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Secondary sulfate minerals associated with acid drainage in the eastern US: Recycling of metals and acidity in surficial environments

Weathering of metal-sulfide minerals produces suites of variably soluble efflorescent sulfate salts at a number of localities in the eastern United States. The salts, which are present on mine wastes, tailings piles, and outcrops, include minerals that incorporate heavy metals in solid solution, primarily the highly soluble members of the melanterite, rozenite, epsomite, halotrichite, and copiapite groups. The minerals were identified by a combination of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron-microprobe. Base-metal salts are rare at these localities, and Cu, Zn, and Co are commonly sequestered as solid solutions within Fe- and Fe-Al sulfate minerals. Salt dissolution affects the surface-water chemistry at abandoned mines that exploited the massive sulfide deposits in the Vermont copper belt, the Mineral district of central Virginia, the Copper Basin (Ducktown) mining district of Tennessee, and where sulfide-bearing metamorphic rocks undisturbed by mining are exposed in Great Smoky Mountains National Park in North Carolina and Tennessee. Dissolution experiments on composite salt samples from three minesites and two outcrops of metamorphic rock showed that, in all cases, the pH of the leachates rapidly declined from 6.9 to <3.7, and specific conductance increased gradually over 24 h. Leachates analyzed after 24-h dissolution experiments indicated that all of the salts provided ready sources of dissolved Al (>30 mg L-1), Fe (>47 mg L-1), sulfate (>1000 mg L-1), and base metals (>1000 mg L-1 for minesites, and 2 mg L-1 for other sites). Geochemical modeling of surface waters, mine-waste leachates, and salt leachates using PHREEQC software predicted saturation in the observed ochre minerals, but significant concentration by evaporation would be needed to reach saturation in most of the sulfate salts. Periodic surface-water monitoring at Vermont minesites indicated peak annual metal loads during spring runoff. At the Virginia site, where no winter-long snowpack develops, metal loads were highest during summer months when salts were dissolved periodically by rainstorms following sustained evaporation during dry spells. Despite the relatively humid climate of the eastern United States, where precipitation typically exceeds evaporation, salts form intermittently in open areas, persist in protected areas when temperature and relative humidity are appropriate, and contribute to metal loadings and acidity in surface waters upon dissolution, thereby causing short-term perturbations in water quality.

Chemical Geology

Iron-titanium oxide minerals and associated alteration phases in some uranium-bearing sandstones

Detrital iron-titanium (Fe-Ti) oxide minerals of the ulvospinel-magnetite (titanomagnetite) and ilmenite-hematite (titanohematite) solid solution series are common in uranium-bearing sandstones. Alteration of Fe-Ti oxide minerals in oxidizing environments formed secondary products (primarily hematite) that are distinct from those produced under reducing conditions (iron disulfide minerals). Oxidation of sulfidized Fe-Ti oxide minerals, by the processes that formed uranium rolls, produced ferric oxide minerals (limonite) having textures that mimic those of the iron disulfides. Titanomagnetite and titanohematite have been severely depleted in the ore-bearing zones of some uranium deposits. The alteration of detrital Fe-Ti oxide minerals near uranium ore deposits may produce characteristic signatures in the magnetization of the sandstone. Knowledge of the distribution and magnetic properties of these minerals can aid in interpreting data from total magnetic-field and magnetic-susceptibility surveys of uranium deposits.

Colorado, New Mexico, Texas, Wyoming

Mineral stimulation of subsurface microorganisms: release of limiting nutrients from silicates

