwater in Dixie Valley, west-central Nevada

Dixie Valley, a primarily undeveloped basin in west-central Nevada, is being considered for groundwater exportation. Proposed pumping would occur from the basin-fill aquifer. In response to proposed exportation, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation and Churchill County, conducted a study to improve the understanding of groundwater resources in Dixie Valley. The objective of this report is to characterize the hydrogeologic framework, the occurrence and movement of groundwater, the general water quality of the basin-fill aquifer, and the potential mixing between basin-fill and geothermal aquifers in Dixie Valley. Various types of geologic, hydrologic, and geochemical data were compiled from previous studies and collected in support of this study. Hydrogeologic units in Dixie Valley were defined to characterize rocks and sediments with similar lithologies and hydraulic properties influencing groundwater flow. Hydraulic properties of the basin-fill deposits were characterized by transmissivity estimated from aquifer tests and specific-capacity tests. Groundwater-level measurements and hydrogeologic-unit data were combined to create a potentiometric surface map and to characterize groundwater occurrence and movement. Subsurface inflow from adjacent valleys into Dixie Valley through the basin-fill aquifer was evaluated using hydraulic gradients and Darcy flux computations. The chemical signature and groundwater quality of the Dixie Valley basin-fill aquifer, and potential mixing between basin-fill and geothermal aquifers, were evaluated using chemical data collected from wells and springs during the current study and from previous investigations. Dixie Valley is the terminus of the Dixie Valley flow system, which includes Pleasant, Jersey, Fairview, Stingaree, Cowkick, and Eastgate Valleys. The freshwater aquifer in the study area is composed of unconsolidated basin-fill deposits of Quaternary age. The basin-fill hydrogeologic unit can be several orders of magnitude more transmissive than surrounding and underlying consolidated rocks and Dixie Valley playa deposits. Transmissivity estimates in the basin fill throughout Dixie Valley ranged from 30 to 45,500 feet squared per day; however, a single transmissivity value of 0.1 foot squared per day was estimated for playa deposits. Groundwater generally flows from the mountain range uplands toward the central valley lowlands and eventually discharges near the playa edge. Potentiometric contours east and west of the playa indicate that groundwater is moving eastward from the Stillwater Range and westward from the Clan Alpine Mountains toward the playa. Similarly, groundwater flows from the southern and northern basin boundaries toward the basin center. Subsurface groundwater flow likely enters Dixie Valley from Fairview and Stingaree Valleys in the south and from Jersey and Pleasant Valleys in the north, but groundwater connections through basin-fill deposits were present only across the Fairview and Jersey Valley divides. Annual subsurface inflow from Fairview and Jersey Valleys ranges from 700 to 1,300 acre-feet per year and from 1,800 to 2,300 acre-feet per year, respectively. Groundwater flow between Dixie, Stingaree, and Pleasant Valleys could occur through less transmissive consolidated rocks, but only flow through basin fill was estimated in this study. Groundwater in the playa is distinct from the freshwater, basin-fill aquifer. Groundwater mixing between basin-fill and playa groundwater systems is physically limited by transmissivity contrasts of about four orders of magnitude. Total dissolved solids in playa deposit groundwater are nearly 440 times greater than total dissolved solids in the basin-fill groundwater. These distinctive physical and chemical flow restrictions indicate that groundwater interaction between the basin fill and playa sediments was minimal during this study period (water years 2009–11). Groundwater in Dixie Valley generally can be characterized as a sodium bicarbonate type, with greater proportions of chloride north of the Dixie Valley playa, and greater proportions of sulfate south of the playa. Analysis of major ion water chemistry data sampled during the study period indicates that groundwater north and south of Township 22N differ chemically. Dixie Valley groundwater quality is marginal when compared with national primary and secondary drinking-water standards. Arsenic and fluoride concentrations exceed primary drinking water standards, and total dissolved solids and manganese concentrations exceed secondary drinking water standards in samples collected during this study. High concentrations of boron and tungsten also were observed. Chemical comparisons between basin-fill and geothermal aquifer water indicate that most basin-fill groundwater sampled could contain 10–20 percent geothermal water. Geothermal indicators such as high temperature, lithium, boron, chloride, and silica suggest that mixing occurs in many wells that tap the basin-fill aquifer, particularly on the north, south, and west sides of the basin. Magnesium-lithium geothermometers indicate that some basin-fill aquifer water sampled for the current study likely originates from water that was heated above background mountain-block recharge temperatures (between 3 and 15 degrees Celsius), highlighting the influence of mixing with warm water that was possibly derived from geothermal sources.

