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USGS2014

Acute and chronic sensitivity of white sturgeon ( Acipenser transmontanus ) and rainbow trout ( Oncorhynchus mykiss ) to cadmium, copper, lead, or zinc in laboratory water-only exposures

White sturgeon (Acipenser transmontanus) are experiencing poor recruitment in the trans boundary reach of the upper Columbia River in eastern Washington State. Limited toxicity data indicated that early life stages of white sturgeon are sensitive to metals. In acute 4-day (d) exposures with larval white sturgeon, previous studies have reported that the 4-day median lethal concentrations (LC50) based on biotic ligand model (BLM) normalization for copper were below the U.S. Environmental Protection Agency national recommended acute water-quality criterion. In previously published chronic 66-d exposures starting with newly fertilized eggs of white sturgeon, 20-percent lethal effect concentrations (LC20s) for copper, cadmium, or zinc generally were within a factor of two of the chronic values of the most sensitive fish species in the databases of the U.S. Environmental Protection Agency water-quality criteria (WQC) for the three metals. However, there were some uncertainties in the chronic exposures previously performed with white sturgeon, including (1) low control survival (37 percent), (2) more control fish tested in each replicate compared to other treatments, (3) limited replication of treatments (n=2), (4) lack of reported growth data (such as dry weight), and (5) wide dilution factors for exposure concentrations (6- to 8-fold dilutions). The U.S. Environmental Protection Agency concluded that additional studies are needed to generate more toxicity data to better define lethal and sublethal toxicity thresholds for metals for white sturgeon. The objective of the study was to further evaluate the acute and chronic toxicity of cadmium, copper, lead, or zinc to early life stages of white sturgeon in water-only exposures. Toxicity tests also were performed with commonly tested rainbow trout (Oncorhynchus mykiss) under similar test conditions to determine the relative sensitivity between white sturgeon and rainbow trout to these metals. Toxicity data generated from this study were used to evaluate the sensitivity of early life stages of white sturgeon and rainbow trout relative to data published for other test organisms. Toxicity data generated from this study also were used to evaluate the level of protection of U.S. Environmental Protection Agency WQC or Washington State water-quality standards (WQS) for copper, zinc, cadmium, or lead to white sturgeon inhabiting the upper Columbia River. Chapter A of this report summarizes the results of acute toxicity tests performed for 4 d with white sturgeon and rainbow trout exposed to copper, cadmium, or zinc. Chapter B of this report summarizes the results of chronic toxicity tests performed for as many as 53 days with white sturgeon or rainbow trout exposed to copper, cadmium, zinc, or lead. Appendixes to the report are available at http://pubs.usgs.gov/sir/2013/5204 . Supporting documentation for chapter A toxicity testing is provided in appendix 1. Supporting documentation for chapter B toxicity testing is provided in Appendix 2. Supporting documentation on analysis of water chemistry for chapter A and chapter B is provided in appendix 3 and 4. The rationale for applying corrections to measured copper and zinc values in water samples from some of the toxicity tests performed in chapter A is provided in appendix 5. A summary of dissolved organic carbon measurement variability and implications for biotic ligand model normalization for toxicity data summarized in chapter A and chapter B are provided in appendix 6. An evaluation of an interlaboratory comparison of analyses for dissolved organic carbon in water from the U.S. Geological Survey Columbia Environmental Research Center and University of Saskatchewan is provided in appendix 7. Finally, appendix 8 provides a summary of retesting of white sturgeon in 2012 to determine if improved survival of sturgeon would affect copper effect concentrations in 24-d copper exposures started with newly hatched larvae, and to evaluate the effect of light intensity or temperature on the response of newly hatched larvae during a 25-d study.

Scientific Investigations Report↗

USGS2001

Mountain Island Lake, North Carolina: Analysis of ambient conditions and simulation of hydrodynamics, constituent transport, and water-quality characteristics, 1996–97