Microorganisms play an important role in the weathering of silicate minerals in many subsurface environments, but an unanswered question is whether the mineral plays an important role in the microbial ecology. Silicate minerals often contain nutrients necessary for microbial growth, but whether the microbial community benefits from their release during weathering is unclear. In this study, we used field and laboratory approaches to investigate microbial interactions with minerals and glasses containing beneficial nutrients and metals. Field experiments from a petroleum-contaminated aquifer, where silicate weathering is substantially accelerated in the contaminated zone, revealed that phosphorus (P) and iron (Fe)-bearing silicate glasses were preferentially colonized and weathered, while glasses without these elements were typically barren of colonizing microorganisms, corroborating previous studies using feldspars. In laboratory studies, we investigated microbial weathering of silicates and the release of nutrients using a model ligand-promoted pathway. A metal-chelating organic ligand 3,4 dihydroxybenzoic acid (3,4 DHBA) was used as a source of chelated ferric iron, and a carbon source, to investigate mineral weathering rate and microbial metabolism. In the investigated aquifer, we hypothesize that microbes produce organic ligands to chelate metals, particularly Fe, for metabolic processes and also form stable complexes with Al and occasionally with Si. Further, the concentration of these ligands is apparently sufficient near an attached microorganism to destroy the silicate framework while releasing the nutrient of interest. In microcosms containing silicates and glasses with trace phosphate mineral inclusions, microbial biomass increased, indicating that the microbial community can use silicate-bound phosphate inclusions. The addition of a native microbial consortium to microcosms containing silicates or glasses with iron oxide inclusions correlated to accelerated weathering and release of Si into solution as well as the accelerated degradation of the model substrate 3,4 DHBA. We propose that silicate-bound P and Fe inclusions are bioavailable, and microorganisms may use organic ligands to dissolve the silicate matrix and access these otherwise limiting nutrients.

Chemical Geology

Some aspects of the geochemistry of sphalerite, Central City District, Colorado

Detailed studies of sphalerite , as a part of a larger study of the Central City district , Colorado , have been undertaken to learn something of the physico-chemical environment of ore deposition. More than 90 samples have been analyzed by chemical and spectrochemical methods and these data are interpreted in the light of experimental information. Sphalerite is a widespread and moderately abundant constituent of the gold- and silver-rich veins of the district . It was deposited during one stage of mineralization, in all environments of the concentrically zoned district except in the core. On a district -wide basis it occurs in three mineral assemblages: sphalerite -pyrite- chalcopyrite-tennantite-galena, sphalerite -pyrite-tennantite-galena, and sphalerite -pyrite-enargite-tennan-tite-galena. Quartz and, locally, other gangues are present.The sphalerite samples contain from 12 to 0.05 weight percent iron and detectable amounts of a restricted suite of minor elements, principally manganese, cadmium, copper, and lead. Manganese correlates directly with iron content, but the other minor elements have random correlations.The iron content of Central City sphalerite is interpreted to be mainly a function of activity of sulfur and temperature. Total pressure and minor elements that may enter the structure of either sphalerite or coexisting pyrite are thought to have negligible effects on the amount of iron in the sphalerite .The iron content of the sphalerite and fluid inclusion studies indicate that mineralization occurred over a temperature range from at least 620° C to about 150° C. In general, the temperatures tended to decrease from the vicinity of the central zone outward toward the peripheral zone. The thermal pattern, however, was complex, and marked by local irregularities.The activity of sulfur decreased with temperature, but to an extent such that more sulfur-rich mineral assemblages could form toward the margins of the district .The minor-element content of the sphalerite is governed by the activities of the various components and by the ability of the host mineral to accomodate it. Manganese varies widely because (1) it is geochemically much more abundant than is zinc and (2) it can also enter other minerals on a large scale. Conversely, because the amount of cadmium is small relative to that of zinc and because it enters only sphalerite in quantitatively significant amounts in hydrothermal environments, the cadmium content of sphalerite is constant. The copper content of the sphalerites is low and in good agreement with recent experimental data of Priestley Toulmin 3d.

