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At least 559 records · Page 31Linked to original sources
USGS1994

New uranium-series ages of the Waimanalo Limestone, Oahu, Hawaii: implications for sea level during the last interglacial period

The Waimanalo Formation (limestone) of Oahu has been correlated with the last interglacial period based on U-series dating of corals by T.-L. Ku and colleagues. The limestone consists of growth-position corals and overlying coral conglomerate. An apparent bimodal distribution of ages for the growth-position corals (mean age = 133 ka) and the overlying coral conglomerate (mean age = 119 ka) has been interpreted to represent two distinct high stands of sea that occurred within the last interglacial period. Both growth-position corals and overlying, conglomerate coral occur in an outcrop east of Kaena Point and consist mainly of Pocillopora and Porites. U-seriesages of growth-position corals that show closed-system conditions are 120 ± 3 ka and 127 ± 4 ka; overlying conglomerate corals have U-seriesages that range from 120 ± 3 ka to 138 ± 4 ka. At Kahe Point, conglomerate corals have ages of 120 ± 3 ka and 134 ± 4 ka. These data show that the growth position corals are not systematically older than the conglomerate corals; thus, there is no evidence for two distinct high stands of sea. Waimanalo deposits at Kahe Point and Mokapu Point (new U-seriesages of 134 ± 4 ka and 127 ± 3 ka) have beach deposits as high as 12.5 m and, at Mokapu Point, growth-position corals as high as 8.5 m. A last-interglacial sea-level stand of +8.5 to +12.5 m conflicts with estimates of +6 m from a number of tectonically stable coastlines and islands in the western Atlantic Ocean. We infer, therefore, that Oahu may be undergoing uplift at a low rate. This uplift may be due to compensatory lithospheric flexure, because the island of Hawaii has been subsiding throughout much of the Quaternary from volcanic loading. Because of this possible uplift, Oahu and islands like it elsewhere in the Pacific cannot be used as reference points for sealevel during the last interglacial period.

Hawai'i↗
USGS1988

A test of uranium-series dating of fossil tooth enamel: Results from Tournal Cave, France

A series of well preserved mammal bones and horse teeth was analyzed from archaeological levels of Tournal Cave (Magdalenian, Aurignacian, and Mousterain) to test the hypothesis that well-crystallized enamel behaves more as a closed system than does whole bone. The isotopic composition of bones and tooth enamels from this deposit meet criteria for confidence, and gave no reasons to suspect contamination or open-system behavior. Two samples for which 231 Pa could be analyzed showed internal concordance with the respective 230 Th ages. In spite of the favourable isotopic criteria, however, comparison of the U-series ages of the bones and the tooth enamel with stratigraphic position and 14 C control indicated the dates were not meaningful. In general, both bones and tooth enamels gave ages too young, although some were clearly too old. Neither group showed any systematic increase of age with stratigraphic depth. Tooth enamel, therefore, shows no advantage over bone for U-series dating for this site. In Tournal cave both bones and enamel are apparently open to U, which is probably cycling as a consequences of post-depositional groundwater movement.

Applied Geochemistry↗
USGS1991

Petrogenesis and geological history of a uranium source rock: a case study in northeastern Washington, U.S.A.

A small (4 km 2 ) drainage basin in northeastern Washington contains highly uraniferous groundwater and highly uraniferous peaty sediments of Holocene age. The U is derived from granitic bedrock that underlies the entire drainage basin and that contains 9–16 ppm U. This local bedrock was studied by petrographic, chemical and isotopic methods to determine conditions of its petrogenesis and post-emplacement history that may have contributed to its present high U content and source-rock capability. The original magma was derived by anatexis of Precambrian continental crust of probable mixed metaigneous and metasedimentary character. Mineral-melt partitioning controlled the enrichment of U in chemically evolved phases of the crystallizing melt. Following emplacement in the upper crust at ∼100Ma, the pluton interacted with meteoric-hydrothermal water at ambient temperatures 300°C. Locally intense fracturing promoted alteration, and fracturing and alteration probably continued during later regional uplift in the Eocene. Regional uplift was followed by low-temperature alteration and weathering in the middle to late Tertiary. The combined result of hydrothermal alteration and low-temperature alteration and weathering was the redistribution of U from primary mineral hosts such as allanite to new sites on fracture surfaces and in secondary minerals such as hematite. Zones of highly fractured and altered rock show the most obvious evidence of this process. A model is proposed in which high-angle fractures beneath the drainage basin were the sites of Tertiary supergene enrichments of U. Recent glacio-isostatic uplift has elevated these older enriched zones to shallow levels where they are now being leached by oxidizing groundwater. The chemistry, mineralogy, texture and geological history of this U source-rock suggest criteria for locating other granitic terrane that may contain uraniferous waters and associated young surficial U deposits. The details of U distribution and mobility at this site also apply to the general topic of U mobility in granitic rocks.