Mountain Island Lake is an impoundment of the Catawba River in North Carolina and supplies drinking water to more than 600,000 people in Charlotte, Gastonia, Mount Holly, and several other communities. The U.S. Geological Survey, in cooperation with the Charlotte-Mecklenburg Utilities, conducted an investigation of the reservoir to characterize hydrologic and water-quality conditions and to develop and apply a simulation model to predict the response of the reservoir to changes in constituent loadings or the flow regime. During 1996–97, flows into Mountain Island Lake were dominated by releases from Cowans Ford Dam on Lake Norman, with more than 85 percent of the total inflow to the reservoir coming from Lake Norman. Riverbend Steam Station discharges accounted for about 12 percent of the inflows to the reservoir, and inflows from tributary streams contributed less than 1.5 percent of the total inflows. Releases through Mountain Island Dam accounted for about 81 percent of outflows from the reservoir, while Riverbend Steam Station withdrawals, which were equal to discharge from the facility, constituted about 13 percent of the reservoir withdrawals. About 5.5 percent of the withdrawals from the reservoir were for water supply. Strong thermal stratification was seldom observed in Mountain Island Lake during April 1996-September 1997. As a result, dissolved-oxygen concentrations were only infrequently less than 4 milligrams per liter, and seldom less than 5 milligrams per liter throughout the entire reservoir, including the coves. The Riverbend Steam Station thermal discharge had a pronounced effect on surface-water temperatures near the outfall. McDowell Creek, which drains to McDowell Creek cove, receives treated wastewater from a large municipal facility and has exhibited signs of poor water-quality conditions in the past. During April 1996-September 1997, concentrations of nitrate, ammonia, total phosphorus, and chlorophyll a were higher in McDowell Creek cove than elsewhere throughout the reservoir. Nevertheless, the highest chlorophyll a concentration measured during the study was 13 micrograms per liter—well below the North Carolina ambient water-quality standard of 40 micrograms per liter. In the mainstem of the reservoir, near-bottom ammonia concentrations occasionally were greater than near-surface concentrations. However, the relatively large top-to-bottom differences in ammonia and phosphorus that have been observed in other Catawba River reservoirs were not present in Mountain Island Lake. External loadings of suspended solids, nitrogen, phosphorus, and biochemical oxygen demand were determined for May 1996-April 1997. Flows through Cowans Ford Dam contributed more than 80 percent of the biochemical oxygen demand and nitrogen load to the reservoir, with McDowell Creek contributing about 15 percent of the biochemical oxygen demand load. In contrast, McDowell Creek contributed about half of the phosphorus load to the reservoir, while inflows through Cowans Ford Dam contributed about one-fourth of the phosphorus load, and the McDowell Creek wastewater-treatment plant contributed about 15 percent of the total phosphorus load. The remainder of the phosphorus loadings came from Gar Creek and the discharge from the Riverbend ash settling pond. Mountain Island Lake is a relatively small (11.3-square-kilometer surface area) impoundment. An area of 181 square kilometers drains directly to the reservoir, but much of this area is undergoing development. In addition, the reservoir receives treated effluent from a municipal wastewater-treatment facility. The two-dimensional, laterally averaged model CE-QUAL-W2 was applied to Mountain Island Lake. The model was configured to simulate water level, water temperature, and 12 water-quality constituents. The model included the mainstem, four coves, three point-source discharges, and three withdrawals. Simulated water levels generally were within 10 centimeters of measured values, indicating a good calibration of the water balance for the reservoir. The root-mean-square difference between measured and simulated water temperatures was about 1 to 1.5 degrees Celsius, and vertical distributions of water temperature were accurately simulated in both the mainstem and coves. Seasonal and spatial patterns of nitrate, ammonia, orthophosphorus, and chlorophyll a were reasonably reproduced by the water-quality model. Because of the absence of the denitrification process in the model formulation, nitrate concentrations typically were overpredicted. Simulated and measured ammonia concentrations seldom differed by more than 0.01 milligram per liter, and simulations of seasonal fluctuations in chlorophyll a were representative of measured conditions. The root mean square of the difference between measured and simulated dissolved-oxygen concentrations was about 1 milligram per liter. The calibrated water-quality model was applied to evaluate (1) the movement of a conservative, neutrally buoyant material, or tracer, through the reservoir for several sets of conditions; (2) the effects of the Riverbend thermal discharge on water temperature in the reservoir; (3) the effects of changes in water-supply withdrawal rates on water-quality conditions; and (4) changes in reservoir water quality in response to changes in point- and nonpoint-source loadings. In general, dissolved material entering Mountain Island Lake from both Cowans Ford Dam and McDowell Creek during the summer moves along the bottom of the lake toward Mountain Island Dam, with little mixing of dissolved material into the surface layers. Simulations suggest that dissolved material can move upstream in the reservoir when flows from Cowans Ford Dam are near zero. Dissolved material can remain in Mountain Island Lake for a period far in excess of the theoretical retention time of 12 days. Simulations indicated that the Riverbend thermal discharge increases water temperature in the surface layers of the downstream part of the reservoir by as much as 5 degrees Celsius. However, the discharge has little effect on near-bottom water temperature. Based on model simulations, a proposed doubling of the water-supply withdrawals from Mountain Island Lake has no readily apparent effect on water quality in the reservoir. The increased withdrawal rate may have some localized effects on circulation in the reservoir, but a more detailed model of the intake zone would be required to identify those effects. The effects of a 20-percent increase in water-chemistry loadings through Cowans Ford Dam and from McDowell Creek were simulated separately. Increased loadings from Cowans Ford Dam had about the same effect on water-quality conditions near Mountain Island Dam as did increased loadings from McDowell Creek. Maintaining good water quality in Mountain Island Lake depends on maintaining good water quality in Lake Norman as well as in the inflows from the McDowell Creek watershed.

North Carolina↗

USGS2020

A comparison of groundwater sampling technologies, including passive diffusion sampling, for radionuclide contamination

