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Petrophysics of Lower Silurian sandstones and integration with the tectonic-stratigraphic framework, Appalachian basin, United States

Petrophysical properties were determined for six facies in Lower Silurian sandstones of the Appalachian basin: fluvial, estuarine, upper shoreface, lower shoreface, tidal channel, and tidal flat. Fluvial sandstones have the highest permeability for a given porosity and exhibit a wide range of porosity (2-18%) and permeability (0.002-450 md). With a transition-zone thickness of only 1-6 m (3-20 ft), fluvial sandstones with permeability greater than 5 md have irreducible water saturation (Siw) less than 20%, typical of many gas reservoirs. Upper shoreface sandstones exhibit good reservoir properties with high porosity (10-21%), high permeability (3-250 md), and low S iw (<20%). Lower shoreface sandstones, which are finer grained, have lower porosity (4-12%), lower permeability (0.0007-4 md), thicker transition zones (6-180 m [20-600 ft]), and higher S iw. In the tidal-channel, tidal-flat, and estuarine facies, low porosity (average < 6%), low permeability (average < 0.02 md), and small pore throats result in large transition zones (30-200 m; 100-650 ft) and high water saturations. The most favorable reservoir petrophysical properties and the best estimated production from the Lower Silurian sandstones are associated with fluvial and upper shoreface facies of incised-valley fills, which we interpret to have formed predominantly in areas of structural recesses that evolved from promontories along a collisional margin during the Taconic orogeny. Although the total thickness of the sandstone may not be as great in these areas, reservoir quality is better than in adjacent structural salients, which is attributed to higher energy depositional processes and shallower maximum burial depth in the recesses than in the salients. Copyright ??2005. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Paleovalley fills: Trunk vs. tributary

A late Mississippian-early Pennsylvanian eustatic sea level drop resulted in a complex lowstand drainage network being eroded across the Illinois Basin in the eastern United States. This drainage system was filled during the early part of the Pennsylvanian. Distinct differences can be recognized between the trunk and tributary paleovalley fills. Fills preserved within the trunk systems tend to be fluvially dominated and consist of bed-load deposits of coarse- to medium-grained sandstone and conglomerate. Conversely, the incised valleys of tributary systems tend to be filled with dark mudstone, thinly interbedded sandstones, and mudstones and siltstones. These finer grained facies exhibit marine influences manifested by tidal rhythmites, certain traces fossils, and macro- and microfauna. Examples of tributary and trunk systems, separated by no more than 7 km (4.3 mi) along strike, exhibit these styles of highly contrasting fills. Useful analogs for understanding this Pennsylvanian system include the Quaternary glacial sluiceways present in the lower Ohio, White, and Wabash river valleys of Indiana (United States) and the modern Amazon River (Brazil). Both the Amazon River and the Quaternary rivers of Indiana have (or had) trunk rivers that are (were) dominated by large quantities of bed load relative to their tributaries. The trunk valley systems of these analogs aggraded much more rapidly than their tributary valleys, which evolved into lakes because depositional rates along the trunk are (were) so high that the mouths of the tributaries have been dammed by bed-load deposits. These Holocene systems illustrate that sediment yields can significantly influence the nature of fill successions within incised valleys independent of rates of sea level changes or proximity to highstand coastlines. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Gas shale/oil shale

The production of natural gas from shales continues to increase in North America, and shale gas exploration is on the rise in other parts of the world since the previous report by this committee was published by American Association of Petroleum Geologists, Energy Minerals Division (2009). For the United States, the volume of proved reserves of natural gas increased 11% from 2008 to 2009, the increase driven largely by shale gas development (Energy Information Administration 2010c). Furthermore, shales have increasingly become targets of exploration for oil and condensate as well as gas, which has served to greatly expand their significance as ‘‘unconventional’’ petroleum reservoirs. This report provides information about specific shales across North America and Europe from which gas (biogenic or thermogenic), oil, or natural gas liquids are produced or is actively being explored. The intent is to reflect the recently expanded mission of the Energy Minerals Division (EMD) Gas Shales Committee to serve as a single point of access to technical information on shales regardless of the type of hydrocarbon produced from them. The contents of this report were drawn largely from contributions by numerous members of the EMD Gas Shales Advisory Committee, with much of the data being available from public websites such as state or provincial geological surveys or other public institutions. Shales from which gas or oil is being produced in the United States are listed in alphabetical order by shale name. Information for Canada is presented by province, whereas for Europe, it is presented by country.

