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Modeling of land use and reservoir effects on nonpoint source pollution in a highly agricultural basin

Nonpoint source (NPS) pollution is tightly linked to land use activities that determine the sources and magnitudes of pollutant loadings to stream water. The pollutant loads may also be alleviated within reservoirs because of the physical interception resulting from changed hydrological regimes and other biochemical processes. It is important but challenging to assess the NPS pollution processes with human effects due to the measurement limitations. The objective of this study is to evaluate the effects of human activities such as land uses and reservoir operation on the hydrological and NPS pollution processes in a highly agricultural area-the Iowa River Basin-using the Soil and Water Assessment Tool (SWAT). The evaluation of model performance at multiple sites reveals that SWAT can consistently simulate the daily streamflow, and monthly/annual sediment and nutrient loads (nitrate nitrogen and mineral phosphorus) in the basin. We also used the calibrated model to estimate the trap efficiencies of sediment (~78%) and nutrients (~30%) in the Coralville Reservoir within the basin. These non-negligible effects emphasize the significance of incorporating the sediment and nutrient removal mechanisms into watershed system studies. The spatial quantification of the critical NPS pollution loads can help identify hot-spot areas that are likely locations for the best management practices.

Iowa

Potential climatic impacts of vegetation change: A regional modeling study

The human species has been modifying the landscape long before the development of modern agrarian techniques. Much of the land area of the conterminous United States is currently used for agricultural production. In certain regions this change in vegetative cover from its natural state may have led to local climatic change. A regional climate version of the Colorado State University Regional Atmospheric Modeling System was used to assess the impact of a natural versus current vegetation distribution on the weather and climate of July 1989. The results indicate that coherent regions of substantial changes, of both positive and negative sign, in screen height temperature, humidity, wind speed, and precipitation are a possible consequence of land use change throughout the United States. The simulated changes in the screen height quantities were closely related to changes in the vegetation parameters of albedo, roughness length, leaf area index, and fractional coverage.

Journal of Geophysical Research D: Atmospheres

Uranium transport in the Walker River Basin, California and Nevada

During the summer of 1976 waters from tributaries, rivers, springs and wells were sampled in the Walker River Basin. Snow and sediments from selected sites were also sampled. All samples were analyzed for uranium and other elements. The resulting data provide an understanding of the transport of uranium within a closed hydrologic basin as well as providing a basis for the design of geochemical reconnaissance studies for the Basin and Range Province of the Western United States. Spring and tributary data are useful in locating areas containing anomalous concentrations of uranium. However, agricultural practices obscure the presence of known uranium deposits and render impossible the detection of other known deposits. Uranium is extremely mobile in stream waters and does not appear to sorb or precipitate. Uranium has a long residence time (2500 years) in the open waters of Walker Lake; however, once it crosses the sediment-water interface, it is reduced to the U(IV) state and is lost from solution. Over the past two million years the amount of uranium transported to the terminal point of the Walker River system may have been on the order of 4 × 10 8 kg . This suggests that closed basin termini are sites for significant uranium accumulations and are, therefore, potential sites of uranium ore deposits.

Journal of Geochemical Exploration

Identifying the decision to be supported: a review of papers from environmental modelling and software

Two of the basic tenets of decision support system efforts are to help identify and structure the decisions to be supported, and to then provide analysis in how those decisions might be best made. One example from wetland management would be that wildlife biologists must decide when to draw down water levels to optimise aquatic invertebrates as food for breeding ducks. Once such a decision is identified, a system or tool to help them make that decision in the face of current and projected climate conditions could be developed. We examined a random sample of 100 papers published from 2001-2011 in Environmental Modelling and Software that used the phrase “decision support system” or “decision support tool”, and which are characteristic of different sectors. In our review, 41% of the systems and tools related to the water resources sector, 34% were related to agriculture, and 22% to the conservation of fish, wildlife, and protected area management. Only 60% of the papers were deemed to be reporting on DSS. This was based on the papers reviewed not having directly identified a specific decision to be supported. We also report on the techniques that were used to identify the decisions, such as formal survey, focus group, expert opinion, or sole judgment of the author(s). The primary underlying modelling system, e.g., expert system, agent based model, Bayesian belief network, geographical information system (GIS), and the like was categorised next. Finally, since decision support typically should target some aspect of unstructured decisions, we subjectively determined to what degree this was the case. In only 23% of the papers reviewed, did the system appear to tackle unstructured decisions. This knowledge should be useful in helping workers in the field develop more effective systems and tools, especially by being exposed to the approaches in different, but related, disciplines. We propose that a standard blueprint for reporting on DSS be developed for consideration by journal editors to aid them in filtering papers that use the term, “decision support”.

