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Geochemical processes controlling uranium mobility in mine drainages

Comprehensive models of ore genesis incorporate metal sources, transport and concentration mechanisms, and preservation mechanisms. Analogous concepts apply to the problem of metal migration from mines, mine wastes, and mine tailings, including: the concentrations, mineralogical occurrence, and availability of metals in mineral deposits, host rocks, mine wastes, and tailings (the source); the mechanisms for metal mobilization and transport during weathering; the mechanisms for metal fixation and the permanence of the fixation. Similarly, undisturbed mineral deposits or alteration zones that are exposed at the Earth's surface may be natural sources from which metals can be solubilized during weathering. Uranium (U), a naturally-occurring radioactive element, may be present in mineral deposits in sufficient concentrations that in itself constitutes ore. It may also be present in ores of other metals at concentrations that exceed average crustal abundances. Any uranium that is not completely removed from these ores in the mining and milling process may be available for mobilization into ground or surface waters via the weathering and oxidation of solid tailings or mine waste piles. This chapter discusses the relative importance of various geochemical processes that control uranium mobility via weathering in both mined and unmined mineralized environments. The data presented in this paper focus on mined areas because the great extent of historic mining in the field areas examined for this study preclude extensive consideration of undisturbed areas.

Book chapter

Getting ocean acidification on decision makers' to-do lists: dissecting the process through case studies

Much of the detailed, incremental knowledge being generated by current scientific research on ocean acidification (OA) does not directly address the needs of decision makers, who are asking broad questions such as: Where will OA harm marine resources next? When will this happen? Who will be affected? And how much will it cost? In this review, we use a series of mainly US-based case studies to explore the needs of local to international-scale groups that are making decisions to address OA concerns. Decisions concerning OA have been made most naturally and easily when information needs were clearly defined and closely aligned with science outputs and initiatives. For decisions requiring more complex information, the process slows dramatically. Decision making about OA is greatly aided (1) when a mixture of specialists participates, including scientists, resource users and managers, and policy and law makers; (2) when goals can be clearly agreed upon at the beginning of the process; (3) when mixed groups of specialists plan and create translational documents explaining the likely outcomes of policy decisions on ecosystems and natural resources; (4) when regional work on OA fits into an existing set of priorities concerning climate or water quality; and (5) when decision making can be reviewed and enhanced.

Oceanography

Evaluation of marsh development processes at Fire Island National Seashore: Recent and historic perspectives

Purpose and significance of the study: Salt marshes are dynamic environments, increasing in vertical elevation and migrating, often landward, as sea level rises. With sea level rise greater than marsh elevation increase, marshes can be submerged, marsh soils become waterlogged, and plant growth becomes stressed, often resulting in conversion of vegetation-dominated marsh to mudflat or open water habitat. Given that the rate of sea level rise is expected to accelerate over the next century and that some marshes in the northeast are becoming submerged (e.g., Jamaica Bay, NY), it is important to understand the processes that control marsh development. More specifically, the objectives of this project were to quantify vertical marsh elevation change in relation to recent rates of sea-level rise and to investigate factors or processes that are most influential in controlling the development and maintenance of Fire Island salt marshes.

Report

Storms as agents of wetland elevation change: their impact on surface and subsurface sediment processes

Direct measures of the impact of major storms on wetland sediment elevation are rare. Recently developed techniques have enabled simultaneous, quantitative observations of surface and subsurface processes affecting sediment elevation. An analysis of ten wetland sites revealed the following patterns of sediment elevation change after storm passage: (1) elevation change equivalent to sediment accretion or erosion, (2) elevation loss in spite of sediment deposition, or in excess of erosion, and (3) elevation gain greater than the amount of sediment accretion. These observations suggest that storms influence sediment elevation not only by sediment deposition and erosion but also through subsurface processes of sediment compaction, root growth and decomposition, and water flux. Wetlands receiving a substantial deposit of sediment did not always realize an equivalent elevation gain. Some realized a net loss in elevation as a result of sediment compaction apparently caused by the weight of the sediment deposit or the tidal surge waters, or both. Sediment elevation collapsed in two mangrove forests with highly organic substrate when the storm killed the forest. In two marshes, elevation gain exceeded deposition apparently through increased sediment water storage or plant root growth via nutrient enrichment from storm sediment deposits. The elevation responses were either temporary or permanent on an ecological time scale (> 8 years). In one organic marsh substrate, compaction was followed by expansion, only to be compacted again by another storm. Thus the elevation response of coastal wetlands to major storms varied depending on local substrate conditions and degree of storm impact.