Natural Resources Research

Use of relational databases to evaluate regional petroleum accumulation, groundwater flow, and CO2 sequestration in Kansas

Large-scale relational databases and geographic information system tools are used to integrate temperature, pressure, and water geo-chemistry data from numerous wells to better understand regional-scale geothermal and hydrogeological regimes of the lower Paleozoic aquifer systems in the mid-continent and to evaluate their potential for geologic CO2 sequestration. The lower Paleozoic (Cambrian to Mississippian) aquifer systems in Kansas, Missouri, and Oklahoma comprise one of the largest regional-scale saline aquifer systems in North America. Understanding hydrologic conditions and processes of these regional-scale aquifer systems provides insight to the evolution of the various sedimentary basins, migration of hydrocarbons out of the Anadarko and Arkoma basins, and the distribution of Arbuckle petroleum reservoirs across Kansas and provides a basis to evaluate CO2 sequestration potential. The Cambrian and Ordovician stratigraphic units form a saline aquifer that is in hydrologic continuity with the freshwater recharge from the Ozark plateau and along the Nemaha anticline. The hydrologic continuity with areas of freshwater recharge provides an explanation for the apparent underpressure in the Arbuckle Group. Copyright ?? 2005. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Evaluation of kinetic uncertainty in numerical models of petroleum generation

Oil-prone marine petroleum source rocks contain type I or type II kerogen having Rock-Eval pyrolysis hydrogen indices greater than 600 or 300-600 mg hydrocarbon/g total organic carbon (HI, mg HC/g TOC), respectively. Samples from 29 marine source rocks worldwide that contain mainly type II kerogen (HI = 230-786 mg HC/g TOC) were subjected to open-system programmed pyrolysis to determine the activation energy distributions for petroleum generation. Assuming a burial heating rate of 1??C/m.y. for each measured activation energy distribution, the calculated average temperature for 50% fractional conversion of the kerogen in the samples to petroleum is approximately 136 ?? 7??C, but the range spans about 30??C (???121-151??C). Fifty-two outcrop samples of thermally immature Jurassic Oxford Clay Formation were collected from five locations in the United Kingdom to determine the variations of kinetic response for one source rock unit. The samples contain mainly type I or type II kerogens (HI = 230-774 mg HC/g TOC). At a heating rate of 1??C/m.y., the calculated temperatures for 50% fractional conversion of the Oxford Clay kerogens to petroleum differ by as much as 23??C (127-150??C). The data indicate that kerogen type, as defined by hydrogen index, is not systematically linked to kinetic response, and that default kinetics for the thermal decomposition of type I or type II kerogen can introduce unacceptable errors into numerical simulations. Furthermore, custom kinetics based on one or a few samples may be inadequate to account for variations in organofacies within a source rock. We propose three methods to evaluate the uncertainty contributed by kerogen kinetics to numerical simulations: (1) use the average kinetic distribution for multiple samples of source rock and the standard deviation for each activation energy in that distribution; (2) use source rock kinetics determined at several locations to describe different parts of the study area; and (3) use a weighted-average method that combines kinetics for samples from different locations in the source rock unit by giving the activation energy distribution for each sample a weight proportional to its Rock-Eval pyrolysis S2 yield (hydrocarbons generated by pyrolytic degradation of organic matter). Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Flow unit modeling and fine-scale predicted permeability validation in Atokan sandstones: Norcan East Kansas

