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At least 559 records · Page 31Linked to original sources
USGS2009

Water quality and evaluation of pesticides in lakes in the Ridge Citrus region of central Florida

Water chemistry, including major inorganic constituents, nutrients, and pesticide compounds, was compared between seven lakes surrounded by citrus agriculture and an undeveloped lake on the Lake Wales Ridge (herein referred to as the Ridge) in central Florida. The region has been recognized for its vulnerability to the leaching of agricultural chemicals into the subsurface due to factors including soils, climate, and land use. About 40 percent of Florida's citrus cultivation occurs in 'ridge citrus' areas characterized by sandy well drained soils, with the remainder in 'flatwoods citrus' characterized by high water tables and poorly drained soils. The lakes on the Ridge are typically flow-through lakes that exchange water with adjacent and underlying aquifer systems. This study is the first to evaluate the occurrence of pesticides in lakes on the Ridge, and also represents one of the first monitoring efforts nationally to focus on regional-scale assessment of current-use pesticides in small- to moderate-sized lakes (5 to 393 acres). The samples were collected between December 2003 and September 2005. The lakes in citrus areas contained elevated concentrations of major inorganic constituents (including alkalinity, total dissolved solids, calcium, magnesium, sodium, potassium, chloride, and sulfate), total nitrogen, pH, and pesticides compared to the undeveloped lake. Nitrate (as N) and total nitrogen concentrations were typically elevated in the citrus lakes, with maximum values of 4.70 and 5.19 mg/L (milligrams per liter), respectively. Elevated concentrations of potassium, nitrate, and other inorganic constituents in the citrus lakes likely reflect inputs from the surficial ground-water system that originated predominantly from agricultural fertilizers, soil amendments, and inorganic pesticides. A total of 20 pesticide compounds were detected in the lakes, of which 12 compounds exceeded the standardized reporting level of 0.06 ug/L (microgram per liter). Those most frequently detected above the 0.06-ug/L level were aldicarb sulfoxide, diuron, simazine degradates hydroxysimazine and didealkylatrazine (DDA), bromacil, norflurazon, and demethyl norflurazon which occurred at detection rates ranging from 25 to 86 percent of samples, respectively. Typically, pesticide concentrations in the lake samples were less than 1 microgram per liter. The number of targeted pesticide compounds detected per lake in the citrus areas ranged from 9 to 14 compared to 3 compounds detected at trace levels in the undeveloped lake. Consistent detections of parents and degradates in quarterly samples indicated the presence of pesticide compounds in the lakes many months or years (for example, bromacil) after their application, signaling the persistence of some pesticide compounds in the lakes and/or ground-water systems. Pesticide degradate concentrations frequently exceeded parent concentrations in the lakes. This study was the first in the Ridge citrus region to analyze for glyphosate - widely used in citrus - and its degradate aminomethylphosphonic acid (AMPA), neither of which were detected, as well as a number of triazine degradates, including hydroxysimazine, which were detected. The lake pesticide concentrations did not exceed current Federal aquatic-life benchmarks, available for 10 of the 20 detected pesticide compounds. Limited occurrences of bromacil, diuron, or norflurazon concentrations were within about 10 to 90 percent of benchmark guidelines for acute effects on nonvascular aquatic plants in one or two of the lakes. The lake pesticide concentrations for several targeted pesticides were relatively high compared to corresponding national stream-water percentiles, which is consistent with this region's vulnerability for pesticide leaching into water resources. Several factors were evaluated to gain insight into the processes controlling pesticide transport and fate, and to assess their utility for estimating th

Florida↗
USGS2011

Aggregation of estimated numbers of undiscovered deposits: an R-script with an example from the Chu Sarysu Basin, Kazakhtan: Chapter B in Global mineral resource assessment

Mineral resource assessments completed by the U.S. Geological Survey during the past three decades express geologically based estimates of numbers of undiscovered mineral deposits as probability distributions. Numbers of undiscovered deposits of a given type are estimated in geologically defined regions. Using Monte Carlo simulations, these undiscovered deposit estimates are combined with tonnage and grade models to derive a probability distribution describing amounts of commodities and rock that could be present in undiscovered deposits within a study area. In some situations, it is desirable to aggregate the assessment results from several study areas. This report provides a script developed in open-source statistical software, R, that aggregates undiscovered deposit estimates of a given type, assuming independence, total dependence, or some degree of correlation among aggregated areas, given a user-specified correlation matrix.