Book chapter

Connecting pattern and process in greater sage-grouse populations and sagebrush landscapes

Abstract. Spatial patterns influence the processes that maintain Greater Sage-Grouse (Centrocercus urophasianus) populations and sagebrush (Artemisia spp.) landscapes on which they depend. We used connectivity analyses to: (1) delineate the dominant pattern of sagebrush landscapes; (2) identify regions of the current range-wide distribution of Greater Sage-Grouse important for conservation; (3) estimate distance thresholds that potentially isolate populations; and (4) understand how landscape pattern, environmental disturbance, or location within the spatial network influenced lek persistence during a population decline. Long-term viability of sagebrush, assessed from its dominance in relatively unfragmented landscapes, likely is greatest in south-central Oregon and northwest Nevada; the Owyhee region of southeast Oregon, southwest Idaho, and northern Nevada; southwest Wyoming; and south-central Wyoming. The most important leks (breeding locations) for maintaining connectivity, characterized by higher counts of sage-grouse and connections with other leks, were within the core regions of the sage-grouse range. Sage-grouse populations presently have the highest levels of connectivity in the Wyoming Basin and lowest in the Columbia Basin Sage-Grouse management zones (SMZs). Leks separated by distances 13-18 km could be isolated due to decreased probability of dispersals from neighboring leks. The range-wide distribution of sage-grouse was clustered into 209 separate components (units in which leks were interconnected within but not among) when dispersal was limited to distances 18 km. The most important components for maintaining connectivity were distributed across the central and eastern regions of the range-wide distribution. Connectivity among sage-grouse populations was lost during population declines from 1965-1979 to 1998-2007, most dramatically in the Columbia Basin SMZ. Leks that persisted during this period were larger in size, were more highly connected, and had lower levels of broad-scale fire and human disturbance. Protecting core regions and maintaining connectivity with more isolated sage-grouse populations may help reverse or stabilize the processes of range contraction and isolation that have resulted in long-term population declines.

Book chapter

Processing techniques for digital sonar images from GLORIA.

Image processing techniques have been developed to handle data from one of the newest members of the remote sensing family of digital imaging systems. This paper discusses software to process data collected by the GLORIA (Geological Long Range Inclined Asdic) sonar imaging system, designed and built by the Institute of Oceanographic Sciences (IOS) in England, to correct for both geometric and radiometric distortions that exist in the original 'raw' data. Preprocessing algorithms that are GLORIA-specific include corrections for slant-range geometry, water column offset, aspect ratio distortion, changes in the ship's velocity, speckle noise, and shading problems caused by the power drop-off which occurs as a function of range.-from Author

Photogrammetric Engineering and Remote Sensing

USE OF SPACE TECHNOLOGY IN FEDERALLY FUNDED LAND PROCESSES RESEARCH IN THE UNITED STATES.

A review of the use of space technology in federally funded earth science research in the US was carried out in 1985 by the President's Office of Science and Technology Policy. Five departments and three independent agencies, representing the primary earth science research agencies in the Federal government, participated in the review. The review by the subcommittee indicated that, while there is considerable overlap in the legislated missions of the earth science agencies, most of the space-related land processes research is complementary. Summaries are provided of the current and projected uses of space technology in land processes activities within the eight Federal organizations.

Conference Paper

Hydraulics and sediment transport processes in a pool-riffle rocky mountain stream

Sediment transport processes related to varying channel-bed morphology were investigated from April to November, 1993 along a 1 km pool-riffle and step-pool reach of North Saint Vrain Creek, a small mountain stream in the Northern Colorado Rocky Mountains. Three hundred sixteen 16-256 mm tracer particles placed in two separate pool-riffle-pool sequences, forty-three direct bedload measurements at three separate cross-sections in discharges ranging between 0.27-8.8 m3/s, and indirect velocity measurements at thirteen cross-sections in 23 discharges ranging between 0.23-9.2 m3/s are used to assess sediment sorting patterns and sediment transport capacity variations. An investigation of secondary flow features and wave patterns provides preliminary evidence of turbulent controls on sediment entrainment and transport, and was used to develop a conceptual model of bedload transport and channel-bed maintenance on North Saint Vrain Creek. Recirculating eddy systems provide a means to constrict flow in pools, leading to modeled velocity-reversals at high flows. Tracer particle depositional evidence also indicates higher sediment transport capacities in pools versus riffles at high flow. Modeled hydraulic conditions and depositional evidence of tracers indicates that high-flow recirculating-eddy-influenced velocity-reversals and associated turbulence may provide the primary pool maintenance processes in this channel.

Conference Paper

Rates and processes of bluff recession along the Lake Michigan shoreline in Illinois

Examined bluffs along 30 km of the Lake Michigan shoreline from Wilmette to Waukegan, Illinois, to measure amounts and variation in retreat rates and to determine what factors control rates and processes of retreat. The predominant bluff-retreat process is shallow- to intermediate-depth translational landsliding triggered by heavy rainfall and wave erosion at the base of the bluff; rotational slumping and shallow creep and earth flow also are common. Using historical maps and airphotos, we measured amounts of bluff-top retreat at 300 locations. For two time periods, 1872-1937 and 1937-1987, rates of retreat vary from 10 to 75 cm/yr between discrete segments of bluffs (defined by lithology) and between time periods for a given bluff segment. The average retreat rates for the entire area, however, do not vary significantly between the two time periods and are approximately 20-25 cm/yr. Longterm average and short-term extreme lake levels and precipitation also do not vary significantly between the two periods, and thus local temporal variations in retreat rate cannot be attributed to these factors. Shore protection built to date may have altered the spatial distribution of retreat rates in the area but has had little overall effect on the average regional retreat rates. -from Authors

Journal of Great Lakes Research

Strong-motion data processing

Processing of strong-motion earthquake accelerograms is now carried out routinely on a world-wide basis. Two international workshops have given participants the opportunity to assess their capabilities. Data from the larger instrumentation networks are disseminated widely. The US Geological Survey's strong-motion network consists largely of film recorders, due to their long reliable life and the relatively slow addition of digital recorders. The USGS processing of film records contains steps which have become necessary in dealing with the triggered nature of these records.

Conference Paper

Deep Europe today: Geophysical synthesis of the upper mantle structure and lithospheric processes over 3.5 Ga

We present a summary of geophysical models of the subcrustal lithosphere of Europe. This includes the results from seismic (reflection and refraction profiles, P- and S-wave tomography, mantle anisotropy), gravity, thermal, electromagnetic, elastic and petrological studies of the lithospheric mantle. We discuss major tectonic processes as reflected in the lithospheric structure of Europe, from Precambrian terrane accretion and subduction to Phanerozoic rifting, volcanism, subduction and continent-continent collision. The differences in the lithospheric structure of Precambrian and Phanerozoic Europe, as illustrated by a comparative analysis of different geophysical data, are shown to have both a compositional and a thermal origin. We propose an integrated model of physical properties of the European subcrustal lithosphere, with emphasis on the depth intervals around 150 and 250 km. At these depths, seismic velocity models, constrained by body-and surface-wave continent-scale tomography, are compared with mantle temperatures and mantle gravity anomalies. This comparison provides a framework for discussion of the physical or chemical origin of the major lithospheric anomalies and their relation to large-scale tectonic processes, which have formed the present lithosphere of Europe. ?? The Geological Society of London 2006.

Geological Society Memoir

Ground control requirements for precision processing of ERTS images

With the successful flight of the ERTS-1 satellite, orbital height images are available for precision processing into products such as 1:1,000,000-scale photomaps and enlargements up to 1:250,000 scale. In order to maintain positional error below 100 meters, control points for the precision processing must be carefully selected, clearly definitive on photos in both X and Y. Coordinates of selected control points measured on existing ½ and 15-minute standard maps provide sufficient accuracy for any space imaging system thus far defined. This procedure references the points to accepted horizontal and vertical datums. Maps as small as 1:250,000 scale can be used as source material for coordinates, but to maintain the desired accuracy, maps of 1:100,000 and larger scale should be used when available.

Book

An elevational gradient in snowpack chemical loading at Glacier National Park, Montana: implications for ecosystem processes

The accumulation and melting of mountain snowpacks are major drivers of ecosystem processes in the Rocky Mountains. These include the influence of snow water equivalent (SWE) timing and amount of release on soil moisture for annual tree growth, and alpine stream discharge and temperature that control aquatic biota life histories. Snowfall also brings with it atmospheric deposition. Snowpacks will hold as much as 8 months of atmospheric deposition for release into mountain ecosystems during the spring melt. These pulses of chemicals influence soil microbiota and biogeochemical processes affecting mountain vegetation growth. Increased atmospheric nitrogen inputs recently have been documented in remote parts of Colorado's mountain systems but no baseline data exist for the Northern Rockies. We examined patterns of SWE and snow chemistry in an elevational gradient stretching from west to east over the continental divide in Glacier National Park in March 1999 and 2000. Sites ranged from 1080m to 2192m at Swiftcurrent Pass. At each site, two vertically-integrated columns of snow were sampled from snowpits up to 600cm deep and analyzed for major cations and anions. Minor differences in snow chemistry, on a volumetric basis, existed over the elvational gradient. Snowpack chemical loading estimates were calculated for NH 4 , SO 4 and NO 3 and closely followed elevational increases in SWE. NO 3 (in microequivalents/square meter) ranged from 1,000 ueq/m 2 at low elevation sites to 8,000+ ueq/m 2 for high elevation sites. Western slopes received greater amounts of SWE and chemical loads for all tested compounds.

Montana

Processing techniques for global land 1-km AVHRR data

The U.S. Geological Survey's (USGS) Earth Resources Observation Systems (EROS) Data Center (EDC) in cooperation with several international science organizations has developed techniques for processing daily Advanced Very High Resolution Radiometer (AVHRR) 1-km data of the entire global land surface. These techniques include orbital stitching, geometric rectification, radiometric calibration, and atmospheric correction. An orbital stitching algorithm was developed to combine consecutive observations acquired along an orbit by ground receiving stations into contiguous half-orbital segments. The geometric rectification process uses an AVHRR satellite model that contains modules for forward mapping, forward terrain correction, and inverse mapping with terrain correction. The correction is accomplished by using the hydrologic features coastlines and lakes from the Digital Chart of the World. These features are rasterized into the satellite projection and are matched to the AVHRR imagery using binary edge correlation techniques. The resulting coefficients are related to six attitude correction parameters: roll, roll rate, pitch, pitch rate, yaw, and altitude. The image can then be precision corrected to a variety of map projections and user-selected image frames. Because the AVHRR lacks onboard calibration for the optical wavelengths, a series of time-variant calibration coefficients derived from vicarious calibration methods and are used to model the degradation profile of the instruments. Reducing atmospheric effects on AVHRR data is important. A method has been develop that will remove the effects of molecular scattering and absorption from clear sky observations, using climatological measurements of ozone. Other methods to remove the effects of water vapor and aerosols are being investigated.

Pecora 12 Symposium

Use of machine-processable field notes in a wilderness mapping project (Granite Fiords area), southeastern Alaska

For reconnaissance geologic mapping and mineral resource evaluation of the Granite Fiords wilderness study area, we developed and used a system of machine-processable field notes. Preprinted field forms standardize notes and serve as checklists that insure collection of all available data. The use of this system cut in half the time required to record data at an outcrop. The system consists of three related but different types of preprinted field sheets, a key to abbreviations and codes, and a set of written instructions. The field sheets include a station sheet for basic outcrop data, a specimen sheet for rock samples, and a geochemical sheet for materials to be chemically analyzed. Data on the field sheets are keypunched on standard IBM cards, then arranged in subfiles and retrieved by using a card sorter. Our system is designed specifically for a region of granitic and metamorphic rocks but is easily modified for use in different geologic terranes. We offer four guidelines for developing a system of machine-processable field notes: (1) Time and money spent to develop the system must be worth its anticipated benefits. (2) The system should be as flexible as possible. (3) It is necessary to tailor the system to a particular geologic terrane or project objective. (4) The system should be as simple and self-explanatory as possible.

Alaska

Microbial and biogeochernical processes Soda Lake, Nevada

Meromictic, alkaline lakes represent modern-day analogues of lacustrine source rock depositional environments. In order to further our understanding of how these lakes function in terms of limnological and biogeochemical processes, we have conducted an interdisciplinary study of Big Soda Lake. Annual mixolimnion productivity (ca. 500 g m -2 ) is dominated by a winter diatom bloom (60% of annual) caused by upward transport of ammonia to the epilimnion. The remainder of productivity is attributable to chemoautotrophs (30%) and photosynthetic bacteria (10%) present at the oxic -anoxic interface from May to November. Studies of bacterial heterotrophy and particulate fluxes in the water column indicate that about 90% of annual productivity is remineralized in the mixolimnion, primarily by fermentative bacteria. However, high rates of sulphate reduction (9-29 mmol m -2 yr -1 ) occur in the monimolimnion waters, which could remineralize most (if not all) of the primary productivity. This discrepancy has not as yet been fully explained. Low rates of methanogenesis also occur in the monimolimnion waters and sediments. Most of the methane is consumed by anaerobic methane oxidation occurring in the monimolimnion water column. Other bacterial processes occurring in the lake are also discussed. Preliminary studies have been made on the organic geochemistry of the monimolimnion sediments. Carbon-14-dating indicates a lower depositional rate prior to meromixis and a downcore enrichment in 13 C of organic carbon and chlorophyll derivatives. Hydrous pyrolysis experiments indicate that the sediment organic matter is almost entirely derived from the water column with little or no contribution from terrestrial sources. The significance of the organics released by hydrous pyrolysis is discussed.

Book chapter

Processing protocol for soil samples potentially contaminated with Bacillus anthracis spores [HS7.52.02 - 514]

This protocol describes the processing steps for 45 g and 9 g soil samples potentially contaminated with Bacillus anthracis spores. The protocol is designed to separate and concentrate the spores from bulk soil down to a pellet that can be used for further analysis. Soil extraction solution and mechanical shaking are used to disrupt soil particle aggregates and to aid in the separation of spores from soil particles. Soil samples are washed twice with soil extraction solution to maximize recovery. Differential centrifugation is used to separate spores from the majority of the soil material. The 45 g protocol has been demonstrated by two laboratories using both loamy and sandy soil types. There were no significant differences overall between the two laboratories for either soil type, suggesting that the processing protocol would be robust enough to use at multiple laboratories while achieving comparable recoveries. The 45 g protocol has demonstrated a matrix limit of detection at 14 spores/gram of soil for loamy and sandy soils.

Report

Plot-scale sediment transport processes on a burned hillslope as a function of particle size

Soil moisture, rainfall, runoff, and sediment transport data were collected from four 1-m 2 hillslope plots after the 2000 Hi Meadow Fire in Colorado. Data were collected daily during three summers, two of which were affected by drought. Maximum 30-minute rainfall intensities, I 30 , were less than 20 mm h -1 and the average runoff volumes per plot were less than 4.7 L per storm. The data were separated into three sediment transport processes based on rainfall intensity and runoff magnitude: (1) dry ravel, (2) rainsplash, and (3) rainflow and then into eight different particle size classes ( D i ). For each class, dry ravel transport had a non-linear dependence on initial soil moisture, θ i , with a maximum at intermediate values of θ i (5-9 % cm 3 cm -3 ). Dry ravel transport rates were small for low θ i , which may be caused by a cementation process, and also small for high θ i , which may be caused by increased surface tension. Rainsplash transport was confined to the I 30 domain from 1-7 mm h -1 was proportional to D i ( I max 30 ) 0.63 . Rainflow transport ( I 30 > 7 mm h -1 ) in shallow flows ( h < 2 mm) was most likely dominated by particles rolling. It had a non-linear dependence on D i with maximum transport of sediment in the 2-4 mm size class. Transport also depended on stream power, but critical stream power was essentially zero, which may indicate that the rainsplash preceding runoff detached soil for transport by overland flow.

Conference Paper