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Quality Assurance Project Plan: Status and trends monitoring of small streams in the Puget Lowlands ecoregion for Stormwater Action Monitoring (SAM)

This Quality Assurance Project Plan (QAPP) details a long term status and trends monitoring study for small streams in the Puget Lowland as part of Stormwater Action Monitoring (SAM) program. SAM is the regional stormwater monitoring program funded by the Phase I Municipal Stormwater permit and the Western Washington Phase II Municipal Stormwater permit permittees. This study of small streams in the Puget Lowland Ecoregion (called Puget Small Streams, PSS study, or SAM_PSS study hereafter) is designed to answer the question, “Are regional conditions in receiving water quality and biota improving in concert with broad implementation of required stormwater management practices?” In 2015, the first round of monitoring evaluated the condition (status) of streams (DeGasperi et al., 2018). Beginning in 2020 and thereafter this study will monitor streams’ changes over time in urban, urbanizing and rural areas of the Puget Lowland. The PSS will follow the protocols developed for the on-going statewide stream health monitoring program-Status and Trends Monitoring for Watershed Health and Salmon Recovery (WHSR) for physical habitat, biological measurements, except for minor changes to water quality parameters to better capture the stormwater-related chemistry signals. In addition this effort will sample sieved sediments for stormwater-related chemistry signals. This QAPP ensures quality data collection, analysis, reporting and management of the SAM PSS monitoring study

Washington

Gypsies in the palace: Experimentalist's view on the use of 3-D physics-based simulation of hillslope hydrological response

As a fundamental unit of the landscape, hillslopes are studied for their retention and release of water and nutrients across a wide range of ecosystems. The understanding of these near-surface processes is relevant to issues of runoff generation, groundwater-surface water interactions, catchment export of nutrients, dissolved organic carbon, contaminants (e.g. mercury) and ultimately surface water health. We develop a 3-D physics-based representation of the Panola Mountain Research Watershed experimental hillslope using the TOUGH2 sub-surface flow and transport simulator. A recent investigation of sub-surface flow within this experimental hillslope has generated important knowledge of threshold rainfall-runoff response and its relation to patterns of transient water table development. This work has identified components of the 3-D sub-surface, such as bedrock topography, that contribute to changing connectivity in saturated zones and the generation of sub-surface stormflow. Here, we test the ability of a 3-D hillslope model (both calibrated and uncalibrated) to simulate forested hillslope rainfall-runoff response and internal transient sub-surface stormflow dynamics. We also provide a transparent illustration of physics-based model development, issues of parameterization, examples of model rejection and usefulness of data types (e.g. runoff, mean soil moisture and transient water table depth) to the model enterprise. Our simulations show the inability of an uncalibrated model based on laboratory and field characterization of soil properties and topography to successfully simulate the integrated hydrological response or the distributed water table within the soil profile. Although not an uncommon result, the failure of the field-based characterized model to represent system behaviour is an important challenge that continues to vex scientists at many scales. We focus our attention particularly on examining the influence of bedrock permeability, soil anisotropy and drainable porosity on the development of patterns of transient groundwater and sub-surface flow. Internal dynamics of transient water table development prove to be essential in determining appropriate model parameterization. ?? 2010 John Wiley & Sons, Ltd.

Hydrological Processes

Assessing streams in the Chesapeake Bay Watershed to guide conservation and restoration activities

Freshwater streams in the Chesapeake Bay watershed are home to numerous aquatic organisms (like fish, amphibians, mussels, and insects) and provide drinking water and recreational opportunities to people living in or visiting the watershed. Land-use changes, such as urban development and increased activities in certain agricultural sectors, have degraded water quality and altered conditions in these streams, thereby affecting their health and function. The U.S. Geological Survey (USGS) is working with Federal, State, and local partners to develop modeled assessments of stream health in freshwater streams and rivers within the Chesapeake Bay watershed. The USGS compiled large datasets for multiple stream health indicators, including instream stressors (salinity, water temperature, physical habitat, and streambank erosion) and living resources (macroinvertebrates and fish communities; fig. 1). These datasets were used by USGS scientists to develop models to predict stream health conditions across the entire region, including areas with little or no monitoring data. Collectively, these stream health assessments provide critical information to natural resource managers who implement restoration and conservation activities in the region.

