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Use of airborne and terrestrial lidar to detect ground displacement hazards to water systems

We investigate the use of multiepoch airborne and terrestrial lidar to detect and measure ground displacements of sufficient magnitude to damage buried pipelines and other water system facilities that might result, for example, from earthquake or rainfall-induced landslides. Lidar scans are performed at three sites with coincident measurements by total station surveying. Relative horizontal accuracy is evaluated by measurements of lateral dimensions of well defined objects such as buildings and tanks; we find misfits ranging from approximately 5 to 12 cm, which is consistent with previous work. The bias and dispersion of lidar elevation measurements, relative to total station surveying, is assessed at two sites: (1) a power plant site (PP2) with vegetated steeply sloping terrain; and (2) a relatively flat and unvegetated site before and after trenching operations were performed. At PP2, airborne lidar showed minimal elevation bias and a standard deviation of approximately 70 cm, whereas terrestrial lidar did not produce useful results due to beam divergence issues and inadequate sampling of the study region. At the trench site, airborne lidar showed minimal elevation bias and reduced standard deviation relative to PP2 (6-20 cm), whereas terrestrial lidar was nearly unbiased with very low dispersion (4-6 cm). Pre- and posttrench bias-adjusted normalized residuals showed minimal to negligible correlation, but elevation change was affected by relative bias between epochs. The mean of elevation change bias essentially matches the difference in means of pre- and posttrench elevation bias, whereas elevation change standard deviation is sensitive to the dispersion of individual epoch elevations and their correlation coefficient. The observed lidar bias and standard deviations enable reliable detection of damaging ground displacements for some pipelines types (e.g., welded steel) but not all (e.g., concrete with unwelded, mortared joints). ?? ASCE 2009.

Journal of Surveying Engineering

Drones and bathymetry show the importance of optimal water depth for nest placement within breeding colonies of Western and Clark’s grebes

Habitat selection involves a series of decisions that are arguably the most important decisions that animals make and these decisions occur at multiple hierarchical spatial scales. Colonial-nesting birds face a unique challenge when selecting a nest site because each bird’s choices are severely constrained by other birds within their breeding colony. Individuals must seek out optimum nesting locations within the constraint of the colony’s geographic location. We investigated how water depth and proximity to open water affected 4th-order nest-site selection of Western and Clark’s Grebes ( Aechmophorus occidentalis, Aechmophorus clarkii ), colonial nesting waterbirds that have declined in abundance across their range. We used an orthomosiac that we created from ~ 500 aerial drone images of a large breeding colony to construct a Resource Selection Function to describe microhabitat features that influence nest-site placement within the colony footprint. Grebes preferred to nest in portions of the colony with intermediate water depths (40-80 cm during nest construction) and they preferred to nest in portions of the colony furthest from open water. Understanding how individual birds make use of available microhabitat features within the footprint of their breeding colony can help inform conservation efforts of colonial-nesting birds, particularly for species that nest in wetland habitats whose water levels are managed for human use.

Idaho

Tire-derived contaminants 6PPD and 6PPD-Q: Analysis, sample handling, and reconnaissance of United States stream exposures

