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USGS2002

Water-quality and ground-water hydrology of the Columbia/Eagle Bluffs Wetland Complex, Columbia, Missouri— 1992-99

In an effort to restore riverine wetlands along the Missouri River, the Missouri Department of Conservation constructed the 2,700-acre Eagle Bluffs Conservation Area. The primary water source for managing 1,200 wetland acres on the Eagle Bluffs Conservation Area is treated effluent received from a 91-acre constructed wastewater-treatment wetland operated by the city of Columbia, Missouri. The combined areas of the Eagle Bluffs Conservation Area and the wastewater-treatment wetland are termed the Columbia/Eagle Bluffs Wetland Complex. The U.S. Geological Survey, in cooperation with the Missouri Department of Conservation and the city of Columbia, Missouri, collected samples quarterly from August 1992 to March 1999 from a monitoring network that included 33 ground-water sites and 4 surface-water sites to establish a baseline pre-effluent data set and to provide post-effluent data for trend analysis. Changes in major chemical constituent concentrations have been observed at several sampling locations between pre- and post-effluent data. Analysis of post-effluent time-series water-quality data indicates changes occurred in sodium, potassium, calcium, sulfate, and chloride concentrations at 13 sites. These changes can be correlated to the beginning of the operation of the wastewater-treatment wetland. The concentrations of these major chemical constituents plot on the mixing continuum between pre-effluent ground water as one end member and the treated effluent as the other end member. At ground water sites that had changes in concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 11 to more than 100 percent. At ground-water sites, few changes were noted in fecal indicator bacteria, nutrients, trace constituents, total and dissolved organic carbon, and organic constituents. Other than changes in boron concentrations at one ground-water site, these changes could not be directly correlated to the operation of the treatment wetland or the management of the Eagle Bluffs Conservation Area. After the treatment wetland began operation, improvement in the water quality in Perche Creek was observed. With respect to fecal indicator bacteria and nutrient concentrations, the water quality of water discharging from the Eagle Bluffs Conservation Area was improved relative to the water entering the area. Persistent ground-water highs have been observed beneath the Eagle Bluffs Conservation Area and wastewater-treatment unit 1 following the flooding of the wetland areas. These ground-water highs occur during the fall and winter months when ground- and surface-water levels are high and during the spring and summer months when the water levels are lower. The Missouri River stage had a strong effect on the water levels in the aquifer during pre-effluent conditions, but the effect has been lessened by the ground-water high.

Missouri↗

USGS2014

Dissolved-solids sources, loads, yields, and concentrations in streams of the conterminous United States

Recent studies have shown that excessive dissolved-solids concentrations in water can have adverse effects on the environment and on agricultural, domestic, municipal, and industrial water users. Such effects motivated the U.S. Geological Survey’s National Water Quality Assessment Program to develop a SPAtially-Referenced Regression on Watershed Attributes (SPARROW) model that has improved the understanding of sources, loads, yields, and concentrations of dissolved solids in streams of the conterminous United States. Using the SPARROW model, long-term mean annual dissolved-solids loads from 2,560 water-quality monitoring stations were statistically related to several spatial datasets that are surrogates for dissolved-solids sources and land-to-water delivery processes. Specifically, sources in the model included variables representing geologic materials, road deicers, urban lands, cultivated lands, and pasture lands. Transport of dissolved solids from these sources was modulated by land-to-water delivery variables that represent precipitation, streamflow, soil, vegetation, terrain, population, irrigation, and artificial drainage characteristics. Where appropriate, the load estimates, source variables, and transport variables were statistically adjusted to represent conditions for the base year 2000. The nonlinear least-squares estimated SPARROW model was used to predict long-term mean annual conditions for dissolved-solids sources, loads, yields, and concentrations in a digital hydrologic network representing nearly 66,000 stream reaches and their corresponding incremental catchments that drain the Nation. Nationwide, the predominant source of dissolved solids yielded from incremental catchments and delivered to local streams is geologic materials in 89 percent of the catchments, road deicers in 5 percent of the catchments, pasture lands in 3 percent of the catchments, urban lands in 2 percent of the catchments, and cultivated lands in 1 percent of the catchments. Whereas incremental catchments with dissolved solids that originated predominantly from geologic sources or from urban lands are found across much of the Nation, incremental catchments with dissolved solids yields that originated predominantly from road deicers are largely found in the Northeast, and incremental catchments with dissolved solids that originated predominantly from cultivated or pasture lands are largely found in the West. The total amount of dissolved solids delivered to the Nation’s streams is 271.9 million metric tons (Mt) annually, of which 194.2 million Mt (71.4%) come from geologic sources, 37.7 million Mt (13.9%) come from road deicers, 18.2 million Mt (6.7%) come from pasture lands, 13.9 million Mt (5.1%) come from urban lands, and 7.9 million Mt (2.9%) come from cultivated lands. Nationwide, the median incremental-catchment yield delivered to local streams is 26 metric tons per year per square kilometer [(Mt/yr)/km 2 ]. Ten percent of the incremental catchments yield less than 4 (Mt/yr)/km 2 , and 10 percent yield more than 90 (Mt/yr)/km 2 . Incremental-catchment yields greater than 50 (Mt/yr)/km 2 mostly occur along the northern part of the West Coast and in a crescent shaped band south of the Great Lakes. For example, the median incremental-catchment yield is 81 (Mt/yr)/km 2 for the Great Lakes, 78 (Mt/yr)/km 2 for the Ohio, and 74 (Mt/yr)/km 2 for the Upper Mississippi water-resources regions. Incremental-catchment yields less than 10 (Mt/yr)/km 2 mostly occur in a wide band across the arid lowland of the interior West that excludes areas along the coast and the extensive, higher mountain ranges. For example, the median incremental-catchment yield is 3 (Mt/yr)/km 2 for the Lower Colorado, 5 (Mt/yr)/km 2 for the Rio Grande, and 8 (Mt/yr)/km 2 for the Great Basin water-resources regions. Predicted incremental loads were cascaded down through the reach network, with loads accumulating from reach to reach. For most stream reaches, the entire incremental load of dissolved solids delivered to the reach was transported to either the ocean or to one of the large streams flowing along the U.S. international boundary without losses occurring along the way. The exceptions to this include streams in the southwestern part of the country, such as the Colorado River, Rio Grande, and streams of internally drained drainages in the Great Basin, where dissolved-solids loads decreased through streamflow diversion for off-stream use, or by infiltration through the streambed. Long-term mean annual flow-weighted concentrations were derived from the predicted accumulated-load and stream-discharge data. Widespread low concentrations, generally less than 100 milligrams per liter (mg/L), occur in many reaches of the New England, South Atlantic-Gulf, and Pacific Northwest water-resources regions as a result of moderate dissolved-solids yields and high runoff rates. Widespread moderate concentrations, generally between 100 and 500 mg/L, occur in many reaches of the Great Lakes, Ohio, and Upper Mississippi River water-resources regions. Whereas dissolved-solids yields are generally high in these regions, runoff rates are also high, which helps moderate concentrations in these regions. Widespread higher concentrations, generally greater than 500 mg/L, occur across a belt of reaches that extends almost continuously from Canada to Mexico in the Midwest, cutting through the Souris-Red-Rainy, Missouri, Arkansas-White-Red, Texas-Gulf, and Rio Grande water-resources regions. Although dissolved-solids yields are moderate to low in these areas, low runoff rates result in the high concentrations for these areas. In 12.6 percent of the Nation’s stream reaches, predicted concentrations of dissolved solids exceed 500 mg/L, the U.S. Environmental Protection Agency’s secondary, nonenforceable drinking water standard. While this standard provides a metric for evaluating predicted concentrations in the context of drinking-water supplies, it should be noted that it only applies to drinking water actually served to customers by water utilities, and it does not apply to all stream reaches in the Nation nor does it apply during times when water is not being withdrawn for use. Exceedance of 500 mg/L is more pronounced in certain water-resources regions than others. For example, about half of the reaches in the Souris-Red-Rainy region have concentrations predicted to exceed 500 mg/L, and between 25 and 37 percent of the reaches in the Missouri, Arkansas-White-Red, Texas-Gulf, Rio Grande, and Lower Colorado regions are predicted to exceed 500 mg/L. Development of stream-load data for use in the SPARROW model also provided long-term temporal trend information in dissolved-solids concentrations at the monitoring stations for their period of record, which was constrained between 1980 and 2009. For the 2,560 monitoring stations used in this study, long-term trends in flow-adjusted dissolved-solids concentrations increased over time at 23 percent of the stations, decreased at 18 percent of the stations, and did not change over time at 59 percent of the stations. Long-term trends show a strong regional spatial pattern where from the western parts of the Great Plains to the West Coast, concentrations mostly either did not change or decreased over time, and from the eastern parts of the Great Plains to the East Coast, concentrations mostly either did not change or increased over time. Results from the trend analysis and from the SPARROW model indicate that, compared to monitoring stations with no trends or decreasing trends, stations with increasing trends are associated with a smaller percentage of the predicted dissolved-solids load originating from geologic sources, and a larger percentage originating from urban lands and road deicers. Conversely, compared to stations with increasing trends or no trends, stations with decreasing trends have a larger percentage of the predicted dissolved-solids load originating from geologic sources and a smaller percentage originating from urban lands and road deicers. Stations with decreasing trends also have larger percentages of predicted dissolved-solids load originating from cultivated lands and pasture lands, compared to stations with increasing trends or no trends.

