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Dietary bioavailability of Cu adsorbed to colloidal hydrous ferric oxide

The dietary bioavailability of copper (Cu) adsorbed to synthetic colloidal hydrous ferric oxide (HFO) was evaluated from the assimilation of 65 Cu by two benthic grazers, a gastropod and a larval mayfly. HFO was synthesized, labeled with 65 Cu to achieve a Cu/Fe ratio comparable to that determined in naturally formed HFO, and then aged. The labeled colloids were mixed with a food source (the diatom Nitzschia palea) to yield dietary 65 Cu concentrations ranging from 211 to 2204 nmol/g (dry weight). Animals were pulse fed the contaminated diet and assimilation of 65 Cu from HFO was determined following 1–3 days of depuration. Mass transfer of 65 Cu from HFO to the diatom was less than 1%, indicating that HFO was the source of 65 Cu to the grazers. Estimates of assimilation efficiency indicated that the majority of Cu ingested as HFO was assimilated (values >70%), implying that colloidal HFO potentially represents a source of dietary Cu to benthic grazers, especially where there is active formation and infiltration of these particles into benthic substrates.

Environmental Science & Technology

International heat flow commission celebrates 40 years

The outflow of heat from the Earth's interior is, in terms of energy, the most impressive terrestrial phenomenon. Its present rate of about 1021 joules per year is order‐of‐magnitudes greater than the energy dissipation of earthquakes or heat loss from volcanic eruptions. The study of the Earth's internal heat plays an important role in understanding the Earth's origin, internal constitution, and plate tectonics. The thermal structure of the Earth, generally referred to as the geothermics, or also as the (terrestrial) heat flow, has been studied for a long time. However, modern geothermics, one of the fundamental geophysical disciplines, is relatively young. The International Heat Flow Commission (IHFC), under which the academic geothermal research on the international scale is organized, was created only in 1963. The IHFC, operating under the International Association of Seismology and Physics of the Earth's Interior (IASPEI), covers a broad scope of geophysical studies, and links the activities of other associations of the International Union of Geodesy and Geophysics (IUGG).

Eos, Earth and Space Science News

Volcano geodesy: Challenges and opportunities for the 21st century

Intrusions of magma beneath volcanoes deform the surrounding rock and, if the intrusion is large enough, the overlying ground surface. Numerical models generally agree that, for most eruptions, subsurface volume changes are sufficient to produce measurable deformation at the surface. Studying this deformation can help to determine the location, volume, and shape of a subsurface magma body and thus to anticipate the onset and course of an eruption. This approach has been successfully applied at many restless volcanoes, especially basaltic shields and silicic calderas, using various geodetic techniques and sensors. However, its success at many intermediate-composition strato-volcanoes has been limited by generally long repose intervals, steep terrain, and structural influences that complicate the history and shape of surface deformation. These factors have made it difficult to adequately characterize deformation in space and time at many of the world's dangerous volcanoes. Recent technological advances promise to make this task easier by enabling the acquisition of geodetic data of high spatial and temporal resolution from Earth-orbiting satellites. Synthetic aperture radar interferometry (InSAR) can image ground deformation over large areas at metre-scale resolution over time-scales of a month to a few years. Global Positioning System (GPS) stations can provide continuous information on three-dimensional ground displacements at a network of key sites -information that is especially important during volcanic crises. By using InSAR to determine the shape of the displacement field and GPS to monitor temporal changes at key sites, scientists have a much better chance to capture geodetic signals that have so far been elusive at many volcanoes. This approach has the potential to provide longer-term warnings of impending volcanic activity than is possible with other monitoring techniques.

Philosophical Transactions of the Royal Society A:

Glass electrodes sensitive to divalent cations

Glass electrodes suitable for measurement of divalent cations have been made and tested. Empirical and theoretical electrode equations have been presented to describe electrode behavior in a variety of aqueous solutions. Most electrodes show response interpretable as showing nearly ideal solid-solution behavior of the cations in the glass surface. The electrodes should be useful in the measurement of divalent-cation activities in natural waters and biological fluids, and useful in general analytical chemistry.

Science

Impact craters on Venus: Initial analysis from Magellan

Magellan radar images of 15 percent of the planet show 135 craters of probable impact origin. Craters more than 15 km across tend to contain central peaks, multiple central peaks, and peak rings. Many craters smaller than 15 km exhibit multiple floors or appear in clusters; these phenomena are attributed to atmospheric breakup of incoming meteoroids. Additionally, the atmosphere appears to have prevented the formation of primary impact craters smaller than about 3 km and produced a deficiency in the number of craters smaller than about 25 km across. Ejecta is found at greater distances than that predicted by simple ballistic emplacement, and the distal ends of some ejecta deposits are lobate. These characteristics may represent surface flows of material initially entrained in the atmosphere. Many craters are surrounded by zones of low radar albedo whose origin may have been deformation of the surface by the shock or pressure wave associated with the incoming meteoroid. Craters are absent from several large areas such as a 5 million square kilometer region around Sappho Patera, where the most likely explanation for the dearth of craters is volcanic resurfacing. There is apparently a spectrum of surface ages on Venus ranging approximately from 0 to 800 million years, and therefore Venus must be a geologically active planet.

Science

Holocene eolian activity in the Minot dune field, North Dakota

Stabilized eolian sand is common over much of the Great Plains region of the United States and Canada, including a subhumid area of ~1500 km 2 near Minot, North Dakota. Eolian landforms consist of sand sheets and northwest-trending parabolic dunes. Dunes and sand sheets in the Minot field are presently stabilized by a cover of prairie grasses or oak woodland. Stratigraphic studies and accelerator mass spectrometry radiocarbon dating of paleosols indicate at least two periods of eolian sand movement in the late Holocene. Pedologic data suggest that all of the dune field has experienced late Holocene dune activity, though not all parts of the dune field may have been active simultaneously. Similar immobile element (Ti, Zr, La, Ce) concentrations support the interpretation that eolian sands are derived from local glaciofluvial and glaciolacustrine sediments. However, glaciolacustrine and glaciofluvial source sediments have high Ca concentrations from carbonate minerals, whereas dune sands are depleted in Ca. Because noneolian-derived soils in the area are calcareous, these data indicate that the Minot dune field may have had extended periods of activity in the Holocene, such that eolian abrasion removed soft carbonate minerals. The southwest-facing parts of some presently stabilized dunes were active during the 1930s drought, but were revegetated during the wetter years of the 1940s. These observations indicate that severe droughts accompanied by high temperatures are the most likely cause of Holocene eolian activity.

North Dakota

Volcanic hazard assessment for an eruption hiatus, or post-eruption unrest context: Modeling continued dome collapse hazards for Soufrière Hills Volcano

Effective volcanic hazard management in regions where populations live in close proximity to persistent volcanic activity involves understanding the dynamic nature of hazards, and associated risk. Emphasis until now has been placed on identification and forecasting of the escalation phase of activity, in order to provide adequate warning of what might be to come. However, understanding eruption hiatus and post-eruption unrest hazards, or how to quantify residual hazard after the end of an eruption, is also important and often key to timely post-eruption recovery. Unfortunately, in many cases when the level of activity lessens, the hazards, although reduced, do not necessarily cease altogether. This is due to both the imprecise nature of determination of the “end” of an eruptive phase as well as to the possibility that post-eruption hazardous processes may continue to occur. An example of the latter is continued dome collapse hazard from lava domes which have ceased to grow, or sector collapse of parts of volcanic edifices, including lava dome complexes. We present a new probabilistic model for forecasting pyroclastic density currents (PDCs) from lava dome collapse that takes into account the heavy-tailed distribution of the lengths of eruptive phases, the periods of quiescence, and the forecast window of interest. In the hazard analysis, we also consider probabilistic scenario models describing the flow’s volume and initial direction. Further, with the use of statistical emulators, we combine these models with physics-based simulations of PDCs at Soufrière Hills Volcano to produce a series of probabilistic hazard maps for flow inundation over 5, 10, and 20 year periods. The development and application of this assessment approach is the first of its kind for the quantification of periods of diminished volcanic activity. As such, it offers evidence-based guidance for dome collapse hazards that can be used to inform decision-making around provisions of access and reoccupation in areas around volcanoes that are becoming less active over time.