Characterizing the reservoir interval into flow units is an effective way to subdivide the net-pay zone into layers for reservoir simulation. Commonly used flow unit identification techniques require a reliable estimate of permeability in the net pay on a foot-by-foot basis. Most of the wells do not have cores, and the literature is replete with different kinds of correlations, transforms, and prediction methods for profiling permeability in pay. However, for robust flow unit determination, predicted permeability at noncored wells requires validation and, if necessary, refinement. This study outlines the use o f a spreadsheet-based permeability validation technique to characterize flow units in wells from the Norcan East field, Clark County, Kansas, that produce from Atokan aged fine- to very fine-grained quartzarenite sandstones interpreted to have been deposited in brackish-water, tidally dominated restricted tidal-flat, tidal-channel, tidal-bar, and estuary bay environments within a small incised-valley-fill system. The methodology outlined enables the identification of fieldwide free-water level and validates and refines predicted permeability at 0.5-ft (0.15-m) intervals by iteratively reconciling differences in water saturation calculated from wire-line log and a capillary-pressure formulation that models fine- to very fine-grained sandstone with diagenetic clay and silt or shale laminae. The effectiveness of this methodology was confirmed by successfully matching primary and secondary production histories using a flow unit-based reservoir model of the Norcan East field without permeability modifications. The methodologies discussed should prove useful for robust flow unit characterization of different kinds of reservoirs. Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Modeling of gas generation from the Barnett Shale, Fort Worth Basin, Texas

The generative gas potential of the Mississippian Barnett Shale in the Fort Worth Basin, Texas, was quantitatively evaluated by sealed gold-tube pyrolysis. Kinetic parameters for gas generation and vitrinite reflectance (Ro) changes were calculated from pyrolysis data and the results used to estimate the amount of gas generated from the Barnett Shale at geologic heating rates. Using derived kinetics for Ro evolution and gas generation, quantities of hydrocarbon gas generated at Ro ??? 1.1% are about 230 L/t (7.4 scf/t) and increase to more that 5800 L/t (186 scf/t) at Ro ??? 2.0% for a sample with an initial total organic carbon content of 5.5% and Ro = 0.44%. The volume of shale gas generated will depend on the organic richness, thickness, and thermal maturity of the shale and also the amount of petroleum that is retained in the shale during migration. Gas that is reservoired in shales appears to be generated from the cracking of kerogen and petroleum that is retained in shales, and that cracking of the retained petroleum starts by Ro ??? 1.1%. This result suggests that the cracking of petroleum retained in source rocks occurs at rates that are faster than what is predicted for conventional siliciclastic and carbonate reservoirs, and that contact of retained petroleum with kerogen and shale mineralogy may be a critical factor in shale-gas generation. Shale-gas systems, together with overburden, can be considered complete petroleum systems, although the processes of petroleum migration, accumulation, and trap formation are different from what is defined for conventional petroleum systems. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

The appraisal of ore reserves at a Japanese copper mine

Estimates of ore reserves at major Japanese metal mines seem, at first glance, to be readily understandable to American engineers and geologists. Close scrutiny, however, generally reveals unexpected features at each mine. For example, the Hitachi copper mine formerly segregated its developed ore reserve into positive and probable on the basis of the possibility of high-grade and low-grade production from individual stopes. Tests were made by the writer at Hitachi on the accuracy of the original reserve estimates of a few ore blocks by comparing those figures with the final production data. The results suggesthat the average reserve estimate of positive ore may be accurate within 20 percent, plus or minus. A ten-year supply of proved ore at the big mines is not unusual; hence Hitachi is not much concerned with the additional categories of probable and possible ore, unless the positive ore has become inaccessible because of caving of the workings. For the sake of comprehensiveness, however, the writer studied the assay maps and stope maps in collaboration with the mine management and estimated tonnages of probable and possible ore, qualified by lower reliability ratings. Exploration prospects also were described in actual figures, subject to a variation of plus-or-minus 75 percent.

