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Availability and quality of water from drift aquifers in Marshall, Pennington, Polk, and Red Lake counties, northwestern Minnesota

Sand and gravel aquifers present within glacial deposits are important sources of water in Marshall, Pennington, Polk, and Red Lake Counties in northwestern Minnesota. Saturated thicknesses of the unconfined aquifers range from 0 to 30 feet. Estimated horizontal hydraulic conductivities range from 2.5 to 600 feet per day. Transmissivity of the unconfined aquifers ranges from 33 to greater than 3,910 feet squared per day. Theoretical maximum well yields for 6 wells with specific-capacity data range from 12 to 123 gallons per minute. Saturated thicknesses of shallow confined aquifers (depth to top of the aquifer less than 100 feet below land surface) range from 0 to 150 feet. Thicknesses of intermediate, deep, and basal confined aquifers (depths to top of the aquifer from 100 to 199 feet, from 200 to 299 feet, and 300 feet or more below land surface, respectively) range from 0 to more than 126 feet. Transmissivity of the confined aquifers ranges from 2 to greater than 210,000 feet squared per day. Theoretical maximum well yields range from 3 to about 2,000 gallons per minute. Recharge to ground water is predominantly from precipitation that percolates downward to the saturated zone. Recharge to unconfined aquifers in the study area ranged from 4.5 to 12.0 inches per year during 1991 and 1992, based on hydrograph analysis. Model simulations done for this study indicate that recharge rates from 8 to 9 inches per year to unconfined aquifers produce the best matches between model-simulated and measured water levels in wells. Discharge from ground water occurs by seepage to streams, lakes and wetlands, ground-water evapotranspiration, and withdrawals through wells. In 1990, total ground-water withdrawals in the study area were 6.0 million gallons per day. All of the withdrawals were from drift aquifers. Numerical models of ground-water flow were constructed to represent two beach-ridge aquifer systems under steady-state conditions. Beach-ridge aquifer systems were simulated in Pennington, Polk, and Red Lake County. Simulated recharge from the infiltration of precipitation accounts for most of the sources of water to the beach-ridge aquifer systems and simulated evapotranspiration accounts for all of the discharge other than ground-water withdrawals. The numerical-model simulations indicate that upward movement of water from underlying confined aquifers to overlying unconfined aquifers is an important component of ground-water flow within the beach-ridge aquifer systems. Simulated long-term, steady-state yields from the unconfined aquifers are generally less than 50 gallons per minute, due to the generally low saturated thickness of the aquifers and the relatively low hydraulic conductivity of the aquifer material. Water from all the drift aquifers in the study area is very hard (more than 180 milligrams per liter of calcium carbonate). The predominant ions in water from the unconfined and shallow confined aquifers were generally calcium and bicarbonate. Water from the intermediate confined aquifers includes a variety of water types, including calcium bicarbonate, calcium sulfate, mixed calcium-sodium bicarbonate, and sodium chloride type waters. Waters from the deep confined aquifers are predominantly calcium bicarbonate, mixed calcium-sodium bicarbonate, and sodium chloride type waters. Mean concentrations of calcium and magnesium generally decreased with depth below land surface. Mean concentrations of sodium and sulfate generally increased with depth. Mean chloride concentrations were greatest for the shallow and deep confined aquifers and least for the unconfined and intermediate confined aquifers. The concentration and percentage (as percent of total cations) of sodium, and concentration of dissolved solids tend to increase from east to west along regional flow paths. Concentrations and percentages (as percent of total anions) of chloride tend to be greater in the western part of the study area than in the eastern part. These trends are probably due to longer residence time of the water in the flow system, and upward leakage of water from the underlying Cretaceous and Paleozoic strata. Waters from the drift aquifers underlying most of the study area generally are suitable for domestic consumption, crop irrigation, and most other uses. Water from 20 wells screened in unconfined and confined aquifers exceeded U.S. Environmental Protection Agency recommended limits for dissolved solids concentrations. Chemical analyses of waters from the unconfined and confined aquifers generally indicated a potentially low sodium hazard and a medium to high salinity hazard for irrigation. Water samples analyzed for nitrate had nitrate concentrations below the reporting limit (0.05 milligrams per liter) in 10 out of 23 wells. Two samples had nitrate concentrations greater than 10 milligrams per liter. Pesticide concentrations in water samples from 17 wells screened in unconfined and shallow confined aquifers were below or only slightly above laboratory reporting limits.