Scientific Investigations Report↗

USGS2011

Notes on the origin of inertinite macerals in coal: Evidence for fungal and arthropod transformations of degraded macerals

The role of fungus in the formation of coal macerals, both as a primary contributor in the form of a fungus fossil/maceral funginite, and in their role in degrading wood, thus producing degraded maceral forms, has been established. Fungus, in the course of breaking down the lignin and cellulose in wood, make the wood more digestible for grazers, such as arthropods. In turn, the remnants of the digested wood and anything else eaten but not completely digested are excreted and can be preserved intact; eaten by other fauna with a repeat of the cycle; or colonized by bacteria and/or coprophilous fungi with or without subsequent preservation. Ultimately, the coprolites can be preserved as a form of macrinite.

International Journal of Coal Geology↗

USGS2007

In situ quantitative analysis of individual H2O-CO2 fluid inclusions by laser Raman spectroscopy

Raman spectral parameters for the Raman ??1 (1285??cm- 1) and 2??2 (1388??cm- 1) bands for CO2 and for the O-H stretching vibration band of H2O (3600??cm- 1) were determined in H2O-CO2 fluid inclusions. Synthetic fluid inclusions containing 2.5 to 50??mol% CO2 were analyzed at temperatures equal to or greater than the homogenization temperature. The results were used to develop an empirical relationship between composition and Raman spectral parameters. The linear peak intensity ratio (IR = ICO2/(ICO2 + IH2O)) is related to the CO2 concentration in the inclusion according to the relation:Mole % C O2 = e- 3.959 IR2 + 8.0734 IRwhere ICO2 is the intensity of the 1388 cm- 1 peak and IH2O is the intensity of the 3600 cm- 1 peak. The relationship between linear peak intensity and composition was established at 350????C for compositions ranging from 2.5 to 50??mol% CO2. The CO2-H2O linear peak intensity ratio (IR) varies with temperature and the relationship between composition and IR is strictly valid only if the inclusions are analyzed at 350????C. The peak area ratio is defined as AR = ACO2/(ACO2 + AH2O), where ACO2 is the integrated area under the 1388??cm- 1 peak and AH2O is the integrated area under the 3600??cm- 1 peak. The relationship between peak area ratio (AR) and the CO2 concentration in the inclusions is given as:Mole % C O2 = 312.5 AR. The equation relating peak area ratio and composition is valid up to 25??mol% CO2 and from 300 to 450????C. The relationship between linear peak intensity ratio and composition should be used for inclusions containing ??? 50??mol% CO2 and which can be analyzed at 350????C. The relationship between composition and peak area ratios should be used when analyzing inclusions at temperatures less than or greater than 350????C (300-450) but can only be used for compositions ??? 25??mol% CO2. Note that this latter relationship has a somewhat larger standard deviation compared to the intensity ratio relationship. Calibration relationships employing peak areas for both members of the Fermi diad (??1 at 1285??cm- 1 and 2??2 at 1388??cm- 1) were slightly poorer than those using only the 2??2 (1388??cm- 1) member owing to interference from quartz peak at approximately 1160??cm- 1. The technique has been applied to natural low-salinity H2O-CO2 inclusions from the Butte, Montana, porphyry copper-molybdenum deposit. Carbon dioxide concentrations obtained range from below detection to 4.2??mol% CO2, and are in good agreement with concentrations determined previously based on microthermometric and petrographic observations. ?? 2007 Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS2017

Radiometric characterization of Landsat Collection 1 products

Landsat data in the U.S. Geological Survey (USGS) archive are being reprocessed to generate a tiered collection of consistently geolocated and radiometrically calibrated products that are suitable for time series analyses. With the implementation of the collection management, no major updates will be made to calibration of the Landsat sensors within a collection. Only calibration parameters needed to maintain the established calibration trends without an effect on derived environmental records will be regularly updated, while all other changes will be deferred to a new collection. This first collection, Collection 1, incorporates various radiometric calibration updates to all Landsat sensors including absolute and relative gains for Landsat 8 Operational Land Imager (OLI), stray light correction for Landsat 8 Thermal Infrared Sensor (TIRS), absolute gains for Landsat 4 and 5 Thematic Mappers (TM), recalibration of Landsat 1-5 Multispectral Scanners (MSS) to ensure radiometric consistency among different formats of archived MSS data, and a transfer of Landsat 8 OLI reflectance based calibration to all previous Landsat sensors. While all OLI/TIRS, ETM+ and majority of TM data have already been reprocessed to Collection 1, a completion of MSS and remaining TM data reprocessing is expected by the end of this year. It is important to note that, although still available for download from the USGS web pages, the products generated using the Pre-Collection processing do not benefit from the latest radiometric calibration updates. In this paper, we are assessing radiometry of solar reflective bands in Landsat Collection 1 products through analysis of trends in on-board calibrator and pseudo invariant site (PICS) responses.