The environmental ubiquity of tire and road wear particles (TRWP) underscores the need to understand the occurrence, persistence, and environmental effects of tire-related chemicals in aquatic ecosystems. One such chemical is 6PPD-quinone (6PPD-Q), a transformation product of the tire antioxidant 6PPD. In urban stormwater runoff 6PPD-Q can exceed acute toxicity thresholds for several salmonid species and is being implicated in significant coho salmon losses in the Pacific Northwest. There is a critical need to understand the prevalence of 6PPD-Q across watersheds to identify habitats heavily affected by TRWPs. We conducted a reconnaissance of 6PPD and 6PPD-Q in surface waters across the United States from sites (N = 94) with varying land use (urban, agricultural, and forested) and streamflow to better understand stream exposures. A rapid, low-volume direct-inject, liquid chromatography mass spectrometry method was developed for the quantitation of 6PPD-Q and screening for 6PPD. Laboratory holding times, bottle material, headspace, and filter materials were investigated to inform best practices for 6PPD-Q sampling and analysis. Glass bottles with PTFE-lined caps minimized sorption and borosilicate glass fiber filters provided the highest recovery. 6PPD-Q was stable for at least 5 months in pure laboratory solutions and for 75 days at 5 °C with minimal headspace in the investigated surface water and stormwaters. Results also indicated samples can be frozen to extend holding times. 6PPD was not detected in any of the 526 analyzed samples and there were no detections of 6PPD-Q at agricultural or forested sites. 6PPD-Q was frequently detected in stormwater (57%, N = 90) and from urban impacted sites (45%, N = 276) with concentrations ranging from 0.002 to 0.29 μg/L. The highest concentrations, above the lethal level for coho salmon, occurred during stormwater runoff events. This highlights the importance of capturing episodic runoff events in urban areas near ecologically relevant habitat or nursery grounds for sensitive species.

Chemosphere

Acute toxicity of runoff from sealcoated pavement to Ceriodaphnia dubia and Pimephales promelas

Runoff from coal-tar-based (CT) sealcoated pavement is a source of polycyclic aromatic hydrocarbons (PAHs) and N -heterocycles to surface waters. We investigated acute toxicity of simulated runoff collected from 5 h to 111 days after application of CT sealcoat and from 4 h to 36 days after application of asphalt-based sealcoat containing about 7% CT sealcoat (AS/CT-blend). Ceriodaphnia dubia (cladocerans) and Pimephales promelas (fathead minnows) were exposed in the laboratory to undiluted and 1:10 diluted runoff for 48 h, then transferred to control water and exposed to 4 h of ultraviolet radiation (UVR). Mortality following exposure to undiluted runoff from unsealed asphalt pavement and UVR was ≤10% in all treatments. Test organisms exposed to undiluted CT runoff samples collected during the 3 days ( C. dubia ) or 36 days ( P. promelas ) following sealcoat application experienced 100% mortality prior to UVR exposure; with UVR exposure, mortality was 100% for runoff collected across the entire sampling period. Phototoxic-equivalent PAH concentrations and mortality demonstrated an exposure-response relation. The results indicate that runoff remains acutely toxic for weeks to months after CT sealcoat application.

Environmental Science & Technology

Water quality in the Allegheny and Monongahela River basins, Pennsylvania, West Virginia, New York, and Maryland, 1996-98

Major influences and findings for ground water quality, surface water quality, and biology in the Allegheny and Monongahela River basins are described and illustrated. Samples were collected in a variety of media to determine trace elements, sulfate, pesticides, nitrate, volatile organic compounds, organochlorine compounds, and radon-222. This report discusses the influences of several land-use practices, such as coal mining, urbanization, agriculture, and forestry. The report also includes a summary of a regional investigation of water quality and quality invertebrates in the Northern and Central Appalachian coal regions.

Maryland, New York, Pennsylvania, West Virginia

Linking hyporheic flow and nitrogen cycling near the Willamette River: A large river in Oregon, USA

