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Characterization of change in tree cover state and condition over the conterminous United States

Variability in the effects of disturbances and extreme climate events can lead to changes in tree cover over time, including partial or complete loss, with diverse ecological consequences. It is therefore critical to identify in space and time the change processes that lead to tree cover change. Studies of change are often hampered by the lack of data capable of consistently detecting different types of change. Using the Landsat satellite record to create a long time-series of land cover and land cover change, the U.S. Geological Survey Land Change Monitoring Assessment and Projection (LCMAP) project has made an annual time series of land cover across the conterminous United States for the period 1985 to 2018. Multiple LCMAP products analyzed together with map validation reference plots provide a robust basis for understanding tree cover change. In LCMAP (Collection 1.2), annual change detection is based on harmonic model breaks calculated at each Landsat pixel from the Continuous Change Detection and Classification (CCDC) algorithm. The results showed that the majority of CCDC harmonic model breaks (signifying change) indicated partial tree cover loss (associated with management practices such as tree cover thinning) as compared to complete tree cover loss (associated with practices like clearcut harvest or fire disturbance). Substantially fewer occurrences of complete tree cover loss were associated with change in land cover state. The area of annual tree cover change increased after the late 1990s and stayed high for the rest of the study period. The reference data showed that tree harvest dominated across the conterminous United States. The majority of tree cover change occurred in evergreen forests. Large estimates of disturbance-related tree cover change indicated that tree cover loss may have previously been underreported due to omission of partial tree cover loss in prior studies. This has considerable implications for forest carbon accounting along with tracking ecosystem goods and services.

Forests

Conceptual hydrogeologic framework and groundwater budget near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This report presents information used to characterize the groundwater-flow system and the development of a numerical model in the AMA. Included are descriptions of the geology and conceptual hydrogeologic framework, groundwater levels and flow directions, groundwater recharge and discharge, numerical groundwater-flow model construction and results, and model limitations. The study area encompasses the western part of Pierce County and the southwestern part of King County, Washington. The study area extends south to the Nisqually River, southwest to Tanwax Creek, northeast to the Green River, and north through the valley near Auburn and adjacent uplands. It is bounded on the east by foothills of the Cascade Range, and on the northwest by Puget Sound.

Washington

U-Pb scheelite ages of tungsten and antimony mineralization in the Stibnite-Yellow Pine district, central Idaho

The Stibnite-Yellow Pine district contains the largest antimony resource in the United States, as well as significant gold, and is a historic producer of tungsten. Application of in situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) direct dating of scheelite from two Au-Sb-W ore deposits, Yellow Pine and Hangar Flats, yielded an older group of U-Pb ages in the range of 60.0 ± 2.8 to 57.0 ± 1.1 Ma and a younger U-Pb age for scheelite intergrown with stibnite of 47.4 ± 1.1 Ma. These in situ analyses were calibrated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb lower intercept ages of two coarsely crystalline scheelite samples that yielded ages of 57.52 ± 0.22 and 56.62 ± 0.16 Ma. Scheelite of the latter age is of sufficient quality to serve as a primary reference material for LA-ICP-MS scheelite U-Pb geochronology. The group of older U-Pb scheelite ages agrees with 40 Ar/ 39 Ar ages of 56.9 ± 1.2 to 56.38 ± 0.54 Ma on adularia from Yellow Pine and Hangar Flats, whereas the younger U-Pb scheelite age is similar to an 40 Ar/ 39 Ar age of 46.00 ± 0.40 Ma on adularia from an epithermal gold-silver deposit in the adjacent Thunder Mountain caldera. Our results indicate that the main stage of tungsten mineralization occurred at ca. 57 Ma, whereas the main stage of antimony mineralization occurred at ca. 47 Ma—thereby providing first-time age constraints for antimony and tungsten mineralization in the Stibnite-Yellow Pine district.

Idaho

Spectral characteristics and mapping of lithium-rich playas in the Basin and Range Province, western United States

This report presents a comprehensive set of prospectivity maps for lithium in brines located within the playas of the Basin and Range Province of western United States. The prospectivity assessment is based on criteria established in the descriptive deposit model outlined in a previous U.S. Geological Survey report, with a focus on regional remote sensing methodologies. The playas within the study area have been systematically ranked according to several key factors, including size, the presence and abundance of source rocks, vegetation as an indicator of water availability, documented prospects, and data products derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor. Notably, the deposits in the playa of Clayton Valley make it stand out as the sole lithium brine-producing playa in the United States. The ASTER sensor provides optimal regional coverage, characterized by a 60-kilometer swath width and unique multispectral capabilities that are not available with other remote sensing instruments. This report and the accompanying maps are intended to serve as resources for further multidisciplinary assessments of lithium or other elements or commodities where prospectivity can be inferred from the presence of proxies such as alteration minerals.