Using traditional high-flow purge methods for long-term water quality monitoring of deep groundwater wells can be expensive, affect contaminant migration, and produce excessive volumes of discharge water that can be difficult to manage. The use of low-flow pumping methods and depth discrete bailers (DDBs) can reduce the cost of sampling deep groundwater wells. In general, using different pumping methods to obtain reproducible and representative groundwater can be challenging. Passive diffusion samplers (PDSs) have successfully been used in long-term monitoring for volatile organic compounds, major ions, and trace-elements, but application has been limited for stable and radioactive isotopes. Beginning in 2018, the United States Geological Survey (USGS) conducted three sampling events to test the ability of PDSs and DDBs to obtain reproducible and representative groundwater samples. The sampled well is completed in a regional, permeable carbonate aquifer and is one in a set of wells that have historically been used for tritium tracer testing. All samples were obtained at 180 m (590 ft) below land surface (bls) in a 13.97 cm (5.5 inch) uncased well that has a total depth of 202 m (662 ft) bls. The first sampling event deployed a regenerated cellulose dialysis membrane (RCDM) PDS for 14 days with deionized water as the blank. The second sampling event deployed a RCDM for 27 days also with deionized water as the blank. The third sampling event deployed a Dual Membrane (DM) PDS for 65 days using a blank of tritium-dead carbonate water. The DM PDS was used to assess the effect of longer-term deployment on tritium concentrations and address whether or not the PDSs reached equilibrium with ambient groundwater. The day after each of the three passive samplers were retrieved a DDB was used to obtain discrete non-integrated groundwater samples. For each DDB sampling day, the bailer was lowered into the well 10 consecutive times to determine if the water chemistry changed from the first to the last bailed sample. Quality assurance samples including blanks and duplicates were obtained during all three sampling events. All blank waters had tritium concentrations less than 21±33 pCi/L. Major ion (e.g. calcium, chloride, sodium, and sulfate) results were compared between all samples obtained with RCDM and DDB. Major ion concentrations showed a coefficient of variation of less than 6% between all RCDM and DDB samples; however, the coefficient of variation between the different deployment times and the two different methods for trace-element concentrations was much larger, particularly for manganese (82%), lead (41%), and zinc (33%). Stable isotope values were compared between the RCDM and DDB samples. The DDB sample results all fell within analytical uncertainty and were considered representative of the formation groundwater. The stable isotope values from the RCDM samples indicated that a longer deployment time was necessary to gain equilibrium and to obtain representative groundwater samples. Tritium results from groundwater samples obtained from the RCDM, DM, and DDB indicate that groundwaters obtained with PDSs produced tritium concentrations 2 to 3 times higher (between 1,426 and 3,060±87 pCi/L) than groundwaters obtained with a DDB (479 to 1,219±51 pCi/L). The longer the passive diffusion samplers were deployed, the higher the tritium concentration, suggesting that equilibrium with tritium was not reached within a 27-day deployment. DDB samples showed tritium results declining from the first to the last bailed sample for all three sampling events. This research suggests that tritium results from groundwater samples obtained from PDSs are more reproducible than samples obtained from DDBs. Also, PDSs likely do not accumulate isotopes of water but rather equilibrate with the ambient groundwater. On the other hand, both PDSs and DDBs were able to provide representative groundwater samples for major ions and have the potential to produce.

Conference Paper↗

USGS2002

Hydrology and chemistry of floodwaters in the Yolo Bypass, Sacramento River system, California, during 2000

Discharges to and floodwaters in the Yolo Bypass were sampled during winter and spring, 2000. The primary purpose of the study was to link changes in water quality in the Yolo Bypass to inflows from the Sacramento River (over Fremont Weir) and from four local streams that discharge to the west side of the floodplain. Specific conductance, chloride, sulfate, dissolved inorganic nutrients, dissolved organic carbon, particulate carbon and nitrogen, suspended particulate matter (mass), and selected dissolved metals were measured in most of the samples. When the Sacramento River was spilling over Fremont Weir, the water chemistry in the Yolo Bypass was very similar to that in the river except along the western margin of the floodplain where influences of local stream inflow were evident. When flow over Fremont Weir stopped, floodwaters drained from the Yolo Bypass, and the local streams were the major discharges as the floodwaters receded eventually to the perennial channel along the eastern margin of the floodplain. After the initial draining of the floodplain, chemical concentrations at sites along the perennial channel showed strong influences of inflows from Cache Creek and Ridge Cut, which are sources of nutrients and contaminants that are potentially hazardous to wildlife. Runoff from spring storms increased flow in the perennial channel and flushed accumulated nutrients and organic matter to the tidal river. Releases of freshwater to the perennial channel might be beneficial in maintaining habitat quality for aquatic species during the dry seasons.

California↗

USGS1990

Breeding biology of the spotted salamander Ambystoma maculatum (Shaw) in acidic temporary ponds at Cape Cod, USA

The relationship between water chemistry and breeding success of spotted salamanders Ambystoma maculatum (Shaw) was examined in temporary woodland ponds on outer Cape Cod, Massachusetts in 1985 and 1986. Most pond waters were dilute (3median coductivity = 57 umhos cm −1 (1 umhos cm −1 = 0·1 mSm −1 )), acidic (median pH = 4·82), and highly colored (median = 140 Pt-Co units). Most acidity was due to abundant organic acids. Salamander survival to hatching was over 80% at 8 of 12 ponds monitored. Complete mortality, preceded by gross abnormalities, was observed only among embryos in the most acidic spawning pond (pH 4·3−4·5) in both years. Embryo transfers between ponds and laboratory studies indicated that reduced survival was due to the interaction of low pH with high tannin-lignin concentration. The use of amphibian embryonic survival to indicate acid rain effects is complicated by multiple habitat parameters and should only be attempted in conjunction with long-term population monitoring.

Massachusetts↗

USGS2006

Hydrogeology of the upper and middle Verde River watersheds, central Arizona

The upper and middle Verde River watersheds in central Arizona are primarily in Yavapai County, which in 1999 was determined to be the fastest growing rural county in the United States; by 2050 the population is projected to more than double its current size (132,000 in 2000). This study combines climatic, surface-water, ground-water, water-chemistry, and geologic data to describe the hydrogeologic systems within the upper and middle Verde River watersheds and to provide a conceptual understanding of the ground-water flow system. The study area includes the Big Chino and Little Chino subbasins in the upper Verde River watershed and the Verde Valley subbasin in the middle Verde Rive watershed...more...A geochemical mixing model was used to quantify fractions of ground-water sources to the Verde River from various parts of the study area. Most of the water in the uppermost 0.2 mile of the Verde River is from the Little Chino subbasin, and the remainder is from the Big Chino subbasin. Discharge from a system of springs increases base flow to about 17 cubic feet per second within the next 2 miles of the river. Ground water that discharges at these springs is derived from the western part of the Coconino Plateau, from the Big Chino subbasin, and from the Little Chino subbasin. More...

