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At least 559 records · Page 31Linked to original sources
USGS1996

Magmatic infiltration and melting in the lower crust and upper mantle beneath the Cima volcanic field, California

Xenoliths of lower crustal and upper mantle rocks from the Cima volcanic field (CVF) commonly contain glass pockets, veins, and planar trains of glass and/or fluid inclusions in primary minerals. Glass pockets occupy spaces formerly occupied by primary minerals of the host rocks, but there is a general lack of correspondence between the composition of the glass and that of the replaced primary minerals. The melting is considered to have been induced by infiltration of basaltic magma and differentiates of basaltic magma from complex conduits formed by hydraulic fracturing of the mantle and crustal rocks, and to have occurred during the episode of CVF magmatism between ∼7.5 Ma and present. Variable compositions of quenched melts resulted from mixing of introduced melts and products of melting of primary minerals, reaction with primary minerals, partial crystallization, and fractionation resulting from melt and volatile expulsion upon entrainment of the xenoliths. High silica melts ( >∼60% SiO 2 ) may result by mixing introduced melts with siliceous melts produced by reaction of orthopyroxene. Other quenched melt compositions range from those comparable to the host basalts to those with intermediate Si compositions and elevated Al, alkalis, Ti, P, and S; groundmass compositions of CVF basalts are consistent with infiltration of fractionates of those basalts, but near-solidus melting may also contribute to formation of glass with intermediate silica contents with infiltration only of volatile constituents.

California↗
USGS2021

Miocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean

Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87 Sr/ 86 Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese crusts, and ironstones from the summit of Rio Grande Rise (RGR), Southwest Atlantic Ocean. Phosphatization of all the rock types occurred throughout the Miocene from 20.2 to 6.8 million years ago (Ma), and occasionally during the Quaternary, mainly through the cementation of carbonate sediments by cryptocrystalline CFA, likely involving the dissolution of the smaller size fraction of foraminifera-nannofossil ooze. Porosity/permeability and abundance of fine calcite material were important factors determining the intensity of phosphatization of the various rock types. Phosphatization was initiated during a transition to a more dynamic circulation system in the South Atlantic Ocean, which remobilized phosphorus from deeper waters and increased primary productivity that culminated with the middle-Miocene Climatic Optimum between ∼17 and 14.8 Ma. The relatively shallow-water depth of RGR summit during the Miocene provided proximity to the oxygen minimum zone, a reservoir for reactive phosphorus, especially during periods of enhanced phosphorus cycling spurred by surface primary productivity. The cessation of phosphatization at RGR resulted from a rapidly cooling and dry climate that characterized the Miocene-Pliocene transition. Our results support previous observations that periods of broadly intensified ocean circulation and local hydrodynamic changes were the key paleoceanographic links to phosphorite formation.

Paleoceanography and Paleoclimatology↗
USGS2010

Legacy of the California Gold Rush: Environmental geochemistry of arsenic in the southern Mother Lode Gold District

Gold mining activity in the Sierra Nevada foothills, both recently and during the California Gold Rush, has exposed arsenic-rich pyritic rocks to weathering and erosion. This study describes arsenic concentration and speciation in three hydrogeologic settings in the southern Mother Lode Gold District: mineralized outcrops and mine waste rock (overburden); mill tailings submerged in a water reservoir; and lake waters in this monomictic reservoir and in a monomictic lake developing within a recent open-pit mine. These environments are characterized by distinct modes of rock-water interaction that influence the local transport and fate of arsenic. Arsenic in outcrops and waste rock occurs in arsenian pyrite containing an average of 2 wt% arsenic. Arsenic is concentrated up to 1300 ppm in fine-grained, friable, iron-rich weathering products of the arsenian pyrite (goethite, jarosite, copiapite), which develop as efflorescences and crusts on weathering outcrops. Arsenic is sorbed as a bidentate complex on goethite, and substitutes for sulfate in jarosite. Submerged mill tailings obtained by gravity core at Don Pedro Reservoir contain arsenic up to 300 ppm in coarse sand layers. Overlying surface muds have less arsenic in the solid fraction but higher concentrations in porewaters (up to 500 μg/L) than the sands. Fine quartz tailings also contain up to 3.5 ppm mercury related to the ore processing. The pH values in sediment porewaters range from 3.7 in buried gypsum-bearing sands and tailings to 7 in the overlying lake sediments. Reservoir waters immediately above the cores contain up to 3.5 μg/L arsenic; lake waters away from the submerged tailings typically contain less than 1 μg/L arsenic. Dewatering during excavation of the Harvard open-pit mine produced a hydrologic cone of depression that has been recovering toward the pre-mining groundwater configuration since mining ended in 1994. Aqueous arsenic concentrations in the 80 m deep pit lake are up to 1000 μg/L. Redistribution of the arsenic occurs during summer stratification, with highest concentrations at middle depths. The total mass of arsenic in the pit lake increases coinciding with early winter rains that erode, partially dissolve, and transport arsenic-bearing salts into the pit lake. Arsenic concentration, speciation, and distribution in the Sierra Nevada foothills depend on many factors, including the lithologic sources of arsenic, climatic influences on weathering of host minerals, and geochemical characteristics of waters with which source and secondary minerals react. Oxidation of arsenian pyrite to goethite, jarosite, and copiapite causes temporary attenuation of arsenic during summer, when these secondary minerals accumulate; subsequent rapid dissemination of arsenic into the aqueous environment is caused by annual winter storms. As the population of the Mother Lode area grows, it is increasingly important to consider these effects during planning and development of land and groundwater resources.

