Mechanisms controlling world water chemistry: Evaporation-crystallization process
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Science↗
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Lunar surface chemistry: A new imaging technique
Detailed chemical maps of the lunar surface have been constructed by applying a new weighted-filter imaging technique to Apollo 15 and Apollo 16 x-ray fluorescence data. The data quality improvement is amply demonstrated by (i) modes in the frequency distribution, representing highland and mare soil suites, which are not evident before data filtering and (ii) numerous examples of chemical variations which are correlated with small-scale (about 15 kilometer) lunar topographic features.
Science↗
Age and chemistry of mesozoic and tertiary plutonic rocks in south-central Alaska
On the basis of potassium-argon mineral ages, plutonic rocks in an area of approximately 22,000 square miles in the southern Alaska Range and the Aleutian Range can be assigned to age groups that show differences in chemical characteristics and geographic distribution. The plutonic groups are Early and Middle Jurassic, Late Cretaceous and early Tertiary, and middle Tertiary in age. Most of the plutonic rocks in the Aleutian Range south of Iliamna Lake appear to be Jurassic, but north of Iliamna Lake, Jurassic plutonic rocks seem to be restricted to a belt on the southeast side of the Chigmit Mountains—Alaska Range. In the western or northwestern part of the Alaska Range north of Iliamna Lake, only Cretaceous and Tertiary plutonic rocks have been found. Rocks rich in K-feldspar are predominant in the Cretaceous and Tertiary plutons, but subordinate in the Jurassic plutons. Most of the mineralization in the region is associated with the Cretaceous and Tertiary plutons.
GSA Bulletin↗
Age and chemistry of tertiary volcanic rocks in north-central Arizona and relation of the rocks to the Colorado Plateaus
During late Miocene (14.8 m.y.) to early Pliocene (10.1 m.y.) time, local latite and widespread basaltic flows accumulated with associated continental sedimentary deposits in north-central Arizona. Some of these rocks were displaced and tilted by normal faults, and new drainage, now occupied in part by basalt flows of late Pliocene age (average 5 m.y., maximum of 6 m.y.), was established at the southern margin of the Colorado Plateaus. The time of faulting and uplift of the Colorado Plateaus in this region is thus bracketed between about 10.1 and 6 m.y. ago. Five analyzed basalts fall within the tholeiitic basalt field of the alkali-silica diagram and twenty are in the alkalic basalt field; in general, they are similar to other alkali-olivine basalts from the western United States.
Arizona↗
Alaska-Aleutian range batholith: Geochronology, chemistry, and relation to circum-Pacific plutonism
Potassium-argon mineral ages and reconnaissance mapping of approximately 65,000 sq km in south-central Alaska indicate that the Mesozoic and Cenozoic plutonic rocks in the region were emplaced during three discrete intrusive epochs. Most of the plutonic rocks are part of the Alaska-Aleutian Range batholith; the remainder appear as outcrops in isolated plutons northeast of the main batholith. Maximum and minimum concordant mineral ages on coexisting biotite and hornblende are used to mark the beginning and ending, respectively, of each intrusive epoch. The oldest intrusive epoch, Early and Middle Jurassic, contains plutonic rocks emplaced between about 176 and 154 m.y. ago. Jurassic plutonism occurred along a magmatic arc at least 1,300 km long, extending from about 480 km southwest of Becharof Lake northeast to the Talkeetna Mountains. Aeromagnetic data suggest that the magmatic arc, which represents the roots of the arc portion of an early Mesozoic arc-trench system, also continues southwest into the Bering Shelf. The associated trench is thought to be represented by an imbricated mélange of ophiolite and submarine lava with associated chert and argillite that occupies a belt 140 km southeast of the magmatic arc. Clastic sediments more than 4.5 km thick occupy the 140-km-wide arc-trench gap. Late Cretaceous and early Tertiary plutonic rocks, emplaced between about 83 and 58 m.y. ago, are found mainly in the northern part of the batholith and in isolated plutons to the northeast toward Mount McKinley. Middle Tertiary plutonic rocks ranging in age from 38 to 26 m.y. occur in two areas within the batholith and also in the Mount McKinley area. Although some of the Late Cretaceous and Tertiary plutons are associated with extrusive rocks, these plutons are largely post-tectonic, and magma was generated beneath both stable platform areas as well as beneath former eugeosynclinal regions in which deformation had essentially ceased. Magma for the Jurassic plutonic rocks appears to have been generated along or above an early Mesozoic subduction zone. The region southeast of the zone is considered to represent a classic example of continental accretion of eugeosynclinal sediments caused by under-thrusting of oceanic crust beneath an island arc. Magma generation for the Cretaceous and Tertiary plutons in the northern part of the batholith does not appear related to the early Mesozoic subduction zone, for it would require that the zone shift inland, or toward the continent, from its position during the Jurassic and then shift away from the continent once again to its present position.
