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USGS2015

Quantification of 15 bile acids in lake charr feces by ultra-high performance liquid chromatography–tandem mass spectrometry

Many fishes are hypothesized to use bile acids (BAs) as chemical cues, yet quantification of BAs in biological samples and the required methods remain limited. Here, we present an UHPLC–MS/MS method for simultaneous, sensitive, and rapid quantification of 15 BAs, including free, taurine, and glycine conjugated BAs, and application of the method to fecal samples from lake charr ( Salvelinus namaycush ). The analytes were separated on a C 18 column with acetonitrile–water (containing 7.5 mM ammonium acetate and 0.1% formic acid) as mobile phase at a flow rate of 0.25 mL/min for 12 min. BAs were monitored with a negative electrospray triple quadrupole mass spectrometer (Xevo TQ-S™). Calibration curves of 15 BAs were linear over the concentration range of 1.00–5,000 ng/mL. Validation revealed that the method was specific, accurate, and precise. The method was applied to quantitative analysis of feces extract of fry lake charr and the food they were eating. The concentrations of analytes CA, TCDCA, TCA, and CDCA were 242.3, 81.2, 60.7, and 36.2 ng/mg, respectively. However, other taurine conjugated BAs, TUDCA, TDCA, and THDCA, were not detected in feces of lake charr. Interestingly, TCA and TCDCA were detected at high concentrations in food pellets, at 71.9 and 38.2 ng/mg, respectively. Application of the method to feces samples from lake charr supported a role of BAs as chemical cues, and will enhance further investigation of BAs as chemical cues in other fish species.

Journal of Chromatography B: Analytical Technologi↗

USGS2002

Liquid chromatographic determination of florfenicol in the plasma of multiple species of fish

A simple method was developed for determining florfenicol concentration in a small volume (250 μl) of plasma from five phylogenetically diverse species of freshwater fish. Florfenicol was isolated from the plasma matrix through C 18 solid-phase extraction and quantified by reversed-phase high-performance liquid chromatography with UV detection. The accuracy (84–104%), precision (%RSD⩽8), and sensitivity (quantitation limit <30 ng/ml) of the method indicate its usefulness for conducting pharmacokinetic studies on a variety of freshwater fish.

Journal of Chromatography B: Analytical Technologi↗

USGS2025

U.S. Geological Survey 2024 Rocky Mountain Region Science Exchange—Showcasing cutting-edge science to adapt to extreme weather events and stakeholder needs

Introduction The Rocky Mountains and the Colorado River Basin in the Western United States are complex, interconnected systems that sustain a large variety of species, including tens of millions of humans. These regions face risks from drought, wildfires, invasive plant and animal species, and habitat reduction. Working with many stakeholders, scientists can help to characterize these risks by providing data and analytical tools to inform land and water resource management decisions. The U.S. Geological Survey 2024 Rocky Mountain Region (Region 7) Science Exchange Workshop, held in April 2024, focused on cutting-edge science techniques, evaluating complex interconnected risks, and coproducing science with science partners and stakeholders. These science topics and communication strategies can be used for developing data, interpretations, and decision support tools needed to provide science that resource managers and other stakeholders can use to better understand complex, dynamic natural systems and develop management strategies to plan for and adapt to risks that threaten human communities and natural ecosystems.

Fact Sheet↗

USGS2010

Evolution of Ore Deposits and Technology Transfer Project: Isotope and Chemical Methods in Support of the U.S. Geological Survey Science Strategy, 2003-2008

Principal functions of the U.S. Geological Survey (USGS) Mineral Resources Program are providing assessments of the location, quantity, and quality of undiscovered mineral deposits, and predicting the environmental impacts of exploration and mine development. The mineral and environmental assessments of domestic deposits are used by planners and decisionmakers to improve the stewardship of public lands and public resources. Assessments of undiscovered mineral deposits on a global scale reveal the potential availability of minerals to the United States and other countries that manufacture goods imported to the United States. These resources are of fundamental relevance to national and international economic and security policy in our globalized world economy. Performing mineral and environmental assessments requires that predictions be made of the likelihood of undiscovered deposits. The predictions are based on geologic and geoenvironmental models that are constructed for the diverse types of mineral deposits from detailed descriptions of actual deposits and detailed understanding of the processes that formed them. Over the past three decades the understanding of ore-forming processes has benefited greatly from the integration of laboratory-based geochemical tools with field observations and other data sources. Under the aegis of the Evolution of Ore Deposits and Technology Transfer Project (referred to hereinafter as the Project), a 5-year effort that terminated in 2008, the Mineral Resources Program provided state-of-the-art analytical capabilities to support applications of several related geochemical tools to ore-deposit-related studies. The analytical capabilities and scientific approaches developed within the Project have wide applicability within Earth-system science. For this reason the Project Laboratories represent a valuable catalyst for interdisciplinary collaborations of the type that should be formed in the coming years for the United States to meet its natural-resources and natural-science needs. This circular presents an overview of the Project. Descriptions of the Project laboratories are given first including descriptions of the types of chemical or isotopic analyses that are made and the utility of the measurements. This is followed by summaries of select measurements that were carried out by the Project scientists. The studies are grouped by science direction. Virtually all of them were collaborations with USGS colleagues or with scientists from other governmental agencies, academia, or the private sector.