Soufrière Hills Volcano

Creating usable science: A Southwest Climate Adaptation Science Center study

The southwestern United States consists of diverse ecosystems that are experiencing increasing pressures from rising temperatures, increasing aridity, and sea level rise. To prepare this region for future uncertainty, there is a need for strong partnerships among researchers and societal partners. The Southwest Climate Adaptation Science Center (SW CASC) acts to foster engaged scholarship from diverse perspectives to produce science relevant for management and policy decisions. Here, we synthesized a subset of SW CASC-funded projects and published manuscripts to illustrate how the combination of new scientific knowledge and the research and practice of engaged scholarship produce actionable science with direct societal impacts. In the SW CASC Contributions to Regional Science section, we touch on new research produced from funded projects on the most common topics: (1) Forest Ecosystems, (2) Coastal Ecosystems, (3) Hydrometeorology, and (4) Research on Engaged Scholarship. In the SW CASC Contributions to Regional Impacts section, we outline engaged scholarship activities to demonstrate how they created societal impacts: (1) the Keepers of the Flame course and workshops, (2) the Southwest Fire Climate Adaptation Partnership and the Southern California Montane Forests Project, (3) the Coastal Managers Workshop, (4) the Colorado River Basin Wiki, and (5) the Natural Resource Workforce Development Program. In the SW CASC Publications Cited in Policy section, we used a bibliometric analysis to assess the impact of the SW CASC-funded research on policy. We analyzed how often publications were used in policy documents, finding a citation rate of 27.6%. This is high compared to similar analyses that found peer-reviewed research articles cited at a rate of 3.9% in policy documents. We conclude that coproduced science makes unique and important contributions to the resilience of the Southwest, not only by generating new knowledge but by building capacity, creating lasting relationships, and informing policy and conservation and management decisions.

Arizona, California, Nevada, Utah

SALTON SEA SCIENTIFIC DRILLING PROJECT: SCIENTIFIC PROGRAM.

The Salton Sea Scientific Drilling Project, was spudded on 24 October 1985, and reached a total depth of 10,564 ft. (3. 2 km) on 17 March 1986. There followed a period of logging, a flow test, and downhole scientific measurements. The scientific goals were integrated smoothly with the engineering and economic objectives of the program and the ideal of 'science driving the drill' in continental scientific drilling projects was achieved in large measure. The principal scientific goals of the project were to study the physical and chemical processes involved in an active, magmatically driven hydrothermal system. To facilitate these studies, high priority was attached to four areas of sample and data collection, namely: (1) core and cuttings, (2) formation fluids, (3) geophysical logging, and (4) downhole physical measurements, particularly temperatures and pressures.

Bulletin. Geothermal Resources Council

Table-top earthquakes; a demonstration of seismology for teachers and students that can be used to augment lessons in earth science, physics, math, social studies, geography

The apparatus consists of a heavy object that is dragged steadily with an elastic cord. Although pulled with a constant velocity, the heavy object repeatedly slides and then stops. A small vibration sensor, attached to a computer display, graphically monitors this intermittent motion. 2 This intermittent sliding motion mimics the intermittent fault slippage that characterizes the earthquake fault zones. In tectonically active regions, the Earth's outer brittle shell, which is about 50 km thick, is slowly deformed elastically along active faults. As the deformation increases, stress also increases, until fault slippage releases the stored elastic energy. This process is called elastic rebound. Detailed instructions are given for assembly and construction of this demonstration. Included are suggested sources for the vibration sensor (geophone) and the computer interface. Exclusive of the personal computer, the total cost is between $125 and $150. I gave a talk at the Geological Society of America's Cordilleran Section Centennial meeting on June 2, 1999. The slides show how this table-top demonstration can be used to help meet many of the K-12 teaching goals described in Benchmarks for Science Literacy (American Association for the Advancement of Science, 1993).