GSA Bulletin↗
Composition and phase chemistry of sulfide globules in basalt from the Mid-Atlantic Ridge rift valley near 37°N lat
The electron microprobe was used to determine the bulk composition of immiscible sulfide globules trapped in the glass phase of 25 fresh submarine basalt samples from the Mid-Atlantic Ridge. Twenty-three samples represent a spectrum of primitive through differentiated tholeiites from the FAMOUS dive area; two are differentiated basalts from the Reykjanes Ridge. The analyzed globules range in diameter from 11 to 233 µm. On the average, they constitute only 0.0022 volume percent of the rocks and contain less than 1.5 percent of the sulfur. Compositions of the globules change with differentiation as measured by Fe/(Fe+Mg) or TiO 2 content of the host glass. Globules in glass containing 0.66 to 1.0 wt percent TiO 2 typically contain 20 to 26 wt percent Ni + Cu and have an average atomic Ni/Cu of 1.6. With differentiation toward 1.6 wt percent TiO 2 , Ni + Cu content of the globules falls to less than 10 wt percent and atomic Ni/Cu falls to 0.4. Sulfur content of the host glasses shows a strong correlation with FeO content, increasing from 840 ppm to 1,370 ppm as FeO content increases from 8.0 to 12.6 wt percent. Reference to experimental studies shows that this relationship is consistent with sulfur saturation of the host glass at liquidus temperatures. Crystal fractionation is considered to be the dominant factor in keeping the differentiating melt at sulfur saturation. The sulfide globules may have persisted in the basaltic melt from its place of formation by partial melting in the mantle, or they may have exsolved from the melt as it became sulfur-saturated in a high-level magma chamber. Globule abundance and composition indicate adjustment to the composition of the melt in which they were trapped. Material balance calculations suggest that one-third of the Cu and commensurate amounts of S, Ni, and Fe have settled from the magma as immiscible globules. The sulfide globules contain less than 4 wt percent magnetite, compatible with low f o2 in the magma. Three sulfide phases coexisted in the globules at about 600 °C: monosulfide solid solution, intermediate solid solution, and pentlandite. At lower temperatures, the intermediate solid solution has broken down, and the monosulfide solid solution has exsolved a second generation of pentlandite.
GSA Bulletin↗
Age, chemistry, and correlations of Neoproterozoic–Devonian igneous rocks of the Arctic Alaska–Chukotka terrane: An overview with new U-Pb ages
The Arctic Alaska–Chukotka terrane is a microcontinent with an origin exotic to Laurentia. We used a sensitive high-resolution ion microprobe (SHRIMP) to date nine samples of Neoproterozoic rock and five samples of Devonian rock from the Brooks Range and Seward Peninsula of Alaska and from the Chukotka Peninsula of northeastern Russia. Felsic magmatism occurred at 968 Ma and 742 Ma in the Brooks Range and at 865 Ma and 670–666 Ma on Seward Peninsula. Felsic igneous rocks in Chukotka were dated at 656 Ma and 574 Ma. Devonian igneous rocks are found throughout the Arctic Alaska–Chukotka terrane, and we dated samples with ages of 391 Ma, 390 Ma, 385 Ma, 371 Ma, and 363 Ma. The felsic character of the Neoproterozoic rocks suggests formation at least in part through crustal melting. The age of the crustal source rocks that melted to form the Neoproterozoic rocks is inferred to be Mesoproterozoic based on Nd model ages ranging from 1.6 to 1.4 Ga. Rocks of this age range have been reported from the basement of Baltica but are rare in Laurentia. The 565 Ma orthogneisses on Seward Peninsula have ca. 1.1 Ga Nd model ages. Devonian igneous rocks have a wide range of model ages ranging from 1.6 to 0.8 Ga. The tectonic setting of the 968 Ma, 865 Ma, and 742 Ma rocks is unknown. The ca. 670 Ma magmatism on Seward Peninsula is interpreted to have occurred in an arc setting based on geochemistry and similarities in their ages to the Avalonian–Cadomian arc system peripheral to Gondwana. Latest Neoproterozoic magmatism is inferred to have occurred in a rift setting based on composition and the Paleozoic passive margin sequence that was deposited across the Arctic Alaska–Chukokta terrane. Devonian magmatism likely occurred in an arc and/or backarc rift setting. Significant uncertainties remain concerning the age of the Arctic Alaska–Chukotka terrane basement, particularly the age of the host rocks for Neoproterozoic intrusions.
