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USGS2019

Unprocessed atmospheric nitrate in waters of the Northern Forest Region in the USA and Canada

Little is known about the regional extent and variability of nitrate from atmospheric deposition that is transported to streams without biological processing in forests. We measured water chemistry and isotopic tracers (δ 18 O and δ 15 N) of nitrate sources across the Northern Forest Region of the U.S. and Canada and reanalyzed data from other studies to determine when, where, and how unprocessed atmospheric nitrate was transported in catchments. These inputs were more widespread and numerous than commonly recognized, but with high spatial and temporal variability. Only 6 of 32 streams had high fractions (>20%) of unprocessed atmospheric nitrate during baseflow. Seventeen had high fractions during stormflow or snowmelt, which corresponded to large fractions in near-surface soil waters or groundwaters, but not deep groundwater. The remaining 10 streams occasionally had some (<20%) unprocessed atmospheric nitrate during stormflow or baseflow. Large, sporadic events may continue to be cryptic due to atmospheric deposition variation among storms and a near complete lack of monitoring for these events. A general lack of observance may bias perceptions of occurrence; sustained monitoring of chronic nitrogen pollution effects on forests with nitrate source apportionments may offer insights needed to advance the science as well as assess regulatory and management schemes.

Environmental Science and Technology↗

USGS2000

Atmospheric deposition and watershed nitrogen export along an elevational gradient in the Catskill Mountains, New York

Cumulative effects of atmospheric N deposition may increase N export from watersheds and contribute to the acidification of surface waters, but natural factors (such as forest productivity and soil drainage) that affect forest N cycling can also control watershed N export. To identify factors that are related to stream-water export of N, elevational gradients in atmospheric deposition and natural processes were evaluated in a steep, first-order watershed in the Catskill Mountains of New York, from 1991 to 1994. Atmospheric deposition of SO4/2-, and probably N, increased with increasing elevation within this watershed. Stream-water concentrations of SO4/2- increased with increasing elevation throughout the year, whereas stream-water concentrations of NO3/- decreased with increasing elevation during the winter and spring snowmelt period, and showed no relation with elevation during the growing season or the fall. Annual export of N in stream water for the overall watershed equaled 12% to 17% of the total atmospheric input on the basis of two methods of estimation. This percentage decreased with increasing elevation, from about 25% in the lowest subwatershed to 7% in the highest subwatershed; a probable result of an upslope increase in the thickness of the surface organic horizon, attributable to an elevational gradient in temperature that slows decomposition rates at upper elevations. Balsam fir stands, more prevalent at upper elevations than lower elevations, may also affect the gradient of subwatershed N export by altering nitrification rates in the soil. Variations in climate and vegetation must be considered to determine how future trends in atmospheric deposition will effect watershed export of nitrogen.

Biogeochemistry↗

USGS1999

Retention of an atmosphere on early Mars

The presence of valley networks and indications of high erosion rates in ancient terrains on Mars suggest that Mars was warm and wet during heavy bombardment. Various processes that could occur on early Mars were integrated into a self-consistent model to determine what circumstances might lead to warm temperatures during and at the end of heavy bombardment. Included were weathering and burial of CO 2 as carbonates, impact erosion, sputtering, and recycling of CO 2 back into the atmosphere by burial and heating. The models suggest that despite losses from the atmosphere by weathering and impact erosion, Mars could retain a 0.5 to 1 bar atmosphere at the end of heavy bombardment partly because weathering temporarily sequesters CO 2 in the ground and protects it from impact erosion while the impact rate is declining and impact erosion is becoming less effective. Because of the low output of the early Sun, surface temperatures can be above freezing only for a very efficient greenhouse, such as that suggested by Forget and Pierrehumbert [1997]. With weak greenhouse models, temperatures are below freezing throughout heavy bombardment, and such a large amount of CO 2 is left in the atmosphere at the end of heavy bombardment that it is difficult to eliminate subsequently to arrive at the present surface inventory. With strong greenhouse models, temperatures are well above freezing during heavy bombardment and drop to close to freezing at the end of heavy bombardment, at which time the atmosphere contains 0.5 to 1 bar of CO 2 . This can be largely eliminated subsequently by sputtering and low-temperature weathering. Such a model is consistent with the change in erosion rate and the declining rate of valley formation at the end of heavy bombardment. Conditions that favor warm temperatures at the end of heavy bombardment are an efficient greenhouse, low weathering rates, low impact erosion rates, and a smaller fraction of heat lost by conduction as opposed to transport of lava to the surface.

