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Water temperature, streamflow, and ground-water elevation in and adjacent to the Russian river between Hopland and Guerneville, California from 1998-2002

Temperature, water level elevation, stage height, and river discharge data for this report were collected in and adjacent to the Russian River from Hopland to Guerneville, CA over a four-year period from 1998 to 2002 to establish baselines for long-term water quality, water supply and habitat. Data files presented in this report were collected by the USGS and the Sonoma County Water Agency's Engineering Resource and Planning, and Natural Resource Divisions. Temperature data were collected in single-channel submersible microloggers or temperature data were collected simultaneously with water-elevation data in dual-channel down-hole data loggers. Stream stage and streamflow data were collected at USGS stream gaging stations located near Hopland, Healdsburg, and Guerneville over a 130 km reach of the Russian River. During the period of record stream flow ranged from 3 to 1458 m3/s. Stream temperature ranged from 8 to 29 oC while groundwater temperature ranged from 10 to 38 oC. Stream stage varied 5 m seasonly, while ground-water level varied 19 m over the same time scale.

California

Ground-water provinces of India

This paper gives a general resume of ground-water utilization and development and describes the occurrence of water in eight ground-water provinces of India. The paper is based in part on observations of the writer during 1951-55 and in part on earlier work of the Geological Survey of India. Ground water has been utilized extensively in India since before the beginning of the Christian era. Currently (1956) ground water is an important source of supply for domestic, stock, municipal, and industrial needs throughout the Republic and is widely used for irrigation in the Peninsular and Ganges-Brahmaputra regions west of longitude 85°. Dug, bored, and drilled wells are the principal means by which ground water is developed, although locally infiltration tunnels or improved springs are used. Methods of lifting or pumping water from wells include the hand line and bucket, the hand-lift pump, the counterpoised sweep, bullocks, and "mote," the water wheel, horizontal and vertical centrifugal pumps, and deep-well turbine pumps. The most common device for lifting water for irrigation is still the time-honored bullock and "mote" (leather bag). However, in modern India there is increasing use of mechanical pumps. With respect to the occurrence of ground water, India can be divided into eight provinces, lying in three major regions, (1) the Peninsular region, (2) the Ganges-Brahmaputra region, and (3) the Himalayan region. The Peninsular region contains six ground-water provinces. Precambrian igneous, metamorphic, and indurated sedimentary rocks and early Tertiary volcanic rocks in three of these provinces yield many small supplies of water, which generally is of good quality but locally is brackish or salty. Cretaceous water-bearing sandstones in another province are moderately productive and in places are developed for large water supplies. Late Tertiary and Quaternary water-bearing sands and gravels in two other provinces sustain many small water supplies and several large water supplies-particularly in the coastal areas of southern India. The Ganges-Brahmaputra region is a single ground-water province in which many tens of thousands of small water supplies and several thousand large supplies are obtained from water-bearing sands and gravels in late Tertiary and Quaternary alluvium. This province constitutes a vast groundwater reservoir, which is the most productive in India. The Himalayan region also is considered as a single province, in which ground water occurs in a series of narrow valleys filled with moderately to highly permeable Quaternary alluvium. These alluvial valleys transmit large quantities of water to the ground-water reservoir in the Ganges-Brahmaputra region.

Economic Geology

Documentation and verification of VST2D; a model for simulating transient, Variably Saturated, coupled water-heat-solute Transport in heterogeneous, anisotropic 2-Dimensional, ground-water systems with variable fluid density

This report describes a model for simulating transient, Variably Saturated, coupled water-heatsolute Transport in heterogeneous, anisotropic, 2-Dimensional, ground-water systems with variable fluid density (VST2D). VST2D was developed to help understand the effects of natural and anthropogenic factors on quantity and quality of variably saturated ground-water systems. The model solves simultaneously for one or more dependent variables (pressure, temperature, and concentration) at nodes in a horizontal or vertical mesh using a quasi-linearized general minimum residual method. This approach enhances computational speed beyond the speed of a sequential approach. Heterogeneous and anisotropic conditions are implemented locally using individual element property descriptions. This implementation allows local principal directions to differ among elements and from the global solution domain coordinates. Boundary conditions can include time-varying pressure head (or moisture content), heat, and/or concentration; fluxes distributed along domain boundaries and/or at internal node points; and/or convective moisture, heat, and solute fluxes along the domain boundaries; and/or unit hydraulic gradient along domain boundaries. Other model features include temperature and concentration dependent density (liquid and vapor) and viscosity, sorption and/or decay of a solute, and capability to determine moisture content beyond residual to zero. These features are described in the documentation together with development of the governing equations, application of the finite-element formulation (using the Galerkin approach), solution procedure, mass and energy balance considerations, input requirements, and output options. The VST2D model was verified, and results included solutions for problems of water transport under isohaline and isothermal conditions, heat transport under isobaric and isohaline conditions, solute transport under isobaric and isothermal conditions, and coupled water-heat-solute transport. The first three problems considered in model verification were compared to either analytical or numerical solutions, whereas the coupled problem was compared to measured laboratory results for which no known analytic solutions or numerical models are available. The test results indicate the model is accurate and applicable for a wide range of conditions, including when water (liquid and vapor), heat (sensible and latent), and solute are coupled in ground-water systems. The cumulative residual errors for the coupled problem tested was less than 10–8 cubic centimeter per cubic centimeter, 10-5 moles per kilogram, and 102 calories per cubic meter for liquid water content, solute concentration and heat content, respectively. This model should be useful to hydrologists, engineers, and researchers interested in studying coupled processes associated with variably saturated transport in ground-water systems.

Water-Resources Investigations Report

Simulation of ground-water flow in the Vevay Township area, Ingham County, Michigan

Ground water is the primary source of water for domestic, public-supply, and industrial use within the Tri-County region that includes Clinton, Eaton, and Ingham Counties in Michigan. Because of the importance of this ground-water resource, numerous communities, including the city of Mason in Ingham County, have begun local Wellhead Protection Programs. In these programs, communities protect their groundwater resource by identifying the areas that contribute water to production wells and potential sources of contamination, and by developing methods to manage and minimize threats to the water supply. In addition, some communities in Michigan are concerned about water availability, particularly in areas experiencing water-level declines in the vicinity of quarry dewatering operations. In areas where Wellhead Protection Programs are implemented and there are potential threats to the water supply, residents and communities need adequate information to protect the water supply. In 1996, a regional ground-water-flow model was developed by the U.S. Geological Survey to simulate ground-water flow in Clinton, Eaton, and Ingham Counties. This model was developed primarily to simulate the bedrock ground-waterflow system; ground-water flow in the unconsolidated glacial sediments was simulated to support analysis of flow in the underlying bedrock Saginaw aquifer. Since its development in 1996, regional model simulations have been conducted to address protection concerns and water availability questions of local water-resources managers. As a result of these continuing model simulations, additional hydrogeologic data have been acquired in the Tri-County region that has improved the characterization of the simulated ground-water-flow system and improved the model calibration. A major benefit of these updates and refinements is that the regional Tri-County model continues to be a useful tool that improves the understanding of the ground-water-flow system in the Tri-County region, provides local water-resources managers with a means to answer ground-water protection and availability questions, and serves as an example that can be applied in other areas of the state. A refined version of the 1996 Tri-County regional ground-water-flow model, developed in 1997, was modified with local hydrogeologic information in the Vevay Township area in Michigan. This model, updated in 2003 for this study, was used to simulate ground-water flow to address groundwater protection and availability questions in Vevay Township. The 2003 model included refinement of glacial and bedrock hydraulic characteristics, better representation of the degree of connection between the glacial deposits and the underlying Saginaw aquifer, and refinement of the model cell size. The 2003 model was used to simulate regional groundwater flow, to delineate areas contributing recharge and zones of contribution to production wells in the city of Mason, and to simulate the effects of present and possible future withdrawals. The areal extent of the 10- and 40-year areas contributing recharge and the zones of contribution for the city of Mason's production wells encompass about 2.3 and 6.2 square miles, respectively. Simulation results, where withdrawals for quarry operations were represented by one well pumping at 1.6 million gallons per day, indicate that water levels would decline slightly over 1 foot approximately 2 miles from the quarry in the glacial deposits and in the Saginaw aquifer. With a reduction of the local riverbed conductance or removal of local river model cells representing Mud Creek, water-level declines would extend further west of Mud Creek and further to the north, east, and south of the simulated quarry. Simulation results indicate that water withdrawn for quarry dewatering operations would decrease ground-water recharge to nearby Mud Creek, would increase ground-water discharge from Mud Creek, and that local water levels would be lowered as a result.

Michigan

Design and analysis of a natural-gradient ground-water tracer test in a freshwater tidal wetland, West Branch Canal Creek, Aberdeen Proving Ground, Maryland

A natural-gradient ground-water tracer test was designed and conducted in a tidal freshwater wetland at West Branch Canal Creek, Aberdeen Proving Ground, Maryland. The objectives of the test were to characterize solute transport at the site, obtain data to more accurately determine the ground-water velocity in the upper wetland sediments, and to compare a conservative, ionic tracer (bromide) to a volatile tracer (sulfur hexafluoride) to ascertain whether volatilization could be an important process in attenuating volatile organic compounds in the ground water. The tracer test was conducted within the upper peat unit of a layer of wetland sediments that also includes a lower clayey unit; the combined layer overlies an aquifer. The area selected for the test was thought to have an above-average rate of ground-water discharge based on ground-water head distributions and near-surface detections of volatile organic compounds measured in previous studies. Because ground-water velocities in the wetland sediments were expected to be slow compared to the underlying aquifer, the test was designed to be conducted on a small scale. Ninety-seven ?-inch-diameter inverted-screen stainless-steel piezometers were installed in a cylindrical array within approximately 25 cubic feet (2.3 cubic meters) of wetland sediments, in an area with a vertically upward hydraulic gradient. Fluorescein dye was used to qualitatively evaluate the hydrologic integrity of the tracer array before the start of the tracer test, including verifying the absence of hydraulic short-circuiting due to nonnatural vertical conduits potentially created during piezometer installation. Bromide and sulfur hexafluoride tracers (0.139 liter of solution containing 100,000 milligrams per liter of bromide ion and 23.3 milligrams per liter of sulfur hexafluoride) were co-injected and monitored to generate a dataset that could be used to evaluate solute transport in three dimensions. Piezometers were sampled 2 to 15 times each, from July 1998 through September 1999, to assess background conditions and monitor tracer movement. During the test, 644 samples were analyzed for fluorescein, 617 samples were analyzed for bromide with an ion-selective electrode, 213 samples were analyzed for bromide with colorimetric methods, and 603 samples were analyzed for sulfur hexafluoride, including samples collected prior to tracer injection to determine background concentrations. Additional samples were analyzed for volatile organic compounds (96 samples) and methane (37 samples) to determine the distribution of these contaminants and the extent of methanogenic conditions within the tracer array; however, these data were not used for the analysis of the test. During the tracer test, the fluorescein dye, bromide, and sulfur hexafluoride were transported predominantly in the upward direction, although all three tracers also moved outward in all directions from the injection point, and it is likely that some tracer mass moved beyond the lateral edges of the array. An analysis of the tracer-test data was performed through the use of breakthrough curves and isoconcentration contour plots. Results show that movement of the fluorescein dye, a non-conservative tracer, was retarded compared to the other two tracers, likely as a result of sorption onto the wetland sediments. Suspected loss of tracer mass along the lateral edges of the array prevented a straightforward quantitative analysis of tracer transport and ground-water velocity from the bromide and sulfur-hexafluoride data. In addition, the initial density of the bromide/sulfur hexafluoride solution (calculated to be 1.097 grams per milli2 Ground-Water Tracer Test, West Branch Canal Creek, Aberdeen Proving Ground, MD liter) could have caused the solution to sink below the injection point before undergoing dilution and moving back up into the array. For these reasons, the data analysis in this report was performed largely through qualitative method

Scientific Investigations Report

Distribution of selected volatile organic compounds determined with water-to-vapor diffusion samplers at the interface between ground water and surface water, Centredale Manor site, North Providence, Rhode Island, September 1999

Volatile organic compounds are present in soils and ground water at the Centredale Manor Superfund Site in North Providence, Rhode Island. In September 1999, water-to-vapor diffusion samplers were placed in the bottom sediments of waterways adjacent to the site to identify possible contaminated ground-water discharge areas. The approximate12-acre site is a narrow stretch of land between the eastern bank of the Woonasquatucket River, downstream from the U.S. Route 44 bridge and a former mill raceway. The samplers were placed along a 2,250-foot reach of the Woonasquatucket River, in the former mill raceway several hundred feet to the east and parallel to the river, and in a cross channel between the river and former mill raceway. Volatile organic compounds were detected in 84 of the 104 water-to-vapor diffusion samplers retrieved. Trichloroethylene and tetrachloro-ethylene were the principal volatile organic compounds detected. The highest vapor concentrations measured for these two chemicals were from diffusion samplers located along an approximate 100-foot reach of the Woonasquatucket River about 500 feet downstream of the bridge; here trichloroethylene and tetrachloroethylene vapor concentrations ranged from about 2,000 to 180,000 and 1,600 to 1,400,000 parts per billion by volume, respectively. Upstream and downstream from this reach and along the former mill raceway, trichloroethylene and tetrachloroethylene vapor concentrations from the diffusion samples were generally less than 100 parts per billion by volume. Along the lower reaches of the river and mill raceway, however, and in the cross channel, vapor concentrations of trichloroethylene exceeded 100 parts per billion by volume and tetrachloroethylene exceeded 1,000 parts per billion by volume in several diffusion samples. Although diffusion sample vapor concentrations are higher than water concentrations in surface waters and in ground water, and they should only be interpreted qualitatively as relative values, these values provide important information as to potential discharge areas of contaminants.

Rhode Island

Description and field analysis of a coupled ground-water/surface-water flow model (MODFLOW/BRANCH) with modifications for structures and wetlands in southern Dade County, Florida

A coupled surface-water model (BRANCH) and ground-water model (MODFLOW) model were tested to simulate the interacting wetlands/surface-water/ ground-water system of southern Dade County. Several options created for the MODFLOW ground- ground-water model were used in representing this field situation. The primary option is the MODBRANCH interfacing software, which allows leakage to be accounted for between the MODFLOW ground-water model and the BRANCH dynamic model for simulation of flow in an interconnected network of open channels. A modification to an existing software routine, which is referred to as BCF2, allows cells in MODFLOW to rewet when dry--a requirement in representing the seasonal wetlands in Dade County. A companion to BCF2 is the modified evapotranspiration routine EVT2. The EVT2 routine changes the cells where evapotranspiration occurs, depending on which cells are wet. The Streamlink package represents direct connections between the canals and wetlands at locations where canals open directly into overland flow. Within the BRANCH model, the capability to represent the numerous hydraulic structures, gated spillways, gated culverts, and pumps was added. The application of these modifications to model surface-water/ground-water interactions in southern Dade County demonstrated the usefulness of the coupled MODFLOW/BRANCH model. Ground-water and surface-water flows are both simulated with dynamic models. Flow exchange between models, intermittent wetting and drying, evapotranspiration, and hydraulic structure operations are all represented appropriately. Comparison was made with a simulation using the RIV1 package instead of MODBRANCH to represent the canals. RIV1 represents the canals by user-defined stages, and computes leakage to the aquifer. Greater accuracy in reproducing measured ground- water heads was achieved with MODBRANCH, which also computes dynamic flow conditions in the canals, unlike RIV1. The surface-water integrated flow and transport two-dimensional model (SWIFT2D) was also applied to the southeastern coastal wetlands for comparison with the wetlands flow approximation made in MODFLOW. MODFLOW simulates the wetlands as a highly conductive upper layer of the aquifer, whereas SWIFT2D solves the hydrodynamic equations. Comparison in this limited test demonstrated no specific advantage for either method of representation. However, much additional testing on a wider variety of geometric and hydraulic situations, such as in areas with greater tidal or other dynamic forcing effects, is needed to make definite conclusions. A submodel of the existing southern Dade County model schematization was used to examine water-delivery alternatives proposed by the U.S. Army Corps of Engineers. For this application, the coupled MODFLOW/BRANCH model was used as a design tool. A new canal and several pumps to be tested to maintain lower water levels in a residential area (while water levels in the Everglades are raised) were added to the model schematization. The pumps were assumed to have infinite supply capacity in the model so that their maximum pumping rates during the simulation could be used to determine pump sizes.

Water-Resources Investigations Report

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada

n investigation of a childhood leukemia cluster by US Centers for Disease Control and Prevention revealed that residents of the Carson Desert, Nevada, are exposed to high levels of W and this prompted an investigation of W in aquifers used as drinking water sources. Tungsten concentrations in 100 ground water samples from all aquifers used as drinking water sources in the area ranged from 0.27 to 742 μg/l. Ground water in which W concentrations exceed 50 μg/l principally occurs SE of Fallon in a geothermal area. The principal sources of W in ground water are natural and include erosion of W-bearing mineral deposits in the Carson River watershed upstream of Fallon, and, possibly, upwelling geothermal waters. Ground water in the Fallon area is strongly reducing and reductive dissolution of Fe and Mn oxyhydroxides may be releasing W; however, direct evidence that the metal oxides contain W is not available. Although W and Cl concentrations in the Carson River, a lake, and water from many wells, appear to be controlled by evaporative concentration, evaporation alone cannot explain the elevated W concentrations found in water from some of the wells. Concentrations of W exceeding 50 μg/l are exclusively associated with Na &#x2013; HCO 3 "> Na–HCO3 and Na–Cl water types and pH > 8.0; in these waters, geochemical modeling indicates that W exhibits <10% adsorption. Tungsten concentrations are strongly and positively correlated with As, B, F, and P, indicating either common sources or common processes controlling their concentrations. Geochemical modeling indicates W concentrations are consistent with pH-controlled adsorption of W. The geochemical model PHREEQC was used to calculate IAP values, which were compared with published Ksp values for primary W minerals. FeWO 4 , MnWO 4 , Na 2 WO 4 , and MgWO 4 were undersaturated and CaWO 4 and SrWO 4 were approaching saturation. These conclusions are tentative because of uncertainty in the thermodynamic data. The similar behavior of As and W observed in this study suggests ground water in areas where elevated As concentrations are present also may contain elevated W concentrations, particularly if there is a mineral or geothermal source of W and reducing conditions develop in the aquifer.

Nevada

Stable isotopes and volatile organic compounds along seven ground-water flow paths in divergent and convergent flow systems, southern California, 2000

Ground water is a major source of drinking water in southern California. In an effort to understand factors influencing the susceptibility of ground water tapped by public supply wells, the U.S. Geological Survey has undertaken studies in cooperation with the California State Water Resources Control Board. The vertical and lateral distribution of stable isotopes (deuterium and oxygen-18) and volatile organic compounds (VOC) were examined along seven ground-water flow paths in three urban ground-water basins in southern California: Central Basin in Los Angeles County, Main Basin in Orange County, and Bunker Hill Basin in San Bernardino County. Forty-seven monitoring wells and 100 public supply wells were sampled. The results of this study suggest that the direction of flow and perhaps the degree of confinement in an aquifer system are important controls on the distribution of VOCs. Ground-water flow in the Central and Main Basins in the southern California coastal plain is characterized as radially divergent, with ground-water flow directions moving outward from focused areas of recharge in the unconfined part of the aquifer system toward dispersed areas of discharge in the more confined part. In these basins, there is a volume of water containing VOCs that extends out into a volume of water containing no VOCs. This pattern suggests that radially divergent flow systems disperse VOCs in distal areas. The overall pattern also suggests that ground water in the pressure area is generally insulated from compounds introduced at land surface. These two factors?dispersion of VOCs due to divergence of flow and insulation from land-surface inputs?suggest that the susceptibility of public supply wells to surface contamination decreases with distance in radially divergent, well confined ground-water flow system. In the inland Bunker Hill Basin, ground-water flow is characterized as radially convergent; ground-water flow directions move inward from dispersed recharge areas in the unconfined part of the aquifer system, toward an area of focused discharge in the more confined part. The number of VOCs increased and the concentrations of individual VOCs increased, or remained the same, with increasing travel distance. Methyl tert-butyl ether was detected only in wells in the confined part of the aquifer system, suggesting that the confining units present in the distal part of the Bunker Hill Basin do not prevent VOCs from reaching ground water. These results suggest that VOCs in the Bunker Hill Basin are collected and concentrated as ground water moves downgradient because of radial convergenence of flow. They also suggest that ground water in the Bunker Hill Basin has an increasing opportunity to pick up VOCs introduced at land surface as it moves along a flow path. Some of the downgradient increase in VOC occurrence and concentration may be due to pumping that selectively removes cleaner ground water, thus leaving ground water containing more VOCs in the aquifer. These two factors?collection of VOCs due to convergence of flow and increasing opportunity to collect surficial contaminants perhaps due to a relative absence of confinement?suggest that the susceptibility of public supply wells to surface contamination increases with distance in radially convergent ground-water flow systems, particularly those that are unconfined.

Water-Resources Investigations Report

Evaluation of baseline ground-water conditions in the Mosteiros, Ribeira Paul, and Ribeira Fajã Basins, Republic of Cape Verde, West Africa, 2005-06

This report documents current (2005-06) baseline ground-water conditions in three basins within the West African Republic of Cape Verde (Mosteiros on Fogo, Ribeira Paul on Santo Antão, and Ribeira Fajã on São Nicolau) based on existing data and additional data collected during this study. Ground-water conditions (indicators) include ground-water levels, ground-water recharge altitude, ground-water discharge amounts, ground-water age (residence time), and ground-water quality. These indicators are needed to evaluate (1) long-term changes in ground-water resources or water quality caused by planned ground-water development associated with agricultural projects in these basins, and (2) the feasibility of artificial recharge as a mitigation strategy to offset the potentially declining water levels associated with increased ground-water development. Ground-water levels in all three basins vary from less than a few meters to more than 170 meters below land surface. Continuous recorder and electric tape measurements at three monitoring wells (one per basin) showed variations between August 2005 and June 2006 of as much as 1.8 meters. Few historical water-level data were available for the Mosteiros or Ribeira Paul Basins. Historical records from Ribeira Fajã indicate very large ground-water declines during the 1980s and early 1990s, associated with dewatering of the Galleria Fajã tunnel. More-recent data indicate that ground-water levels in Ribeira Fajã have reached a new equilibrium, remaining fairly constant since the late 1990s. Because of the scarcity of observation wells within each basin, water-level data were combined with other techniques to evaluate ground-water conditions. These techniques include the quantification of ground-water discharge (well withdrawals, spring discharge, seepage to springs, and gallery drainage), field water-quality measurements, and the use of environmental tracers to evaluate sources of aquifer recharge, flow paths, and ground-water residence times. In the Mosteiros Basin, measured well and spring discharge is about 220,000 cubic meters per year. For the Ribeira Paul Basin, measured well discharge, spring discharge, and ground-water seepage to springs is about 1,600,000 cubic meters per year. Ribeira Fajã Basin is the driest of the three basins with a precipitation rate of about half that of the other two basins. The only measurable ground-water discharge from this basin is from Galleria Fajã, estimated to be about 150,000 cubic meters per year. Measured discharge for all three basins does not include submarine outflow or agricultural/phreatophyte consumptive use (Paul Basin, only) and is assumed to be less than total ground-water discharge. Ground-water ages indicate that recharge to wells and springs occurred from more than 50 years ago at some locations to within the past decade at other sites. Ground water in Paul is younger than that in the other two basins, indicating that recharge generally occurred within the past 50 years. Ground water at all the dateable sites using tritium/helium in both the Mosteiros and Ribeira Fajã Basins show that recharge occurred more than 50 years before the sampling dates. Ground-water tritium/helium age dating was not possible at some sites in Mosteiros and Ribeira Fajã Basins because of the presence of helium in the aquifer derived from the mantle or aquifer matrix. However, this helium was useful for accurate age dating of the unaffected ground-water sites. Dissolved gases indicate that most ground-water recharge occurs at mid and high altitudes within all three basins; calculated recharge altitudes ranged from 700 to more than 2,000 meters. In the Mosteiros and Ribeira Fajã Basins, recharge altitudes are much higher than the wells and springs. This suggests that it may take many years for artificial recharge to result in a beneficial impact on the aquifer in areas where the agricultural projects are implemented. Recharge altitudes in Paul Basin also were generally higher than their respective ground-water discharge sampling sites except for one spring, Seladinha. This spring, in combination with generally younger ground-water ages in Paul, indicates the existence of some short flow paths where artificial recharge may possibly enhance available water resources within a few years. The salinity of wells and springs is generally low in the Ribeira Paul and Ribeira Fajã Basins, but somewhat higher in Mosteiros Basin. Specific-conductance measurements of wells and springs in Ribeira Paul and Ribeira Fajã ranged from about 200 to 700 microsiemens per centimeter at 25 degrees Celsius. Although the Monte Vermelho spring in Mosteiros Basin also has very low salinity (200 microsiemens per centimeter at 25 degrees Celsius), water from the wells along the coastal plain has specific-conductance measurements of as much as 16,000 microsiemens per centimeter at 25 degrees Celsius. These higher values indicate some brackish water intrusion. Additional ground-water development of the Mosteiros coastal plain may exacerbate this situation.

Mosteiros basin, Ribeira Fajã basin, Ribeira Paul

Optimization of ground-water withdrawal at the old O-Field area, Aberdeen Proving Ground, Maryland

The U.S. Army disposed of chemical agents, laboratory materials, and unexploded ordnance at the Old O-Field landfill at Aberdeen Proving Ground, Maryland, beginning prior to World War II and continuing until at least the 1950?s. Soil, ground water, surface water, and wetland sediments in the Old O-Field area were contaminated by the disposal of these materials. The site is in the Atlantic Coastal Plain, and is characterized by a complex series of Pleistocene and Holocene sediments formed in various fluvial, estuarine, and marine-marginal hydrogeologic environments. A previously constructed transient finite-difference ground-water-flow model was used to simulate ground-water flow and the effects of a pump-and-treat remediation system designed to prevent contaminated ground water from flowing into Watson Creek (a tidal estuary and a tributary to the Gunpowder River). The remediation system consists of 14 extraction wells located between the Old O-Field landfill and Watson Creek.Linear programming techniques were applied to the results of the flow-model simulations to identify optimal pumping strategies for the remediation system. The optimal management objective is to minimize total withdrawal from the water-table aquifer, while adhering to the following constraints: (1) ground-water flow from the landfill should be prevented from reaching Watson Creek, (2) no extraction pump should be operated at a rate that exceeds its capacity, and (3) no extraction pump should be operated at a rate below its minimum capacity, the minimum rate at which an Old O-Field pump can function. Water withdrawal is minimized by varying the rate and frequency of pumping at each of the 14 extraction wells over time. This minimizes the costs of both pumping and water treatment, thus providing the least-cost remediation alternative while simultaneously meeting all operating constraints.The optimal strategy identified using this objective and constraint set involved operating 13 of the 14 extraction wells at rates ranging from 0.4 to 4.9 gallons per minute.

Water-Resources Investigations Report

Ground-water flow and the possible effects of remedial actions at J-Field, Aberdeen Proving Ground, Maryland

J-Field, located in the Edgewood Area of Aberdeen Proving Ground, Md, has been used since World War II to test and dispose of explosives, chemical warfare agents, and industrial chemicals resulting in ground-water, surface-water, and soil contami- nation. The U.S. Geological Survey finite-difference model was used to better understand ground-water flow at the site and to simulate the effects of remedial actions. A surficial aquifer and a confined aquifer were simulated with the model. A confining unit separates these units and is represented by leakance between the layers. The area modeled is 3.65 mi2; the model was constructed with a variably spaced 40 X 38 grid. The horizontal and lower boundaries of the model are all no-flow boundaries. Steady-state conditions were used. Ground water at the areas under investigation flows from disposal pit areas toward discharge areas in adjacent estuaries or wetlands. Simulations indicate that capping disposal areas with an impermeable cover effectively slows advective ground water flow by 0.7 to 0.5 times. Barriers to lateral ground-water flow were simulated and effectively prevented the movement of ground water toward discharge areas. Extraction wells were simulated as a way to contain ground-water contamination and to extract ground water for treatment. Two wells pumping 5 gallons per minute each at the toxic-materials disposal area and a single well pumping 2.5 gallons per minute at the riot-control-agent disposal area effectively contained contamination at these sites. A combi- nation of barriers to horizontal flow east and south of the toxic-materials disposal area, and a single extraction well pumping at 5 gallons per minute can extract contaminated ground water and prevent pumpage of marsh water.

Water-Resources Investigations Report

Estimates of residence time and related variations in quality of ground water beneath Submarine Base Bangor and vicinity, Kitsap County, Washington

Estimates of residence time of ground water beneath Submarine Base Bangor and vicinity ranged from less than 50 to 4,550 years before present, based on analysis of the environmental tracers tritium, chlorofluorocarbons (CFCs), and carbon-14 (14C), in 33 ground-water samples collected from wells tapping the ground-water system. The concentrations of multiple environmental tracers tritium, CFCs, and 14C were used to classify ground water as modern (recharged after 1953), pre-modern (recharged prior to 1953), or indeterminate. Estimates of the residence time of pre-modern ground water were based on evaluation of 14C of dissolved inorganic carbon present in ground water using geochemical mass-transfer modeling to account for the interactions of the carbon in ground water with carbon of the aquifer sediments. Ground-water samples were obtained from two extensive aquifers and from permeable interbeds within the thick confining unit separating the sampled aquifers. Estimates of ground-water residence time for all ground-water samples from the shallow aquifer were less than 45 years and were classified as modern. Estimates of the residence time of ground water in the permeable interbeds within the confining unit ranged from modern to 4,200 years and varied spatially. Near the recharge area, residence times in the permeable interbeds typically were less than 800 years, whereas near the discharge area residence times were in excess of several thousand years. In the deeper aquifers, estimates of ground-water residence times typically were several thousand years but ranged from modern to 4,550 years. These estimates of ground-water residence time based on 14C were often larger than estimates of ground-water residence time developed by particle-tracking analysis using a ground-water flow model. There were large uncertainties?on the order of 1,000-2,000 years?in the estimates based on 14C. Modern ground-water tracers found in some samples from large-capacity production wells screened in the deeper aquifer may be the result of preferential ground-water pathways or induced downward flow caused by pumping stress. Spatial variations in water quality were used to develop a conceptual model of chemical evolution of ground water. Stable isotope ratios of deuterium and oxygen-18 in the 33 ground-water samples were similar, indicating similar climatic conditions and source of precipitation recharge for all of the sampled ground water. Oxidation of organic matter and mineral dissolution increased the concentrations of dissolved inorganic carbon and common ions in downgradient ground waters. However, the largest concentrations were not found near areas of ground-water discharge, but at intermediate locations where organic carbon concentrations were greatest. Dissolved methane, derived from microbial methanogenesis, was present in some ground waters. Methanogenesis resulted in substantial alteration of the carbon isotopic composition of ground water. The NETPATH geochemical model code was used to model mass-transfers of carbon affecting the 14C estimate of ground-water residence time. Carbon sources in ground water include dispersed particulate organic matter present in the confining unit separating the two aquifers and methane present in some ground water. Carbonate minerals were not observed in the lithologic material of the ground-water system but may be present, because they have been found in the bedrock of stream drainages that contribute sediment to the study area.

Water-Resources Investigations Report

Patterns and age distribution of ground-water flow to streams

Simulations of ground-water flow in a generic aquifer system were made to characterize the topology of ground-water flow in the stream subsystem and to evaluate its relation to deeper ground-water flow. The flow models are patterned after hydraulic characteristics of aquifers of the Atlantic Coastal Plain and are based on numerical solutions to three-dimensional, steady-state, unconfined flow. The models were used to evaluate the effects of aquifer horizontal-to-vertical hydraulic conductivity ratios, aquifer thickness, and areal recharge rates on flow in the stream subsystem. A particle tracker was used to determine flow paths in a stream subsystem, to establish the relation between ground-water seepage to points along a simulated stream and its source area of flow, and to determine ground-water residence time in stream subsystems. In a geometrically simple aquifer system with accretion, the source area of flow to streams resembles an elongated ellipse that tapers in the down gradient direction. Increased recharge causes an expansion of the stream subsystem. The source area of flow to the stream expands predominantly toward the stream headwaters. Base flow gain is also increased along the reach of the stream. A thin aquifer restricts ground-water flow and causes the source area of flow to expand near stream headwaters and also shifts the start-of-flow to the drainage basin divide. Increased aquifer anisotropy causes a lateral expansion of the source area of flow to streams.

Groundwater