Alaska↗
Trace element chemistry of zircons from oceanic crust: A method for distinguishing detrital zircon provenance
We present newly acquired trace element compositions for more than 300 zircon grains in 36 gabbros formed at the slow-spreading Mid-Atlantic and Southwest Indian Ridges. Rare earth element patterns for zircon from modern oceanic crust completely overlap with those for zircon crystallized in continental granitoids. However, plots of U versus Yb and U/Yb versus Hf or Y discriminate zircons crystallized in oceanic crust from continental zircon, and provide a relatively robust method for distinguishing zircons from these environments. Approximately 80% of the modern ocean crust zircons are distinct from the field defined by more than 1700 continental zircons from Archean and Phanerozoic samples. These discrimination diagrams provide a new tool for fingerprinting ocean crust zircons derived from reservoirs like that of modern mid-ocean ridge basalt (MORB) in both modern and ancient detrital zircon populations. Hadean detrital zircons previously reported from the Acasta Gneiss, Canada, and the Narryer Gneiss terrane, Western Australia, plot in the continental granitoid field, supporting hypotheses that at least some Hadean detrital zircons crystallized in continental crust forming magmas and not from a reservoir like modern MORB. ?? 2007 The Geological Society of America.
Geology↗
Spatio-temporal variability in movement, age, and growth of mountain whitefish ( Prosopium williamsoni ) in a river network based upon PIT tagging and otolith chemistry
Connectivity of river networks and the movements among habitats can be critical for the life history of many fish species, and understanding of the patterns of movement is central to managing populations, communities, and the landscapes they use. We combined passive integrated transponder tagging over 4 years and strontium isotopes in otoliths to demonstrate that 25% of the mountain whitefish ( Prosopium williamsoni ) sampled moved between the Methow and Columbia rivers, Washington, USA. Seasonal migrations downstream from the Methow River to the Columbia River to overwinter occurred in autumn and upstream movements in the spring. We observed migration was common during the first year of life, with migrants being larger than nonmigrants. However, growth between migrants and nonmigrants was similar. Water temperature was positively related to the proportion of migrants and negatively related to the timing of migration, but neither was related to discharge. The broad spatio-temporal movements we observed suggest mountain whitefish, and likely other nonanadromous fish, require distant habitats and also suggests that management and conservation strategies to keep connectivity of large river networks are imperative.
Washington↗
Complex interactions of deer herbivory, soil chemistry, and competing vegetation explain oak–hickory forest tree regeneration in central Pennsylvania, USA
The root causes of forest tree regeneration failure are difficult to resolve, although numerous studies show ungulate herbivory, soil conditions, and competition from undesirable vegetation as likely contributors. To better understand the relative importance of each issue, we conducted a 7-year manipulative experiment to assess the interactive effects of white-tailed deer ( Odocoileus virginianus ) herbivory, soil acidity, and competing vegetation on tree regeneration in oak–hickory forests of central Pennsylvania, USA. Outcomes depended on initial tree seedling abundance, and all three factors had significant interactions. At low initial seedling abundance, fencing resulted in the greatest increase, but all treatments had a positive effect on seedling growth and abundance. At higher initial seedling abundance, abundance failed to recover 7 years after herbicide treatment and soil pH was an important predictor. When soil pH was >4.6 from lime application, seedling growth and abundance in unfenced controls with high initial abundance was comparable to the fenced-only treatment. Competing vegetation, assumed to be a symptom of excessive, long-term deer herbivory, does not seem to be the primary factor limiting tree regeneration in our study area. Ameliorating acid deposition warrants greater consideration as a management action because it could provide long-lasting benefits compared to short-term fence installations.