Scientific Investigations Report↗

USGS2018

Hydrogeologic controls and geochemical indicators of groundwater movement in the Niles Cone and southern East Bay Plain groundwater subbasins, Alameda County, California

Beginning in the 1970s, Alameda County Water District began infiltrating imported water through ponds in repurposed gravel quarries at the Quarry Lakes Regional Park, in the Niles Cone groundwater subbasin, to recharge groundwater and to minimize intrusion of saline, San Francisco Bay water into freshwater aquifers. Hydraulic connection between distinct aquifers underlying Quarry Lakes allows water to recharge the upper aquifer system to depths of 400 feet below land surface, and the Deep aquifer to depths of more than 650 feet. Previous studies of the Niles Cone and southern East Bay Plain groundwater subbasins suggested that these two subbasins may be hydraulically connected. Characterization of storage capacities and hydraulic properties of the complex aquifers and the structural and stratigraphic controls on groundwater movement aids in optimal storage and recovery of recharged water and provides information on the ability of aquifers shared by different water management agencies to fulfill competing storage and extraction demands. The movement of recharge water through the Niles Cone groundwater subbasin from Quarry Lakes and the possible hydraulic connection between the Niles Cone and the southern East Bay Plain groundwater subbasins were investigated using interferometric synthetic aperture radar (InSAR), water-chemistry, and isotopic data, including tritium/helium-3, helium-4, and carbon-14 age-dating techniques. InSAR data collected during refilling of the Quarry Lakes recharge ponds show corresponding ground-surface displacement. Maximum uplift was about 0.8 inches, reasonable for elastic expansion of sedimentary materials experiencing an increase in hydraulic head that resulted from pond refilling. Sodium concentrations increase while calcium and magnesium concentrations in groundwater decrease along groundwater flowpaths from the Niles Cone groundwater subbasin through the Deep aquifer to the northwest toward the southern East Bay Plain groundwater subbasin. Residual effects of pre-1970s intrusion of saline water from San Francisco Bay, including high chloride concentrations in groundwater, are evident in parts of the Niles Cone subbasin. Noble gas recharge temperatures indicate two primary recharge sources (Quarry Lakes and Alameda Creek) in the Niles Cone groundwater subbasin. Although recharge at Quarry Lakes affects hydraulic heads as far as the transition zone between the Niles Cone and East Bay Plain groundwater subbasins (about 5 miles), the effect of recharged water on water quality is only apparent in wells near (less than 2 miles) recharge sources. Groundwater chemistry from upper aquifer system wells near Quarry Lakes showed an evaporated signal (less negative oxygen and hydrogen isotopic values) relative to surrounding groundwater and a tritium concentration (2 tritium units) consistent with recently recharged water from a surface-water impoundment. Uncorrected carbon-14 activities measured in water sampled from wells in the Niles Cone groundwater subbasin range from 16 to 100 percent modern carbon (pmC). The geochemical reaction modeling software NETPATH was used to interpret carbon-14 ages along a flowpath from Quarry Lakes toward the East Bay Plain groundwater subbasin. Model results indicate that changes in groundwater chemistry are controlled by cation exchange on clay minerals and weathering of primary silicate minerals. Old groundwater (lower carbon-14 activities) is characterized by high dissolved silica and pH. Interpreted carbon-14 ages ranged from 830 to more than 7,000 years before present and are less than helium-4 ages that range from 2,000 to greater than 11,000 years before present. The average horizontal groundwater velocity along the studied flowpath, as calculated using interpreted carbon-14 ages, through the Deep aquifer of the Niles Cone groundwater subbasin is between 3 and 12 feet per year. The groundwater velocity decreases near the boundary of the transition zone to the southern East Bay Plain groundwater subbasin to about 0.5 feet per year. These changes may result from water recharged from different sources converging in flowpaths north of the transition zone, or a boundary to flow between the Niles Cone and southern East Bay Plain groundwater subbasins, likely owing to changes in lithology caused by depositional patterns.

California↗

USGS2013

The influence of vegetation on the hydrodynamics and geomorphology of a tree island in Everglades National Park (Florida, United States)

Transpiration-driven nutrient accumulation has been identified as a potential mechanism governing the creation and maintenance of wetland vegetation patterning. This process may contribute to the formation of nutrient-rich tree islands within the expansive oligotrophic marshes of the Everglades (Florida, United States). This study presents hydrogeochemical data indicating that tree root water uptake is a primary driver of groundwater ion accumulation across one of these islands. Sap flow, soil moisture, water level, water chemistry, and rainfall were measured to identify the relationships between climate, transpiration, and groundwater uptake by phreatophytes and to examine the effect this uptake has on groundwater chemistry and mineral formation in three woody plant communities of differing elevations. During the dry season, trees relied more on groundwater for transpiration, which led to a depressed water table and the advective movement of groundwater and dissolved ions, including phosphorus, from the surrounding marsh towards the centre of the island. Ion exclusion during root water uptake led to elevated concentrations of all major dissolved ions in the tree island groundwater compared with the adjacent marsh. Groundwater was predominately supersaturated with respect to aragonite and calcite in the lower-elevation woody communities, indicating the potential for soil formation. Elevated groundwater phosphorous concentrations detected in the highest-elevation woody community were associated with the leaching of inorganic sediments (i.e. hydroxyapatite) in the vadose zone. Understanding the complex feedback mechanisms regulating plant/groundwater/surface water interactions, nutrient dynamics, and potential soil formation is necessary to manage and restore patterned wetlands such as the Everglades.

