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At least 55 records · Page 3Linked to original sources
USGS2019

Tectono-magmatic evolution of porphyry belts in the central Tethys region of Turkey, the Caucasus, Iran, western Pakistan, and southern Afghanistan

Exploration in the central Tethys region of Turkey, Armenia, Azerbaijan, Georgia, Iran, and weste rn Pakistan has led to the identification of the giant Reko Diq (24 Mt Cu and 1300 t Au), Sar Cheshmeh (8.9 Mt Cu and 0.46 Mt Mo), Sungun (5.1 Mt Cu and 0.20 Mt Mo), and Kadjaran (4.6 Mt Cu, 0.94 Mt Mo, and 1100 t Au), and 10 other large (1–2 Mt Cu) porphyry deposits including Saindak, Cevizlidere, Teghout, Meiduk, and Halilağa. Continued exploration efforts have also resulted in the development of porphyry-related gold deposits such as Kişladağ (9.6 Moz Au), Çöpler (3.7 Moz Au), Aği Daği (1.7 Moz Au), and Sary Gunay (3.0 Moz Au), and in the generation of several other promising exploration projects. The distribution in space and time of porphyry deposits in the central Tethys region was shaped by complex pre- to post-mineral tectonic, igneous, collisional, uplift and burial events. These events are represented by a partially-overlapping and variably exhumed and covered collage of twenty-six Early Jurassic to Holocene magmatic belts permissive for the occurrence of porphyry deposits (porphyry tracts and sub-tracts). Twelve tracts or sub-tracts are characterized by compressional continental arcs that formed on drifting terranes or continental margins, 10 developed in compressional to extensional intra-oceanic arc and backarc-rift settings, and 4 formed in extensional post-collisional environments over amalgamated terranes. Eight of these belts were variably affected by coeval and younger metamorphic, fold-and-thrust, and extensional faulting events. Fifty-four porphyry Au-(Cu), Cu-Au, Cu-Mo, Mo-Cu deposits, 15 porphyry-related Au, Au-(Mo) and W-(Mo-Au) deposits, 239 porphyry prospects, and 68 other porphyry-related mineral sites were identified in the study region. Of the 376 porphyry and porphyry-related sites, about 11% formed in island arc, 42% in continental arc, 20% in backarc, and 27% in post-collisional settings. Of the 69 porphyry and porphyry-related deposits, 7% developed in intra-oceanic arc, 41% in continental arc, 27% in backarc, and 25% in post-collisional settings. The largest occur in either compressional continental arc (18 deposits including the Reko Diq and Sar Cheshmeh giants) or post-collisional (13 deposits including the Kadjaran and Sungun giants) environments. Ninety percent of the largest porphyry or porphyry-related deposits occur in only 9 of the 26 permissive porphyry tracts or sub-tracts. Moreover, 88, 90, and 77% of the identified Cu, Mo, and Au resources are contained in porphyry deposits that occur in only 4 of these 9 tracts. Of these 4 tracts, 3 outline arc settings, and one delimits a post-collisional environment. The compositional diversity of porphyry intrusions in these tectono-magmatic environments generally varies from island arc settings with the most restricted range (partly alkaline but mainly calc-alkaline dioritic to granodioritic-tonalitic), to continental arc (calc-alkaline dioritic-quartz dioritic, granodioritic, quartz monzonitic-granitic, and less commonly mildly alkaline), to backarc (mildly alkaline and calc-alkaline dioritic to granitic), to post-collisional settings with the most expansive range (alkaline and calc-alkaline mafic to felsic, and weakly peraluminous). Metal associations also vary broadly as a function of porphyry intrusion composition from weakly peraluminous to metaluminous felsic (Mo[±W ± Cu]; <2% of porphyry-related systems [i.e., Tyrnyauz]), to metaluminous felsic and intermediate (Cu-Mo[±Au]; 85% [i.e., Cevizlidere, Haft Cheshmeh, Kahang, Sar Cheshmeh, Sungun, Teghout, Reko Diq, Saindak]), to mildly alkaline felsic and intermediate (Cu-Au[±Mo] [i.e., Agarak, Kadjaran, Kale Kafi]) and mafic (Au-Cu; 12% [i.e., Çöpler]), and to alkaline felsic (Au-Mo; 1% of porphyry-related systems [i.e., Kişladağ). Tectonic changes were critical in triggering the formation of large porphyry deposits in the region. Large porphyry deposits were preferentially emplaced in continental arc settings shortly before major collisional events (Dar Alu, Kahang, Meiduk, Now Chun, and the giant Sar Cheshmeh and Reko Diq deposits), or in post-subduction environments shortly after collision (Bakirçay, Güzelyayla, Haft Cheshmeh, Masjed Daghi, and the giant Kadjaran and Sungun deposits) or during periods of prominent extension (Aği Daği, Halilağa, Kişladağ, Sari Gunay, and Zarshuran porphyry-related deposits). Collision-induced uplift, erosion, and removal of coeval volcanic rocks favorably exposed the hypabyssal level of subduction-related porphyry deposits. Extensional structures that developed parallel and orthogonal to the compressional principal stress component along transtensional or transpressional strike-slip faults or in pull-apart basins commonly controlled porphyry-related deposits in post-collisional settings. The latter deposits typically exhibit shallow epithermal levels of emplacement because of preservation by burial. Seventeen porphyry deposits and one porphyry-related deposit in the study region are reported to contain significant supergene resources. Relatively mature levels of secondary copper enrichment in dominantly granodioritic to granitic porphyry deposits occur in areas where large pyrite-rich quartz-sericite alteration zones have been preserved and exposed to surface oxidation (Güzelyayla and Ulutaş in northeastern Turkey; Agarak, Ankavan, Dastakert, Kadjaran, and Teghout in Armenia; Ali Javad in northern Iran; Kale Kafi in central Iran; Darreh Zar, Meiduk, Now Chun, and Sar Cheshmeh in southeastern Iran; and Tanjeel in southwestern Pakistan). Chalcocite blankets also developed over porphyry deposits in regions where significant post-mineral faulting has occurred (Muratdere and Sarıçayıryayla in western Turkey). Normal faulting also enhanced secondary enrichment of gold in the Halilağa porphyry and Sary Gunay porphyry-related deposits located respectively in western Turkey and northern Iran. Evaluation of provincial as well as local controls strongly suggests that continued exploration in the region will lead to the identification of additional porphyry and porphyry-related deposits. These deposits will likely be found under younger cover formations in porphyry belts that are already known, and in association with superjacent high- and intermediate-sulfidation epithermal deposits, or increasingly peripheral skarn, carbonate-replacement, and sediment-hosted deposits. Application of suitable exploration techniques to detect concealed and/or deformed deposits in porphyry belts that remain under-explored may also prove productive.