Colorado

Surface-water, ground-water, and sediment geochemistry of epizonal and shear-hosted mineral deposits in the Tintina Gold Province--arsenic and antimony distribution and mobility: Chapter G in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

Epigenetic mineral deposits in the Tintina Gold Province are generally characterized by high concentrations of arsenic and antimony in their mineral assemblage. A total of 347 samples (ground water, surface water, and stream sediment) were collected to investigate the distribution and mobility of arsenic and antimony in the environment near known mineral deposits. Samples were collected from east to west at Keno Hill and Brewery Creek, Yukon, Canada; and Cleary Hill, True North, Scrafford Mine, Fairbanks, Ryan Lode, Stampede Creek, Slate Creek, and Donlin Creek, all in Alaska. Surface- and ground-water samples are all slightly acidic to near-neutral in pH (5-8), have a wide range in specific conductance (surface water 17-2,980 microsiemens per centimeter and ground water 170-2,940 microsiemens per centimeter), and show elevated dissolved arsenic and antimony concentrations (arsenic in surface water is less than 1 to 380 micrograms per liter and in ground water is less than 1 micrograms per liter to 1.5 milligrams per liter; antimony in surface water is less than 2 to 660 micrograms per liter and in ground water is less than 2 to 60 micrograms per liter). Stream sediments downstream from these deposits have high concentrations of arsenic and antimony (arsenic median is 1,670 parts per million, maximum is 10,000 parts per million; antimony median is 192 parts per million, maximum is 7,200 parts per million). The mobility of arsenic and antimony is controlled by the local redox environment, with arsenic being less mobile in oxidized surface waters relative to antimony, and arsenic more mobile in reduced ground water. These factors suggest that both antimony and arsenic may be useful pathfinder elements in water and sediment for targeting similar style deposits elsewhere in the Tintina Gold Province.

Alaska;Yukon

Regional Crustal Structures and Their Relationship to the Distribution of Ore Deposits in the Western United States, Based on Magnetic and Gravity Data

Upgraded gravity and magnetic databases and associated filtered-anomaly maps of western United States define regional crustal fractures or faults that may have guided the emplacement of plutonic rocks and large metallic ore deposits. Fractures, igneous intrusions, and hydrothermal circulation tend to be localized along boundaries of crustal blocks, with geophysical expressions that are enhanced here by wavelength filtering. In particular, we explore the utility of regional gravity and magnetic data to aid in understanding the distribution of large Mesozoic and Cenozoic ore deposits, primarily epithermal and porphyry precious and base metal deposits and sediment-hosted gold deposits in the western United States cordillera. On the broadest scale, most ore deposits lie within areas characterized by low magnetic properties. The Mesozoic Mother Lodge gold belt displays characteristic geophysical signatures (regional gravity high, regional low-to-moderate background magnetic field anomaly, and long curvilinear magnetic highs) that might serve as an exploration guide. Geophysical lineaments characterize the Idaho-Montana porphyry belt and the La Caridad-Mineral Park belt (from northern Mexico to western Arizona) and thus indicate a deep-seated control for these mineral belts. Large metal accumulations represented by the giant Bingham porphyry copper and the Butte polymetallic vein and porphyry copper systems lie at intersections of several geophysical lineaments. At a more local scale, geophysical data define deep-rooted faults and magmatic zones that correspond to patterns of epithermal precious metal deposits in western and northern Nevada. Of particular interest is an interpreted dense crustal block with a shape that resembles the elliptical deposit pattern partly formed by the Carlin trend and the Battle Mountain-Eureka mineral belt. We support previous studies, which on a local scale, conclude that structural elements work together to localize mineral deposits within regional zones or belts. This study of mineral deposits of the western United States demonstrates the ability of magnetic and gravity data to elucidate the regional geologic framework or structural setting and to contribute in locating favorable environments for hydrothermal mineralization.

Economic Geology

U.S. Geological Survey Mineral Resources Program—Mineral resource science supporting informed decisionmaking

The USGS Mineral Resources Program (MRP) delivers unbiased science and information to increase understanding of mineral resource potential, production, and consumption, and how mineral resources interact with the environment. The MRP is the Federal Government’s sole source for this mineral resource science and information. Program goals are to (1) increase understanding of mineral resource formation, (2) provide mineral resource inventories and assessments, (3) broaden knowledge of the effects of mineral resources on the environment and society, and (4) provide analysis on the availability and reliability of mineral supplies.

