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Strontium isotopic geochemistry of the Devils Lake drainage system, North Dakota: A preliminary study and potential paleoclimatic implications

A series of water samples (precipitation, surface water and ground water) from the Devils Lake drainage basin in central North Dakota have been analyzed for their ??180 and ??D and 87Sr/86Sr. The ??180 and ??D of snow and most ground water samples fall near the meteoric water line, with the ground water being isotopically heavier than the snow, indicating that a portion of the recharge must come from non-winter precipitation events. One ground water and all the surface water samples fall below the meteoric water line, demonstrating extensive evaporation. The 87Sr/86Sr ratio of the snow is more radiogenic than those of the ground water samples, indicating that the ground water has increased its 86Sr content by the dissolution of mafic rock in the aquifer. Stump Lake has a much inure radiogenic Sr isotopic ratio than the waters of Devils Lake suggesting a source of water different from that of Devils Lake. The East Stump Lake water, on the other hand, appears to be either a mix of Devils Lake and Stump Lake waters, or Devils Lake water diluted with precipitation.

Journal of Paleolimnology↗

Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake Reservoir, Dallas, Texas

Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km2 reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km2. Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 ??g kg-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 ??g kg-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 ??g kg-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 ??g kg-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane continued at least until 1990. Recent use of dieldrin and aldrin, which degrades to dieldrin, has not been reported; however, increasing trends in dieldrin since the 1970s suggest recent urban use could have occurred.

Journal of Paleolimnology↗

A preliminary investigation of siliceous microfossil succession in late quaternary sediments from Lake Baikal, Siberia

Siliceous microfossil assemblage succession was analyzed in a 100 m sediment core from Lake Baikal, Siberia. The core was recovered from the lake's central basin at a water depth of 365 m. Microfossil abundance varied greatly within the intervals sampled, ranging from samples devoid of siliceous microfossils to samples with up to 3.49 x 10 11 microfossils g -1 sediment. Fluctuations in abundance appear to reflect trends in the marine δ 18 O record, with peak microfossil levels generally representing climate optima. Microfossil taxa present in sampled intervals changed considerably with core depth. Within each sample a small number of endemic diatom species dominated the assemblage. Changes in dominant endemic taxa between sampled intervals ranged from extirpation of some taxa, to shifts in quantitative abundance. Differences in microfossil composition and the association of variations in abundance with climate fluctuations suggest rapid speciation in response to major climatic excursions.

Journal of Paleolimnology↗

Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica

Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hore, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km2, maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake=wide integration. Shallow-water (<1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4-16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (2-31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta. Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.

Journal of Paleolimnology↗

Unusual carbon and oxygen isotropic ratios of ostracodal calcite from last interglacial (Sangamon episode) lacustrine sediment in Raymond Basin, Illinois, USA

The stable isotopic records of ostracode valves deposited during the last interglaciation in Raymond Basin, Illinois, have ??13C and ??18O values as high as +16.5??? and +9.2??? respectively, the highest values yet reported from continental ostracodal calcite. Located in south-central Illinois, Raymond, Pittsburgh, Bald Knob, and Hopwood Farm basins collectively have yielded important long pollen and ostracode records that date from about 130 000 years ago to the present. Although fossils from the present-day interglaciation are not well preserved, these records constitute the only described, conformable, fossiliferous successions of this age from the interior of glaciated North America. The high ??13C values from Raymond Basin are attributed to the residual effects of methane loss either by ebullition or by emission through the stems of senescent emergent aquatic vegetation. A mass balance model suggests that an increase in ??13C of dissolved inorganic carbon on the order of +15??? is possible within a few hours given modest rates of methanogenesis of about 0.02 mol m-2 d-1. The ??13C records from other studies of ostracode valves have values approaching, but not exceeding about +14??? suggesting a limiting value to ???13C enrichment due to simultaneous inputs and outputs of dissolved inorganic carbon. Values of ??18O in ostracodal calcite are quite variable (-4 to +9???) in sediment from the late Sangamon subepisode. A model of isotopic enrichment in a desiccating water body implies that a reduction in reservoir volume of 20% could produce this range of isotopic values. High humidity and evaporation probably account for most of the ??18O variability.

Journal of Paleolimnology↗

Stable isotopes and sediments from Pickerel Lake, South Dakota, USA: A 12ky record of environmental changes

Sedimentological parameters and stable O- and C-isotopic composition of marl and ostracode calcite selected from a 17.7-m-long core from the 8-m-deep center of Pickerel Lake, northeastern South Dakota, provide one of the longest (ca. 12ky) paleoenvironmental records from the northern Great Plains. The late Glacial to early Holocene climate in the northern Great Plains was characterized by changes from cold and wet to cold and dry, and back to cold and wet conditions. These climatic changes were controlled by fluctuations in the positions of the Laurentide ice sheet and the extent of glacial Lake Agassiz. We speculate that the cold and dry phase may correspond to the Younger Dryas event. A salinity maximum was reached between 10.3 and 9.5 ka, after which Pickerel Lake shifted from a system controlled by atmospheric changes to a system controlled by groundwater seepage that might have been initiated by the final withdrawal of Glacial Lake Agassiz. A prairie lake was established at approximately 8.7 ka, and lasted until about 2.2 ka. During this mid-Holocene prairie period, drier conditions than today prevailed, interrupted by periods of increased moisture at about 8, 4, and 2.2 ka. Prairie conditions were more likely dry and cool rather than dry and warm. The last 2.2 ka are characterized by higher climatic variability with 400-yr aridity cycles including the Medieval Warm Period and the Little Ice Age. Although the signal of changing atmospheric circulation is overprinted by fluctuations in the positions of the ice sheet and glacial Lake Agassiz during the late Glacial-Holocene transition, a combination of strong zonal circulation and strong monsoons induced by the presence of the ice sheet and high insolation may have provided mechanisms for increased precipitation. Zonal flow introducing dry Pacific air became more important during the prairie period but seems to have been interrupted by short periods of stronger meridional circulation with intrusions of moist air from the Gulf of Mexico. More frequent switching between periods of zonal and meridional circulation seem to be responsible for increased climatic variability during the last 2.2 ka.

Journal of Paleolimnology↗

Stable carbon and oxygen isotope record of central Lake Erie sediments

Stable carbon and oxygen isotope data from mollusc aragonite extracted from sediment cores provide new information on the origin and history of sedimentation in the southwestern area of the central basin of Lake Erie. Sediments infilling the Sandusky subbasin consist of three lithologic units overlying glacial deposits. The lowest of these is a soft gray mud overlain by a shell hash layer containing Sphaerium striatinum fragments. A fluid mud unit caps the shell hash layer and extends upwards to the sediment-water interface. New stable isotope data suggest that the soft gray mud unit is of postglacial, rather than proglacial, origin. These data also suggest that the shell hash layer was derived from erosional winnowing of the underlying soft gray mud layer. This winnowing event may have occurred as a result of the Nipissing flood. The Pelee-Lorain moraine, which forms the eastern boundary of the Sandusky subbasin, is an elevated area of till capped by a sand deposit that originated as a beach. The presence of both the shell hash layer and relict beach deposit strengthens the interpretation that the Nipissing flood was a critical event in the development of the southwestern area of the central basin of Lake Erie. This event, which returned drainage from the upper lakes to the Lake Erie basin, was a dominant influence on regional stratigraphy, bathymetry, and depositional setting.

Journal of Paleolimnology↗

Greigite (Fe3S4) as an indicator of drought - The 1912-1994 sediment magnetic record from White Rock Lake, Dallas, Texas, USA

Combined magnetic and geochemical studies were conducted on sediments from White Rock Lake, a reservoir in suburban Dallas (USA), to investigate how land use has affected sediment and water quality since the reservoir was filled in 1912. The chronology of a 167-cm-long core is constrained by the recognition of the pre-reservoir surface and by 137Cs results. In the reservoir sediments, magnetic susceptibility (MS) and isothermal remanent magnetization (IRM) are largely carried by detrital titanomagnetite that originally formed in igneous rocks. Titanomagnetite and associated hematite are the dominant iron oxides in a sample from the surficial deposit in the watershed but are absent in the underlying Austin Chalk. Therefore, these minerals were transported by wind into the watershed. After about 1960, systematic decreases in Ti, Fe, and Al suggest diminished input of detrital Fe-Ti oxides from the surficial deposits. MS and IRM remain constant over this interval, however, implying compensation by an increase in strongly magnetic material derived from human activity. Anthropogenic magnetite in rust and ferrite spherules (from fly ash?) are more common in sediment deposited after about 1970 than before and may account for the constant magnetization despite the implied decrease in detrital Fe-Ti oxides. An unexpected finding is the presence of authigenic greigite (Fe3S4), the abundance of which is at least partly controlled by climate. Greigite is common in sediments that predate about 1975, with zones of concentration indicated by relatively high IRM/MS. High greigite contents in sediment deposited during the early to mid-1950s and during the mid-1930s correspond to several-year periods of below-average precipitation and drought from historical records. Relatively long water-residence times in the reservoir during these periods may have led to elevated levels of sulfate available for bacterial sulfate reduction. The sulfate was probably derived via the oxidation of pyrite that is common in the underlying Austin Chalk. These results provide a basis for the paleoenvironmental interpretation of greigite occurrence in older lake sediments. The results also indicate that greigite formed rapidly and imply that it can be preserved in the amounts produced over a short time span (in this lake, only a few years). This finding thus suggests that, in some lacustrine settings, greigite is capable of recording paleomagnetic secular variation.

Journal of Paleolimnology↗

Biogenic silica from the BDP93 drill site and adjacent areas of the Selenga Delta, Lake Baikal, Siberia

Biogenic silica contents of sediments on the lower Selenga Delta and Buguldeika saddle in Lake Baikal show distinct fluctuations that reflect changes in diatom productivity, and ultimately, climate. The pattern of the upper 50 m of the section, dating from about 334 ka, is similar to that of the marine oxygen-isotope record, increasingly so as the younger sediments become progressively finer grained and less locally derived with time. The last two interglaciations are marked by biogenic silica abundances similar to those of the Holocene. The equivalent of marine oxygen-isotope stage 3 is distinctly intermediate in character between full glacial and full interglacial biogenic silica values. Following near-zero values during the last glacial maximum, biogenic silica began to increase at about 13 ka. The rise in biogenic silica to Holocene values was interrupted by an abrupt decrease during Younger Dryas time, about 11 to 10 14C ka.

Lake Baikal, Selenga Delta, Siberia↗

The carbon cycle and biogeochemical dynamics in lake sediments

The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.

Journal of Paleolimnology↗

Geochemical effects of rapid sedimentation in aquatic systems: Minimal diagenesis and the preservation of historical metal signatures

Rapid sedimentation exerts a pronounced influence on early sedimentary diagenesis in that there is insufficient time for a sediment particle to equilibrate in any one sediment layer before that layer may be displaced vertically by another layer. These sedimentation patterns are common in surface-water reservoirs whose sedimentation rates (1-10 cm yr-1) are several orders of magnitude greater than those for natural lakes (0.01-0.5 cm yr-1). Two examples of the effects of rapid sedimentation on geochemical metal signatures are presented here. Interstitial-water data (Fe) from two sites in the Cheyenne River Embayment of Lake Oahe on the Missouri River illustrate the effects of changing sedimentation rates on dissolved species. Rapid burial during high-flow yrs appears to limit early sedimentary diagenesis to aerobic respiration. Solid-phase metal data (Pb) from a site in Pueblo Reservoir on the upper Arkansas River in Colorado appear to record historical releases by flooding of abandoned mine sites upstream in Leadville, Colorado. Interstitial-water ammonia and ferrous Fe data indicate that at least one interval at depth in the sediment where solid metal concentrations peak is a zone of minimal diagenesis. The principal diagenetic reactions that occur in these sediments are aerobic respiration and the reduction of Mn and Fe oxides. Under slower sedimentation conditions, there is sufficient time for particulate organic matter to decompose and create a diagenetic environment where metal oxides may not be stable. The quasi-steady-state interstitial Fe profiles from Tidal Potomac River sediments are an example of such a situation. This occurs primarily because the residence time of particles in the surficial sediment column is long enough to allow benthic organisms and bacteria to perform their metabolic functions. When faster sedimentation prevails, there is less time for these metabolic reactions to occur since the organisms do not occupy a sediment layer for any length of time. Also, the quantity and quality of the organic matter input to the sediment layer is important in that reservoirs often receive more terrestrial organic matter than natural lakes and this terrestrial organic matter is generally more refractory than autochthonous aquatic organic matter.

Journal of Paleolimnology↗

A 1500-year record of climatic and environmental change in Elk Lake, Clearwater County, Minnesota II: Geochemistry, mineralogy, and stable isotopes

Most of the sediment components that have accumulated in Elk Lake, Clearwater County, northwestern Minnesota, over the past 1500 years are authigenic or biogenic (CaCO3, biogenic SiO2, organic matter, iron and manganese oxyhydroxides, and iron phosphate) and are delivered to the sediment-water interface on a seasonal schedule where they are preserved as distinct annual laminae (varves). The annual biogeochemical cycles of these components are causally linked through the 'carbon pump', and are recapitulated in longer-term cycles, most prominently with a periodicity of about 400 years. Organic carbon is fixed in the epilimnion by photosynthetic removal of CO2, which also increases the pH, triggering the precipitation of CaCO3. The respiration and degradation of fixed organic carbon in the hypolimnion consumes dissolved oxygen, produces CO2, and lowers the pH so that the hypolimnion becomes anoxic and undersaturated with respect to CaCO3 during the summer. Some of the CaCO3 produced in the epilimnion is dissolved in the anoxic, lower pH hypolimnion and sediments. The amount of CaCO3 that is ultimately incorporated into the sediments is a function of how much is produced in the epilimnion and how much is consumed in the hypolimnion and the sediments. Iron, manganese, and phosphate accumulate in the anoxic hypolimnion throughout the summer. Sediment-trap studies show that at fall overturn, when iron-, manganese-, and phosphate-rich bottom waters mix with carbonate- and oxygen-rich surface waters, precipitation of iron and manganese oxyhydroxides, iron phosphate, and manganese carbonate begins and continues into the winter months. Detrital clastic material in the sediments of Elk Lake deposited over the last 1500 years is a minor component (<10% by weight) that is mostly wind-borne (eolian). Detailed analyses of the last 1500 years of the Elk Lake sediment record show distinct cycles in eolian clastic variables (e.g. aluminum, sodium, potassium, titanium, and quartz), with a periodicity of about 400 years. The 400-yr cycle in eolian clastic material does not correspond to the 400-yr cycles in redox-sensitive authigenic components, suggesting that the clastic component is responding to external forcing (wind) whereas the authigenic components are responding to internal forcing (productivity), although both may ultimately be forced by climate change. Variations in the oxygen and carbon isotopic composition of CaCO3 are small but appear to reflect small variations in ground water influx that are also driven by external forcing.

Journal of Paleolimnology↗

A 1500-year record of climatic and environmental change in Elk Lake, Minnesota I: Varve thickness and gray-scale density

The deepest part (29.5 m) of Elk Lake, Clearwater County, northwestern Minnesota, contains a complete Holocene section that is continuously varved. The varve components are predominantly autochthonous (CaCO3, organic matter, biogenic silica, and several iron and manganese minerals), but the varves do contain a minor detrital-clastic (aluminosilicate) component that is predominantly wind-borne (eolian) and provides an important record of atmospheric conditions. Singular spectrum analysis (SSA) and wavelet analysis of varve thickness recognized significant periodicities in the multicentennial and multidecadal bands that varied in power (i.e., variable significance) and position (i.e., variable period) within the periodic bands. Persistent periodicities of about 10, 22, 40, and 90 years, and, in particular, multicentennial periodicities in varve thickness and other proxy variables are similar to those in spectra of radiocarbon production, a proxy for past solar activity. This suggests that there may be a solar control, perhaps through geomagnetic effects on atmospheric circulation. Multicentennial and multidecadal periodicities also occur in wavelet spectra of relative gray-scale density. However, gray-scale density does not appear to correlate with any of the measured proxy variables, and at this point we do not know what controlled gray scale.

Journal of Paleolimnology↗

Ostracode-based reconstruction from 23,300 to about 20,250 cal yr BP of climate, and paleohydrology of a groundwater-fed pond near St. Louis, Missouri

The water chemistry of a groundwater-fed sinkhole-pond near St. Louis, Missouri, and its associated climate during the last glaciation are reconstructed by comparison with autecological data of modern ostracodes from about 5,500 sites in Canada. A 4.8-m succession of fossiliferous sediment yielded ostracode assemblages that collectively are generally found today in ponds in North America including the species Cyclocypris ampla, C. laevis, Cypridopsis vidua, Candona crogmaniana, C. distincta, and C. ohioensis. Fossils of Picea needles and the ostracode Cyclocypris sharpei imply that best analog sites for the succession are in central to south-central Canada. The pond formed 23,300 ?? 400 cal yr BP when a sinkhole became plugged by a clay bed about 1 m thick. By about 20,250 cal yr BP, the pond had desiccated and was buried by loess. The sediment accumulation rate was about 0.18 cm/yr, and each sample interval (6 cm) represents a time slice of ???33 years. Data from this record provides the first fairly high resolution proxy record of the glacial paleoclimate of the mid-latitude of North America. The analog data indicate the water in the hydrologically-open spring-fed pond was less than 1 m deep. The paleoclimatic reconstructions imply gradually drier conditions and uniform, cool temperatures. The shallow water depth indicates that the temperature reconstruction is robust with mean annual temperatures (MATs) that ranged between 0.8 and 3.9??C, and mean July temperatures that ranged from 16.8 and 18.1??C. Other estimated climatic parameters include mean annual precipitation (MAP; 430 to 840 mm/yr), and moisture balance (P-E; -111 to 298 mm/yr). Compared to values measured today at St. Louis, the MAP was about 400 mm less, MAT about 10??C cooler, and P-E, about the same. These values are consistent with other published reconstructions based on modern analog analysis of fossil beetles and pollen, and paleothermometry based on amino acid racemization. The total dissolved solids (TDS) progressively increased from about 87 to 431 mg/L. Changes in TDS reflect either the balance between the relative inputs of karst groundwater and overland flow, or changes in the duration of water-rock interaction associated with the groundwater. The postulated long-term 900 ?? 200 year cyclicity of growing-season moisture and temperature, attributed to El Nin??o-Southern Oscillation cycles, is not expressed in the reconstructed hydrologic or climatic data. This is attributed, in part, to the mediating effect on temperature by monothermic groundwater input to this flow-through system.

Journal of Paleolimnology↗

Basis for paleoenvironmental interpretation of magnetic properties of sediment from Upper Klamath Lake (Oregon): Effects of weathering and mineralogical sorting

Studies of magnetic properties enable reconstruction of environmental conditions that affected magnetic minerals incorporated in sediments from Upper Klamath Lake. Analyses of stream sediment samples from throughout the catchment of Upper Klamath Lake show that alteration of Fe-oxide minerals during subaerial chemical weathering of basic volcanic rocks has significantly changed magnetic properties of surficial deposits. Titanomagnetite, which is abundant both as phenocrysts and as microcrystals in fresh volcanic rocks, is progressively destroyed during weathering. Because fine-grained magnetite is readily altered due to large surface-to-volume ratios, weathering causes an increase in average magnetic grain size as well as reduction in the quantity of titanomagnetite both absolutely and relative to hematite. Hydrodynamic mineralogical sorting also produces differences in magnetic properties among rock and mineral grains of differing sizes. Importantly, removal of coarse silicate and Fe-oxide grains by sorting concentrated extremely fine-grained magnetite in the resulting sediment. The effects of weathering and sorting of minerals cannot be completely separated. These processes combine to produce the magnetic properties of a non-glacial lithic component of Upper Klamath Lake sediments, which is characterized by relatively low magnetite content and coarse magnetic grain size. Hydrodynamic sorting alone causes significant differences between the magnetic properties of glacial flour in lake sediments and of fresh volcanic rocks in the catchment. In comparison to source volcanic rocks, glacial flour in the lake sediment is highly enriched in extremely fine-grained magnetite.

Journal of Paleolimnology↗

Record of late Pleistocene glaciation and deglaciation in the southern Cascade Range: II. Flux of glacial flour in a sediment core from Upper Klamath Lake, Oregon

During the late Wisconsin, glacial flour from alpine glaciers along the east side of the Cascade Range in southern Oregon was deposited in Upper Klamath Lake. Quantitative interpretation of magnetic properties and grain-size data of cored sediments from Caledonia Marsh on the west side of the lake provides a continuous record of the flux of glacial flour spanning the last ≈37 000 calendar years. For modeling purposes, the lake sediments from the 13-m core were divided into three sedimentary components defined from magnetic, geochemical, petrographic, and grain-size data. The components are (1) strongly magnetic, glacial flour made up of extremely fine-grained, fresh volcanic rock particles, (2) less magnetic lithic material made up of coarser, weathered volcanic detritus, and (3) non-magnetic biogenic material (largely biogenic silica). Quantitative interpretation is possible because there has been no significant postdepositional destruction or formation of magnetic minerals, nor alteration affecting grain-size distributions. Major steps involved in the interpretation include: (1) computation of biogenic and lithic components; (2) determination of magnetic properties and grain-size distributions of the non-glacial and glacial flour end-members; (3) computation of the contents of weathered and glacial flour components for each sample; (4) development of an age model based on the mass accumulation of the non-glacial lithic component; and (5) use of the age model and glacial flour contents to compute the flux of glacial flour. Comparison of the glacial flour record from Upper Klamath Lake to mapped glacial features suggests a nearly linear relation between flux of glacial flour and the extent of nearby glaciers. At ≈22 ka, following an extended period during which glaciers of limited size waxed and waned, late Wisconsin (Waban) glaciers began to grow, reaching their maximum extent at ≈19 ka. Glaciers remained near their maximum extent for ≈1000 years. During this period, lake sediments were made up of ≈80% glacial flour. The content of glacial flour decreased as the glaciers receded, and reached undetectable levels by 14 ka.

Oregon↗

Record of late Pleistocene glaciation and deglaciation in the southern Cascade Range. I. Petrological evidence from lacustrine sediment in Upper Klamath Lake, southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37-25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.

Oregon↗

Chronology of sediment deposition in Upper Klamath Lake, Oregon

A combination of tephrochronology and 14C, 210Pb, and 137Cs measurements provides a robust chronology for sedimentation in Upper Klamath Lake during the last 45 000 years. Mixing of surficial sediments and possible mobility of the radio-isotopes limit the usefulness of the 137Cs and 210Pb data, but 210Pb profiles provide reasonable average sediment accumulation rates for the last 100-150 years. Radiocarbon ages near the top of the core are somewhat erratic and are too old, probably as a result of detrital organic carbon, which may have become a more common component in recent times as surrounding marshes were drained. Below the tops of the cores, radiocarbon ages in the center of the basin appear to be about 400 years too old, while those on the margin appear to be accurate, based on comparisons with tephra layers of known age. Taken together, the data can be combined into reasonable age models for each site. Sediments have accumulated at site K1, near the center of the basin, about 2 times faster than at site CM2, on the margin of the lake. The rates are about 0.10 and 0.05 cm/yr, respectively. The chronological data also indicate that accumulation rates were slower during the early to middle Holocene than during the late Holocene, consistent with increasing wetness in the late Holocene.

Oregon↗