Chu Sarysu Basin↗
USGS2010

Conceptual ecological models to guide integrated landscape monitoring of the Great Basin

The Great Basin Integrated Landscape Monitoring Pilot Project was developed in response to the need for a monitoring and predictive capability that addresses changes in broad landscapes and waterscapes. Human communities and needs are nested within landscapes formed by interactions among the hydrosphere, geosphere, and biosphere. Understanding the complex processes that shape landscapes and deriving ways to manage them sustainably while meeting human needs require sophisticated modeling and monitoring. This document summarizes current understanding of ecosystem structure and function for many of the ecosystems within the Great Basin using conceptual models. The conceptual ecosystem models identify key ecological components and processes, identify external drivers, develop a hierarchical set of models that address both site and landscape attributes, inform regional monitoring strategy, and identify critical gaps in our knowledge of ecosystem function. The report also illustrates an approach for temporal and spatial scaling from site-specific models to landscape models and for understanding cumulative effects. Eventually, conceptual models can provide a structure for designing monitoring programs, interpreting monitoring and other data, and assessing the accuracy of our understanding of ecosystem functions and processes.

Scientific Investigations Report↗
USGS2021

Complex vulnerabilities of the water and aquatic carbon cycles to permafrost thaw

The spatial distribution and depth of permafrost are changing in response to warming and landscape disturbance across northern Arctic and boreal regions. This alters the infiltration, flow, surface and subsurface distribution, and hydrologic connectivity of inland waters. Such changes in the water cycle consequently alter the source, transport, and biogeochemical cycling of aquatic carbon (C), its role in the production and emission of greenhouse gases, and C delivery to inland waters and the Arctic Ocean. Responses to permafrost thaw across heterogeneous boreal landscapes will be neither spatially uniform nor synchronous, thus giving rise to expressions of low to medium confidence in predicting hydrologic and aquatic C response despite very high confidence in projections of widespread near-surface permafrost disappearance as described in the 2019 Intergovernmental Panel on Climate Change Special Report on the Ocean and Cryosphere in a Changing Climate: Polar Regions. Here, we describe the state of the science regarding mechanisms and factors that influence aquatic C and hydrologic responses to permafrost thaw. Through synthesis of recent topical field and modeling studies and evaluation of influential landscape characteristics, we present a framework for assessing vulnerabilities of northern permafrost landscapes to specific modes of thaw affecting local to regional hydrology and aquatic C biogeochemistry and transport. Lastly, we discuss scaling challenges relevant to model prediction of these impacts in heterogeneous permafrost landscapes.

Arctic↗
USGS1980

Land use and land cover, 1972-77, Culpeper Basin, Virginia-Maryland

Land use refers to man's activities that relate directly to the land. Lover cover describes the land surface- vegetation, water, naturally- occurring soil and rock, and artificial constructions. In showing land use and land cover in the Culpeper Basin, this map features a consistent level of detail and standardization of categories. The use of the 1:125,000 compilation scale is appropriate, because this type of data is used frequently for different purposes by people representing several disciplines- land use planners, land managers, resource managemnet planners, and others. For example, maps and data similar to this publication have been used for river basin planning, for analysis of land use and land cover changes relative to recreation, for river quality assessment, for preparation of environmental impact statements, and for studies on urbanization. These efforts have been made at the multicounty regional, State, and Federal levels.