Leipzig

Calculating crop water requirement satisfaction in the West Africa Sahel with remotely sensed soil moisture

The Soil Moisture Active Passive (SMAP) mission will provide soil moisture data with unprecedented accuracy, resolution, and coverage, enabling models to better track agricultural drought and estimate yields. In turn, this information can be used to shape policy related to food and water from commodity markets to humanitarian relief efforts. New data alone, however, do not translate to improvements in drought and yield forecasts. New tools will be needed to transform SMAP data into agriculturally meaningful products. The objective of this study is to evaluate the possibility and efficiency of replacing the rainfall-derived soil moisture component of a crop water stress index with SMAP data. The approach is demonstrated with 0.1°-resolution, ~10-day microwave soil moisture from the European Space Agency and simulated soil moisture from the Famine Early Warning Systems Network Land Data Assimilation System. Over a West Africa domain, the approach is evaluated by comparing the different soil moisture estimates and their resulting Water Requirement Satisfaction Index values from 2000 to 2010. This study highlights how the ensemble of indices performs during wet versus dry years, over different land-cover types, and the correlation with national-level millet yields. The new approach is a feasible and useful way to quantitatively assess how satellite-derived rainfall and soil moisture track agricultural water deficits. Given the importance of soil moisture in many applications, ranging from agriculture to public health to fire, this study should inspire other modeling communities to reformulate existing tools to take advantage of SMAP data.

Journal of Hydrometeorology

Drainage investment and wetland loss: an analysis of the national resources inventory data

The United States Soil Conservation Service (SCS) conducts a survey for the purpose of establishing an agricultural land use database. This survey is called the National Resources Inventory (NRI) database. The complex NRI land classification system, in conjunction with the quantitative information gathered by the survey, has numerous applications. The current paper uses the wetland area data gathered by the NRI in 1982 and 1987 to examine empirically the factors that generate wetland loss in the United States. The cross-section regression models listed here use the quantity of wetlands, the stock of drainage capital, the realty value of farmland and drainage costs to explain most of the cross-state variation in wetland loss rates. Wetlands preservation efforts by federal agencies assume that pecuniary economic factors play a decisive role in wetland drainage. The empirical models tested in the present paper validate this assumption.