Arizona, Baja California, California, Chihuahua, I

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida

Using probability difference to compare streamflow information of alternatives for efficient operation of monitoring networks

Efficient operation of streamflow monitoring networks requires investments in technology and labor that provide the greatest benefits from available resources. Economic analyses comparing the costs and benefits from different types of alternatives for monitoring have not been practical to implement. Streamflow information provides a generic measure of benefits that can be incorporated into operational decisions as an objective for monitoring networks. A methodology for comparing how accuracy, monitoring period, and monitoring instead of modeling affects streamflow information is developed from information-theoretic approaches for network design but contributes three novel features: (1) a probability-difference model for conditional probability of monotonically paired variables, (2) explicit discounting of unverified information that may exceed the accuracy of streamflow records, and (3) run analysis to account for non-stationarity in streamflow probabilities. Application of the methodology to the U.S. Geological Survey streamflow monitoring network indicates the value of monitoring period to reduce the uncertainty of streamflow probabilities and, thus, increase streamflow information. The methodology has important limitations, particularly for sites with non-perennial streamflow, but demonstrates that probability difference could be used to evaluate operational alternatives to increase the efficiency of monitoring networks.

PLOS Water

Water quality of Rob Roy Reservoir and Lake Owen, Albany County, and Granite Springs and Crystal Lake Reservoirs, Laramie County, Wyoming, 1997-98

The water quality of four reservoirs was assessed during 1997 and 1998 as a cooperative project between the Cheyenne Board of Public Utilities and the U. S. Geological Survey. The four reservoirs, Rob Roy, Lake Owen, Granite Springs, and Crystal Lake, provide approximately 75 percent of the public water supply for Cheyenne, Wyoming. Samples of water and bottom sediment were collected and analyzed for selected physical, chemical, and biological characteristics to provide data about the reservoirs. Water flows between the reservoirs through a series of pipelines and stream channels. The reservoirs differ in physical characteristics such as elevation, volume, and depth. Profiles of temperature, dissolved oxygen, specific conductance, and pH were examined. Three of the four reservoirs exhibited stratification during the summer. The profiles indicate that stratification develops in all reservoirs except Lake Owen. Stratification developed in Rob Roy, Granite Springs, and Crystal Lake Reservoirs by mid-July in 1998 and continued until September, with the thickness of the epilimnion increasing during that time. Secchi disk readings indicated Rob Roy Reservoir had the clearest water of the four reservoirs studied. The composition of the phytoplankton community was different in the upper two reservoirs from that in the lower two reservoirs. Many of the species found in Rob Roy Reservoir and Lake Owen are associated with oligotrophic, nutrient-poor conditions. In contrast, many of the species found in Granite Springs and Crystal Lake Reservoirs are associated with mesotrophic or eutrophic conditions. The total number of taxa identified also increased downstream. The chemical water type in the reservoirs was similar, but dissolved-solids concentrations were greater in the downstream reservoirs. Water in all four reservoirs was a calcium-bicarbonate type. In the fall of 1997, Rob Roy Reservoir had the lowest dissolved-solids concentration (19 milligrams per liter), whereas Crystal Lake Reservoir had the highest concentration (63 milligrams per liter). Relatively little differences in the concentrations of major-ion species were noted between samples collected near the surface and near the bottom of the same reservoir. In contrast, iron and manganese concentrations generally were higher in samples collected near the bottom of a reservoir than in near-surface samples collected from the same reservoir. Composite bottom-sediment samples from all four reservoirs contained similar concentrations of bulk constituents such as aluminum, iron, phosphorus and titanium, but varied in concentrations of trace elements. Trace-element concentrations in Rob Roy Reservoir and Lake Owen were similar to the crustal average, whereas in Granite Springs and Crystal Lake Reservoirs the concentrations were similar to granitic rocks.

