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Confirmation of a meteoritic component in impact-melt rocks of the Chesapeake Bay impact structure, Virginia, USA - Evidence from osmium isotopic and PGE systematics

The osmium isotope ratios and platinum-group element (PGE) concentrations of impact-melt rocks in the Chesapeake Bay impact structure were determined. The impact-melt rocks come from the cored part of a lower-crater section of suevitic crystalline-clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The 187Os/188Os ratios of impact-melt rocks range from 0.151 to 0.518. The rhenium and platinum-group element (PGE) concentrations of these rocks are 30-270?? higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact-melt rocks. Because the PGE abundances in the impact-melt rocks are dominated by the target materials, interelemental ratios of the impact-melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact-melt rocks include a bulk meteoritic component of 0.01-0.1% by mass. Several impact-melt rocks with lowest initial 187Os/188Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%-0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01-0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact-melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact-melt rocks, and 2) variable fractionations of PGE during syn- to post-impact events. ?? The Meteoritical Society, 2006.

Meteoritics and Planetary Science

Chesapeake Bay impact structure: Morphology, crater fill, and relevance for impact structures on Mars

The late Eocene Chesapeake Bay impact structure (CBIS) on the Atlantic margin of Virginia is one of the largest and best-preserved "wet-target" craters on Earth. It provides an accessible analog for studying impact processes in layered and wet targets on volatile-rich planets. The CBIS formed in a layered target of water, weak clastic sediments, and hard crystalline rock. The buried structure consists of a deep, filled central crater, 38 km in width, surrounded by a shallower brim known as the annular trough. The annular trough formed partly by collapse of weak sediments, which expanded the structure to ???85 km in diameter. Such extensive collapse, in addition to excavation processes, can explain the "inverted sombrero" morphology observed at some craters in layered targets. The distribution of crater-fill materials i n the CBIS is related to the morphology. Suevitic breccia, including pre-resurge fallback deposits, is found in the central crater. Impact-modified sediments, formed by fluidization and collapse of water-saturated sand and silt-clay, occur in the annular trough. Allogenic sediment-clast breccia, interpreted as ocean-resurge deposits, overlies the other impactites and covers the entire crater beneath a blanket of postimpact sediments. The formation of chaotic terrains on Mars is attributed to collapse due to the release of volatiles from thick layered deposits. Some flat-floored rimless depressions with chaotic infill in these terrains are impact craters that expanded by collapse farther than expected for similar-sized complex craters in solid targets. Studies of crater materials in the CBIS provide insights into processes of crater expansion on Mars and their links to volatiles. ?? The Meteoritical Society, 2006.

Meteoritics and Planetary Science

Evidence of the impacting body of the Ries crater - the discovery of Fe-Cr-Ni veinlets below the crater bottom

Fe-Cr-Ni particles and veinlets have been discovered in the top 15 m of the compressed zone with abundant shatter cones below the bottom of the Ries crater. The metallic particles are less than a few microns across. They occur in various minerals along healed intergranular and locally in intragranular microfractures in quartz diorite, amphibolite and chloritized granite of the basement crystalline rocks. The particles consist of major Fe, Cr, and Ni with minor Si and Ca. Origin due to contamination is absolutely ruled out. We believe that these Fe-Cr-Ni particles are probably condensed from the vaporized impacting body which produced the Ries crater. These particles were injected with high velocity into microfractures near the top of the compressed zone, implanted in and across various minerals before these microfractures were resealed. The presence of Si and Ca as well as the fact that the Cr content is nearly twice that of Ni, led us to conclude that the Ries impacting body is very likely not an iron meteorite but a stony meteorite.

Earth and Planetary Science Letters

Discovery of microscopic evidence for shock metamorphism at the Serpent Mound structure, south-central Ohio: Confirmation of an origin by impact

The origin of the Serpent Mound structure in south-central Ohio has been disputed for many years. Clearly, more evidence was needed to resolve the confusion concerning the origin of the Serpent Mound feature either by endogenic processes or by hypervelocity impact. A petrographic study of 21 samples taken from a core 903 m long drilled in the central uplift of the structure provides evidence of shock metamorphism in the form of multiple sets of planar deformation features in quartz grains, as well as the presence of clasts of altered impact-melt rock. Crystallographic orientations of the planar deformation features show maxima at the shock-characteristic planes of {101??3} and {101??2} and additional maxima at {101??1}, {213??1}, and {516??1}. Geochemical analyses of impact breccias show minor enrichments in the abundances of the siderophile elements Cr, Co, Ni, and Ir, indicating the presence of a minor meteoritic component.

Earth and Planetary Science Letters

ReOs isotope systematics of NiCu sulfide ores, Sudbury Igneous Complex, Ontario: Evidence for a major crustal component

Sudbury Igneous Complex sublayer ores from the Levack West, Falconbridge and Strathcona mines were analyzed for their Re and Os concentrations and Os isotopic compositions. The Re-Os isotope systematics of three ores from the different mines give isochron ages of1 840 ± 60 Ma, 1770 ± 60 Ma and 1780 ± 110 Ma, suggesting that the Re-Os system became closed at the time of, or soon after the 1850 ± 1 Ma crystallization age of the complex. The Os isotopic compositions of different portions of the complex at the time of crystallization varied considerably, with initial 187 Os/ 186 Os 1850 ranging from 4.64 at Levack West to 7.55 at Strathcona. These heterogeneities require that the Os, and probably also the other platinum-group elements contained in the ores, were derived from at least two sources. In addition, the high initial 187 Os/ 186 Os ratios indicate that the Os was derived predominantly from ancient crust. Previous studies have suggested that the complex either crystallized from a mixture of mantle-derived basaltic melt and ancient continental crust, or was derived exclusively from the fusion of ancient continental crust resulting from a meteorite impact. Results of modelling suggest that if a contemporaneous mantle-derived basaltic melt was involved in the origin of the SIC, it likely contributed < 50% of the Os to all three ores. The large percentage of ancient crust involved in the production of the ores is most consistent with an interpretation of substantial crustal fusion resulting from meteorite impact.

Earth and Planetary Science Letters

Nomad Rover field experiment, Atacama Desert, Chile 1. Science results overview

Nomad was deployed for a 45 day traverse in the Atacama Desert, Chile, during the summer of 1997. During this traverse, 1 week was devoted to science experiments. The goal of the science experiments was to test different planetary surface exploration strategies that included (1) a Mars mission simulation, (2) a science on the fly experiment, where the rover was kept moving 75% of the operation time. (The goal of this operation was to determine whether or not successful interpretation of the environment is related to the time spent on a target. The role of mobility in helping the interpretation was also assessed.) (3) a meteorite search using visual and instrumental methods to remotely identify meteorites in extreme environments, and (4) a time-delay experiment with and without using the panospheric camera. The results were as follow: the remote science team positively identified the main characteristics of the test site geological environment. The science on the fly experiment showed that the selection of appropriate targets might be even more critical than the time spent on a study area to reconstruct the history of a site. During the same operation the science team members identified and sampled a rock from a Jurassic outcrop that they proposed to be a fossil. The presence of paleolife indicators in this rock was confirmed later by laboratory analysis. Both visual and instrumental modes demonstrated the feasibility, in at least some conditions, of carrying out a field search for meteorites by using remote-controlled vehicles. Finally, metrics collected from the observation of the science team operations, and the use team members made of mission data, provided critical information on what operation sequences could be automated on board rovers in future planetary surface explorations.

Atacama Desert

Rhenium-osmium isotope constraints on the age of iron meteorites

Rhenium and osmium concentrations and the osmium isotopic compositions of iron meteorites were determined by negative thermal ionization mass spectrometry. Data for the IIA iron meteorites define an isochron with an uncertainty of approximately ±31 million years for meteorites ∼4500 million years old. Although an absolute rheniumosmium closure age for this iron group cannot be as precisely constrained because of uncertainty in the decay constant of 187 Re, an age of 4460 million years ago is the minimum permitted by combined uncertainties. These age constraints imply that the parent body of the IIAB magmatic irons melted and subsequently cooled within 100 million years after the formation of the oldest portions of chondrites. Other iron meteorites plot above the IIA isochron, indicating that the planetary bodies represented by these iron groups may have cooled significantly later than the parent body of the IIA irons.

Science

History of the Pasamonte achondrite: Relative susceptibility of the SmNd, RbSr, and UPb systems to metamorphic events

The Rb Sr, Sm Nd, and U Pb systematics of the eucrite Pasamonte have been studied in order to investigate the relative susceptibility of the different systems to post-crystallization events and to determine the age and history of the meteorite. The Rb Sr and 238 U- 206 Pb data of mineral separates do not define an isochron but the Sm Nd data define an internal isochron which corresponds to the formation age of 4.58 ± 0.12b.y. (10 9 years). The 207 Pb- 206 Pb data of mineral separates define an apparent age of 4.53 ± 0.03b.y. , however we conclude that this age, while in agreement with the Sm Nd age, is not strictly valid since the U Pb data indicate at least three stages of evolution. The U Pb data indicate that the parent body of the meteorite experienced brecciation shortly after the formation of the parent body surface ( ∼4.2–4.45b.y. ago) and a recent disturbance (collision?) 6 ± 30m.y. ago. The latter age is within the range of cosmic ray exposure ages for achondrites.

Earth and Planetary Science Letters

Enstatite chondrites and enstatite achondrites (aubrites) were not derived from the same parent body

Enstatite achondrites (aubrites) were not derived from known enstatite chondrites by melting and fractionation on one and the same parent body, for these and other reasons: (1) There is no satisfactory mechanism for fractionating metal plus troilite in enstatite chondrites to form these phases in different proportions and with different Ti contents in aubrites. (2) Many enstatite chondrites and aubrites are regolith or fragmental breccias, but clasts of one within the other have not been found. (3) Cosmic ray exposure ages of the two groups are difficult to explain if they are from the same parent body, but are easy to explain if they are from different parent bodies. Siderophile element abundances in metal from the Mt. Egerton meteorite, which consists of enstatite and metallic Fe,Ni, preclude it from being a complementary differentiate of the aubrites. Rather, it appears that Mt. Egerton was formed from the same source material as enstatite chondrites, but the components were mixed in different proportions.

Earth and Planetary Science Letters

Seawater osmium isotope evidence for a middle Miocene flood basalt event in ferromanganese crust records

Three ferromanganese crusts from the northeast, northwest and central Atlantic were re-dated using osmium (Os) isotope stratigraphy and yield ages from middle Miocene to the present. The three Os isotope records do not show evidence for growth hiatuses. The reconstructed Os isotope-based growth rates for the sections older than 10??Ma are higher than those determined previously by the combined beryllium isotope (10Be/9Be) and cobalt (Co) constant-flux methods, which results in a decrease in the maximum age of each crust. This re-dating does not lead to significant changes to the interpretation of previously determined radiogenic isotope neodymium, lead (Nd, Pb) time series because the variability of these isotopes was very small in the records of the three crusts prior to 10??Ma. The Os isotope record of the central Atlantic crust shows a pronounced minimum during the middle Miocene between 15 and 12??Ma, similar to a minimum previously observed in two ferromanganese crusts from the central Pacific. For the other two Atlantic crusts, the Os isotope records and their calibration to the global seawater curve for the middle Miocene are either more uncertain or too short and thus do not allow for a reliable identification of an isotopic minimum. Similar to pronounced minima reported previously for the Cretaceous/Tertiary and Eocene/Oligocene boundaries, possible interpretations for the newly identified middle Miocene Os isotope minimum include changes in weathering intensity and/or a meteorite impact coinciding with the formation of the No??rdlinger Ries Crater. It is suggested that the eruption and weathering of the Columbia River flood basalts provided a significant amount of the unradiogenic Os required to produce the middle Miocene minimum. ?? 2008 Elsevier B.V.

Earth and Planetary Science Letters

Lunar rock compositions and some interpretations

Samples of igneous "gabbro," "basalt," and lunar regolith have compositions fundamentally different from all meteorites and terrestrial basalts. The lunar rocks are anhydrous and without ferric iron. Amounts of titanium as high as 7 weight percent suggest either extreme fractionation of lunar rocks or an unexpected solar abundance of titanium. The differences in compositions of the known, more "primitive" rocks in the planetary system indicate the complexities inherent in defining the solar abundances of elements and the initial compositions of the earth and moon.

Science

On the origin of lunar soil 12033

The lunar soil 12033 is compositionally distinctly different from both the local rocks at the Apollo 12 site and other lunar samples. It must be a recent deposit, else it would not have retained its identity. It contains a meteoritic component which is about 0.59 times as large as that in the more typical Apollo 12 soils. The amount of meteoritic component may be either a fortuitous residuum from the object which produced the 12033 material as crater ejecta, or 12033 may consist of a mixture of an exotic component with the local soil in approximately 41:59 proportions. The available evidence favors the latter interpretation.

Earth and Planetary Science Letters

Some triple-filament lead isotope ratio measurements and an absolute growth curve for single-stage leads

Triple-filament analyses of three standard lead samples are used to calibrate a mass spectrometer in an absolute sense. The bias we measure is 0.0155 percent per mass unit, and the precision (for 95% confidence limits) is ±0.13% or less for all ratios relative to 204 Pb. Although its precision is not quite so good as that of the lead-tetramethyl method in the analysis of large samples, the triple-filament method is less complex and is an attractive alternative for smaller sample sizes down to 500 μg. Triple-filament data are presented for six possibly single-stage lead ores and one feldspar. These new data for ores are combined with corrected tetramethyl data for stratiform lead deposits to compute absolute parameters for a universal single-stage lead isotope growth curve. Absolute isotopic ratios for primeval lead have been determined by Oversby and because all the previous data for both meteorites and lead ores were similarly fractionated, the absolute value of 238 U 204 Pb= 9.09 ± 0.06 for stratiform leads is little different from the value 8.99 ± 0.05 originally computed by Ostic, Russell and Stanton. Absolute values for lead isotope ratios for all interlaboratory standard samples presently available from the literature are tabulated.

Earth and Planetary Science Letters

Corrigendum to “Widespread occurrence of (per)chlorate in the Solar System” [Earth Planet. Sci. Lett. 430 (2015) 470–476]

The authors regret that two sets of data (Atacama (Rao et al., 2010) and Mars Meteorite Range (Kounaves et al., 2014)) in Fig. 2 of our article were plotted in the wrong units. The correction does not change the relationship between ClO 3 &#x2212; "> ClO3− and ClO 4 &#x2212; "> ClO4− ; it only shifts the magnitude of the concentrations. The conclusions of the article are not affected. The corrected Fig. 2 appears below.