Fact Sheet

Porphyry copper deposits of the world: database, map, and grade and tonnage models

Mineral deposit models are important in exploration planning and quantitative resource assessments for two reasons: (1) grades and tonnages among deposit types are significantly different, and (2) many types occur in different geologic settings that can be identified from geologic maps. Mineral deposit models are the keystone in combining the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Too few thoroughly explored mineral deposits are available in most local areas for reliable identification of the important geoscience variables or for robust estimation of undiscovered deposits-thus we need mineral-deposit models. Globally based deposit models allow recognition of important features because the global models demonstrate how common different features are. Well-designed and -constructed deposit models allow geologists to know from observed geologic environments the possible mineral deposit types that might exist, and allow economists to determine the possible economic viability of these resources in the region. Thus, mineral deposit models play the central role in transforming geoscience information to a form useful to policy makers. The foundation of mineral deposit models is information about known deposits-the purpose of this publication is to make this kind of information available in digital form for porphyry copper deposits. This report is an update of an earlier publication about porphyry copper deposits. In this report we have added 84 new porphyry copper deposits and removed 12 deposits. In addition, some errors have been corrected and a number of deposits have had some information, such as grades, tonnages, locations, or ages revised. This publication contains a computer file of information on porphyry copper deposits from around the world. It also presents new grade and tonnage models for porphyry copper deposits and for three subtypes of porphyry copper deposits and a map showing the location of all deposits. The value of this information and any derived analyses depends critically on the consistent manner of data gathering. For this reason, we first discuss the rules used in this compilation. Next, the fields of the data file are considered. Finally, we provide new grade and tonnage models.

Open-File Report

Porphyry copper deposits of the world: Database and grade and tonnage models, 2008

This report is an update of earlier publications about porphyry copper deposits (Singer, Berger, and Moring, 2002; Singer, D.A., Berger, V.I., and Moring, B.C., 2005). The update was necessary because of new information about substantial increases in resources in some deposits and because we revised locations of some deposits so that they are consistent with images in GoogleEarth. In this report we have added new porphyry copper deposits and removed a few incorrectly classed deposits. In addition, some errors have been corrected and a number of deposits have had some information, such as grades, tonnages, locations, or ages revised. Colleagues have helped identify places where improvements were needed. Mineral deposit models are important in exploration planning and quantitative resource assessments for a number of reasons including: (1) grades and tonnages among deposit types are significantly different, and (2) many types occur in different geologic settings that can be identified from geologic maps. Mineral deposit models are the keystone in combining the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Too few thoroughly explored mineral deposits are available in most local areas for reliable identification of the important geoscience variables or for robust estimation of undiscovered deposits?thus we need mineral-deposit models. Globally based deposit models allow recognition of important features because the global models demonstrate how common different features are. Well-designed and -constructed deposit models allow geologists to know from observed geologic environments the possible mineral deposit types that might exist, and allow economists to determine the possible economic viability of these resources in the region. Thus, mineral deposit models play the central role in transforming geoscience information to a form useful to policy makers. The foundation of mineral deposit models is information about known deposits. The purpose of this publication is to make this kind of information available in digital form for porphyry copper deposits. The consistently defined deposits in this file provide the foundation for grade and tonnage models included here and for mineral deposit density models (Singer and others, 2005: Singer, 2008).