Washington↗
USGS2004

Comparison of in situ uranium KD values with a laboratory determined surface complexation model

Reactive solute transport simulations in groundwater require a large number of parameters to describe hydrologic and chemical reaction processes. Appropriate methods for determining chemical reaction parameters required for reactive solute transport simulations are still under investigation. This work compares U(VI) distribution coefficients (i.e. KD values) measured under field conditions with KD values calculated from a surface complexation model developed in the laboratory. Field studies were conducted in an alluvial aquifer at a former U mill tailings site near the town of Naturita, CO, USA, by suspending approximately 10 g samples of Naturita aquifer background sediments (NABS) in 17-5.1-cm diameter wells for periods of 3 to 15 months. Adsorbed U(VI) on these samples was determined by extraction with a pH 9.45 NaHCO3/Na2CO3 solution. In wells where the chemical conditions in groundwater were nearly constant, adsorbed U concentrations for samples taken after 3 months of exposure to groundwater were indistinguishable from samples taken after 15 months. Measured in situ K D values calculated from the measurements of adsorbed and dissolved U(VI) ranged from 0.50 to 10.6 mL/g and the KD values decreased with increasing groundwater alkalinity, consistent with increased formation of soluble U(VI)-carbonate complexes at higher alkalinities. The in situ K D values were compared with KD values predicted from a surface complexation model (SCM) developed under laboratory conditions in a separate study. A good agreement between the predicted and measured in situ KD values was observed. The demonstration that the laboratory derived SCM can predict U(VI) adsorption in the field provides a critical independent test of a submodel used in a reactive transport model. ?? 2004 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗
USGS2011

Composition, stability, and measurement of reduced uranium phases for groundwater bioremediation at Old Rifle, CO

Reductive biostimulation is currently being explored as a possible remediation strategy for U-contaminated groundwater, and is being investigated at a field site in Rifle, CO, USA. The long-term stability of the resulting U(IV) phases is a key component of the overall performance of the remediation approach and depends upon a variety of factors, including rate and mechanism of reduction, mineral associations in the subsurface, and propensity for oxidation. To address these factors, several approaches were used to evaluate the redox sensitivity of U: (1) measurement of the rate of oxidative dissolution of biogenic uraninite (UO 2(s) ) deployed in groundwater at Rifle, (2) characterization of a zone of natural bioreduction exhibiting relevant reduced mineral phases, and (3) laboratory studies of the oxidative capacity of Fe(III) and reductive capacity of Fe(II) with regard to U(IV) and U(VI), respectively.

Colorado↗
USGS2011

Uranium and barium cycling in a salt wedge subterranean estuary: The influence of tidal pumping

The contribution of submarine groundwater discharge (SGD) to oceanic metal budgets is only beginning to be explored. Here, we demonstrate that biogeochemical processes in a northern Florida subterranean estuary (STE) significantly alter U and Ba concentrations entering the coastal ocean via SGD. Tidal pumping controlled the distribution of dissolved metals in shallow beach groundwater. Hourly observations of intertidal groundwaters revealed high U and low Ba concentrations at high tide as a result of seawater infiltration into the coastal aquifer. During ebb tide, U decreased and Ba increased due to freshwater dilution and, more importantly, biogeochemical reactions that removed U and added Ba to solution. U removal was apparently a result of precipitation following the reduction of U(VI) to U(IV). A significant correlation between Ba and dissolved organic carbon (DOC) in shallow beach groundwaters implied a common source, likely the mineralization of marine particulate organic matter driven into the beach face by tidal pumping. In deeper groundwaters, where the labile organic matter had been depleted, Ba correlated with Mn. We estimate that net SGD fluxes were − 163 and + 1660 μmol m − 1 d − 1 for U and Ba, respectively (or − 1 and + 8 μmol m − 2 d − 1 if a 200-m wide seepage area is considered). Our results support the emerging concept that subterranean estuaries are natural biogeochemical reactors where metal concentrations are altered relative to conservative mixing between terrestrial and marine endmembers. These deviations from conservative mixing significantly influence SGD-derived trace metal fluxes.