Minnesota

Foraging habitat for shorebirds in southeastern Missouri and its predicted future availability

Water management to protect agriculture in alluvial floodplains often conflicts with wildlife use of seasonal floodwater. Such is the case along the Mississippi River in southeastern Missouri where migrating shorebirds forage in shallow-flooded fields. I estimated the current availability of habitat for foraging shorebirds within the New Madrid and St. Johns Basins based on daily river elevations (1943–2009), under assumptions that shorebirds forage in open habitat with water depth <15 cm and use mudflats for 3 days after exposure. The area of shorebird foraging habitat, based on replicated 50-year random samples, averaged 975 ha per day during spring and 33 ha per day during fall. Adjustments to account for habitat quality associated with different water depths, duration of mudflat exposure, intra-seasonal availability, and state of agricultural crops, indicated the equivalent of 494 ha daily of optimal habitat during spring and 11 ha during fall. Proposed levees and pumps to protect cropland would reduce shorebird foraging habitat by 80 %: to 211 ha (108 optimal ha) per day during spring and 9 ha (<3 optimal ha) per day during fall. Alternative water management that allows natural flooding below a prescribed elevation would retain nearly all existing shorebird foraging habitat during fall and about 60 % of extant habitat during spring.

Missouri

Pesticide contamination detected across five wildlife refuges in the Sacramento Valley of California

An important goal for the applied ecological sciences is to understand the extent to which the biodiversity on conserved or managed lands is exposed to anthropogenic stressors. Among the various categories of conserved lands in the United States, the National Wildlife Refuge System is focused on the protection and management of native wildlife and plant populations. Refuge lands can be associated with wetlands and, especially in California, tend to be near areas of intense human use, including agriculture. The proximity of refuges to cultivated lands results in potential exposure to pesticide drift, which increases the possibility of non-target effects on plants and wildlife. We used a passive sampler approach to quantify aerial pesticide deposition during 28 days in spring of 2023, across five refuges in the Sacramento Valley of California. Pesticides were detected across all refuges and plots within the study area, with 36 individual compounds identified, including insecticides, herbicides, and fungicides, from 176 silicone bands from 49 plots. Distance to agriculture was not an important predictor in our models for most indices of contamination. However, our models revealed that the nearest crop type was an important mediator of the importance of distance to agriculture, as fungicide contamination decreased with distance to agriculture only when orchards were the nearest crop type. The overall lack of distance effects suggests that the interior of refuges in the study area do not necessarily provide more protection from pesticides than refuge edges, although larger refuges could offer more protection. We currently lack information on how the level of contamination found herein is biologically relevant to wildlife, and ongoing monitoring efforts have found productive communities of insects in the study area. The results of this study provide a foundation for future investigations on refuges to analyze impacts of specific pesticide compounds on plants and wildlife.

California

Trends in pesticide use on soybean, corn and cotton since the introduction of major genetically modified crops in the United States

BACKGROUND Genetically modified (GM) varieties of soybean, corn and cotton have largely replaced conventional varieties in the United States. The most widely used applications of GM technology have been the development of crops that are resistant to a specific broad-spectrum herbicide (primarily glyphosate) or that produce insecticidal compounds within the plant itself. With the widespread adoption of GM crops, a decline in the use of conventional pesticides was expected. RESULTS There has been a reduction in the annual herbicide application rate to corn since the advent of GM crops, but the herbicide application rate is mostly unchanged for cotton. Herbicide use on soybean has increased. There has been a substantial reduction in the amount of insecticides used on both corn and cotton since the introduction of GM crops. CONCLUSIONS The observed changes in pesticide use are likely to be the result of many factors, including the introduction of GM crops, regulatory restrictions on some conventional pesticides, introduction of new pesticide technologies and changes in farming practices. In order to help protect human and environmental health and to help agriculture plan for the future, more detailed and complete documentation on pesticide use is needed on a frequent and ongoing basis.