Florida↗

USGS2007

A sample-freezing drive shoe for a wire line piston core sampler

Loss of fluids and samples during retrieval of cores of saturated, noncohesive sediments results in incorrect measures of fluid distributions and an inaccurate measure of the stratigraphic position of the sample. To reduce these errors, we developed a hollow drive shoe that freezes in place the lowest 3 inches (75 mm) of a 1.88‐inch‐diameter (48 mm), 5‐foot‐long (1.5 m) sediment sample taken using a commercial wire line piston core smapler. The end of the core is frozen by piping liquid carbon dioxide at ambient temperature through a steel tube from a bottle at the land surface to the drive shoe where it evaporates and expands, cooling the interior surface of the shoe to about ‐ 109°F (‐ 78°C). Freezing a core end takes about 10 minutes. The device was used to collect samples for a study of oil‐water‐air distributions, and for studies of water chemistry and microbial activity in unconsolidated sediments at the site of an oil spill near Bemidji, Minnesota. Before freezing was employed, samples of sandy sediments from near the water table sometimes flowed out of the core barrel as the sampler was withdrawn. Freezing the bottom of the core allowed for the retention of all material that entered the core barrel and lessened the redistribution of fluids within the core. The device is useful in the unsaturated and shallow saturated zones, but does not freeze cores well at depths greater than about 20 feet (6 m) below water, possibly because the feed tube plugs with dry ice with increased exhaust back‐pressure, or because sediment enters the annulus between the core barrel and the core barrel liner and blocks the exhaust.

Ground Water Monitoring and Remediation↗

USGS2007

Selected field parameters from streams and preliminary analytical data from water and macroinvertebrate samples, Central Colorado Assessment Project, task, 2004 and 2005

The U.S. Geological Survey (USGS) Central Colorado Assessment Project (CCAP) began in October 2003 and is planned to last through September 2008. One major goal of this project is to compare the relationships between surface-water chemistry and aquatic fauna in mined and unmined areas. To accomplish this goal, we are conducting a State-scale reconnaissance sampling program, in which we are collecting water and macroinvertebrate samples. Selected results from the first two years of project analyses are reported here. We plan to develop statistical models and use geographic information system (GIS) technology to quantify the relationships between ecological indicators of metal contamination in Rocky Mountain streams and water quality, landscape and land-use characteristics (for example, mine density, geology, geomorphology, vegetation, topography). Our research will test the hypothesis that physicochemical variables and ecological responses to metal concentrations in stream water in Rocky Mountain streams are ultimately determined largely by historical land uses.

Colorado↗

USGS1987

Water-quality data-collection activities in Colorado and Ohio; Phase II, Evaluation of 1984 field and laboratory quality-assurance practices

Serious questions have been raised by Congress about the usefulness of water-quality data for addressing issues of regional and national scope and, especially, for characterizing the current quality of the Nation's streams and ground water. In response, the U.S. Geological Survey has undertaken a pilot study in Colorado and Ohio to (1) determine the characteristics of current (1984) water-quality data-collection activities of Federal, regional, State, and local agencies, and academic institutions; and (2) determine how well the data from these activities, collected for various purposes and using different procedures, can be used to improve our ability to answer major broad-scope questions, such as: A. What are (or were) natural or near-natural water-quality conditions? B. What are existing water-quality conditions? C. How has water quality changed, and how do the changes relate to human activities? Colorado and Ohio were chosen for the pilot study largely because they represent regions with different types of waterquality concerns and programs. The study has been divided into three phases, the objectives of which are: Phase I--Inventory water-quality data-collection programs, including costs, and identify those programs that met a set of broad criteria for producing data that are potentially appropriate for water-quality assessments of regional and national scope. Phase II--Evaluate the quality assurance of field and laboratory procedures used in producing the data from programs that met the broad criteria of Phase I. Phase III--Compile the qualifying data and evaluate the adequacy of this data base for addressing selected water-quality questions of regional and national scope. Water-quality data are collected by a large number of organizations for diverse purposes ranging from meeting statutory requirements to research on water chemistry. Combining these individual data bases is an appealing and potentially cost-effective way to attempt to develop a data base adequate for regional or national water-quality assessments. However, to combine data from diverse sources, field and laboratory procedures used to produce the data need to be equivalent and need to meet specific qualityassurance standards. It is these factors that are the focus of Phase II, which is described in this report. In the first phase of this study, an inventory was made of all public organizations and academic institutions that undertook water-quality data-collection activities in Colorado and Ohio in 1984. Water-quality programs identified in Phase I were tested against a set of broad screening criteria. A total of 44 waterquality programs in Colorado and 29 programs in Ohio passed the Phase-I screen and were examined in Phase II. These programs accounted for an estimated 165,000 analyses in Colorado and 76,300 analyses in Ohio for 20 selected constituents and properties. Although qualifying programs included both surface- and ground-water sampling, they emphasized surface waters and produced few groundwater analyses (3,660 for Colorado and 470 for Ohio). For Phase II, information about field and laboratory qualityassurance practices was provided by each organization and its supporting laboratories through questionnaires. This information was evaluated against a set of specific criteria for field and laboratory practices. The criteria were developed from guidelines published by public agencies and professional organizations such as the American Public Health Association, the U.Sc, Environmental Protection Agency, and the U.S. Geological Survey. Each of the eight criteria that comprise the Phase-II screen fall into one of two major categories--field practices or laboratory practices.