Ibaraki Prefecture

An evaluation of the U.S. Geological Survey World Petroleum Assessment 2000

This study compares the additions to conventional crude oil and natural gas reserves as reported from January 1996 to December 2003 with the estimated undiscovered and reserve-growth volumes assessed in the U.S. Geological Survey World Petroleum Assessment 2000, which used data current through 1995. Approximately 28% of the estimated additions to oil reserves by reserve growth and approximately 11% of the estimated undiscovered oil volumes were realized in the 8 yr since the assessment (27% of the time frame for the assessment). Slightly more than half of the estimated additions to gas reserves by reserve growth and approximately 10% of the estimated undiscovered gas volumes were realized. Between 1995 and 2003, growth of oil reserves in previously discovered fields exceeded new-field discoveries as a source of global additions to reserves of conventional oil by a ratio of 3:1. The greatest amount of reserve growth for crude oil occurred in the Middle East and North Africa, whereas the greatest contribution from new-field discoveries occurred in sub-Saharan Africa. The greatest amount of reserve growth for natural gas occurred in the Middle East and North Africa, whereas the greatest contribution from new-field discoveries occurred in the Asia Pacific region. On an energy-equivalent basis, volumes of new gas-field discoveries exceeded new oil-field discoveries. Copyright ?? 2005. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Egret-Hibernia(!), a significant petroleum system, northern Grand Banks area, offshore eastern Canada

Egret-Hibernia(!) is a well-explored petroleum system (3.25 billion barrels oil equivalent [BOE]) located in the Jeanne d'Arc Basin on the Labrador - Newfoundland shelf. Rifting and sediment fill began in the Late Triassic. Egret source rock was deposited in the Late Jurassic at about 153 Ma. After this time, alternating reservoir rock and seal rock were deposited with some syndepositional faulting. By the end of the Early Cretaceous, faults and folds had formed numerous structural traps. For the next 100 m.y., overburden rock thermally matured the source rock when it reached almost 4 km (2.5 mi) burial depth. For 2 km (1.25 mi) below this depth, oil and gas were expelled, until the source was depleted. The expelled petroleum migrated updip to nearby faulted, anticlinal traps, where much of it migrated across faults and upsection to the Hibernia Formation (44% recoverable oil) and Avalon Formation (28%). Accumulation size decreased, and gas content increased from west to east, independent of trap size. These changes correspond to a decrease in source rock richness and quality from west to east. Almost all (96%) of the discovered petroleum resides in the Lower Cretaceous or older reservoir rock units. All accumulations found to date are normally pressured in structural traps. Fifty-two exploration wells found eighteen discoveries. Their size ranges from 1.2 to 0.01 billion BOE. Most discoveries were made between 1979 and 1991. The discovery cycle began with larger accumulations and progressed to smaller accumulations. The estimated sizes of the larger accumulations have grown since 1990. Estimated mean value for undiscovered hydrocarbons is 3.8 billion BOE, thereby raising the ultimate size of Egret-Hibernia(!) to 6.19 billion BOE. Copyright ?? 2005. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Crustal insights from gravity and aeromagnetic analysis: Central North Slope, Alaska

Aeromagnetic and gravity data are processed and interpreted to reveal deep and shallow information about the crustal structure of the central North Slope, Alaska. Regional aeromagnetic anomalies primarily reflect deep crustal features. Regional gravity anomalies are more complex and require detailed analysis. We constrain our geophysical models with seismic data and interpretations along two transects including the Trans-Alaska Crustal Transect. Combined geophysical analysis reveals a remarkable heterogeneity of the pre-Mississippian basement. In the central North Slope, pre-Mississippian basement consists of two distinct geophysical domains. To the southwest, the basement is dense and highly magnetic; this basement is likely mafic and mechanically strong, possibly acting as a buttress to basement involvement in Brooks Range thrusting. To the northeast, the central North Slope basement consists of lower density, moderately magnetic rocks with several discrete regions (intrusions?) of more magnetic rocks. A conjugate set of geophysical trends, northwest-southeast and southwest-northeast, may be a factor in the crustal response to tectonic compression in this domain. High-resolution gravity and aeromagnetic data, where available, reflect details of shallow fault and fold structure. The maps and profile models in this report should provide useful guidelines and complementary information for regional structural studies, particularly in combination with detailed seismic reflection interpretations. Future challenges include collection of high-resolution gravity and aeromagnetic data for the entire North Slope as well as additional deep crustal information from seismic, drilling, and other complementary methods. Copyrights ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Geologic framework of the Mississippian Barnett Shale, Barnett-Paleozoic total petroleum system, Bend arch-Fort Worth Basin, Texas

This article describes the primary geologic characteristics and criteria of the Barnett Shale and Barnett-Paleozoic total petroleum system (TPS) of the Fort Worth Basin used to define two geographic areas of the Barnett Shale for petroleum resource assessment. From these two areas, referred to as "assessment units," the U.S. Geological Survey estimated a mean volume of about 26 tcf of undiscovered, technically recoverable hydrocarbon gas in the Barnett Shale. The Mississippian Barnett Shale is the primary source rock for oil and gas produced from Paleozoic reservoir rocks in the Bend arch-Fort Worth Basin area and is also one of the most significant gas-producing formations in Texas. Subsurface mapping from well logs and commercial databases and petroleum geochemistry demonstrate that the Barnett Shale is organic rich and thermally mature for hydrocarbon generation over most of the Bend arch-Fort Worth Basin area. In the northeastern and structurally deepest part of the Fort Worth Basin adjacent to the Muenster arch, the formation is more than 1000 ft (305 m) thick and interbedded with thick limestone units; westward, it thins rapidly over the Mississippian Chappel shelf to only a few tens of feet. The Barnett-Paleozoic TPS is identified where thermally mature Barnett Shale has generated large volumes of hydrocarbons and is (1) contained within the Barnett Shale unconventional continuous accumulation and (2) expelled and distributed among numerous conventional clastic- and carbonate-rock reservoirs of Paleozoic age. Vitrinite reflectance (Ro) measurements show little correlation with present-day burial depth. Contours of equal Ro values measured from Barnett Shale and typing of produced hydrocarbons indicate significant uplift and erosion. Furthermore, the thermal history of the formation was enhanced by hydrothermal events along the Ouachita thrust front and Mineral Wells-Newark East fault system. Stratigraphy and thermal maturity define two gas-producing assessment units for the Barnett Shale: (1) a greater Newark East fracture-barrier continuous Barnett Shale gas assessment unit, encompassing an area of optimal gas production where dense impermeable limestones enclose thick (???300 ft; ???91 m) Barnett Shale that is within the gas-generation window (Ro ??? 1.1%); and (2) an extended continuous Barnett Shale gas assessment unit covering an area where the Barnett Shale is within the gas-generation window, but is less than 300 ft (91 m) thick, and either one or both of the overlying and underlying limestone barriers are absent. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Families of miocene monterey crude oil, seep, and tarball samples, coastal California

Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs to better assess their origins and distributions in coastal California. These samples were used to construct a chemometric (multivariate statistical) decision tree to classify 288 additional samples. The results identify three tribes of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl and lower calcareous-siliceous members of the Monterey Formation at Naples Beach near Santa Barbara. An attempt to correlate these families to rock extracts from these members in the nearby COST (continental offshore stratigraphic test) (OCS-Cal 78-164) well failed, at least in part because the rocks are thermally immature. Geochemical similarities among the oil tribes and their widespread distribution support the prograding margin model or the banktop-slope-basin model instead of the ridge-and-basin model for the deposition of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher plant input. Tribe 2 contains four oil families with traits intermediate between tribes 1 and 3, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey source rock favored petroleum generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. In a test of the decision tree, 10 tarball samples collected from beaches in Monterey and San Mateo counties in early 2007 were found to originate from natural seeps representing different organofacies of Monterey Formation source rock instead from one anthropogenic pollution event. The seeps apparently became more active because of increased storm activity. Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Geochemical constraints on the origin and volume of gas in the New Albany Shale (Devonian-Mississippian), eastern Illinois Basin