Maryland↗
USGS2006

The occurrence of volatile organic compounds in aquifers of the United States

The U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program recently completed a national assessment of volatile organic compounds (VOCs) in ground water (Zogorski and others, 2006). As part of this assessment, samples of ambient ground water collected from 3,498 wells during 1985-2002 were selected for characterizing the occurrence of 55 VOCs in 98 aquifer studies. The 55 VOCs were assigned to the following groups on the basis of their primary usage (or origin): (1) fumigants, (2) gasoline hydrocarbons, (3) gasoline oxygenates, (4) organic synthesis compounds, (5) refrigerants, (6) solvents, and (7) trihalo-methanes (chlorination by-products). The samples were collected throughout the conterminous United States as well as Alaska and Hawaii. The sampled wells had a variety of uses including domestic supply (61 percent), public supply (15 percent), monitoring (10 percent), other (13 percent), and unknown (1 percent). NAWQA aquifer studies are large-scale resource assessments of ground water that provide a general characterization of water-quality conditions in locally and regionally important aquifers or portions thereof. In general, the aquifers (or portions thereof) selected for study were some of the most intensively used aquifers for drinking water in greaterHawaiiOahuAlaskathe Nation. The 98 aquifer studies collectively provide an important national perspective on the current (1985-2002) extent of VOC contamination and regional patterns of VOC occurrence in ground water. More information about this national assessment of VOCs is available at a supporting Web site (http://water.usgs.gov/nawqa/vocs/national_assessment).

Scientific Investigations Map↗
USGS2009

Geophysical data from offshore of the Chandeleur Islands, eastern Mississippi Delta

This report contains the geophysical and geospatial data that were collected during two cruises on the R/V Acadiana along the eastern, offshore side of the Chandeleur Islands in 2006 and 2007. Data were acquired with the following equipment: a Systems Engineering and Assessment, Ltd., SwathPlus interferometric sonar; a Klein 3000 dual-frequency sidescan sonar; and an EdgeTech 512i chirp sub-bottom profiling system. The long-term goal of this mapping effort is to produce high-quality, high-resolution geologic maps and geophysical interpretations that can be utilized to investigate the impact of Hurricane Katrina, identify sand resources within the region, and make predictions regarding the future evolution of this coastal system.

Louisiana↗
USGS2014

Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

Fossil fuels from the Appalachian basin region have been major contributors to the Nation’s energy supplies over much of the last three centuries. Appalachian coal and petroleum resources are still available in sufficient quantities to contribute significantly to fulfilling the Nation’s energy needs. Although both conventional oil and gas continue to be produced in the Appalachian basin, most new wells in the region are drilled in shale reservoirs to produce natural gas. U.S. Geological Survey (USGS) Professional Paper 1708 is a modern, indepth collection of reports, cross sections, and maps that describe the geology of the Appalachian basin and its fossil fuel resources. This publication supplements and updates older USGS regional studies of Appalachian basin coal and petroleum resources. Some chapters are new, and several have been published in outside journals or as other USGS publications. Although this volume is not a comprehensive regional treatment of all notable geologic and fossil fuel localities in the Appalachian basin, the selected study areas and topics presented in the chapters pertain to large segments of the basin and a wide range of stratigraphic intervals. This volume discusses the locations of coal and petroleum accumulations, the stratigraphic and structural framework, and the geochemical characteristics of the coal beds and petroleum in the basin, as well as the results of recent USGS assessments of coal, oil, and gas resources in the basin. Many of the maps and accompanying data supporting the reports in this volume are available from chapter I.1 as downloadable geographic information system (GIS) data files about the characteristics of selected coal beds and oil and gas fields, locations of oil and gas wells, coal production, coal chemistry, total petroleum system (TPS) boundaries, and bedrock geology. Log ASCII Standard (LAS) files for geophysical (gamma ray) wireline well logs are included in other chapters. Professional Paper 1708 is intended primarily for geoscientists in academia, industry, and government who are interested in Appalachian basin geology and its coal and petroleum resources. Other users, however, may find the topics, papers, and digital images valuable for land-use and policy planning. Among the anticipated benefits of the report are improvements in (1) resource assessment estimates and methodology, (2) exploration strategies, (3) basin models, and (4) energy use policies.

