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A volcanic activity alert-level system for aviation: Review of its development and application in Alaska

An alert-level system for communicating volcano hazard information to the aviation industry was devised by the Alaska Volcano Observatory (AVO) during the 1989–1990 eruption of Redoubt Volcano. The system uses a simple, color-coded ranking that focuses on volcanic ash emissions: Green—normal background; Yellow—signs of unrest; Orange—precursory unrest or minor ash eruption; Red—major ash eruption imminent or underway. The color code has been successfully applied on a regional scale in Alaska for a sustained period. During 2002–2011, elevated color codes were assigned by AVO to 13 volcanoes, eight of which erupted; for that decade, one or more Alaskan volcanoes were at Yellow on 67 % of days and at Orange or Red on 12 % of days. As evidence of its utility, the color code system is integrated into procedures of agencies responsible for air-traffic management and aviation meteorology in Alaska. Furthermore, it is endorsed as a key part of globally coordinated protocols established by the International Civil Aviation Organization to provide warnings of ash hazards to aviation worldwide. The color code and accompanying structured message (called a Volcano Observatory Notice for Aviation) comprise an effective early-warning message system according to the United Nations International Strategy for Disaster Reduction. The aviation color code system currently is used in the United States, Russia, New Zealand, Iceland, and partially in the Philippines, Papua New Guinea, and Indonesia. Although there are some barriers to implementation, with continued education and outreach to Volcano Observatories worldwide, greater use of the aviation color code system is achievable.

Alaska

Invasive hitchhiking organisms on aquarium plants: An emerging pathway of introduction

The aquarium trade is a global industry responsible for the movement of live plants and animals, but it also serves as a major pathway for the introduction and spread of aquatic invasive species. Invasive species contribute to biodiversity loss, disrupt ecosystems, and can have widespread economic and societal impacts. A significant but poorly understood invasion risk in the plant aquarium trade is the transport of hitchhiking species, which are organisms unintentionally transported along with a species of primary interest in trade. Aquatic hitchhikers can persist in aquaria and later be released into the wild, potentially establishing invasive populations. While some studies have identified hitchhiking as a pathway for aquatic species spread, it remains largely unrecognized in international regulations. Increased awareness, triggered by incidents such as zebra mussels found in aquarium plants, highlights the need for further investigation into this emerging pathway of concern. As a response, we reviewed the current state of knowledge regarding aquatic plants in the aquarium trade as vectors for transporting invasive hitchhiking species, with a particular focus on how morphological complexity of plants influences associated hitchhikers. We found that although awareness of hitchhiking species in the aquarium trade is increasing, few studies have empirically examined aquarium plants as vectors for invasive species. Understanding this pathway can help to inform invasive species management around the plant aquarium trade and to keep aquarium organisms in a sustainable manner.

Management of Biological Invasions

Recommended approaches to the scientific evaluation of ecotoxicological hazards and risks of endocrine-active substances

A SETAC Pellston Workshop ® “Environmental Hazard and Risk Assessment Approaches for Endocrine-Active Substances (EHRA)” was held in February 2016 in Pensacola, Florida, USA. The primary objective of the workshop was to provide advice, based on current scientific understanding, to regulators and policy makers; the aim being to make considered, informed decisions on whether to select an ecotoxicological hazard- or a risk-based approach for regulating a given endocrine-disrupting substance (EDS) under review. The workshop additionally considered recent developments in the identification of EDS. Case studies were undertaken on 6 endocrine-active substances (EAS—not necessarily proven EDS, but substances known to interact directly with the endocrine system) that are representative of a range of perturbations of the endocrine system and considered to be data rich in relevant information at multiple biological levels of organization for 1 or more ecologically relevant taxa. The substances selected were 17α-ethinylestradiol, perchlorate, propiconazole, 17β-trenbolone, tributyltin, and vinclozolin. The 6 case studies were not comprehensive safety evaluations but provided foundations for clarifying key issues and procedures that should be considered when assessing the ecotoxicological hazards and risks of EAS and EDS. The workshop also highlighted areas of scientific uncertainty, and made specific recommendations for research and methods-development to resolve some of the identified issues. The present paper provides broad guidance for scientists in regulatory authorities, industry, and academia on issues likely to arise during the ecotoxicological hazard and risk assessment of EAS and EDS. The primary conclusion of this paper, and of the SETAC Pellston Workshop on which it is based, is that if data on environmental exposure, effects on sensitive species and life-stages, delayed effects, and effects at low concentrations are robust, initiating environmental risk assessment of EDS is scientifically sound and sufficiently reliable and protective of the environment. In the absence of such data, assessment on the basis of hazard is scientifically justified until such time as relevant new information is available.