Earth and Planetary Science Letters

Craters on Earth, Moon, and Mars: Multivariate classification and mode of origin

Testing extraterrestrial craters and candidate terrestrial analogs for morphologic similitude is treated as a problem in numerical taxonomy. According to a principal-components solution and a cluster analysis, 402 representative craters on the Earth, the Moon, and Mars divide into two major classes of contrasting shapes and modes of origin. Craters of net accumulation of material (cratered lunar domes, Martian “calderas,” and all terrestrial volcanoes except maars and tuff rings) group apart from craters of excavation (terrestrial meteorite impact and experimental explosion craters, typical Martian craters, and all other lunar craters). Maars and tuff rings belong to neither group but are transitional. The classification criteria are four independent attributes of topographic geometry derived from seven descriptive variables by the principal-components transformation. Morphometric differences between crater bowl and raised rim constitute the strongest of the four components. Although single topographic variables cannot confidently predict the genesis of individual extraterrestrial craters, multivariate statistical models constructed from several variables can distinguish consistently between large impact craters and volcanoes.

Earth and Planetary Science Letters

Widespread occurrence of (per)chlorate in the Solar System

Perchlorate (ClO− 4 ) and chlorate (ClO− 3 ) are ubiquitous on Earth and ClO− 4 has also been found on Mars. These species can play important roles in geochemical processes such as oxidation of organic matter and as biological electron acceptors, and are also indicators of important photochemical reactions involving oxyanions; on Mars they could be relevant for human habitability both in terms of in situ resource utilization and potential human health effects. For the first time, we extracted, detected and quantified ClO− 4 and ClO− 3 in extraterrestrial, non-planetary samples: regolith and rock samples from the Moon, and two chondrite meteorites (Murchison and Fayetteville). Lunar samples were collected by astronauts during the Apollo program, and meteorite samples were recovered immediately after their fall. This fact, together with the heterogeneous distribution of ClO− 4 and ClO− 3 within some of the samples, and their relative abundance with respect to other soluble species (e.g., NO− 3 ) are consistent with an extraterrestrial origin of the oxychlorine species. Our results, combined with the previously reported widespread occurrence on Earth and Mars, indicate that ClO− 4 and ClO− 3 could be present throughout the Solar System.

Earth and Planetary Science Letters

Thermomagnetic analysis of meteorites, 3. C3 and C4 chondrites

Thermomagnetic analysis was made on samples of all known C3 and C4 chondrites in a controlled oxygen atmosphere. Considerable variation was noted in the occurrence of magnetic minerals, comparable to the variation observed earlier in the C2 chondrites. Magnetite was found as the only major magnetic phase in samples of only three C3 chondrites (2–4 wt.%) and the Karoonda C4 chondrite (7.7 wt.%). The magnetite content of these three C3 chondrites is only about one-third that observed in the C1 and C2 chondrites which were found to contain magnetite as the only magnetic phase. Five C3 chondrites were observed to undergo chemical change during heating, producing magnetite: this behavior is characteristic of troilite oxidation. Upper limits on initial magnetite content of about 1–9% were established for these meteorites. Samples of the remaining five C3 chondrites and the Coolidge C4 chondrite were found to contain both magnetite and metallic iron. In two samples, iron containing ≤2% Ni was observed, while in the other four, the iron contained 6–8 wt.% Ni. In addition to containing both magnetite and iron metal, three of these samples reacted during heating to form additional magnetite. Variations in the magnetic mineralogy and, hence by inference bulk mineralogy, of C3 and C4 chondrites indicate a more complex genesis than is evident from whole-rock elemental abundance patterns.

Earth and Planetary Science Letters

Thermomagnetic analysis of meteorites, 2. C2 chondrites

Samples of all eighteen of the known C2 chondrites have been analyzed thermomagnetically. For eleven of these, initial Fe 3 O 4 content is low (generally <1%) and the J s -T curves are irreversible. The heating curves show variable greater (up to 10 times) than it is initially. This behavior is attributed to the production of magnetite from a thermally unstable phase — apparently FeS. Four of the remaining seven C2 chondrites contain Fe 3 O 4 as the only significant magnetic phase: initial magnetite contents range from 4 to 13%. The remaining three C2 chondrites contain iron or nickel-iron in addition to Fe 3 O 4 . These seven C2 chondrites show little evidence of the breakdown of a thermally unstable phase.

Earth and Planetary Science Letters