Several approaches were used to characterize ground water/surface water interactions near the Willamette River - A large (ninth order) river in Oregon, USA. A series of potentiometric surface maps demonstrated the presence of highly dynamic hydraulic gradients between rivers and the adjacent aquifer. Hyporheic zone gradients extended on the order of hundreds of meters. River gains and losses at the river stretch scale (tens of kilometers) were consistent with fluxes implied by the potentiometric surface maps, and apparently reflect regional ground water/surface water interactions. Gains and losses of up to 5-10% of streamflow were observed at this scale. On the river reach scale (1-2 km), gains and losses on the order of 5% of streamflow were interpreted as representing primarily local hyporheic exchange. Isotopic and chemical data collected from shallow hyporheic zone wells demonstrated interaction between regional ground water and river water. The origin of sampled hyporheic zone water ranged from a mixture dominated by regional ground water to water containing 100% river water. The common assumption that ground and river water mix primarily in the river channel is not applicable in this system. Isotopic and chemical data also indicated that significant (nearly complete) vegetative nitrate uptake and/or nitrate reduction occurred in water from 4 of 12 hyporheic zone sites. In these cases, it was primarily nitrate transported to the hyporheic zone in regional ground water that was removed from solution. Isotopes of water and nitrate indicated that hyporheic zone water sampled at two sites was composed of water originating as river water and demonstrated that significant vegetative nitrate uptake and nitrate reduction occurred along these hyporheic zone flowpaths. Thus, the hyporheic zone may, in some instances, serve to remove nitrate from river water. Additional investigations with chemical tools and microbial enzyme assays were conducted at one hyporheic site. A strong vertical redox gradient was observed, with nitrate-limited denitrification potential in deeper sediment and both nitrification and denitrification potential in shallower sediment. Since nitrogen cycling is strongly affected by redox conditions, nitrogen cycling in the hyporheic zone of this large-river system likely is affected by dynamics of ground water/surface water interactions that control fluxes of nitrogen and other redox species to hyporheic zone sediment.

Oregon

Simulation of future streamflow and irrigation demand based on climate and urban growth projections in the Cape Fear and Pee Dee River Basins, North Carolina and South Carolina, 2055–65

Water resources in the coastal region of North Carolina and South Carolina (Coastal Carolinas) are currently under stress from competing ecological and societal needs. Projected changes in climate and population are expected to place even more stress on water resources in the region. The Coastal Carolinas Focus Area Study was initiated by the U.S. Geological Survey Water Availability and Use Science Program’s National Water Census to investigate these stressors and their effects on water resources for the Coastal Carolinas. As part of that study, the Soil and Water Assessment Tool (SWAT) model was used to investigate future streamflow and irrigation demand under six scenarios for the Cape Fear and Pee Dee River Basins, which flow through the Coastal Carolinas and into the Atlantic Ocean. For each river basin, historical (2000 through 2014) Soil and Water Assessment Tool models were minimally calibrated, and future (2055 through 2065) scenario models were developed based on three alternative global climate models, two alternative urban growth projections, and water-use projections that correspond to each global climate model and urban growth projection pair. The river basins were delineated into 2,928 and 5,678 subbasins for the Cape Fear and Pee Dee, respectively, each approximately 2.6 square miles (mi 2 ) in size. The best available water-use and wastewater discharge data were used for historical model calibration. The models simulated monthly mean streamflow with median Nash-Sutcliffe efficiency values of 0.53 (n = 36) and 0.61 (n = 33) in the Cape Fear and Pee Dee River Basins, respectively. Average percent bias was −4.8 percent for the Cape Fear River Basin and −1.2 percent for the Pee Dee River Basin. Catchments for streamgages chosen for model calibration that were small (less than 100 mi 2 ) to medium (100–1,000 mi 2 ) in area tended to perform better than larger catchments (greater than 1,000 mi 2 ). Historical models were used to develop future model scenarios by replacing historical weather, land-use, and water-use input datasets with projected datasets. One small, gaged catchment was selected to illustrate how the models can be used to evaluate the relative differences in simulated streamflow resulting from alternative global climate models and urban growth projections. For the selected catchment, future climate projections had a much greater influence on simulated streamflow than urban growth projections. Simulated cumulative monthly mean streamflow results for this catchment differed by 26 percent under alternative global climate models and differed by 2.4 percent under alternative urban growth projections. Irrigation demand was modeled for subbasins with cropland. Simulated differences in irrigation demand were more pronounced and widespread across the model domain under the alternative future climate scenarios compared to alternative urban growth scenarios. The calibrated and future scenario models have the capability to run on a daily time step and simulate streamflow and irrigation demand for thousands of small subbasins in the Cape Fear and Pee Dee River Basins. The models and underlying datasets enable future analyses for large and small areas within the basins.