Wyoming

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia

Sackung at Bald Eagle ridge, central Colorado: An updated interpretation of ridge-spreading movement, structures, and mechanisms from 50 years (1975–2025) of U.S. Geological Survey research

Slow gravitational failures of mountain peaks and ridges are poorly understood. Herein, we report on 50 years of studies at a slowly spreading castellate ridge in the Sawatch Range in central Colorado. The orientations of geomorphic-structural features indicate that the fractured Precambrian granitic rock underlying the ridge has extended and spread northwestward toward the formerly glacier-covered Busk Creek valley. Results from surveying, field-based geomorphic-structural mapping using lidar, rock mass quality measurements, a passive seismic survey, and satellite radar provide a major update to research started by U.S. Geological Survey researchers in the 1970s and 1980s. New insights include a recognition that the entire ridge has slowly moved by concurrent sliding along an inferred northwest dipping, compound basal-slip surface (or zone), and through the formation of multiple grabens by normal faulting and flexural toppling along sets of pre-existing fractures that dip moderately (∼45°) to the southeast. We were unable to distinguish the presence of a sudden and strong contrast in seismic velocity across the inferred slip surface. Movement during the 50-year study period has been episodic and gradually decreasing, in correspondence with decreasing cumulative annual precipitation and increasing mean annual air temperatures. The fastest moving area, just upslope from the glacier trimline, had an average horizontal velocity of 3 – 4 mm/yr. Evidence suggests that movement started as a paraglacial response mechanism, but because of the site’s proximity to the Rio Grande Rift, we cannot exclude earthquake shaking as a mechanism for initiation or enhancement of slope movement. An estimate of longer-term horizontal movement from the exposed basal-slip surface at the uphill side of the ridgetop graben is ∼1.1 mm/yr for the 13 – 14 ky post-glacial period. Broad implications of our work are that: (1) long-term measurements (decades or longer) of slope movement can add insights into how sackungen form and evolve through time; (2) the identification of thrust faults and toes in zones of compression near valley bottoms can be crucial for interpreting sackung failure mechanisms, and (3) the use of passive-seismic techniques to identify the depth to a slip surface may not be successful in granitic terrain dominated by planar fractures and subtle changes in rock-mass characteristics.

Colorado

Simulated ground-motion records for the seismic assessment of monumental masonry structures

Earthquakes are natural disasters that can cause widespread devastation and loss of life. Simulated ground-motion records can be useful in regions with limited seismic stations or a history of damaging but infrequent earthquakes. This is especially true in areas with a high concentration of heritage masonry structures, which are especially susceptible to damage, as simulated records can be crucial in predicting their seismic response and protecting these buildings from seismic damage. Despite the importance of simulated earthquakes, few studies have investigated how effective they are compared to real earthquakes when assessing the structural response of heritage buildings. To address this knowledge gap, we employ two different simulation methods of the Mw 6.2 Faial earthquake, which occurred on July 9th, 1998, in the Azores, to replicate the recorded time-series at four available stations within an epicentral distance of 150 km. The study has two objectives: first, to validate the simulated records of the 1998 Faial earthquake using alternative stochastic ground-motion simulation approaches, and second, to determine how these approaches impact the seismic assessment of historic masonry structures. To accomplish these objectives, this study uses real and simulated ground-motion datasets to conduct non-linear response history analyses of the São Francisco Church, a monumental structure in Horta that sustained damage during the Faial earthquake. The results show that both simulation approaches yield structural responses similar to the observed records.

Conference Paper

Invasion of perennial sagebrush steppe by shallow-rooted exotic cheatgrass reduces stable forms of soil carbon in a warmer but not cooler ecoregion

Soil organic carbon ('SOC') in drylands comprises nearly a third of the global SOC pool and has relatively rapid turnover and thus is a key driver of variability in the global carbon cycle. SOC is also a sensitive indicator of longer-term directional change and disturbance-responses of ecosystem C storage. Biome-scale disruption of the dryland carbon cycle by exotic annual grass invasions (mainly Bromus tectorum, 'Cheatgrass') threatens carbon storage and corresponding benefits to soil hydrology and nutrient retention. Past studies on cheatgrass impacts mainly focused on total C, and of the few that evaluated SOC, none compared the very different fractions of SOC, such as relatively unstable particulate organic carbon (POC) or relatively stable, mineral-associated organic carbon (MAOC). We measured SOC and its POC and MAOC constituents in the surface soils of sites that had sagebrush canopies but differed in whether their understories had been invaded by cheatgrass or not, in both warm and relatively colder ecoregions of the western USA. MAOC stocks were 36.1% less in the 0–10 cm depth and 46.1% less in the 10–20 cm depth in the cheatgrass-invaded stands compared to the uninvaded stands of the warmer Colorado Plateau, but not in the cooler and more carbon-rich Wyoming Basin ecoregion. In plots where cheatgrass increased SOC, it was via unstable POC. These findings indicate that cheatgrass effects on the distribution of soil carbon among POC and MAOC fractions may vary among ecoregions, and that cheatgrass can reduce forms of carbon that are otherwise considered stable and 'secure', i.e. sequestered.