Appalachian basin↗
USGS2013

Missing great earthquakes

The occurrence of three earthquakes with moment magnitude (Mw) greater than 8.8 and six earthquakes larger than Mw 8.5, since 2004, has raised interest in the long-term global rate of great earthquakes. Past studies have focused on the analysis of earthquakes since 1900, which roughly marks the start of the instrumental era in seismology. Before this time, the catalog is less complete and magnitude estimates are more uncertain. Yet substantial information is available for earthquakes before 1900, and the catalog of historical events is being used increasingly to improve hazard assessment. Here I consider the catalog of historical earthquakes and show that approximately half of all Mw ≥ 8.5 earthquakes are likely missing or underestimated in the 19th century. I further present a reconsideration of the felt effects of the 8 February 1843, Lesser Antilles earthquake, including a first thorough assessment of felt reports from the United States, and show it is an example of a known historical earthquake that was significantly larger than initially estimated. The results suggest that incorporation of best available catalogs of historical earthquakes will likely lead to a significant underestimation of seismic hazard and/or the maximum possible magnitude in many regions, including parts of the Caribbean.

Journal of Geophysical Research B: Solid Earth↗
USGS2024

Mercury concentrations in Seaside Sparrows and Marsh Rice Rats differ across the Mississippi River Estuary

Mercury (Hg) concentrations and their associated toxicological effects in terrestrial ecosystems of the Gulf of Mexico are largely unknown. Compounding this uncertainty, a large input of organic matter from the 2010 Deepwater Horizon oil spill may have altered Hg cycling and bioaccumulation dynamics. To test this idea, we quantified blood concentrations of total mercury (THg) in Seaside Sparrows ( Ammospiza maritima ) and Marsh Rice Rats ( Oryzomys palustris ) in marshes west and east of the Mississippi River in 2015 and 2016. We also tested for a difference in THg concentrations between oiled and non-oiled sites. To address the potential confounding effect of diet variation on Hg transfer, we used stable nitrogen (δ 15 N) and carbon (δ 13 C) isotope values as proxies of trophic position and the source of primary production, respectively. Our results revealed that five to six years after the spill, THg concentrations were not higher in sites oiled by the spill compared to non-oiled sites. In both species, THg was higher at sites east of the Mississippi River compared to control and oiled sites, located west. In Seaside Sparrows but not in Marsh Rice Rats, THg increased with δ 15 N values, suggesting Hg trophic biomagnification. Overall, even in sites with the most elevated THg, concentrations were generally low. In Seaside Sparrows, THg concentrations were also lower than previously reported in this and other closely related passerines, with only 7% of tested birds exceeding the lowest observed effect concentration associated with toxic effects across bird species (0.2 µg/g ww ) . The factors associated with geographic heterogeneity in Hg exposure remain uncertain. Clarification could inform risk assessment and future restoration and management actions in a region facing vast anthropogenic changes.

Ecotoxicology↗
USGS2009

Natural offshore oil seepage and related tarball accumulation on the California coastline — Santa Barbara Channel and the southern Santa Maria Basin; source identification and inventory

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three “tribes” of 13 C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (Tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (Tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception, where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. It is very desirable to be able to clearly distinguish the naturally occurring seep oils from the anthropogenically derived platform oils. Within the “training set” of oils and tars (388 samples), the biomarker parameters are sometimes sufficient to allow unique discrimination of individual platform oils. More often however, platform samples and seep samples with sources geographically close to each other are too similar to each other, with respect to the biomarker parameters, to definitively differentiate them on that basis alone. In some cases other parameters can be helpful. These other parameters are related to the degree of biogeochemical degradation or weathering that the oils or tars have experienced. These components include the typical oil distribution of n-alkane hydrocarbons and isoprenoids pristane and phytane. All of the platform oils in our sample set contain these components. On the other hand, the seep oils or tars have been exposed to significant biodegradation while in the near subsurface. The majority, but not all of seep oils or tars have been biodegraded up to or beyond the loss of n-alkanes and isoprenoids. Seep oils found in the vicinity of Coal Oil Point or Arroyo Burro are apparently the least weathered and are particularly likely to retain significant n-alkanes and isoprenoids. Therefore the combination of chemometric fingerprinting and the presence or absence of n-alkanes and isoprenoids help to differentiate anthropogenic production oils versus natural seeps oils and tars. The differentiation is not always definitive because of the close chemical similarity of some samples and the variability in the biodegradation progression. This is the case near Coal Oil Point, and near Platform A (Dos Cuadros Field) where seep oils and Platform Holly and Platform A oils are genetically very similar and cannot be definitively distinguished after a period of a few days of weathering. In contrast, oils from the Point Conception platforms can be distinguished on the basis of chemometric fingerprinting alone. In the middle of this spectrum are oils from Platforms Harmony, Heritage, and Hondo, where it is expected that oil weathering would take on the order of two weeks to a month to produce tarballs similar to those seen near Point Conception. In this case there is a much greater degree of weathering needed to proceed from produced oil to the biodegraded tar characteristic of tarball stranded on the beach. Tar deposition on beaches was monitored as part of cooperative with the County of Santa Barbara Energy Division and the U.S. Geological Survey during 2001-2003. We found tar deposition varies on a seasonal basis. In general, tarballs accumulate at a faster rate or remain longer on all beaches during the summer and fall months. The reasons for this are unclear based on our limited observations, however we speculate that factors such as prevailing winds and currents combined with more quiescent wave conditions favors the accumulation and preservation of tarballs on the beach during the summer and fall months. In contrast, winter storms, with much greater wave action remove beach sand and other materials, and stormy seas tend to break up oil that might weather into tarballs. Natural seepage is affected by the spring/neap tidal cycle; however, the link to tar deposition is unclear. Longer periods of monitoring are needed to address the variability in the data and provide a more robust statistical analysis.