Conference Paper↗

USGS2021

Discharge and dissolved-solids characteristics of Blacks Fork above Smiths Fork, Wyoming, April 2018 through September 2019

The Colorado River Basin Salinity Control Forum was formed in 1973 to coordinate salinity control efforts among the States in the Colorado River Basin, including Wyoming. The Colorado River Salinity Control Act of 1974 (Public Law 93–320) authorized “the construction, operation, and maintenance of certain works in the Colorado River Basin to control the salinity of water delivered to users in the United States and Mexico.” Water-quality standards for salinity in the lower Colorado River Basin were adopted in 1975. To help meet these standards, the Bureau of Reclamation, Natural Resource Conservation Service, and States within the Colorado River Basin have implemented salinity control projects that focus on reducing salt loading associated with irrigated agriculture by improving water delivery systems and water management practices. The term salinity is synonymous with dissolved solids in this report. The Bureau of Reclamation, in conjunction with the Colorado River Basin Salinity Control Forum, was interested in determining the contribution of dissolved solids from Blacks Fork above Smiths Fork to the Colorado River and initiated a study of Blacks Fork above Smiths Fork in 2018. In early 2018, the U.S. Geological Survey installed a streamgage at the most downstream location on the Blacks Fork, upstream from the convergence with Smiths Fork, to characterize the stream. The Blacks Fork above Smiths Fork, near Lyman, Wyoming, streamgage (U.S. Geological Survey identifier 09219200) was operated from April 4, 2018, through September 30, 2019, collecting continuous stream stage and specific-conductance data, from which continuous discharge, dissolved-solids concentrations, and dissolved-solids loads were calculated. Seven sites were selected on Blacks Fork and a tributary to describe a snapshot of the discharge and dissolved-solids characteristics. These sites were sampled during July, August, and September 2018 and June, July, August, and September 2019 report. Discharge at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) from April through September in 2018 was lower and less variable than during the same period in 2019. The mean daily (mean of the daily means) discharge during those 6 months in 2018 (15.1 cubic feet per second [ft 3 /s]) was about one-tenth of the discharge during the same period in 2019 (152 ft 3 /s). The cumulative monthly discharge during April through September in 2018 was 5,360 acre-feet, about one-tenth of the discharge during the same period in 2019 which was 54,700 acre-feet. Similar differences in discharge between the 2018 and 2019 periods also are noted at other Blacks Fork streamgages in the area. Continuous specific conductance data and the statistical relation between specific conductance and dissolved-solids concentrations were used to calculate the daily mean dissolved-solids concentrations. Dissolved solids often have an inverse relation with discharge because higher discharges typically have a diluting effect that lowers the dissolved-solids concentrations. In general, when discharges at the Blacks Fork above Smiths Fork streamgage (09219200) are higher, dissolved-solids concentrations are generally lower. However, the high dissolved-solids concentrations that are measured during high discharges indicate that the system has natural variability and the dissolved-solids concentrations are determined by more factors than just discharge. The mean daily dissolved-solids concentration during April through September 2018 was 1,630 milligrams per liter and during the same period in 2019 was 1,100 milligrams per liter. Dissolved-solids loads were calculated as the product of the discharge and dissolved-solids concentration. The daily mean dissolved-solids loads during 2018 were typically lower than during 2019. This result is primarily because the discharge was much lower in 2018 than in 2019. Therefore, although the daily mean dissolved-solids concentrations tended to be higher in 2018, the substantially higher discharges in 2019 had more of an effect on the dissolved-solids loads than the dissolved-solids concentrations. The cumulative dissolved-solids load at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) during the 18-month study was 81,200 tons, with a mean daily load of 149 tons per day. During the 6-month period from April through September 2018, the cumulative dissolved-solids load at the streamgage was estimated to be 8,740 tons and, during the same 6 months in 2019, the cumulative dissolved-solids load was estimated to be 60,900 tons. During the fall and winter between the two periods, the cumulative dissolved-solids load was 11,600 tons. Discharge and dissolved-solids concentrations from samples collected during the synoptic sampling events were highly variable among most sites during most synoptic sampling events and also highly variable at most sites among different sampling events. The two sites upstream from the tributary input from Threemile Creek had lower dissolved-solids concentrations than sites including and downstream from the tributary. Sites including and downstream from the tributary had similar values and variability of dissolved-solids loads, with the exception of the farthest downstream site at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) that tended to have larger dissolved-solids loads and higher variability among synoptic sampling events.

Scientific Investigations Report↗

USGS2010

U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center-Fiscal Year 2009 Annual Report

The Earth Resources Observation and Science (EROS) Center is a U.S. Geological Survey (USGS) facility focused on providing science and imagery to better understand our Earth. As part of the USGS Geography Discipline, EROS contributes to the Land Remote Sensing (LRS) Program, the Geographic Analysis and Monitoring (GAM) Program, and the National Geospatial Program (NGP), as well as our Federal partners and cooperators. The work of the Center is shaped by the Earth sciences, the missions of our stakeholders, and implemented through strong program and project management and application of state-of-the-art information technologies. Fundamentally, EROS contributes to the understanding of a changing Earth through 'research to operations' activities that include developing, implementing, and operating remote sensing based terrestrial monitoring capabilities needed to address interdisciplinary science and applications objectives at all levels-both nationally and internationally. The Center's programs and projects continually strive to meet and/or exceed the changing needs of the USGS, the Department of the Interior, our Nation, and international constituents. The Center's multidisciplinary staff uses their unique expertise in remote sensing science and technologies to conduct basic and applied research, data acquisition, systems engineering, information access and management, and archive preservation to address the Nation's most critical needs. Of particular note is the role of EROS as the primary provider of Landsat data, the longest comprehensive global land Earth observation record ever collected. This report is intended to provide an overview of the scientific and engineering achievements and illustrate the range and scope of the activities and accomplishments at EROS throughout fiscal year (FY) 2009. Additional information concerning the scientific, engineering, and operational achievements can be obtained from the scientific papers and other documents published by EROS staff. We welcome comments and follow-up questions on any aspect of this Annual Report and invite any of our customers or partners to contact us at their convenience. To communicate with us, or for more information about EROS, contact: Communications and Outreach, USGS EROS Center, 47914 252nd Street, Sioux Falls, South Dakota 57198, jsnelson@usgs.gov, http://eros.usgs.gov/.