Chesapeake Bay Watershed

An approach to urban waterway assessment using holistic values and reciprocity

Current aquatic ecosystem assessment methods and tools often focus on physical, chemical, and biological indicators of ecosystem health. This approach to ecosystem assessment is not always straightforward to execute in urban environments and ignores potential connectivity between social and environmental outcomes. During a workshop at the Symposium on Urbanization and Stream Ecology in Brisbane, Australia in 2023 (SUSE6), we developed an approach to urban aquatic ecosystem assessment that incorporates a holistic perspective. Specifically, our approach considers both environmental (biological, chemical, and physical integrity) and social (community connection, human safety, resource use) values of urban waterways. This approach is inclusive of Indigenous perspectives, such as the concept of reciprocity, whereby consideration of both the environment and society leads to a healthy ecosystem. To highlight how this holistic assessment approach could be used, we present real-world examples that included assessing both environmental and societal values informed by reciprocity or balanced perspectives. This approach can be broadly applied and adapted to specific aquatic ecosystem conditions and projects, providing an inclusive, community-centered approach for assessing the health of waterways in urban environments.

Freshwater Science

Guidelines for the field evaluation of desert tortoise health and disease

Field evaluation of free-ranging wildlife requires the systematic documentation of a variety of environmental conditions and individual parameters of health and disease, particularly in the case of rare or endangered species. In addition, defined criteria are needed for the humane salvage of ill or dying animals. The purpose of this paper is to describe, in detail, the preparation, procedures, and protocols we developed and tested for the field evaluation of wild desert tortoises ( Gopherus agassizii ). These guidelines describe: preparations for the field, including developing familiarity with tortoise behavior and ecology, and preparation of standardized data sheets; journal notes to document background data on weather conditions, temperature, rainfall, locality, and historic and recent human activities; procedures to prevent the spread of disease and parasites; data sheets for live tortoises to record tortoise identification, location, sex, body measurements and activity; health profile forms for documenting and grading physical abnormalities of tortoise posture and movements, general condition (e.g., lethargy, cachexia), external parasites, and clinical abnormalities associated with shell and upper respiratory diseases; permanent photographic records for the retrospective analysis of progression and regression of upper respiratory and eye diseases, analysis of shell lesions and evaluation of growth and age; and indications and methods for salvaging ill or dying tortoises for necropsy evaluation. These guidelines, tested on 5,000 to 20,000 tortoises over a 10 to 27 yr period, were designed to maximize acquisition of data for demographic, ecological, health and disease research projects; to reduce handling and stress of individual animals; to avoid spread of infectious disease; to promote high quality and consistent data sets; and to reduce the duration and number of field trips. The field methods are adapted for desert tortoise life cycle, behavior, anatomy, physiology, and pertinent disease; however the model is applicable to other species of reptiles. Comprehensive databases of clinical signs of disease and health are crucial to research endeavors and essential to decisions on captive release, epidemiology of disease, translocation of wild tortoises, breeding programs, and euthanasia.

Journal of Wildlife Diseases

Health and condition of endangered juvenile Lost River and shortnose suckers relative to water quality and fish assemblages in Upper Klamath Lake, Oregon, and Clear Lake Reservoir, California

Executive Summary Most mortality of endangered Lost River ( Deltistes luxatus ) and shortnose ( Chasmistes brevirostris ) suckers in Upper Klamath Lake, Oregon, appears to occur within the first year of life. However, juvenile suckers in Clear Lake Reservoir, California, appear to survive longer and may even recruit to the spawning populations. Our goal in this study was to develop productive lines of inquiry into the causes of mortality of juvenile suckers, especially in Upper Klamath Lake, through comparison of sucker health and environmental conditions in both lakes. The health of juvenile suckers was associated with physical, biological, and chemical characteristics in each lake from July to September 2013 and 2014. Water-quality dynamics differed substantially between lakes. Diel fluctuations were greater for dissolved-oxygen concentrations and pH in Upper Klamath Lake than in Clear Lake Reservoir, but diel temperature fluctuations were greater in Clear Lake Reservoir. Minimum dissolved-oxygen concentrations were as low as 1.0 milligram per liter (mg/L) in Upper Klamath Lake, but were no lower than 5.7 mg/L in Clear Lake Reservoir. Unionized ammonia (NH 3 ) concentrations were near or less than the minimum reporting limit of 0.002 mg/L NH 3 in Clear Lake Reservoir and generally were less than the concentration known to cause cellular changes to the gills or mortality of suckers in Upper Klamath Lake. Concentrations of microcystins were less than the detection limit (&le;0.10 microgram per liter [&mu;g/L]) in both dissolved (<63 micrometers [&mu;m]) and particulate (&ge;63 &mu;m) fractions of water samples collected from Clear Lake Reservoir in both years. In Upper Klamath Lake, concentrations of microcystins were relatively low in the 2013 particulate fractions and dissolved fractions of samples in both years, but as high as 44.30 &mu;g/L, more than 44 times the World Health Organization recommended levels for drinking water (1 &mu;g/L), in the 2014 particulate fraction. However, there was little histological evidence and no chemical evidence that these concentrations in water were harmful to suckers that we captured. The species and age compositions of juvenile sucker populations differed between lakes. A total of 98 percent of all juvenile suckers captured in Upper Klamath Lake were age-0. In contrast, as many as six age classes of suckers were represented in Clear Lake Reservoir, indicating much better juvenile survival than in Upper Klamath Lake. Based on genetic species identification, 98 percent of juvenile suckers collected from Clear Lake Reservoir were shortnose or Klamath largescale suckers ( Catostomus snyderi ). In contrast, there was a high degree of apparent genetic hybridization in juvenile suckers collected from Upper Klamath Lake, and both Lost River and non-Lost River juvenile suckers were nearly equally represented in samples. Neither gross nor histological examination revealed a high prevalence of abnormalities in suckers that might indicate a mechanism for juvenile mortality in Upper Klamath Lake. Therefore, high mortality primarily may have occurred outside our study period (for example, in spring or over winter), or was owing to a factor that could not be detected with our methods (for example, predation). Alternatively, abnormalities in a small percentage of passively captured suckers in Upper Klamath Lake may indicate health-related issues that were more prevalent in populations than in our samples. Some apparent symptoms of stress or exposure to irritants, such as peribiliary cuffing in hepatocytes and mild inflammation and necrosis in gill tissues, were present in suckers from both lakes and do not appear to be clues to the cause of differential mortality between lakes. Seasonal trends in energy storage as glycogen and triglycerides were similar between lakes, indicating prey availability was not a factor in differential mortality. Differences in sucker health and condition between lakes were considered the most promising clues to the causes of differential juvenile sucker morality between lakes. A low prevalence of petechial hemorrhaging of the skin (16 percent) and deformed opercula (8 percent) in Upper Klamath Lake suckers may indicate exposure to a toxin other than microcystin. Suckers grew slower in their first year of life, but had similar or greater triglyceride and glycogen levels in Upper Klamath Lake compared to Clear Lake Reservoir. These findings do not suggest a lack of prey quantity but may indicate lower prey quality in Upper Klamath Lake.

California, Oregon

Water for the Nation: An overview of the USGS Water Resources Division

The Water Resources Division (WRD) of the U.S. Geological Survey (USGS) provides reliable, impartial, timely information needed to understand the Nation's water resources. WRD actively promotes the use of this information by decisionmakers to: * Minimize the loss of life and property as a result of water-related hazards such as floods, droughts, and land movement. * Effectively manage ground-water and surface-water resources for domestic, agricultural, commercial, industrial, recreational, and ecological uses. * Protect and enhance water resources for human health, aquatic health, and environmental quality. * Contribute to wise physical and economic development of the Nation's resources for the benefit of present and future generations.

General Information Product

A review of major storm impacts on coastal wetland elevations

Storms have long been recognized as agents of geomorphic change to coastal wetlands. A review of recent data on soil elevation dynamics before and after storms revealed that storms affected wetland elevations by storm surge, high winds, and freshwater flushing of the estuary (inferred). The data also indicate that measures of sediment deposition and erosion can often misrepresent the amount and even direction of elevation change because of storm influences on subsurface processes. Simultaneous influence on both surface and subsurface processes by storms means that soil elevation cannot always be accurately estimated from surface process data alone. Eight processes are identified as potentiatly influencing soil elevation: sediment deposition, sediment erosion, sediment compaction, soil shrinkage, root decomposition (following tree mortality from high winds), root growth (following flushing with freshwater, inferred), soil swelling, and lateral folding of the marsh root mat. Local wetland conditions (e.g., marsh health, tide height, groundwater level) and the physical characteristics of the storm (e.g., angle of approach, proximity, amount of rain, wind speed, and storm surge height) were apparently important factors determining the storm's effect on soil elevation. Storm effects on elevation were both permanent (on an ecological time scale) and short-lived, but even short-term changes have potentially important ecological consequences. Shallow soil subsidence or expansion caused by a storm must be considered when calculating local rates of relative sea level rise and evaluating storm effects on wetland stability.

Estuaries and Coasts

US Atlantic coast striped bass: Issues with a recovered population

Striped bass, Morone saxatilis (Walbaum), is an anadromous species naturally occurring along the US Atlantic coast, which historically supported valuable commercial and recreational fisheries. In response to a near order-of-magnitude decline in landings, the Atlantic States Marine Fisheries Commission enacted a management plan in 1981 protecting fish until they could spawn at least once. By 1989, recruitment increased in natal rivers and regulations were relaxed, permitting limited fisheries by 1990. By 1995, the stock was declared fully recovered. Since the recovery, concern has increased over the health of the stocks. In the 1990s, fish in poor physical condition with dermal lesions became common in Chesapeake Bay. Pathogens of most concern in cultures from fish include the genus Mycobacterium. Coincident with declines in fish health were changes in diets, declines of preferred prey, and reduced growth and condition. Theories were suggested linking declines in condition to reductions in forage base or pathogens. Diets have changed since the 1950s and while many Chesapeake fish are infected with mycobacteria, it is still not known how or if these factors are linked. The highest priorities for research were considered to be: linking numerous local and regional studies to provide a coast-wide perspective; continuation of investigations linking population health to the prey-base; determination of the cause-effect of mycobacteria infections; and formulation of management options.

Fisheries Management and Ecology

Coastal Circulation and Sediment Dynamics in War-in-the-Pacific National Historical Park, Guam; measurements of waves, currents, temperature, salinity, and turbidity, June 2007-January 2008

Flow in and around coral reefs affects a number of physical, chemical and biologic processes that influence the health and sustainability of coral reef ecosystems. These range from the residence time of sediment and contaminants to nutrient uptake and larval retention and dispersal. As currents approach a coast they diverge to flow around reef structures, causing high horizontal and vertical shear. This can result in either the rapid advection of material in localized jets, or the retention of material in eddies that form in the lee of bathymetric features. The high complexity and diversity both within and between reefs, in conjunction with past technical restrictions, has limited our understanding of the nature of flow and the resulting flux of physical, chemical, and biologic material in these fragile ecosystems. Sediment, nutrients, and other pollutants from a variety of land-based activities adversely impact many coral reef ecosystems in the U.S. and around the world. These pollutants are transported in surface water runoff, groundwater seepage, and atmospheric fallout into coastal waters, and there is compelling evidence that the sources have increased globally as a result of human-induced changes to watersheds. In Guam, and elsewhere on U.S. high islands in the Pacific and Caribbean, significant changes in the drainage basins due to agriculture, feral grazing, fires, and urbanization have in turn altered the character and volume of land-based pollution released to coral reefs. Terrigenous sediment run-off (and the associated nutrients and contaminants often absorbed to it) and deposition on coral reefs are recognized to potentially have significant impact on coral health by blocking light and inhibiting photosynthesis, directly smothering and abrading coral, and triggering increases in macro algae. Studies that combine information on watershed, surface water- and groundwater-flow, transport and fate of sediment and other pollutants in the reef environment, and their impact on reef health and ecology are essential for effective reef management. Two of the main anthropogenic activities along west-central Guam's coastline that may impact the region's coral reef ecosystems include pollution and coastal land use/development, as discussed in the review by Porter and others (2005). The pollution threats include point-sources, such as municipal wastewater (Northern District, Hagatna, Naval Station Guam, and Agat-Santa Rita Waster Water Treatment Plants), cooling water (Tanguisson Steam and Cabras Power Plants), and numerous storm water, ballast water, and tank bottom draw outfalls; nonpoint sources include septic systems, urban runoff, illegal dumping, and groundwater discharges. Poor land-use practices include development without the use of runoff management measures, increased areal extent of impervious surfaces and decreased extent of vegetative barriers, and recreational off-road vehicle use. Furthermore, feral ungulates and illegal wildfires remove protective vegetative cover and generally result in increased soil erosion. While anthropogenic point-sources have been reduced in many areas due to better management practices, nonpoint sources have either stayed constant or increased. Between 1975 and 1999, it is estimated that Guam lost more than a quarter of its tree cover, and more than 750 wildfires each year have resulted in a greater proportion of badlands and other erosion-prone land surfaces with high erosion rates (Forestry and Soil Resources Division, 1999). Approximately 1.8 square kilometers (km2) of Asan Bay, west-central Guam, lies within the National Park Service's (NPS) War-in-the-Pacific National Historical Park's (WAPA) Asan Unit; the bay is the sink for material coming out of the Asan watershed. Anthropogenic modifications of the watersheds adjacent to Asan Bay, which include intentionally-set wildfires, construction, and agriculture (Minton, 2005), are believed to have increased over the past 25