Colorado, Ohio↗

USGS2004

Geochemistry, radiocarbon ages, and paleorecharge conditions along a transect in the central High Plains aquifer, southwestern Kansas, USA

Water samples from short-screen monitoring wells installed along a 90-km transect in southwestern Kansas were analyzed for major ions, trace elements, isotopes (H, B, C, N, O, S, Sr), and dissolved gases (He, Ne, N 2 , Ar, O 2 , CH 4 ) to evaluate the geochemistry, radiocarbon ages, and paleorecharge conditions in the unconfined central High Plains aquifer. The primary reactions controlling water chemistry were dedolomitization, cation exchange, feldspar weathering, and O 2 reduction and denitrification. Radiocarbon ages adjusted for C mass transfers ranged from <2.6 ka ( 14 C) B.P. near the water table to 12.8 ± 0.9 ka ( 14 C) B.P. at the base of the aquifer, indicating the unconfined central High Plains aquifer contained a stratified sequence of ground water spanning Holocene time. A cross-sectional model of steady-state ground-water flow, calibrated using radiocarbon ages, is consistent with recharge rates ranging from 0.8 mm/a in areas overlain by loess to 8 mm/a in areas overlain by dune sand. Paleorecharge temperatures ranged from an average of 15.2 ± 0.7 °C for the most recently recharged waters to 11.6 ± 0.4 °C for the oldest waters. The temperature difference between Early and Late Holocene recharge was estimated to be 2.4 ± 0.7 °C, after taking into account variable recharge elevations. Nitrogen isotope data indicate NO 3 in paleorecharge (average concentration=193 μM) was derived from a relatively uniform source such as soil N, whereas NO 3 in recent recharge (average concentration=885 μM) contained N from varying proportions of fertilizer, manure, and soil N. Deep water samples contained components of N 2 derived from atmospheric, denitrification, and deep natural gas sources. Denitrification rates in the aquifer were slow (5 ± 2× 10 −3 μmol N L −1 a −1 ), indicating this process would require >10 ka to reduce the average NO 3 concentration in recent recharge to the Holocene background concentration.

Kansas↗

USGS2009

The Drenchwater deposit, Alaska: An example of a natural low pH environment resulting from weathering of an undisturbed shale-hosted Zn-Pb-Ag deposit

The Drenchwater shale-hosted Zn-Pb-Ag deposit and the immediate vicinity, on the northern flank of the Brooks Range in north-central Alaska, is an ideal example of a naturally low pH system. The two drainages, Drenchwater and False Wager Creeks, which bound the deposit, differ in their acidity and metal contents. Moderately acidic waters with elevated concentrations of metals (pH ??? 4.3, Zn ??? 1400 ??g/L) in the Drenchwater Creek drainage basin are attributed to weathering of an exposed base-metal-rich massive sulfide occurrence. Stream sediment and water chemistry data collected from False Wager Creek suggest that an unexposed base-metal sulfide occurrence may account for the lower pH (2.7-3.1) and very metal-rich waters (up to 2600 ??g/L Zn, ??? 260 ??g/L Cu and ???89 ??g/L Tl) collected at least 2 km upstream of known mineralized exposures. These more acidic conditions produce jarosite, schwertmannite and Fe-hydroxides commonly associated with acid-mine drainage. The high metal concentrations in some water samples from both streams naturally exceed Alaska state regulatory limits for freshwater aquatic life, affirming the importance of establishing base-line conditions in the event of human land development. The studies at the Drenchwater deposit demonstrate that poor water quality can be generated through entirely natural weathering of base-metal occurrences, and, possibly unmineralized black shale.

Applied Geochemistry↗

USGS1995

Distribution of phytobenthos in the Yakima River basin, Washington, in relation to geology, land use and other environmental factors

Benthic-algal distributions in the Yakima River, Washington, basin were, examined in relation to geology, land use, water chemistry, and stream habitat using indicator-species classification ( TWINSPAN ) and canonical correspondence analysis (CCA). Algal assemblages identified by TWINSPAN were each associated with a narrow range of water-quality conditions. In the Cascade geologic province, where timber harvest and grazing are the dominant land uses, differences in community structure (CCA site scores) and concentrations of major ions (Ca and Mg) and nutrients (solute P, SiO 2 and inorganic N) varied with dominant rock type of the basin. In agricultural areas of the Columbia Plateau province, differences in phytobenthos structure were based primarily on the degree of enrichment of dissolved solids, inorganic N, and solute P from irrigation-return flows and subsurface drainage. Habitat characteristics strongly correlated with community structure included reach altitude, turbidity, substratum embeddedness (Columbia Plateau), large woody-debris density (Cascade Range), and composition and density of the riparian vegetation. Algal biomass (AFDM) correlated with composition and density of the riparian vegetation but not with measured chemical-constituent concentrations. Nitrogen limitation in streams of the Cascade Range favored nitrogen-fixing blue-green algae and diatoms with endosymbiotic blue-greens, whereas nitrogen heterotrophs were abundant in agricultural areas of the Columbia Plateau.