California↗
USGS1999

Environmental processes that affect mineral deposits in the eastern United States

A thorough understanding of the environmental processes that affect mineral deposits and mine wastes has become increasingly important as the Nation wrestles with how to meet our current demand for metals without compromising the environment and how to mitigate the damage caused by the mining practices of previous generations. Regulatory requirements are dominated by empirical approaches to environmental problems associated with mining, but mitigation and reclamation can be enhanced greatly by a theoretical and conceptual understanding of the processes that affect the availability, transport, and fixation of metals and the generation of acidic waters. U.S. Geological Survey (USGS) research efforts in the Eastern United States are concentrating on environmental processes that affect a class of mineral deposits known as massive sulfide deposits. These occurrences were valued historically for their sulfur content and recently for their metals. This deposit type is a research priority because of its economic significance and high potential for adverse environmental impact due to its high sulfide content and the low acid-buffering capacity of host rocks. Numerous examples of these deposits are found in the East, including reclaimed mine sites, abandoned mines, active mines, and sites currently in the permitting process for future production. Published studies of mine drainage chemistry from the Iron Mountain massive sulfide deposit in California have documented extreme conditions of very low pH and high heavy-metal concentrations. These extreme conditions are attributed to the unique hydrologic and climatic settings of the deposit and probably are independent of the mineral deposit type. Areas currently under study include Bald Mountain, Maine, the Great Smoky Mountains National Park, the Vermont copper belt, Contrary Creek, Virginia, and Prince William Forest Park, Virginia (fig.1). Goals of the research are (1) to give land-use planners and the mining industry a better empirical framework from which to assess potential environmental impacts of mining, particularly under eastern climatic conditions, and (2) to provide a better theoretical and conceptual framework from which to design more effective and cost efficient mitigation and reclamation programs.

Information Handout↗
USGS2008

Evolving magma storage conditions beneath Mount St. Helens inferred from chemical variations in melt inclusions from the 1980-1986 and current (2004-2006) eruptions