Circular↗

USGS1962

Glass electrodes sensitive to divalent cations

Glass electrodes suitable for measurement of divalent cations have been made and tested. Empirical and theoretical electrode equations have been presented to describe electrode behavior in a variety of aqueous solutions. Most electrodes show response interpretable as showing nearly ideal solid-solution behavior of the cations in the glass surface. The electrodes should be useful in the measurement of divalent-cation activities in natural waters and biological fluids, and useful in general analytical chemistry.

Science↗

USGS2007

The United States Polar Rock Repository: A geological resource for the Earth science community

The United States Polar Rock Repository (USPRR) is a U. S. national facility designed for the permanent curatorial preservation of rock samples, along with associated materials such as field notes, annotated air photos and maps, raw analytic data, paleomagnetic cores, ground rock and mineral residues, thin sections, and microfossil mounts, microslides and residues from Polar areas. This facility was established by the Office of Polar Programs at the U. S. National Science Foundation (NSF) to minimize redundant sample collecting, and also because the extreme cold and hazardous field conditions make fieldwork costly and difficult. The repository provides, along with an on-line database of sample information, an essential resource for proposal preparation, pilot studies and other sample based research that should make fieldwork more efficient and effective. This latter aspect should reduce the environmental impact of conducting research in sensitive Polar Regions. The USPRR also provides samples for educational outreach. Rock samples may be borrowed for research or educational purposes as well as for museum exhibits.

Open-File Report↗

USGS2012

The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Science objectives and mast unit description

ChemCam is a remote sensing instrument suite on board the "Curiosity" rover (NASA) that uses Laser-Induced Breakdown Spectroscopy (LIBS) to provide the elemental composition of soils and rocks at the surface of Mars from a distance of 1.3 to 7 m, and a telescopic imager to return high resolution context and micro-images at distances greater than 1.16 m. We describe five analytical capabilities: rock classification, quantitative composition, depth profiling, context imaging, and passive spectroscopy. They serve as a toolbox to address most of the science questions at Gale crater. ChemCam consists of a Mast-Unit (laser, telescope, camera, and electronics) and a Body-Unit (spectrometers, digital processing unit, and optical demultiplexer), which are connected by an optical fiber and an electrical interface. We then report on the development, integration, and testing of the Mast-Unit, and summarize some key characteristics of ChemCam. This confirmed that nominal or better than nominal performances were achieved for critical parameters, in particular power density (>1 GW/cm 2 ). The analysis spot diameter varies from 350 μm at 2 m to 550 μm at 7 m distance. For remote imaging, the camera field of view is 20 mrad for 1024×1024 pixels. Field tests demonstrated that the resolution (˜90 μrad) made it possible to identify laser shots on a wide variety of images. This is sufficient for visualizing laser shot pits and textures of rocks and soils. An auto-exposure capability optimizes the dynamical range of the images. Dedicated hardware and software focus the telescope, with precision that is appropriate for the LIBS and imaging depths-of-field. The light emitted by the plasma is collected and sent to the Body-Unit via a 6 m optical fiber. The companion to this paper (Wiens et al. this issue) reports on the development of the Body-Unit, on the analysis of the emitted light, and on the good match between instrument performance and science specifications.

Space Science Reviews↗

USGS2020

Technical memorandum: Compound specific isotope analysis, Oak Grove Village well site OU1, Franklin County, Missouri