Journal of Geophysical Research E: Planets↗

USGS2001

Use of 17 O/ 16 O to trace atmospherically-deposited sulfate in surface waters: A case study in alpine watersheds in the Rocky Mountains

Building on the discovery of excess 17 O in atmospheric sulfate by Lee et al. (2001), we have carried out a case study to determine whether 17 O might provide a new tool for quantifying the impact of atmospheric deposition on surface-water sulfate loads. In Rocky Mountain alpine regions, excess 17 O was found to be characteristics of atmospheric sulfate deposited in snow. Excess 17 O was also evident in stream sulfate in one of two high-elevation watersheds where analyses were made. Isotope mass balance calculations gave surprizingly low atmospheric contributions to stream sulfate suggesting that (1) despite abundant outcrop and sparse soil in these areas, significant sulfate may be taken up and released by soil microbes before being exported in streams, and (2) surface waters can carry multiple non-atmospheric sulfate types, some possibly anthropogenic. Measurements of 17 O may prove very useful in studies of sulfate behavior in a variety of surficial environments.

Geophysical Research Letters↗

USGS2011

Mars atmospheric surface interactions and the CO2 cycle

Mars' northern and southern seasonal polar caps are formed during their respective autumn and winter seasons both by condensation of atmospheric carbon dioxide (CO 2 ) directly onto the surface, and through atmospheric precipitation in the form of CO 2 snow. During the polar spring and summer, the seasonal ice sublimes, returning CO 2 to the atmosphere. Roughly 25% of the atmosphere, which is 95% CO 2 by volume, is cycled through the seasonal caps annually. This CO 2 cycle dominates atmospheric circulation on Mars and must be thoroughly understood before the fundamental questions about Mars' climate history and the global distribution of near‐surface water can be addressed.

Eos, Transactions, American Geophysical Union↗

USGS2013

Contributions of atmospheric nitrogen deposition to U.S. estuaries: Summary and conclusions: Chapter 8

A NOAA project was initiated in 1998, with support from the U.S. EPA, to develop state-of-the-art estimates of atmospheric N deposition to estuarine watersheds and water surfaces and its delivery to the estuaries. Work groups were formed to address N deposition rates, indirect (from the watershed) yields from atmospheric and other anthropogenic sources, and direct deposition on the estuarine waterbodies, and to evaluate the levels of uncertainty within the estimates. Watershed N yields were estimated using both a land-use based process approach and a national (SPARROW) model, compared to each other, and compared to estimates of N yield from the literature. The total N yields predicted by the national model were similar to values found in the literature and the land-use derived estimates were consistently higher. Atmospheric N yield estimates were within a similar range for the two approaches, but tended to be higher in the land-use based estimates and were not wellcorrelated. Median atmospheric N yields were around 15% of the total N yield for both groups, but ranged as high as 60% when both direct and indirect deposition were considered. Although not the dominant source of anthropogenic N, atmospheric N is, and will undoubtedly continue to be, an important factor in culturally eutrophied estuarine systems, warranting additional research and management attention.

Book chapter↗

USGS2026

Shifting winter atmospheric teleconnections to the North Pacific reconcile Younger-Dryas and Holocene δ18O signals

Using Alaskan lake sediment oxygen isotope records (δ 18 O), which trace the δ 18 O of precipitation, we establish that abrupt atmospheric shifts occurred during the last deglacial period in the North Pacific-Arctic. The robust lake δ 18 O chronologies confidently correlate Younger-Dryas (YD) atmospheric adjustments in Alaska with Greenland ice-core records and their seasonal sensitivity are consistent with cooling during winter. In contrast, abrupt δ 18 O decreases during the late Holocene observed in our records, of similar magnitude as the YD, are best explained by atmospheric modes involving long-distance transport of sub-tropical Pacific moisture. Our sediment cores are among the most reliably dated records yet produced in the circum-Arctic and show that similar decreases in δ 18 O of winter precipitation during the YD and late Holocene were driven by different atmospheric teleconnections. These results underscore major roles for seasonality and atmospheric patterns in the conceptual understanding of global scale climate oscillations, both past and future.

Alaska↗

USGS2019

Emerging investigator series: Atmospheric cycling of indium in the northeastern United States

Indium is critical to the global economy and is used in an increasing number of electronics and new energy technologies. However, little is known about its environmental behavior or impacts, including its concentrations or cycling in the atmosphere. This study determined indium concentrations in air particulate matter at five locations across the northeastern United States over the course of one year, in 1995. Historical records from a Massachusetts bog core showed that indium atmospheric concentrations in this region changed only modestly between 1995 and 2010. Atmospheric indium concentrations varied significantly both geographically and temporally, with average concentrations in PM 3 of 2.1 ± 1.6 pg m −3 (1 standard deviation), and average particle-normalized concentrations of 0.2 ± 0.2 μg In per g PM 3 . Peaks in the particle-normalized concentrations in two New York sites were correlated with wind direction; air coming from the north contributed higher concentrations of indium than air coming from the west. This correlation, along with measurements of indium in zinc smelter emissions and coal fly ash, suggests that indium in the atmosphere in the northeastern United States comes from a relatively constant low-level input from coal combustion in the midwest, and higher but more sporadic contributions from the smelting of lead, zinc, copper, tin, and nickel north of the New York sample sites. Understanding the industrial sources of indium to the atmosphere and how they compare with natural sources can lead to a better understanding of the impact of human activities on the indium cycle, and may help to establish a baseline for monitoring future impacts as indium use grows.

Massachusetts, New York↗

USGS2021

Modelling tilt noise caused by atmospheric processes at long periods for several horizontal seismometers at BFO—A reprise

Tilting of the ground due to loading by the variable atmosphere is known to corrupt very long period horizontal seismic records (below 10 mHz) even at the quietest stations. At BFO (Black Forest Observatory, SW-Germany), the opportunity arose to study these disturbances on a variety of simultaneously operated state-of-the-art broad-band sensors. A series of time windows with clear atmospherically caused effects was selected and attempts were made to model these ‘signals’ in a deterministic way. This was done by simultaneously least-squares fitting the locally recorded barometric pressure and its Hilbert transform to the ground accelerations in a bandpass between 100 and 3600 s periods. Variance reductions of up to 97 per cent were obtained. We show our results by combining the ‘specific pressure induced accelerations’ for the two horizontal components of the same sensor as vectors on a horizontal plane, one for direct pressure and one for its Hilbert transform. It turned out that at BFO the direct pressure effects are large, strongly position dependent and largely independent of atmospheric events for instruments installed on piers, while three post-hole sensors are only slightly affected. The infamous ‘cavity effects’ are invoked to be responsible for these large effects on the pier sensors. On the other hand, in the majority of cases all sensors showed very similar magnitudes and directions for the vectors obtained for the regression with the Hilbert transform, but highly variable from event to event especially in direction. Therefore, this direction most certainly has to do with the gradient of the pressure field moving over the station which causes a larger scale deformation of the crust. The observations are very consistent with these two fundamental mechanisms of how fluctuations of atmospheric surface pressure causes tilt noise. The results provide a sound basis for further improvements of the models for these mechanisms. The methods used here can already help to reduce atmospherically induced noise in long-period horizontal seismic records.

Geophysical Journal International↗

USGS2023

Atmospheric correction intercomparison of hyperspectral and multispectral imagery over agricultural study sites

In this research effort we assess the performance of atmospheric correction-based surface reflectance (SR) retrievals from two satellite image sources, one with very high spatial resolution (VHR) (<5-m) and the other high spectral resolution (~10-nm). The VHR images are from MAXARs WorldView-3 (WV3) satellite and the high spectral resolution images are from Agenzia Spaziale Italianas (ASI) PRecursore IperSpettrale della Missione Applicativa (PRISMA) satellite. We use various atmospheric correction (AC) tools to provide intercomparisons of both AC tools and image source SR estimates. The AC tools we evaluated include Fast Line-of-sight Atmospheric Analysis of Hypercubes (FLAASH) within ENVI version 4.7, MODerate resolution atmospheric TRANsmission (MODTRAN) versions 5.3.3 and 6.0, and ASIs Level-2D correction for PRISMA imagery. Prior to correcting WV3 and PRISMA imagery to SR, we performed manual geometric corrections of imagery as both image sources were found to lack consistent georegistration. We performed comparisons at two study sites in Maryland, USA, including the United States Department of Agriculture Beltsville Agricultural Research Center (BARC) and an agricultural study site on Marylands Eastern Shore region. For the BARC site, we used WV3 imagery acquired on 2022-04-02 and PRISMA imagery acquired on 2022-04-28, focusing on evaluation of AC tool SR retrieval performance for each image source separately due to large time differences in image acquisitions where SR values are likely impacted by changing field conditions. For the Eastern Shore site, WV3 imagery was acquired on 2022-05-18 and 2022-05-30, and PRISMA imagery was acquired on 2022-05-21, allowing for quantitative evaluation of both AC tool performance and intercomparison between WV3 and PRISMA imagery. Having WV3 imagery acquired before and after PRISMA imagery allows for interpretation of major changes in field conditions and thus, identification of fields to exclude from intercomparisons. For intercomparison assessments, we computed relative percent difference (RPD) between the AC tool SR retrievals. For image source comparisons, 4-m WV3 pixels were resampled to 30-m PRISMA pixels after which 30-m WV3 bands and PRISMA spectra were compared to one another visually for both study sites. To provide rigorous SR retrieval intercomparisons between image sources, PRISMA spectra were resampled to WV3-equivalent bands for RPD computation for the Eastern Shore site. In addition to the SR retrieval intercomparisons between the AC tools, we carry out a quasi-validation where we retrieve fractional crop residue cover (fR) from the satellite image sources by calculating established spectral indices (SIs) and calibrating SIs with ground-measured fR acquired within several days of satellite overpasses. These SIs include the Cellulose Absorption Index (CAI) (Nagler et al. 2000), Shortwave Infrared Normalized Difference Residue Index (SINDRI) (Serbin et al. 2009), Lignin-Cellulose Absorption Index (LCAI) (Daughtry et al. 2005), and Lignin-Cellulose Peak Center Difference Index (LCPCDI) (Hively et al. 2021) 1-4. The most accurate crop residue SIs are generally based on shortwave infrared (SWIR) reflectance bands ranging from 2000 nm to 2400 nm that measure dry vegetation lignocellulose absorption features at 2100 and 2300 nm 1-5. For instance, the CAI identifies a 2100 nm cellulose absorption feature with a central band positioned on this feature, and two spectrally adjacent bands at 2040 and 2210 nm, while the LCAI identifies the 2300 nm lignin absorption feature compared to bands at 2165 and 2210 nm. Particular focus on intercomparisons for the SWIR region is critical as atmospheric water, carbon dioxide, and methane impact accurate SR retrieval as shown in Figure 1.a. Our final analysis concludes with the selection of the top-performing AC approach between the WV3 and PRISMA imagery (as indicated by low SR RPD) and then compares PRIMSA and 30-m WV3 imagery with original 4-m WV3 imagery to assess the degree to which spatial resolution impacts the retrieval of fR. Figure 1 provides a comparative example of WV3 and PRISMA imagery used to compute SINDRI which is then calibrated to fR using second order polynomial equations from Hively et al. (2018) 6. Figure 1 fR calibrations will be updated with newly acquired ground survey data from May 2022 to further improve the accuracy of image source and AC tool intercomparisons.

Conference Paper↗

USGS2020

Regional coordination between riparian dependence and atmospheric demand in willows (Salix L.) of western North America

Aim Plants vary in their hydrological and climatic niches. How these niche dimensions covary among closely related species can help identify co‐adaptations to hydrological and climatic factors, as well as predict biodiversity responses to environmental change. Location Western United States. Methods Relationships between riparian dependence and climate niches of willows ( Salix L.) were assessed, incorporating phylogenetics and functional traits to understand the adaptive nature of those relationships. The riparian dependence niche was estimated as the mean distance between georeferenced occurrence records and the nearest stream based on the National Hydrography Database. Results were compared to oaks ( Quercus L.), a less riparian‐dependent clade, with the expectation of different niche relationships. Results Willows generally occurred closer to streams than expected by chance, but riparian dependence varied substantially among species. Riparian dependence was positively correlated with mean annual temperature and diurnal temperature range niche, both indicators of atmospheric demand on evapotranspiration. Phylogenetic independent contrast correlations for these relationships were significant as well, and the high degree of niche convergence among species indicated evolutionarily labile co‐adaptations to riparian dependence and atmospheric demand. Plant height increased with mean annual temperature niche, and specific leaf area increased with residual variation in height, indicating underlying morphological correlates of niche variation. Oaks, on the other hand, exhibited no relationship between atmospheric demand and riparian dependence, and weaker niche relationships with riparian dependence overall. Main conclusions These results support the assertion that hydric‐adapted, woody riparian plants compensate for increased atmospheric demand on transpiration with a reliable supply of water provided by riparian habitats and that this trade‐off may be unique from mesic–xeric woody plants. Conservation of warm‐adapted riparian trees and shrubs under increasing temperatures and atmospheric demand may necessitate reversal of groundwater depletion. Cool‐adapted species may be best conserved through maintenance or expansion of riparian buffers as they become more riparian obligate with warming.