Nevada↗

USGS2000

Use of biological characteristics of common carp ( Cyprinus carpio ) to indicate exposure to hormonally active agents in selected Minnesota streams, 1999

The presence of hormonally active agents (HAAs) was determined in selected Minnesota streams using biological characteristics (measures of endocrine disruption) of common carp ( Cyprinus carpio ) exposed to wastewater treatment plant (WWTP) effluent and runoff from agricultural and forested land. Four biological characteristics of common carp were used as indicators of HAAs in the streams selected for this study: (1) high concentrations of vitellogenin in male fish and low concentrations in female fish, (2) high or low plasma concentrations of the sex steroid hormones (17β-estradiol and 11-ketotestosterone), (3) low gonado-somatic index (GSI) (gonad weight divided by total body weight multiplied by 100) values, and (4) abnormal gonad histopathology (high percent of atretic oocytes in female ovaries and high percent ceroid/lipofuscin tissue in male or female gonads). The study design was a paired site approach targeting sites downstream and upstream of WWTP discharges on different streams. Male (221 individuals) and female (201 individuals) common carp were collected using electrofishing techniques from seven streams with sites at two locations (upstream and downstream of WWTPs), and eight sites located downstream of WWTPs with no upstream-paired sites. Samples were collected between August 3 and September 13, 1999. The presence of HAAs in selected Minnesota streams was indicated by biological characteristics in common carp. Biological characteristics used in this study identified WWTP effluent as a potential source of HAAs. Additionally, fish located at sites upstream of WWTP effluent primarily draining agricultural land show indications of HAAs, which may be the result of agricultural runoff or other sources of HAAs. There was variability among all sites and among sites within each site group. Differences among sites may be due to differences in water chemistry or fish exposure time. Natural variation in the biological characteristics may account for some of the differences observed in this study. This study and others indicate the presence of HAAs in surface water and the potential signs of endocrine disruption in resident fish populations. Detailed controlled studies could confirm the effects of particular chemicals such as pesticides or components of WWTPs on fish reproduction and population structure.

Minnesota↗

USGS1993

National water summary 1990-91: Hydrologic events and stream water quality

National Water Summary 1990-91 Hydrologic Events and Stream Water Quality was planned to complement existing Federal-State water-quality reporting to the U.S. Congress that is required by the Clean Water Act of 1972. This act, formally known as the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500), and its amendments in 1977,1979,1980,1981,1983, and 1987, is the principal basis for Federal-State cooperation on maintaining and reporting on water quality in the United States. Under section 305(b) of the Clean Water Act, the States must designate uses for waterbodies, biennially assess whether the waterbodies meet designated uses, and report to the U.S. Environmental Protection Agency (EPA), which in turn summarizes the findings of the State assessments in a biennial National Water Quality Inventory report to the Congress. This volume of the National Water Summary uses a nationally consistent data base and methods of statistical analysis to document stream water quality in the United States, Puerto Rico, and the Western Pacific Islands. As a basis for preparation of this report, the U.S. Geological Survey (uses) created a data base of waterquality data from about 2,900 stream water-quality monitoring stations in the United States (Lanfear, 1993). These data, which were extracted primarily from the uses National Water Information System (NWIS) and supplemented with data from the EPA national data base known as STORET, consisted mostly of water-chemistry and physical-sediment data. About 1,400 of these stations met a criterion, used in this volume for trends analysis of data, of having a period of record that began before water year 1980. (A water year is the period from October 1 through September 30 and is identified by the calendar year at the end of the period.) Inasmuch as the determination of trends requires about 10 years of data, few biological data were suitable for trends analysis because biological indicators of water quality were not being collected extensively by water year 1980. Also, because of the lack of long-term data, an assessment of the water quality of lakes and reservoirs is not included in this National Water Summary . Constituent and waterproperty data were selected from this data base and analyzed with statistical techniques that have been used extensively by the uses to summarize conditions and trends in water quality. (Throughout the remainder of this article, the term "constituent" is used also to represent water properties, such as pH and alkalinity.) Selected results from this analysis are presented graphically, both by State and nationally, in this volume. The data base created for preparation of this volume and the resulting nationally consistent statistical analysis of these data provide a unique opportunity to compare and contrast stream water-quality conditions and trends nationally and State by State. Because of the complexity of water quality and the natural seasonal and diurnal variations in the concentrations of waterquality constituents, the determination of trends in water quality requires a relatively long period of record. Trends in constituent concentrations in the State summaries in this volume were calculated for one or more of four periods water years 1970-89,1975-89,1980- 89, and 1982-89. Unfortunately, few water-quality monitoring stations have periods of record of more than 10 or 15 years, and therefore most analyses in the State summaries were done for 8- or 10-year periods. Although interest in water quality has continued to heighten since passage of the Clean Water Act, funds for support of data-collection programs are limited and data records of many of the constituents now of current concern, especially organic constituents, do not exist or are less than 10-years long; consequently only a modest number of organic constituents are presented in this volume. Discussion of conditions and trends in water quality in this National Water Summary also draw upon information about land use, population, water use, application of agricultural chemicals in rural areas, the siting of industrial facilities, and other ancillary information. Because the results of analysis of a restricted number of constituents are presented in this volume, State 305(b) reports also are cited in the discussion of water quality in each State. The following discussion is an overview of the three parts of this 1990-91 National Water Summary - "Hydrologic Conditions and Water-Related Events, Water Years 1990-91," "Hydrologic Perspectives on Water Issues," and "State Summaries of Stream Water Quality."