Open-File Report↗

USGS2020

Assessment of bridge scour countermeasures at selected bridges in the United States, 2014–18

Erosion of the streambed, known also as scour, around pier 3 of the New York State Thruway bridge over Schoharie Creek caused the pier to fail, which ultimately resulted in bridge failure during the flooding event of April 5, 1987. The Federal Highway Administration (FHWA) responded to the need for better guidance on the evaluation of bridge scour and the selection and installation of scour countermeasures with the release of several Hydraulic Engineering Circulars. Although this information has been available, used, and updated over the years, an evaluation of the current conditions of scour countermeasures has not been performed. Therefore, the U.S. Geological Survey, in cooperation with the FHWA, began a study in 2013 to assess the current conditions of bridge scour countermeasures at selected sites around the country. The bridge scour countermeasure site assessments included reviewing countermeasure design plans, field inspections, traditional surveys, motion-compensated terrestrial light detection and ranging technology (lidar), high-resolution multi-beam bathymetry scanning, underwater video imaging, and a review of the peak and daily streamflow history for the associated river or stream. A total of 34 bridge scour countermeasure sites were selected in 11 states for this study. The types of countermeasures installed at the bridge scour study sites ranged from riprap, the most common countermeasure in the study, to A-Jacks and cabled-concrete mattresses. The installed countermeasures were generally exposed to hydraulic forces from floods that equaled or exceeded the 1-percent, and even the 0.2-percent, annual exceedance probability at some of the study sites, but not all. The field inspections and countermeasure evaluations identified areas of shifting, slumping, and some scour holes and damage or washouts to the countermeasures, but generally most remained in place. The high-resolution laser scanner data, photo imaging and traditional survey data, and field notes were provided to the FHWA for expert evaluation of the bridge scour countermeasure performance.

Alabama, Florida, Idaho, Illinois, Indiana, Iowa, ↗

USGS2024

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https://ca.water.usgs.gov/bay-delta/2018-delta-wide-mapping-surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California↗

USGS1961

Tephroite in California manganese deposits

Recent studies of manganese deposits and mineral specimens in the Sierran belt of sedimentary rocks as well as in the Klamath Mountains to the north and in the Rand Mountains to the south, have shown the presence of tephroite , the orthosilicate of manganese (Mn2Si04), at numerous localities. Earlier studies of these deposits have shown that the original layered deposits of carbonate and hydrous silicates of manganese have been widely altered by metamorphism to spessartite (Mn3Al2-(SiO.),), rhodonite (MnSi03), and piedmontite (Ca2(Al,Mn"',Fe"')3-Si3Oi2(OH)). Recent work shows that layered manganese oxides also were present in the original sedimentary rocks. It shows also, that tephroite has formed widely in the original assemblage of carbonate, silicate, and oxide of manganese ; in several localities, a little alleghanyite (2Mn2-S1O4 - Mn(OH,F)2) has been formed. Rhodonite, spessartite, and piedmontite uniformly follow the tephroite ; in places, bementite and neotocite are present. In one deposit a little pyroxmangite ( (Mn,Fe,Ca)Si03) has been noted and in another, some crystals that are probably pyrophanite (MnTi03), not yet recorded in the United States. By contrast, the restudy of large collections of material from deposits in sedimentary rocks of the Franciscan formation in the Coast Ranges indicates the tephroite is very uncommon; it has been recognized with assurance at only one locality-Alum Rock Park, Santa Clara County. In the Coast Ranges, rhodonite and spessartite, the high manganese garnet, are very uncommon. The assemblages of manganese silicates indicate that the layered deposits of manganese minerals in the Sierra belt have been metamorphosed to a higher degree than those of the Coast Ranges. This review also shows the presence of axinite, the boro-silicate of aluminum, calcium, and manganese , in three deposits .

California↗

USGS2020

Compilation of mercury data and associated risk to human and ecosystem health, Bad River Band of Lake Superior Chippewa, Wisconsin

Mercury is an environmentally ubiquitous neurotoxin, and its methylated form presents health risks to humans and other biota, primarily through dietary intake. Because methylmercury bioaccumulates and biomagnifies in living tissue, concentrations progressively increase at higher trophic positions in ecosystem food webs. Therefore, the greatest health risks are for organisms at the highest trophic positions and for humans who consume organisms such as fish from these high trophic positions. Data on environmental mercury concentrations in various media and biota provide a basis for comparison among sites and regions and for evaluating ecosystem health risks. The U.S. Geological Survey, in cooperation with the Natural Resources Department, Bad River Band of Lake Superior Chippewa, have compiled a dataset from analyses of mercury concentrations in surface water, bed sediment, fish tissue, Rana clamitans (green frog) tissue, Haliaeetus leucocephalus (bald eagle) feathers, Lontra canadensis (North American river otter) hair, Zizania palustris (northern wild rice), and litterfall from samples collected in the Bad River watershed, Wisconsin during 2004–18. These data originated from either the Natural Resources Department or another agency based on samples collected within or near to Bad River Tribal lands before transfer to the U.S. Geological Survey for compilation and analysis at the onset of the project. This report describes the compiled mercury dataset, provides comparisons to similar measurements in the region and elsewhere, and evaluates health risks to humans and to the sampled biota. Except for litterfall, data were not collected on a consistent, regular basis over a sufficient period to evaluate temporal patterns. The reported mercury concentrations are generally similar to those reported elsewhere in the upper Great Lakes region. Reported values are consistent with atmospheric deposition as the principal source and reflect a favorable environment for mercury methylation. Fish mercury concentrations increased at higher food web positions and generally increased with length in most species measured. Sander vitreus (walleye) present the greatest risk to humans among fishes considered here because of their high trophic position and associated elevated mercury concentrations in combination with relatively high walleye consumption rates by the Native American community. Methylmercury concentrations in wild rice are generally low and likely pose little health risk. Despite reports of declining atmospheric mercury deposition across eastern North America during the past decade, a downward trend in litterfall mercury deposition was not evident in samples collected during 2012–18. Limitations in this data compilation and analysis were noted due to missing information such as collection dates and site locations for some samples. Regular monitoring of mercury in litterfall and surface waters along with periodic collection of fish would enable evaluation of temporal change in the mercury cycle that might affect future risk to humans and aquatic ecosystem inhabitants.

Wisconsin↗

USGS1948

Preliminary notes on distribution of uranium in the Florida pebble phosphate field and suggestions for studying and sampling

The accompanying map and sections show examples of the present state of information about the occurrence of the "Leached" uranium-bearing bed in the Florida pebble phosphate district. The dashed lines on the map define, as closely as present data permit, the limit of the area in which this bed contains significant amounts of uranium. The figures next to localities on the map indicate first, the thickness of the bed in feet; and second the uranium content in thousandths of percent. For example, the figures 16-10 next to the TVA localities in Secs. 9 and 10, T. 32 S., R. 26 E. indicate 16 feet at 0.010 percent uranium. A "0" by a locality indicates either that the uranium content is less than 0.001 percent or less than the concentration in the underlying phosphate beds (matrix of the miners) or that the leached bed is not present.