Integrated Environmental Assessment and Management

Improvements in the use of aquatic herbicides and establishment of future research directions

Peer-reviewed literature over the past 20 years identifies significant changes and improvements in chemical control strategies used to manage nuisance submersed vegetation. The invasive exotic plants hydrilla (Hydrilla verticillata L.f. Royle) and Eurasian watermilfoil (Myriophyllum spicatum L.) continue to spread and remain the plant species of greatest concern for aquatic resource managers at the national scale. Emerging exotic weeds of regional concern such as egeria (Egeria densa Planch.), curlyleaf pondweed (Potamogeton crispus L.), and hygrophila (Hygrophila polysperma (Roxb.) T. Anders), as well as native plants such as variable watermilfoil (Myriophyllum heterophyllum Michx), and cabomba (Cabomba caroliniana Gray) are invasive outside their home ranges. In addition, there is always the threat of new plant introductions such as African elodea (Lagarosiphon major (Ridley) Moss) or narrow-leaf anacharis (Egeria najas Planchon). The registration of the bleaching herbicide fluridone in the mid 1980s for whole-lake and large-scale management stimulated numerous lines of research involving reduction of use rates, plant selectivity, residue monitoring, and impacts on fisheries. In addition to numerous advances, the specificity of fluridone for a single plant enzyme led to the first documented case of herbicide resistance in aquatic plant management. The resistance of hydrilla to fluridone has stimulated a renewed interest by industry and others in the registration of alternative modes of action for aquatic use. These newer chemistries tend to be enzyme-specific compounds with favorable non-target toxicity profiles. Registration efforts have been facilitated by increased cooperation between key federal government agencies that have aquatic weed control and research responsibilities, and regulators within the U.S. Environmental Protection Agency (USEPA). We reviewed past and current research efforts to identify areas in need of further investigation and to establish priorities for future research directions in chemical management of submersed plants. The priorities we identified include: (A) improving methods for evaluating non-target impacts of herbicides with an emphasis on threatened and endangered species, or species of special concern; (B) improving herbicide performance in flowing-water environments, including irrigation canals; (C) screening and developing new herbicides to supplement fluridone for large-scale or whole-lake management approaches; (D) screening and developing new organic algaecides to supplement the use of copper-based compounds; (E) developing risk assessment tools to educate the public on the risks of invasive species and chemical management options; (F) increasing cooperative research with ecologists and fisheries scientists to evaluate the long-term impacts of invasive species introductions and herbicide programs on native plant assemblages, water quality, and fish populations; and (G) improving the integration of chemical control technology with other aquatic plant management disciplines. While circumstances may dictate setting new priorities or dropping current ones, the list we have generated represents our vision of the needs that will require the greatest focus over the next several years.

Conference Paper

Proceedings for a workshop on deposit modeling, mineral resource assessment, and their role in sustainable development

The world's use of nonfuel mineral resources continues to increase to support a growing population and increasing standards of living. The ability to meet this increasing demand is affected especially by concerns about possible environmental degradation associated with minerals production and by competing land uses. What information does the world need to support global minerals development in a sustainable way? Informed planning and decisions concerning sustainability and future mineral resource supply require a long–term perspective and an integrated approach to resource, land use, economic, and environmental management worldwide. Such perspective and approach require unbiased information on the global distribution of identified and especially undiscovered resources, the economic and political factors influencing their development, and the potential environmental consequences of their exploitation. The U.S. Geological Survey and the former Deposit Modeling Program of the International Union of Geological Sciences (IUGS) of the United Nations Educational, Scientific and Cultural Organization (UNESCO) sponsored a workshop on "Deposit Modeling, Mineral Resource Assessment, and Their Role in Sustainable Development" at the 31st International Geological Congress (IGC) in Rio de Janeiro, Brazil, on August 18–19, 2000. The purpose of the workshop was to review the state-of-the-art in mineral deposit modeling and resource assessment and to examine the role of global assessments of nonfuel mineral resources in sustainable development. The workshop addressed questions such as the following: Which of the available mineral deposit models and assessment methods are best suited for predicting the locations, deposit types, and amounts of undiscovered nonfuel mineral resources remaining in the world? What is the availability of global geologic, mineral deposit, and mineral exploration information? How can mineral resource assessments be used to address economic and environmental issues? Presentations included overviews of assessment methods applied in previous national and other small-scale assessments of large regions and of the resulting assessment products and their uses. Twenty-seven people from Canada, China, Finland, Germany, Japan, Peru, Slovenia, South Africa, United States, and Venezuela participated in the 2-day post-Congress workshop. The attendees represented academia, government, environmental organizations, and the mining industry.

Circular

Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review

This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O 2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors.

Chemical Geology

Use of experimental ecosystems in regulatory decision making

Tiered testing for the effects of chemicals on aquatic ecosystems has begun to include tests at the ecosystem level as a component in pesticide regristration. Because such tests are expensive, regulators and industry need to know what additional information they can gain from such tests relative to the costs of the simpler single-species toxicity bioassays. Requirements for ecosystem-level testing have developed because resource managers have not fully understood the implications of potential damage to resources without having evaluations of the predicted impacts under field conditions. We review approaches taken in the use of experimental ecosystems, discuss benefits and limitations of small- and large-scale ecosystem tests, and point to correlative approaches between laboratory and field toxicity testing. Laboratory experimental ecosystems (microcosms) have been successfully used to measure contaminant bioavailability, to determine routes of uptake in moderately complex aquatic systems, and to isolate factors modifying contaminant uptake into the biota. Such factors cannot be as readily studied in outdoor experimental ecosystems because direct cause-and-effect relations are often confounded and difficult to isolate. However, laboratory tests can be designed to quantify the relations among three variables: known concentrations of Stressors; specific sublethal behavioral, biochemical, and physiological effects displayed by organisms; and responses that have been observed in ecosystem-level analyses. For regulatory purposes, the specificity of test results determines how widely they can be applied. Ecotoxicological research should be directed at attempts to identify instances where single-species testing would be the appropriate level of analysis for identifying critical ecological endpoints and for clarifying relationships between ecosystem structure and function, and where it would be inadequate for a given level of analysis.

Environmental Management

Implementation plan of the National Cooperative Geologic Mapping Program strategy—Great Lakes (Central Lowland and Superior Upland Physiographic Provinces)

Introduction The U.S. Geological Survey (USGS) National Cooperative Geologic Mapping Program (NCGMP) has published a strategic plan entitled “Renewing the National Cooperative Geologic Mapping Program as the Nation’s Authoritative Source for Modern Geologic Knowledge”. This plan provides the following vision, mission, and goals for the program for the years 2020–30: Vision: create an integrated, three-dimensional (3D), digital geologic map of the United States. Mission: characterize, interpret, and disseminate a national geologic framework model of the Earth through geologic mapping. Goal: focus on geological mapping as a core function of the USGS within the long-term vision and mission of creating a digital geologic map and geologic framework model of the Nation. To achieve the goal outlined in the strategic plan, the NCGMP has developed an Implementation Plan. This Implementation Plan will guide annual reviews of the FEDMAP component (that is, the component of the USGS NCGMP that funds geologic mapping by USGS geologists) of the NCGMP projects described in the plan and the development of the annual FEDMAP prospectus, which will ensure the application of the NCGMP strategy. This publication is part of the Implementation Plan of the NCGMP strategy and addresses the following three major topics: continued development of a consistent National geologic map and database; the major unanswered geologic questions in the region; and the societal concerns associated with these geologic questions, such as hazards, geologic and hydrologic resources, and environmental issues. The regions used in this chapter correspond with physiographic divisions of the United States as defined by Fenneman. Physiographic divisions are delineated on the basis of topography, and to a lesser extent, the geologic structure and history. The physiographic divisions are subdivided into physiographic provinces, and the physiographic provinces are subdivided into physiographic sections. Fenneman’s physiographic divisions of the United States provide a robust and useful spatial organization for delineating large geographic regions of the United States for various scientific and industrial applications.

Great Lakes (Central Lowland and Superior Upland P

Arsenic in Chinese coals: Distribution, modes of occurrence, and environmental effects

Arsenic, one of the most hazardous elements occurring in coals, can be released to the environment during coal processing and combustion. Based on the available literature and published results obtained in our laboratory, the content, distribution and the modes of occurrence of As in Chinese coals, and its environmental and impacts are reviewed in this article. With the 4763 sets of data (from the literature) rearranged, the arithmetic mean As concentration of each province and weighted mean As concentration of the entire country (using the expected coal reserves as the weighting factor) were calculated. The weighted mean As concentration in Chinese coals is 3.18 mg/kg, with As concentration increasing from northern China to southern China. The As concentration in coal varies with coal-forming ages and coal ranks. Arsenic has several modes of occurrence in coals. According to results obtained by other studies and our own experiments, As is mainly associated with mineral matter (such as pyrite and other sulfide minerals) in coals, although a significant amount of arsenic is associated with organic matter. The accumulation of As in coal is controlled by many geological factors during coal-forming processes, including plant decomposition, sedimentary environments, and epigenetic hydrothermal activity. During the combustion of coal, As is released to the air, water, and soil, causing serious environmental pollution. More than 45% of the coal consumed in China is utilized by power plants, and it is estimated that nearly 522 tonnes, 21 tonnes and 252 tonnes of As are emitted into the atmosphere by industries, residential buildings and coal-fired power plants, respectively, every year.

Article

The confluences of ideas leading to, and the flow of ideas emerging from, individual-based modeling of riverine fishes

In this review article, we trace the history of events leading to the development of individual-based models (IBMs) to represent aquatic organisms in rivers and streams. As a metaphor, we present this history as a series of confluences between individual scientists (tributaries) sharing ideas. We describe contributions of these models to science and management. One iconic feature of river IBMs is the linkage between flow and the physical habitat experienced by individual animals, and the first model that focused on this linkage is briefly described. We continue by reviewing the contributions of riverine IBMs to eight broad areas of scientific inquiry. The first four areas include research to understand 1) the effects of flow regimes on fish populations, 2) species interactions (e.g., size-mediated competition and predation), 3) fish movement and habitat selection, and 4) contaminant and water quality impacts on populations. Next, we review research using IBMs 5) to guide conservation biology of imperiled taxa through population viability analysis, including research 6) to understand river fragmentation by dams and reconnection, 7) to understand genetic outcomes for riverine metapopulations, and 8) to anticipate the future effects of temperature and climate change. This rich body of literature has contributed to both theoretical insights (e.g., about animal behavior and life history) and applied insights (e.g., population-level effects of flow regimes, temperature, and the effects of hydropower and other industries that share rivers with aquatic biota). We finish by exploring promising branches that lie ahead in the braided, downstream channel that represents future river modeling research.

Ecological Modelling

Environmental geochemistry and sediment quality in Lake Pontchartrain: database development and review

This paper reports on preliminary results of a project to develop a comprehensive data base of chemical and environmental information on sediments from Lake Pontchartrain, Louisiana, and surrounding water bodies. The goal is to evaluate all data for reliability and comparability, and to make it widely accessible and useful to all users. Methods for processing heterogeneous, historical data follow previous methods employed in the Boston Harbor and Massachusetts Bay area. Data from 11 different data sets, encompassing about 900 total samples, have been entered to date. Questionable or anomalous data were noted in a minority of cases. Problems tend to follow distinct patterns and are relatively easy to identify. Hence, comparability of data has not proven to be the major obstacle to synthesis efforts that was anticipated in earlier years (NRC, 1989). Quality-controlled data sets show that the bulk of sediment samples in the more central parts of Lake Pontchartrain have values within normal background for heavy metals like Cu, Pb, and Zn. The same or lower concentrations were found in the vicinity of the Bonnet Carre Spillway, representing influx from the Mississippi River. Mean concentrations for Cu, Pb, and Zn were 17, 21, and 74 µg/g (total dissolution analyses), respectively. However, values as high as 267 µg/g Pb and comparable increases for other metal and organic contaminants are found in sediments within 2 km of the coastal strip of New Orleans. Additional sampling in such areas and in other inland coastal waterways is needed, since such levels are above the threshold for potential toxic effects on benthic organisms, according to effects-based screening criteria. The most contaminated sites, Bayou Trepagnier and Bayou Bonfouca, involve industrial areas where waste discharge has now been controlled or remediated, but where sediments may retain large concentrations of contaminants, e.g. tenths of a percent of Pb, Cr, and Zn or more for Bayou Trepagnier.

Louisiana

Arsenic, Boron, and Fluoride Concentrations in Ground Water in and Near Diabase Intrusions, Newark Basin, Southeastern Pennsylvania

During an investigation in 2000 by the U.S. Environmental Protection Agency (USEPA) of possible contaminant releases from an industrial facility on Congo Road near Gilbertsville in Berks and Montgomery Counties, southeastern Pennsylvania, concentrations of arsenic and fluoride above USEPA drinking-water standards of 10 ?g/L and 4 mg/L, respectively, and of boron above the USEPA health advisory level of 600 ?g/L were measured in ground water in an area along the northwestern edge of the Newark Basin. In 2003, the USEPA requested technical assistance from the U.S. Geological Survey (USGS) to help identify sources of arsenic, boron, and fluoride in the ground water in the Congo Road area, which included possible anthropogenic releases and naturally occurring mineralization in the local bedrock aquifer, and to identify other areas in the Newark Basin of southeastern Pennsylvania with similarly elevated concentrations of these constituents. The USGS reviewed available data and collected additional ground-water samples in the Congo Road area and four similar hydrogeologic settings. The Newark Basin is the largest of the 13 major exposed Mesozoic rift basins that stretch from Nova Scotia to South Carolina. Rocks in the Newark Basin include Triassic through Jurassic-age sedimentary sequences of sandstones and shales that were intruded by diabase. Mineral deposits of hydrothermal origin are associated with alteration zones bordering intrusions of diabase and also occur as strata-bound replacement deposits of copper and zinc in sedimentary rocks. The USGS review of data available in 2003 showed that water from about 10 percent of wells throughout the Newark Basin of southeastern Pennsylvania had concentrations of arsenic greater than the USEPA maximum contaminant level (MCL) of 10 ?g/L; the highest reported arsenic concentration was at about 70 ?g/L. Few data on boron were available, and the highest reported boron concentration in well-water samples was 60 ?g/L in contrast to concentrations over 5,000 ?g/L in the Congo Road area. Although concentrations of fluoride up to 4 mg/L were reported for a few well-water samples collected throughout the Newark Basin, about 90 percent of the samples had concentrations of 0.5 mg/L or less. The USGS sampled 58 wells primarily in 5 areas in the Newark Basin, southeastern Pennsylvania, from February 2004 through April 2005 to identify other possible areas of elevated arsenic, boron, and fluoride and to characterize the geochemical environment associated with elevated concentrations of these constituents. Sampled wells included 12 monitor wells at an industrial facility near Congo Road, 45 private-supply wells in Berks, Montgomery, and Bucks Counties, and 1 private-supply well near Dillsburg, York County, an area where elevated fluoride in ground water had been reported in the adjacent Gettysburg Basin. Wells were sampled in transects from the diabase through the adjacent hornfels and into the unaltered shales of the Brunswick Group. Field measurements were made of pH, temperature, dissolved oxygen concentration, and specific conductance. Samples were analyzed in the laboratory for major ions, nutrients, total organic carbon, dissolved and total concentrations of selected trace elements, and boron isotopic composition. Generally, the ground water from the 46 private-supply wells had relatively neutral to alkaline pH (ranging from 6.1 to 9.1) and moderate concentrations of dissolved oxygen. Most water samples were of the calcium-bicarbonate type. Concentrations of arsenic up to 60 ?g/L, boron up to 3,950 ?g/L, and fluoride up to 0.70 mg/L were measured. Drinking-water standards or health advisories (for constituents that do not have standards established) were exceeded most frequently (about 20 percent of samples) for arsenic and boron and less frequently (6 percent or less of samples) for total iron, manganese, sulfate, nitrate, lead, molybdenum, and strontium. In water from 12 monitor

Scientific Investigations Report

Mapping of Florida's coastal and marine resources: Setting priorities workshop

The importance of mapping habitats and bioregions as a means to improve resource management has become increasingly clear. Large areas of the waters surrounding Florida are unmapped or incompletely mapped, possibly hindering proper management and good decisionmaking. Mapping of these ecosystems is among the top priorities identified by the Florida Oceans and Coastal Council in their Annual Science Research Plan. However, lack of prioritization among the coastal and marine areas and lack of coordination of agency efforts impede efficient, cost–effective mapping. A workshop on Mapping of Florida’s Coastal and Marine Resources was sponsored by the U.S. Geological Survey (USGS), Florida Department of Environmental Protection (FDEP), and Southeastern Regional Partnership for Planning and Sustainability (SERPPAS). The workshop was held at the USGS Florida Integrated Science Center (FISC) in St. Petersburg, FL, on February 7-8, 2007. The workshop was designed to provide State, Federal, university, and non-governmental organizations (NGOs) the opportunity to discuss their existing data coverage and create a prioritization of areas for new mapping data in Florida. Specific goals of the workshop were multifold, including to: provide information to agencies on state-of-the-art technology for collecting data; inform participants of the ongoing mapping programs in waters off Florida; present the mapping needs and priorities of the State and Federal agencies and entities operating in Florida; work with State of Florida agencies to establish an overall priority for areas needing mapping; initiate discussion of a unified classification of habitat and bioregions; discuss and examine the need to standardize terminology and data collection/storage so that data, in particular habitat data, can be shared; identify opportunities for partnering and leveraging mapping efforts among agencies and entities; identify impediments and organizational gaps that hinder collection of data for mapping; seek innovative solutions to the primary obstacles identified; identify the steps needed to move mapping of Florida’s oceans and coasts forward, in preparation for a better coordinated, more cost-effective mapping program to allow State and Federal agencies to make better decisions on coastal-resource issues. Over 90 invited participants representing more than 30 State and Federal agencies, universities, NGOs, and private industries played a large role in the success of this two-day workshop. State of Florida agency participants created a ranked priority order for mapping 13 different regions around Florida. The data needed for each of the 13 priority regions were outlined. A matrix considering State and Federal priorities was created, utilizing input from all agencies. The matrix showed overlapping interests of the entities and will allow for partnering and leveraging of resources. The five most basic mapping needs were determined to be bathymetry, high-vertical resolution coastline for sea-level rise scenarios, shoreline change, subsurface geology, and benthic habitats at sufficient scale. There was a clear convergence on the need to coordinate mapping activities around the state. Suggestions for coordination included: creating a glossary of terms: a standard for specifying agency data-mapping needs; creating a geographic information officer (GIO) position or permanent organizing group to maintain communications established at this workshop and to maintain progress on the issues identified during the workshop. The person or group could develop a website, maintain a project-status matrix, develop a list of contacts, create links to legislative updates and links to funding sources; developing a web portal and one-stop/clearinghouse of data. There was general consensus on the need to adopt a single habitat classification system and a strategy to accommodate existing systems smoothly. Unresolved aspects of the systems warrant that a separate workshop would be needed to work out details. Participants recognized that the State priority list would necessarily be updated periodically. An annual review of priorities would facilitate information exchange, mapping activities updates, and re-allocation of funding among changing priorities. It was recognized that mapping of State waters would take billions of dollars and in light of tightening budgets there was need for processes that could be used to appropriate or leverage monies for mapping and reduce data-collection costs. Fourteen different avenues were explored. There was a clear consensus that the linking of public to private partnerships to support mapping was imperative, and ways to achieve this were discussed.

Florida

Occurrence of human pharmaceuticals in water resources of the United States: A review

The widespread environmental presence of some pharmaceuticals and other organic wastewater compounds has been documented globally (e.g. Buser et al. 1998; Ternes 1998; Stumpf et al.1999; Heberer et al. 2001; Kümmerer 2001; Ternes et al. 2001; Scheytt et al. 2001; Golet et al. 2002; Kolpin et al. 2002; Boyd et al. 2003; Metcalf et al. 2003). Recently, there have been several literature reviews and summary studies of the occurrence, fate, transport, and treatment of targeted human pharmaceuticals in wastewater effluent and associated environmental waters across the globe (e.g. Daughton and Ternes 1999; Sedlak et al. 2000; Suter and Giger 2000; Daughton and Jones-Lepp 2001; Jones et al. 2001; Heberer 2002; and Drewes et al. 2002). The occurrence of pharmaceutical compounds in water resources is explained by their ubiquitous use, excretion of large percentages of the mass consumed, and incomplete removal during wastewater treatment (Stumpf et al.1999). The recent increase in detection of trace concentrations (typically less than a part per billion) of pharmaceuticals in water resources across the globe reflects improvements in laboratory analytical methods (Sedlak et al. 2000) and the associated increases in field surveys. The detection of pharmaceutical compounds in large rivers in Europe and in the North Sea (Buser et al. 1998; Ternes 1998; Stumpf et al. 1999) highlighted the fact that highly soluble, trace organic compounds, such as pharmaceuticals, may escape removal in wastewater treatment, and the mixing and concentration of wastewaters through conventional wastewater treatment processes could provide a means of delivering these chemicals to environmental waters in a manner that would contaminate water resources on a large scale at trace levels (Richardson and Bowron 1985). In the United States, some of the first detections of a limited number of pharmaceutically active compounds or their transformation products were found in waters associated with landfill leachates or sewage effluent (Tabak and Bunch 1970; Garrison et al. 1976; Hignite and Azarnoff 1977; Bouwer et al. 1982; Eckel et al. 1991) decades ago. At the time of these studies, other industrial contaminants were the focus of regulatory and scientific interest; therefore, further studies on the environmental occurrence and transport of pharmaceutical compounds were rare.

Book chapter

Hydrogeology of Webb County, Texas

Introduction Webb County, in semiarid South Texas on the U.S.-Mexico border, is a region confronted by increasing stresses on natural resources. Laredo (fig. 1), the largest city in Webb County (population 193,000 in 2000), was one of the 10 fastest-growing metropolitan areas in the country during 1990-2000 (Perry and Mackun, 2001). Commercial and industrial activities have expanded throughout the region to support the maquiladora industry (manufacturing plants in Mexico) along the border and other growth as a result of the passage of the North American Free Trade Agreement. The Rio Grande currently (2002) is the primary source of public water supply for Laredo and other cities along the border in Webb County (fig. 1). Other cities, such as Bruni and Mirando City in the southeastern part of the county, rely on ground-water supplies to meet municipal demands. Increased water demand associated with development and population growth in the region has increased the need for the City of Laredo and Webb County to evaluate alternative water sources to meet future demand. Possible options include (1) supplementing the surface-water supply with ground water, and (2) applying artificial storage and recovery (ASR) technology to recharge local aquifers. These options raise issues regarding the hydraulic capability of the aquifers to store economically substantial quantities of water, current or potential uses of the resource, and possible effects on the quality of water resulting from mixing ground water with alternative source waters. To address some of these issues, the U.S. Geological Survey (USGS), in cooperation with the City of Laredo, began a study in 1996 to assess the ground-water resources of Webb County. A hydrogeologic study was conducted to review and analyze available information on the hydrogeologic units (aquifers and confining units) in Webb County, to locate available wells in the region with water-level and water-quality information from the aquifers, and to analyze the hydraulic properties of the aquifers. The purpose of this report is to document the findings of the study. The information is organized by hydrogeologic unit and presented on this and six other sheets.

Texas

The principal rare earth elements deposits of the United States: A summary of domestic deposits and a global perspective

The rare earth elements (REE) are fifteen elements with atomic numbers 57 through 71, from lanthanum to lutetium ('lanthanides'), plus yttrium (39), which is chemically similar to the lanthanide elements and thus typically included with the rare earth elements. Although industrial demand for these elements is relatively small in tonnage terms, they are essential for a diverse and expanding array of high-technology applications. REE-containing magnets, metal alloys for batteries and light-weight structures, and phosphors are essential for many current and emerging alternative energy technologies, such as electric vehicles, energy-efficient lighting, and wind power. REE are also critical for a number of key defense systems and other advanced materials. Section 843 of the National Defense Authorization Act for Fiscal Year 2010, Public Law 111-84, directs the Comptroller General to complete a report on REE materials in the defense supply chain. The Office of Industrial Policy, in collaboration with other U.S. Government agencies, has initiated (in addition to this report) a detailed study of REE. This latter study will assess the Department of Defense's use of REE, as well as the status and security of domestic and global supply chains. That study will also address vulnerabilities in the supply chain and recommend ways to mitigate any potential risks of supply disruption. To help conduct this study, the Office of Industrial Policy asked the U.S. Geological Survey (USGS) to report on domestic REE reserves and resources in a global context. To this end, the enclosed report is the initial USGS contribution to assessing and summarizing the domestic REE resources in a global perspective. In 2009, the Mineral Resources Program of the USGS organized a new project under the title Minerals at Risk and For Emerging Technologies in order to evaluate mineral resource and supply issues of rare metals that are of increasing importance to the national economy. Leaders and members of this project, with the assistance of the USGS National Minerals Information Center, prepared the enclosed USGS report on domestic REE resources. The USGS Mineral Resources Program has investigated domestic and selected foreign REE resources for many decades, and this report summarizes what has been learned from this research. The USGS National Minerals Information Center (formerly Minerals Information Team) has monitored global production, trade, and resources for an equally long period and is the principal source of statistics used in this report. The objective of this study is to provide a nontechnical overview of domestic reserves and resources of REE and possibilities for utilizing those resources. At the present time, the United States obtains its REE raw materials from foreign sources, almost exclusively from China. Import dependence upon a single country raises serious issues of supply security. In a global context, domestic REE resources are modest and of uncertain value; hence, available resources in traditional trading partners (such as Canada and Australia) are of great interest for diversifying sources of supply. This report restates basic geologic facts about REE relevant to assessing security of supply, followed by a review of current United States consumption and imports of REE, current knowledge of domestic resources, and possibilities for future domestic production. Further detail follows in a deposit-by-deposit review of the most significant domestic REE deposits (see index map). Necessary steps to develop domestic resources are discussed in a separate section, leading into a review of current domestic exploration and a discussion of the value of a future national mineral resource assessment of REE. The report also includes an overview of known global REE resources and discusses the reliability of alternative foreign sources of REE.

Scientific Investigations Report

Building groundwater modeling capacity in Mongolia

Ulaanbaatar, the capital city of Mongolia (fig. 1), is dependent on groundwater for its municipal and industrial water supply. The population of Mongolia is about 3 million people, with about one-half the population residing in or near Ulaanbaatar (World Population Review, 2016). Groundwater is drawn from a network of shallow wells in an alluvial aquifer along the Tuul River. Evidence indicates that current water use may not be sustainable from existing water sources, especially when factoring the projected water demand from a rapidly growing urban population (Ministry of Environment and Green Development, 2013). In response, the Government of Mongolia Ministry of Environment, Green Development, and Tourism (MEGDT) and the Freshwater Institute, Mongolia, requested technical assistance on groundwater modeling through the U.S. Army Corps of Engineers (USACE) to the U.S. Geological Survey (USGS). Scientists from the USGS and USACE provided two workshops in 2015 to Mongolian hydrology experts on basic principles of groundwater modeling using the USGS groundwater modeling program MODFLOW-2005 (Harbaugh, 2005). The purpose of the workshops was to bring together representatives from the Government of Mongolia, local universities, technical experts, and other key stakeholders to build in-country capacity in hydrogeology and groundwater modeling. A preliminary steady-state groundwater-flow model was developed as part of the workshops to demonstrate groundwater modeling techniques to simulate groundwater conditions in alluvial deposits along the Tuul River in the vicinity of Ulaanbaatar. ModelMuse (Winston, 2009) was used as the graphical user interface for MODFLOW for training purposes during the workshops. Basic and advanced groundwater modeling concepts included in the workshops were groundwater principles; estimating hydraulic properties; developing model grids, data sets, and MODFLOW input files; and viewing and evaluating MODFLOW output files. A key to success was developing in-country technical capacity and partnerships with the Mongolian University of Science and Technology; Freshwater Institute, Mongolia, a non-profit organization; United Nations Educational, Scientific and Cultural Organization (UNESCO); the Government of Mongolia; and the USACE.