Major element, trace element, and volatile concentrations in 187 glassy melt inclusions and 25 groundmass glasses from the 1980-86 eruption of Mount St. Helens are presented, together with 103 analyses of touching FE-Ti oxide pairs from the same samples. These data are used to evaluate the temporal evolution of the magmatic plumbing system beneath the volcano during 1980-86 and so provide a framework in which to interpret analyses of melt inclusions from the current (2004-2006) eruption. Major and trace element concentrations of all melt inclusions lie at the high SiO 2 end of the data array defined by eruptive products of the late Quaternary age from Mount St. Helens. For several major and trace elements, the glasses define a trend that is oblique to the whole-rock trend, indicating that different mineral assemblages were responsible for the two trends. The whole-rock trend can be ascribed to differentiation of hydrous basaltic parents in a deep-seated magma reservoir, probably at depths great enough to stabilize garnet. In contrast, the glass trends were generated by closed-system crystallization of the phenocryst and microlite mineral assemblages at low pressures. The dissolved H 2 O content of the melt inclusions from 1980-86, as measured by the ion microprobe, ranges from 0 to 6.7 wt. percent, with the highest values obtained from the plinian phase of May 18, 1980. Water contents decrease with increasing SiO 2 , consistent with decompression-driven crystallization. Preliminary data for dissolved CO 2 in melt inclusions from the May 18 plinian phase from August 7, 1980, indicate that X H 2 O in a vapor phase was approximately constant at 0.80, irrespective of H 2 O content, suggestive of closed-system degassing with a high bubble fraction or gas streaming through the subvolcanic system. Temperature and f O 2 estimates for touching Fe-Ti oxides show evidence for heating during crystallization owing to release of latent heat. Consequently, magmas with the highest microlite crystallinities record the highest temperatures. Magmas also become progressively reduced during ascent and degassing, probably as a result of redox equilibria between exsolving S-bearing gases and magmas. The lowest temperature oxides have f O 2 ≈ NNO, similar to high-temperature fumarole gases from the volcano. The temperature and f O 2 of the magma tapped by the plinian phase of May 18, 1980, are 870-875°C and NNO+0.8, respectively. The dissolved volatile contents of the melt inclusions have been used to calculate sealing pressures; that is, the pressure at which chemical exchange between inclusion and matrix melt ceased. These are greatest for the May 18 plinian magma (120 to 320 MPa); lower pressures are recorded by samples of the preplinian cryptodome and by all post-May 18 magmas. Magma crystallinity, calculated from melt-inclusion Rb contents, is negatively correlated with sealing pressure, consistent with decompression crystallization. Elevated contents of Li in melt inclusions from the cryptodome and post-May 18 samples are consistent with transfer of Li in a magmatic vapor phase from deeper parts of the magma system to magma stored at shallower levels. The Li enrichment attains its maximum extent at ~150 MPa, which is ascribed to separation of a single vapor phase into H 2 O-rich gas and dense Li-rich brine at the top of the magma column. There are striking correlations between melt-inclusion chemistry and monitoring data for the 1980-86 eruption. Dissolved SO 2 contents of melt inclusions from any given event, multiplied by the mass of magma erupted during that event, correlate with the measured flux of SO 2 at the surface, suggesting that magma degassing and melt-inclusion sealing are closely related in time and space. Textural and chemical evidence indicates that melt inclusions became effectively sealed (physically or kinetically) shortly before eruption. Thus by converting pressure to depth using a density model and edifice-loading algorithm for the volcano, changing depths of magma extraction with time can be tracked and compared to the seismic record. The plinian eruption of May 18, 1980, involved magma stored 5-11 km below sea level; this is inferred to be the subvolcanic magma chamber. The preceding eruptions, including the May 18, 1980, blast, involved magma withdrawal from the cryptodome and conduit down to 5 km below sea level. Subsequent 1980 eruptions tapped magma down to depths of ≤10 km below sea level. Tapping of magma stored deeper than 2 km below sea level stopped abruptly at the end of 1980, coincident with the onset of extensive shallow seismicity and a change from explosive to effusive eruption style from 1981 to 1986. Overall, the 1980-86 eruption is consistent with the evisceration of a thin, vertically extensive body of magma extending from 5 to at least 11 km below sea level and connected to the surface by a thin conduit. In the absence of sustained high magma-supply rates from depth, decompression crystallization of magma ascending through the system leads eventually to plugging of the conduit. The current eruption of Mount St. Helens shares some similarities with the 1981-86 dome-building phase of the previous eruption, in that there is extensive shallow seismicity and extrusion of highly crystalline material in the form of a sequence of flows and spines. Melt inclusions from the current eruption have low H 2 O contents, consistent with magma extraction from shallow depths. Highly enriched Li in melt inclusions suggests that vapor transport of Li is a characteristic feature of Mount St. Helens. Melt inclusions from the current eruption have subtly different trace-element chemistry from all but one of the 1980-86 melt inclusions, with steeper rareearth-element (REE) patterns and low U, Th, and high-fieldstrength elements (HFSE), indicating addition of a new melt component to the magma system. It is anticipated that increasing involvement of the new melt component will be evident as the current eruption proceeds.

Washington↗
USGS1996

Influence of stretching and density contrasts on the chemical evolution of continental magmas: An example from the Ivrea-Verbano Zone

The southern Ivrea-Verbano Zone of the Italian Western Alps contains a huge mafic complex that intruded high-grade metamorphic rocks while they were resident in the lower crust. Geologic mapping and chemical variations of the igneous body were used to study the evolution of underplated crust. Slivers of crustal rocks (septa) interlayered with igneous mafic rocks are concentrated in a narrow zone deep in the complex (Paragneiss-bearing Belt) and show evidence of advanced degrees of partial melting. Variations of rare-earth-element patterns and Sr isotope composition of the igneous rocks across the sequence are consistent with increasing crustal contamination approaching the septa. Therefore, the Paragneiss-bearing Belt is considered representative of an “assimilation region” where in-situ interaction between mantle- and crust-derived magmas resulted in production of hybrid melts. Buoyancy caused upwards migration of the hybrid melts that incorporated the last septa and were stored at higher levels, feeding the Upper Mafic Complex. Synmagmatic stretching of the assimilation region facilitated mixing and homogenization of melts. Chemical variations of granitoids extracted from the septa show that deep septa are more depleted than shallow ones. This suggests that the first incorporated septa were denser than the later ones, as required by the high density of the first-injected mafic magmas. It is inferred that density contrasts between mafic melts and crustal rocks play a crucial role for the processes of contamination of continental magmas. In thick under plated crust, the extraction of early felsic/hybrid melts from the lower crust may be required to increase the density of the lower crust and to allow the later mafic magmas to penetrate higher crustal levels.