North Carolina, South Carolina

Estimated rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas

During 1989-90, the U.S. Geological Survey (USGS), in cooperation with the Harris-Galveston Coastal Subsidence District, conducted a field study to determine the depth to the water table and to estimate the rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas. The study area (fig. 1) comprises about 2,000 square miles of outcrops of the Chicot and Evangeline aquifers in northwestern Harris County, Montgomery County, and southern Walker County. The depth to the water table was estimated using seismic refraction, and an estimated rate of recharge in the aquifer outcrops was computed using the tritium-interface method (Andres and Egger, 1985) in which environmental tritium is the ground-water tracer. The water table generally ranges in depth between 10 and 30 feet in the study area, and the average total recharge rate was estimated to be not larger than 6 inches per year. The rate is total recharge to the saturated zone, rather than net recharge to the deep regional flow system. The total recharge can be reduced by evapotranspiration and by local discharge, mainly to streams. These results are published in USGS Water-Resources Investigations Report 96-4018 (Noble and others, 1996). A second study of environmental tritium in the same area as the 1989-90 study, also in cooperation with the Harris-Galveston Coastal Subsidence District, was done in 1996 to confirm the results of the original study. This fact sheet documents the estimation of an upper limit on the average total recharge rate on the basis of the vertical movement of tritium in ground water during 1953-89 and during 1953-95.

Fact Sheet

Feasibility of using portable, noninvasive pipe flowmeters and time totalizers for determining water use

The feasibilityty of using noninvasive flowmeters for determining water use was investigated by attempting, and at some sites repeating, instantaneous pipe-flow measurements at 45 water-withdrawal sites by use of four portable noninvasive pipe flowmeters. The flowmeters measure flow in pipes; this flow is related to water use. Because actual water use can differ from the total flow in the pipe, water use is not, in itself, measured by the flowmeters. The transit-time flowmeter successfully measured flow on 81 of 88 measurement attempts. The time-of-flight flowmeter successfully measured flow on 85 of 93 measurement attempts. One reflective-doppler flowmeter successfully measured flow on 71 of 75 measurement attempts. Another type of reflective-doppler flowmeter, which required air bubbles or paniculate matter in the flow, successfully measured flow on 19 of 92 measurement attempts. Flows at most water-withdrawal sites selected for this study did not include paniculate matter. At 10 site visits where inline flowmeter measurements were available for comparison and where three of the four selected portable flowmeters were successful, the transit-time flowmeter measurements had a mean log-percent difference from the inline measurements of 2.8 and a standard deviation of 3.7. The time-of-flight flowmeter measurements had a mean log-percent difference of 7.5 and a standard deviation of 7.6. The reflective-doppler flowmeter measurements had a mean log-percent difference of -14 and a standard deviation of 18. The feasibility of using time totalizers for determining water use was investigated by observing seven vibration time totalizers (VTT's) mounted at five sites. None of the units exhibited adverse effects from the heat, precipitation, or humidity associated with Indiana summers. One VTT was mounted at a public water-supply site where inductive time-totalizer measurements were available for comparison. The VTT agreed within 8 hours of the inductive time totalizer after 2,340 hours of pump operation. There were no mechanical prpblems with the VTT units used in this study.

Indiana

Evapotranspiration and canopy resistance at an undeveloped prairie in a humid subtropical climate