Open-File Report

Proceedings of the 25th Himalaya-Karakoram-Tibet Workshop

For a quarter of a century the Himalayan-Karakoram-Tibet (HKT) Workshop has provided scientists studying the India-Asia collision system a wonderful opportunity for workshop-style discussion with colleagues working in this region. In 2010, HKT returns to North America for the first time since 1996. The 25th international workshop is held from June 7 to10 at San Francisco State University, California. The international community was invited to contribute scientific papers to the workshop, on all aspects of geoscience research in the geographic area of the Tibetan Plateau and its bounding ranges and basins, from basic mapping to geochemical and isotopic analyses to large-scale geophysical imaging experiments. In recognition of the involvement of U.S. Geological Survey (USGS) scientists in a wide range of these activities, the USGS agreed to publish the extended abstracts of the numerous components of HKT-25 as an online Open-File Report, thereby ensuring the wide availability and distribution of these abstracts, particularly in the HKT countries from which many active workers are precluded by cost from attending international meetings. In addition to the workshop characterized by contributed presentations, participants were invited to attend a pre-meeting field trip from the Coast Ranges to the Sierra Nevada, to allow the international group to consider how the tectonic elements of the Pacific margin compare to those of the Himalayan belt. Following the workshop, the National Science Foundation (NSF) sponsored a workshop on the 'Future directions for NSF-sponsored geoscience research in the Himalaya/Tibet' intended to provide NSF Program Directors with a clear statement and vision of community goals for the future, including the scientific progress we can expect if NSF continues its support of projects in this geographic region, and to identify which key geoscience problems and processes are best addressed in the Himalaya and Tibet, what key datasets are needed, and how NSF can best support the evolving need for interdisciplinary investigations. This workshop also has clear societal relevance. Recent earthquakes have brought international attention to active tectonics and earthquake hazards in the HKT region. Prominent examples include the Mw 7.8 Kokoxili (Qinghai, China) earthquake of 2001, the Mw 7.6 Kashmir (Pakistan) earthquake of 2005, the Mw 7.9 Wenchuan (Sichuan, China) earthquake of 2008, and this year the Mw 6.9 Yushu (Qinghai, China) earthquake. Geological and geophysical field work conducted both before these earthquakes, as well as in response to them, has helped to define the active faults and regional tectonics in the HKT region. The research presented at this workshop provides the framework necessary for improved seismic hazard assessments in this region. The organizers gratefully acknowledge the support of NSF's Continental Dynamics Program and its Office of International Science and Engineering, through award EAR-0965796. We thank San Francisco State University's Sheldon Axler, Dean of the College of Science and Engineering, and Toby Garfield, Director of the Romberg Tiburon Center, for use of their conference facilities; and the Department of Geosciences, particularly Deb Shulman and Miriam Knof, for administrative support. The California Academy of Sciences generously hosted a reception for visiting delegates, and Brad Ritts (Chevron Exploration Technology Company), Todd Greene (California State University, Chico) and John Shervais (Utah State University) together co-led the pre-conference field trip. Technical editing of this volume was led by Roxanne Renedo (U.S. Geological Survey) with assistance from Margaret Milia (Stanford University). We are grateful to the U.S. Geological Survey (USGS) Earthquake Hazards Program and the USGS Menlo Park (California) Publishing Service Center for making this online report possible.

Open-File Report

Activities in tectonics of Research Committee of American Association of Petroleum Geologists

During 1945 and 1946, the Research Committee of the American Association of Petroleum Geologists, under the chairmanship of Shepard W. Lowman, has been engaged in “a reconnaissance survey of research in petroleum geology and allied sciences with explicit reference to exploration” in order “to formulate a comprehensive research program which the American Association of Petroleum Geologists may adopt as its recommendation for that research most needed to improve our ability to find oil” [see “References” at end of report, Lowman, 1945]. In order to make this survey, the field was divided among a number of subcommittees, including a Subcommittee on Tectonics, of which the writer was chairman. Preliminary reports, discussing the research possibilities in the various fields covered by the subcommittees, were submitted in January, 1946, and concrete recommendations were formulated by the Research Committee at the Chicago meeting of the Association in April 1946 [Lowman, 1946]. Final reports of the subcommittees will be published later in 1946 in the Bulletin of the American Association of Petroleum Geologists.