California↗
USGS2025

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—Comparison of four (2018, 2020, 2021, 2022) spring high-resolution mapping surveys

Executive Summary This report summarizes results from boat-based, high-resolution water-quality mapping surveys completed before, during, and after upgrades to the EchoWater Resource Recovery Facility (EchoWater Facility), the regional wastewater facility for the City of Sacramento and surrounding areas, near Elk Grove, California. Surveys were completed in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) in spring (May or June) 2018, 2020, 2021, and 2022. In each survey, a suite of in situ sensors were used to continuously (one measurement per second) measure water-quality conditions, nutrients, phytoplankton abundance, and species composition. In addition to in situ data collection, discrete water samples were collected about every 2 miles while underway for determination of phosphate, ammonium, and nitrate concentration. The boat stopped at about 30 locations to collect discrete samples for a suite of additional analytes, including phytoplankton enumeration. The four surveys represent snapshots in time across different phases of the EchoWater Facility Biological Nutrient Reduction (BNR) upgrade. The May 2018 survey represents conditions before the upgrade. The second survey (June 2020) represents conditions after implementation of the Nitrifying Sidestream Treatment. The third survey (May 2021) was completed immediately after the completion of the BNR upgrade and represents a transitional period, and the final survey (May 2022) represents post-upgrade conditions. Relevant hydrologic and climatic context such as water-year type, X 2 position (the distance from the Golden Gate Bridge to the point upstream where bottom salinity is 2 parts per thousand; Jassby and others, 1995), water export to import ratio, and management actions like the Delta Cross Channel gate operations are presented for each survey so they may be considered in comparisons among surveys. Differences in water-quality parameters, like turbidity, temperature, salinity, pH, and dissolved oxygen (DO) improve understanding of nutrient cycling and phytoplankton dynamics. Because the Delta is a complex system, we divided the study area into hydrologic zones to better examine general trends and obtain a broadscale view of differences among the 4 study years. Results are presented for each survey and parameter using box plots to compare the different hydrologic zones. We also present each parameter using contour maps by survey to display gradients across the system. The most evident change to water quality in the Delta across surveys is related to the EchoWater Facility BNR upgrade, which included nitrification and denitrification processes. Through this upgrade, effluent ammonium (NH 4 + ) concentrations were reduced by more than 95 percent (from about 2,000 micromolars [μM] to below the reporting limit of 35 μM), and nitrate (NO 3 − ) concentrations increased from near zero to about 500 μM; therefore, the concentration of dissolved inorganic nitrogen (DIN; the sum of NH 4 + and NO 3 − ) in the effluent was reduced by about 75 percent between May 2018 and May 2022. The BNR upgrade resulted in a reduction in NH 4 + concentrations in aquatic habitats immediately below the facility, designated as the “north Delta tidal transition zone” (Bergamaschi and others, 2024), from about 30 μM pre-upgrade to near zero during the 2022 spring survey, whereas effluent NO 3 − increased from median concentrations of about 7 μM to about 15 μM. Because of the reduced effluent nitrogen loads and variability in Sacramento River nitrogen