Open-File Report

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids, acidity, alkalinity, Cl - , F - and SO 4 2- found in receiving streams, rivers, and lakes are affected by all of these factors and their interactions. Remediation of mine sites is an engineering concern but to design a remediation plan without understanding the hydrogeochemical processes of contaminant mobilization can lead to ineffective and excessively costly remediation. Furthermore, remediation needs a goal commensurate with natural background conditions rather than water-quality standards that might bear little relation to conditions of a highly mineralized terrain. This paper reviews hydrogeochemical generalizations, primarily from US Geological Survey research, that enhance our understanding of the origin, transport, and fate of contaminants released from mined and mineralized areas. Mobility of potential or actual contaminants from mining and mineral processing activities depends on (1) occurrence : is the mineral source of the contaminant actually present? (2) abundance : is the mineral present in sufficient quantity to make a difference? (3) reactivity : what are the energetics, rates, and mechanisms of sorption and mineral dissolution and precipitation relative to the flow rate of the water? and (4) hydrology : what are the main flow paths for contaminated water? Estimates of relative proportions of minerals dissolved and precipitated can be made with mass-balance calculations if minerals and water compositions along a flow path are known. Combined with discharge, these mass-balance estimates quantify the actual weathering rate of pyrite mineralization in the environment and compare reasonably well with laboratory rates of pyrite oxidation except when large quantities of soluble salts and evaporated mine waters have accumulated underground. Quantitative mineralogy with trace-element compositions can substantially improve the identification of source minerals for specific trace elements through mass balances. Post-dissolution sorption and precipitation (attenuation) reactions depend on the chemical behavior of each element, solution composition and pH, aqueous speciation, temperature, and contact-time with mineral surfaces. For example, little metal attenuation occurs in waters of low pH (<3.5) and metals tend to maintain element ratios indicative of the main mineral or group of minerals from which they dissolved, except Fe, SiO 2 , and redox-sensitive oxyanions (As, Sb, Se, Mo, Cr, V). Once dissolved, metal and metalloid concentrations are strongly affected by redox conditions and pH. Iron is the most reactive because it is rapidly oxidized by bacteria and archaea and Fe(III) hydrolyzes and precipitates at low pH (1&ndash;3) which is related directly to its first hydrolysis constant, pK 1 = 2.2. Several insoluble sulfate minerals precipitate at low pH including anglesite, barite, jarosite, alunite and basaluminite. Aluminum hydrolyzes near pH 5 (pK 1 = 5.0) and provides buffering and removal of Al by mineral precipitation from pH 4&ndash;5.5. Dissolved sulfate behaves conservatively because the amount removed from solution by precipitation is usually too small relative to the high concentrations in the water column and relative to the flow rate of the water.

Applied Geochemistry

Porphyry copper deposits of the world: Database, maps, and preliminary analysis

Mineral deposit models are important in exploration planning and quantitative resource assessments for two reasons: (1) grades and tonnages among deposit types are significantly different, and (2) many types occur in different geologic settings that can be identified from geologic maps. Mineral deposit models are the keystone in combining the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Far too few thoroughly explored mineral deposits are available in most local areas for reliable identification of the important geoscience variables or for robust estimation of undiscovered deposits—thus we need mineral-deposit models. Globally based deposit models, such as those presented here, allow recognition of important features because the global models demonstrate how common different features are. Well-designed and -constructed deposit models allow geologists to know from observed geologic environments the possible mineral deposit types that might exist, and allow economists to determine the possible economic viability of these resources in the region. Thus, mineral deposit models play the central role in transforming geoscience information to a form useful to policy makers. The foundation of mineral deposit models is information about known deposits—the purpose of this publication is to make this kind of information available in digital form for a group of porphyry copper deposits. This publication contains a computer file of information on porphyry copper deposits around the world. It also presents new grade and tonnage models for three subtypes of porphyry copper deposits, maps showing locations and general ages of these deposits, and a preliminary analysis with a number of figures summarizing many of the properties of these porphyry-style deposits. These summaries can be considered a new, quantified, form of most parts of descriptive models such as those in Cox and Singer (1986). The value of this information and analyses depends critically on the consistent manner of data gathering. For this reason, we first discuss the rules used in this compilation. Next the fields of the data file are considered. Finally, we discuss some of the things that can be done with the data.

Open-File Report

Geochemistry of host rocks in the Howards Pass district, Yukon-Northwest Territories, Canada: implications for sedimentary environments of Zn-Pb and phosphate mineralization