A study involving Compound Specific Isotope Analysis (CSIA) of trichloroethene (TCE) in groundwater at the Oak Grove Village (OGV) Well Site was conducted by the U.S. Environmental Protection Agency (EPA) in 2014 in an effort to fingerprint the source(s). This technical memorandum, written as a joint effort between HydroGeoLogic, Inc. (HGL) and the U.S. Geological Survey (USGS) Central Midwest Water Science Center (Schumacher, 2019), documents the procedures and analysis of the CSIA investigation. CSIA is an analytical method that measures the isotopic ratios of naturally occurring stable isotopes in specific chemical compounds in environmental samples. CSIA using primarily the ratio of carbon 13 C/ 12 C (δ 13 C), known as 1-D CSIA, has been used for decades in evaluating degradation pathways of organic compounds, including chlorinated solvents such as TCE. Ratios of stable chlorine isotopes 37 Cl/ 35 Cl (δ 37 Cl) also have been used with carbon isotopes, collectively known as 2-D CSIA, and most recently isotopes of hydrogen 2 H/ 1 H (δ 2 H) have been added, collectively known as 3-D CSIA, in attempts to further determine source, transport, and fate of compounds such as TCE (Ertl et al., 1998; Hunkeler et al., 2011; Kuder et al., 2013; McHugh et al., 2011; Shouakar-Stash et al., 2003; EPA, 2008; and van Warmerdam et al., 1995.

Missouri↗

USGS2001

The Landsat 7 mission: terrestrial research and applications for the 21st century

The Landsat Earth observation approach introduced in 1972 created a new way of monitoring land cover and land use globally. The Landsat 7 mission, successfully launched on April 15, 1999, continues those observations and demonstrates significant progress in precise numerical radiometry, spectral differentiation, and seasonally repetitive monitoring. Substantial improvements in calibration procedures, both prior to launch and during normal operations, have also been made to ensure long-term stability in the acquired spectral radiometry. Landsat 7 data acquisitions are being driven by a long-term data acquisition plan that was designed to ensure that substantially cloud-free, seasonal coverage would be recorded and archived in the US for all land areas of the globe. NASA competitively selected a Landsat Science Team, consisting of representatives from US universities and government agencies, to exploit the Landsat 7 record for global change research. This team is addressing the technical and analytical means to process and analyze the core of this observation record, and for the first time in the history of the Landsat mission, the technical and operational aspects of the mission are being driven by the goals of the US science community. The expected outcome of these efforts is a rapid improvement in understanding the Earth system, as well as conceptual knowledge that will underpin significant advancements in the application of this technology for commercial, operational, educational, and research purposes. Pathways to achieve effective Landsat continuity in the early decades of the 21st century are also being given careful attention, and there is no question that the lessons learned from the Landsat 7 mission will strongly influence these next-generation sensor systems.

Remote Sensing of Environment↗

USGS2016

Benefits and limitations of using decision analytic tools to assess uncertainty and prioritize Landscape Conservation Cooperative information needs

The Landscape Conservation Cooperatives (LCCs) are a network of partnerships throughout North America that are tasked with integrating science and management to support more effective delivery of conservation at a landscape scale. In order to achieve this integration, some LCCs have adopted the approach of providing their partners with better scientific information in an effort to facilitate more effective and coordinated conservation decisions. Taking this approach has led many LCCs to begin funding research to provide the information for improved decision making. To ensure that funding goes to research projects with the highest likelihood of leading to more integrated broad scale conservation, some LCCs have also developed approaches for prioritizing which information needs will be of most benefit to their partnerships. We describe two case studies in which decision analytic tools were used to quantitatively assess the relative importance of information for decisions made by partners in the Plains and Prairie Potholes LCC. The results of the case studies point toward a few valuable lessons in terms of using these tools with LCCs. Decision analytic tools tend to help shift focus away from research oriented discussions and toward discussions about how information is used in making better decisions. However, many technical experts do not have enough knowledge about decision making contexts to fully inform the latter type of discussion. When assessed in the right decision context, however, decision analyses can point out where uncertainties actually affect optimal decisions and where they do not. This helps technical experts understand that not all research is valuable in improving decision making. But perhaps most importantly, our results suggest that decision analytic tools may be more useful for LCCs as way of developing integrated objectives for coordinating partner decisions across the landscape, rather than simply ranking research priorities.

Journal of Fish and Wildlife Management↗

USGS2011

College and university environmental programs as a policy problem (Part 2): Strategies for improvement

Environmental studies and environmental sciences programs in American and Canadian colleges and universities seek to ameliorate environmental problems through empirical enquiry and analytic judgment. In a companion article (Part 1) we describe the environmental program movement (EPM) and discuss factors that have hindered its performance. Here, we complete our analysis by proposing strategies for improvement. We recommend that environmental programs re-organize around three principles. First, adopt as an overriding goal the concept of human dignity—defined as freedom and social justice in healthy, sustainable environments. This clear higher-order goal captures the human and environmental aspirations of the EPM and would provide a more coherent direction for the efforts of diverse participants. Second, employ an explicit, genuinely interdisciplinary analytical framework that facilitates the use of multiple methods to investigate and address environmental and social problems in context. Third, develop educational programs and applied experiences that provide students with the technical knowledge, powers of observation, critical thinking skills and management acumen required for them to become effective professionals and leaders. Organizing around these three principles would build unity in the EPM while at the same time capitalizing on the strengths of the many disciplines and diverse local conditions involved.

Environmental Management↗

USGS2012

Review and update of the applications of organic petrology: Part 1, geological applications

Organic petrology developed as coal petrology at the beginning of the 20th century dedicated mainly to the study of coals because of their utilization in industry. Coal petrology was then considered a branch of coal science. Later, with the development of specialized nomenclature, classification of coal components, and the standardization and improvement of analytical (microscopical) methods, this discipline expanded in interests and name, becoming organic petrology. Organic petrology carries a broader context, being as well a tool applied in the study of dispersed organic matter in sedimentary rocks due to its importance in exploration for fossil fuel resources. At present, organic petrology is a discipline widely recognized for its role in fundamental and applied research with respect to both coal utilization and in geosciences. Throughout the 20th century several important monographs have been published on the discipline of organic petrology, including “Stach's textbook of coal petrology” (1st edition 1935, 2nd 1975, 3rd 1982), updated as the more general “Organic petrology” by Taylor et al. (1998). More recently, the text “Applied coal petrology: the role of petrology in coal utilization” was published by Suárez-Ruiz and Crelling (2008). This review is the first in a two-part review series that describes and updates the role of organic petrology in geosciences. A second part complementing this one and focused on the applications of organic petrology to other scientific fields will follow.

International Journal of Coal Geology↗

USGS2025

What is eDNA method standardization and why do we need it?

The rapid advancement of environmental DNA ( eDNA ) science in the past two decades has inspired a concomitant growth in the development of eDNA sampling and analytical methods. However, these methods are often developed by individual laboratories or institutions, which can isolate protocols within programmes, agencies or regions and prevent the beneficial exchange of data and ideas. Recent efforts to advance national and international coordination have resulted in a groundswell of standardisation efforts, but there is still considerable confusion around the role of formal standards for regulatory or research applications. With this commentary, we hope to provide clarity on the terminology used in standardisation discussions, including the differences between formal standards and best practice guidelines. Additionally, we discuss how eDNA method choice may be informed by environmental management scenarios and review examples of formal eDNA method standards being used to inform management action. The eDNA community now has an opportunity to develop a roadmap for method development to help close standardisation gaps, advance eDNA method adoption and accelerate our ability to monitor biological life at the scales our current environmental challenges demand.

Metabarcoding and Metagenomics↗

USGS2000

Sampling for mercury at subnanogram per litre concentrations for load estimation in rivers

Estimation of constituent loads in streams requires collection of stream samples that are representative of constituent concentrations, that is, composites of isokinetic multiple verticals collected along a stream transect. An all-Teflon isokinetic sampler (DH-81) cleaned in 75??C, 4 N HCl was tested using blank, split, and replicate samples to assess systematic and random sample contamination by mercury species. Mean mercury concentrations in field-equipment blanks were low: 0.135 ng??L-1 for total mercury (??Hg) and 0.0086 ng??L-1 for monomethyl mercury (MeHg). Mean square errors (MSE) for ??Hg and MeHg duplicate samples collected at eight sampling stations were not statistically different from MSE of samples split in the laboratory, which represent the analytical and splitting error. Low fieldblank concentrations and statistically equal duplicate- and split-sample MSE values indicate that no measurable contamination was occurring during sampling. Standard deviations associated with example mercury load estimations were four to five times larger, on a relative basis, than standard deviations calculated from duplicate samples, indicating that error of the load determination was primarily a function of the loading model used, not of sampling or analytical methods.

Canadian Journal of Fisheries and Aquatic Sciences↗

USGS2020

Moving from decision to action in conservation science

Biodiversity loss is a major threat to the integrity of ecosystems and is projected to worsen, yet the path to successful conservation remains elusive. Decision support frameworks (DSFs) are increasingly applied by resource managers to navigate the complexity, uncertainty, and differing socio-ecological objectives inherent to conservation problems. Most published conservation research that uses DSFs focuses on analytical stages (e.g., identifying an optimal decision), making it difficult to assess and learn from previous examples in a conservation practice context. Here, we (1) evaluate the relationship between the application of decision science and the resulting conservation outcomes, and (2) identify and address existing barriers to the application of DSFs to conservation practice. To do this, we develop a framework for evaluating conservation initiatives using decision science that emphasizes setting attainable goals, building momentum, and obtaining partner buy-in. We apply this framework to a systematic review of amphibian conservation decision support projects, including a follow-up survey of the pertinent conservation practitioners, stakeholders, and scientists. We found that all projects identified optimal solutions to reach stated objectives, but positive conservation outcomes were limited when implementation challenges arose. Further, we identified multiple barriers (e.g., dynamic and hierarchical leadership, scale complexity, limited resource availability) that can inhibit the progression from decision identification to action implementation (i.e., ‘decision-implementation gap’), and to successful conservation outcomes. Based on these results, we provide potential actionable steps and avenues for future development of DSFs to facilitate the transition from decision to action and the realization of conservation successes.

Biological Conservation↗

USGS2012

The Stanford-U.S. Geological Survey SHRIMP ion microprobe--a tool for micro-scale chemical and isotopic analysis

Answers to many questions in Earth science require chemical analysis of minute volumes of minerals, volcanic glass, or biological materials. Secondary Ion Mass Spectrometry (SIMS) is an extremely sensitive analytical method in which a 5–30 micrometer diameter "primary" beam of charged particles (ions) is focused on a region of a solid specimen to sputter secondary ions from 1–5 nanograms of the sample under high vacuum. The elemental abundances and isotopic ratios of these secondary ions are determined with a mass spectrometer. These results can be used for geochronology to determine the age of a region within a crystal thousands to billions of years old or to precisely measure trace abundances of chemical elements at concentrations as low as parts per billion. A partnership of the U.S. Geological Survey and the Stanford University School of Earth Sciences operates a large SIMS instrument, the Sensitive High-Resolution Ion Microprobe with Reverse Geometry (SHRIMP–RG) on the Stanford campus.

Fact Sheet↗

USGS2019

Analytical framework to estimate water use associated with continuous oil and gas development

An analytical framework was designed to estimate water use associated with continuous oil and gas (COG) development in support of the U.S. Geological Survey Water Availability and Use Science Program. This framework was developed to better understand the relation between the production of COG resources for energy and the amount of water needed to sustain this type of energy development in the United States. The total mean undiscovered, technically recoverable volume of COG has increased, highlighting the continued need to develop approaches to better characterize water use associated with COG development. The analytical framework can be used to estimate water use associated with COG development for three water-use components—direct, indirect, and ancillary water use—that are related to the life cycle of COG development. Direct water use is defined as water used in a wellbore to complete a well, including the water used for drilling, cementing, stimulating, and maintaining the well during production. Indirect water use is the water used at or near the well site, including water used for dust abatement, for cleaning equipment, and for crew and staff use. Ancillary water use is all other water used during the life cycle of COG development that is not categorized as direct or indirect, such as additional local or regional water use resulting from a change (for example, population) related to COG development. The analytical framework includes the data inputs, the processes involved in estimating the water-use coefficients and analyzing their uncertainties, and the outputs. The analytical framework was developed as an R script, which contains the statistical models used to estimate water-use components. The availability of data across COG reservoirs in the United States is variable and presents challenges for estimating water use for extracting COG from their reservoirs; thus, the R script can be modified for the types of data available within a COG reservoir, the extent and resolution of data available for each water-use component, and the desired output of the water-use assessment. The script was written so that the units of the data in the script were standardized. Water-use estimates were simulated for the mean and 10th, 50th, and 90th percentiles of the data distributions. Uncertainties were quantified with confidence intervals for the estimated coefficients. Uncertainty for estimated or simulated data can be calculated with the R script by providing a range of representative values that are within the appropriate confidence intervals of the mean of the data.

Lower 48 states↗

USGS2021

Cyprosulfamide: Analysis of the herbicide safener and two of its degradates in surface water and groundwater from the Midwestern United States

Herbicide safeners are commonly included in herbicide formulations to selectively protect crops from herbicide toxicity but are poorly understood in terms of their environmental occurrence and fate. This study established an analytical method for a newer safener, cyprosulfamide, and two of its degradates, cyprosulfamide desmethyl and N -cyclopropyl-4-sulfamoylbenzamide, in water via solid-phase extraction and liquid chromatography with tandem mass spectroscopy. To evaluate the potential for off-field transport and transformation of cyprosulfamide, the method was used to analyze groundwater and surface water samples collected near cornfields in the midwestern United States where cyprosulfamide had been applied. All three compounds were detected in surface water samples ( N = 34); N -cyclopropyl-4-sulfamoylbenzamide was most frequently detected (56%), followed by cyprosulfamide (25%) and cyprosulfamide desmethyl (19%). Maximum concentrations ranged from 22.0 to 5185.9 ng/L, with the highest concentrations and detection rates during the growing season. None of our target analytes were detected in groundwater.

ACS Agricultural Science and Technology↗