loads from upstream sources, DIN concentrations in the north Delta tidal transition zone decreased from a median of 53.3 μM in 2018 to 35.3 μM in 2020, 20.7 μM in 2021, and 11.3 μM in 2022 during the spring surveys. The changes in DIN concentration and form observed in the north Delta tidal transition zone after the EchoWater Facility upgrade extended downstream but were rapidly altered by hydrologic mixing, biogeochemical processes, and other nutrient source inputs. Most of the Delta indicated near-zero concentrations of NH 4 + 1 year after the completion of the EchoWater Facility upgrades represented by the 2022 survey. Exceptions to this finding were observed in the San Joaquin River near Stockton and in Suisun Bay, indicating there are NH 4 + inputs to these locations from other sources (for example, Stockton Regional Wastewater Control Facility and Central Contra Costs Sanitary District wastewater treatment plants or agricultural and urban runoff). Although there was an increase in NO 3 − concentrations in the north Delta tidal transition zone after the upgrade, increases in NO 3 − in other zones were not apparent, presumably because nitrification of effluent derived ammonium was no longer a source of NO 3 − . Concentrations of DIN in many Delta zones were lower in 2022 compared to 2018 and 2020, with concentrations near or below what is considered potentially nitrogen limiting conditions for phytoplankton growth in the North Delta tidal transition zone and the Cache Slough complex channel system. Unrelated to the EchoWater Facility upgrade, NO 3 − and therefore DIN concentrations increased in the San Joaquin River near Stockton and in adjacent water bodies by survey date (likely associated with increasing drought conditions). The Mokelumne River had low DIN concentrations, except in 2018 when the Delta Cross Channel was open, which allowed nutrient-rich Sacramento River water to flow into this section of the river. Data from these surveys also support the hypothesis that nutrient drawdown during phytoplankton blooms may create localized nitrogen limiting conditions. The BNR upgrade resulted in lower effluent phosphate (PO 4 3− ) concentrations, which lowered PO 4 3− concentrations in some zones of the Delta during the four spring surveys; however, PO 4 3− concentrations throughout the Delta remained above 0.3 μM, indicating that primary productivity was not limited by phosphorous availability. DIN and PO 4 3− decreased after the upgrade in many areas of the Delta, and the DIN to dissolved inorganic phosphorus (DIN:DIP) ratio remained similar to pre-upgrade conditions and was often below the Redfield Ratio of 16, indicating nitrogen is more likely to limit phytoplankton growth than phosphorous. Inputs of dissolved organic carbon (DOC) from the EchoWater Facility are a minor source of this constituent to the Delta, so the upgrade had little to no effect on DOC concentrations across the Delta. Because phytoplankton abundance and species composition in the Delta are shaped by multiple factors other than nutrients (for example, light availability, temperature, salinity, and predation), it is important to consider these factors (as well as long-term monitoring) in addition to the EchoWater Facility upgrade. Although phytoplankton populations were low across much of the Delta during the spring surveys, several localized phytoplankton blooms (defined here as greater than 15 micrograms per liter [μg/L] of chlorophyll) provide insight into conditions that may favor the growth of beneficial and harmful species.

Callifornia↗
USGS2017

Reassessing rainfall in the Luquillo Mountains, Puerto Rico: Local and global ecohydrological implications