Open-File Report

Hydrologic investigations and a preliminary conceptual model of the groundwater system at North Penn Area 1 Superfund Site, Souderton, Montgomery County, Pennsylvania

The U.S. Geological Survey (USGS) conducted hydrogeologic investigations, reviewed existing data, and developed a preliminary conceptual model of the groundwater system as part of technical support of the U.S. Environmental Protection Agency (EPA) at the North Penn Area 1 Superfund Site (hereafter, the NP1 Site) located within the Borough of Souderton in Montgomery County, Pennsylvania. Field work and monitoring took place during 2012–18. The area is underlain by sedimentary formations that form a fractured-rock aquifer used for drinking water and industrial supply. The EPA placed the Site on the National Priorities List in 1989, identifying tetrachloroethylene (PCE) and trichloroethylene (TCE) as contaminants of concern. During 2012–18, the USGS conducted field activities that included drilling an 82-foot (ft)-deep monitoring well (MG 2220) in 2016, reconstructing a 208-ft-deep former industrial production well (MG 668 [Granite Knitting Mill]), and collecting borehole geophysical and video logs and water levels from those and five additional wells, which ranged in depth from about 50 to 200 ft below land surface. Continuous water levels were collected during 2014–17, and a synoptic set of water levels were measured in April 2018 in the seven wells. The borehole geophysical logs (caliper, acoustic televiewer, natural gamma, single-point resistance, vertical flow, and fluid temperature and resistivity) and borehole video logs in the seven wells were evaluated to assess potential for lithologic correlation and to identify and describe water-bearing features, which included both low- and high-angle fractures and other openings oriented along dipping bedding planes, joints, or possible faults. Borehole geophysical logs collected by USGS in 1992 in a 300-ft-deep former production well near the Site were also evaluated. Few to no distinctive features were identified on geophysical logs (natural gamma and single-point resistance) that could be used for correlation, thus limiting this approach to determining local geologic structure. Extensive fracturing in the upper 62 ft of monitoring well MG 2220 indicates that the well was likely drilled through a zone of faulting, and other evidence of faulting is present in the area near the Site. Assessment of continuous water levels showed hydraulic connections among some wells as indicated by rising or falling water levels in response to changes in pumping rates at nearby wells. A map of water levels measured in April 2018 indicates potential for groundwater flow generally toward the stream to the south and southwest of the Site, but the limited water-level data are insufficient to describe vertical groundwater gradients or lateral gradients in any detail. Review of 1999–2022 volatile organic compound (VOC) monitoring data collected by the Pennsylvania Department of Environmental Protection for five monitoring wells indicates that the highest groundwater concentrations of PCE and TCE were found in samples from extraction well MG 2201 (S-1) downgradient from, and nearest to, the previously identified Site contaminant source area, and these concentrations fluctuated through time. PCE concentrations were higher than TCE concentrations in samples from all five monitoring wells and were much higher than TCE concentrations in samples from extraction well MG 2201 (S-1). Temporally variable recharge is a possible factor affecting observed fluctuations in PCE concentrations in groundwater samples from well extraction MG 2201 (S-1), as indicated by a general inverse relation between PCE concentrations and water levels in a nearby long-term observation well. The PCE concentration of 1,830 micrograms per liter (μg/L) in a May 2018 water sample from monitoring well MG 2220 was more than four times the PCE concentration of 444 μg/L in a December 2017 sample from the nearby extraction well MG 2201 (S-1), which is open to fewer fractures. Low concentrations of VOCs were measured in surface water at two stream sites downgradient from wells with the highest groundwater VOC concentrations at the Site, indicating that discharge of contaminated groundwater to the stream is likely. Development of a conceptual model of the groundwater system was constrained by limited data. In areas with no pumping, groundwater-flow directions generally are thought to be controlled by topography and geologic structure (bedding orientation) and likely to the south and southwest of the Site, with local flow directions affected by orientations of fractures, joints, and local faults. Additional investigations that could help improve the conceptual model of the groundwater system and help delineate the extent of groundwater contamination and its transport are discussed.

Pennsylvania