Canadian Journal of Fisheries and Aquatic Sciences↗

USGS2017

Groundwater quality for 75 domestic wells in Lycoming County, Pennsylvania, 2014

Groundwater is a major source of drinking water in Lycoming County and adjacent counties in north-central and northeastern Pennsylvania, which are largely forested and rural and are currently undergoing development for hydrocarbon gases. Water-quality data are needed for assessing the natural characteristics of the groundwater resource and the potential effects from energy and mineral extraction, timber harvesting, agriculture, sewage and septic systems, and other human influences. This report, prepared in cooperation with Lycoming County, presents analytical data for groundwater samples from 75 domestic wells sampled throughout Lycoming County in June, July, and August 2014. The samples were collected using existing pumps and plumbing prior to any treatment and analyzed for physical and chemical characteristics, including nutrients, major ions, metals and trace elements, volatile organic compounds, gross-alpha particle and gross beta-particle activity, uranium, and dissolved gases, including methane and radon-222. Results indicate groundwater quality generally met most drinking-water standards, but that some samples exceeded primary or secondary maximum contaminant levels (MCLs) for arsenic, iron, manganese, total dissolved solids (TDS), chloride, pH, bacteria, or radon-222. Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 9 of the 75 (12 percent) well-water samples, with concentrations as high as 23.6 μg/L; arsenic concentrations were higher than the health advisory level (HAL) of 2 μg/L in 23 samples (31 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 μg/L in 20 of the 75 samples. Total manganese concentrations exceeded the SMCL of 50 μg/L in 20 samples and the HAL of 300 μg/L in 2 of those samples. Three samples had chloride concentrations that exceeded the SMCL of 250 milligrams per liter (mg/L); two of those samples exceeded the SMCL of 500 mg/L for TDS. The pH ranged from 5.3 to 9.15 and did not meet the SMCL range of 6.5 to 8.5 in 22 samples, with 17 samples having a pH less than 6.5 and 8 samples having pH greater than 8.5. Generally, the samples that had elevated TDS, chloride, or arsenic concentrations had high pH. Total coliform bacteria were detected in 39 of 75 samples (52 percent), with Escherichia coli detected in 10 of those 39 samples. Radon-222 activities ranged from non-detect to 7,420 picocuries per liter (pCi/L), with a median of 863 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 50 (67 percent) of the 75 samples; radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 3 samples. Water from 15 of 75 (20 percent) wells had concentrations of methane greater than the reporting level of 0.01 mg/L; detectable methane concentrations ranged from 0.04 to 16.8 mg/L. Two samples had methane concentrations (13.1 and 16.8 mg/L) exceeding the action level of 7 mg/L. Low levels of ethane (up to 0.12 mg/L) were present in the five samples with the highest methane concentrations (near or above 1 mg/L) that were analyzed for hydrocarbon compounds and isotopic composition. The isotopic composition of methane in four of these groundwater samples, from the Catskill and Lock Haven Formations and the Hamilton Group, have sample carbon isotopic ratio delta values (carbon-13/carbon-12) ranging from –42.36 to –36.08 parts per thousand (‰) and hydrogen isotopic ratio delta values (deuterium/protium) ranging from –212.0 to –188.4 ‰, which are consistent with the isotopic compositions reported for mud-gas logging samples from these geologic units and a thermogenic source of the methane. However, the isotopic composition and ratios of methane to ethane in a fifth sample indicate the methane in that sample may be of microbial origin that subsequently underwent oxidation. The fifth sample had the highest concentration of methane, 16.8 mg/L, with an carbon isotopic ratio delta values of -50.59 ‰ and a hydrogen isotopic ratio delta values of -209.7 ‰. The six well-water samples with the highest methane concentrations also had among the highest pH values (8.25 to 9.15) and elevated concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Three of the six groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported at undetermined depth below the freshwater aquifer and for gas and oil well brines in Pennsylvania. The sample with the highest methane concentration and most other samples with low methane concentrations (less than about 1 mg/L) have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt, septic systems, and (or) animal waste. Brines that are naturally present may originate from deeper parts of the aquifer system, while anthropogenic sources are more likely to affect shallow groundwater because they occur on or near the land-surface. The spatial distribution of groundwater compositions generally indicate that (1) uplands along the western border of Lycoming County usually have dilute, slightly acidic oxygenated, calcium-bicarbonate type waters; (2) intermediate altitudes or areas of carbonate bedrock usually have water of near neutral pH, with highest amounts of hardness (calcium and magnesium); (3) stream valleys, low elevations where groundwater may be discharging, and deep wells in uplands usually have water with pH values greater than 8 and highest arsenic, sodium, lithium, bromide concentrations. Geochemical modeling indicated that for samples with elevated pH, sodium, lithium, bromide, and alkalinity, the water chemistry could have resulted by dissolution of calcite (calcium carbonate) combined with cation-exchange and mixing with a small amount of brine. Through cation-exchange reactions between water and bedrock, which are equivalent to processes in a water softener, calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. Thus, the assessment of groundwater quality in Lycoming County indicates groundwater is generally of good quality, but various parts of Lycoming County can have groundwater with low to moderate concentrations of methane and other constituents that appear in naturally present brine and produced waters from gas and oil wells at high concentrations."

Pennsylvania↗

USGS2009

Geochemistry of surface water in alpine catchments in central Colorado, USA: Resolving host-rock effects at different spatial scales

The US Geological Survey is conducting a study of surface-water quality in the Rocky Mountains of central Colorado, an area of approximately 55,000 km 2 . Using new and existing geologic maps, the more than 200 rock formations represented in the area were arranged into 17 groups based on lithologic similarity. The dominant regional geologic feature affecting water quality in central Colorado is the Colorado mineral belt (CMB), a NE-trending zone hosting many polymetallic vein or replacement deposits, and porphyry Mo deposits, many of which have been mined historically. The influence of the CMB is seen in lower surface-water pH (<5), and higher concentrations of SO 4 2 - (>100 mg/L) and chalcophile metals such as Cu (>10 ??g/L), Zn (>100 ??g/L), and Cd (>1 ??g/L) relative to surface water outside the CMB. Not all streams within the CMB have been affected by mineralization, as there are numerous catchments within the CMB that have no mineralization or alteration exposed at the surface. At the regional-scale, and away from sites affected by mineralization, hydrothermal alteration, or mining, the effects of lithology on water quality can be distinguished using geochemical reaction modeling and principal components analysis. At local scales (100 s of km 2 ), effects of individual rock units on water chemistry are subtle but discernible, as shown by variations in concentrations of major lithophile elements or ratios between them. These results demonstrate the usefulness of regional geochemical sampling of surface waters and process-based interpretations incorporating geologic and geochemical understanding to establish geochemical baselines.

Applied Geochemistry↗

USGS2008

Framework for Evaluating Water Quality of the New England Crystalline Rock Aquifers

Little information exists on regional ground-water-quality patterns for the New England crystalline rock aquifers (NECRA). A systematic approach to facilitate regional evaluation is needed for several reasons. First, the NECRA are vulnerable to anthropogenic and natural contaminants such as methyl tert-butyl ether (MTBE), arsenic, and radon gas. Second, the physical characteristics of the aquifers, termed 'intrinsic susceptibility', can lead to variable and degraded water quality. A framework approach for characterizing the aquifer region into areas of similar hydrogeology is described in this report and is based on hypothesized relevant physical features and chemical conditions (collectively termed 'variables') that affect regional patterns of ground-water quality. A framework for comparison of water quality across the NECRA consists of a group of spatial variables related to aquifer properties, hydrologic conditions, and contaminant sources. These spatial variables are grouped under four general categories (features) that can be mapped across the aquifers: (1) geologic, (2) hydrophysiographic, (3) land-use land-cover, and (4) geochemical. On a regional scale, these variables represent indicators of natural and anthropogenic sources of contaminants, as well as generalized physical and chemical characteristics of the aquifer system that influence ground-water chemistry and flow. These variables can be used in varying combinations (depending on the contaminant) to categorize the aquifer into areas of similar hydrogeologic characteristics to evaluate variation in regional water quality through statistical testing.

Open-File Report↗

USGS2015

Results of mineral, chemical, and sulfate isotopic analyses of water, soil, rocks, and soil extracts from the Pariette Draw Watershed, Uinta Basin, Utah

In 2010, Utah Department of Environmental Quality (DEQ) Division of Water Quality (UDWQ, 2010) determined that water quality in Pariette Draw was in violation of Federal and State water quality criteria for total dissolved solids (TDS), selenium (Se), and boron (B). The measure of total dissolved solids is the sum of all the major ion concentrations in solution and in this case, the dominant ions are sodium (Na) and sulfate (SO4), which can form salts like thenardite (Na2SO4) and mirabilite (Na2SO4⋅H2O). The Utah Department of Environmental Quality (2010) classified the contamination as natural background and from nonpoint sources related to regional lithology and irrigation practices. Although the daily loads of the constituents of concern and water chemistry have been characterized for parts of the watershed, little is known about the controls that bedrock and soil mineralogy have on salt, Se, and B storage and the water-rock interactions that influence the mobility of these components in ground and surface waters. Studies in the Uncompahgre River watershed in Colorado by Tuttle and others (2014a, 2014b) show that salt derived from weathering of shale in a semiarid climate is stored in a variety of minerals that contribute solutes to runoff and surface waters based on a complex set of conditions such as water availability, geomorphic position (for example, topography controls the depth of salt accumulation in soils), water-table fluctuations, redox conditions, mineral dissolution kinetics, ion-exchange reactions, and secondary mineral formation. Elements like Se and B commonly reside in soluble salt phases, so knowledge of the behavior of salt minerals also sheds light on the behavior of associated contaminants. The goal of this study was to establish a process-based understanding of salt, Se, and B behavior to address whether these contaminants can be better managed, or if uncontrollable natural processes will overwhelm any attempts to bring Pariette Draw into compliance with respect to recently established total maximum daily limits (TMDLs). We collected data to refine our knowledge about the role of rock weathering and soil formation in the transport and storage of salt in the watershed and to show how salt is cycled under irrigated and natural conditions. Our approach was to sample rock, soils, and sediment on irrigated and natural terrain for mineralogical analysis to determine the residence of salt and associated Se and B, classify minerals as primary (related to rock formation) or secondary weathering products, and characterize mineral dissolution kinetics. Mineral and chemical analyses and selective extractions of rocks and soils provide useful information in understanding solute movement and mineral dissolution/ formation. The resulting data are critical in determining residence of salt, Se, and B in weathered rock and soil and understanding the mobility during water-rock-soil interactions. This report summarizes our methods for sample and data collection and tabulates the mineral, chemical, and isotopic data collected.

Utah↗