Florida↗
USGS2016

Establishing a pre-mining geochemical baseline at a uranium mine near Grand Canyon National Park, USA

During 2012, approximately 404,000 ha of Federal Land in northern Arizona was withdrawn from consideration of mineral extraction for a 20-year period to protect the Grand Canyon watershed from potentially adverse effects of U mineral exploration and development. The development, operation, and reclamation of the Canyon Mine during the withdrawal period provide an excellent field site to understand and document off-site migration of radionuclides within the withdrawal area. As part of the Department of Interior's (DOI's) study plan for the exclusion area, the objective of our study is to utilize pre-defined decision units (DUs) in areas within and surrounding the Canyon Mine to demonstrate how newly established incremental sampling methodologies (ISM) combined with multivariate statistical methods can be used to document a repeatable and statistically defensible measure of pre-mining baseline conditions in surface soils and stream sediment samples prior to ore extraction. During the survey in June 2013, the highest pre-mining 95% upper confidence level (UCL) concentrations with respect to As, Mo, U, and V were found in the triplicate samples collected from surface soils in the mine site DU designated as M1. Gamma activities were slightly elevated in soils within the M1 DU (up to 28 &mu;R/h); however, off-site gamma activities in soil and stream-sediment samples were lower (< 6 to 12 &mu;R/h). Hierarchical cluster analysis (HCA) was applied to 33 chemical constituents contained in the multivariate data generated from the analysis of triplicate samples collected in the soil and stream sediment DUs within and surrounding Canyon Mine. Most of the triplicate samples from individual DUs were grouped in the same dendrogram cluster when using a similarity value (SV) of 0.70 (unitless). Different group membership of triplicate samples from two of the four haul road DUs was likely the result of heterogeneity induced by non-native soil material introduced from the gravel road base or from vehicular traffic. Application of HCA and ISM will provide critical metrics to meet DOI's long-term goals for assessing off-site migration of radionuclides resulting from mining and reclamation in the current (2015) exclusion area associated within the Grand Canyon watershed and the associated national park.

Arizona↗
USGS2026

Evidence for a biological origin of uranium-rich carbon masses within the Ediacaran Salt Range Formation of Pakistan

Thucholites are unique organic structures found in igneous and sedimentary rocks composed of a U-C-rich interior enclosed by an organic outer shell. Their formation and occurrence have perplexed scientists for over 100 years. Typically, thucholites are sparse in sedimentary rocks but where found in abundance, they may be the result of rapid paleoecological disruptions, e.g., volcanic ashfall. Here, we evaluated thucholites from the Ediacaran Salt Range Formation of the Indus Basin in Pakistan using field emission scanning electron microscopy (FESEM) and nanoscale secondary ion mass spectroscopy (NanoSIMS) to propose a two-stage mechanism for thucholite development. NanoSIMS results suggest organic matter in thucholite cores formed by biological fractionation (represented by the presence of lighter 13 C/ 12 C and 34 S/ 32 S) while the outer organic mantle formed via radiolysis-induced polymerization. FESEM elemental analysis confirms compositional differences between the two thucholite components (core and mantle), further implying their contrasting origins. Dimensional comparison of thucholite cores and their U-bearing mineral morphologies to ancient and modern U-biomineralized microbes suggests that the thucholite cores formed from metal-biological interactions. The presence of volcanogenic biotite, alkali feldspar, and clay spherules (interpreted as devitrified volcanic glass) with thucholite suggests that the thucholite cores in the Salt Range Formation are biological responses to rapid paleoenvironmental change from volcanic eruption which preserved the fossilized morphologies of Proterozoic microorganisms.

Salt Range↗
USGS2014

Uranium-series ages of corals, sea level history, and palaeozoogeography, Canary Islands, Spain: an exploratory study for two Quaternary interglacial periods