Contributions to Mineralogy and Petrology↗
USGS2003

Response of benthic invertebrate assemblages to metal exposure and bioaccumulation associated with hard-rock mining in northwestern streams, USA

Benthic macroinvertebrate assemblages, environmental variables, and associated mine density were evaluated during the summer of 2000 at 18 reference and test sites in the Coeur d'Alene and St. Regis River basins, northwestern USA as part of the US Geological Survey's National Water-Quality Assessment Program. Concentrations of Cd, Pb, and Zn in water and (or) streambed sediment at test sites in basins where production mine density was ???0.2 mines/km2 (in a 500-m stream buffer) were significantly higher than concentrations at reference sites. Zn and Pb were identified as the primary contaminants in water and streambed sediment, respectively. These metal concentrations often exceeded acute Ambient Water Quality Criteria for aquatic life and the National Oceanic and Atmospheric Administration Probable Effect Level for streambed sediment. Regression analysis identified significant correlations between production mine density in each basin and Zn concentrations in water and Pb in streambed sediment (r2 = 0.69 and 0.65, p < 0.01). Metal concentrations in caddisfly tissue, used to verify site-specific exposures of benthos, also were highest at sites downstream from intensive mining. Benthic invertebrate taxa richness and densities were lower at sites downstream than upstream of areas of intensive hard-rock mining and associated metal enrichment. Benthic invertebrate metrics that were most effective in discriminating changes in assemblage structure between reference and mining sites were total number of taxa, number of Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa, and densities of total individuals, EPT individuals, and metal-sensitive Ephemeroptera individuals.

Journal of the North American Benthological Societ↗
USGS2018

Strategic and critical metals in produced geothermal fluids from Nevada and Utah

Herein we summarize the results of an investigation dealing with the concentrations and inventories of strategic, critical and valuable materials (SCVM) in produced fluids from geothermal and hydrocarbon reservoirs (50-250° C) in Nevada and Utah. Water samples were collected from thirty-four production wells across eight geothermal fields, the Uinta Basin oil/gas province in northeast Utah, and the Covenant oil field in southwestern Utah; additional water samples were collected from six hot springs in the Sevier Thermal Belt in southwestern Utah. Most SCVM concentrations in produced waters range from <0.1 to 100 µg/kg; the main exception is lithium, which has concentrations that range from <1000 to 25,000 ug/kg. Relatively high concentrations of gallium, germanium, scandium, selenium, and tellurium are measured too. Geothermal waters contain very low concentrations of REEs, below analytical detections limits (0.01 µg/kg), but the concentrations of lanthanum, cerium, and europium range from 0.05 to 5 µg/kg in Uinta basin waters. Among the geothermal fields, the Roosevelt Hot Spring reservoir appears to have the largest inventories of germanium and lithium, and Patua appears to have the largest inventories of gallium, scandium, selenium, and tellurium. By comparison, the Uinta basin has larger inventories of gallium. The concentrations of gallium, germanium, lithium, scandium, selenium, and tellurium in produced waters appear to be partly related to reservoir temperature and concentrations of total dissolved salts. The relatively high concentration and large inventory of lithium occurring at Roosevelt Hot Springs may be related to granitic-gneissic crystalline rocks, which host the reservoir. Analyses of calcite scales from Dixie Valley indicate enrichments in cobalt, gallium, gold, palladium, selenium and tellurium, and these metals appear to be depositing at deep levels in production wells due to boiling. Comparisons with SCVM mineral deposits suggest that brines in sedimentary basins, or derived from lacustrine evaporites, enable aqueous transport of gallium, germanium, and lithium.

Conference Paper↗
USGS1951

Diamond-drill exploration of the Rousseau talc prospect, Cambridge, Vermont, and the Barnes Hill prospect, Waterbury, Vermont