Detailed lithogeochemical data are reported here on early Paleozoic sedimentary rocks that host the large Howards Pass stratiform Zn-Pb deposits in Yukon-Northwest Territories. Redox-sensitive trace elements (Mo, Re, V, U) and Ce anomalies in members of the Duo Lake Formation record significant environmental changes. During the deposition of lower footwall units (Pyritic siliceous and Calcareous mudstone members), bottom waters were anoxic and sulphidic, respectively; these members formed in a marginal basin that may have become increasingly restricted with time. Relative to lower members, a major environmental change is proposed for deposition of the overlying Lower cherty mudstone member, which contains phosphorite beds up to ∼0.8 m thick in the upper part, near the base of the Zn-Pb deposits. The presence of these beds, together with models for modern phosphorite formation, suggests P input from an upwelling system and phosphorite deposition in an upper slope or outer shelf setting. The overlying Active mudstone member contains stratabound to stratiform Zn-Pb deposits within black mudstone and gray calcareous mudstone. Data for unmineralized black mudstone in this member indicate deposition under diverse redox conditions from suboxic to sulphidic. Especially distinctive in this member are uniformly low ratios of light to heavy rare earth elements that are unique within the Duo Lake Formation, attributed here to the dissolution of sedimentary apatite by downward-percolating acidic metalliferous brines. Strata that overlie the Active member (Upper siliceous mudstone member) consist mainly of black mudstone with thin (0.5–1.5 cm) laminae of fine-grained apatite, recording continued deposition on an upper slope or outer shelf under predominantly suboxic bottom waters. Results of this study suggest that exploration for similar stratiform sediment-hosted Zn-Pb deposits should include the outer parts of ancient continental margins, especially at and near stratigraphic transitions from marginal basin facies to overlying slope or shelf facies.

Mineralium Deposita

Marine minerals in Alaska — A review of coastal and deep-ocean regions

Minerals occurring in marine environments span the globe and encompass a broad range of mineral categories, forming within varied geologic and oceanographic settings. They occur in coastal regions, either from the continuation or mechanical reworking of terrestrial mineralization, as well as in the deep ocean, from diagenetic, hydrogenetic, and hydrothermal processes. The oceans cover most of the Earth’s surface and as a result, any inventory of global resources is incomplete without the inclusion of marine minerals. This study by the U.S. Geological Survey reviews current knowledge regarding deep-ocean and coastal marine minerals within the marine areas surrounding Alaska, including the Alaska Outer Continental Shelf (OCS). For the purposes of this study, we have divided these areas in to eight regions: (1) Gulf of Alaska seamounts, (2) Chukchi Borderland, (3) Canada Basin, (4) Aleutian Arc, (5) Seward Peninsula, (6) Goodnews Bay, (7) Bristol Bay and Alaska Peninsula, and (8) southern and southeastern Alaska. The Alaska OCS encompasses several areas broadly conducive to marine mineral formation, including extensional basins resulting from an active subduction zone where massive sulfide deposits may form, deep abyssal plains with conditions that may lead to manganese nodule formation, seamounts that can provide substrate for the growth of ferromanganese crusts, and erosional settings and submerged continental crust where placer deposits are found. For deep-ocean hydrothermal minerals and manganese nodules, the Alaska OCS contains prospective regions, including the Canada Basin and the Aleutian Arc; however, no such minerals have yet been identified. We explore the probability that these minerals occur based on reviews of existing geologic and oceanographic data within the relevant sections. In regions far from shore data are limited. Deep-ocean ferromanganese crusts are known to occur in two regions: (1) the Gulf of Alaska seamounts and (2) the Chukchi Borderland in the Arctic Ocean. Limited sampling has occurred in both regions, and along the Chukchi Borderland the sampling was outside of the OCS and the U.S. Exclusive Economic Zone. Data relevant to coastal minerals is more extensive, and in some places fairly systematic sampling was conducted. Several nearshore placer deposits have been exploited for decades; however, the potential for nearshore extension of terrestrial ore deposits is less well considered. This contribution considers the state of knowledge regarding marine mineral occurrences within the Alaska regions and identifies the data gaps in order to help inform future marine mineral related research efforts around Alaska.