Pest Management Science

Attributes for MRB_E2RF1 Catchments by Major River Basins in the Conterminous United States: Nutrient Application (Phosphorus and Nitrogen) for Fertilizer and Manure Applied to Crops (Cropsplit), 2002

This tabular data set represents the estimated amount of phosphorus and nitrogen fertilizers applied to selected crops for the year 2002, compiled for every MRB_E2RF1 catchment of Major River Basins (MRBs, Crawford and others, 2006). The source data set is based on 2002 fertilizer data (Ruddy and others, 2006) and tabulated by crop type per county (Alexander and others, 2007). The MRB_E2RF1 catchments are based on a modified version of the U.S. Environmental Protection Agency's (USEPA) ERF1_2 and include enhancements to support national and regional-scale surface-water quality modeling (Nolan and others, 2002; Brakebill and others, 2011). Data were compiled for MRB_E2RF1 catchments for the conterminous United States covering New England and Mid-Atlantic (MRB1), South Atlantic-Gulf and Tennessee (MRB2), the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy (MRB3), the Missouri (MRB4), the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf (MRB5), the Rio Grande, Colorado, and the Great basin (MRB6), the Pacific Northwest (MRB7) river basins, and California (MRB8).

Data Series

Could mangroves be Tampa Bay's next cash crop?

Obviously, no one is recommending cutting down mangroves to sell, but environmental managers are working toward putting a price tag on the benefits they provide to help ensure that they are protected. Though the process is just beginning here, estimates from studies in other locations indicate that the 15,000 acres of mangrove forests surrounding Tampa Bay could be worth $75 to $225 million a year for the services they provide.

Florida

Conservation status of the world’s swan populations, Cygnus sp. and Coscoroba sp.: a review of current trends and gaps in knowledge

Recent estimates of the world’s swan Cygnus sp. populations indicate that there are currently between 1.5–1.6 million birds in 8 species, including the Coscoroba Swan Coscoroba coscoroba as an honorary swan. Monitoring programmes in Europe and North America indicate that most populations increased following the introduction of national and international legislation to protect the species during the early- to mid-20th century. A switch from feeding primarily on aquatic vegetation to foraging on farmland (especially high-energy arable crops) in winter during the second half of the 20th century, is also considered a contributing factor. Trumpeter Swans Cygnus buccinator famously increased from just 69 individuals known to exist in 1935 (although small numbers were missed) to c. 76,000 at the present time, and most of the northern hemisphere swan populations have continued to show increasing/stable trends over the last 20 years. The exception to this pattern is a decline since 1995 in the Northwest European Bewick’s Swan population, following an increase in its population size during the 1970s–1980s, which is now being addressed through implementation of an International Single Species Action Plan. A proposal to change enforcement regulations of the Migratory Bird Treaty Act in the United States is also of concern, as potentially undermining protection for Trumpeter Swans in North America, illustrating the importance of politics and legislation as well as on-the-ground measures for species conservation. Elsewhere, less is known about the trends and conservation status for swans in central and eastern Asia, though count and research programmes introduced in China, added to those underway in Japan and Korea, have recently greatly enhanced our knowledge of swan populations on the East Asian flyway. Trends for the Black Swan Cygnus atratus in Australia and for the Black-necked Swan Cygnus melancoryphus in South America are also poorly known, because of the large numbers involved for the former and a lack of coordinated counts across difficult terrain for the latter. These southern hemisphere species are considered vulnerable to water resource developments ( i.e . where diversion of water is shrinking wetlands), and to droughts associated with El Nino events and climate change. More extensive monitoring is therefore required to determine whether swan populations and species are stable, fluctuating or in decline.

Wildfowl

Developing spatially explicit footprints of plausible land-use scenarios in the Santa Cruz Watershed, Arizona and Sonora

The SLEUTH urban growth model is applied to a binational dryland watershed to envision and evaluate plausible future scenarios of land use change into the year 2050. Our objective was to create a suite of geospatial footprints portraying potential land use change that can be used to aid binational decision-makers in assessing the impacts relative to sustainability of natural resources and potential socio-ecological consequences of proposed land-use management. Three alternatives are designed to simulate different conditions: (i) a Current Trends Scenario of unmanaged exponential growth, (ii) a Conservation Scenario with managed growth to protect the environment, and (iii) a Megalopolis Scenario in which growth is accentuated around a defined international trade corridor. The model was calibrated with historical data extracted from a time series of satellite images. Model materials, methodology, and results are presented. Our Current Trends Scenario predicts the footprint of urban growth to approximately triple from 2009 to 2050, which is corroborated by local population estimates. The Conservation Scenario results in protecting 46% more of the Evergreen class (more than 150,000 acres) than the Current Trends Scenario and approximately 95,000 acres of Barren Land, Crops, Deciduous Forest (Mesquite Bosque), Grassland/Herbaceous, Urban/Recreational Grasses, and Wetlands classes combined. The Megalopolis Scenario results also depict the preservation of some of these land-use classes compared to the Current Trends Scenario, most notably in the environmentally important headwaters region. Connectivity and areal extent of land cover types that provide wildlife habitat were preserved under the alternative scenarios when compared to Current Trends.

Arizona;Sonora

Evaluation of a method for comparing phosphorus loads from barnyards and croplands in Otter Creek Watershed, Wisconsin

Control of phosphorus from rural nonpoint sources is a major focus of current efforts to improve and protect water resources in Wisconsin and is recommended in almost every priority watershed plan prepared for the State's Nonpoint Source (NFS) Program. Barnyards and crop- lands usually are identified as the primary rural sources of phosphorus. Numerous questions have arisen about which of these two sources to control and about the method currently being used by the NFS program to compare phosphorus loads from barnyards and croplands. To evaluate the method, the U.S. Geological Survey (USGS). in cooperation with the Wisconsin Department of Natural Resources, used phosphorus-load and sediment-load data from streams and phosphorus concentrations in soils from the Otter Creek Watershed (located in the Sheboygan River Basin: fig. 1) in conjunction with two computer-based models.

Wisconsin

Groundwater quality in the Columbia Plateau, Snake River Plain, and Oahu basaltic-rock and basin-fill aquifers in the Northwestern United States and Hawaii, 1992-2010

This assessment of groundwater-quality conditions of the Columbia Plateau, Snake River Plain, and Oahu for the period 1992&ndash;2010 is part of the U.S. Geological Survey&rsquo;s National Water Quality Assessment (NAWQA) program. It shows where, when, why, and how specific water-quality conditions occur in groundwater of the three study areas and yields science-based implications for assessing and managing the quality of these water resources. The primary aquifers in the Columbia Plateau, Snake River Plain, and Oahu are mostly composed of fractured basalt, which makes their hydrology and geochemistry similar. In spite of the hydrogeologic similarities, there are climatic differences that affect the agricultural practices overlying the aquifers, which in turn affect the groundwater quality. Understanding groundwater-quality conditions and the natural and human factors that control groundwater quality is important because of the implications to human health, the sustainability of rural agricultural economies, and the substantial costs associated with land and water management, conservation, and regulation. The principal regional aquifers of the Columbia Plateau, Snake River Plain, and Oahu are highly vulnerable to contamination by chemicals applied at the land surface; essentially, they are as vulnerable as many shallow surficial aquifers elsewhere. The permeable and largely unconfined character of principal aquifers in the Columbia Plateau, Snake River Plain, and Oahu allow water and chemicals to infiltrate to the water table despite depths to water commonly in the hundreds of feet. The aquifers are essentially unconfined over large areas, having few extensive clay layers to impede infiltration through permeable volcanic rock and alluvial sediments. Agriculture is intensive in all three study areas, and heavy irrigation has imposed large artificial flows of irrigation recharge that rival or exceed natural recharge rates. Fertilizers and pesticides applied at land surface are leached from soil and transported to deep water tables with the infiltrating irrigation recharge, resulting in a layer of degraded water quality overlying better quality regional groundwater beneath. This &ldquo;irrigation-recharge layer&rdquo; is best known on Oahu, where it has been studied since the 1960s; however, the extent of nitrate and pesticide contamination in the Columbia Plateau and Snake River Plain indicate that the same situation exists in those areas. Contamination from agricultural and urban activities is present not only at shallow depths in surficial materials of the three areas, but extends regionally in the deep, principal bedrock aquifers that are tapped for drinking water by domestic and public-supply wells. Naturally occurring constituents and nitrate concentrations above human-health benchmarks&mdash;Maximum Contaminant Levels (MCLs), and Health-Based Screening Levels (HBSLs)&mdash;were more common in the Columbia Plateau and the Snake River Plain than in Oahu. Concentrations of anthropogenic constituents (constituents related to human activities) above human-health benchmarks were more common in Oahu. Naturally occurring contaminants, such as arsenic and radon, may be present in groundwater at concentrations of potential concern for human health in relatively undeveloped settings that otherwise may not be perceived as susceptible to contamination. Even though the median depth to groundwater in Oahu is more than 300 feet, the common occurrence of anthropogenic compounds in groundwater indicates that Oahu has a high susceptibility to contamination. Nitrate concentrations in groundwater were above the national background concentrations of 1 milligram per liter (mg/L) in all three study areas. In the Columbia Plateau, nitrate exceeded the human-health benchmark of 10 mg/L in 20 percent of the wells sampled. In the Snake River Plain, nitrate exceeded the human-health benchmark of 10 mg/L in 3 percent of the wells sampled. Nitrate can persist in groundwater for years and even decades in the oxygen-rich groundwater of the Columbia Plateau and the Snake River Plain, so prudent groundwater protection measures are critical to protect drinking water resources by reducing nitrate leaching from the land surface. Nitrate logistic regression models indicated that areas with a high percentage of land in crops (such as potatoes or sugarcane) and soils with low amounts of organic matter are most likely to have elevated nitrate concentrations in the groundwater. Areas where agricultural activities were absent had much lower probabilities of detecting elevated nitrate concentrations. The Columbia Plateau had a much higher probability of having elevated nitrate concentrations, with most of the land area having greater than a 50 percent probability of elevated nitrate concentrations. Oahu and the Snake River Plain had a much lower probability of having elevated nitrate concentrations because of their lower percentage of agricultural land. Pesticides were detected at many sites in groundwater of the Columbia Plateau, Snake River Plain, and Oahu but generally at low concentrations below human-health benchmarks. Atrazine and its degradate (a compound produced from the breakdown of a parent pesticide), deethylatrazine, were the most commonly detected pesticides in groundwater sampled in the Columbia Plateau and Snake River Plain. Bromacil was the most commonly detected pesticide on Oahu. The other pesticides most commonly detected in the study areas include simazine, hexazinone, metribuzin, diuron, prometon, metolachlor, p,p&rsquo; -DDE, dieldrin, 2-4-D, and alachlor. DDE (a degradate of DDT) and dieldrin are still being detected in groundwater despite having been banned for more than 30 years. Codetection of multiple pesticides in water from a single well was common. The widespread occurrence of pesticides in groundwater in the study areas indicates that the groundwater is highly susceptible to pesticide contamination. Some pesticides were detected in groundwater samples from all three study areas, but other pesticides were detected only in samples from Oahu, or only in samples from the Columbia Plateau and Snake River Plain. This is because some pesticides (such as atrazine) are broad-spectrum pesticides that are used on many crops in many different areas of the United States. Other pesticides (such as simazine, metribuzin, and metolachlor) are used on row crops (such as potatoes, barley, and alfalfa) grown in the Columbia Plateau and Snake River Plain, but not on pineapple or sugarcane grown in Oahu. Atrazine logistic-regression models indicate that areas with a high percentage of land in crops (such as potatoes or sugarcane), a low percentage of fallow land, and highly permeable soils with low amounts of organic matter are most likely to have atrazine detected in the groundwater. Areas where agricultural activities were absent had much lower probabilities of atrazine being detected. The Snake River Plain had a much higher probability of atrazine detections, with more than 50 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu had a much lower probability of atrazine contamination, with only 24 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu and the Columbia Plateau had some of the highest percentages of soil fumigant detections in groundwater in the United States. Soil fumigants are volatile organic compounds (VOCs) used as pesticides, which are applied to soils to reduce populations of plant parasitic nematodes (harmful rootworms), weeds, fungal pathogens, and other soil-borne microorganisms. They are used in Oahu and the Columbia Plateau on crops such as pineapple and potatoes. All three areas (Columbia Plateau, Snake River Plain, and Oahu) had fumigant concentrations exceeding human-health benchmarks for drinking water.

Hawai'i, Idaho, Nevada, Oregon, Utah, Washington,

Ground-water age dating and other tools used to assess land-use effects on water quality

A relatively new method for age dating recent ground water along with other investigative tools improve our understanding of land-use effects on the water quality in a surficial aquifer and adjacent streams in the Red River of the North Basin: Ground water commonly takes more than 20 years to reach depths in the surficial aquifer where it is withdrawn for use. Water withdrawn from most drinking-water wells was recharged through land areas greater than 1 mile upgradient. Because of these long travel times and distances, land-management practices on the land and aquifer-protection strategies may take as much as 50 years to produce measurable improvement in water quality. The amount of fertilizer and some herbicides used to enhance crop growth in this study area can be related to the distribution and trends of nitrate and herbicides found in the surficial aquifer.

Red River of the North Basin

Review: Endophytic microbes and their potential applications in crop management

Endophytes are microbes (mostly bacteria and fungi) present in plants. Endophytic microbes are often functional in that they may carry nutrients from the soil into plants, modulate plant development, increase stress tolerance of plants, suppress virulence in pathogens, increase disease resistance in plants, and suppress development of competitor plant species. Endophytic microbes have been shown: 1) obtain nutrients in soils and transfer nutrients to plants in the rhizophagy cycle and other nutrient‐transfer symbioses; 2) increase plant growth and development; 3) reduce oxidative stress of hosts; 4) protect plants from disease; 5) deter feeding by herbivores; and 6) suppress growth of competitor plant species. Because of the effective functions of endophytic microbes, we suggest that endophytic microbes may significantly reduce use of agrochemicals (fertilizers, fungicides, insecticides, and herbicides) in the cultivation of crop plants. The loss of endophytic microbes from crop plants during domestication and long‐term cultivation could be remedied by transfer of endophytes from wild relatives of crops to crop species. Increasing atmospheric carbon dioxide levels could reduce the efficiency of the rhizophagy cycle due to repression of reactive oxygen used to extract nutrients from microbes in roots.

Pest Management Science

Water quality of the Flint River basin, Alabama and Tennessee, 1999-2000

The U.S. Geological Survey monitored eight stream sites in the Flint River Basin during the period January 1999 through May 2000, to characterize patterns in the occurrence of pesticides, fecal-indicator bacteria, and nutrients in relation to season and streamflow conditions and to land-use patterns. This study is part of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Every water sample collected from the Flint River Basin had detectable levels of at least two pesticides; 64 percent of the samples contained mixtures of at least five pesticides. In general, pesticides detected most frequently and at highest concentrations in streams corresponded to the pesticides with the highest rates of use in the watersheds. Detections of fluometuron, norflurazon, and atrazine were more frequent (by a margin of 15 percent or more) in samples from the Flint River when compared with the frequencies of pesticide detections at 62 agricultural stream sites across the Nation. Detections of fluometuron in the Flint River were more frequent even when compared with a cotton-cultivation subset of the 62 sites. For most pesticides, maximum concentrations did not exceed criteria to protect aquatic life; however, maximum concentrations of atrazine, cyanazine, and malathion exceeded aquaticlife criteria in at least one sample. Concentrations near or exceeding the aquatic-life criteria occurred only during the spring and summer (April-July), and generally occurred during storm flows. Less than 5 percent of the estimated mass of pesticides applied annually to agricultural areas in the Flint River Basin was transported to the stream at the monitoring points on the Flint River near Brownsboro, Alabama, and on Hester Creek near Plevna, Alabama. The pesticides with the highest ratios (greater than 3 percent) of the amount transported instream to the amount applied?atrazine, metolachlor, fluometuron, and norflurazon?are preemergent herbicides applied to the soil before the crops have emerged, which increases the probability of transport in surface runoff. Concentrations of the fecal-bacteria indicator Escherichia coli (E. coli) in the Flint River and Hester Creek exceeded the U.S. Environmental Protection Agency criterion for recreation in almost all storm samples, and in many samples collected up to 6 days following a storm. Concentrations in the Flint River were strongly correlated with sample turbidity, suggesting that turbidity might be useful as a surrogate for estimating E. coli concentrations. Concentrations of the nutrients nitrogen and phosphorus in samples from the Flint River generally exceeded thresholds indicating eutrophic potential, whereas concentrations in samples from Hester Creek were generally below the thresholds. When compared with nutrient data from a set of 24 agricultural basins across the southeastern region of the United States, concentrations in the Flint River and Hester Creek were slightly above the regional median. Base-flow concentrations of certain pesticides, nutrients, and E. coli were compared to land-use information for eight sites in the Flint River Basin. The highest base-flow concentrations of aldicarb sulfoxide, fluometuron, and phosphorus were found in the tributaries with the greatest density of cotton acreage in the watershed. Similarly, high base-flow concentrations of total nitrogen were correlated with a high percentage of cultivated land in the watershed. Lack of information about distribution of stream access by livestock weakened the analysis of correlation between livestock and base-flow concentrations of E. coli and nutrients. Input of dissolved and suspended chemicals from the Flint River during storms influences water quality in the reach of the Tennessee River from which the City of Huntsville, Alabama, withdraws about 40 percent of its drinking water. During the storm of April 2-5, 2000, concentrations of several pesticides were