Eos, Transactions, American Geophysical Union

Volcanology: Lessons learned from Synthetic Aperture Radar imagery

Twenty years of continuous Earth observation by satellite SAR have resulted in numerous new insights into active volcanism, including a better understanding of subsurface magma storage and transport, deposition of volcanic materials on the surface, and the structure and development of volcanic edifices. This massive archive of data has resulted in fundamental leaps in our understanding of how volcanoes work – for example, identifying magma accumulation at supposedly quiescent volcanoes, even in remote areas or in the absence of ground-based data. In addition, global compilations of volcanic activity facilitate comparison of deformation behavior between different volcanic arcs and statistical evaluation of the strong link between deformation and eruption. SAR data are also increasingly used in timely hazard evaluation thanks to decreases in data latency and growth in processing and analysis techniques. The existing archive of SAR imagery is on the cusp of being enhanced by a new generation of satellite SAR missions, in addition to ground-based and airborne SAR systems, which will provide enhanced temporal and spatial resolution, broader geographic coverage, and improved availability of data to the scientific community. Now is therefore an opportune time to review the contributions of SAR imagery to volcano science, monitoring, and hazard mitigation, and to explore the future potential for SAR in volcanology. Provided that the ever-growing volume of SAR data can be managed effectively, we expect the future application of SAR data to expand from being a research tool for analyzing volcanic activity after the fact, to being a monitoring and research tool capable of imaging a wide variety of processes on different temporal and spatial scales as those processes are occurring. These data can then be used to develop new models of how volcanoes work and to improve quantitative forecasts of volcanic activity as a means of mitigating risk from future eruptions.

Journal of Volcanology and Geothermal Research

Land cover changes associated with recent energy development in the Williston Basin; Northern Great Plains, USA

The Williston Basin in the Northern Great Plains has experienced rapid energy development since 2000. To evaluate the land cover changes resulting from recent (2000 – 2015) development, the area and previous land cover of all well pads (pads) constructed during this time was determined, the amount of disturbed and reclaimed land adjacent to pads was estimated, land cover changes were analyzed over time for three different well types, and the effects from future development were predicted. The previous land cover of the 12,990 ha converted to pads was predominately agricultural (49.5%) or prairie (47.4%) with lesser amounts of developed (2.3%), aquatic (0.5%), and forest (0.4%). Additionally, 12,121 ha have likely been disturbed and reclaimed. The area required per gas well remained constant through time while the land required per oil well increased initially and then decreased as development first shifted from conventional to unconventional drilling and then to multi-bore pads. For non-oil-and- gas wells (i.e. stratigraphic test wells, water wells, injection wells, etc.), the area per well increased through time likely due to increased produced water disposal requirements. Future land cover change is expected to be 2.7 times greater than recent development with much of the development occurring in five counties in the core Bakken development area. Direct land cover change and disturbance from recent and expected development are predicted to affect 0.4% of the landscape across the basin; however, in the core Bakken development area, 2.3% of the landscape will be affected including 2.1% of the remaining grassland. Although future development will result in significant land cover change, evolving industry practices and proactive siting decisions, such as development along energy corridors and placing pads in areas previously altered by human activity, have the potential to reduce the ecological effects of future energy development in the Williston Basin.

Williston Basin

Neutron activation analysis of fluid inclusions for copper, manganese, and zinc

Microgram quantities of copper, manganese, and zinc, corresponding to concentrations greater than 100 parts per million, were found in milligram quantities of primary inclusion fluid extracted from samples of quartz and fluorite from two types of ore deposits. The results indicate that neutron activation is a useful analytical method for studying the content of heavy metal in fluid inclusions.

Science

In Service to the Nation: The Geology Scientist Emeritus Program

The Geology Scientist Emeritus Program of the U.S. Geological Survey was established in 1986 as part of the Bureau's Volunteer for Science Program. The purpose of the Scientist Emeritus (SE) Program is to help support retired USGS senior scientists as they volunteer their expertise, intellect, and creativity in efforts that allow them to remain active in the geoscience community, enhance the program activities of the Geology Discipline, and serve the public. The SE Program is open to all scientists and technical experts who have demonstrated leadership qualities and contributed to the goals of the USGS during a productive career. As long as the individual applying has been a scientist or technical expert, he or she may be considered for the SE Program, regardless of their previous position with the USGS.

Fact Sheet

Visitor and community survey results for Kilauea Point National Wildlife Refuge and Lighthouse: Completion report

The U.S. Fish and Wildlife Service (USFWS) and the Central Federal Lands Highway Division of the Federal Highway Administration, U.S. Department of Transportation are currently pursuing the planning and potential design of an alternative transportation system (ATS) for Kilauea Point National Wildlife Refuge (Refuge or Kilauea Point NWR). The USFWS and CFLHD seek an alternative transportation solution that provides the highest quality visitor experience and is sensitive to biological and cultural resources and the needs of the local community. In planning the alternative transportation system, managers need to consider how an ATS would change factors such as visitor access, visitor experience, visitor willingness to pay, and visitor net economic benefits. The Policy Analysis and Science Assistance branch (PASA) at the U.S. Geological Survey Fort Collins Science Center is dedicated to studying relations between humans and the environment. The objective of PASA is to conduct studies to understand how humans are affected by environmental management decisions and how human activities impact use and conservation of natural resources.

Hawaii

Summary of the history and research of the U.S. Geological Survey gas hydrate properties laboratory in Menlo Park, California, active from 1993 to 2022

The U.S. Geological Survey (USGS) Clathrate Hydrate Properties Project, active from 1993 to 2022 in Menlo Park, California, stemmed from an earlier project on the properties of planetary ices supported by the National Aeronautics and Space Administration’s (NASA’s) Planetary Geology and Geophysics Program. We took a material science approach in both projects, emphasizing chemical purity of samples, having controlled grain size and grain texture, and having verified crystal structures and phase relations. A foundational contribution from our USGS Gas Hydrate Properties Laboratory (GHPL) was in demonstrating the ability to reproducibly create such pure clathrate hydrate samples for study. Clathrate sample synthesis was achieved by heating sieved and weighed pure granular water ice in the presence of cold clathrate-forming gas or liquid. During heating, the ice melts at the grain scale and reacts with the gas to form clathrate. The resulting material has the desired uniformity and purity, with known intergranular porosity; our subsequent measurements showed that these clathrates exhibited the established clathrate structures and phase relations. This novel synthesis method was successful in creating clathrates of pure methane, ethane, propane, carbon dioxide, and multi-component gases. By mixing sand or silt with granular ice, we were also able to make clathrate-sediment aggregates with controlled grain textures. This simple method, adopted by many others in the community, permitted us to measure the physical and chemical properties of well-characterized and well-crystallized clathrates and clathrate/sediment aggregates. At about the same time, we adapted conventional scanning electron microscopy to cryogenic conditions for analysis of grain-scale characteristics of clathrates made in the GHPL as well as those collected from nature by drill core. The uniformity and reproducibility of our samples also allowed us to investigate how clathrates respond to environmental changes in chemistry, temperature, and pressure: we measured chemical exchange rates with dissolved gas species—such as noble gases and chlorofluorocarbons—as well as rates of clathrate dissolution and decomposition. These advances include the first accurate mapping of the conditions that promote the remarkable process of “anomalous preservation” at room pressure, a metastability that offers potential application for low-cost and safe transportation of natural gas from gas fields far from pipelines. Another advancement stemming from the GHPL was the compaction of as-synthesized porous clathrates to nearly full density by applying external pressure using three different techniques. Compaction allows for high-accuracy measurements of many fundamental physical and chemical properties of these materials, such as elastic wavespeeds and moduli, complete thermal properties, decomposition rates, thermal expansion, and clathrate equations of state. These properties and others, in turn, have helped USGS scientists to interpret geophysical well logs and active geophysical surveys, as well as model the rates of gas production from hydrate deposits in nature. Studying this class of icy minerals that occur in abundance on Earth and in the outer solar system has been a fascinating laboratory journey. Here, we summarize the history and major findings of the USGS GHPL in Menlo Park, including both in-house research as well as findings from the synergistic collaborations with other agencies and institutes that were key to the success of our laboratory. The Menlo Park GHPL was more formally incorporated within the USGS Gas Hydrates Project, a collaboration among multiple USGS Science Centers, in the early 2000s under the leadership of Deborah Hutchinson, and now under the leadership of Carolyn Ruppel and Timothy Collett.

Open-File Report