Tethys region↗
USGS2019

Calcrete uranium deposits in the Southern High Plains, USA

The Southern High Plains (SHP) is a new and emerging U.S. uranium province. Here, uranyl vanadates form deposits in Pliocene to Pleistocene sandstone, dolomite, and limestone. Fifteen calcrete uranium occurrences are identified; two of these, the Buzzard Draw and Sulfur Springs Draw deposits, have combined in-place resources estimated at about 4 million pounds of U 3 O 8 . Ore minerals carnotite and finchite are hosted in dolomite at the Sulfur Springs Draw deposit, with accessory fluorite, celestine, smectite/illite, autunite, and strontium carbonate. Host carbonate at the Sulfur Springs Draw deposit is ∼190 ka and mineralization mobilized as recently as 3.8 ka. Ash collected near the deposit is 631 ka and erupted from the Yellowstone caldera complex. The Triassic Dockum Group that contains sandstone-hosted uranium deposits throughout the region and underlies the SHP is a potential source for uranium and vanadium. Regional uplift and dissection reintroduced oxygenated groundwater into the Dockum Group, mobilizing uranium. Additional uranium may have been contributed to groundwater by weathering of volcanic ash in Pliocene and Pleistocene host rocks. The locations of the uranium occurrences are mostly in modern drainage systems in the southeast portion of the SHP. Modelling of modern groundwater in the SHP carried out in a parallel study shows that a single fluid could form carnotite through evaporation, and that fluids of the requisite composition are more prevalent in the southern portion of the SHP. The southeastern portion of the SHP hosts more uranium occurrences due to a variety of factors including (1) upward transport of groundwater and connectivity between source and host rock, (2) higher uranium and vanadium content of groundwater, (3) higher rates of groundwater recharge in this region to drive the mineralizing system, and (4) shallower groundwater facilitating surface evaporation. Ongoing erosion of host rocks challenges preservation of deposits and may limit their size.

Southern High Plains↗
USGS2019

Crustal architecture beneath the southern Midcontinent (USA) and controls on Mesoproterozoic iron-oxide mineralization from 3D geophysical models