Florida↗

USGS2012

Archive of digital boomer subbottom data collected during USGS cruise 05FGS01 offshore east-central Florida, July 17-29, 2005

In July of 2005, the U.S. Geological Survey (USGS), in cooperation with the Florida Geological Survey (FGS), conducted a geophysical survey of the Atlantic Ocean offshore of Florida's east coast from Flagler Beach to Daytona Beach. This report serves as an archive of unprocessed digital boomer subbottom data, trackline maps, navigation files, Geographic Information System (GIS) files, Field Activity Collection System (FACS) logs and formal Federal Geographic Data Committee (FGDC) metadata. Filtered and gained (showing a relative increase in signal amplitude) digital images of the seismic profiles are also provided. Refer to the Acronyms page for expansions of acronyms and abbreviations used in this report. The USGS Saint Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier to each cruise or field activity. For example, 05FGS01 tells us the data were collected in 2005 for cooperative work with the FGS and the data were collected during the first field activity for that project in that calendar year. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity ID. The boomer subbottom processing system consists of an acoustic energy source that is made up of capacitors charged to a high voltage and discharged through a transducer in the water. The transducer is towed on a sled floating on the water surface and when discharged emits a short acoustic pulse, or shot, which propagates through the water column and shallow stratrigraphy below. The acoustic energy is reflected at density boundaries (such as the seafloor or sediment layers beneath the seafloor), detected by the receiver (a hydrophone streamer), and recorded by a PC-based seismic acquisition system. This process is repeated at timed intervals (for example, 0.5 s) and recorded for specific intervals of time (for example, 100 ms). In this way, a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track is produced. Figure 1 displays the acquisition geometry. Refer to table 1 for a summary of acquisition parameters and table 2 for trackline statistics. The archived trace data are in standard Society of Exploration Geophysicists (SEG) SEG Y format (Barry and others, 1975), except an ASCII format is used for the first 3,200 bytes of the card image header instead of the standard EBCDIC format. For a detailed description about the recorded trace headers, refer to the SEG Y Format page. The SEG Y files may be downloaded and processed with commercial or public domain software such as Seismic Unix (Cohen and Stockwell, 2005). See the How To Download SEG Y Data page for download instructions. The printable profiles provided here are GIF images that were processed and gained using SU software; refer to the Software page for links to example SU processing scripts. The processed SEG Y data were also exported to Chesapeake Technology, Inc. (CTI) SonarWeb software to produce a geospatially interactive version of the profile that allows the user to obtain a geographic location and depth from the profile for a given cursor position; this information is displayed in the status bar of the browser. Please note that clicking on the profile image switches it to "Expanded View" (a compressed image of the entire line) and cursor tracking is not available in this mode.

Florida↗

USGS1988

The Geology and Remarkable Thermal Activity of Norris Geyser Basin, Yellowstone National Park, Wyoming

Norris Geyser Basin, normally shortened to Norris Basin, is adjacent to the north rim of the Yellowstone caldera at the common intersection of the caldera rim and the Norris-Mammoth Corridor, a zone of faults, volcanic vents, and thermal activity that strikes north from the caldera rim to Mammoth Hot Springs. An east-west fault zone terminates the Gallatin Range at its southern end and extends from Hebgen Lake, west of the park, to Norris Basin. No local evidence exists at the surface in Norris Basin for the two oldest Yellowstone volcanic caldera cycles (~2.0 and 1.3 m.y.B.P.). The third and youngest cycle formed the Yellowstone caldera, which erupted the 600,000-year-old Lava Creek Tuff. No evidence is preserved of hydrothermal activity near Norris Basin during the first 300,000.years after the caldera collapse. Glaciation probably removed most of the early evidence, but erratics of hot-spring sinter that had been converted diagenetically to extremely hard, resistant chalcedonic sinter are present as cobbles in and on some moraines and till from the last two glacial stages, here correlated with the early and late stages of the Pinedale glaciation <150,000 years B.P.). Indirect evidence for the oldest hydrothermal system at Norris Basin indicates an age probably older than both stages of Pinedale glaciation. Stream deposits consisting mainly of rounded quartz phenocrysts of the Lava Creek Tuff were subaerial, perhaps in part windblown and redeposited by streams. A few small rounded pebbles are interpreted as chalcedonic sinter of a still older cycle. None of these are precisely dated but are unlikely to be more than 150,000 to 200,000 years old. ...Most studies of active hydrothermal areas have noted chemical differences in fluids and alteration products but have given little attention to differences and models to explain evolution in types. This report, in contrast, emphasizes the kinds of changes in vents and their changing chemical types of waters and then provides models for explaining these differences. Norris Basin is probably not an independent volcanic-hydrothermal system. The basin and nearby acid-leached areas (from oxidation of H2S-enriched vapor) are best considered as parts of the same system, extending from Norris Basin to Roaring Mountain and possibly to Mammoth. If so, are they parts of a single large system centered within the Yellowstone caldera, or are Norris Basin and the nearby altered areas both parts of one or more young independent corridor systems confined, at least in the shallow crust, to the Norris-Mammoth Corridor? Tentatively, we favor the latter relation, probably having evolved in the past ~300,000 years. A model for large, long-lived, volcanic-hydrothermal activity is also suggested, involving all of the crust and upper mantle and using much recent geophysical data bearing on crust-mantle interrelations. Our model for large systems is much superior to previous suggestions for explaining continuing hydrothermal activity over hundreds of thousands of years, but is less attractive for the smaller nonhomogenized volcanic system actually favored here for the Norris-Mammoth Corridor.

Professional Paper↗

USGS2015

Lithology, hydrologic characteristics, and water quality of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas

A study to assess the potential of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas, as a viable source of public-supply water was conducted by the U.S. Geological Survey in cooperation with the Little Rock, District, U.S. Army Corps of Engineers. An important study component was to identify possible changes in hydrologic conditions following installation of James W. Trimble Lock and Dam 13 (December 1969) on the Arkansas River near the study area. Data were gathered for the study in regard to the lithology, hydrologic characteristics, and water quality of the aquifer. Lithologic information was obtained from drillers’ logs of wells drilled from 1957 through 1959. Water-quality samples were collected from 10 irrigation wells and analyzed for inorganic constituents and pesticides. To evaluate the potential viability of the alluvial aquifer in the Van Buren area, these data were compared to similar stratigraphic, lithologic, and groundwater-quality data from the Arkansas River Valley alluvial aquifer at Dardanelle, Ark., where the aquifer provides a proven, productive, sole-source of public-supply water. Drillers’ logs for 59 wells in the Van Buren study area revealed well depths ranging from 25 to 52 feet (ft), with a mean depth of 42 ft. The thickness of the lower sand/gravel interval serving as the water-producing zone ranged from 5 to 47 ft, with a mean thickness of 29 ft. The presence of gravel was noted in only 4 of 59 well logs available for review from the study area. Percent sand was calculated from well logs in the study area, and these sand percentages were overlain onto an orthophotograph map to examine the areal distribution of sand percentage in relation to geomorphologic features of the flood plain in the study area. The logs denoting the greatest percent sand tend to occur in areas near to the river and on the concave (point bar) side of abandoned channels, while the lower percent sand tends to occur on the convex (channel fill and backswamp deposits) side of the abandoned channels. Comparison of hydrographs from water levels collected between 1957 and 1972 to cumulative departure from mean monthly and mean annual precipitation showed overall good fit and explained the long-term decreasing water levels from the earliest period of record through October 1967, followed by a sharp rise in water levels concurrent with rises in cumulative departure from mean monthly and mean annual precipitation. Hydrographs for four wells ranging from 0.8 to 4.5 miles upstream from the dam and potentially affected by rising river stage were compared to graphs of river stage and cumulative departure from mean monthly precipitation. Water levels for these wells showed minimal discernible effect by rising river stage following dam completion. Periods of increased precipitation compared closely to increases in water level for all hydrographs, regardless of river stage, and periods of no precipitation resulted in declining water levels, although river stage continued to slowly rise during these same periods. The Arkansas River has greater salinity than local groundwater, providing a quantitative tracer for any groundwater recharge originating from the river. Comparison of predam and postdam groundwater-chloride concentrations showed no increase in chloride concentrations after dam installation, which is consistent with hydrologic data. These data suggest that the dominant source of groundwater recharge in the Arkansas River Valley alluvial aquifer is infiltration of precipitation through proximal, coarse channel deposits, with minimal influx of river water. Groundwater-quality data collected from 10 wells in the study area indicated a calcium-bicarbonate water type. No primary drinking-water standards were exceeded for any constituents, and iron and manganese were the only constituents exceeding secondary drinking-water regulations. Six of the 10 well-water samples were analyzed for the presence of pesticides, as row-crop agriculture is the dominant land use in the study area. Six herbicide compounds and one herbicide metabolite were detected at concentrations substantially below those of the Federal primary drinking-water standards and health advisories. The hydrologic and geochemical data gathered for this study provide a qualitative assessment of the potential of the Arkansas River Valley alluvial aquifer as a source of public water supply in the Van Buren area. Results indicate minimal influx of water from the Arkansas River, and recharge to the aquifer appears to be dominantly by infiltration of precipitation through overlying alluvium. If vertical wells are used as a source of public water supply, then several wells will have to be used in combination at relatively low pumping rates and placed in areas with a greater percent sand. Use of a horizontal well configuration near the river to increase production may depend on infiltration of river water to supplement water removed from storage, especially where areas of lower permeability sediments might be encountered within the surrounding alluvium. If a poor hydraulic connection exists between the river and the alluvium, as indicated by this study, then production will depend on ample precipitation and recharge throughout the year and groundwater storage sufficient to prevent declining water levels where pumping rates exceed recharge.

Arkansas↗

USGS2021

Geohydrologic and water-quality characterization of a fractured-bedrock test hole in an area of Marcellus Shale gas development, Sullivan County, Pennsylvania

The stratigraphy, water-bearing zones, and quality of groundwater were characterized in a 1,400-ft-deep test hole drilled during 2013 in fractured bedrock in Sullivan County, Pa., by collection and analysis of measurements made during drilling, geophysical logs, and depth-specific hydraulic tests and water samples. The multidisciplinary characterization of the test hole was a cooperative effort between the Pennsylvania Department of Natural Resources, Bureau of Geological Survey (BGS), and the U.S. Geological Survey (USGS). The study provided information to aid the bedrock mapping of the Laporte 7.5-minute quad-rangle by BGS to help quantify the depth and character of fresh and saline groundwater in an area of shale-gas exploration (described in this report), which could help gas operators protect groundwater resources. The Laporte test hole was drilled with air-hammer methods in an upland setting in the headwaters of Loyalsock Creek in the Glaciated High Plateau section of the Appalachian Plateaus physiographic province. Bedrock residuum and till were penetrated from land surface to 8.5 ft, the Huntley Mountain Formation of Mississippian and Devonian age was penetrated from 8.5 to 540 ft, and the Catskill Formation of Devonian age was penetrated from 540 to 1,400 ft. Fractures, determined from optical televiewer, acoustic televiewer, and video logs, were commonly encountered to 200 ft bls (below land surface), then decreased exponentially with depth, except at a highly fractured zone from 637 to 644 ft bls. Most fractures were along bedding planes and had a strike of about 243 degrees and dip about 4 degrees to the northwest, consistent with the test-hole location on the north limb of the Muncy Creek anticline. Few fractures were noted below 650 ft. The depths of fresh and saline water-bearing fracture zones were identified in the test hole by geophysical-log analysis and were verified by pumping samples from zones isolated with packers and by collecting samples in the open hole with a wire-line point sampler. Six water-bearing zones associated with single or multiple fractures were identified at depths of 130–135, 180, 267–275, 425, 637–644, and 1,003 ft bls. Under ambient conditions, fresh water entered the hole from fractures at 130-135 and 180 ft bls, flowed downward and exited at fractures from 267–275, 425, and 637–644 ft. When pumped at 16.2 gal/min, most of the water from the open test hole was contributed from the fracture at 180 ft bls. Transmissivity, estimated from analysis of the specific-capacity data and flowmeter logs, is about 850 ft 2 /d for the entire open hole, and about 60 percent of the transmissivity is contributed from the fracture zone at 180 ft bls. The hydraulic heads in the deep water-bearing zones at 425 and 637–644 ft were about 100 ft lower than hydraulic heads in shallow water-bearing zones at 180 ft bls and above, indicating a large downward vertical hydraulic gradient. Water samples pumped from fracture zones isolated by packers at and above the water-bearing zone at 450 ft bls were fresh with dissolved-solids contents of 105 mg/L or less. The sample isolated at 637–644 ft bls was probably affected by leakage around packers, but the specific-conductance samples collected during drilling that were believed to be representa-tive of the fracture zone at 637–644 ft bls indicated slightly saline water. Below the 637–644 ft zone, a flowmeter log in the open hole did not detect any vertical flow, and the temperature log approached the geothermal gradient, indicating little ambient fluid flow and minimal fracture transmissivity below this depth. A petrophysical-log analysis using estimates of formation water resistivity from Archie’s Equation indicated an apparent transition from fresh to saline water in the sandstones occurs between 450 to 900 ft bls, with saline water indicated below 900 ft. Small seeps of saline water were delineated at 958, 989, and 1,003 ft bls by a time series of specific-conductance logs, and a discrete-point water sample at 990 ft bls with total dissolved-solids concentration of 19,900 mg/L verified that highly saline water was present below 900 ft bls. Occurrence of saline water at a depth of about 900 ft bls is below altitude of streams within 3 to 5 miles of the test hole but is about 930 ft above the altitude at the mouth of Loyalsock Creek where is enters the West Branch Susquehanna River at Montours-ville, Pa. The depth to saline water in this test hole is close to depths estimated at two other deep test holes drilled by the BGS in upland settings in Bradford and Tioga Counties in north-ern Pennsylvania. The saline water from 990 ft bls had a chemical composition similar to Appalachian Basin brines that had been diluted with fresh water. Predominant ions in the saline water were sodium, chloride, and calcium. Trace constituents of strontium, bromide, barium, lithium, and molybdenum were all more than 5,000 times greater than in freshwater samples from 167 or 270 ft bls. Methane concentration in the saline water sample from 990 ft was 120 mg/L. The concentration ratios of methane to higher-chain hydrocarbon gases and isotopic ratios of 13 C/ 12 C and 2 H/ 1 H of methane indicate that the gases are likely of thermogenic origin. In the sample from 990 ft bls, the 13 C/ 12 C of methane was less negative (-34.81 per mil) than 13 C/ 12 C of ethane (-37.1 per mil). Isotopic reversals such as this are generally found in gases from rocks older than the Catskill Formation, so its recognition in a natural upland setting at relatively shallow depth could be important when interpreting isotopic results to identify the origin of stray gas in the area.