Open-File Report

Measuring and attributing sedimentary and geomorphic responses to modern climate change: Challenges and opportunities

Today, climate change is affecting virtually all terrestrial and nearshore settings. This commentary discusses the challenges of measuring climate-driven physical landscape responses to modern global warming: short and incomplete data records, land use and seismicity masking climatic effects, biases in data availability and resolution, and signal attenuation in sedimentary systems. We identify opportunities to learn from historical and paleo data, select especially sensitive study sites, and report null results to better characterize the extent and nuances of climate-change effects. We then discuss efforts to improve attribution practices, which will lead to better predictive capabilities. We encourage the earth-science community to prioritize scientific research on climate-driven physical landscape changes so that societies will be better prepared to manage the effects on health and safety, infrastructure, water–food–energy security, economics, and ecosystems that follow from climate-driven physical landscape change.

Earth's Future

Evaluation of daily stream temperature predictions (1979-2021) across the contiguous United States using a spatiotemporal aware machine learning algorithm

Stream temperature controls a variety of physical and biological processes that affect ecosystems, human health, and economic activities. We used 42 years (1979–2021) of data to predict daily summary statistics of stream temperature across >50,000 stream reaches in the contiguous United States using a recurrent graph convolution network. We comprehensively documented the performance – both across all reaches and by stream type (e.g., reservoir or groundwater influence) – as a baseline for future improvement. The model showed reach-level RMSE of <2 °C with 90 % prediction intervals that contain 90.7 % of observations. We also assessed how the model captured variability in ecologically relevant metrics (e.g., R 2 for annual 7-day maximum = 0.76; R 2 for days exceeding 25 °C = 0.75). This model does not outperform state-of-the-art machine learning efforts (e.g., RMSE ≤1.5 °C) due to a limited input set but does provide the most spatially complete modeling to date to support water availability assessments.

contiguous United States

The future of nearshore processes research

The nearshore is the transition region between land and the continental shelf including (from onshore to offshore) coastal plains, wetlands, estuaries, coastal cliffs, dunes, beaches, surf zones (regions of wave breaking), and the inner shelf (Figure ES-1). Nearshore regions are vital to the national economy, security, commerce, and recreation. The nearshore is dynamically evolving, is often densely populated, and is under increasing threat from sea level rise, long-term erosion, extreme storms, and anthropogenic influences. Worldwide, almost one billion people live at elevations within 10 m of present sea level. Long-term erosion threatens communities, infrastructure, ecosystems, and habitat. Extreme storms can cause billions of dollars of damage. Degraded water quality impacts ecosystem and human health. Nearshore processes, the complex interactions between water, sediment, biota, and humans, must be understood and predicted to manage this often highly developed yet vulnerable nearshore environment. Over the past three decades, the understanding of nearshore processes has improved. However, societal needs are growing with increased coastal urbanization and threats of future climate change, and significant scientific challenges remain. To address these challenges, members of academia, industry, and federal agencies (USGS, USACE, NPS, NOAA, FEMA, ONR) met at the “The Past and Future of Nearshore Processes Research: Reflections on the Sallenger Years and a New Vision for the Future” workshop to develop a nearshore processes research vision where societal needs and science challenges intersect. The resulting vision is comprised of three broad research themes: Long-term coastal evolution due to natural and anthropogenic processes: As global climate change alters the rates of sea level rise and potentially storm patterns and coastal urbanization increases over the coming decades, an understanding of coastal evolution is critical. Improved knowledge of long-term morphological, ecological, and societal processes and their interactions will result in an improved ability to simulate coastal change. This will enable proactive solutions for resilient coasts and better guidance for reducing coastal vulnerability. Extreme Events: Flooding, erosion, and the subsequent recovery: Hurricane Sandy caused flooding and erosion along hundreds of miles of shoreline, flooded New York City, and impacted communities and infrastructure. Overall U.S. coastal extreme event related economic losses have increased substantially. Furthermore, climate change may cause an increase in coastal extreme events and rising sea levels could increase the occurrence of extreme events. Addressing this research theme will result in an improved understanding of the physical processes during extreme events, leading to improved models of flooding, erosion, and recovery. The resulting societal benefit will be more resilient coastal communities. The physical, biological and chemical processes impacting human and ecosystem health: Nearshore regions are used for recreation, tourism, and human habitation, and provide habitat and valuable ecosystem services. These areas must be sustained for future generations, however overall coastal water quality is declining due to microbial pathogens, fertilizers, pesticides, and heavy metal contamination, threatening ecosystem and human health. To ensure sustainable nearshore regions, predictive real-time water- and sediment-based based pollutant modeling capabilities must be developed, which requires expanding our knowledge of the physics, chemistry, and biology of the nearshore. The resulting societal benefits will include better beach safety, healthier ecosystems, and improved mitigation and regulatory policies. The scientists and engineers of the U.S. nearshore community are poised to make significant progress on these research themes, which have significant societal impact. The U.S. nearshore community, including academic, government, and industry colleagues, recommends multi-agency investment into a coordinated development of observational and modeling research infrastructure to address these themes, as discussed in the whitepaper. The observational infrastructure should include development of new sensors and methods, focused observational programs, and expanded nearshore observing systems. The modeling infrastructure should include improved process representation, better model coupling, incorporation of data assimilation techniques, and testing of real-time models. The observations will provide test beds to compare and improve models.

Report

The quality of our Nation’s waters--Ecological health in the Nation's streams, 1993-2005

This report summarizes a national assessment of the ecological health of streams done by the U.S. Geological Survey's (USGS) National Water-Quality Assessment Program (NAWQA). Healthy functioning stream ecosystems provide society with many benefits, including water purification, flood control, nutrient recycling, waste decomposition, fisheries, and aesthetics. The value to society of many of these benefits is substantial; for example, sportfishing in the United States generates an estimated annual economic output of $125 billion, including more than 1 million jobs (National Research Council, 2005; American Sportfishing Association, 2008). Continued monitoring and assessment of the Nation’s streams is needed to support informed decisions that will safeguard this important natural and economic resource. The quality of streams and rivers is often assessed with measures of the chemical or physical properties of water. However, a more comprehensive perspective is obtained if resident biological communities are also assessed. Guidelines to protect human health and aquatic life have been established for specific physical and chemical properties of water and have become useful yardsticks with which to assess water quality. Biological communities provide additional crucial information because they live within streams for weeks to years and therefore integrate through time the effects of changes to their chemical or physical environment. In addition, biological communities are a direct measure of stream health—an indicator of the ability of a stream to support aquatic life. Thus, the condition of biological communities, integrated with key physical and chemical properties, provides a comprehensive assessment of stream health.

conterminous United States

Relationships between the health of Alaska Native communities and our environment -- phase 1, exploring and communicating

Alaska Natives depend on local natural resources for nutritional and, for many, spiritual health. As a result, public health in Alaska is strongly influenced by the relationship between people and their surrounding physical, chemical, and biological environments. Alaska is vast with diverse wildlife and plant communities that are valued as subsistence foods (fig. 1). These resources are supported by equally diverse ecosystems and their underpinning landforms and geologies. The U.S. Geological Survey (USGS) is attempting to integrate physical, chemical, and biological information to better describe current (2013) environments and project scenarios for the future. Integrating ecological data into the public health dialogue is challenging for the more than 280 rural communities of Alaska. This fact sheet reviews a recent USGS effort, the Geographic Information System (GIS) Native Health Project, to better incorporate scientific information into such dialogue.

Alaska

Prioritization of constituents for national- and regional-scale ambient monitoring of water and sediment in the United States

A total of 2,541 constituents were evaluated and prioritized for national- and regional-scale ambient monitoring of water and sediment in the United States. This prioritization was done by the U.S. Geological Survey (USGS) in preparation for the upcoming third decade (Cycle 3; 2013–23) of the National Water-Quality Assessment (NAWQA) Program. This report provides the methods used to prioritize the constituents and the results of that prioritization. Constituents were prioritized by the NAWQA National Target Analyte Strategy (NTAS) work group on the basis of available information on physical and chemical properties, observed or predicted environmental occurrence and fate, and observed or anticipated adverse effects on human health or aquatic life. Constituents were evaluated within constituent groups that were determined on the basis of physical or chemical properties or on uses or sources. Some constituents were evaluated within more than one constituent group. Although comparable objectives were used in the prioritization of constituents within the different constituent groups, differences in the availability of information accessed for each constituent group led to the development of separate prioritization approaches adapted to each constituent group to make best use of available resources. Constituents were assigned to one of three prioritization tiers: Tier 1, those having the highest priority for inclusion in ambient monitoring of water or sediment on a national or regional scale (including NAWQA Cycle 3 monitoring) on the basis of their likelihood of environmental occurrence in ambient water or sediment, or likelihood of effects on human health or aquatic life; Tier 2, those having intermediate priority for monitoring on the basis of their lower likelihood of environmental occurrence or lower likelihood of effects on human health or aquatic life; and Tier 3, those having low or no priority for monitoring on the basis of evidence of nonoccurrence or lack of effects on human health or aquatic life, or of having insufficient evidence of potential occurrence or effects to justify placement into Tier 2. Of the 1,081 constituents determined to be of highest priority for ambient monitoring (Tier 1), 602 were identified for water and 686 were identified for sediment (note that some constituents were evaluated for both water and sediment). These constituents included various types of organic compounds, trace elements and other inorganic constituents, and radionuclides. Some of these constituents are difficult to analyze, whereas others are mixtures, isomers, congeners, salts, and acids of other constituents; therefore, modifications to the list of high-priority constituents for ambient monitoring could be made on the basis of the availability of suitable methods for preparation, extraction, or analysis. An additional 1,460 constituents were placed into Tiers 2 or 3 for water or sediment, including some constituents that had been placed into Tier 1 for a different matrix; 436 constituents were placed into Tier 2 for water and 246 constituents into Tier 2 for sediment; 979 constituents were placed into Tier 3 for water and 779 constituents into Tier 3 for sediment.

Scientific Investigations Report

Environmental health science at the U.S. Geological Survey

USGS environmental health science focuses on the environment-health interface. Research characterizes the processes that affect the interaction among the physical environment, the living environment, and people, as well as the factors that affect ecological and human exposure to disease agents and the resulting toxicologic or infectious disease. The mission of USGS in environmental health science is to contribute scientific information to environmental, natural resource, agricultural, and public-health managers, who use that information to support sound decisionmaking. Coordination with partners and stakeholders will enable USGS to focus on the highest priority environmental health issues, to make relevant, timely, and useable contributions, and to become a “partner of first choice” for environmental health science.

Fact Sheet

TiO 2 as a photocatalyst for control of the aquatic invasive alga, Cladophora, under natural and artificial light

Cladophora, a nuisance and invasive, filamentous algae (Chlorophyta), massively accumulates along the shores of the lower Great Lakes each summer causing great economic damage and compromising recreational opportunity and perhaps public health. In vitro experiments showed that Cladophora samples were physically and biologically degraded when subjected to TiO 2 -mediated photocatalysis. For the most successful photocatalytic process, TiO 2 was immobilized on a glass surface and used in combination with either sunlight or artificial UV light. The loss of vital algal pigments was monitored using UV&ndash;vis spectrophotometry, and cell structural changes were determined by microscopic observation. Cladophora, in the presence of TiO 2 -covered glass beads, experienced a loss of chloroplast pigments after 2 h of UV lamp light irradiation. In a separate experiment, sunlight exposure over 4 days (&sim;24 h) resulted in the complete oxidative degradation of the green chloroplast pigments, verified by the UV spectra of the algal extracts. These results suggest that TiO 2 , mobilized on sunlit silicates may be useful in controlling growth and survival of this alga in the Great Lakes, thus mitigating many of the economic, aesthetic ecological impacts of this invasive alga.

Journal of Photochemistry and Photobiology A: Chem