Journal of Environmental Management

Environmental fate and effects of the lampricide bayluscide: a review

Bayluscide is an additive to TFM that increases the effectiveness of TFM as a lampricide. A review of the literature was undertaken to determine the environmental fate and effects of Bayluscide. Niclosamide (2', 5-dichloro-4'-nitrosalicylanilide), the active ingredient of Bayluscide, degrades rapidly in natural water and sediment systems, however, the rate of degradation is very slow in autoclaved samples. This difference suggests that degradation under laboratory conditions is dependent on microbial activity and hydrolysis plays a minor role in degradation of niclosamide. The major degradation product of niclosamide has been reported to be aminoniclosamide (2',5-dichloro-4'-aminosalicylanilide), which represented more than 50% of the residues extractable from sediments. Significantly more of the chemical is adsorbed to sediments with higher organic content and at lower pH's. The mobility of niclosamide in soil can be characterized as slight to medium; the estimated leaching distance would range from 0 to > 25 cm depending on the soil type and pH. The active ingredient of Bayluscide (niclosamide) is decomposed by ultra-violet light depending on the intensity and duration of the exposure. The uptake of residues by most invertebrates exposed to super(14)C-niclosamide is fairly rapid and equilibrium is reached within 24 h. About 90% of the accumulated residues were lost within 48 h after the organisms were transferred to clean flowing water. As with invertebrates, fish rapidly accumulate and eliminate residues of niclosamide. Three distinct residues were isolated from the extracts of edible fillet tissue; parent niclosamide, the glucuronide conjugate of niclosamide, and the sulfate ester of niclosamide. Aquatic plants and agricultural crops do not appear to be adversely affected at concentrations of Bayluscide used for lamprey or snail control. Mayflies (Hexagenia sp.). tend to be susceptible to TFM, but are relatively resistant to the effects of exposure to Bayluscide. Bayluscide was originally developed as a molluscicide to eliminate snails. Therefore, it is not surprising that mollusks are extremely sensitive to Bayluscide. Oral, dermal, and ocular administration of Bayluscide to mammals resulted in no clinical signs of systemic toxicity. Tests of the chronic effects of Bayluscide indicated that it is not mutagenic or carcinogenic. Bayluscide is not persistent in the environment; it breaks down in natural water and sediment systems through hydrolysis, photolysis, and microbial degradation. Given the limited use and tight control maintained by the U.S. Fish and Wildlife Service during applications of lampricides, Bayluscide presents minimal risk to human health and safety of the environment.

Journal of Great Lakes Research

Tracking domestic ducks: A novel approach for documenting poultry market chains in the context of avian influenza transmission

Agro-ecological conditions associated with the spread and persistence of highly pathogenic avian influenza (HPAI) are not well understood, but the trade of live poultry is suspected to be a major pathway. Although market chains of live bird trade have been studied through indirect means including interviews and questionnaires, direct methods have not been used to identify movements of individual poultry. To bridge the knowledge gap on quantitative movement and transportation of poultry, we introduced a novel approach for applying telemetry to document domestic duck movements from source farms at Poyang Lake, China. We deployed recently developed transmitters that record Global Positioning System (GPS) locations and send them through the Groupe Spécial Mobile (GSM) cellular telephone system. For the first time, we were able to track individually marked ducks from 3 to 396 km from their origin to other farms, distribution facilities, or live bird markets. Our proof of concept test showed that the use of GPS-GSM transmitters may provide direct, quantitative information to document the movement of poultry and reveal their market chains. Our findings provide an initial indication of the complexity of source-market network connectivity and highlight the great potential for future telemetry studies in poultry network analyses.

Poyang Lake

Hydrologic connectivity and the contribution of stream headwaters to ecological integrity at regional scales

Cumulatively, headwater streams contribute to maintaining hydrologic connectivity and ecosystem integrity at regional scales. Hydrologic connectivity is the water-mediated transport of matter, energy and organisms within or between elements of the hydrologic cycle. Headwater streams compose over two-thirds of total stream length in a typical river drainage and directly connect the upland and riparian landscape to the rest of the stream ecosystem. Altering headwater streams, e.g., by channelization, diversion through pipes, impoundment and burial, modifies fluxes between uplands and downstream river segments and eliminates distinctive habitats. The large-scale ecological effects of altering headwaters are amplified by land uses that alter runoff and nutrient loads to streams, and by widespread dam construction on larger rivers (which frequently leaves free-flowing upstream portions of river systems essential to sustaining aquatic biodiversity). We discuss three examples of large-scale consequences of cumulative headwater alteration. Downstream eutrophication and coastal hypoxia result, in part, from agricultural practices that alter headwaters and wetlands while increasing nutrient runoff. Extensive headwater alteration is also expected to lower secondary productivity of river systems by reducing stream-system length and trophic subsidies to downstream river segments, affecting aquatic communities and terrestrial wildlife that utilize aquatic resources. Reduced viability of freshwater biota may occur with cumulative headwater alteration, including for species that occupy a range of stream sizes but for which headwater streams diversify the network of interconnected populations or enhance survival for particular life stages. Developing a more predictive understanding of ecological patterns that may emerge on regional scales as a result of headwater alterations will require studies focused on components and pathways that connect headwaters to river, coastal and terrestrial ecosystems. Linkages between headwaters and downstream ecosystems cannot be discounted when addressing large-scale issues such as hypoxia in the Gulf of Mexico and global losses of biodiversity.