Pennsylvania↗

USGS2015

Archive of Sidescan Sonar and Swath Bathymetry Data Collected During USGS Cruise 13CCT04 Offshore of Petit Bois Island, Gulf Islands National Seashore, Mississippi, August 2013

In August of 2013, the U.S. Geological Survey conducted a geophysical survey offshore of Petit Bois Island, Mississippi. This effort was part of the U.S. Geological Survey Gulf of Mexico Science Coordination partnership with the U.S. Army Corps of Engineers to assist the Mississippi Coastal Improvements Program and the Northern Gulf of Mexico Ecosystem Change and Hazards Susceptibility Project, by mapping the shallow geologic stratigraphic framework of the Mississippi Barrier Island Complex. This geophysical survey will provide additional data necessary for scientists to define, interpret, and provide baseline bathymetry and seafloor habitat for this area, and to aid scientists in predicting future geomorphological changes of the islands with respect to climate change, storm impact, and sea-level rise. Furthermore, these data will provide information for barrier island restoration, particularly in Camille Cut, and protection for the historical Fort Massachusetts on Ship Island, Mississippi. The geophysical data were collected during one cruise ( USGS Field Activity Numbers 13CCT04 ) aboard the Research Vessel Tommy Munro offshore along the gulf side of Petit Bois Island, Gulf Islands National Seashore, Mississippi. Data were acquired with the following equipment: a Systems Engineering and Assessment, Ltd., SWATH plus interferometric sonar (468 kilohertz (kHz)), an EdgeTech 424 (4-24 kHz), an EdgeTech 525i chirp subbottom profiling system, and a Klein 3900 sidescan sonar system. This report serves as an archive of the processed interferometric swath bathymetry and sidescan sonar data. Geographic information system data products include an interpolated digital elevation model, an acoustic backscatter mosaic, trackline maps, and point data files. Additional files include error analysis maps, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata. NOTE: These data are scientific in nature and are not to be used for navigation. Any use of trade names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Mississippi↗

USGS2008

Davis Pond freshwater prediversion biomonitoring study: freshwater fisheries and eagles