Environmental Research Communications

Relationship of basin structure and bedrock lithology to faulting in the 2019 Ridgecrest earthquake region, California, from gravity and aeromagnetic data

We investigate patterns of cumulative offsets on the faults that ruptured in 2019 and along the Garlock Fault in the Ridgecrest region, California using recently published gravity and aeromagnetic data. We also examine the relationship of basin structure and bedrock structure to the 2019 M7.1 Ridgecrest earthquake ruptures (Fig. 1A), which were primarily along a dextral northwest-striking fault system, and along a sinistral northeast-striking fault, which ruptured hours earlier with a M6.4 event.

California

Geologic map of the southern Stillwater Range, Nevada

The southern Stillwater Range in west-central Nevada contains the western part of the Oligocene Stillwater-Clan Alpine caldera complex, which extends about 55 kilometers (km) east from the west side of the Stillwater Range to the northwestern Desatoya Mountains. The complex consists of at least seven nested ignimbrite calderas and subjacent plutonic rocks emplaced into a complex basement composed of Mesozoic metasedimentary and metavolcanic rocks and Cretaceous granitic plutons. The calderas formed during large-volume (100s to greater than (>) 2,500 cubic kilometers [km 3 ]) eruptions of silicic ignimbrites between about 30.4 and 25.1 million years before present (Ma). The Job Canyon and Poco Canyon calderas and the western part of the much larger Elevenmile Canyon caldera, and their plutonic roots, are exposed in the southern Stillwater Range. There, the caldera complex was steeply tilted during large-magnitude crustal extension in the middle Miocene, and further exhumed during the late Miocene to Holocene Basin and Range extension that formed the modern Stillwater Range. This tilted crustal section affords an exceptional opportunity to view structural cross sections of ignimbrite calderas and their plutonic roots to paleodepths as much as 9–10 km.

Nevada

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana

Conceptual and numerical groundwater flow model of the Iowa River alluvial aquifer near Tama County, Iowa, 1980 through 2022

The Iowa River alluvial aquifer is an important source of water on the Meskwaki Settlement in Tama County, Iowa, which is land owned by the Sac & Fox Tribe of the Mississippi in Iowa (commonly known as the Meskwaki Nation). The U.S. Geological Survey constructed a groundwater flow model, including a conceptual and numerical model, of the Iowa River alluvial aquifer and underlying hydrogeologic units near the Meskwaki Settlement in Tama County, Iowa, for the period of January 1980–August 2022 to estimate the fraction of water pumped from the Iowa River alluvial aquifer by Meskwaki Settlement wells that is derived from streamflow depletion in the Iowa River and its tributaries. Streamflow depletion is a reduction in streamflow caused by groundwater pumping and includes the interception by groundwater production wells of water that otherwise would have been discharged to streams (called “captured groundwater discharge”) and induced infiltration of streamflow to the production wells. Calibrated model runs were performed with no simulated pumping and simulated pumping only at Meskwaki Settlement wells, and the change in simulated flow rates between the groundwater system and streams for the two model runs represents the amount of streamflow depletion in the Iowa River and tributary streams resulting from pumping at the Meskwaki Settlement wells. Streamflow depletion in the Iowa River and its tributaries as a percentage of simulated pumping at the Meskwaki Settlement wells was calculated by dividing this difference by the total simulated pumping rate for the Meskwaki Settlement wells. The model results demonstrate that the mean monthly streamflow depletion, including induced infiltration and captured discharge, in the Iowa River and its tributary streams as a percentage of mean monthly pumping at the Meskwaki Settlement wells was 97.4 percent and ranged from 65.4 to 112 percent. Of the total streamflow depletion, mean monthly induced recharge was 20.9 percent and ranged from 4.9 to 37.2 percent. Mean monthly captured discharge was 76.5 percent and ranged from 57.1 to 97.1 percent. These results indicate that most of the water pumped from the Meskwaki Settlement wells is the result of streamflow depletion, in the form of both induced infiltration and captured discharge.

Iowa

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee