SEARCH · Geology Reports

Results for “Complexity”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3Linked to original sources

USGS2012

An axial view of a metamorphic core complex: Crustal structure of the Whipple and Chemehuevi Mountains, southeastern California

A 135‐km‐long, NW‐SE trending, seismic refraction/wide‐angle reflection profile provides a unique along‐strike view of the crustal structure of a belt of metamorphic core complexes in southeastern California: the Whipple, Chemehuevi, and Sacramento mountains metamorphic core complexes. Interpretation of the seismic data was done by two‐dimensional forward modeling of travel times and amplitudes. The final model consists of (1) a thin (< 1.5 km) veneer of upper plate and fractured lower plate rocks (velocities of 1.5–5.3 km s −1 ) overlying a fairly homogeneous basement with velocities of 6.0 km s −1 ; (2) a localized, high‐velocity (6.4 km s −1 ) body, situated directly beneath the Whipple Mountains; (3) a 6.3–6.4 km s −1 middle crust that is thickest beneath the core complexes; (4) a 6.65±0.15 km s −1 lower crust; (5) crustal thickness of 27 km with a deeper crustal root (3 km) beneath the Whipple Mountains metamorphic core complex; and (6) a P n velocity of 8.0±0.10 km s −1 . The crustal structure that underlies the belt of metamorphic core complexes provides new insights into the processes that control extension in the deep crust. Upper crustal velocities are higher beneath the Whipple Mountains (where velocities increase to 6.4 km s −1 at ∼5 km depth) than beneath the Chemehuevi and Sacramento mountains. In addition, midcrustal discontinuities rise 2–5 km beneath the Whipple complex compared to the other complexes. These observations support greater uplift and a slightly deeper midcrustal origin for the rocks now exposed in the core of the Whipple Mountains compared to rocks in the Chemehuevi and Sacramento mountains. Despite the enhanced uplift and extension in the Whipple Mountains, the crust is thicker here (30 km) than anywhere else along the Colorado River extensional corridor. This may be in part a relic of compressional and magmatic thickening during the Mesozoic. However, we suggest that inflation of the crust during Tertiary extension was the dominant mechanism. Both mantle‐derived magmatism and lateral ductile inflow in the crust are proposed.

Arizona, California↗

USGS2012

Anatomy of a metamorphic core complex: seismic refraction/wide-angle reflection profiling in southeastern California and western Arizona

The metamorphic core complex belt in southeastern California and western Arizona is a NW-SE trending zone of unusually large Tertiary extension and uplift. Midcrustal rocks exposed in this belt raise questions about the crustal thickness, crustal structure, and the tectonic evolution of the region. Three seismic refraction/wide-angle reflection profiles, acquired and analyzed as a part of the U.S. Geological Survey's Pacific to Arizona Crustal Experiment, were collected to address these issues. The results presented here, which focus on the Whipple and Buckskin-Rawhide mountains, yield a consistent three-dimensional image of this part of the metamorphic core complex belt. The seismic refraction/wide-angle reflection data are of excellent quality and are characterized by six principal phases that can be observed on all three profiles. These phases include refractions from the near-surface and crystalline basement, reflections from boundaries in the middle and lower crust, and reflections and refractions from the upper mantle. The final model consists of a thin veneer (<2 km) of upper plate and fractured lower plate rocks (1.5–5.5 km s−1 ) overlying a fairly homogeneous basement (∼6.0 km s −1 ) and a localized high-velocity (6.4 km s −1 ) body situated beneath the western Whipple Mountains. A prominent midcrustal reflection is identified beneath the Whipple and Buckskin-Rawhide mountains between 10 and 20 km depth. This reflector has an arch-like shape and is centered beneath, or just west of, the metamorphic core complex belt. This event is underlain by a weaker, approximately subhorizontal reflection at 24 km depth. Together, these two discontinuities define a lens-shaped midcrustal layer with a velocity of 6.35–6.5 km s −1 . The apex of this midcrustal layer corresponds roughly to a region of major tectonic denudation and uplift (∼10 km) defined by surface geologic mapping and petrologic barometry studies. The layer thins to the northeast and is absent in the Transition Zone. The 6.35–6.5 km s −1 velocities are compatible with a diorite composition or a mixture of mafic and silicic rocks. This midcrustal layer is underlain by a higher-velocity lower crustal layer that is modeled as only 3–6 km thick beneath the metamorphic core complex belt and regions to the southwest. To the northeast, however, this layer thickens to 8–10 km as the midcrustal layer pinches out above it. The velocity of the lower crust is constrained by traveltime modeling and is 6.6±0.15 kms −1 beneath the western Transition Zone and the metamorphic core complex belt; higher velocities may be present farther to the southwest where the layer is thin. The velocity of the lower crust is too low to accommodate significant amount of mafic underplating at the base of the crust. Instead, we interpret the velocities to indicate that the lower crust is passively thinned beneath these regions without significant addition of mafic mantle-derived intrusions. The crust-mantle boundary does not dome up beneath the core complexes but remains approximately subhorizontal at a depth of 26–28 km or, in the case of the Whipple Mountains, actually deepens; a 3-km crustal root is modeled. This lack of upward doming of the Moho, together with the vertical alignment of the metamorphic core complex belt over what are believed to be extension-related structures in the middle and lower crust, suggest that there is no lateral offset of upper crustal deformation from deeper zones of extension, as one would expect if extension occurred along crust-penetrating shear zones (Wernicke, 1981; Wernicke et al., 1985). Instead, domed and inflated middle crust and thinned lower crust directly underlie the region of greatest thinning of the upper crust.

Journal of Geophysical Research↗

USGS2002

Floristic quality assessment of one natural and three restored wetland complexes in North Dakota, USA

Floristic quality assessment is potentially an important tool for conservation efforts in the northern Great Plains of North America, but it has received little rigorous evaluation. Floristic quality assessments rely on coefficients assigned to each plant species of a region’s flora based on the conservatism of each species relative to others in the region. These “coefficients of conservatism” (C values) are assigned by a panel of experts familiar with a region’s flora. The floristic quality assessment method has faced some criticism due to the subjective nature of these assignments. To evaluate the effect of this subjectivity on floristic quality assessments, we performed separate evaluations of the native plant communities in a natural wetland complex and three restored wetland complexes. In our first assessment, we used C values assigned “subjectively” by the Northern Great Plains Floristic Quality Assessment Panel. We then performed an independent assessment using the observed distributions of species among a group of wetlands that ranged from highly disturbed to largely undisturbed (data-generated C values). Using the panel-assigned C values, mean C values ( C ¯ "> C ¯ C¯ ) of the restored wetlands rarely exceeded 3.4 and never exceeded 3.9, with the highest values occurring in the oldest restored complex; all but two wetlands in the natural wetland complex had a C ¯ "> C ¯ C¯ greater than 3.9. Floristic quality indices (FQI) for the restored wetlands rarely exceeded 22 and usually reached maximums closer to 19, with higher values occurring again in the oldest restored complex; only two wetlands in the natural complex had an FQI less than 22. We observed that 95% confidence limits for species richness and percent natives overlapped greatly among wetland complexes, whereas confidence limits for both C ¯ "> C ¯ C¯ and FQI overlapped little. C ¯ "> C ¯ C¯ and FQI values were consistently greater when we used the datagenerated C values than when we used the panel-assigned C values; nonetheless, conclusions reached based on these two independent assessment techniques were virtually identical. Our results are consistent with the opinion that coefficients assigned subjectively by expert botanists familiar with a region’s flora provide adequate information to perform accurate floristic quality assessments.

Wetlands↗

USGS2008

Coarse-clast ridge complexes of the Caribbean: A preliminary basis for distinguishing tsunami and storm-wave origins

Coastal gravel-ridge complexes deposited on islands in the Caribbean Sea are recorders of past extreme-wave events that could be associated with either tsunamis or hurricanes. The ridge complexes of Bonaire, Jamaica, Puerto Rico (Isla de Mona), and Guadeloupe consist of polymodal clasts ranging in size from sand to coarse boulders that are derived from the adjacent coral reefs or subjacent rock platforms. Ridge-complex morphologies and crest elevations are largely controlled by availability of sediments, clast sizes, and heights of wave runup. The ridge complexes are internally organized, display textural sorting and a broad range of ages including historical events. Some display seaward-dipping beds and ridge-and-swale topography, and some terminate in fans or steep avalanche slopes. Together, the morphologic, sedimentologic, lithostratigraphic, and chronostratigraphic evidence indicates that shore-parallet ridge complexes composed of gravel and sand that are tens of meters wide and several meters thick are primarily storm-constructed features that have accumulated for a few centuries or millennia as a result of multiple high-frequency intense-wave events. They are not entirely the result of one or a few tsunamis as recently reported. Tsunami deposition may account for some of the lateral ridge-complex accretion or boulder fields and isolated blocks that are associated with the ridge complexes. Copyright ?? 2008, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

USGS2003

Crustal structure in the Elko-Carlin Region, Nevada, during Eocene gold mineralization: Ruby-East Humboldt metamorphic core complex as a guide to the deep crust

The deep crustal rocks exposed in the Ruby - East Humboldt metamorphic core complex , northeastern Nevada , provide a guide for reconstructing Eocene crustal structure ∼50 km to the west near the Carlin trend of gold deposits. The deep crustal rocks, in the footwall of a west-dipping normal-sense shear system, may have underlain the Piñon and Adobe Ranges about 50 km to the west before Tertiary extension, close to or under part of the Carlin trend. Eocene lakes formed on the hanging wall of the fault system during an early phase of extension and may have been linked to a fluid reservoir for hydrothermal circulation. The magnitude and timing of Paleogene extension remain indistinct, but dikes and tilt axes in the upper crust indicate that spreading was east -west to northwest-southeast, perpendicular to a Paleozoic and Mesozoic orogen that the spreading overprinted. High geothermal gradients associated with Eocene or older crustal thinning may have contributed to hydrothermal circulation in the upper crust . Late Eocene eruptions, upper crustal dike intrusion, and gold mineralization approximately coincided temporally with deep intrusion of Eocene sills of granite and quartz diorite and shallower intrusion of the Harrison Pass pluton into the core - complex rocks. Stacked Mesozoic nappes of metamorphosed Paleozoic and Precambrian rocks in the core complex lay at least 13 to 20 km deep in Eocene time, on the basis of geobarometry studies. In the northern part of the complex , the presently exposed rocks had been even deeper in the late Mesozoic, to >30 km depths, before losing part of their cover by Eocene time. Nappes in the core plunge northward beneath the originally thicker Mesozoic tectonic cover in the north part of the core complex . Mesozoic nappes and tectonic wedging likely occupied the thickened midlevel crustal section between the deep crustal core - complex intrusions and nappes and the overlying upper crust . These structures, as well as the subsequent large-displacement Cenozoic extensional faulting and flow in the deep crust , would be expected to blur the expression of any regional structural roots that could correlate with mineral belts. Structural mismatch of the mineralized upper crust and the tectonically complex middle crust suggests that the Carlin trend relates not to subjacent deeply penetrating rooted structures but to favorable upper crustal host rocks aligned within a relatively coherent regional block of upper crust .

Nevada↗

USGS1999

The Silent Canyon caldera complex — A three-dimensional model based on drill-hole stratigraphy and gravity inversion

The structural framework of Pahute Mesa, Nevada, is dominated by the Silent Canyon caldera complex, a buried, multiple collapse caldera complex. Using the boundary surface between low density Tertiary volcanogenic rocks and denser granitic and weakly metamorphosed sedimentary rocks (basement) as the outer fault surfaces for the modeled collapse caldera complex, it is postulated that the caldera complex collapsed on steeply- dipping arcuate faults two, possibly three, times following eruption of at least two major ash-flow tuffs. The caldera and most of its eruptive products are now deeply buried below the surface of Pahute Mesa. Relatively low-density rocks in the caldera complex produce one of the largest gravity lows in the western conterminous United States. Gravity modeling defines a steep sided, cup-shaped depression as much as 6,000 meters (19,800 feet) deep that is surrounded and floored by denser rocks. The steeply dipping surface located between the low-density basin fill and the higher density external rocks is considered to be the surface of the ring faults of the multiple calderas. Extrapolation of this surface upward to the outer, or topographic rim, of the Silent Canyon caldera complex defines the upper part of the caldera collapse structure. Rock units within and outside the Silent Canyon caldera complex are combined into seven hydrostratigraphic units based on their predominant hydrologic characteristics. The caldera structures and other faults on Pahute Mesa are used with the seven hydrostratigraphic units to make a three-dimensional geologic model of Pahute Mesa using the "EarthVision" (Dynamic Graphics, Inc.) modeling computer program. This method allows graphic representation of the geometry of the rocks and produces computer generated cross sections, isopach maps, and three-dimensional oriented diagrams. These products have been created to aid in visualizing and modeling the ground-water flow system beneath Pahute Mesa.

Nevada↗

USGS2025

Land cover change within wetland complexes at Dixie Meadows, Churchill County, Nevada: 2015 – 2023

Dixie Meadows, Nevada, is a system of geothermal springs and seeps that feed a complex of marshes and wetland meadows that are located within lands managed by the Bureau of Land Management (BLM) and the Department of Defense (DOD). A previous U.S. Geological Survey report documented variability in satellite imagery-based land cover classifications for seven wetland complexes at near monthly time intervals between October 2015 and January 2022. This report presents additional data, extending analysis to November 2023. Land cover classifications between October 2015 and November 2023 demonstrated an association between vegetation cover characteristics and surface moisture, with Class 1 having dry, bare soil or sparse upland vegetation, Class 2 having moist, bare soil or sparse to small vegetation, Class 3 having dense green vegetation with potentially saturated soil conditions, Class 4 having a mix of shallow surface water, saturated soil, and dense green vegetation, and Class 5 having open surface water. Most of the wetland complexes occur close to spring outflows primarily within land managed by the DOD, though portions are also within BLM lands. The intervening and surrounding landscape outside of the wetland complexes assessed in this study are managed by the BLM. As a result, Class 1 land covers had the largest areal coverage for BLM managed lands. Classes 2 and 3 land covers were primarily mapped inside the wetland complexes and thus had the largest area coverage within DOD managed lands. Class 4 was almost exclusively mapped within the wetland complexes and thus was largely contained within DOD managed lands. Class 5 (open water) was exclusively mapped in and adjacent to a single wetland complex with catchment ponds on land managed by the BLM. The distribution of these land cover classes over the study period was seasonally and annually variable. Land cover areas of Classes 1 and 2 were larger during the spring months. Conversely, land cover areas of Classes 3 and 4 tended to be greatest during the summer or fall. These patterns might be influenced by differences in seasonal water sources and phenology.

Nevada↗

USGS1989

Mammals of the Braulio Carrillo- La Selva Complex, Costa Rica

Costa Rica's La Selva-Braulio Carrillo complex encompasses a 60-km protected corridor of Caribbean rain and cloud forest extending from 30 m at the La Selva Biological Station to 2,906 m at the top of Volcán Barva. The 52,000-ha complex covers four life zones and two transitional zones, including tropical wet forest, tropical wet forest cool-transition, tropical premontane wet-transition rain forest, tropical premontane rain forest, lower montane rain forest, and montane rain forest. Located in the northeastern part of the country, the area is representative of Central American Caribbean slope forests that extend from Mexico to Panama. The extensive elevational gradient of the complex provides protected habitat for a variety of altitudinal migrants. With support from the National Geographic Society and Rice Foundation, the Organization for Tropical Studies organized a biological survey of the complex in early 1986. The mammal team worked at six sites along the elevational transect established by the expedition: 300 m, 700 m, 1,000 m, 1,500 m, 2,050 m, and 2,600 m. We supplemented our collecting records with unpublished records made available by colleagues, records in the published literature, and specimens in museum collections. In addition, observations recorded by a variety of observers at the La Selva Biological Station are summarized. The mammal fauna of the complex comprises 142 species including 79 bats, 23 rodents, 15 carnivores, 7 marsupials, 6 edentates, 4 artiodactyls, 3 primates, 2 rabbits, 2 shrews, and 1 perissodactyl. At least 10 additional species are likely to occur there. The only species of mammal likely to have been extirpated from the area is the giant anteater. Recognizing the importance of the area to wildlife and to mankind in general, the government of Costa Rica added 13,500 ha to the complex on 13 April 1986. This area, previously known as the “Zona Protectora,” provided the mid-elevational link between the lowlands of the La Selva Biological Station and the montane forests of Braulio Carrillo National Park. Unfortunately, destruction of the rain forests surrounding the complex will soon render it an isolated island of protected forest. Thus, the area will become increasingly valuable as a refuge for many species with home ranges that require extensive tracts of undisturbed habitat.

North American Fauna↗

USGS2014

Accuracy of travel time distribution (TTD) models as affected by TTD complexity, observation errors, and model and tracer selection

Analytical models of the travel time distribution (TTD) from a source area to a sample location are often used to estimate groundwater ages and solute concentration trends. The accuracies of these models are not well known for geologically complex aquifers. In this study, synthetic datasets were used to quantify the accuracy of four analytical TTD models as affected by TTD complexity, observation errors, model selection, and tracer selection. Synthetic TTDs and tracer data were generated from existing numerical models with complex hydrofacies distributions for one public-supply well and 14 monitoring wells in the Central Valley, California. Analytical TTD models were calibrated to synthetic tracer data, and prediction errors were determined for estimates of TTDs and conservative tracer (NO 3 −) concentrations. Analytical models included a new, scale-dependent dispersivity model (SDM) for two-dimensional transport from the watertable to a well, and three other established analytical models. The relative influence of the error sources (TTD complexity, observation error, model selection, and tracer selection) depended on the type of prediction. Geological complexity gave rise to complex TTDs in monitoring wells that strongly affected errors of the estimated TTDs. However, prediction errors for NO3− and median age depended more on tracer concentration errors. The SDM tended to give the most accurate estimates of the vertical velocity and other predictions, although TTD model selection had minor effects overall. Adding tracers improved predictions if the new tracers had different input histories. Studies using TTD models should focus on the factors that most strongly affect the desired predictions.

California↗

USGS1982

Genetic implications of minor-element and Sr-isotope geochemistry of alkaline rock complexes in the Wet Mountains area, Fremont and Custer counties, Colorado

Concentrations of Rb, Sr, and REE (rare earth elements), and Sr-isotopic ratios in rocks of the Cambrian alkaline complexes in the Wet Mountains area, Colorado, show that rocks formed as end-products of a variety of magmas generated from different source materials. The complexes generally contain a bimodal suite of cumulus mafic-ultramafic rocks and younger leucocratic rocks that include nepheline syenite and hornblende-biotite syenite in the McClure Mountain Complex, nepheline syenite pegmatite in the Gem Park Complex, and quartz syenite in the complex at Democrat Creek. The nepheline syenite and hornblende-biotite syenite at McClure Mountain (535??5m.y.) are older than the syenitic rocks at Democrat Creek (511??8m.y.). REE concentrations indicate that the nepheline syenite at McClure Mountain cannot be derived from the hornblende-biotite syenite, which it intrudes, or from the associated mafic-ultramafic rocks. REE also indicate that mafic-ultramafic rocks at McClure Mountain have a source distinct from that of the mafic-ultramafic rocks at Democrat Creek. In the McClure Mountain Complex, initial87Sr/86Sr ratios for mafic-ultramafic rocks (0.7046??0.0002) are similar to those of hornblende-biotite syenite (0.7045??0.0002), suggesting a similar magmatic source, whereas ratios for carbonatites (0.7038??0.0002) are similar to those of nepheline syenite (0.7038??0.0002). At Democrat Creek, initial ratios of syenitic rocks (0.7032??0.0002) and mafic-ultramafic rocks (0.7028??0.0002) are different from those of corresponding rocks at McClure Mountain. ?? 1982 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2012

Local and landscape associations between wintering dabbling ducks and wetland complexes in Mississippi

Landscape features influence distribution of waterbirds throughout their annual cycle. A conceptual model, the wetland habitat complex, may be useful in conservation of wetland habitats for dabbling ducks (Anatini). The foundation of this conceptual model is that ducks seek complexes of wetlands containing diverse resources to meet dynamic physiological needs. We included flooded croplands, wetlands and ponds, public-land waterfowl sanctuary, and diversity of habitats as key components of wetland habitat complexes and compared their relative influence at two spatial scales (i.e., local, 0.25-km radius; landscape, 4-km) on dabbling ducks wintering in western Mississippi, USA during winters 2002–2004. Distribution of mallard ( Anas platyrhynchos ) groups was positively associated with flooded cropland at local and landscape scales. Models representing flooded croplands at the landscape scale best explained occurrence of other dabbling ducks. Habitat complexity measured at both scales best explained group size of other dabbling ducks. Flooded croplands likely provided food that had decreased in availability due to conversion of wetlands to agriculture. Wetland complexes at landscape scales were more attractive to wintering ducks than single or structurally simple wetlands. Conservation of wetland complexes at large spatial scales (≥5,000 ha) on public and private lands will require coordination among multiple stakeholders.