The Geological Survey carried out a program of diamond-drilling at two localities in Vermont during the period July-September 1950. The deposits chosen for drilling were two of the more promising talc deposits associated with ultramafic rocks of several that had been mapped earlier by the Geological Survey, but could not be evaluated accurately because critical data were lacking that could be obtained only by sub-surface exploration. The Rousseau talc prospect is in Cambridge township, Lamoille County, Vermont. Surface rights are owned by L. and N. N. Porter; mineral rights are owned by Eastern Magnesia Talc Co. Three drill holes encountered no talc; the other five penetrated from 2 to 110 feet of talc ore. The deposit lies on the west limb of the Green Mountain anticlinorium. The country rock consists of quartz-chlorite-sericite schist and chlorite-albite schist. The schistosity strikes slightly west of north and dips 20° - 40° to the west. The talc deposit is roughly lenticular, and although generally concordant in detail with the schistosity of the country rock, is slightly cross-cutting in overall relationship. The entire deposit is composed of Tit (talc-carbonate rock) and steatite, out is presumably derived from ultramafic igneous rooks which were first serpentinized. The dimensions of the lens are about 700 feet by 500 feet by 130 feet. The talc is of good quality and is suitable, either as a mine run product or as a flotation concentrate, for most industrial uses other than industrial steatite. No pencil stock was encountered. The Barnes hill talc prospect is in Waterbury township, Washington County, Vermont. Surface rights are divided among Donald P. and Glenola Brown, John Barnes, and Eastern Magnesia Talc Co. One drill hole at Barnes hill was barren. The other six penetrated about 20 to 140 feet of talc ore. The deposit lies on the east limb of the Green Mountain anticlinorium. The country rock outside of the ultramafic rock body consists of quartz-chlorite-sericite schist, chlorite-albite schist; and chlorite amphibolite, which strike generally about N, 20° E. and dip steeply to the east. The ultramafic body is elliptical in plan, about 1,600 feet long and 360 feet wide. The vertical dimension is unknown. The original ultramafic rock has been almost completely serpentinized and is extensively altered to grit and steatite. The talc ore is somewhat irregularly distributed throughout the ultramafic body, but it is possible to delineate with considerable confidence portions of the body that consist predominantly of ore. The largest ore bodies are in the eastern and northern parts of the ultramafic body. The ore contains more or less admixed serpentine, and so is only of intermediate to fairly good color (whiteness). It is suitable for many industrial uses in which purity and high whiteness are not necessary. No pencil stock was seen.

Vermont↗
USGS2006

Chapter 5. Assessment of undiscovered conventional oil and gas resources-Lower Cretaceous Travis Peak and Hosston formations, Jurassic Smackover interior salt basins total petroleum system, in the East Texas basin and Louisiana-Mississippi salt basins provinces

The Lower Cretaceous Travis Peak Formation of east Texas and southern Arkansas (and the correlative Hosston Formation of Louisiana and Mississippi) is a basinward-thickening wedge of terrigenous clastic sedimentary rocks that underlies the northern Gulf of Mexico Basin from east Texas across northern Louisiana to southern Mississippi. Clastic detritus was derived from two main fluvial-deltaic depocenters, one in northeastern Texas and the other extending from southeastern Mississippi northwestward into northeastern Louisiana. Across the main hydrocarbon-productive trend in east Texas and northern Louisiana, the Travis Peak and Hosston Formations are about 2,000 ft thick. The most likely sources for hydrocarbons in Travis Peak and Hosston reservoirs are two stratigraphically lower units, lime mudstones of the Upper Jurassic Smackover Formation and organic-rich shales of the Upper Jurassic Bossier Shale of the Cotton Valley Group. As a result of the absence of proximal source rocks and a lack of effective migration pathways from stratigraphically or geographically distant source rocks, hydrocarbon charge is sufficient for development of conventional gas accumulations but insufficient for development of basin-centered gas. The petroleum assessment of the Travis Peak and Hosston Formations was conducted by using a total petroleum system model. A total petroleum system includes all of the important elements of a hydrocarbon fluid system needed to develop oil and gas accumulations, including source and reservoir rocks, hydrocarbon generation, migration, traps and seals, and undiscovered accumulations. A total petroleum system is mappable and may include one or more assessment units. For each assessment unit, reservoir rocks contain similar geology, exploration characteristics, and risk. The Jurassic Smackover Interior Salt Basins Total Petroleum System is defined for this assessment to include (1) Upper Jurassic Smackover carbonates and calcareous shales and organic-rich shales of the Upper Jurassic Bossier Shale of the Cotton Valley Group and (2) Lower Cretaceous Travis Peak and Hosston Formations. The Jurassic Smackover Interior Salt Basins Total Petroleum System includes three conventional Travis Peak-Hosston assessment units: Travis Peak-Hosston Gas and Oil (AU 50490205), Travis Peak-Hosston Updip Oil (AU 50490206), and Travis Peak-Hosston Hypothetical Updip Oil (AU 50490207). A fourth assessment unit, the Hosston Hypothetical Slope-Basin Gas Assessment Unit, was named and numbered (AU 50490208) but not geologically defined or quantitatively assessed owing to a lack of data. Together, assessment units 50490205 to 50490207 are estimated to contain a mean undiscovered conventional resource of 29 million barrels of oil, 1,136 billion cubic feet of gas, and 22 million barrels of natural gas liquids.