Water Supply Paper↗

USGS2014

Adaptations of indigenous bacteria to fuel contamination in karst aquifers in south-central Kentucky

The karst aquifer systems in southern Kentucky can be dynamic and quick to change. Microorganisms that live in these unpredictable aquifers are constantly faced with environmental changes. Their survival depends upon adaptations to changes in water chemistry, taking advantage of positive stimuli and avoiding negative environmental conditions. The U.S. Geological Survey conducted a study in 2001 to determine the capability of bacteria to adapt in two distinct regions of water quality in a karst aquifer, an area of clean, oxygenated groundwater and an area where the groundwater was oxygen depleted and contaminated by jet fuel. Water samples containing bacteria were collected from one clean well and two jet fuel contaminated wells in a conduit-dominated karst aquifer. Bacterial concentrations, enumerated through direct count, ranged from 500,000 to 2.7 million bacteria per mL in the clean portion of the aquifer, and 200,000 to 3.2 million bacteria per mL in the contaminated portion of the aquifer over a twelve month period. Bacteria from the clean well ranged in size from 0.2 to 2.5 mm, whereas bacteria from one fuel-contaminated well were generally larger, ranging in size from 0.2 to 3.9 mm. Also, bacteria collected from the clean well had a higher density and, consequently, were more inclined to sink than bacteria collected from contaminated wells. Bacteria collected from the clean portion of the karst aquifer were predominantly (,95%) Gram-negative and more likely to have flagella present than bacteria collected from the contaminated wells, which included a substantial fraction (,30%) of Gram-positive varieties. The ability of the bacteria from the clean portion of the karst aquifer to biodegrade benzene and toluene was studied under aerobic and anaerobic conditions in laboratory microcosms. The rate of fuel biodegradation in laboratory studies was approximately 50 times faster under aerobic conditions as compared to anaerobic, sulfur-reducing conditions. The optimum pH for fuel biodegradation ranged from 6 to 7. These findings suggest that bacteria have adapted to water-saturated karst systems with a variety of active and passive transport mechanisms.

Kentucky↗

USGS2011

Response of lake chemistry to atmospheric deposition and climate in selected Class I wilderness areas in the western United States, 1993-2009

The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Forest Service, Air Resource Management, conducted a study to evaluate long-term trends in lake-water chemistry for 64 high-elevation lakes in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming during 1993 to 2009. Understanding how and why lake chemistry is changing in mountain areas is essential for effectively managing and protecting high-elevation aquatic ecosystems. Trends in emissions, atmospheric deposition, and climate variables (air temperature and precipitation amount) were evaluated over a similar period of record. A main objective of the study was to determine if changes in atmospheric deposition of contaminants in the Rocky Mountain region have resulted in measurable changes in the chemistry of high-elevation lakes. A second objective was to investigate linkages between lake chemistry and air temperature and precipitation to improve understanding of the sensitivity of mountain lakes to climate variability.

Colorado;Idaho;Utah;Wyoming↗