In January 2001, the construction of the Davis Pond freshwater diversion structure was completed by the U.S. Army Corps of Engineers. The diversion of freshwater from the Mississippi River is intended to mitigate saltwater intrusion from the Gulf of Mexico and to lessen the concomitant loss of wetland areas. In addition to the freshwater inflow, Barataria Bay basin would receive nutrients, increased flows of sediments, and water-borne and sediment-bound compounds. The purpose of this biomonitoring study was, therefore, to serve as a baseline for prediversion concentrations of selected contaminants in bald eagle ( Haliaeetus leucocephalus ) nestlings (hereafter referred to as eaglets), representative freshwater fish, and bivalves. Samples were collected from January through June 2001. Two similarly designed postdiversion studies, as described in the biological monitoring program, are planned. Active bald eagle nests targeted for sampling eaglet blood (n = 6) were generally located southwest and south of the diversion structure. The designated sites for aquatic animal sampling were at Lake Salvador, at Lake Cataouatche, at Bayou Couba, and along the Mississippi River. Aquatic animals representative of eagle prey were collected. Fish were from three different trophic levels and have varying feeding strategies and life histories. These included herbivorous striped mullet ( Mugil cephalus ), omnivorous blue catfish ( Ictalurus furcatus ), and carnivorous largemouth bass ( Micropterus salmoides ). Three individuals per species were collected at each of the four sampling sites. Freshwater Atlantic rangia clams ( Rangia cuneata ) were collected at the downstream marsh sites, and zebra mussels ( Dreissena spp.) were collected on the Mississippi River. The U.S. Geological Survey (USGS) Biomonitoring of Environmental Status and Trends (BEST) protocols served as guides for fish sampling and health assessments. Fish are useful for monitoring aquatic ecosystems because they accumulate pesticides and other contaminants. Biomarker data on individual fish, generated at the USGS National Wetlands Research Center (Lafayette, La.), included percent white blood cells in whole blood, spleen weight to body weight ratio, liver weight to body weight ratio, condition factor, splenic macrophage aggregates, and liver microsomal 7-ethoxyresorufin-o-deethylase (EROD) activity. Fish age was estimated by comparing total lengths with values from the same species in the Southeast United States as determined from the literature. Contaminant analyses were coordinated by the U.S. Fish and Wildlife Service (USFWS) Analytical Control Facility (Laurel, Md.), where residues of organochlorine (OC) pesticides, total polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), aliphatic hydrocarbons (AHs), and trace elements were determined. The organic contaminant data were generated at the Mississippi State University Chemical Lab (Mississippi State, Miss.), and the inorganic contaminant data were generated by the Texas A&M University Geochemical and Environmental Research Group (College Station, Tex.). Statistical tests were performed to assess relationships among contaminants, fish age, fish species, and collection sites. Trends in interspecific differences among fish in concentrations of contaminants were noted. Striped mullet (hereafter mullet) frequently displayed the highest chemical concentrations. Levels of contaminants were generally higher in samples obtained from the Mississippi River than in those collected from the diversion area and were higher in mussels and clams (hereafter bivalves) than in fish. Because the Mississippi River sampling site for mullet and largemouth bass was downriver of the structure and south of New Orleans and the catfish site was upriver, the downriver data may not be directly reflective of the results from the receiving waters at the Davis Pond structure. Compared to the Caernarvon freshwater prediversion study in 1990 that assessed possible influx of contaminants with the freshwater diversion, contaminant levels in fishes and bivalves in this study were generally lower, yet three nontoxic inorganic elements in Davis Pond fish samples exhibited ranges of concentrations that were more than two times higher than did those from Caernarvon. Levels in bivalves were different between diversions but about equal in the numbers of trace elements showing high levels per location. Contaminant values were compared to those listed in various literature and agency sources, both regional and national, including the National Contaminant Biomonitoring Program (NCBP), in which the 85th percentile and above represents what is considered to be an elevated contaminant concentration and cause for concern. Generally, bivalves were at the high end of their ranges for both organic and inorganic contaminants. In this study, OCs were detectable in 67 percent of fish from the Mississippi River site, ranging from 0.15 to 1.09 μg/g wet weight (ww) or fresh weight (fw), and in 11 percent of the fish from the marsh sites, ranging from 0.06 to 0.612 μg/g ww. Bivalves from the Mississippi River had OC levels of 0.096 μg/g ww, whereas none were detectable in bivalves at the marsh sites. In this study, p,p ’-dichlorodiphenyldichloroethylene ( p,p’ -DDE) (a biodegradation product of DDT [dichlorodiphenyl trichloroethane]) and total PCBs were the most frequently detected OCs and were primarily from the Mississippi River. For total OC content, using adjusted least squares means, some significant interactions were noted between fish species and sites. PAHs were detected in aquatic animals at all sites (range of 0.017–17.534 μg/g ww), as were AHs (range of 0.423–4.549 μg/g ww); the highest levels of PAHs and AHs were found in bivalves from the Mississippi River. When analysis of variance (α = 0.05) was performed with data from aquatic animals, there were only two significant relationships between PAHs, AHs, and OCs between species, site, and age or the interaction among these variables. There was an interaction between fish species and n-decane (an AH) in that mullet and largemouth bass had significantly higher levels than did catfish ( P = 0.0175). When general linear means were used to investigate associations of inorganic contaminants among fish species, site, and age or any interactions among these variables, no significant results were noted for arsenic, cadmium, lead, beryllium, boron, molybdenum, or nickel. The range of mercury in fish in this study was 0.04–0.14 μg/g ww (0.14– 0.48 μg/g dry weight [dw]), with the most elevated levels detected in predatory largemouth bass at the sampling point farthest downstream from the structure and within the marsh area. Mercury was positively correlated with fish age ( P = 0.0152), where levels were estimated to increase 0.0253 parts per million (ppm) dw per year. In the Mississippi River, catfish showed significantly higher levels of mercury than did mullet or largemouth bass ( P = 0.00167). Among fish species, mullet displayed the highest levels in fish of aluminum, barium, manganese, and iron, all considered to have low toxicity in hydrologic systems. An interaction between fish and site was seen with aluminum ( P = 0.0031), where concentrations in mullet were significantly higher in the Mississippi River than at the other sites, as was also seen with barium ( P = 0.0009), chromium ( P = <0.0001), manganese ( P = 0.0004), strontium ( P = 0.0074), vanadium ( P = 0.0156), and zinc ( P = 0.0059). For iron ( P = 0.0.0001), mullet and largemouth bass at both the Mississippi River and Lake Salvador showed higher levels than did catfish, and these two species showed higher levels at two of the four sites. An interaction between fish and site was also seen with chromium ( P = <0.0001) in that concentrations in mullet were significantly higher in the Mississippi River than at the other sites, as was also seen with strontium ( P = 0.0074), vanadium ( P = 0.0156), and zinc ( P = 0.0059), metals for which deleterious effects have been demonstrated in other ecosystems. The NCBP program lists the 85th percentile for zinc at 34.2 μg/g fw (117.9 μg/g dw). In the Davis Pond prediversion biomonitoring study (hereafter the current study), one fish (MUL31RIVER, fish ID 8) showed values higher than that (125.4 μg/g dw or 37.54 μg/g ww), and the Mississippi River bivalve sample (MUSSRIVER) had a value of 140 μg/g dw (41.2 μg/g ww). In the current study, approximately 86 percent of the fish had measurable selenium levels, yet none reached the 85th percentile. The 85th percentile for selenium from the NCBP was 0.73 μg/g ww. Significantly higher levels of selenium were seen in mullet than in largemouth bass and catfish ( P = 0.0023). The NCBP 85th percentile for lead is 0.22 μg/g ww (0.76 μg/g dw). In the current study, the range of concentrations of lead was as much as 18.3 ppm dw (MUL31RIVER, fish ID 8), with the three most elevated values (range of 3.46–5.31 μg/g ww) coming from mullet from the Mississippi River. Biomarker data are measurable and directly reflect the condition of the animal, and measuring more than one biomarker in an individual increases confidence in health assessments. In the current study, biomarkers included macrophage aggregates (MAs), liver (hepatosomatic index [HSI]) and spleen (splenosomatic index [SSI]) weight to body weight ratios, percent white blood cells (WBCs) in whole blood, and condition factor. Few significant differences were noted with any of the biomarkers between sites, and there were no relationships between species and sites. For improved use of biomarker assessments, an increase in fish sample size would be useful for postdiversion sampling, as would comparisons of fish of the same sex and reproductive condition. During the current study, success for eagle nests in the diversion area and reference sites was similar as determined by numbers of nestlings fledged. When temperatures were below average during winter 2000, nests in both regions similarly failed. At each nest, the primary evidence of food items was small mammals. Eaglets (n = 6) generally appeared healthy, and whole blood concentrations of organic contaminants exceeded detection limits with three incidences of p,p’ -DDE (0.002–0.006 μg/L ww) and one incidence of oxychlordane (0.002 μg/L ww). The levels of p,p’ -DDE were well below those that have been inversely correlated with productivity and success rates of nesting bald eagles on a regional scale. The low values found in the whole blood samples for OC pesticides and PCBs were even lower when corrected for plasma volume. Aluminum values were 3.66 and 5.75 μg/L in two samples, zinc ranged from 5.21 to 6.77 μg/L ww in six samples, and silicon ranged from 1.7 to 4.6 μg/L in four samples. Selenium was detectable in each bird with the range at 0.332–0.566 μg/L ww, and strontium ranged from 0.0581 to 0.0975 μg/L ww. Mercury was detectable in blood samples from each bird and ranged from 0.0254 to 0.0845 μg/L ww, whereas lead was detectable in four samples and ranged from 0.0042 to 0.0136 μg/L ww. Although no detectable levels of total PCBs were found (also correlated with decreased reproductive productivity), 70 percent of the aquatic animals from the Mississippi River contained total PCBs (range 0.13–0.79 μg/L), whereas only about 7 percent of the aquatic animals sampled from the marsh area contained PCBs. Suggestions for postdiversion sampling include lowering the analytical detection limit for some metals, sampling aquatic animals over the course of a single season, obtaining a higher sample number of mature fish of one species (for example, blue catfish) within a range of total lengths for biomarker analyses, obtaining otoliths for estimating fish ages, assessing dioxins in eaglet blood, examining triazines in water, and obtaining all Mississippi River fish samples as close to the Davis Pond structure intake as possible. Because contaminants found in blood of eaglets reflect their prey species and because of the contaminant levels found in fish in the current study, eaglets may not be consuming primarily these species; therefore, obtaining juvenile nutria ( Myocastor coypus ) or turtle species for contaminant analyses might be considered, as well as collecting greater blood volume and using plasma to measure OCs and PCBs. Data obtained postdiversion will be compared with prediversion data to monitor changes.

Louisiana↗