Alabama, Arkansas. Florida, Georgia, Louisiana, Mi↗
USGS2014

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗
USGS2012

Geology of the Mount St. Helens area: Record of discontinuous volcanic and plutonic activity in the Cascade Arc of southern Washington

The Quaternary edifice of Mount St. Helens volcano was built upon a deeply eroded terrane of gently folded and altered volcanic and plutonic rocks that represent the core of the Tertiary Cascade magmatic arc. These rocks constitute an east dipping homoclinal sequence, several kilometers thick, of subaerially erupted mafic to silicic flows and volcaniclastic strata; K‐Ar ages from this section range from about 28 to 23 Ma (late Oligocene and earliest Miocene), which corresponds to an apparent lull in Cascade volcanism to the north of Mount Rainier. Volcanism was essentially continuous during this period of time, and neither a well‐defined base nor top of the section is exposed within the mapped area. Basalt and basaltic andesite dominate the lower part of the mid‐Tertiary section, whereas andesitic and dacitic rocks comprise most of the upper part. This section was intruded by numerous mafic to silicic dikes, sills, and irregular plutonic bodies, most no more than a few million years younger than their host rocks, and subjected to pervasive burial metamorphism and widespread hydrothermal alteration. Large areas of hornfelsed rock surrounding even relatively small intrusions indicate that the proportion of plutonic rock becomes significantly greater at shallow depth beneath the existing erosion surface. A large granitic pluton intruded the mid‐Tertiary section north of Spirit Lake at about 21 Ma. The Earl porphyry copper deposit occurs within the pluton but appears too young (17 Ma) to be genetically related to it. In contrast to the rather continuous and voluminous Oligocene to early Miocene activity, volcanism since then in the Mount St. Helens area has been localized and Volumetrically minor. Products of three younger eruptive periods have been recognized: a sequence of 15 m.y. old pyroxene andesite flows resting unconformably on mid‐Tertiary strata south of Mount St. Helens, widespread shallow dikes and sills of pyroxene andesite between 10 and 8 m.y. old, and compositionally diverse rocks erupted during the past 3 m.y. The Quaternary lavas are more potassic than the Tertiary lavas and typically contain phenocrysts of hornblende and biotite, which are absent from the older rocks. A number of Tertiary structures define a broad NNE trending zone that may reflect a deep‐seated lithospheric flaw that has controlled the locus of Cascade magmatism in southern Washington for the past 25 m.y. Mount St. Helens lies within this zone at the intersection of the NNW striking St. Helens seismic zone (SHZ) and an ENE trending alignment of Pleistocene silicic plug‐domes. No surface breakage has been detected along the SHZ, which is apparently very young. The linear zone of silicic vents is probably controlled by a fault that has been interpreted from seismic records to occur directly beneath the volcano. This zone parallels the directions of regional maximum horizontal compressive stress and North America/Juan de Fuca plate convergence. Mount St. Helens is an example of a low‐volume tectonically controlled magmatic system in an early stage of development.

Washington↗
USGS2017

Manganese

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits. From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources and about 25 percent of its reserves. South Africa, Brazil, and Ukraine together accounted for nearly 65 percent of reserves in 2013. The combination of total import reliance for manganese, the mineral commodity’s essential uses in our industrialized society, and the potential for supply disruptions because of the limited sources of the ore makes manganese among the most critical minerals for the United States. Manganese is the 12th most abundant element in Earth’s crust. Its concentration varies among common types of rocks, mostly in the range of from 0.1 to 0.2 percent. The highest quality manganese ores contain from 40 to 45 percent manganese. The formation of these ores requires specialized geologic conditions that concentrate manganese at several hundred times its average crustal abundance. The dominant processes in forming the world’s principal deposits take place in the oceans. As a result, most important manganese deposits occur in ancient marine sedimentary rocks that are now exposed on continents as a result of subsequent tectonic uplift and erosion. In many cases, other processes have further enriched these manganiferous sedimentary rocks to form some of today’s highest grade ores. Modern seabed resources of ferromanganese nodules cover vast areas of the present ocean floor and are still forming by complex interactions of marine microorganisms, manganese dissolved in seawater, and chemical processes on the seabed. Manganese is ubiquitous in soil, water, and air. It occurs most often in solid form but can become soluble under acidic conditions. Manganese mining, like any activity that disturbs large areas of Earth’s surface, has the potential to produce increases in manganese concentrations that could be harmful to humans or the environment if not properly controlled. Although manganese is an essential nutrient for humans and most other organisms, overexposure can lead to neurotoxicity in humans. Workers at manganese mining and processing facilities have the greatest potential to inhale manganese-rich dust. Without proper protective equipment, these workers may develop a permanent neurological disorder known as manganism. Each manganese mine is unique and presents its own suite of potential hazards and preventative measures. Likewise, various nations have their own sets of standards to ensure safe mining, isolation of mine waste, treatment of mine waters, and mine closure and restoration. Interest in mining trace metals contained in ferromanganese nodules and crusts on the seabed has increased rapidly in the past decade. Prime areas for future research include overcoming the technological challenges presented by mining as deep as 6,500 meters below sea level and understanding and mitigating the potential impacts of seabed mining on marine ecosystems.

Professional Paper↗
USGS2019

Monitoring, forecasting collapse events, and mapping pyroclastic deposits at Sinabung volcano with satellite imagery

During the ongoing (2013–present) eruption of Sinabung volcano, north Sumatra, we have routinely used a variety of satellite remote sensing data to observe and forecast lava dome and lava flow collapse events, to map the resulting pyroclastic deposits, and to estimate effusion rates. In this paper, we focus on the first two years of the current eruption (September 2013–December 2015), and we summarize major events in 2016. We divide the eruption into 5 major phases: 1) phreatomagmatic (July 2013–18 December 2013), 2) first dome growth and collapse (18 December 2013–10 January 2014), 3) lava-flow (10 January 2014–mid-September 2014), 4) second lava dome and collapse (mid-September 2014–July 2015), 5) lava dome collapse and ash explosion phase (August 2015–present). Throughout the eruption, remotely sensed information has been instrumental in assessing the stability of the lava dome and flow and to forecast collapse events that produce pyroclastic density currents (PDCs: block-and-ash flows, co-ignimbrite surges, and blasts). Forecasts based on remote sensing data in combination with seismic, geodetic and gas-monitoring data have also helped inform decisions related to alert levels and evacuations. Relatively unusual aspects of the Sinabung eruption include the transition from dome to flow morphology (phase 2 to phase 3 transition) and the frequent occurrence during phase 3 of collapses from the lava flow-front and flow-margins—collapses that produced extensive pyroclastic density currents. By analogy to the well-known “Merapi type” collapses and pyroclastic deposits, we propose that lava flow-front and flow-margin collapses with associated PDCs be known as “Sinabung type.” Although detailed study of deposits has not been possible due to continuing hazards, our observations suggest that the transition from lava dome to lava flow and the occurrence of flow-front and flow-margin collapses reflect a particular combination of lava viscosity and steepness of slope. Our observations also show clear evidence of at least one slope-parallel high-velocity and dilute PDC (a “blast”) that emanated from a lava-margin collapse site 500 m downslope from the vent. This 1 February 2014 blast downed and singed a forest out to at least 3.9 km from the collapse site and killed 16 people. We also use a combination of field and remotely sensed data to map the distribution of Sinabung deposits. We estimate eruptive volumes and extrusion rates by combining sequential measurements of lava surface and pyroclastic flow areas with thickness estimates derived from simple geometric assumptions, oblique photographs and Digital Elevation Models (DEMs) derived from remotely sensed data. Our estimates of short-term effusion rates vary widely on a daily to weekly basis, from <1 to >20 m 3 s −1 . In a few cases, periods of increased extrusion precede lava flow-front collapses by a few days to a week, suggesting delays in transmittance of effusion pulses as lava moves from vent to flow front. We find that, as of 1 January 2016, the total area of deposits is 10 7 m 2 , and their approximate deposit volume is about 0.3 km 3 , equivalent to 0.2 km 3 Dense Rock Equivalent (DRE). We anticipate that our deposit maps will be valuable in the future as a framework for the study of the magmatic and textural evolution of eruptive products through time.

Sinabung volcano↗
USGS2013

Petrologic, tectonic, and metallogenic evolution of the southern segment of the ancestral Cascades magmatic arc, California and Nevada