Journal of the American Water Resources Associatio

A Simplified Method for Sampling and Analysis of High Volume Surface Water for Organic Contaminants Using XAD-2

A simple compressed-gas driven system for field processing and extracting water for subsequent analyses of hydrophobic organic compounds is presented. The pumping device is a pneumatically driven pump and filtration system that can easily clarify at 4L/min. The extraction device uses compressed gas to drive filtered water through two parallel XAD-2 resin columns, at about 200 mL/min. No batteries or inverters are required for water collection or processing. Solvent extractions were performed directly in the XAD-2 glass columns. Final extracts are cleaned-up on Florisil cartridges without fractionation and contaminants analyzed by GC-MS. Method detection limits (MDLs) and recoveries for dissolved organic contaminants, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and pesticides are reported along with results of surface water analysis for the San Francisco Bay, CA.

Journal of Environmental Science and Health - Part

The LTAR cropland Common Experiment at Lower Chesapeake Bay

The Lower Chesapeake Bay (LCB) Long-Term Agroecosystem Research (LTAR) Common Experiment (CE) located in Beltsville, MD, focuses on research of concern to producers of the major regional crops, which are corn ( Zea mays L.), soybean [ Glycine max (L.) Merr.], wheat ( Triticum aestivum L.), and various forage species. Livestock production in the region includes broiler and laying chickens ( Gallus gallus domesticus L.) and dairy and beef cattle ( Bos taurus L.). The LCB region is among the most heavily populated in the United States. Urban development pressure is high for both farms and natural areas. The need to restore Chesapeake Bay water quality is a major influence on regional agricultural practices. Conservation practices such as cover cropping, no-till agriculture, and nutrient management planning are more common in the region compared to nationally. However, farmers still face management challenges implementing practices that address water quality and the rise of herbicide-resistant weeds. Researchers at the LCB site recognize the need to protect the Chesapeake and Delaware Bays and maintain farmer profitability. The LCB CE compares a 3-year crop rotation system featuring alternative crop management (cover crop intensification, crop rotation diversification, and integrated weed management [IWM]) with a prevailing 2-year system (no cover crops and no IWM), both under continuous no-tillage, to identify the optimal balance to promote the sustainability of regional cropping systems. The LTAR LCB site provides data-driven tools and solutions to support farmers in the mid-Atlantic region.

Delaware, Maryland, New Jersey, Pennsylvania, Virg

Sensitivity of summer climate to anthropogenic land-cover change over the Greater Phoenix, AZ, region

This work evaluates the first-order effect of land-use/land-cover change (LULCC) on the summer climate of one of the nation's most rapidly expanding metropolitan complexes, the Greater Phoenix, AZ, region. High-resolution-2-km grid spacing-Regional Atmospheric Modeling System (RAMS) simulations of three "wet" and three "dry" summers were carried out for two different land-cover reconstructions for the region: a circa 1992 representation based on satellite observations, and a hypothetical land-cover scenario where the anthropogenic landscape of irrigated agriculture and urban pixels was replaced with current semi-natural vegetation. Model output is evaluated with respect to observed air temperature, dew point, and precipitation. Our results suggest that development of extensive irrigated agriculture adjacent to the urban area has dampened any regional-mean warming due to urbanization. Consistent with previous observationally based work, LULCC produces a systematic increase in precipitation to the north and east of the city, though only under dry conditions. This is due to a change in background atmospheric stability resulting from the advection of both warmth from the urban core and moisture from the irrigated area. ?? 2008 Elsevier Ltd. All rights reserved.

Journal of Arid Environments

An exploratory investigation of the landscape-lake interface: Land cover controls over consumer N and C isotopic composition in Lake Michigan rivermouths

Rivermouth ecosystems are areas where tributary waters mix with lentic near-shore waters and provide habitat for many Laurentian Great Lakes fish and wildlife species. Rivermouths are the interface between terrestrial activities that influence rivers and the ecologically important nearshore. Stable isotopes of nitrogen (N) and carbon (C) in consumers were measured from a range of rivermouths systems to address two questions: 1) What is the effect of rivermouth ecosystems and land cover on the isotopic composition of N available to rivermouth consumers? 2) Are rivermouth consumers composed of lake-like or river-like C? For question 1, data suggest that strong relationships between watershed agriculture and consumer N are weakened or eliminated at the rivermouth, in favor of stronger relationships between consumer N and depositional areas that may favor denitrification. For question 2, despite apparently large riverine inputs, consumers only occasionally appear river-like. More often consumers seem to incorporate large amounts of C from either the nearshore or primary production within the rivermouth itself. Rivermouths appear to be active C and N processing environments, thus necessitating their explicit incorporation into models estimating nearshore loading and possibly contributing to their importance to Great Lakes biota.

Lake Michigan

Use of land surface remotely sensed satellite and airborne data for environmental exposure assessment in cancer research

In recent years, geographic information systems (GIS) have increasingly been used for reconstructing individual-level exposures to environmental contaminants in epidemiological research. Remotely sensed data can be useful in creating space-time models of environmental measures. The primary advantage of using remotely sensed data is that it allows for study at the local scale (e.g., residential level) without requiring expensive, time-consuming monitoring campaigns. The purpose of our study was to identify how land surface remotely sensed data are currently being used to study the relationship between cancer and environmental contaminants, focusing primarily on agricultural chemical exposure assessment applications. We present the results of a comprehensive literature review of epidemiological research where remotely sensed imagery or land cover maps derived from remotely sensed imagery were applied. We also discuss the strengths and limitations of the most commonly used imagery data (aerial photographs and Landsat satellite imagery) and land cover maps.

Journal of Exposure Science and Environmental Epid

Metabolism of niclosamide in sediment and water systems

A series of experiments analyzed the kinetics and mechanisms of [ 14C]niclosamide degradation. The aerobic aquatic metabolism of [ 14C]niclosamide was studied in nonsterile river water/sediment mixtures. Test systems, maintained under aerobic conditions, were treated with niclosamide and incubated in the dark at 25.0 ?? 1.0 ??C for 30 days. Half-lives of 4.9 and 5.4 days were calculated for the chlorosalicylic acid- and chloronitroaniline-labeled test systems, respectively. From 0 to 21 days after treatment (DAT), the only metabolism product observed in either test system was aminoniclosamide. At the final sampling interval, five peaks were resolved from the chlorosalicylic acid label, and three peaks were resolved from the chloronitroaniline label test substance. By 30 DAT, sediment-bound residues represented ???70% of the observed radioactivity. For the anaerobic aquatic metabolism of [14C]niclosamide, test systems were incubated under anaerobic conditions for 365 days. Half-lives of 0.65 day for the chlorosalicylic acid label and 2.79 days for the chloronitroaniline label were calculated. From 0 to 3 DAT, niclosamide was first transformed into aminoniclosamide. Aminoniclosamide is readily formed, as it was observed in the chlorosalicylic acid label 0 DAT sampling. Several minor metabolites were observed in the water and sediment extracts. None of these metabolites were formed to a significant amount until the parent niclosamide dissipated below the detection limit. Two of the byproducts from these metabolism studies are polar unknowns eluting at 3 and 5 min by HPLC, similar to the unknowns observed in aqueous photolysis studies.

Journal of Agricultural and Food Chemistry

Adaptive management for soil ecosystem services

Ecosystem services provided by soil include regulation of the atmosphere and climate, primary (including agricultural) production, waste processing, decomposition, nutrient conservation, water purification, erosion control, medical resources, pest control, and disease mitigation. The simultaneous production of these multiple services arises from complex interactions among diverse aboveground and belowground communities across multiple scales. When a system is mismanaged, non-linear and persistent losses in ecosystem services can arise. Adaptive management is an approach to management designed to reduce uncertainty as management proceeds. By developing alternative hypotheses, testing these hypotheses and adjusting management in response to outcomes, managers can probe dynamic mechanistic relationships among aboveground and belowground soil system components. In doing so, soil ecosystem services can be preserved and critical ecological thresholds avoided. Here, we present an adaptive management framework designed to reduce uncertainty surrounding the soil system, even when soil ecosystem services production is not the explicit management objective, so that managers can reach their management goals without undermining soil multifunctionality or contributing to an irreversible loss of soil ecosystem services.