Several types of critical mineral-bearing ore deposits in the southern Midcontinent region of the U.S. are hosted in Mesoproterozoic igneous rocks largely concealed beneath Paleozoic cover. Discerning the architecture of igneous intrusions and volcanic centers in the crust is fundamental to understanding the geologic evolution of this vast region and its mineral resources. To advance the understanding of the geologic framework beneath the Southeast Missouri Iron Metallogenic Province, we invert continental-scale magnetic and gravity anomaly data to three-dimensional (3D) physical property models. The regional models image altered and mineralized igneous rocks near the Precambrian basement surface and underlying intrusive complexes that extend down to the Moho. At shallow crustal levels, our models confirm that iron oxide-apatite ± rare earth element (IOA±REE) deposits and iron oxide-copper-gold ± cobalt (IOCG) deposits occur within or near the edges of large low density/low susceptibility early Mesoproterozoic (ca 1.4 Ga) silicic calderas and (ca 1.3 Ga) granitic plutons. Previous isotopic and geochemical studies conclude that the iron deposits and their volcanic host rocks originated from mantle-derived and crustal melts that erupted during regional extension. Extension was associated with thermal event(s) that produced the large-scale silicic magmatism related to the ca 1.45 Ga Eastern Granite Rhyolite Province (EGRP) and the 1.35 Ga Southern Granite Rhyolite Province (SGRP). We postulate that early in the evolution of the EGRP, several trans-crustal magmatic plumbing systems developed that are evident in the 3D models. The Southeast Missouri Metallogenic Province is underlain by one such magmatic system that is expressed as a northwest-trending ~ 50 km-wide by 200 km-long elongate track of high susceptibility at deep crustal levels. The high susceptibility corridor splays upward through the crust to the Precambrian surface where the iron deposits are the epigenetic manifestation of this magmatic event. Our findings confirm that the iron deposits, with no distinct connection at the surface, are connected to one large magmatic system at depth. We propose that other similar susceptibility tracks, which are present along the top of the mantle, mark additional feeder zones that allowed magma to ascend to the main eruptive centers that produced the Granite Rhyolite Provinces. The early Mesoproterozoic extensional tectonic framework established crustal-scale pathways that controlled the distribution of subsequent magmatic activity, including the ca 1.4 Ga calderas and underlying intrusions, ca 1.3 Ga silicic plutons and Phanerozoic alkaline intrusions. If these interpretations are correct, our study has identified large areas that are prospective for critical mineral-bearing ore deposits and, importantly, suggests that the Mesoproterozoic architecture may have influenced subsequent magmatism and hydrothermal activity in the southern Midcontinent of the U.S.

Ore Geology Reviews↗
USGS2020

Apatite trace element geochemistry and cathodoluminescent textures—Acomparison between regional magmatism and the Pea Ridge IOA-REE andBoss IOCG deposits, southeastern Missouri iron metallogenic province, USA

The southeast Missouri iron metallogenic province contains a remarkable wealth of historically important Fe, Cu, Au, and rare earth element (REE) deposits including the Pea Ridge iron oxide-apatite-rare earth element (IOA-REE) deposit and the Boss iron oxide-copper-gold (IOCG) deposit. These deposits are coeval with silicic and intermediate composition magmatism in the St. Francois Mountains terrane. Magmatism, iron-oxide (±Cu, Au, Co) and apatite formation, and REE mineralization overlapped in space and time, but the specific role of regional magmatism in the metallogenesis of these deposits remains unclear and basic petrogenetic models are still debated. We report results from high-spatial resolution textural and geochemical analyses of apatite from regional igneous and ore rocks to elucidate their petrogenetic histories and evaluate deposit models. Backscattered electron and spectral cathodoluminescence imaging of apatite reveal no primary igneous zoning, but show different domains with intricate rims and dissolution/reprecipitation textures, each with distinctive REE patterns in many samples. Apatite from all samples are nearly endmember fluorapatite containing up to ~1.3 wt% Cl and F/Cl ratios span nearly three orders of magnitude. Fresh igneous fluorapatite contain low Na2O (0.15 wt%) while most Pea Ridge ore samples contain higher Na2O (up to ~0.45 wt%), and concentrations of sulfur in fluorapatite of all types are generally moderate to low (0.3 wt% SO3). Significant amounts of Fe (60,000 ppm), Mg (30,000 ppm), Mn (7,000 ppm), and Sr (12,000 ppm) are contained in fluorapatite of all sample types, and they also have moderate amounts of As (4,000 ppm), Ba (2,000 ppm), Th (400 ppm), and U (80 ppm). Fluorapatite show an extraordinarily large range of REE (~0.1-2.0 wt%) and Y (~100-7000 ppm) concentrations. While fresh igneous fluorapatite share many geochemical features with metasomatized igneous fluorapatite and ore-stage fluorapatite from the Pea Ridge IOA and Boss IOCG ore zones, they also have distinct geochemical signatures that are indicative of unique trace element partitioning and substitution mechanisms. These distinguishing textural and geochemical signatures preclude ore-zone fluorapatite genesis directly from a magma (i.e., crystallization directly from a silicate melt) but are permissive of ore-zone fluorapatite formation by magmatic-hydrothermal fluids derived from the regional magmas. Basinal brines may play an important role in the formation of fluorapatite, especially from the Pea Ridge hematite and Boss magnetite-rich zones. Fluorapatite from different ore zones likely formed by crystallization during pulses of hydrothermal fluids with varying Cl-, Na-, and F-contents, which fundamentally controlled the carrying capacity and solubility of REE+Y and generated geochemically distinctive generations of fluorapatite. Exploration geologists using fluorapatite trace element geochemistry to identify IOA and IOCG deposits should proceed with caution, as more high-quality data from these deposits are needed to improve multivariate discrimination analysis. Fluorapatite from IOA/IOCG deposits can be reasonably discriminated from that of other mineral deposit types (e.g., porphyry/epithermal, skarn, orogenic), but no criteria successfully discriminate yet between IOA and IOCG deposits.