Pennsylvania↗
Fluid chemistry and evolution of hydrothermal fluids in an Archaean transcrustal fault zone network: The case of the Cadillac Tectonic Zone, Abitibi greenstone belt, Canada
Detailed fluid geochemistry studies on hydrothermal quartz veins from the Rouyn-Noranda and Val-d'Or areas along the transcrustal Cadillac Tectonic Zone (CTZ) indicate that unmineralized (with respect to gold) sections of the CTZ contained a distinct CO2-dominated, H2S-poor hydrothermal fluid. In contrast, both gold mineralized sections of the CTZ (e.g., at Orenada #2) and associated higher order shear zones have a H2O-CO2 ?? CH4-NaCl hydrothermal fluid. Their CO2/H2S ratios indicate H2S-rich compositions. The Br/Cl compositions in fluid inclusions trapped in these veins indicate that hydrothermal fluids have been equilibrated with the crust. Oxygen isotope ratios from hydrothermal quartz veins in the CTZ are consistently 2??? more enriched than those of associated higher order shear zones, which are interpreted to be a function of greater fluid/rock ratios in the CTZ and lower fluid/rock ratios, and more efficient equilibration of the hydrothermal fluid with the wall rock, in higher order shear zones. An implication from this study is that the lower metal endowment of the transcrustal CTZ, when compared with the higher metal endowment in higher order shear zones (ratio of about 1 : 1000), may be the result of the lack of significant amounts of H2O-H2S rich fluids in most of the CTZ. In contrast, gold mineralization in the higher order shear zones appear to be controlled by the high H2S activity of the aqueous fluids, because gold was likely transported in a bisulfide complex and was deposited during sulfidation reactions in the wall rock and phase separation in the quartz veins. ?? 2007 NRC Canada.
Canadian Journal of Earth Sciences↗
Ferromanganese deposits from the Gulf of Alaska Seamount Province: Mineralogy, chemistry, and origin
Ferromanganese-oxide deposits dredged from four seamounts (Welker, Miller, Murray, and Patton) in the Gulf of Alaska Seamount Province include poorly crystallized microlaminated crusts on basalt substrate, well-crystallized Mn-oxide veins in epiclastic sedimentary rocks, and crystalline Mn-oxide layers and micronodules in phosphorite. The principal rock types dredged are alkali-basalt pillow fragments and tuffaceous conglomerate and sandstone. The glassy rims of pillow fragments, the glassy goundmass of large volcanic clasts, and the tuffaceous component of the sediment are altered to palagonite. Other low-temperature alteration products include phillipsite, smectite, and carbonate-apatite.Thick (10–50 mm) Fe–Mn crusts consist mainly of δ-MnO 2 ; straight and cuspate growth laminae indicate variable growth rates and periods of nondeposition. A larger number of detrital particles toward the top of thick crusts record the increasing influence of active volcanoes of the Aleutian arc during northwestward movement of the Pacific plate. Thick crusts on basalt substrate have higher Mn/Fe ratios and lower Co content than Fe–Mn crusts from low-latitude seamounts of the central Pacific region. Thin (< 10 mm) crusts on volcaniclastic substrate contain todorokite and birnessite and have higher Mn/Fe ratios, Ni, and Cu and lower Fe and Co than thick Gulf of Alaska crusts.Veins of todorokite and cryptomelane with complex internal structure occur in altered tuffaceous sandstone and conglomerate from Miller Seamount. Fibrous todorokite has a composition similar to those of other marine examples but may contain up to 7% Mn 2+ in M2 sites. Microprobe analysis of the marine cryptomelane indicates a composition that is approximately (K,Ba) 1–2 (Mn 4+ ,Co) 7–8 O 16 ∙ x (H 2 O).A third type of Fe–Mn deposit in phosphorite is an intimate mixture of todorokite (and minor δ-MnO 2 )-bearing layers and micronodules, carbonate-apatite, and phillipsite that encloses grains of altered volcanic glass and lithic fragments.The microlaminated structure, mineralogy (predominantly δ-MnO 2 ), and composition (Mn/Fe ratio and transition metal, rare earth element, U, and Th contents) of the thick crusts are characteristic of hydrogenetic Fe–Mn crusts elsewhere in the Pacific. Conversely, the crystallinity and chemical composition of the Mn-oxide veins and thin crusts indicate formation during diagenesis of the volcanogenic sediment substrate. Mn and other transition metals are mobilized during low-temperature oxidative alteration (palagonitization) of basaltic volcanic glass; the oxidation of Fe 2+ to Fe 3+ during palagonitization and the dissolution of the dilute biogenic fraction of the sediment combine to lower the Eh of ambient pore fluid and enhance the mobility of Mn 2+ . Diagenesis in the phosphatic sandstone from Patton Seamount involves organic-rich sediment and pore waters elevated in phosphorus owing to upwelling above a large volcanic edifice.