Ongoing arc magmatism along western North America was preceded by ancestral arc magmatism that began ca. 45 Ma and evolved into modern arc volcanism. The southern ancestral arc segment, active from ca. 30 to 3 Ma, adjoins the northern segment in northern California across a proposed subducted slab tear. The east edge of the Walker Lane approximates the east edge of the southern arc whose products, mostly erupted from stratovolcanoes and lava dome complexes arrayed along the crest of the ancestral arc, extend down the west flank of the Sierra Nevada. Southern arc segment rocks include potassic, calc-alkaline intermediate- to silicic-composition lava flows, lava dome complexes, and associated volcaniclastic deposits. Northern and southern segment rocks are similar to other convergent-margin magmatic arc rocks but are compositionally distinct from each other. Southern segment rocks have lower TiO 2 , FeO*, CaO, and Na 2 O contents and higher K 2 O contents, and exhibit less compositional-temporal variation. Compositional distinctions between the northern and southern segment rocks reflect the composition and thickness of the crust beneath which the associated magma systems were sourced. Northern segment rock compositions are consistent with generation beneath thin, primitive crust, whereas southern segment rocks represent magmas generated and fractionated beneath thicker, more evolved crust. Although rocks in the two arc segments have similar metal abundances, they are metallogenically distinct. Small porphyry copper deposits are characteristic of the northern segment whereas significant epithermal precious metal deposits are most commonly associated with the southern segment. These metallogenic differences are also fundamentally linked to the tectonic settings and crustal regimes within which these two arc segments evolved.

California, Nevada↗
USGS2011

Undiscovered petroleum resources for the Woodford Shale and Thirteen Finger Limestone-Atoka Shale assessment units, Anadarko Basin

In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (R o ), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.

Open-File Report↗
USGS1974

Mineral resources of Du Noir Addition, Washakie Wilderness area, Fremont County, Wyoming

The Du Noir Addition to the Washakie Wilderness area consists of 34,200 acres (13,840 hectares) of scenic mountainous terrain that adjoins the Teton Wilderness and Washakie Wilderness areas. The area was studied in 1973 by the U.S. Geological Survey and U.S. Bureau of Mines to evaluate its mineral, fuel, and geothermal energy potential. This evaluation is based on a search of the geologic literature, claim and production records, and fieldwork including mapping, inspection of claims and prospects, interpretation of aeromagnetic maps, and analyses of bedrock and stream-sediment samples. Flat-lying Eocene volcaniclastic rocks of the Absaroka volcanic field are exposed in about two-thirds of the Du Noir Addition. These volcanics unconformably overlie the deeply eroded, northwest-trending Du Noir anticline in which Paleozoic marine strata of Devonian through Permian age are exposed. Of lesser importance are small deposits of Eocene non-volcanic conglomerate, and basaltic intrusive and extrusive rocks of late Pliocene and possibly younger age. The results of this study indicate that the mineral, fuel, and geothermal potential of the Du Noir Addition are minimal. Low-grade copper-molybdenum mineralization occurs outside the addition, associated with intrusive rocks, but no indications of alteration or mineralization were found within the study area. Anomalous, but not economically important, concentrations of molybdenum and uranium were found in Permian and Eocene carbonaceous shales. Phosphate rock in the Phosphoria Formation occurs in beds too thin to constitute a resource. Large amounts of very pure limestone are present in the Madison Limestone, but equally pure limestone, much closer to transportation facilities, is found throughout this part of Wyoming. That part of the Du Noir anticline in the addition is too deeply eroded to be a likely reservoir of oil and gas. Present data indicates a low potential for geothermal energy in or near the addition.

Wyoming↗
USGS2026

Cenozoic distributed volcanism of the Arabia Plate—A review

Cenozoic volcanic rocks of the Arabia Plate cover about 140,000 square kilometers across a distance of about 3,000 kilometers from southern Yemen to southeastern Turkey. The majority of volcanic products are alkali basalts that erupted in restricted areas, commonly over periods of a million or more years, building mafic lava fields, each known in Arabic as a “harrat.” Harrat volcanism commenced following the Oligocene flood-lava effusions that blanketed the (now) Ethiopian highlands, southern Sudan, and western Yemen, and overlapped the latest Oligocene to early Miocene initial riftings of the Red Sea and Gulf of Aden, but the majority of harrat volcanism has been since approximately 13–10 million years ago. Persistent harrat magmatism in restricted locations led to the development of intermediate and evolved magmas (hawaiites, mugearites, benmoreites, trachytes, comendites, and phonolites) mainly through intracrustal crystallization-differentiation. Most of these intermediate and evolved magmas erupt at sites of the greatest aggregate volcanic relief, reflecting sites of the greatest overall magmatic fluxes. Production of fractionated magmas at these sites negates “monogenetic” as an appropriate descriptor of harrat volcanism. This chapter summarizes the geologic, eruptive, and tectonic history and aspects of the petrogenesis of the Cenozoic Arabian alkalic province. Particular emphasis is placed on results of a joint study of Ḩarrat Rahat adjacent to the city of Al Madīnah al Munawwarah, Kingdom of Saudi Arabia, published as U.S. Geological Survey Professional Paper 1862 and Saudi Geological Survey Special Report SGS–SP–2021–1. A goal of this chapter is to provide an introduction to those unfamiliar with this vast, enigmatic, and fascinating region of distributed continental volcanism.

Arabia Plate↗