Mississippi↗

USGS2009

The structure and stability of aqueous rare-earth elements in hydrothermal fluids: New results on neodymium(III) aqua and chloroaqua complexes in aqueous solutions to 500 °C and 520 MPa

X-ray absorption spectroscopy (XAS) measurements were made at the Nd L3-edge on neodymium(III) aqua and chloroaqua complexes in low pH aqueous solutions from 25 to 500????C and up to 520??MPa. Analysis of the extended X-ray absorption fine structure of the XAS spectra measured from a 0.07??m Nd/0.16??m HNO3 aqueous solution reveals a contraction of the Nd-O distance of the Nd3+ aqua ion at a uniform rate of ~ 0.013????/100????C and a uniform reduction of the number of coordinated H2O molecules from 10.0 ?? 0.9 to 7.4 ?? 0.9 over the range from 25 to 500????C and up to 370??MPa. The rate of reduction of the first-shell water molecules with temperature for Nd3+ (26%) is intermediate between the rate for the Gd3+ aqua ion (22% from 25 to 500????C) and the rates for the Eu3+ (29% from 25 to 400????C) and the Yb3+ aqua ions (42% from 25 to 500????C) indicating an intermediate stability of the Nd3+ aqua ion consistent with the tetrad effect. Nd L3-edge XAS measurements of 0.05??m NdCl3 aqueous solution at 25 to 500????C and up to 520??MPa show that stepwise inner-sphere complexes most likely of the type Nd(H2O)?? - nCln+3 - n occur in the solution at elevated temperatures, where ?? ??? 9 at 150????C decreasing to ~ 6 at 500????C and the number of chloride ions (n) of the chloroaqua complexes increases uniformly with temperature from 1.2 ?? 0.2 to 2.0 ?? 0.2 in the solution upon increase of temperature from 150 to 500????C. Conversely, the number of H2O ligands of Nd(H2O)?? - nCln+3 - n complexes is uniformly reduced with temperature from 7.5 ?? 0.8 to 3.7 ?? 0.3 in the aqueous solution, in the same temperature range. These data show greater stability of neodymium(III) than gadolinium(III) and ytterbium(III) chloride complexes in low pH aqueous solutions at elevated temperatures. Our data suggest a greater stability of aqueous light REE than that of heavy REE chloride complexes in low pH fluids at elevated temperatures consistent with REE analysis of fluids from deep-sea hydrothermal vents. ?? 2008 Elsevier B.V.

Chemical Geology↗

USGS2025

Contrasting long-term trends in channel width and shoreline complexity

Drought and reservoir management in the Colorado River Watershed have decreased peak flows and sediment loads reducing the ability of rivers to change their channels. Multiple studies have documented the resulting decrease in channel width, but less attention has been paid to long-term trends in shoreline complexity, including the number and size of islands. We used a sequence of aerial photographs and satellite images collected in 13 different years to measure decadal trends in channel complexity in Gray Canyon along the Green River, Utah. We quantified channel width and shoreline complexity for each year of available imagery. Between 1938 and 2021 peak flows decreased by 34% and channel width decreased by 18% confirming observations elsewhere in the system of decreasing width in response to decreasing flows. Over the same period, however, shoreline complexity increased by 5.5% and the number of islands almost tripled, indicating that merging of islands into the encroaching floodplain was outpaced by formation and growth of new islands. The increase in shoreline complexity occurred between 1938 and 2006. Since 2006 there has been no further net increase, suggesting that room for new island formation may now be limited in the narrower channel. Sequences of channel delineations already mapped to quantify long-term changes in channel width at other sites could easily be used to determine whether the increases in shoreline complexity we observed at Gray Canyon are matched elsewhere.

Colorado, Utah, Wyoming↗

USGS2021

Geometry of the Bushveld Complex from 3D potential field modelling

A full three-dimensional (3D) potential field model of the central and southern Bushveld Complex reveals information about the Complex in areas obscured by younger geological cover. Previously, two-dimensional gravity models and a few magnetic models limited to certain sections of the Bushveld Complex have been used to propose geometries for the Rustenburg Layered Suite, especially in the western and eastern lobes. These models were often used to support different emplacement models. Although these models provided valuable information, two-and-a-half-dimensional (2.5D) potential field modelling is not well suited to modelling complex 3D geology. Also, in most cases, only the magnetic or gravity data were modelled, but jointly modelling both data sets better constrains the results, as was shown recently for a 3D model of the northern lobe. Joint 3D modelling of regional gravity and magnetic data combined with published crustal thickness models derived from broadband seismic tomography studies and constrained by density and susceptibility data, geologic mapping, boreholes and seismic reflection data were used to create a 3D model of the central and southeastern sections of the Bushveld Complex, as well as the southern part of the northern lobe. The model shows a complex geometry with thick continuous Rustenburg Layered Suite S in most of the western and southeastern lobes, but less continuous Rustenburg Layered Suite in the eastern lobe. Large domes or thick granites and granophyre in the latter interrupt the continuity of the Rustenburg Layered Suite and the western and eastern lobes are strictly speaking only partially connected in places. However, they are not separate intrusions, but one disconnected by pre-existing and synmagmatic updoming. Three possible feeders were modelled in the northern, western, and south-eastern lobes.

Precambrian Research↗

USGS2000

Characterization of U(VI)-carbonato ternary complexes on hematite: EXAFS and electrophoretic mobility measurements

We have measured U(VI) adsorption on hematite using EXAFS spectroscopy and electrophoresis under conditions relevant to surface waters and aquifers (0.01 to 10 μM dissolved uranium concentrations, in equilibrium with air, pH 4.5 to 8.5). Both techniques suggest the existence of anionic U(VI)-carbonato ternary complexes. Fits to EXAFS spectra indicate that U(VI) is simultaneously coordinated to surface FeO 6 octahedra and carbonate (or bicarbonate) ligands in bidentate fashions, leading to the conclusion that the ternary complexes have an inner-sphere metal bridging (hematite-U(VI)-carbonato) structure. Greater than or equal to 50% of adsorbed U(VI) was comprised of monomeric hematite-U(VI)-carbonato ternary complexes, even at pH 4.5. Multimeric U(VI) species were observed at pH ≥ 6.5 and aqueous U(VI) concentrations approximately an order of magnitude more dilute than the solubility of crystalline β-UO 2 (OH) 2 . Based on structural constraints, these complexes were interpreted as dimeric hematite-U(VI)-carbonato ternary complexes. These results suggest that Fe-oxide-U(VI)-carbonato complexes are likely to be important transport-limiting species in oxic aquifers throughout a wide range of pH values.

Geochimica et Cosmochimica Acta↗

USGS1999

Kinematic analysis of melange fabrics: Examples and applications from the McHugh Complex, Kenai Peninsula, Alaska

Permian to Cretaceous melange of the McHugh Complex on the Kenai Peninsula, south-central Alaska includes blocks and belts of graywacke, argillite, limestone, chert, basalt, gabbro, and ultramafic rocks, intruded by a variety of igneous rocks. An oceanic plate stratigraphy is repeated hundreds of times across the map area, but most structures at the outcrop scale extend lithological layering. Strong rheological units occur as blocks within a matrix that flowed around the competent blocks during deformation, forming broken formation and melange. Deformation was noncoaxial, and disruption of primary layering was a consequence of general strain driven by plate convergence in a relatively narrow zone between the overriding accretionary wedge and the downgoing, generally thinly sedimented oceanic plate. Soft-sediment deformation processes do not appear to have played a major role in the formation of the melange. A model for deformation at the toe of the wedge is proposed in which layers oriented at low angles to ??1 are contracted in both the brittle and ductile regimes, layers at 30-45??to ??1 are extended in the brittle regime and contracted in the ductile regime, and layers at angles greater than 45??to ??1 are extended in both the brittle and ductile regimes. Imbrication in thrust duplexes occurs at deeper levels within the wedge. Many structures within melange of the McHugh Complex are asymmetric and record kinematic information consistent with the inferred structural setting in an accretionary wedge. A displacement field for the McHugh Complex on the lower Kenai Peninsula includes three belts: an inboard belt of Late Triassic rocks records west-to-east-directed slip of hanging walls, a central belt of predominantly Early Jurassic rocks records north-south directed displacements, and Early Cretaceous rocks in an outboard belt preserve southwest-northeast directed slip vectors. Although precise ages of accretion are unknown, slip directions are compatible with inferred plate motions during the general time frame of accretion of the McHugh Complex. The slip vectors are interpreted to preserve the convergence directions between the overriding and underriding plates, which became more oblique with time. They are not considered indicative of strain partitioning into belts of orogen-parallel and orogen-perpendicular displacements, because the kinematic data are derived from the earliest preserved structures, whereas fabrics related to strain partitioning would be expected to be superimposed on earlier accretion-related fabrics.Permian to Cretaceous melange of the McHugh Complex on the Kenai Peninsula, south-central Alaska includes blocks and belts of graywacke, argillite, limestone, chert, basalt, gabbro, and ultramafic rocks, intruded by a variety of igneous rocks. An oceanic plate stratigraphy is repeated hundreds of times across the map area, but most structures at the outcrop scale extend lithological layering. Strong rheological units occur as blocks within a matrix that flowed around the competent blocks during deformation, forming broken formation and melange. Deformation was noncoaxial, and disruption of primary layering was a consequence of general strain driven by plate convergence in a relatively narrow zone between the overriding accretionary wedge and the downgoing, generally thinly sedimented oceanic plate. Soft-sediment deformation processes do not appear to have played a major role in the formation of the melange. A model for deformation at the toe of the wedge is proposed in which layers oriented at low angles to ??1 are contracted in both the brittle and ductile regimes, layers at 30-45?? to ??1 are extended in the brittle regime and contracted in the ductile regime, and layers at angles greater than 45?? to ??1 are extended in both the brittle and ductile regimes. Imbrication in thrust duplexes occurs at deeper levels within the wedge. Many structures within melange of the McHugh Complex are asymmetric and record

Journal of Structural Geology↗

USGS2002

Simulation of the mobility of metal-EDTA complexes in groundwater: The influence of contaminant metals

Reactive transport simulations were conducted to model chemical reactions between metal−EDTA (ethylenediaminetetraacetic acid) complexes during transport in a mildly acidic quartz−sand aquifer. Simulations were compared with the results of small-scale tracer tests wherein nickel−, zinc−, and calcium−EDTA complexes and free EDTA were injected into three distinct chemical zones of a plume of sewage-contaminated groundwater. One zone had a large mass of adsorbed, sewage-derived zinc; one zone had a large mass of adsorbed manganese resulting from mildly reducing conditions created by the sewage plume; and one zone had significantly less adsorbed manganese and negligible zinc background. The chemical model assumed that the dissolution of iron(III) from metal−hydroxypolymer coatings on the aquifer sediments by the metal−EDTA complexes was kinetically restricted. All other reactions, including metal−EDTA complexation, zinc and manganese adsorption, and aluminum hydroxide dissolution were assumed to reach equilibrium on the time scale of transport; equilibrium constants were either taken from the literature or determined independently in the laboratory. A single iron(III) dissolution rate constant was used to fit the breakthrough curves observed in the zone with negligible zinc background. Simulation results agreed well with the experimental data in all three zones, which included temporal moments derived from breakthrough curves at different distances downgradient from the injections and spatial moments calculated from synoptic samplings conducted at different times. Results show that the tracer cloud was near equilibrium with respect to Fe in the sediment after 11 m of transport in the Zn-contaminated region but remained far from equilibrium in the other two zones. Sensitivity studies showed that the relative rate of iron(III) dissolution by the different metal−EDTA complexes was less important than the fact that these reactions are rate controlled. Results suggest that the published solubility for ferrihydrite reasonably approximates the Fe solubility of the hydroxypolymer coatings on the sediments. Aluminum may be somewhat more soluble than represented by the equilibrium constant for gibbsite, and its dissolution may be rate controlled when reacting with Ca−EDTA complexes.

Environmental Science & Technology↗

USGS1999

Spectroscopic confirmation of uranium(VI)-carbonato adsorption complexes on hematite

Evaluating societal risks posed by uranium contamination from waste management facilities, mining sites, and heavy industry requires knowledge about uranium transport in groundwater, often the most significant pathway of exposure to humans. It has been proposed that uranium mobility in aquifers may be controlled by adsorption of U(VI)−carbonato complexes on oxide minerals. The existence of such complexes has not been demonstrated, and little is known about their compositions and reaction stoichiometries. We have used attenuated total reflectance Fourier transform infrared (ATR-FTIR) and extended X-ray absorption fine structure (EXAFS) spectroscopies to probe the existence, structures, and compositions of ≡FeO surface −U(VI)−carbonato complexes on hematite throughout the pH range of uranyl uptake under conditions relevant to aquifers. U(VI)−carbonato complexes were found to be the predominant adsorbed U(VI) species at all pH values examined, a much wider pH range than previously postulated based on analogy to aqueous U(VI)−carbonato complexes, which are trace constituents at pH < 6. This result indicates the inadequacy of the common modeling assumption that the compositions and predominance of adsorbed species can be inferred from aqueous species. By extension, adsorbed carbonato complexes may be of major importance to the groundwater transport of similar actinide contaminants such as neptunium and plutonium.

Environmental Science & Technology↗