Missouri↗
USGS2020

Mineral deposits of the Mesoproterozoic Midcontinent Rift system in the Lake Superior region – A space and time classification

The Mesoproterozoic Midcontinent Rift System (MRS) of North America hosts a diverse suite of magmatic and hydrothermal mineral deposits in the Lake Superior region where rift rocks are exposed at or near the surface. Historically, hydrothermal deposits, such as Michigan’s native copper deposits and the White Pine sediment-hosted stratiform copper deposit, were major MRS metal producers. On-going exploration for and potential development of copper-nickel sulfide deposits hosted by the Duluth Complex of Minnesota and the opening of the Eagle nickel mine in Michigan indicate an expanding interest in MRS magmatic deposits. MRS hydrothermal and magmatic mineral deposits, many of which are significant past, present, and likely future providers of critical minerals, here are placed into a space and time metallogenic framework. To construct this framework, regional MRS mineral deposits extracted from the U.S. Geological Survey Mineral Resources Data System (MRDS) and the Ontario Ministry of Energy, Northern Development and Mines Mineral Deposit Inventory (MDI) were supplemented by other known and recently recognized mineral deposits described in the literature. All mineral deposits were classified by deposit type, host rock age and type, and estimated timing of mineralization. Deposits were then put into a tectonic evolutionary framework (stages) for the MRS, which shows that deposits formed within discrete spatial and temporal stages of rift evolution.

Lake Superior region↗
USGS2021

Mineral deposit discovery order and three-part quantitative assessments

Larger oil pools tending to be discovered earlier in an exploration play suggests the same pattern might exist for mineral deposits and could be used in predicting sizes of undiscovered deposits in mineral assessments. The volume of individual petroleum pools is highly correlated with surface projection area of pools in basins. The gradual additions to individual oil pool reserves over time adds to the appearance of larger pools being discovered earlier. Comparisons of surface projected areas of mineral deposits to their tonnages showed significant positive relationships in all 10 deposit types analyzed, suggesting that larger deposits should be discovered earlier than small deposits. Analysis of deposits consistent with three-part mineral assessments identified 9 combinations of mineral deposit types in large regions each containing multiple geological permissive tracts showing negative and 1 positive relationships of deposit size with discovery date significant at the 1% level. Twenty other tests of regions containing multiple permissive settings had either negative or positive relationships, none significantly different from those that might occur by chance. The large regions are mostly based on political boundaries. These results suggest mineral deposit discovery order is not the same as observed in oil pool exploration. The widely employed three-part quantitative mineral resource assessments are an obvious choice to benefit from patterns of declining deposit sizes with order of discovery. The 30 tests of relationships of discovery dates to deposit sizes demonstrated here were performed with deposits consistent with those in three-part assessments, but the large areas are not consistent with permissive tracts used in these assessments because they also contain substantial non-permissive geology. In 100 permissive tracts assessed with three-part assessments of multiple deposit types located throughout the world, the median number of known well-explored deposits is 1 and 90 percent of tracts report less than 9 deposits. The number of well-explored deposits in three-part assessed tracts tends to be quite small, limiting any ability to recognize a discovery order versus size relationship. In a three-part assessment of undiscovered porphyry copper deposits of South America, only 7 of 26 delineated tracts contained more than 2 known deposits and only 1 had a significant negative relationship between tonnage of known deposits and year of discovery (p = 0.04). Most predicted undiscovered deposits in this tract were expected to be under extensive unexplored post-mineralization cover, meaning the general grade and tonnage model should be applied because the discovery order process starts over. Projection of deposit sizes based on discovery order would provide a biased estimate of the undiscovered deposit sizes in this case. Thus, although a discovery order versus size relationship could exist in three-part mineral assessments, only rarely might the pattern be useful to predict sizes of undiscovered deposits.

Ore Geology Reviews↗
USGS2022

Data-driven prospectivity modelling of sediment-hosted Zn-Pb mineral systems and their critical raw materials

Demand for critical raw materials is expected to accelerate over the next few decades due to continued population growth and the shifting consumption patterns of the global economy. Sedimentary basins are important sources for critical raw materials and new discoveries of sediment–hosted Mississippi Valley–type (MVT) and/or clastic–dominated (CD) Zn–Pb deposits are likely required to mitigate future supply chain disruptions for Zn, Pb, Ag, Cd, Ga, Ge, Sb, and In. Herein we integrate public geoscience datasets using a discrete global grid to system to model the mineral potential for MVT and CD deposits across Canada, the United States of America, and Australia. Statistical analysis of the model results demonstrates that surface–wave tomography and derivative products from satellite gravity datasets can be used to map the most favourable paleo–tectonic settings of MVT and CD deposits inboard of orogenic belts and at the rifted edges of cratonic lithosphere, respectively. Basin development at pre–existing crustal boundaries was likely important for maintaining the low geothermal–gradients that are favourable for metal transport and generating the crustal fluid pathways that were reactivated during ore–formation, as suggested by the statistical association of both sediment–hosted mineral deposit types with the edges of upward–continued gravity and long–wavelength magnetic anomalies. Multivariate statistical analysis demonstrates that the most prospective combination of these geophysical datasets varies for each geological region and deposit type. We further demonstrate that maximum and minimum geological ages, coupled with Phanerozoic paleogeographic reconstructions, represent mappable proxies for the availability of oxidized, brine–generating regions that are the most likely source of ore–forming fluids (e.g., low– to mid–latitude carbonate platforms and evaporites). Ore deposition was likely controlled by interaction between oxidized, low–temperature brines and sulfidic and/or carbonaceous rocks, which, in some cases, can be mapped at the exposed surface or identified using the available rock descriptions. Baseline weights–of–evidence models are based on regional geophysics and are the least impacted by missing surface information but yield relatively poor results, as demonstrated by the low area–under–the–curve (AUC) for the spatially independent test set on the success–rate plot (AUC = 0.787 for MVT and AUC = 0.870 for CD). Model performance can be improved by: (1) using advanced methods that were trained and validated during a series of semi–automated machine learning competitions; and/or (2) incorporating geological and geophysical datasets that are proxies for each component of the mineral system. The best–performing gradient boosting machine models yield higher AUC for the test set (AUC = 0.983 for MVT and AUC = 0.991 for CD) and reduce the search space by >94%. The model results highlight the potential benefits of mapping sediment–hosted mineral systems at continental scale to improve mineral exploration targeting for critical raw materials.

Ore Geology Reviews↗
USGS2022

Late Jurassic-Early Cretaceous orogenic gold mineralization in the Klamath Mountains, California: Constraints from 40Ar/39Ar dating of hydrothermal muscovite

The Klamath Mountains gold province is the second most important historical producer in California, having produced more than 7 Moz of gold from both lode and placer sources. Hydrothermal muscovite grains from gold-bearing veins provide the first 40 Ar/ 39 Ar age constraints indicative of a protracted period of mineralization in the Klamath Mountains. The data indicate that the window for orogenic gold mineralization in the Klamath Mountains was from ∼160–140 Ma, coinciding in age with the oldest orogenic gold deposits in the Sierra Nevada foothills province to the south, although mineralization continued in the latter along the Mother Lode belt for another 20–30 million years. Despite the broad age overlap between hydrothermal activity and magmatism, the former relates to a regional thermal event, and there is no genetic link between the two. Instead, a correlation exists between the timing of lode gold formation and discrete tectonic events, changes in stress regime, and fault movement. The maximum age corresponds to a major plate reorganization in the Pacific basin and initial gold mineralization continuing into the Sierra Nevada foothills gold province to the south. The minimum age corresponds to the westerly lateral offset of the Klamath Mountains from the Sierra Nevada and the then-active arc, marking the termination of both magmatism and gold-producing hydrothermal activity in the Klamath Mountains. Lode gold mineralization in the Klamath Mountains is compatible with a crustal source of metals and fluids that were released during metamorphic devolatilization and focused via hydrothermal fluid flow along regional faults.

California↗
USGS2022

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗
USGS2022

Indicator mineral analyses of stream-sediment samples using automated mineralogy and mineral chemistry: Applicability to exploration in covered terranes in eastern Alaska, USA

In the past two decades, significant research efforts have been devoted to porphyry copper indicator mineral (PCIM) identification and mineral chemistry to assist exploration. Such studies are important in the Yukon-Tanana upland region of eastern Alaska because well-established geochemical exploration techniques, such as the geochemistry of stream-sediment samples, are less effective in the search for mineral resources owing to cover materials that subdue geochemical signatures. The unglaciated Yukon-Tanana upland region is well-endowed with mineral resources, including porphyry Cu-Mo-Au deposits at Taurus, Bluff, Dennison, and Oreo. Using automated scanning electron microscope (SEM) techniques, numerous PCIMs have been identified in rocks and stream-sediment samples that would likely not have been observed using visual binocular microscope methods. Sulfide minerals such as chalcopyrite, chalcocite, covellite, bornite, molybdenite, and pyrrhotite were identified in rock samples, and more than half of the stream-sediment samples from drainages containing known porphyry mineral occurrences contain chalcopyrite with or without bornite. Many drainages without known occurrences also contain these minerals, which suggests potential for additional occurrences. Svanbergite, an aluminum phosphate sulfate (APS) mineral [SrAl 3 (PO 4 )(SO 4 )(OH) 6 ], was identified in some of the altered or mineralized rock samples from Taurus, and in stream drainages containing porphyry occurrences and may represent the best indicator mineral for Taurus-like porphyry deposits. Apatite chemistry has great potential as a tool for assessing the presence of porphyry mineralization. Grains from rock and stream-sediment samples that contain high Cl (>∼0.4 wt%), Fe (>0.4 wt%), and Mn (>2000 ppm) clearly distinguish apatite from other sources (metamorphic, unmineralized igneous rocks). This study is one of the first to document new streamlined indicator mineral sample collection and processing methods and to combine automated SEM techniques and chemistry of minerals derived from both bedrock and surficial (stream) sediments as they apply to porphyry exploration.

Alaska↗
USGS2022

A case of Te-rich low-sulfidation epithermal Au-Ag deposits in a calc-alkaline magmatic arc, NE China

Tellurium-bearing low-sulfidation epithermal Au-Ag deposits are significant producers of gold, silver, and potentially strategic elements if mineral processing methods are optimized for recovery. Although these deposits are generally related to alkaline magmatism, our study documents an unusual occurrence of Te-rich low-sulfidation epithermal systems in the North Heilongjiang Belt in northeast China that is spatially and temporally associated with calc-alkaline magmatism and tectonic extension in a continental arc‐setting. In the North Heilongjiang Belt, Te-bearing Au-Ag deposits are usually sited in dilatant zones, mostly along extensional NW structures or at their intersections with deep‐seated NE-striking faults such as the Nenjiang-Heihe and Jiayin-Mudanjiang lineaments. Of these deposits, Sandaowanzi is well‐known for its bonanza gold grades. These faults localized andesitic to rhyolitic volcano-plutonic centers that evolved from mantle‐derived mafic melts to intermediate compositions due to differentiation and crustal assimilation as documented by their mineralogy and Sr, Nd, and Pb isotope compositions. During assimilation of country rocks, fluids containing 3 He and other volatiles derived from mantle magmas displaced or mixed with external groundwater containing radiogenic 4 He derived from country rocks. In this belt, the bulk metal content of Au, Ag and Te was probably introduced by deep mantle‐derived mafic‐intermediate calc‐alkaline intrusions. However, our study does not exclude input of metals leached from underlying metasedimentary rocks and older Te‐bearing Au mineralization. The noble gas, hydrogen, oxygen and lead isotope compositions of fluid inclusions and ore minerals suggest that the deposits formed by mixing between magmatic fluids and convecting meteoric ground waters containing lead leached from surrounding country rocks. At deeper levels, isotopic evidence suggests that Au-Ag-Te (Bi) precipitated with pyrite, quartz, sericite, and carbonate minerals due to mixing with Te-rich fluids. At shallower levels, Au and Ag precipitated contemporaneously with base‐metal sulfides, hydrothermal quartz and sericite during episodic boiling as evidenced by silica morphology and mineral textures. The relatively uniform spacing of epithermal systems along NW- and NE-trending structures in the North Heilongjiang Belt was used to identify unexplored spaces within this mineral belt that are prospective for concealed low-sulfidation epithermal gold deposits. Although some of the Au-Ag deposits in this belt are enriched in Te, there is a lack of coeval alkaline igneous rocks that are commonly associated with Te-bearing gold deposits elsewhere in the world (e.g., Cripple Creek, Emperor, and Lihir Island).

North Heilongjiang Belt↗
USGS2023

Geophysical data provide three dimensional insights into porphyry copper systems in the Silverton caldera, Colorado, USA

The Silverton caldera in southwest Colorado, USA hosts polymetallic veins and pervasively altered rocks indicative of porphyry copper systems. Nearly a kilometer of erosion has exposed multiple levels of the hydrothermal systems from shallow lithocaps down to quartz-sericite-pyrite veins. New airborne electromagnetic and magnetic survey data are integrated with previous alteration mapping and porphyry models to show the subsurface geophysical response of shallow to deep levels of the porphyry system. Qualitative map views show lateral changes in the magnetization and resistivity of the hydrothermally altered rocks. The volcanic terrain exhibits high magnetization and high amplitude anomalies map near-surface plutonic rocks associated with porphyry systems. Magnetic susceptibility measurements on outcrops of hydrothermally altered rocks indicate magnetite content decreases upward and outward from the source intrusions where magnetic anomaly lows are observed over the lithocaps. The resistivity maps highlight hydrothermal alteration as resistivity lows with exception being rocks having propylitic alteration. Quantitative resistivity models show low resistivity zones with an apparent thickness around 50–150 m beneath quartz-sericite-pyrite veins interpreted to be the result of supergene processes that may continue today, and the calculated magnetic source depths occur near the top of this zone. The resistivity models also show rocks having propylitic, silicic, and quartz-alunite-pyrophyllite assemblages exhibit high resistivity with depth, and argillic alteration assemblages had high resistivity due to high quartz content. This integrated approach presented in a three-dimensional environment provides guidance when exploring for porphyry copper systems in less exposed terrains.

Colorado↗
USGS2023

Sandstone-hosted uranium deposits of the Colorado Plateau, USA

More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U 3 O 8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma).

Arizona, Colorado, Nevada, New Mexico, Utah↗
USGS2024

Microtextural evidence for the recrystallization of opal-A to quartz in epithermal veins: A case study from the McLaughlin deposit, California

High-grade ores in low-sulfidation epithermal deposits commonly consist of banded veins containing quartz as the most abundant gangue mineral. Previous studies suggested that at least some of the quartz has formed as a product of recrystallization from a noncrystalline silica precursor. Detailed petrographic studies confirm that high-grade veins from the <2.2 Ma McLaughlin deposit in California were originally entirely composed of opal-A G . The noncrystalline silica is isotropic in crossed-polarized light and consists of compacted microspheres that are up to several micrometers in size. In many bands of the high-grade veins, the thermodynamically unstable opal-A G has matured to quartz. The recrystallization of the noncrystalline silica resulted in the development of quartz and ore textures that mask the original conditions of vein formation. Incipient recrystallization of the opal-A G caused the formation of lepispheres consisting of opal-CT as well as the development of concentrically banded silica spheres. Continued maturation led to the growth of elongated quartz crystals or complexly shaped quartz aggregates in the cores of the concentrically banded silica spheres. Amalgamation of quartz crystals caused the development of mosaic quartz or flamboyant quartz. Ripening produced large prismatic quartz crystals, which are characterized by zones of feathery appearance. Fluid inclusions within the quartz formed through recrystallization are typically highly irregular in shape and show inconsistent liquid-to-vapor volumetric proportions, but assemblages with consistent ratios are also present. Bands rich in fluid inclusions occurring along former recrystallization fronts in prismatic quartz crystals resemble growth zones in zonal quartz. Recrystallization of the silica matrix resulted in grain coarsening of the ore minerals and encapsulation of ore minerals by quartz. In areas where recrystallization of the noncrystalline silica proceeded to completeness, the quartz textures could be easily misinterpreted to indicate that quartz growth occurred in open space with the ore minerals infilling vug spaces. Correct recognition of recrystallization textures has significant implications for paragenetic investigations on vein material from epithermal deposits as well as the design of fluid inclusion studies.

California↗
USGS2025

Solution-collapse breccia pipe uranium deposits of the southern Colorado Plateau, northwestern Arizona, USA

Some of the highest-grade uranium deposits in the United States occur in breccia pipes that formed by solution and collapse of sedimentary strata, which occur in the southern portion of the Colorado Plateau in northwestern Arizona. The host breccia pipes are up to 1200 m in vertical extent, average about 90 m in diameter, and can cross-cut strata from their base in the Mississippian Redwall Limestone to as stratigraphically high on some plateaus as the Triassic Chinle Formation. These uranium-base metal deposits are up to 600 m thick and formed within the breccia pipes where they transect the Permian Coconino Sandstone, Hermit Formation, and the Esplanade Sandstone. Of the hundreds of breccia pipes identified across this region, only a small percentage are known to contain mineralization. The main uranium ore mineral is uraninite that is intergrown with at least 20 base-metal sulfide minerals, which contribute Fe, Cu, Co, As, Pb, Zn, Ni, and Ag to the deposits. This study considered regional stratigraphy, sulfur isotope systematics, mineralogy, in situ dating, and compilation and analysis of previous work on the deposits. A comprehensive deposit model has not been published for these deposits. This analysis identified new additions to update the deposit model for these unusual, possibly unique deposits. Proposed modifications to the model include: (1) the source, mechanisms, timing of the base-metal sulfide mineral assemblages, and (2) the source, mechanism, and timing of the uranium mineralization. Sulfide and uranium deposition are shown to be separate mineralization events. The study proposes the possible role of gypsum as a source of sulfur for the sulfide minerals in the deposits. Groundwaters carrying uranium encountered the preexisting sulfides in breccia pipes, reducing the uranyl ions, and precipitating U oxide (as uraninite). Analysis of the regional stratigraphy recognized that numerous beds of gypsum are in the strata that lie only tens of meters above the breccia pipe deposits. In the breccia pipe region, if these stratigraphic units (Toroweap and Kaibab Formations) do not contain gypsum layers then the underlying pipes are not mineralized; where these Permian gypsum layers do occur, breccia pipes can host mineralization. This new understanding should be useful in identifying the prospective region for mineralized pipes.

Arizona↗
USGS2026

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois↗
USGS2026

Global pegmatite-hosted lithium, cesium, and rubidium resources: A dataset for grade and tonnage modeling

Quantitative mineral resource assessments of potential undiscovered deposits can inform future mineral supply scenarios, but their accuracy is conditional on building robust grade and tonnage models of known deposits. This study presents an up-to-date global compilation and analysis of recently discovered and original, in-situ pegmatite-hosted Li, Cs, and Rb resources prior to historic production. Our analysis yields a median tonnage of 21.2 million tons (Mt) and grade of 1.12% Li 2 O, respectively, for global Li pegmatite deposits ( n = 73). The grades and tonnages of Li pegmatite resources vary depending on the age of the bedrock host domain, pegmatite crystallization age, and primary ore mineralogy. Lithium pegmatite resources hosted in Archean to transitional Archean-Paleoproterozoic domains have the largest median tonnage (29.8 Mt; n = 38), and those hosted in Paleoproterozoic to Mesoproterozoic domains have smaller median tonnages (6.5 Mt; n = 16). Cesium deposits where pollucite is the primary ore mineral have a bimodal grade distribution, with modes of 2.40 and 0.035 wt% Cs 2 O for high- and low-grade deposits, respectively, while Rb deposits are more unimodal with a median grade of 0.247 wt% Rb 2 O. Pegmatite-hosted Cs and Rb resources have median tonnages of 7.6 and 6.3 Mt, respectively. Covariation between ore mineralogy and the degree of crustal enrichment in pegmatite-hosted deposits is diagnostic of petrogenetic differences, including melt source characteristics, magma evolution, or variable degrees of volatile solubility. The Li pegmatite compilation is suitable for fitting robust numerical models to support quantitative assessments. More well-defined Rb and Cs pegmatite resources are required for quantitative assessments, but these data provide useful information about original in-place resources for framing supply discussions.

Ore Geology Reviews↗
USGS2000

Late-kinematic timing of orogenic gold deposits and significance for computer-based exploration techniques with emphasis on the Yilgarn Block, Western Australia

Orogenic gold deposits are a widespread coherent group of epigenetic ore deposits that are sited in accretionary or collisional orogens. They formed over a large crustal-depth range from deep-seated low-salinity H 2 O–CO 2 ±CH 4 ±N 2 ore fluids and with Au transported as thio-complexes. Regional structures provide the main control on deposit distribution. In many terranes, first-order faults or shear zones appear to have controlled regional fluid flow, with greatest ore-fluid fluxes in, and adjacent to, lower-order faults, shear zones and/or large folds. Highly competent and/or chemically reactive rocks are the most common hosts to the larger deposits. Focusing of supralithostatic ore fluids into dilatant zones appears to occur late during the evolutionary history of the host terranes, normally within D 3 or D 4 in a D 1 –D 4 deformation sequence. Reactivation of suitably oriented pre-existing structures during a change in far-field stress orientation is a factor common to many deposits, and repeated reactivation may account for multiple mineralization episodes in some larger deposits. Absolute robust ages of mineralization support their late-kinematic timing, and, in general, suggest that deposits formed diachronously towards the end of the 100 to 200 m.y. long evolutionary history of hosting orogens. For example, in the Yilgarn Block, a region specifically emphasised in this study, orogenic gold deposits formed in the time interval between 40 and 90 m.y., with most about 60 to 70 m.y., after the youngest widespread basic-ultrabasic volcanism and towards the end of felsic magmatism. The late timing of orogenic gold deposits is pivotal to geologically-based exploration methodologies. This is because the present structural geometries of: (i) the deposits, (ii) the hosting goldfields, and (iii) the enclosing terranes are all essentially similar to those during gold mineralization, at least in their relative position to each other. Thus, interpretation of geological maps and cross-sections and three-dimensional models can be used to accurately simulate the physical conditions that existed at the time of ore deposition. It is particularly significant that the deposits are commonly related to repetitive and predictable geometries, such as structural heterogeneities within or adjacent to first-order structures, around rigid granitoid bodies, or in specific “locked-up” fold-thrust structures. Importantly, the two giant greenstone-hosted goldfields, Kalgoorlie and Timmins, show a remarkably similar geometry at the regional scale. Computer-based stress mapping and GIS-based prospectivity mapping are two computer-based quantitative methodologies that can utilize and take advantage of the late timing aspect of this deposit type to provide important geological aids in exploration, both in broad regions and more localized goldfields. Both require an accurate and consistent solid geology map, stress mapping requires knowledge of the far-field stresses during mineralization, and the empirical prospectivity mapping requires data from a significant number of known deposits in the terrane. The Kalgoorlie Terrane, in the Yilgarn Block, meets these criteria, and illustrates the potential of these methodologies in the exploration for orogenic gold deposits. Low minimum stress anomalies, interpreted to represent dilational zones during gold-related deformation, coincide well with the positions of known goldfields rather than individual gold deposits in the terrane, and there are additional as-yet unexplained anomalies. The prospectivity analysis confirms that predictable and repetitive factors controlling the siting of deposits are: (i) proximity to, and orientation and curvature of, granitoid-greenstone contacts, (ii) proximity to segments of crustal faults which strike in a preferred direction, (iii) proximity to specific lithological contacts which have similar preferred strike, (iv) proximity to anticlinal structures, and (v) the presence of preferred reactive host rocks (e.g., dolerite). The prospectivity map defines a series of anomalous areas, which broadly conform to those of the stress map (>78% correspondence). The most prospective category on this map covers less than 0.3% of the greenstone belts and yet hosts 16% of the known deposits, which have produced>80% of known gold. Thus, it discriminates in favour of the larger economically more-attractive deposits in the terrane. The successful application of stress mapping and prospectivity mapping to geology-based exploration for orogenic gold deposits indicates that more quantitative analysis of geological map data is a profitable line of research. The computer-based nature of these methodologies is ideal for the production of an ultimate, integrated, deposit target map, which can be compared to other, more conventional, targeting parameters such as geophysical and geochemical anomalies. Such an integrated strategy appears the way forward in the increasingly difficult task of cost-effective global exploration for orogenic gold deposits in poorly exposed terranes.

Western Australia↗