Reliable estimates of evapotranspiration from areas of wildland vegetation are needed for many types of water-resource investigations. However, little is known about surface fluxes from many areally important vegetation types, and relatively few comparisons have been made to examine how well evapotranspiration models can predict evapotranspiration for soil-, climate-, or vegetation-types that differ from those under which the models have been calibrated. In this investigation at a prairie site in west-central Florida, latent heat flux (λ E ) computed from the energy balance and alternatively by eddy covariance during a 15-month period differed by 4 percent and 7 percent on hourly and daily time scales, respectively. Annual evapotranspiration computed from the energy balance and by eddy covariance were 978 and 944 mm, respectively. An hourly Penman-Monteith (PM) evapotranspiration model with stomatal control predicated on water-vapor-pressure deficit at canopy level, incoming solar radiation intensity, and soil water deficit was developed and calibrated using surface fluxes from eddy covariance. Model-predicted λ E agreed closely with λ E computed from the energy balance except when moisture from dew or precipitation covered vegetation surfaces. Finally, an hourly PM model developed for an Amazonian pasture predicted λ E for the Florida prairie with unexpected reliability. Additional comparisons of PM-type models that have been developed for differing types of short vegetation could aid in assessing interchangeability of such models.

Florida

Use of soil leachates to define the extent of brine-contaminated soils at the USGS petroleum environmental research site "B", Osage County, northeastern Oklahoma

Soils at an active oil production site with a history of surface releases of produced water were investigated to determine the chemical signature of salt contamination and the spatial distribution of soil salinity in relation to areas of obvious salt scarring. Grab samples of shallow soil (0-15 cm) and selected soil profiles to depths of 0.6 to 1.7 m were collected onsite and offsite using a 5-cm diameter stainless steel soil auger. Air dried and disaggregated soil from 15 cm intervals (100 g) was mixed with 100 ml of distilled-deionized water to dissolve readily soluble salts. After 24 hours the water was separated by centrifugation followed by filtration through a 0.45 micrometer membrane. Specific conductance was measured immediately. Dissolved chloride (Cl) and sulfate (SO4) were initially estimated with Cl titration strips and turbidimetric measurements respectively. More accurate measurements of dissolved Cl, SO4, and bromide (Br) were later performed by ion chromatography. Brine-contaminated soil was indicated by (1) unusually elevated Cl concentrations or relatively low ratios of conductance/Cl in aqueous leachates compared to leachates of uncontaminated soils, and (2) ratios of Cl/Br in leachates (250± 30) that fall within the range of Cl/Br ratios measured in local produced waters (220-320). Leachates of background soils from the area were characterized by low conductance (sandy soils) or dissolved solids dominated by sulfates (shaley soils). At the study site, the surface (0-15 cm) distribution of elevated soil salinity was largely confined to areas of obvious salt scarring. Within the area of salt scars, elevated salinity persisted to depths of refusal by manual augering. The technique will be applied to deeper samples obtained by mechanical augering or direct push techniques.

Oklahoma

Assessment of physical, chemical, and hydrologic factors affecting the infiltration of treated wastewater in the New Jersey Coastal Plain, with emphasis on the Hammonton Land Application Facility

A hydrogeologic and water-quality investigation of the Hammonton Land Application Facility (Hammonton LAF) in Hammonton, New Jersey, was conducted to determine the factors that impede the infiltration of treated wastewater and to assess the potential for similar conditions to exist elsewhere in the Coastal Plain of New Jersey (particularly within the Pinelands National Reserve). Gamma logs, sediment cores, and hydraulic-profile testing indicate that extensive fine-grained strata and iron-cemented sands underlying the Hammonton LAF may impede infiltration and lead to the perching of diluted treated wastewater. Perched water was observed in augured holes adjacent to infiltration trenches, and analysis of wastewater loading and infiltration data indicates that infiltration trenches may receive lateral flow from multiple perched-water sources. Analysis of water-quality properties characteristic of treated wastewater show that although infiltrated wastewater is reaching the underlying aquifer, lengthy holding times and a long recharge pathway greatly reduce the concentrations of nitrate, boron, and many organic compounds typical of wastewater. Conditions at two currently operating facilities and one potential future facility in the New Jersey Coastal Plain were compared to those at the Hammonton Land Application Facility (LAF). Facilities operating as designed are not underlain by the restrictive strata that exist at the Hammonton LAF. Careful characterization of the geology and hydrology of the unsaturated zone underlying infiltration structures of future facilities in the New Jersey Coastal Plain and similar hydrogeologic settings will help to avoid constructing infiltration structures over or within low-hydraulic-conductivity strata that will decrease infiltration rates.