Mountains receive a greater proportion of precipitation than other environments, and thus make a disproportionate contribution to the world’s water supply. The Luquillo Mountains receive the highest rainfall on the island of Puerto Rico and serve as a critical source of water to surrounding communities. The area’s role as a long-term research site has generated numerous hydrological, ecological, and geological investigations that have been included in regional and global overviews that compare tropical forests to other ecosystems. Most of the forest- and watershed-wide estimates of precipitation (and evapotranspiration, as inferred by a water balance) have assumed that precipitation increases consistently with elevation. However, in this new analysis of all known current and historical rain gages in the region, we find that similar to other mountainous islands in the trade wind latitudes, leeward (western) watersheds in the Luquillo Mountains receive lower mean annual precipitation than windward (eastern) watersheds. Previous studies in the Luquillo Mountains have therefore overestimated precipitation in leeward watersheds by up to 40%. The Icacos watershed, however, despite being located at elevations 200–400 m below the tallest peaks and to the lee of the first major orographic barrier, receives some of the highest precipitation. Such lee-side enhancement has been observed in other island mountains of similar height and width, and may be caused by several mechanisms. Thus, the long-reported discrepancy of unrealistically low rates of evapotranspiration in the Icacos watershed is likely caused by previous underestimation of precipitation, perhaps by as much as 20%. Rainfall/runoff ratios in several previous studies suggested either runoff excess or runoff deficiency in Luquillo watersheds, but this analysis suggests that in fact they are similar to other tropical watersheds. Because the Luquillo Mountains often serve as a wet tropical archetype in global assessments of basic ecohydrological processes, these revised estimates are relevant to regional and global assessments of runoff efficiency, hydrologic effects of reforestation, geomorphic processes, and climate change.

Luquillo Mountains↗
USGS2020

Hydrologic modeling for flow-ecology science in the Southeastern United States and Puerto Rico

An understanding of the applicability and utility of hydrologic models is critical to support the effective management of water resources throughout the Southeastern United States (SEUS) and Puerto Rico (PR). Hydrologic models have the capacity to provide an estimate of the quantity of available water at ungauged locations (i.e., areas of the country where a U.S. Geological Survey [USGS] continuous record gauge is not installed) and provide the baseline flow information necessary to develop the linkages between water availability and characteristics of streamflow that support ecological communities (i.e., support the development of flow-ecology response models). This report inventories and then directly examines and compares a subset of hydrologic models used to estimate streamflow at a number of gauged basins across the SEUS and PR. This effort was designed to evaluate, quantify, and compare the magnitude of error and to investigate the potential causes of error associated with predicted streamflows from seven hydrologic models of varying complexity and calibration strategy. This was accomplished by computing and then comparing classical hydrologic model fit statistics (e.g., mean bias, coefficient of determination [R2], root mean squared error [RMSE], Nash-Sutcliffe Efficiency [NSE]) and understanding the bias in the prediction in these and a subset of ecologically relevant flow metrics (ERFMs). Additionally, streamflow predictions from a larger regional-scale hydrologic model were compared to those of several fine-scale hydrologic models under a range of hypothetical climate change scenarios to determine the range of predicted streamflow responses to fixed climate perturbations. A pilot study was conducted using predicted streamflow and boosted regression trees to develop a set of predictive flow-ecology response models to assess the potential change in fish species richness in the North Carolina Piedmont under several scenarios of water availability change. This report is intended to provide a general assessment of all the tools and techniques available to support hydrologic modeling for flow-ecology science in the SEUS and PR. It is our hope that the approach used herein to understand differences in streamflow predictions among a subset of hydrologic models that have been applied in the SEUS for developing flow-ecology response models will provide water resource managers and stakeholders with an informed pathway for developing the capacity to link streamflow and ecological response and an understanding of some of the limitations associated with these type of modeling efforts.

Alabama, Florida, Georgia, Mississippi, North Caro↗
USGS2020

Water priorities for the Nation—U.S. Geological Survey Integrated Water Availability Assessments

The United States faces growing challenges to its water supply, infrastructure, and aquatic ecosystems because of population growth, climate change, floods and droughts, and aging water delivery systems. To help address these challenges, the U.S. Geological Survey (USGS) Water Resources Mission Area has established new strategic priorities that capitalize on the operational and scientific strengths of the USGS to address these complex societal issues. The USGS Integrated Water Availability Assessment Program within the Water Resources Mission Area will provide nationally consistent assessments of water available for human and ecological needs and identify factors that limit water availability. Integrated Water Availability Assessments will assess current conditions, long-term trends, factors responsible for current conditions and observed trends, and provide forecasts of future changes at national and regional scales.

Conterminous United States↗