This study involved analyses of kerogen petrography, gas desorption, geochemistry, microporosity, and mesoporosity of the New Albany Shale (Devonian-Mississippian) in the eastern part of the Illinois Basin. Specifically, detailed core analysis from two locations, one in Owen County, Indiana, and one in Pike County, Indiana, has been conducted. The gas content in the locations studied was primarily dependent on total organic carbon content and the micropore volume of the shales. Gas origin was assessed using stable isotope geochemistry. Measured and modeled vitrinite reflectance values were compared. Depth of burial and formation water salinity dictated different dominant origins of the gas in place in the two locations studied in detail. The shallower Owen County location (415-433 m [1362-1421 ft] deep) contained significant additions of microbial methane, whereas the Pike County location (832-860 m [2730-2822 ft] deep) was characterized exclusively by thermogenic gas. Despite differences in the gas origin, the total gas in both locations was similar, reaching up to 2.1 cm3/g (66 scf/ton). Lower thermogenic gas content in the shallower location (lower maturity and higher loss of gas related to uplift and leakage via relaxed fractures) was compensated for by the additional generation of microbial methane, which was stimulated by an influx of glacial melt water, inducing brine dilution and microbial inoculation. The characteristics of the shale of the Maquoketa Group (Ordovician) in the Pike County location are briefly discussed to provide a comparison to the New Albany Shale. Copyright ??2010. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Oil and gas geochemistry and petroleum systems of the Fort Worth Basin

Detailed biomarker and light hydrocarbon geochemistry confirm that the marine Mississippian Barnett Shale is the primary source rock for petroleum in the Fort Worth Basin, north-central Texas, although contributions from other sources are possible. Biomarker data indicate that the main oil-generating Barnett Shale facies is marine and was deposited under dysoxic, strong upwelling, normal salinity conditions. The analysis of two outcrop samples and cuttings from seven wells indicates variability in the Barnett Shale organic facies and a possibility of other oil subfamilies being present. Light hydrocarbon analyses reveal significant terrigenous-sourced condensate input to some reservoirs, resulting in terrigenous and mixed marine-terrigenous light hydrocarbon signatures for many oils. The light hydrocarbon data suggest a secondary, condensate-generating source facies containing terrigenous or mixed terrigenous-marine organic matter. This indication of a secondary source rock that is not revealed by biomarker analysis emphasizes the importance of integrating biomarker and light hydrocarbon data to define petroleum source rocks. Gases in the Fort Worth Basin are thermogenic in origin and appear to be cogenerated with oil from the Barnett Shale, although some gas may also originate by oil cracking. Isotope data indicate minor contribution of biogenic gas. Except for reservoirs in the Pennsylvanian Bend Group, which contain gases spanning the complete range of observed maturities, the gases appear to be stratigraphically segregated, younger reservoirs contain less mature gas, and older reservoirs contain more mature gas. We cannot rule out the possibility that other source units within the Fort Worth Basin, such as the Smithwick Shale, are locally important petroleum sources. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Mesozoic (Upper Jurassic-Lower Cretaceous) deep gas reservoir play, central and eastern Gulf coastal plain

The Mesozoic (Upper Jurassic-Lower Cretaceous) deeply buried gas reservoir play in the central and eastern Gulf coastal plain of the United States has high potential for significant gas resources. Sequence-stratigraphic study, petroleum system analysis, and resource assessment were used to characterize this developing play and to identify areas in the North Louisiana and Mississippi Interior salt basins with potential for deeply buried gas reservoirs. These reservoir facies accumulated in Upper Jurassic to Lower Cretaceous Norphlet, Haynesville, Cotton Valley, and Hosston continental, coastal, and marine siliciclastic environments and Smackover and Sligo nearshore marine shelf, ramp, and reef carbonate environments. These Mesozoic strata are associated with transgressive and regressive systems tracts. In the North Louisiana salt basin, the estimate of secondary, nonassociated thermogenic gas generated from thermal cracking of oil to gas in the Upper Jurassic Smackover source rocks from depths below 3658 m (12,000 ft) is 4800 tcf of gas as determined using software applications. Assuming a gas expulsion, migration, and trapping efficiency of 2-3%, 96-144 tcf of gas is potentially available in this basin. With some 29 tcf of gas being produced from the North Louisiana salt basin, 67-115 tcf of in-place gas remains. Assuming a gas recovery factor of 65%, 44-75 tcf of gas is potentially recoverable. The expelled thermogenic gas migrated laterally and vertically from the southern part of this basin to the updip northern part into shallower reservoirs to depths of up to 610 m (2000 ft). Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