Journal of Environmental Management

Crop classification modelling using remote sensing and environmental data in the Greater Platte River Basin, USA

With an ever expanding population, potential climate variability and an increasing demand for agriculture-based alternative fuels, accurate agricultural land-cover classification for specific crops and their spatial distributions are becoming critical to researchers, policymakers, land managers and farmers. It is important to ensure the sustainability of these and other land uses and to quantify the net impacts that certain management practices have on the environment. Although other quality crop classification products are often available, temporal and spatial coverage gaps can create complications for certain regional or time-specific applications. Our goal was to develop a model capable of classifying major crops in the Greater Platte River Basin (GPRB) for the post-2000 era to supplement existing crop classification products. This study identifies annual spatial distributions and area totals of corn, soybeans, wheat and other crops across the GPRB from 2000 to 2009. We developed a regression tree classification model based on 2.5 million training data points derived from the National Agricultural Statistics Service (NASS) Cropland Data Layer (CDL) in relation to a variety of other relevant input environmental variables. The primary input variables included the weekly 250 m US Geological Survey Earth Observing System Moderate Resolution Imaging Spectroradiometer normalized differential vegetation index, average long-term growing season temperature, average long-term growing season precipitation and yearly start of growing season. An overall model accuracy rating of 78% was achieved for a test sample of roughly 215 000 independent points that were withheld from model training. Ten 250 m resolution annual crop classification maps were produced and evaluated for the GPRB region, one for each year from 2000 to 2009. In addition to the model accuracy assessment, our validation focused on spatial distribution and county-level crop area totals in comparison with the NASS CDL and county statistics from the US Department of Agriculture (USDA) Census of Agriculture. The results showed that our model produced crop classification maps that closely resembled the spatial distribution trends observed in the NASS CDL and exhibited a close linear agreement with county-by-county crop area totals from USDA census data ( R 2 = 0.90).

Greater Platte River Basin

The human dimension of fire regimes on Earth

Humans and their ancestors are unique in being a fire‐making species, but ‘natural’ (i.e. independent of humans) fires have an ancient, geological history on Earth. Natural fires have influenced biological evolution and global biogeochemical cycles, making fire integral to the functioning of some biomes. Globally, debate rages about the impact on ecosystems of prehistoric human‐set fires, with views ranging from catastrophic to negligible. Understanding of the diversity of human fire regimes on Earth in the past, present and future remains rudimentary. It remains uncertain how humans have caused a departure from ‘natural’ background levels that vary with climate change. Available evidence shows that modern humans can increase or decrease background levels of natural fire activity by clearing forests, promoting grazing, dispersing plants, altering ignition patterns and actively suppressing fires, thereby causing substantial ecosystem changes and loss of biodiversity. Some of these contemporary fire regimes cause substantial economic disruptions owing to the destruction of infrastructure, degradation of ecosystem services, loss of life, and smoke‐related health effects. These episodic disasters help frame negative public attitudes towards landscape fires, despite the need for burning to sustain some ecosystems. Greenhouse gas‐induced warming and changes in the hydrological cycle may increase the occurrence of large, severe fires, with potentially significant feedbacks to the Earth system. Improved understanding of human fire regimes demands: (1) better data on past and current human influences on fire regimes to enable global comparative analyses, (2) a greater understanding of different cultural traditions of landscape burning and their positive and negative social, economic and ecological effects, and (3) more realistic representations of anthropogenic fire in global vegetation and climate change models. We provide an historical framework to promote understanding of the development and diversification of fire regimes, covering the pre‐human period, human domestication of fire, and the subsequent transition from subsistence agriculture to industrial economies. All of these phases still occur on Earth, providing opportunities for comparative research.

Journal of Biogeography