Diversity and Distributions↗

USGS2000

Coupled atmosphere-biophysics-hydrology models for environmental modeling

The formulation and implementation of LEAF-2, the Land Ecosystem–Atmosphere Feedback model, which comprises the representation of land–surface processes in the Regional Atmospheric Modeling System (RAMS), is described. LEAF-2 is a prognostic model for the temperature and water content of soil, snow cover, vegetation, and canopy air, and includes turbulent and radiative exchanges between these components and with the atmosphere. Subdivision of a RAMS surface grid cell into multiple areas of distinct land-use types is allowed, with each subgrid area, or patch, containing its own LEAF-2 model, and each patch interacts with the overlying atmospheric column with a weight proportional to its fractional area in the grid cell. A description is also given of TOPMODEL, a land hydrology model that represents surface and subsurface downslope lateral transport of groundwater. Details of the incorporation of a modified form of TOPMODEL into LEAF-2 are presented. Sensitivity tests of the coupled system are presented that demonstrate the potential importance of the patch representation and of lateral water transport in idealized model simulations. Independent studies that have applied LEAF-2 and verified its performance against observational data are cited. Linkage of RAMS and TOPMODEL through LEAF-2 creates a modeling system that can be used to explore the coupled atmosphere–biophysical–hydrologic response to altered climate forcing at local watershed and regional basin scales.

Journal of Applied Meteorology↗

USGS2014

Tritium and deuterium content of atmospheric hydrogen

The tritium and deuterium content of 24 samples of atmospheric hydrogen collected at ground level near Buffalo. N.Y. (U.S.A.). Hamburg (Germany), and Nürnberg (Germany) during 1954 to 1956 was measured. At the beginning of 1954 the T/H-ratio was found to have been 9.18 · 10 -14 i.e. about a factor of 10 higher than 1949 (FALTINGS and HARTECK) and 1951 (v. GROSSE et al.), probably due to the first explosion of a thermonuclear device in November 1952. In spite of a major test series of thermonuclear weapons in spring of 1954 (Operation CASTLE) no further increase in the tritium content was found during 1954 and 1955. It shows instead a seasonal variation with low tritium content in summer and about a threefold higher one in winter. Simultaneously, there is a good correlation between the tritium and deuterium concentrations. From 1956 on a noticeable increase in the tritium content due to more man-made HT produced or released by thermonuclear devices into the atmosphere was found, in agreement with measurements by GONSIOR. A possible explanation of the experimental results as well as a mode to test the validity of the model suggested is given. The deuterium concentrations of the samples analysed vary between about +7 percent and –17 percent, compared to Standard Lake Michigan Water with a ratio D/H = 0.0148 ± 0.0002 mol percent. Although from these results only a correlation factor between the tritium and deuterium content of “mean atmospheric hydrogen” and not their absolute values can be derived it is obvious that atmospheric hydrogen and the water vapour of the atmosphere are not in thermodynamic equilibrium, as has been pointed out before by HARTECK and SUESS.

Zeitschrift fur Naturforschung A↗

USGS2006

Water resources of Monroe County, New York, water years 2000-02: Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads in streams

This report, the fifth in a series that presents analyses of the hydrologic data collected in Monroe County since 1984, interprets data from four surface-water-monitoring sites in the Irondequoit Creek basin (Irondequoit Creek at Railroad Mills, East Branch Allen Creek at Pittsford, Allen Creek near Rochester, and Irondequoit Creek above Blossom Road); and from three sites on tributaries to the Genesee River (Oatka Creek at Garbutt, Honeoye Creek at Honeoye Falls, and Black Creek at Churchville) and from the Genesee River at Charlotte Docks. It also interprets data from a site on Northrup Creek, which provides information on nutrient loads delivered to Long Pond, a small eutrophic embayment of Lake Ontario. The report also includes water-level and water-quality data from nine observation wells in Ellison Park, and atmospheric-deposition data from a collection site at Mendon Ponds. Atmospheric Deposition : Average annual precipitation for 2000–02 was 33.11 in., 0.94 in. below normal. Average annual loads of some chemical constituents in atmospheric deposition for 2000–02 differed considerably from those for the previous period of record. Loads of all nutrients except ammonia decreased by amounts ranging from 28 percent (ammonia + organic nitrogen and phosphorus) to 2 percent (nitrite + nitrate), whereas ammonia loads an increased by 8 percent. Loads of dissolved sodium and total zinc in atmospheric deposition increased by 56 percent, and 54, percent respectively, over the previous period of record. Average annual loads of other constituents showed decreases ranging from 41 percent (dissolved magnesium) to 17 percent (dissolved chloride). Loads of all nutrients deposited in the Irondequoit Creek basin from atmospheric sources during 2000–02 greatly exceeded those transported by Irondequoit Creek. The ammonia load deposited in the basin was 165 times the load transported at Blossom Road (the most downstream site); the ammonia + organic nitrogen load was 2.8 times greater, orthophosphate 9.7 times greater, total phosphorus 1.2 times greater, and the nitrite + nitrate load was 1.6 times greater. Average yields of dissolved chloride and dissolved sulfate from atmosphoric sources were much less than those transported by streamflow at Blossom Road—chloride was about 1.5 percent and sulfate about 9.1 percent of the amount transported by Irondequoit Creek. Ground water : Ground-water-levels and water quality data were collected from 9 observation wells in Ellison Park in Monroe County. All wells except Mo 2 and Mo 659 are in the flood plain of Irondequoit Creek. Water levels indicate frequent reversals in direction of lateral flow toward or away from Irondequoit Creek, and all wells except Mo2 and Mo 659 respond to water level fluctuations in the Creek. Trend tests on water levels for the period of record indicate a slight upward trend in water levels at all nine wells, two of which (Mo 3 and Mo 667) were statistically significant. Concentrations of ammonia and ammonia + organic nitrogen showed a general decrease for the current period of record. Total phosphorus concentrations showed an increase at four wells and a decrease at four wells. Water quality data showed that the highest median concentrations of nutrients continues to occur in Mo 667 and the highest median concentrations of common ions was at Mo 664. Streamflow : Statistical analysis of long-term (greater than 15 years) streamflow records for unregulated streams in Monroe County indicated that annual mean flows for water years (A water year is the 12-month period from October 1 through September 30 of the following year.) 2000–02 generally were in the normal range (75th to 25th percentile), although Allen Creek continued to show a significant downward trend in mean monthly streamflow during the 1984–2002 water years. Chemical Concentration in Streams : Concentrations of several constituents in streams of the Irondequoit Creek basin showed statistically significant (α = 0.05) trends from the beginning of their period of record through 2002. Three of the four Irondequoit Creek sites (Allen Creek, Blossom Road, and Railroad Mills) showed downward trends in ammonia (4.6 to 12.0 percent per year) and ammonia + organic nitrogen (2.8 to 5.3 percent per year). Allen Creek showed downward trends in nitrite + nitrate and total phosphorus (both 1.2 percent per year), and Irondequoit Creek above Blossom Road showed an upward trend in orthophosphate (1.8 percent per year). Three Irondequoit Creek sites showed upward trends in dissolved chloride: Railroad Mills (4.8 percent per year), Allen Creek, and Blossom Road (both 1.9 percent per year). Allen Creek showed a downward trend in sulfate of 0.98 percent per year, whereas Blossom Road showed a downward trend in suspended solids of 4.0 percent per year. Volatile suspended solids showed an upward trend of 3.2 percent per year at Allen Creek and a downward trend of 2.2 percent per year at Blossom Road. Northrup Creek in western Monroe County, showed significant downward trends in concentrations of volatile suspended solids (2.5 percent per year), total phosphorus (5.3 percent per year), and orthophosphate (9.9 percent per year). The Genesee River at Charlotte Docks showed downward trends in volatile suspended solids (2.1 percent per year) and ammonia + organic nitrogen (4.5 percent per year). Oatka Creek at Garbutt showed an upward trend of 21.4 percent per year in turbidity. Chemical Loads in Streams : Mean annual yields (pounds or tons per square mile) of many constituents at the Irondequoit Creek sites were lower than those in previous reporting periods. Suspended solids and nitrite + nitrate yields were lower at three of the sites, and yields of volatile suspended solids, ammonia, and total phosphorus were lower at two of the sites. East Branch Allen Creek showed lower yields for five of the nine constituents for 2000–02, than for previous reporting periods. The decreased yields at East Branch Allen Creek are likely due to the Jefferson Road stormflow-detention basin and the much lower than normal runoff for the 2000–02 period.

New York↗

USGS2001

Water resources of Monroe County, New York, water years 1994-96, with emphasis on water quality in the Irondequoit Creek basin: Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek drains 169 square miles in the eastern part of Monroe County. Nutrients transported by Irondequoit Creek to Irondequoit Bay on Lake Ontario have contributed to the eutrophication of the Bay. Sewage-treatment-plant effluent, a major source of nutrients to the creek and its tributaries, was eliminated from the basin in 1979 by diversion to a regional wastewater-treatment facility, but sediment and contaminants from nonpoint sources continue to enter the creek and Irondequoit Bay. This report analyzes data from five surface-water monitoring sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek at Pittsford, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard. It is the third in a series of reports that present interpretive analyses of the hydrologic data collected in Monroe County since 1984. Also included are data from a site on Northrup Creek, which drains a 23.5-square-mile basin west of the Genesee River in western Monroe County, to provide information on surface-water quality in a stream west of the Genesee River and on loads of nutrients delivered to Long Pond, a small eutrophic embayment of Lake Ontario, and data from the Genesee River for comparison of historical water-quality conditions with 1994-96 conditions. Water-level and water-quality data from nine observation wells in Ellison Park, and atmospheric-deposition data from Mendon Ponds, also are included. Average annual yields of chemical constituents from atmospheric deposition for 1994-96 were generally similar to those for the previous 10 years (1984-93), except for dissolved sodium, dissolved potassium, total phosphorus, and orthophosphate, which ranged from 42 percent (dissolved sodium) to 275 percent (dissolved potassium) greater than during 1984-93, and dissolved sulfate and ammonia, which were about 30 percent less than in 1984-93. Loads of all nutrients deposited in the Irondequoit Creek basin from atmospheric sources during water years 1994-96 exceeded those removed by Irondequoit Creek at Blossom Road—ammonia by 5,600 percent, orthophosphate by 2,500 percent, ammonia + organic nitrogen by 350 percent, total phosphorus by 300 percent and nitrite + nitrate by 140 percent. Average yields of dissolved chloride and dissolved sulfate from atmospheric deposition were much less than those transported in streamflow—yields of dissolved chloride from atmospheric sources were only 1.9 percent, and yields of sulfate were only 9.2 percent, of those transported in streamflow at Blossom Road. Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends from the beginning of their period of record through 1996. The constituents that showed the greatest number of statistically significant trends were dissolved chloride, ammonia, and ammonia + organic nitrogen. Dissolved chloride showed an upward trend at Blossom Road, Allen Creek, and Empire Boulevard and a downward trend at Railroad Mills. Ammonia showed downward trends at Allen Creek, Blossom Road and Railroad Mills. Ammonia + organic nitrogen showed a downward trend at Allen Creek, Blossom Road, and Empire Boulevard. Nitrite + nitrate showed a downward trend at Allen Creek, and orthophosphate showed an upward trend at that site. Turbidity and total suspended solids showed a downward trend at Empire Boulevard. Neither total phosphorus nor volatile suspended solids showed statistically significant trends in concentration at any of the Irondequoit basin sites. Northrup Creek showed a downward trend in total suspended solids and ammonia + organic nitrogen, and an upward trend in dissolved chloride. The Genesee River showed a downward trend in ammonia + organic nitrogen and chloride, and an upward trend in orthophosphate. Most constituents for the 1994-96 water years showed lower average yields at Blossom Road than for the 1989-93 water years, but dissolved chloride showed higher yields for the 1994-96 water years at all sites except Blossom Road. Ammonia + organic nitrogen and total phosphorus showed a decrease in yield at all sites after 1993, and nitrite + nitrate showed slightly higher yields for 1994-96 at the upstream, predominantly rural sites, and lower yields at the downstream, more urban sites, than during 1989-93. The trends and changes in surface-water quality after 1993 can be attributed to several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) streamflow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1994-96 were in the normal range (75th to 25th percentile), although Allen Creek showed a statistically significant downward trend in monthly mean streamflow over the 1984-96 water years.

New York↗

USGS1999

Water resources of Monroe County, New York, water years 1989-93, with emphasis on water quality in the Irondequoit Creek basin: Part 2. Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek, which drains 169 square miles in the eastern part of Monroe County, has been recognized as a source of contaminants that contribute to the eutrophication of Irondequoit Bay on Lake Ontario. The discharge from sewage-treatment plants to the creek and its tributaries was eliminated in 1979 by diversion to another wastewater-treatment facility, but sediment and nonpoint-source pollution remain a concern. This report presents data from five surface-water sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard, to supplement published data from 1984-88. Data from Northrup Creek, which drains 11.7 square miles in western Monroe County, provide information on surface-water quality west of the Genesee River. Also presented are water-level and water-quality data from 12 observation-well sites in Ellison and Powdermill Parks and atmospheric-deposition data from 1 site (Mendon Ponds). Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends during 1989-93. Concentrations of total suspended-solids and volatile suspended-solids in Irondequoit Creek at Blossom Road decreased 13.5 and 12.5 percent per year, respectively, and those at Empire Boulevard decreased 33.5 and 22 percent per year, respectively. Concentrations of ammonia plus organic nitrogen increased 17.6 percent per year at one site in the basin, but decreased 8.5 and 22.3 percent per year at two sites. Nitrite plus nitrate decreased at only one site (3.5 percent per year). Concentrations of total phosphorus increased at two sites (about 7 percent per year) and decreased at two other sites (7.6 and 29.9 percent per year), and orthophosphate concentrations increased at one site (10.8 percent per year). Dissolved chloride increased at three sites (1.7 to 10.9 percent per year), and dissolved sulfate decreased at one site (2.1 percent per year) and increased at one site (6.8 percent per year). Median concentrations of constituents were significantly lower in atmospheric deposition than in streamflow, although annual deposition of ammonia nitrogen, nitrite plus nitrate, total phosphorus, and orthophosphate in the basin exceeded the amounts removed by streamflow. Atmospheric deposition of chloride and sulfate, by contrast, represented only 1 and 12 percent, respectively, of the loads transported by Irondequoit Creek (Blossom Road site). Comparison of water-quality data from the Allen Creek site and Irondequoit Creek at Blossom Road from water years 1989-93 with corresponding data from 1984-88 indicates significant changes in median concentrations of several constituents. The concentration of dissolved chloride increased at Blossom Road and was unchanged at Allen Creek, whereas sulfate decreased at both sites. Concentrations of ammonia plus organic nitrogen, and nitrite plus nitrate, were significantly lower during 1989-93 than during 1984-88 at both sites. Total phosphorus concentration was lower during 1984-88 than during 1989-93 at Blossom Road but showed no change at Allen Creek, and orthophosphate concentration for 1989-93 was lower than in 1984-88 at both sites. Comparison of chemical loads in atmospheric deposition also indicates significant changes in many constituents. Five-year-mean loads of sodium, sulfate, and lead in atmospheric deposition for 1989-93 exceeded those for 1984-88, whereas 5-year-mean loads of calcium, magnesium, potassium, chloride, nitrite plus nitrate, ammonia nitrogen, and orthophosphate for 1989-93 were lower than in 1984-88. The changes in surface-water quality resulted from several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) flow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1989- 93 were in the normal range (20th- to 80th-percentile). The greatest mean annual flow in this period-about 140 percent of normal at Irondequoit Creek and Black Creek-occurred in 1993, but the annual mean flow for that water year at Allen Creek was only 98 percent of normal. The lowest annual mean flows of these streams-ranging from 75 percent of normal to 93 percent of normal-occurred in 1989. The average annual mean flows for these streams for 1989-93 was 104 percent of normal, and that for 1984-88 was normal.

New York↗

USGS2015

Carbon exchange between the atmosphere and subtropical forested cypress and pine wetlands

Carbon dioxide exchange between the atmosphere and forested subtropical wetlands is largely unknown. Here we report a first step in characterizing this atmospheric–ecosystem carbon (C) exchange, for cypress strands and pine forests in the Greater Everglades of Florida as measured with eddy covariance methods at three locations (Cypress Swamp, Dwarf Cypress and Pine Upland) for 2 years. Links between water and C cycles are also examined at these three sites, as are methane emission measured only at the Dwarf Cypress site. Each forested wetland showed net C uptake from the atmosphere both monthly and annually, as indicated by the net ecosystem exchange (NEE) of carbon dioxide (CO 2 ). For this study, NEE is the difference between photosynthesis and respiration, with negative values representing uptake from the atmosphere that is retained in the ecosystem or transported laterally via overland flow (unmeasured for this study). Atmospheric C uptake (NEE) was greatest at the Cypress Swampp (−900 to −1000 g C m 2 yr −1 ), moderate at the Pine Upland (−650 to −700 g C m 2 yr −1 ) and least at the Dwarf Cypress (−400 to −450 g C m 2 yr −1 ). Changes in NEE were clearly a function of seasonality in solar insolation, air temperature and flooding, which suppressed heterotrophic soil respiration. We also note that changes in the satellite-derived enhanced vegetation index (EVI) served as a useful surrogate for changes in NEE at these forested wetland sites.

Florida↗

USGS1993

Diffusional limits to the consumption of atmospheric methane by soils

Net transport of atmospheric gases into and out of soil systems is primarily controlled by diffusion along gas partial pressure gradients. Gas fluxes between soil and the atmosphere can therefore be estimated by a generalization of the equation for ordinary gaseous diffusion in porous unsaturated media. Consumption of CH4 by methylotrophic bacteria in the top several centimeters of soil causes the uptake of atmospheric CH4 by aerated soils. The capacity of the methylotrophs to consume CH4 commonly exceeds the potential of CH4 to diffuse from the atmosphere to the consumers. The maximum rate of uptake of atmospheric CH4 by soil is, therefore, limited by diffusion and can be calculated from soil physical properties and the CH4 concentration gradient. The CH4 concentration versus depth profile is theoretically described by the equation for gaseous diffusion with homogeneous chemical reaction in porous unsaturated media. This allows for calculation of the in situ rate of CH4 consumption within specified depth intervals.

Conference Paper↗