North Slope, Alaska: Source rock distribution, richness, thermal maturity, and petroleum charge

Four key marine petroleum source rock units were identified, characterized, and mapped in the subsurface to better understand the origin and distribution of petroleum on the North Slope of Alaska. These marine source rocks, from oldest to youngest, include four intervals: (1) Middle-Upper Triassic Shublik Formation, (2) basal condensed section in the Jurassic-Lower Cretaceous Kingak Shale, (3) Cretaceous pebble shale unit, and (4) Cretaceous Hue Shale. Well logs for more than 60 wells and total organic carbon (TOC) and Rock-Eval pyrolysis analyses for 1183 samples in 125 well penetrations of the source rocks were used to map the present-day thickness of each source rock and the quantity (TOC), quality (hydrogen index), and thermal maturity (Tmax) of the organic matter. Based on assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original TOC (TOCo) and the original hydrogen index (HIo) prior to thermal maturation. The quantity and quality of oil-prone organic matter in Shublik Formation source rock generally exceeded that of the other units prior to thermal maturation (commonly TOCo > 4 wt.% and HIo > 600 mg hydrocarbon/g TOC), although all are likely sources for at least some petroleum on the North Slope. We used Rock-Eval and hydrous pyrolysis methods to calculate expulsion factors and petroleum charge for each of the four source rocks in the study area. Without attempting to identify the correct methods, we conclude that calculations based on Rock-Eval pyrolysis overestimate expulsion factors and petroleum charge because low pressure and rapid removal of thermally cracked products by the carrier gas retards cross-linking and pyrobitumen formation that is otherwise favored by natural burial maturation. Expulsion factors and petroleum charge based on hydrous pyrolysis may also be high compared to nature for a similar reason. Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle

Stratigraphic framework and estuarine depositional environments of the Miocene Bear Lake Formation, Bristol Bay Basin, Alaska: Onshore equivalents to potential reservoir strata in a frontier gas-rich basin

The Miocene Bear Lake Formation is exposed along the coast and mountains of the central Alaska Peninsula and extends offshore as part of the Bristol Bay Basin. The Bear Lake Formation is up to 2360 m (7743 ft) thick in an offshore well and is considered to have the highest reservoir potential in this gasrich frontier basin. Our new macrofossil and palynological data, collected in the context of measured stratigraphic sections, allow us to construct the first chronostratigraphic framework for this formation. Biostratigraphic age assignments for the numerous, commonly isolated, onshore exposures of the Bear Lake Formation show that deposition initiated sometime before the middle Miocene (15 Ma) and extended to possibly the earliest Pliocene. The bulk of the Bear Lake Formation, however, was deposited during the middle and late Miocene based on our new findings. We interpret the Bear Lake Formation as the product of a regional transgressive estuarine depositional system based on lithofacies analysis. The lower part of the formation is characterized by trough cross-stratified sandstone interbedded with coal and pedogenic mudstone deposited in fluvial and swamp environments of the uppermost parts of the estuarine system. The lower-middle part of the formation is dominated by nonbioturbated, wavy- and flaser-bedded sandstone and siltstone that were deposited in supratidal flat environments. The uppermiddle part of the Bear Lake Formation is characterized by inclined heterolithic strata and coquinoid mussel beds that represent tidal channel environments in the middle and lower tracts of the estuarine system. The uppermost part of the formation consists of tabular, bioturbated sandstone with diverse marine invertebrate macrofossil faunas. We interpret this part of the section as representing the subtidal tract of the lower estuarine system and possibly the adjacent shallow inner shelf. A comparison of our depositional framework for the Bear Lake Formation with core and well-log data from onshore and offshore wells indicates that similar Miocene depositional systems existed throughout much of the Bristol Bay Basin. The documented changes in depositional environments within the Bear Lake Formation are also important for understanding upsection changes in the geometries of potential reservoirs. Copyright ??2009. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle