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USGS2014

Forcing functions governing salt transport processes in coastal navigation canals and connectivity to surrounding marshes in South Louisiana using Houma Navigation Canal as a surrogate

Understanding how circulation and mixing processes in coastal navigation canals influence the exchange of salt between marshes and coastal ocean, and how those processes are modulated by external physical processes, is critical to anticipating effects of future actions and circumstance. Examples of such circumstances include deepening the channel, placement of locks in the channel, changes in freshwater discharge down the channel, changes in outer continental shelf (OCS) vessel traffic volume, and sea level rise. The study builds on previous BOEM-funded studies by investigating salt flux variability through the Houma Navigation Canal (HNC). It examines how external physical factors, such as buoyancy forcing and mixing from tidal stirring and OCS vessel wakes, influence dispersive and advective fluxes through the HNC and the impact of this salt flux on salinity in nearby marshes. This study quantifies salt transport processes and salinity variability in the HNC and surrounding Terrebonne marshes. Data collected for this study include time-series data of salinity and velocity in the HNC, monthly salinity-depth profiles along the length of the channel, hourly vertical profiles of velocity and salinity over multiple tidal cycles, and salinity time series data at three locations in the surrounding marshes along a transect of increasing distance from the HNC. Two modes of vertical current structure were identified. The first mode, making up 90% of the total flow field variability, strongly resembled a barotropic current structure and was coherent with alongshelf wind stress over the coastal Gulf of Mexico. The second mode was indicative of gravitational circulation and was linked to variability in tidal stirring and the longitudinal salinity gradients along the channel’s length. Diffusive process were dominant drivers of upestuary salt transport, except during periods of minimal tidal stirring when gravitational circulation became more important. Salinity in the surrounding marshes was much more responsive to salinity variations in the HNC than it was to variations in the lower Terrebonne marshes, suggesting that the HNC is the primary conduit for saltwater intrusion to the middle Terrebonne marshes. Finally, salt transport to the middle Terrebonne marshes directly associated with vessel wakes was negligible.

Louisiana↗

USGS2025

Quantifying the effect of petrogenic carbon on SOC turnover for two Rocky Mountain soils: When are petrogenic carbon corrections required?

Petrogenic organic carbon (OC petro ), derived from sedimentary rocks, is an often overlooked and poorly quantified source of soil organic carbon (SOC), which may influence measured or modeled SOC composition, age, and stability. In this study, we exploited differences in thermochemical stability between OC petro and biogenic SOC (OC bio ) using stepped elemental analysis to quantify the fractional contribution of OC petro to total SOC (f petro ), and we conducted a sensitivity analysis to estimate the effects of OC petro on modeled SOC transit times and system ages. Specifically, we compared the effects of accounting for OC petro inputs in SOC turnover modeling (using SoilR) for two montane meadow soils that are underlain by Cretaceous Mancos Shale. At these sites, we estimate that OC petro comprises 7%–9% of the total SOC stock (f petro = 0.07–0.09). However, accounting for OC petro as a mixture of inert and passive C or as completely inert C had negligible effects on SOC transit times and system ages, suggesting that there is a threshold of OC petro content under which there is minimal effect on calculated SOC turnover. Based on our sensitivity analysis, we estimate this threshold to be f petro = 0.125, further supporting that the accurate calculation of OC petro remains an important factor in estimating SOC turnover.

Colorado↗

USGS2021

Modeling at-sea density of marine birds to support renewable energy planning on the Pacific outer continental shelf of the contiguous United States

This report describes the at-sea spatial distributions of marine birds in Pacific OCS waters off the contiguous U.S. (Figure 1.1) to inform marine spatial planning in the region. The goal was to estimate long-term average spatial distributions for marine bird species using all available science-quality transect survey data and numerous bathymetric, oceanographic, and atmospheric predictor variables. We developed seasonal habitat-based spatial models of the at-sea distribution for 33 individual species and 13 taxonomic groups of marine birds throughout the study region. A statistical modeling framework was used to estimate numerical relationships between bird sighting data (i.e., standardized counts) and a range of temporal (e.g., Pacific Decadal Oscillation [PDO] index), spatially static (e.g., depth), and spatially dynamic (e.g., sea surface chlorophyll-a concentration) environmental variables. The estimated relationships were then used to predict spatially explicit long-term average density (individuals per km 2 ) throughout the study area for each species/group in each of four seasons. Bird sighting data came from multiple scientific survey programs and consisted of at-sea counts of birds collected between 1980 and 2017 using boat-based and fixed-wing aerial transect survey methods. Spatial environmental variables were derived from remote sensing satellite data and an ocean dynamics model.

California, Oregon, Washington↗

USGS2011

Biomarker chemistry and flux quantification methods for natural petroleum seeps and produced oils, offshore southern California

Sustained, natural oil seepage from the seafloor is common off southern California, and is of great interest to resource managers, who are tasked with distinguishing natural from anthropogenic oil sources. The major purpose of this study was to build upon the work previously funded by the Bureau of Ocean Energy Management (BOEM) and the U.S. Geological Survey (USGS) that has refined the oil-fingerprinting process to enable differentiation of the highly similar Monterey Formation oils from Outer Continental Shelf (OCS) production and adjacent natural seeps. In these initial studies, biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic-matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. The analysis resulted in a predictive model of oil source families that could be applied to samples of unknown origin.

California↗

USGS2014

Demography and behavior of polar bears summering on land in Alaska

Polar bears (Ursus maritimus) in the southern Beaufort Sea population (SB) are spending increased time on the coastal North Slope of Alaska between July and October (Gleason and Rode 2010). The duration spent on land by polar bears, satellite collared on the sea-ice in the spring, during the summer and fall has also increased (USGS, unpublished data; Figure 1). This change in polar bear ecology has relevance for human-bear interactions, subsistence harvest, prevalence of defense kills, and disturbance associated with existing land-based development [e.g., National Petroleum Reserve of Alaska (NPRA), Arctic National Wildlife Refuge (ANWR)], Native Alaskan communities, recreation (ANWR) and tourism (e.g., bear viewing in Kaktovik, AK). These activities have the potential to impact, in new ways, the status of the entire SB population. Concomitantly, the change in polar bear ecology will impact these human activities, and a base-line characterization of this phenomenon can better inform mitigation (e.g., industry permitting under the Endangered Species Act and Marine Mammal Protection Act). In this study we aim to characterize the demography, habitat-use, and aspects of foraging ecology and health of polar bears spending fall on land. The SB population is characterized by a divergent-sea ice ecology, where polar bears typically spend most of the year on the sea-ice, even as the pack ice retreats northward, away from the coast, to its minimal extent in September (Amstrup et al. 2008; Durner et al. 2009). From 2000 – 2005, using coastal aerial surveys, Schliebe et al. (2008) observed between 3.7 and 8% of polar bears from SB (~ 60 – 120 of 1526, Regher et al. 2006) on land during the autumn. Sighting probability was not estimated in these surveys, and therefore the numbers represent minimum numbers of bears on land. Our analysis of USGS data suggest an annual average of 15% (± 3%, SE) of polar bears satellite-tagged on the spring-time sea ice (total n = 18 of 124 satellite tags, 2003 – 2009) come to land during July – October. Based on these data, and an assumption that bears satellite-tagged on the spring time sea ice are representative of the entire SB population of independent bears, there would be an average of 230 bears on land each fall. In contrast to the SB population, in five of the world’s 19 polar bear populations (Obbard et al. 2010), polar bears spend significant periods of time on land (1 – 5 months) when ice completely melts. In these seasonal-ice populations (Amstrup et al. 2008), polar bears are largely in a hypophagic condition (e.g., Hobson et al. 2009), relying on fat stores from the spring hyperphagic season, when ringed seals (Phoca hispida) pup. In general, these seasonal-ice populations are demographically productive (Taylor et al. 2005), although recently an increase in the ice-free season has resulted in a population decline in western Hudson Bay (Stirling et al. 1999; Regehr et al. 2007). There have been measured declines in the body condition and productivity of polar bears in SB, and changes in these parameters have been linked to declining optimal ice habitat (e.g., Durner et al. 2009; Regehr et al. 2010). We do not understand the relationship between land-use and the overall status of the population. Individual polar bears that use land may have increased or decreased fitness, in comparison to polar bears that remain on ice in the autumn. This project, which focuses on the biology of animals that spend time on-shore, will help address this question. This project is funded by the Bureau of Ocean Energy Management (BOEM) under Agreement No. M09PG00025 and the USGS Outer Continental Shelf Program (OCS) for FY 2009-2014. Parts of this study are also funded by US Fish and Wildlife Service, Office of Marine Mammals Management; the Bureau of Land Management; and the North Slope Borough, Department of Wildlife Management. This report is comprehensive, describing results for achieving the overlap

Beaufort Sea, Chukchi Sea↗

USGS1986

Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental sigal?

Geochemical studies of Cretaceous strata rich in organic carbon (OC) from Deep Sea Drilling Project (DSDP) sites and several land sections reveal several consistent relationships among amount of OC, hydrocarbon generating potential of kerogen (measured by pyrolysis as the hydrogen index, HI), and the isotopic composition of the OC. First, there is a positive correlation between HI and OC in strata that contain more than about 1% OC. Second, percent OC and HI often are negatively correlated with carbon isotopic composition (σ 13 C) of kerogen. The relationship between HI and OC indicates that as the amount of organic matter increases, this organic matter tends to be more lipid rich reflecting the marine source of the organic matter. Cretaceous samples that contain predominantly marine organic matter tend to be isotopically lighter than those that contain predominantly terrestrial organic matter. Average σ 13 C values for organic matter from most Cretaceous sites are between −26 and −28‰, and values heavier than about −25‰ occur at very few sites. Most of the σ 13 C values of Miocene to Holocene OC-rich strata and modern marine plankton are between −16 to −23‰. Values of σ 13 C of modern terrestrial organic matter are mostly between −23 and −33‰. The depletion of terrestial OC in 13 C relative to marine planktonic OC is the basis for numerous statements in the literature that isotopically light Cretaceous organic matter is of terrestrial origin, even though other organic geochemical and(or) optical indicators show that the organic matter is mainly of marine origin. A difference of about 5‰ in σ 13 C between modern and Cretaceous OC-rich marine strata suggests either that Cretaceous marine planktonic organic matter had the same isotopic signature as modern marine plankton and that signature has been changed by diagenesis, or that OC derived from Cretaceous marine plankton was isotopically lighter by about 5‰ relative to modern plankton OC. Diagenesis does not produce a significant shift in σ 13 C in Miocene to Holocene sediments, and therefore probably did not produce the isotopically light Cretaceous OC. This means that Cretaceous marine plankton must have had σ 13 C values that were about 5‰ lighter than modern marine plankton, and at least several per mil lighter than Cretaceous terrestrial vegetation. The reason for these lighter values, however, is not obvious. It has been proposed that concentrations of CO 2 were higher during the middle Cretaceous, and this more available CO 2 may be responsible for the lighter σ 13 C values of Cretaceous marine organic matter.

Marine Geology↗

USGS2020

Assessing the exposure of three diving bird species to offshore wind areas on the U.S. Atlantic Outer Continental Shelf using satellite telemetry

Aim The United States Atlantic Outer Continental Shelf (OCS) has considerable offshore wind energy potential. Capturing that resource is part of a broader effort to reduce CO 2 emissions. While few turbines have been constructed in U.S. waters, over a dozen currently planned offshore wind projects have the potential to displace marine birds, potentially leading to effective habitat loss. We focused on three diving birds identified in Europe to be vulnerable to displacement. Our research aimed to determine their potential exposure to areas designated or proposed for offshore wind development along the Atlantic OCS. Methods Satellite tracking technology was used to determine the spatial and temporal use and movement patterns of Surf Scoters ( Melanitta perspicillata ), Red‐throated Loons ( Gavia stellata ) and Northern Gannets ( Morus bassanus ), and calculate their exposure to each offshore wind area. We tagged 236 adults in 2012–2015 on the Atlantic OCS from New Jersey to North Carolina; an additional 147 birds tagged in previous tracking studies were integrated into our analyses. Tracking data were analysed in two‐week intervals using dynamic Brownian bridge movement models to develop composite spatial utilization distributions. For each species, these distributions were then used to calculate the spatio‐temporal exposure to each offshore wind area. Results Surf Scoters and Red‐throated Loons were exposed to offshore wind areas almost exclusively during migration because these species were distributed among coastal and inshore waters during winter months. In contrast, Northern Gannets ranged over a much larger area, reaching farther offshore and south in winter, thus exhibited the greatest exposure to extant offshore wind areas. Conclusions Results of this study provide better understanding of how diving birds use current and potential future offshore wind areas on the Atlantic OCS, and can inform permitting, risk assessment and pre‐ and post‐construction impact assessments of offshore energy infrastructure.

Atlantic Outer Continental Shelf↗

USGS2004

Water-quality, biological, and physical-habitat conditions at fixed sites in the Cook Inlet Basin, Alaska, National Water-Quality Assessment Study Unit, October 1998-September 2001

The Cook Inlet Basin study unit of the U.S. Geological Survey National Water-Quality Assessment Program comprises 39,325 square miles in south-central Alaska. Data were collected at eight fixed sites to provide baseline information in areas where no development has taken place, urbanization or logging have occurred, or the effects of recreation are increasing. Collection of water-quality, biology, and physical-habitat data began in October 1998 and ended in September 2001 (water years 1999-2001). The climate for the water years in the study may be categorized as slightly cool-wet (1999), slightly warm-wet (2000), and significantly warm-dry (2001). Total precipitation was near normal during the study period, and air temperatures ranged from modestly cool in water year 1999 to near normal in 2000, and to notably warm in 2001. Snowmelt runoff dominates the hydrology of streams in the Cook Inlet Basin. Average annual flows at the fixed sites were approximately the same as the long-term average annual flows, with the exception of those in glacier-fed basins, which had above-average flow in water year 2001. Water temperature of all streams studied in the Cook Inlet Basin remained at 0 oC for about 6 months per year, and average annual water temperatures ranged from 3.3 to 6.2 degrees Celsius. Of the water-quality constituents sampled, all concentrations were less than drinking-water standards and only one constituent, the pesticide carbaryl, exceeded aquatic-life standards. Most of the stream waters of the Cook Inlet Basin were classified as calcium bicarbonate, which reflects the underlying geology. Streams in the Cook Inlet Basin draining areas with glaciers, rough mountainous terrain, and poorly developed soils have low concentrations of nitrogen, phosphorus, and dissolved organic carbon compared with concentrations of these same constituents in streams in lowland or urbanized areas. In streams draining relatively low-lying areas, most of the suspended sediment, nutrients, and dissolved organic carbon are transported in the spring from the melting snowpack. The urbanized stream, Chester Creek, had the highest concentrations of calcium, magnesium, chloride, and sodium, most likely because of the application of de-icing materials during the winter. Several volatile organic compounds and pesticides also were detected in samples from this stream. Aquatic communities in the Cook Inlet Basin are naturally different than similar sites in the contiguous United States because of the unique conditions of the northern latitudes where the Cook Inlet Basin is located, such as extreme diurnal cycles and long periods of ice cover. Blue-green algae was the dominant algae found at all sites although in some years green algae was the most dominant algae. Macroinvertebrate communities consist primarily of Diptera (true flies), Ephemeroptera (mayflies), and Plecoptera (stoneflies). Lowland areas have higher abundance of aquatic communities than glacier-fed basins. However, samples from the urbanized stream, Chester Creek, were dominated by oligochaetes, a class of worms. Most of the functional feeding groups were collector-gatherers. The number of taxa for both algae and macroinvertebrates were highest in water year 2001, which may be due to the relative mild winter of 2000?2001 and the above average air temperatures for this water year. The streams in the Cook Inlet Basin typically are low gradient. Bank substrates consist of silt, clay, or sand, and bed substrate consists of coarse gravel or cobbles. Vegetation is primarily shrubs and woodlands with spruce or cottonwood trees. Canopy angles vary with the size of the stream or river and are relatively low at the smaller streams and high at the larger streams. Suitable fish habitat, such as woody debris, pools, cobble substrate, and overhanging vegetation, is found at most sites. Of the human activities occurring in the fixed site basins ? high recreational use, logging, and urbanizat

Scientific Investigations Report↗

USGS2019

Negligible cycling of terrestrial carbon in many lakes of the arid circumpolar landscape

High-latitude environments store nearly half of the planet’s below-ground organic carbon (OC), mostly in perennially frozen permafrost soils. Climatic changes drive increased export of terrestrial OC into many aquatic networks, yet the role that circumpolar lakes play in mineralizing this carbon is unclear. Here we directly evaluate ecosystem-scale OC cycling for lakes of interior Alaska. This arid, low-relief lake landscape is representative of over a quarter of total northern circumpolar lake area, but is greatly under-represented in current studies. Contrary to projections based on work in other regions, the studied lakes had a negligible role in mineralizing terrestrial carbon; they received little OC from ancient permafrost soils, and had small net contribution to the watershed carbon balance. Instead, most lakes recycled large quantities of internally derived carbon fixed from atmospheric CO 2 , underscoring their importance as critical sites for material and energy provision to regional food webs. Our findings deviate from the prevailing paradigm that northern lakes are hotspots of terrestrial OC processing. The shallow and hydrologically disconnected nature of lakes in many arid circumpolar landscapes isolates them from terrestrial carbon processing under current climatic conditions.

Nature Geoscience↗

USGS2003

Biomagnification factors (fish to osprey eggs from Willamette River, Oregon, U.S.A.) for PCDDS, PCDFS, PCBS, and OC pesticides

A migratory population of 78 pairs of Osprey ( Pandion haliaetus ) nesting along the Willamette River in westernOregon was studied in 1993. The study was designed to determinecontaminant concentrations in eggs, contaminant concentrationsin fish species predominant in the Ospreys diet, andBiomagnification Factors (BMFs) of contaminants from fish specieseaten to Osprey eggs. Ten Osprey eggs and 25 composite samplesof fish (3 species) were used to evaluate organochlorine (OC)pesticides, polychlorinated biphenyls (PCBs), polychlorinateddibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans(PCDFs). Mercury was also analyzed in fish. Geometric meanresidues in Osprey eggs were judged low, e.g., DDE 2.3 μg g -1 wet weight (ww), Σ PCBs 0.69 μg g -1 , 2,3,7,8-TCDD 2.3 ng kg -1 , and generally well below known threshold values for adverse effects on productivity, and the population was increasing. Osprey egg residue data presentedby River Mile (RM) are discussed, e.g., higher PCDDs were generally found immediately downstream of paper mills and eggsfrom the Willamette River had significantly elevated PCBs and PCDDs compared to reference eggs collected nearby in the CascadeMountains. Prey remains at nest sites indicated that the Largescale Sucker ( Catostomus macrocheilus ) and NorthernPikeminnow ( Ptychocheilus oregonensis ) accounted for an estimated 90.1% of the biomass in the Osprey diet, and composite samples of these two species were collected from different sampling sites throughout the study area for contaminant analyses. With the large percentage of the fishbiomass in the Osprey diet sampled for contaminants (and fisheaten by Ospreys similar in size to those chemically analyzed),and fish contaminant concentrations weighted by biomass intake, a mean BMF was estimated from fish to Osprey eggs for the largeseries of contaminants. BMFs ranged from no biomagnification(0.42) for 2,3,7,8-TCDF to 174 for OCDD. Our findings for themigratory Osprey were compared to BMFs for the resident HerringGull ( Larus argentatus ), and differences are discussed. Webelieve a BMF approach provides some basic understanding ofrelationships between contaminant burdens in prey species offish-eating birds and contaminants incorporated into their eggs,and may prove useful in understanding sources of contaminants inmigratory species although additional studies are needed.

Oregon↗

USGS2007

Effect of in ovo exposure to an organochlorine mixture extracted from double crested cormorant eggs (Phalacrocorax auritus) and PCB 126 on immune function of juvenile chickens

Organochlorine (OC) contaminants including polychlorinated biphenyls (PCBs) and p, p'-dichlorodiphenyldichloroethylene (DDE) have been associated with immune modulation in wild fish-eating birds from the Great Lakes. The objective of this study was to evaluate the immune function of juvenile chickens after in ovo exposure to PCB 126 or an environmentally relevant OC mixture extracted from eggs of double crested cormorants (Phalacrocorax auritus) from Green Bay, Lake Michigan, USA. Fertile white leghorn chicken (Gallus domesticus) eggs were injected before incubation with 0.55-1.79 ng TCDD equivalents (TEQ)/egg PCB 126 and 1.2-4.9 ng TEQs/egg of cormorant egg extract into the air cell in two separate experiments. After hatching, the immune function was tested using in vivo phytohemagglutinin (PHA) skin response in 11-day-old chicks, antibody titers to immunization with sheep red blood cells (SRBC) in 28-day-old chicks, and, at necropsy, thymus and bursal mass and cellularity. PCB 126 decreased antibody titers at all doses and decreased the thymus and bursa index but not cellularity at 1.79 ng TEQ/egg. The cormorant egg extract caused no significant alterations in immune function even though it has been demonstrated as immunotoxic in chicken embryos. However, twofold to threefold increases in total anti-SRBC titers in 28-day-old chicks exposed to 1.2 or 2.4 ng TEQ/egg of cormorant extract were similar to elevations in anti-SRBC titer observed in Caspian tern (Sterna caspia) chicks from a highly OC-contaminated site in Saginaw Bay, Lake Huron. Posthatch exposure to OC through fish consumption in addition to in ovo OC exposure might be associated with the immune modulation reported in wild birds. Chicks in this study might have begun to compensate for embryonic immunotoxicity by the ages at which we studied them. ?? 2007 Springer Science+Business Media, LLC.

Archives of Environmental Contamination and Toxico↗

USGS1979

Maps showing late Pleistocene and Holocene evolution of the South Texas continental shelf

Interpretation of acoustical profiles has provided insight into the late Quaternary geologic history of the Continental Shelf off South Texas. (See the geographic index map on sheet 1 for location of the area studied.) The profiles reveal the interplay of tectonism, sedimentation, and cyclic fluctuations of sea level in the building and geologic evolution of the continental terrace. The sequence of sediments studied extends to about 200 meters (m) beneath the sea-floor surface. Four seismic-stratigraphic units underlain by four prominent sound reflectors were identified and mapped. This geologic synthesis, for which the research was funded by the U.S. Bureau of Land Management (BLM), is but one aspect of a coordinated, multidisciplinary environmental study of the South Texas Outer Continental Shelf sponsored by BLM (Berryhill, 1976, 1977). The environmental studies are keyed to the leasing of Federal Outer Continental Shelf (OCS) lands for petroleum exploration and production. Their purpose is to provide the data development of petroleum resources on the OCS, as well as to provide the basis for predicting the impact of oil and gas exploration and production on the marine environment. Of primary concern is the recognition of geologic conditions that might be hazardous to structures placed on the sea floor. Geologic hazards relate directly to the potential for significant movement of the sea floor in the future. Judging sea-floor stability and recognizing geologic features that are potentially hazardous require an understanding of the recent geologic history of the area, which, in turn, entails determining the relative rates and interactions of sedimentation and tectonism through time. In addition to the primary objective, the synthesis provides knowledge about the magnitude and extent of sea-level fluctuations in the western Gulf of Mexico, and it provides a depositional facies model of possible use in appraising the resource potential of the more deeply buried sediments.

Texas↗

USGS2020

Habitat affinities and at-sea ranging behaviors among main Hawaiian Island seabirds: Breeding seabird telemetry, 2013–2016

Recent Hawaiʻi state clean energy policy mandates and federal interest in developing offshore renewable energy resources have prompted unsolicited lease requests for offshore wind energy infrastructure (OWEI) to be located in ocean waters off Hawaiʻi. This study describing at-sea ranging behaviors for five seabirds was intended to provide new information on Hawaiian breeding seabird distribution at sea, habitat utilization, and ranging behaviors within near-island waters and throughout outer continental shelf (OCS) waters surrounding the main Hawaiian Islands (MHI). We also estimate the percentage of time the five study species spent flying at altitudes equivalent to an expected rotor-swept-zone (RSZ; 30–194 m) for an offshore wind turbine and discuss potential collision risk from OWEI to the seabirds studied here. The MHI supports important seabird breeding populations and individual seabirds can now be equipped with a wide-variety of data loggers and location tracking devices that can provide complex, high-resolution information on movement patterns at sea. In this study, we used GPS loggers and temperature-depth-recorders (TDRs) to examine the at-sea distributions and ranging behaviors of five abundantly breeding species in the MHI: Red-tailed Tropicbird, Laysan Albatross, Wedge-tailed Shearwater, Brown Booby, and Red-footed Booby. We tracked these breeding seabirds from 14 different sites throughout the MHI; study colonies were located on the main islands of Maui, Oʻahu, Kauaʻi, and on associated islets. We used the Residence in Space and Time (RST) algorithm to classify behavior into resting, transiting, and searching/foraging (Torres et al. 2017). We used GPS altitude measurements to examine species-specific flight height and to estimate time spent flying in the RSZ. We mapped rediscretized tracking data for seabirds at each study colony according to behavioral class and trip type (when applicable) using kernel density estimates. During 2014–2016, we obtained GPS and TDR data from 59 and 34 Red-tailed Tropicbirds, respectively. Taken together, individuals revealed a bimodal (short- [~3 h, <100 km range] and long- [>3 d, >800 km range]) trip foraging strategy. While ranging at sea, we estimated that Red-tailed Tropicbirds spend 70.6% (95% confidence interval [CI] 70.1–71.0%) of flight time in the RSZ. TDR data for tropicbirds was noisy and we could not reliably identify dives. During 2014 and 2016, we obtained GPS data from 35 Laysan Albatrosses nesting on Kauaʻi and Oʻahu. Individuals during the mid- to late-chick rearing period engaged in a bimodal short- (<6 d, <400 km range) and long- (>6 d, >2,000 km range) trip foraging strategy. While ranging at sea, we estimated that Laysan Albatrosses spend 2.57% (95% CI 2.50–2.64%) of flight time in the RSZ. During 2013–2015, we obtained GPS and TDR data from 313 and 55 Wedge-tailed Shearwaters, respectively. Considering all the data together, individuals revealed a multi-modal trip duration foraging strategy consisting of intra-day (<24 h, <100 km range), short (<4 d, ~200 km range), and long (>4 d, ~100–400 km range) trips. While ranging at sea, we estimated that Wedge-tailed Shearwaters spend 5.20% (95% CI 5.13–5.27%) of flight time in the RSZ. Wedge-tailed Shearwaters dove to a mean (± SD) depth of 1.78 ± 1.35 m (median = 1.38 m); the deepest dive recorded was to 10.06 m. The mean dive duration for Wedge-tailed Shearwaters was 3.12 ± 3.44 s (median = 1.80 s). During 2014–2015, we obtained GPS and TDR data from 42 and 37 Brown Boobies, respectively. Almost all foraging trips (97%) were single-day trips and we did not detect any bimodality in the distribution of single-day trip durations. Brown Boobies foraged relatively close to their colony (<60 km range) and focused their at-sea use in nearshore, coastal waters off Kauaʻi and Niʻihau. While foraging at sea, we estimated that Brown Boobies spend 3.41% (95% CI 3.16–3.67%) of flight time in the RSZ

Hawaii↗

USGS2008

Organochlorine pollutants and stable isotopes in resident and migrant passerine birds from northwest Michoacán, Mexico

Although concentrations of organochlorine compounds (OCs) in birds from most of the United States and Canada have decreased over the last 30 years, there is still concern that migrant birds might be exposed to elevated concentrations of OCs during migration in Latin America. The Lerma-Chapala Basin in west-central Mexico is an important migration corridor and wintering area for many species. The objectives of this study were to assess if resident and migrant birds wintering in western Michoacán, Mexico accumulated elevated concentrations of OCs during fall and spring and to determine if the stable isotopes δ 15 N, δ 13 C, and δD could be used to predict burdens and origins of DDE accumulation. Resident and migrant passerine insectivorous birds were collected during fall and spring (2001–2002) in northwest Michoacán, near Chapala Lake, Mexico. The carcasses were analyzed for OCs and tail feathers were analyzed for stable isotopes δ 15 N, δ 13 C, and δD. The OCs detected in more than 50% of the samples were: oxychlordane (79%), p,p ’-DDE (100%), p ,p′-DDT (57%), and total PCBs (100%). p,p ′-DDE was the OC detected at the highest concentrations, whereas residues of other OCs were near or below detection limits. Overall, there were no significant differences in concentrations of OCs between seasons or between resident and migrant birds. Concentrations of DDE and oxychlordane were somewhat higher in migrant and resident birds during spring than in fall; however, concentrations were significantly different only for oxychlordane. Two resident birds collected in fall and spring had DDE residues >10 μg/g wet weight in carcass. There were no significant differences in δ 13 C and δ 15 N values among species, between seasons, or between migrant and resident birds. However, δD values were clearly different between species and helped differentiate migrant from resident birds. δD values also were negatively and significantly correlated with DDE concentrations in carcass. Birds with more depleted δD values in feathers tended to have higher DDE concentrations than those with less depleted δD values, suggesting a potential latitudinal accumulation of DDE. Overall, our results suggest that during fall and spring, there is not a significant buildup of persistent OCs in migrant and resident passerine insectivorous birds in northwest Michoacán, Mexico.

Michoacán↗

USGS2004

Aquifer vulnerability to pesticide pollution: Combining soil, land-use and aquifer properties with molecular descriptors

This study uses an extensive survey of herbicides in groundwater across the midwest United States to predict occurrences of a range of compounds across the region from a combination of their molecular properties and the properties of the catchment of a borehole. The study covers 100 boreholes and eight pesticides. For each of the boreholes its catchment the soil, land-use and aquifer properties were characterized. Discriminating boreholes where pollution occurred from those where no pollution occurred gave a model that was 74% correct with organic carbon content, percentage sand content and depth to the water table being significant properties of the borehole catchment. Molecular topological descriptors as well as K oc , solubility and half-life were used to characterize each compound included in the study. Inclusion of molecular properties makes it possible to discriminate between occurrence and non-occurrence of each compound in each well. The best-fit model combines: organic carbon content, percentage sand content and depth to the water table with molecular descriptors representing molecular size, molecular branching and functional group composition of the herbicides.