Water-Resources Investigations Report

Dynamic replacement and loss of soil carbon on eroding cropland

Links between erosion/sedimentation history and soil carbon cycling were examined in a highly erosive setting in Mississippi loess soils. We sampled soils on (relatively) undisturbed and cropped hillslopes and measured C, N, 14 C, and CO 2 flux to characterize carbon storage and dynamics and to parameterize Century and spreadsheet 14 C models for different erosion and tillage histories. For this site, where 100 years of intensive cotton cropping were followed by fertilization and contour plowing, there was an initial and dramatic decline in soil carbon content from 1870 to 1950, followed by a dramatic increase in soil carbon. Soil erosion amplifies C loss and recovery: About 100% of the original, prehistoric soil carbon was likely lost over 127 years of intensive land use, but about 30% of that carbon was replaced after 1950. The eroded cropland was therefore a local sink for CO 2 since the 1950s. However, a net CO 2 sink requires a full accounting of eroded carbon, which in turn requires that decomposition rates in lower slopes or wetlands be reduced to about 20% of the upland value. As a result, erosion may induce unaccounted sinks or sources of CO 2 , depending on the fate of eroded carbon and its protection from decomposition. For erosion rates typical of the United States, the sink terms may be large enough (1 Gt yr −1 , back‐of‐the‐envelope) to warrant a careful accounting of site management, cropping, and fertilization histories, as well as burial rates, for a more meaningful global assessment.

Global Biogeochemical Cycles

The potential of fruit trees to enhance converted habitats for migrating birds in southern Mexico

Migration routes used by Nearctic migrant birds can cover great distances; they also differ among species, within species, and between years and seasons. As a result, migration routes for an entire migratory avifauna can encompass broad geographic areas, making it impossible to protect continuous stretches of habitat sufficient to connect the wintering and breeding grounds for most species. Consequently, ways to enhance habitats converted for human use (i.e. for pasture, crop cultivation, human settlement) as stopover sites for migrants are especially important. Shelterbelts around pastures and fields, if planted with species targeted to support migrant (and resident) bird species that naturally occupy mature forest habitats and that are at least partially frugivorous, could be a powerful enhancement tool for such species, if the birds will enter the converted areas to feed. I tested this approach for Nearctic migrant birds during the spring migration through an area in Chiapas, Mexico. Mature forest tree species whose fruits are eaten by birds were surveyed. Based on life form, crop size and fruit characteristics, I selected three tree species for study: Cymbopetalum mayanum (Annonaceae), Bursera simaruba (Burseraceae) and Trophis racemosa (Moraceae). I compared the use of fruits of these species by migrants and residents in forest with their use of the fruits of isolated individuals of the same species in pasture and cropland. All three plant species were useful for enhancing converted habitats for forest-occupying spring migrants, although species differed in the degree to which they entered disturbed areas to feed on the fruits. These tree species could probably enhance habitats for migrants at sites throughout the natural geographic ranges of the plants; in other geographic areas for other target bird groups, other tree species might be more appropriate.

Bird Conservation International

Characterization of the hydrogeology and water quality at the Management Systems Evaluation Area near Princeton, Minnesota, 1991-92

The Management Systems Evaluation Area (MSEA) program is part of a multi-scale, inter-agency initiative to evaluate the effects of agricultural management systems on water quality in the midwest corn belt. The Minnesota MSEA project is one of five projects selected to represent the principal hydrogeologic settings and geographic diversity of prevailing management systems in the midwest corn belt. The Minnesota MSEA research area is located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. The water-quality monitoring network within the 65-hectare research area consists of 29 observation wells and 22 multiport wells. Thirteen observation wells also are located outside the research area. Glacial deposits beneath the research area generally consist of fine to medium sand in the unsaturated zone and coarse to very coarse sand and gravel in the saturated zone. The average depth to the water table is about 3.6 meters below land surface. Ground-water recharge during 1992 was lower (4.9-13.2 centimeters) than during 1991 (11.7-25.7 centimeters) because of reduced precipitation (58.5 centimeters during 1992 and 94.5 centimeters during 1991). Estimates of saturated horizontal hydraulic conductivity for the surficial aquifer were made using five methods. Results were within about two orders of magnitude and also agree favorably with estimates from a previous study of the Anoka Sand Plain. The smallest hydraulic conductivities were obtained using laboratory analyses (0.0052 centimeters per second) and the largest estimate was obtained from results of an aquifer test (0.2820 centimeters per second). The estimate of hydraulic conductivity based on the time of travel of chloride (0.0655 centimeters per second) is considered most accurate and representative of the surficial aquifer in the research area. Anthropogenic effects of previous land use were detected in water samples collected during April 1991, prior to implementation of the MSEA farming systems. Concentrations of nitrate-nitrogen (nitrate-N) in the surficial aquifer equaled or exceeded the U.S. Environmental Protection Agency's recommended maximum contaminant level of 10 milligrams per liter (mg/L) in 4 of the 7 wells in the research area. The maximum concentration of nitrate-N in ground water from these wells was 23 mg/L with a median of 10 mg/L. The median concentration of nitrate-N for these wells exceeded the median in wells located upgradient from the research area (2.1 mg/L). Similarly, the median concentration of chloride from wells in the research area (11 mg/L) exceeded the median in upgradient wells (3.8 mg/L). On-site sources of the elevated nitrate-N include decomposition of alfalfa, grown on-site during 1981-89, and application of nitrogen fertilizer to corn during 1990. A likely on-site source of the elevated chloride is application of potassium-chloride fertilizer to crops prior to 1991. Atrazine was detected by gas chromatography mass spectroscopy in 2 of the 7 wells in the research area at concentrations of 0.04 and 0.17 micrograms per liter (ug/L), well below the U.S. Environmental Protection Agency's recommended maximum contaminant level of 3 ug/L. The median concentration in these Wells was less than the qualitative detection limit of 0.01 ug/L. Atrazine metabolite de-ethylatrazine was the most frequently detected herbicide or herbicide metabolite. De-ethylatrazine was detected in 5 of the 7 wells in the research area at concentrations ranging from 0.12 to 0.32 ug/L with a median concentration of 0.14 ug/L. Atrazine metabolite de-isopropylatrazine was not detected above the qualitative detection limit of 0.06 ug/L. The most likely sources of atrazine are applications to the research area during 1990 or from precipitation.

Minnesota

Continuous nitrate monitoring in groundwater and potential contribution to surface-water nitrogen loads in Mason County, Illinois

Illinois has some of the most productive farmland in the country. The use of fertilizers to improve crop production has increased, which has resulted in an increase in the concentration of nitrogen in many streams and aquifers. The U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, is continuously monitoring (one reading every 15 minutes) the concentration of nitrate plus nitrite, as nitrogen, in a groundwater well and assessing the potential contribution to surface-water nitrogen loads. Continuous monitoring of the nitrate concentration allows for the collection of a larger dataset in comparison to periodic or event-based sampling. This fact sheet describes the data collection methods, describes the overall experimental design, and displays data collected for the study. The analysis of continuous data improves understanding of the fate and transport of nitrate.

Illinois

Mangrove ecosystems: Importance, threats and opportunities for restoration

Mangroves are crucial for biodiversity conservation, coastal protection, and supporting local livelihoods. Mangroves may also protect coasts from storms and rising sea levels and can play a major role in climate mitigation. Threats to their health include activities such as infrastructural development, urban encroachment, aquaculture and crop farming, and oil and gas exploration. We review the threats and opportunities for the restoration of mangrove ecosystems on the coasts of Africa, which are highly impacted by oil spills. The most important challenge for mangrove restoration identified in this review is the restoration of appropriate hydrologic and salinity regimes prior to natural recruitment or the active planting of propagules.

Water