We present the first U-series ages of corals from emergent marine deposits on the Canary Islands. Deposits at + 20 m are 481 ± 39 ka, possibly correlative to marine isotope stage (or MIS) 11, while those at + 12 and + 8 m are 120.5 ± 0.8 ka and 130.2 ± 0.8 ka, respectively, correlative to MIS 5.5. The age, elevations, and uplift rates derived from MIS 5.5 deposits on the Canary Islands allow calculations of hypothetical palaeo-sea levels during the MIS 11 high sea stand. Estimates indicate that the MIS 11 high sea stand likely was at least + 9 m (relative to present sea level) and could have been as high as + 24 m. The most conservative estimates of palaeo-sea level during MIS 11 would require an ice mass loss equivalent to all of the modern Greenland and West Antarctic ice sheets; the more extreme estimates would require additional ice mass loss from the East Antarctic ice sheet. Extralimital southern species of mollusks, found in both MIS 11 and MIS 5.5 deposits on the Canary Islands, imply warmer-than-modern sea surface temperatures during at least a part of MIS 11 and much warmer sea surface temperatures during at least a part of MIS 5.5. Both MIS 11 and MIS 5.5 marine deposits on the Canary Islands contain extralimital northern species of mollusks as well, indicating cooler-than-present waters at times during these interglacial periods. We hypothesize that the co-occurrence of extralimital southern and northern species of marine invertebrates in the fossil record of the Canary Islands reflects its geographic location with respect to major synoptic-scale controls on climate and ocean currents. Previous interglacials may have been characterized by early, insolation-forced warming, along with northward migration of the intertropical convergence zone (ITCZ), accompanied by weakened trade winds and diminished upwelling. This allowed the arrival of extralimital southern taxa from the tropical Senegalese faunal province. During later parts of the MIS 11 and 5.5 interglacials, decreased insolation may have resulted in southward migration of the ITCZ, strengthened trade winds, and re-establishment of upwelling. Such conditions may have brought about not only local extinction of the Senegalese fauna, but allowed southward migration of the cooler-water Mediterranean fauna to the Canary Islands in the later parts of interglacials, a complex palaeoclimate record that is mirrored in the deep-sea core record.

Canary Islands↗
USGS2015

Uranium-series ages of fossil corals from Mallorca, Spain: The "Neotyrrhenian" high stand of the Mediterranean Sea revisited

The emergent marine deposits of the Mediterranean basin have been recognized as an important record of Quaternary sea level history for more than a century. Previous workers identified what have been interpreted to be two separate high stands of sea in the late Quaternary, namely the &ldquo;Eutyrrhenian&rdquo; (thought to be ~ 120 ka) and the &ldquo;Neotyrrhenian&rdquo; (thought to be either ~ 100 ka or ~ 80 ka). On Mallorca, Spain, both of these named deposits lie close to present sea level, implying paleo-sea levels slightly above present during both marine isotope stages (MIS) 5.5/5e and either 5.3/5c or 5.1/5a. If these interpretations are correct, they conflict, at least in part, with sea level records from far-field localities. We analyzed corals from the Neotyrrhenian beds on Mallorca, which gave U-series ages from ~ 126 ka to ~ 118 ka. These ages are consistent with previously published amino acid data that show that the Neotyrrhenian and Eutyrrhenian deposits are not significantly different in age. A fossil molluscan fauna from the Neotyrrhenian deposits on Mallorca has a warm-water paleozoogeographic aspect, with nine southward-ranging species and four extralimital southern species. When compared with sea surface temperatures obtained from planktonic foraminifera and alkenones from ODP core 977 in the nearby Alboran Sea, the only time period that shows comparable warmth is MIS 5.5/5e, consistent with the U-series ages of corals from the Neotyrrhenian deposits. We propose that the Neotyrrhenian deposits are a beachrock facies of the same age as the Eutyrrhenian deposits. This interpretation is consistent with the differences in physical sedimentology of the two deposits, explains the U-series and amino acid data indicating the same age, is consistent with the very slight elevation difference of the Neotyrrhenian and Eutyrrhenian beds, and explains the similar, though not identical paleozoogeographic aspects of their fossil faunas.

Mallorca↗
USGS2016

Contrasting distributions of groundwater arsenic and uranium in the western Hetao basin, Inner Mongolia: Implication for origins and fate controls

Although As concentrations have been investigated in shallow groundwater from the Hetao basin, China, less is known about U and As distributions in deep groundwater, which would help to better understand their origins and fate controls. Two hundred and ninety-nine groundwater samples, 122 sediment samples, and 14 rock samples were taken from the northwest portion of the Hetao basin, and analyzed for geochemical parameters. Results showed contrasting distributions of groundwater U and As, with high U and low As concentrations in the alluvial fans along the basin margins, and low U and high As concentrations downgradient in the flat plain. The probable sources of both As and U in groundwater were ultimately traced to the bedrocks in the local mountains (the Langshan Mountains). Chemical weathering of U-bearing rocks (schist, phyllite, and carbonate veins) released and mobilized U as UO 2 (CO 3 ) 2 2 &minus; and UO 2 (CO 3 ) 3 4 &minus; species in the alluvial fans under oxic conditions and suboxic conditions where reductions of Mn and NO 3 &minus; were favorable (OSO), resulting in high groundwater U concentrations. Conversely, the recent weathering of As-bearing rocks (schist, phyllite, and sulfides) led to the formation of As-bearing Fe(III) (hydr)oxides in sediments, resulting in low groundwater As concentrations. Arsenic mobilization and U immobilization occurred in suboxic conditions where reduction of Fe(III) oxides was favorable and reducing conditions (SOR). Reduction of As-bearing Fe(III) (hydr)oxides, which were formed during palaeo-weathering and transported and deposited as Quaternary aquifer sediments, was believed to release As into groundwater. Reduction of U(VI) to U(IV) would lead to the formation of uraninite, and therefore remove U from groundwater. We conclude that the contrasting distributions of groundwater As and U present a challenge to ensuring safe drinking water in analogous areas, especially with high background values of U and As.

Hetao Basin, Inner Mongolia↗
USGS2012

Sea-level history of past interglacial periods: New evidence from uranium-series dating of corals from Curaçao, Leeward Antilles islands

Curaçao has reef terraces with the potential to provide sea-level histories of interglacial periods. Ages of the Hato (upper) unit of the “Lower Terrace” indicate that this reef dates to the last interglacial period, Marine Isotope Stage (MIS) 5.5. On Curaçao, this high sea stand lasted at least 8000 yr (~ 126 to ~ 118 ka). Elevations and age of this reef show that late Quaternary uplift rates on Curaçao are low, 0.026–0.054 m/ka, consistent with its tectonic setting. Ages of ~ 200 ka for corals from the older Cortalein unit of the Lower Terrace correlate this reef to MIS 7, with paleo-sea level estimates ranging from − 3.3 m to + 2.3 m. The estimates are in agreement with those for MIS 7 made from other localities and indicate that the penultimate interglacial period was a time of significant warmth, on a par with the present interglacial period. The ~ 400 ka (MIS 11) Middle Terrace I on Curaçao, dated by others, may have formed from a paleo-sea level of + 8.3 to + 10.0 m, or (less likely) + 17 m to + 20 m. The lower estimates are conservative compared to previous studies, but still require major ice sheet loss from Greenland and Antarctica.

Leeward Antilles↗
USGS2002

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

A 230Th-234U-238U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the 232Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for 230Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappabe deposit) order of the 230Th/U ages were preserved in all cases; (2) back-calculated initial 234U/238U fall in a restricted range (typically 1.67??0.19), so that 234U/238U ages with errors of about 100 kyr (2??) could be reliably determined for the oldest, 400 to 1000 ka rinds: and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt 230Th/U ages. We conclude that 230Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of 238U/232Th, or isochrons. Copyright ?? 2002 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗
USGS2002

Uranium-series disequilibrium in tuffs from Yucca Mountain, Nevada, as evidence of pore-fluid flow over the last million years

Samples of tuff from boreholes drilled into fault zones in the Exploratory Studies Facility (ESF) and relatively unfractured rock of the Cross Drift tunnels, at Yucca Mountain, Nevada, have been analysed by U-series methods. This work is part of a project to verify the finding of fast flow-paths through the tuff to ESF level, indicated by the presence of 'bomb' 36Cl in pore fluids. Secular radioactive equilibrium in the U decay series, (i.e. when the radioactivity ratios 234U/238U, 230Th/234U and 226Ra/230Th all equal 1.00) might be expected if the tuff samples have not experienced radionuclide loss due to rock-water interaction occurring within the last million years. However, most fractured and unfractured samples were found to have a small deficiency of 234U (weighted mean 234U/238U=0.95??0.01) and a small excess of 230Th (weighted mean 230Th/234U 1.10??0.02). The 226Ra/230Th ratios are close to secular equilibrium (weighted mean = 0.94??0.07). These data indicate that 234U has been removed from the rock samples in the last ???350 ka, probably by pore fluids. Within the precision of the measurement, it would appear that 226Ra has not been mobilized and removed from the tuff, although there may be some localised 226Ra redistribution as suggested by a few ratio values that are significantly different from 1.0. Because both fractured and unfractured tuffs show approximately the same deficiency of 234U, this indicates that pore fluids are moving equally through fractured and unfractured rock, More importantly, fractured rock appears not to be a dominant pathway for groundwater flow (otherwise the ratio would be more strongly affected and the Th and Ra isotopic ratios would likely also show disequilibrium). Application of a simple mass-balance model suggests that surface infiltration rate is over an order of magnitude greater than the rate indicated by other infiltration models and that residence time of pore fluids at ESF level is about 400 a. Processes of U sorption, precipitation and re-solution are believed to be occurring and would account for these anomalous results but have not been included in the model. Despite the difficulties, the U-series data suggest that fractured rock, specifically the Sundance and Drill Hole Wash faults, are not preferred flow paths for groundwater flowing through the Topopah Spring tuff and, by implication, rapid-flow, within 50 a, from the surface to the level of the ESF is improbable. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