New Jersey

Water resources activities in Kentucky, 1993-94

The U.S. Geological Survey (USGS) is the principal Federal water-resources data collection and investigation agency. Through the Water Resources Division District Office in Kentucky, the USGS investigates the occurrence, distribution, quantity, movement, and chemical and biological quality of surface and ground water in the State. The mission of this program is to collect, interpret, and publish information on water resources. Almost all research and data collection is a cooperative effort in which planning and financial support are shared by State and local agencies and governments. Other activities are funded by other Federal agencies or by direct Congressional appropriation. This report is intended to inform the public and cooperating agencies, vitally interested in the water resources of Kentucky, as to the current status of the Distfict's data collection and investigation program. Included in the report are summaries of water-resources activities in Kentucky conducted by the USGS. Also included is a description of the USGS mission and program, District organization, funding sources and cooperating agencies, and a list of USGS publications relevant to the water resources of the State.

Open-File Report

Integrated assessment of wastewater reuse, exposure risk, and fish endocrine disruption in the Shenandoah River watershed

Reuse of municipal and industrial wastewater treatment plant (WWTP) effluent is an important component in augmenting global freshwater supplies. The Shenandoah River Watershed was selected to conduct on-site exposure experiments to assess endocrine disrupting characteristics of different source waters. This investigation of the Shenandoah River Watershed integrates WWTP wastewater reuse modeling, hydrological and chemical characterization, and in vivo endocrine disruption bioassessment to assess contaminant sources, exposure pathways, and biological effects. The percentage of accumulated WWTP effluent in each river reach (ACCWW) was used to predict environmental concentrations for consumer product chemicals (boron), pharmaceutical compounds (carbamazepine), and steroidal estrogens (estrone, 17-beta-estradiol, estriol, and 17-alpha-ethinylestradiol). Fish endocrine disruption was evaluated using vitellogenin induction in male or juvenile fathead minnows. Water samples were analyzed for >500 inorganic and organic constituents to characterize the complex contaminant mixtures. Municipal ACCWW at drinking water treatment plant surface-water intakes ranged from <0.01 to 2.1 % under mean-annual streamflow and up to 4.7 % under August streamflow. Measured and predicted environmental concentrations resulted in 17-beta-estradiol equivalency quotients ranging from <0.05 to 5.1 ng L-1 indicating low-to-moderate risk of fish endocrine disruption. Results from the fish exposure experiments also showed limited estrogenic effects as indicated by the low (0.5- to 3.2-fold) vitellogenin induction.

Shenandoah River watershed

Geohydrology and water quality of Cenozoic and Mesozoic units in southeast Missouri

The U.S. Geological Survey is conducting a regional water-resources investigation of the Gulf Coast Regional Aquifer System, which includes the Mississippi embayment aquifer system in the southeast lowlands of Missouri (Grubb, 1986). The regional study will describe and evaluate the significant aquifer systems of Tertiary and younger age in parts of 10 States (Grubb, 1984). Paleozoic, Mesozoic, and Cenozoic geologic units in southeast Missouri have been described and mapped to define the aquifers of the area (Mesko, in press). This report describes aquifers in unconsolidated sediments of Cenozoic and Mesozoic age of southeast Missouri and presents geohydrologic and water-quality information collected during the study. The southeast lowlands of Missouri is underlain by a multiaquifer ground-water system consisting of unconsolidated and consolidated sediment (table 1, sheet 2). Unconsolidated aquifers, from youngest to oldest, are the Mississippi River Valley alluvial aquifer, Claiborne and Wilcox aquifers (Cenozoic age), and the McNairy aquifer (Mesozoic age). Numerous geologic formations that primarily consist of sand and clay comprise these units. Consolidated aquifers underlying the region are the Ozark and St. Francois aquifers (Paleozoic age). These aquifers in Paleozoic rocks occur at greater depth and produce saline quality water (except near the margin of the embayment), and are not discussed in detail in this report.

Hydrologic Atlas

U.S. Geological Survey; North Carolina's water resources; a partnership with State, Federal and local agencies

For more than 80 years, the Federal-State Cooperative Program in North Carolina has been an effective partnership that provides timely water information for all levels of government. The cooperative program has raised awareness of State and local water problems and issues and has enhanced transfer and exchange of scientific information. The U.S. Geological Survey (USGS) conducts statewide water-resources investigations in North Carolina that include hydrologic data collection, applied research studies, and other interpretive studies. These programs are funded through cooperative agreements with the North Carolina Departments of Environment, Health, and Natural Resources; Human Resources; and Transportation, as well as more than a dozen city and county governmental agencies. The USGS also conducts special studies and data-collection programs for Federal agencies, including the Department of Defense, the U.S. Soil Conservation Service, the Tennessee Valley Authority, and the U.S. Environmental Protection Agency that contribute to North Carolina's water information data base. Highlights of selected programs are presented to show the scope of USGS activities in North Carolina and their usefulness in addressing water-resource problems. The reviewed programs include the statewide data-collection program, estuarine studies, the National Water-Quality Assessment program, military installation restoration program, and groundwater flow model-development program in the Coastal Plain and Piedmont provinces.

North Carolina

Water resources data for Arizona, water year 1978

Water resources data for the 1978 water year for Arizona consist of records of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes and reservoirs; water levels of observation wells; and quality of ground water. This report contains discharge records for 241 gaging stations, annual peaks for 77 crest-stage partial-record stations, and discharge measurements at 58 miscellaneous sites; contents only records for 9 lakes and reservoirs; stage and contents for 1 lake; elevations only for 2 lakes or reservoirs; gage height only for 1 lake and 1 head over a dam; 16 supplementary records, included with gaging-station records, consisting of month end or monthly stage, contents, and evaporation of lakes and reservoirs, diversions, and return flows; 2 low-flow investigations; water-quality records for 87 continuous record stations and 16 miscellaneous sites; water levels for 101 observation wells; and water-quality data for water from 189 wells. The data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal and State Agencies in Arizona.

Arizona

Characterization of DOC in riparian wetland pore water and its interference in stable water isotope analysis of δ2H and δ18O

Wetlands play an important role in carbon retention, which is greatly dependent on hydrological conditions. Therefore, the interest in wetland hydrology has increased over recent decades. In wetland hydrology, stable water isotopes ( δ 2 H, δ 18 O) have found increasing use, as laser-based instruments have become readily available and allow for faster analysis and lower costs. However, the use of laser-based determinations of stable hydrogen and oxygen isotopes in wetland pore waters might be challenging because of dissolved organic carbon (DOC), especially as wetland pore waters often contain elevated DOC concentrations. To study the potential interference of DOC on laser-based stable water isotopes determination, we determined concentration, fluorescence and absorbance characteristics of DOC in pore waters collected from six restored and six near-natural riparian wetlands. The water samples’ δ 2 H and δ 18 O values were determined by two laser absorption spectrometers (LAS) and, for reference, in parallel by dual-inlet isotope-ratio mass spectrometry (DI-IRMS). The two LAS methods showed significant deviations from the DI-IRMS-determinations. Variations in the specific UV absorbance index (SUVA 254 , the quotient of the absorbance at 254 nm and the DOC concentration), which indicates the aromaticity of the DOC, partially accounted for interference for δ 2 H measurements. Elevated SUVA 254 index values were especially linked to restored wetlands. Studies that investigate pore waters with high DOC aromaticity but where the DOC is not characterized, and which require a high accuracy of the δ 2 H-values for interpretation of the hydrological system, may be severely affected by DOC interference.

Journal of Hydrology