Alaska↗
Some blood chemistry values for the Rainbow Trout (Salmo gairdneri)
Normal distribution curves were graphically fitted to approximately 1400 clinical test values obtained from the plasma or kidney tissue of more than 200 yearling rainbow trout ( Salmo gairdneri ). Estimated normal ranges were ascorbate, 102–214 μg/g; blood urea nitrogen (BUN), 0.9–4.5 mg/100 ml; chloride, 84–132 mEq/liter; cholesterol, 161–365 mg/100 ml; cortisol, 1.5–18.5 μg/100 ml; glucose, 41–151 mg/100 ml; and total protein, 2–6 g/100 ml.
Journal of the Fisheries Research Board of Canada↗
Vitality and chemistry of roots of red spruce in forest floors of stands with a gradient of soil Al/Ca ratios in the northeastern United States
Number of living root tips per branch, percent dead roots, percent mycorrhizae and mycorrhizal morphotype, response of woody roots to wounding and colonization by fungi, and concentrations of starch, soluble sugars, phenols, percent C and N and C/N ratio, and Al Ca, Fe, K, Mg, Mn, and P were measured for 2 consecutive years in roots of red spruce (Picea rubens Sarg.) in stands in the northeastern United States (nine in 1993 and two additional in 1994) dominated by red spruce and with a gradient of forest floor exchangeable Al/Ca ratios. Root vitality was measured for nonwoody and coarse woody roots; chemical variables were measured for nonwoody (<1 mm), fine woody (1 to <2 mm), and coarse woody (2 to <5 mm) roots. There were significant differences among sites for all variables, particularly in 1993, although few were related to the Al/Ca ratio gradient. Percent mycorrhizae decreased, while some morphotypes increased or decreased as the Al/Ca ratio increased. In nonwoody roots, N increased as the Al/Ca ratio increased. Most sampled trees appeared to be in good or fair health, suggesting that an adverse response of these root variables to high Al concentrations may be apparent only after a significant change in crown health.
Canadian Journal of Forest Research↗
Diagenesis, compaction, and fluid chemistry modeling of a sandstone near a pressure seal: Lower Tuscaloosa Formation, Gulf Coast
Petrographic, isotopic, and fluid-inclusion evidence from normally and overpressured sand-stones of the lower Tuscaloosa Formation (Upper Cretaceous) in the Gulf Coast documents quartz-overgrowth precipitation at 90°C or less, calcite cement precipitation at approximately 100° and 135°C, and prismatic quartz cement precipitation at about 125°C. Textural evidence suggests that carbonate cement dissolution occurred before the second phases of calcite and quartz precipitation, and was followed by precipitation of grain-rimming chlorite and pore-filling kaolinite. Geochemical calculations demonstrate that present-day lower Tuscaloosa Formation water from 5500 m depth could either dissolve or precipitate calcite cements in model simulations of upward water low. Calcite dissolution or precipitation depends on P CO2 variability with depth (i.e., whether there is one or two-phase flow) or on the rate of generation of CO 2 with depth. Calculations suggest that 10 5 -10 6 rock volumes of water are required to flow through the section to precipitate 1-10% calcite cement. Compaction analysis suggests that late-stage compaction occurred in normally pressured sandstones after dissolution of carbonate cements, but was hindered in overpressured sandstones despite the presence of high porosity. These results document the inhibition of compaction by overpressured fluids and constrain the timing of pressure seal formation. Modeling results demonstrate that the proposed paragenesis used to constrain timing of pressure seal formation is feasible, and that most of the cement diagenesis occurred before the pressure seal became effective as a permeability barrier.
Louisiana↗
Chemistry of illite/smectite and end-member illite
Chemical data from three different series of diagenetic illite/smectites (I/S), analyzed statistically by two regresion techniques, indicate that the content of fixed-K per illite layer is not constant, but ranges from ∼0.55 per O 10 (OH) 2 for illite layers in randomly interstratified I/S (R=0; > 50% smectite layers) to ∼1.0 per O 10 (OH) 2 for illite layers formed in ordered I/S (R>0; <50% smectite layers). By extrapolation of the experimental data, the following chemical characteristics were obtained for end-member illite derived from the alteration of smectite in bentonite: average fixed-K per illite layer = 0.75 per O 10 (OH) 2 ; total charge = about −0.8; cation-exchange capacity = 15 meq/100 g; surface area (EGME) = 150 m 2 /g.
Clays and Clay Minerals↗