Alaska

Mapping critical minerals from the sky

Critical mineral resources titanium, zirconium, and rare earth elements occur in placer deposits over vast parts of the U.S. Atlantic Coastal Plain. Key questions regarding provenance, pathways of minerals to deposit sites, and relations to geologic features remain unexplained. As part of a national effort to collect data over regions prospective for critical minerals, the first public high-resolution aeroradiometric survey over the U.S. Atlantic Coastal Plain was conducted over Quaternary sediments in South Carolina. The new data provide an unprecedented view of potential deposits by imaging Th-bearing minerals in the heavy mineral assemblage. Sand ridges show the highest radiometric Th values with localized, linear anomalies, especially along the shoreface and in areas reworked by multiple processes and/or during multiple episodes. Estuarine areas with finer-grained sediments show lower, distributed Th anomalies. Th values averaged over geologic unit areas are similar for both environments, suggesting that heavy minerals are present but have not been locally concentrated in the lower-energy estuarine environments. Radiometric K highlights immature minerals such as mica and potassium feldspar. K is elevated within shallow sediments younger than ca. 130 ka, an attribute that persists in regional data from northern South Carolina to northern Florida. Both K and Th are elevated over the floodplains of the Santee River and other rivers with headwaters in the igneous and metamorphic Piedmont Terrane. The persistence of K anomalies for distances of more than 100 km from the Santee River floodplain suggests that heavy minerals are delivered from the Piedmont to offshore areas by major rivers, transported along the coast by the longshore current, and redeposited onshore by marine processes.

Florida, Georgia, South Carolina

Microbial transformation of elements: The case of arsenic and selenium

Microbial activity is responsible for the transformation of at least one third of the elements in the periodic table. These transformations are the result of assimilatory, dissimilatory, or detoxification processes and form the cornerstones of many biogeochemical cycles. Arsenic and selenium are two elements whose roles in microbial ecology have only recently been recognized. Known as "essential toxins", they are required in trace amounts for growth and metabolism but are toxic at elevated concentrations. Arsenic is used as an osmolite in some marine organisms while selenium is required as selenocysteine (i.e. the twenty-first amino acid) or as a ligand to metal in some enzymes (e.g. FeNiSe hydrogenase). Arsenic resistance involves a small-molecular-weight arsenate reductase (ArsC). The use of arsenic and selenium oxyanions for energy is widespread in prokaryotes with representative organisms from the Crenarchaeota, thermophilic bacteria, low and high G+C gram-positive bacteria, and Proteobacteria. Recent studies have shown that both elements are actively cycled and play a significant role in carbon mineralization in certain environments. The occurrence of multiple mechanisms involving different enzymes for arsenic and selenium transformation indicates several different evolutionary pathways (e.g. convergence and lateral gene transfer) and underscores the environmental significance and selective impact in microbial evolution of these two elements.

International Microbiology

Worldwide occurrences of arsenic in ground water

Numerous aquifers worldwide carry soluble arsenic at concentrations greater than the World Health Organization--and U.S. Environmental Protection Agency--recommended drinking water standard of 10 mg per liter. Sources include both natural (black shales, young sediments with low flushing rates, gold mineralization, and geothermal environments) and anthropogenic (mining activities, livestock feed additives, pesticides, and arsenic trioxide wastes and stockpiles). Increased solubility and mobility of arsenic is promoted by high pH (>8.5), competing oxyanions, and reducing conditions. In this Policy Forum, Nordstrom argues that human health risks from arsenic in ground water can be minimized by incorporating hydrogeochemical knowledge into water management decisions and by more careful monitoring for arsenic in geologically high-risk areas.

Science

Aeromagnetic maps of the Latir Peak and Wheeler Peak Wildernesses and the Columbine-Hondo Wilderness Study Area, Taos County, New Mexico

This report interprets data from a helicopter-borne magnetic survey to help delineate subsurface geology. Such data, acquired near the ground, reflect greater magnetic detail than do data acquired at higher altitude. Data from a high-altitude reconnaissance aeromagnetic survey (U.S. Geological Survey, 1976) are used selectively to assist in the interpretation of the helicopter data. Interpretations are chiefly empirical, wherein magnetic anomalies characterizing known geologic features in the region are used as interpretive criteria for identifying such features where they are concealed. Identifying geologic environments favorable for mineral deposits is a primary objective of this report. Geophysical interpretations of a broader and more general scope are made from other geophysical data by Cordell and Jones (in press).

New Mexico