Midwest region↗

USGS2026

Erosional and hydrological controls on the age and thermochemical stability of particulate organic carbon in an Arctic river

Understanding the mechanisms that drive the mobilization and fate of organic carbon (OC) in Arctic landscapes is important for modeling the feedbacks among permafrost thaw, carbon cycling, and climate change. While significant progress has been made toward measuring in situ OC decomposition in permafrost soils and bulk particulate organic carbon (POC) export from Arctic rivers, few studies have distinguished the source and lability of POC across Arctic landscapes, limiting our ability to predict whether mobilized POC will be oxidized to CO 2 and CH 4 or buried in downstream depositional environments. This study uses ramped pyrolysis/oxidation radiocarbon (RPO- 14 C) analyses to investigate spatial and temporal variations in the thermochemical stability and radiocarbon content of fluvial POC during downstream transport from mountains to the coast in the Canning River (North Slope, Alaska). Fluvial POC in the headwaters is predominantly comprised of high activation energy, thermally recalcitrant petrogenic OC (OC petro ) derived from shale bedrock. Moving into the foothills and low-relief coastal plains, river bank erosion primarily drives mobilization of labile, low activation energy, soil-derived OC (OC soil ). Fluvial POC in mountainous upstream reaches consisted of ∼70% OC petro and just ∼30% OC soil , while POC in the downstream coastal plain reaches comprised ∼85% OC soil and ∼15% OC petro . The high relative lability of POC exported to the coast indicates high susceptibility to oxidation and microbial decomposition, which could enhance CO 2 release as the Arctic hydrologic cycle intensifies. However, the persistence of refractory OC petro in the suspended load indicates the potential for long-term burial of rock organic carbon in marine sediments.

Alaska↗

USGS2006

Gas hydrate potential of the mid Atlantic outer continental shelf

For the last two years, the Minerals Management Service (MMS) has been studying the resource potential of gas hydrates in federal offshore lands of the Outer Continental Shelf (OCS) off the Atlantic, Gulf of Mexico, Pacific, and Alaska in collaboration with the U.S. Geological Survey (USGS), the Department of Energy (DOE), the National Oceanic and Atmospheric Administration (NOAA), the Naval Research Lab (NRL) and academia. Utilizing its extensive seismic, well, and geochemical databases, the MMS will be reporting the in-place resource numbers within the next few months. Though the methodology of the study was not prospect oriented, discrete prospects have been recognized.

Fire in the Ice: NETL Methane Hydrate Newsletter↗

USGS2013

Variations of iron flux and organic carbon remineralization in a subterranean estuary caused by interannual variations in recharge

We determine the inter-annual variations in diagenetic reaction rates of sedimentary iron (Fe ) in an east Florida subterranean estuary and evaluate the connection between metal fluxes and recharge to the coastal aquifer. Over the three-year study period (from 2004 to 2007), the amount of Fe-oxides reduced at the study site decreased from 192 g/yr to 153 g/yr and associated organic carbon (OC) remineralization decreased from 48 g/yr to 38 g/yr. These reductions occurred although the Fe-oxide reduction rates remained constant around 1 mg/cm 2 /yr. These results suggest that changes in flow rates of submarine groundwater discharge (SGD) related to changes in precipitation may be important to fluxes of the diagenetic reaction products. Rainfall at a weather station approximately 5 km from the field area decreased from 12.6 cm/month to 8.4 cm/month from 2004 to 2007. Monthly potential evapotranspiration (PET) calculated from Thornthwaite’s method indicated potential evapotranspiration cycled from about 3 cm/month in the winter to about 15 cm/month in the summer so that net annual recharge to the aquifer decreased from 40 cm in 2004 to -10 cm in 2007. Simultaneously, with the decrease in recharge of groundwater, freshwater SGD decreased by around 20% and caused the originally 25 m wide freshwater seepage face to decrease in width by about 5 m. The smaller seepage face reduced the area under which Fe-oxides were undergoing reductive dissolution. Consequently, the observed decrease in Fe flux is controlled by hydrology of the subterranean estuary. These results point out the need to better understand linkages between temporal variations in diagenetic reactions and changes in flow within subterranean estuaries in order to accurately constrain their contribution to oceanic fluxes of solutes from subterranean estuaries.

Florida↗