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Efficacy and toxicity of iodine disinfection of Atlantic salmon eggs

Recent interest in the restoration of Atlantic salmon Salmo salar in the Great Lakes has given rise to new culture techniques and management programs designed to reduce pathogen transmission while stabilizing and enhancing wild populations. We examined the toxicity of iodine to Atlantic salmon eggs and its effectiveness as a disinfectant against bacteria on egg surfaces. We spawned and fertilized eight gravid Atlantic salmon from Cayuga Lake, New York, and exposed their eggs to 10 concentrations of iodine (5, 10, 50, 75, 100, 500, 750, 1,000, 5,000, and 7,500 mg/L) for 30 min during water hardening. An additional subsample of unfertilized eggs was also exposed to some of the same concentrations of iodine (5, 10, 50, 75, and 100 mg/L) to determine the efficiency of disinfection. Viable eggs were only obtained from four females. Survival of eggs to the eyed stage and hatch tended to be reduced at iodine concentrations of 50 and 75 mg/L and was significantly reduced at concentrations of 100 mg/L iodine or more. We calculated the concentrations of iodine that killed 50% of the Atlantic salmon eggs at eye-up and hatch to be 175 and 85 mg/L, respectively. Aeromonas veronii, A. schubertii, A. hydrophila, A. caviae, Plesiomonas shiggeloides , and Citrobacter spp. were the predominant bacteria present on the surface of green eggs and were significantly reduced by an iodine immersion. The use of iodine as a disinfectant on Atlantic salmon eggs was effective at low concentrations (50–75 mg/L), for which toxicity to Atlantic salmon was minimal.

North American Journal of Aquaculture↗

Surface-water quality at fixed sites in the Western Lake Michigan Drainages, Wisconsin and Michigan, and the effects of natural and human factors, 1993-95

Streamwater samples were collected from April 1993 through July 1995 at 11 fixed sites in the Western Lake Michigan Drainages Study Unit of the U.S. Geological Survey's National Water-Quality Assessment Program. Water samples were collected monthly at all Fixed Sites, and an additional two to four samples were collected each year during periods of high flow. Streamflow was monitored continuously at the Fixed Sites for the duration of the study period. This report describes field techniques used to collect the water samples, and the analytical methods used for laboratory analyses, statistical analyses of the data, and an attempt to determine the effect of natural and anthropogenic factors on concentrations of nutrients and selected major ions and suspended solids. Locations of eight of the Fixed Sites were selected to represent areas with unique combinations of land use/land cover, surficial deposits, and bedrock geology and are referred to as 'indicator sites.' The remaining three sites were located near the mouths of major rivers and are referred to as 'integrator sites.' The integrator sites represent a large part of the total flow from the Study Unit to Green Bay and western Lake Michigan, and drain various combinations of land use, bedrock, and surficial deposits. These data indicate that land use and surficial deposits may be the primary factors affecting nitrate and total phosphorus concentrations in this Study Unit. Median concentrations of nitrate at the forested sites were less than the National Median Concentration (NMC), and those at urban fixed sites were similar to the NMC. Median nitrate concentrations at the Tomorrow River, North Branch Milwaukee River, and Duck Creek agricultural indicator sites were twice the NMC, but median concentrations at the remaining agricultural indicator sites were similar to the NMC. Nitrate concentrations at one agricultural indicator site exceeded the U. S. Environmental Protection Agency (USEPA) maximum contaminant level in three run-off samples in the growing seasons of 1994 and 1995. Median concentrations of total phosphorus at the forested indicator sites were below the NMC. Tomorrow River was the only agricultural indicator site where the median total-phosphorus concentration was less than the NMC; median concentrations at the remaining agricultural Fixed Sites were similar to the NMC and exceeded 0.1 mg/L, the USEPA suggested total-phosphorus concentration in flowing water. The USEPA recommends that total-phosphorus concentration not exceed this limit to discourage excessive aquatic plant growth in flowing waters. Median total-phosphorus concentration at the urban indicator site was less than the urban NMC. Median concentrations for both nitrate and total phosphorus at the mouth of the Fox River and the Milwaukee River integrator sites were similar to the NMC for the dominant land use, agriculture, within their basins, and were lower than that at the Menominee River integrator site with a dominant forest land use. During this study, potassium concentrations were generally highest in areas of clay-dominated surficial deposits, silica was generally highest in areas of sandy surficial deposits, iron generally highest in areas of igneous/metamorphic bedrock, and calcium generally highest in areas of carbonate bedrock. The highest median fluoride concentration occurred at an urban site that receives treated water.

Michigan, Wisconsin↗

High frequency radar measurements of tidal currents flowing through San Pablo Strait, San Francisco Bay

High frequency (HF) radar measurements of the surface current averaged over the upper 0.5 m in San Pablo Strait were compared with current meter measurements of the subsurface current made at 9.4 m below mean lower low water (MLLW) over two 12.4-h tidal cycles. After averaging the radar and current meter data over two tidal cycles, a southerly (ebbing direction) surface current of 32 cm·s −1 was deduced from the radar measurements and a northerly (flooding direction) subsurface current of 7 cm·s −1 from the current meter measurements. This nontidal flow is maintained by freshwater discharge from the Sacramento–San Joaquin Rivers into Suisun and San Pablo Bays. The radar measurement technique provides quantitative estimates of the surface currents that previously were determined only from surface drifter studies.

Limnology and Oceanography↗

Evapotranspiration from selected fallowed agricultural fields on the Tule Lake National Wildlife Refuge, California, during May to October 2000

An investigation of evapotranspiration, vegetation quantity and composition, and depth to the water table below the land surface was made at three sites in two fallowed agricultural lots on the 15,800-hectare Tule Lake National Wildlife Refuge in northern California during the 2000 growing season. All three sites had been farmed during 1999, but were not irrigated since the 1999 growing season. Vegetation at the lot C1B and lot 6 stubble sites included weedy species and small grain plants. The lot 6 cover crop site supported a crop of cereal rye that had been planted during the previous winter. Percentage of coverage by live vegetation ranged from 0 to 43.2 percent at the lot C1B site, from approximately 0 to 63.2 percent at the lot 6 stubble site, and it was estimated to range from 0 to greater than 90 percent at the lot 6 cover crop site. Evapotranspiration was measured using the Bowen ratio energy balance technique and it was estimated using a model that was based on the Priestley-Taylor equation and a model that was based on reference evapotranspiration with grass as the reference crop. Total evapotranspiration during May to October varied little among the three evapotranspiration measurement sites, although the timing of evapotranspiration losses did vary among the sites. Total evapotranspiration from the lot C1B site was 426 millimeters, total evapotranspiration from the lot 6 stubble site was 444 millimeters, and total evapotranspiration from the lot 6 cover crop site was 435 millimeters. The months of May to July accounted for approximately 78 percent of the total evapotranspiration from the lot C1B site, approximately 63 percent of the evapotranspiration from the lot 6 stubble site, and approximately 86 percent of the total evapotranspiration from the lot 6 cover crop site. Estimated growing season precipitation accounted for 16 percent of the growing-season evapotranspiration at the lot C1B site and for 17 percent of the growing-season evapotranspiration at the lot 6 stubble and cover crop sites. The ratio of evapotranspiration rate to the reference evapotranspiration rate was strongly correlated with percentage of site coverage by vegetation at the lot C1B and lot 6 stubble sites (correlation coefficient = 0.95, sample size = 6), where percentage of site coverage was determined from quantitative vegetation surveys. It is concluded that evapotranspiration was mediated by the vegetation at all three sites, and that the differences in seasonal timing of evapotranspiration losses were caused by differences in timing of vegetation growth and development and senescence among the sites. Depth to the water table below the land surface at lot C1B ranged from 0.67 meters in early July to greater than 1.39 meters in late August. Depth to the water table at lot 6 ranged from 0.77 meter in late May to greater than 1.40 meters in late August.

Water-Resources Investigations Report↗

Molluscan isotope sclerochronology in marine palaeoclimatology: Taxa, technique and timespan issues

Study of the accretionary biomineralised hardparts of organisms (sclerochronology) can make a useful contribution to palaeoclimatology. Ontogenetic sequences of isotopic data (δ 18 O and Δ 47 values) from the shells of marine molluscs are a source of information on seasonal sea-surface temperatures that can be used for detailed and rigorous evaluation of the outputs of numerical climate models. In situations where there is significant seasonality, and where shell preservation is adequate, accurate information about winter and summer surface temperature can be obtained from shallow-water benthic forms (bivalves and gastropods), in particular the early ontogeny of fast-growing species. Accurate information about winter surface temperature can also be obtained from individuals that lived at mid-shelf depths (20–40 m), but summer seafloor values from these need upward adjustment to derive a plausible surface temperature if thermal stratification of the water column occurs in this season. Ontogenetic δ 18 O profiles from planktonic pteropod gastropods are a potential source of insight into seasonal surface temperatures in the ocean basins; these organisms merit investigation for provision of information to complement shelf data. Temperature profiles constructed from shell δ 18 O require an estimate of the δ 18 O value of ambient seawater, which can be derived by back-calculation from the Δ 47 -temperature supplied by the same shell material. Alternatively, through appropriate sampling and data processing, seasonal temperatures can be obtained directly from Δ 47 profiles. Climate parameters are defined in terms of the mean state over a period of 30 consecutive years, a statistic (e.g., for seasonal temperatures) which can be derived from the long isotopic temperature records obtainable from bivalve species that live for many tens or hundreds of years. Efforts should be made to acquire such records, especially averaged data from crossdated shells, to specify climate parameters for precise times in the past. Information for precise times would be of particular value for icehouse intervals like the late Cenozoic, characterised by high frequency (high amplitude) climate fluctuation. Short records from non-crossdated shells can nevertheless provide useful insights into climate, particularly if a large dataset is obtained, supplying a reliable picture of the mean state and range of variation in climate parameters over the interval represented by the shells.

Quaternary Science Reviews↗

Prediction of suspended-sediment concentrations at selected sites in the Fountain Creek watershed, Colorado, 2008-09

In 2008, the U.S. Geological Survey (USGS), in cooperation with Pikes Peak Area Council of Governments, Colorado Water Conservation Board, Colorado Springs City Engineering, and the Lower Arkansas Valley Water Conservancy District, began a small-scale pilot study to evaluate the effectiveness of the use of a computational model of streamflow and suspended-sediment transport for predicting suspended-sediment concentrations and loads in the Fountain Creek watershed in Colorado. Increased erosion and sedimentation damage have been identified by the Fountain Creek Watershed Plan as key problems within the watershed. A recommendation in the Fountain Creek Watershed plan for management of the basin is to establish measurable criteria to determine if progress in reducing erosion and sedimentation damage is being made. The major objective of this study was to test a computational method to predict local suspended-sediment loads at two sites with different geomorphic characteristics in order to evaluate the feasibility of using such an approach to predict local suspended-sediment loads throughout the entire watershed. Detailed topographic surveys, particle-size data, and suspended-sediment samples were collected at two gaged sites: Monument Creek above Woodmen Road at Colorado Springs, Colorado (USGS gage 07103970), and Sand Creek above mouth at Colorado Springs, Colorado (USGS gage 07105600). These data were used to construct three-dimensional computational models of relatively short channel reaches at each site. The streamflow component of these models predicted a spatially distributed field of water-surface elevation, water velocity, and bed shear stress for a range of stream discharges. Using the model predictions, along with measured particle sizes, the sediment-transport component of the model predicted the suspended-sediment concentration throughout the reach of interest. These computed concentrations were used with predicted flow patterns and channel morphology to determine fluxes of suspended sediment for the median particle size and for the measured range of particle sizes in the channel. Three different techniques were investigated for making the suspended-sediment predictions; these techniques have varying degrees of reliance on measured data and also have greatly differing degrees of complexity. Based on these data, the calibrated Rouse method provided the best balance between accuracy and both computational and data collection costs; the presence of substantial washload was the primary factor in eliminating the simpler and the more complex techniques. Based on this work, using the selected technique at additional sites in the watershed to determine relative loads and source areas appears plausible. However, to ensure that the methodology presented in this report yields reasonable results at other selected sites in the basin, it is necessary to collect additional verification data sets at those locations.

Colorado↗

Shallow groundwater quality and geochemistry in the Fayetteville Shale gas-production area, north-central Arkansas, 2011

The Mississippian Fayetteville Shale serves as an unconventional gas reservoir across north-central Arkansas, ranging in thickness from approximately 50 to 550 feet and varying in depth from approximately 1,500 to 6,500 feet below the ground surface. Primary permeability in the Fayetteville Shale is severely limited, and successful extraction of the gas reservoir is the result of advances in horizontal drilling techniques and hydraulic fracturing to enhance and develop secondary fracture porosity and permeability. Drilling and production of gas wells began in 2004, with a steady increase in production thereafter. As of April 2012, approximately 4,000 producing wells had been completed in the Fayetteville Shale. In Van Buren and Faulkner Counties, 127 domestic water wells were sampled and analyzed for major ions and trace metals, with a subset of the samples analyzed for methane and carbon isotopes to describe general water quality and geochemistry and to investigate the potential effects of gas-production activities on shallow groundwater in the study area. Water-quality analyses from this study were compared to historical (pregas development) shallow groundwater quality collected in the gas-production area. An additional comparison was made using analyses from this study of groundwater quality in similar geologic and topographic areas for well sites less than and greater than 2 miles from active gas-production wells. Chloride concentrations for the 127 groundwater samples collected for this study ranged from approximately 1.0 milligram per liter (mg/L) to 70 mg/L, with a median concentration of 3.7 mg/L, as compared to maximum and median concentrations for the historical data of 378 mg/L and 20 mg/L, respectively. Statistical analysis of the data sets revealed statistically larger chloride concentrations (p-value <0.001) in the historical data compared to data collected for this study. Chloride serves as an important indicator parameter based on its conservative transport characteristics and relatively elevated concentrations in production waters associated with gas extraction activities. Major ions and trace metals additionally had lower concentrations in data gathered for this study than in the historical analyses. Additionally, no statistical difference existed between chloride concentrations from water-quality data collected for this study from 94 wells located less than 2 miles from a gas-production well and 33 wells located 2 miles or more from a gas-production well; a Wilcoxon rank-sum test showed a p-value of 0.71. Major ion chemistry was investigated to understand the effects of geochemical and reduction-oxidation (redox) processes on the shallow groundwater in the study area along a continuum of increased rock-water interaction represented by increases in dissolved solids concentration. Groundwater in sandstone formations is represented by a low dissolved solids concentration (less than 30 mg/L) and slightly acidic water type. Shallow shale aquifers were represented by dissolved solids concentrations ranging upward to 686 mg/L, and water types evolving from a dominantly mixed-bicarbonate and calcium-bicarbonate to a strongly sodium-bicarbonate water type. Methane concentration and carbon isotopic composition were analyzed in 51 of the 127 samples collected for this study. Methane occurred above a detection limit of 0.0002 mg/L in 32 of the 51 samples, with concentrations ranging upward to 28.5 mg/L. Seven samples had methane concentrations greater than or equal to 0.5 mg/L. The carbon isotopic composition of these higher concentration samples, including the highest concentration of 28.5 mg/L, shows the methane was likely biogenic in origin with carbon isotope ratio values ranging from -57.6 to -74.7 per mil. Methane concentrations increased with increases in dissolved solids concentrations, indicating more strongly reducing conditions with increasing rock-water interaction in the aquifer. As such, groundwater-quality data collected for this study indicate that groundwater chemistry in the shallow aquifer system in the study area is a result of natural processes, beginning with recharge of dilute atmospheric precipitation and evolution of observed groundwater chemistry through rock-water interaction and redox processes.

Arkansas↗

Spatial and temporal distribution of bacterial indicators and microbial-source tracking within Tumacácori National Historical Park and the upper Santa Cruz River, southern Arizona and northern Mexico, 2015–2016

Tumacácori National Historical Park (TUMA) in southern Arizona protects the culturally important Mission San José de Tumacácori, while also managing a part of the ecologically diverse riparian corridor of the Santa Cruz River. The quality of the water flowing through depends solely on upstream watershed activities, and among the water-quality issues concerning TUMA is the microbiological pathogens in the river introduced by human and animal sources that pose a significant human health risk to employees and visitors. The U.S. Geological Survey (USGS) conducted a 3-year study to understand the sources, timing, and distribution of the fecal-indicator bacteria Escherichia coli ( E. coli ) within TUMA and the upstream watershed. The information provided in this investigation is a result of a comprehensive approach to quantify the spatial and temporal variability of E. coli and suspended sediment in the Upper Santa Cruz River Watershed. Several types of flow were sampled from base flow to flood flow and at high frequency intervals (rise, peak, and recession) to determine daily variability, as well as seasonal variability. Hydrologic data collection and estimation techniques were used to establish a hydrologic relation with E. coli and suspended sediment. Furthermore, source tracking was used to describe the potential sources of E. coli . Models were developed that are expected to be useful for predicting E. coli concentrations to help TUMA managers understand instantaneous conditions to keep the public and staff informed about potentially harmful water-quality conditions. In addition, the concentration, flux, and source information will provide more accurate data for other surface-water modeling and can be useful in the development of total maximum daily load standards. This will help TUMA describe the water-quality conditions at the park and waters flowing through the park, as well as prioritize and help carry out future best-management actions to address these issues.

Tumacácori National Historical Park, Upper Santa C↗

Physics-based satellite-derived bathymetry (SDB) using Landsat OLI images

The estimation of depth in optically shallow waters using satellite imagery can be efficient and cost-effective. Active sensors measure the distance traveled by an emitted laser pulse propagating through the water with high precision and accuracy if the bottom peak intensity of the waveform is greater than the noise level. However, passive optical imaging of optically shallow water involves measuring the radiance after the sunlight undergoes downward attenuation on the way to the sea floor, and the reflected light is then attenuated while moving back upward to the water surface. The difficulty of satellite-derived bathymetry (SDB) arises from the fact that the measured radiance is a result of a complex association of physical elements, mainly the optical properties of the water, bottom reflectance, and depth. In this research, we attempt to apply physics-based algorithms to solve this complex problem as accurately as possible to overcome the limitation of having only a few known values from a multispectral sensor. Major analysis components are atmospheric correction, the estimation of water optical properties from optically deep water, and the optimization of bottom reflectance as well as the water depth. Specular reflection of the sky radiance from the water surface is modeled in addition to the typical atmospheric correction. The physical modeling of optically dominant components such as dissolved organic matter, phytoplankton, and suspended particulates allows the inversion of water attenuation coefficients from optically deep pixels. The atmospheric correction and water attenuation results are used in the ocean optical reflectance equation to solve for the bottom reflectance and water depth. At each stage of the solution, physics-based models and a physically valid, constrained Levenberg–Marquardt numerical optimization technique are used. The physics-based algorithm is applied to Landsat Operational Land Imager (OLI) imagery over the shallow coastal zone of Guam, Key West, and Puerto Rico. The SDB depths are compared to airborne lidar depths, and the root mean squared error (RMSE) is mostly less than 2 m over water as deep as 30 m. As the initial choice of bottom reflectance is critical, along with the bottom reflectance library, we describe a pure bottom unmixing method based on eigenvector analysis to estimate unknown site-specific bottom reflectance.

Remote Sensing↗

Evaluating environmental and economic consequences of alternative pest management strategies: results of modeling workshops

The U.S. Environmental Protection Agency (EPA) needs a comprehensive method to evaluate the human health and environmental effects of alternative agricultural pest management strategies. This project explored the utility of Adaptive Environmental Assessment (AEA) techniques for meeting this need. The project objectives were to produce models for environmental impact analysis, improve communications, identify research needs and data requirements, and demonstrate a process for resolving conflicts. The project was structured around the construction (in an initial 2 1/2-day workshop) and examination (in a second 2 1/2-day workshop) of a simulation model of a corn agroecosystem. The model conceptualized at the first workshop simulates the effect of corn agrecosystem decisions on crop production, economic returns, and environmental indicators. The model is composed of five interacting submodels: 1) a Production Strategies submodel which makes decisions concerning tillage, planting, fertilizer and pesticide applications, and harvest; 2) a Hydrology/Chemical Transport submodel which represents soil hydrology, erosion, and concentrations of fertilizers and pesticides in the soil, runoff, surface waters, and percolation; 3) a Vegetation submodel which simulates growth of agricultural crops (corns and soybeans) and weeds; 4) a Pests submodel which calculates pest population levels and resulting crop damage; and 5) an Environmental Effects submodel which calculates indicators of potential fish kills, human health effects, and wildlife habitat. The most persistent data gaps encountered in quantifying the model were coefficients to relate environmental consequences to alternative pest management strategies. While the model developed in the project is not yet accurate enough to be used for real-world decisions about the use of pesticides on corn, it does contain the basic structure upon which such a model could be built. More importantly at this stage of development, the project has shown that very complex systems can be modeled in short periods of time and that the process of building such models increases understanding among disciplinary specialists and between diverse institutional interests. This process can be useful to EPA as the agency cooperates with other institutions to meet its responsibilities in less costly ways. Activities at the second 2 1/2-day workshop included a review of the model, incorporation of necessary corrections, simulation of policy scenarios, and examination of techniques to address remaining institutional conflicts. Participants were divided into three groups representing environmental, production or industry, and regulatory interests. Each group developed scenarios that would be most appealing to their particular interest and the scenarios were simulated by the agroecosystem computer model. Negotiators from each of the interest groups decided whether a hypothetical herbicide should be relabeled and if certain restrictions should be imposed on its use. Other participants functioned as experts and consultants on caucus teams. A solution to the hypothetical problem was successfully negotiated. Workshop participants and project staff agreed that the model and processes developed during the project should be used in training students, extension specialists, farmers, researchers, and chemical producers in collaborative problem solving methods. More productive research can be planned, and more realistic models of complex systems can be built in this way. More importantly, greater trust of decisionmakers in computer models, better understanding by technical experts about disciplines other than their own, and improved cooperation between institutional interests can be achieved. This trust, understanding, and cooperation are critical ingredients in solving problems that are too complex to be resolved by independent disciplinary activity and unilateral decision authority.

Report↗

Integrating science and resource management in Tampa Bay, Florida

Tampa Bay is recognized internationally for its remarkable progress towards recovery since it was pronounced "dead" in the late 1970s. Due to significant efforts by local governments, industries and private citizens throughout the watershed, water clarity in Tampa Bay is now equal to what it was in 1950, when population in the watershed was less than one-quarter of what it is today. Seagrass extent has increased by more than 8,000 acres since the mid-1980s, and fish and wildlife populations are increasing. Central to this successful turn-around has been the Tampa Bay resource management community's long-term commitment to development and implementation of strong science-based management strategies. Research institutions and agencies, including Eckerd College, the Florida Wildlife Commission Fish and Wildlife Research Institute, Mote Marine Laboratory, National Oceanic and Atmospheric Administration, the Southwest Florida Water Management District, University of South Florida, U.S. Environmental Protection Agency, U.S. Geological Survey, local and State governments, and private companies contribute significantly to the scientific basis of our understanding of Tampa Bay's structure and ecological function. Resource management agencies, including the Tampa Bay Regional Planning Council's Agency on Bay Management, the Southwest Florida Water Management District's Surface Water Improvement and Management Program, and the Tampa Bay Estuary Program, depend upon this scientific basis to develop and implement regional adaptive management programs. The importance of integrating science with management has become fully recognized by scientists and managers throughout the region, State and Nation. Scientific studies conducted in Tampa Bay over the past 10&ndash;15 years are increasingly diverse and complex, and resource management programs reflect our increased knowledge of geology, hydrology and hydrodynamics, ecology and restoration techniques. However, a synthesis of this research and its integration into resource management has not been prepared for Tampa Bay since the mid-1980s. The need for an up-to-date synthesis of Tampa Bay science and management has resulted in the production of this document. The U.S. Geological Survey recently completed a 5-year Tampa Bay Integrated Science Study, and the Tampa Bay Estuary Program updated the Comprehensive Conservation and Management Plan for Tampa Bay in 2006. These efforts build upon results of the many research and management studies and programs summarized here.

Florida↗

Measuring human-induced land subsidence from space

Satellite Interferometric Synthetic Aperture Radar (InSAR) is a revolutionary technique that allows scientists to measure and map changes on the Earth's surface as small as a few millimeters. By bouncing radar signals off the ground surface from the same point in space but at different times, the radar satellite can measure the change in distance between the satellite and ground (range change) as the land surface uplifts or subsides. Maps of relative ground-surface change (interferograms) are constructed from the InSAR data to help scientists understand how ground-water pumping, hydrocarbon production, or other human activities cause the land surface to uplift or subside. Interferograms developed by the USGS for study areas in California, Nevada, and Texas are used in this fact sheet to demonstrate some of the applications of InSAR to assess human-induced land deformation

Fact Sheet↗

Water and stream-sediment sampling techniques for use in uranium exploration

Methods of sampling water and stream sediments for uranium were established in this study. Water samples should be taken using a US DH-48 water sampler across the stream channel and should be filtered and acidified in situ. Stream sediments should be taken as a composite sample up and across the axis of the channel. Only sediment fractions less than 90 ?m (170 mesh) should be analyzed for uranium. The elements As, Ca, Al, B, Mg, K, and Na exhibit a positive correlation with uranium in surface waters, while a much larger suite of elements exhibit a positive correlation with uranium in stream sediments: K, Mn, Mg, Ti, Ca, Al, Fe, Pb, Cr, Y, Zr, Li, Zn, Th, and As. Analyses have revealed that anomalies detected in either the dissolved or suspended fractions of water, or the stream sediments, are frequently not reflected in the other two; hence, all three should be sampled and analyzed.

Open-File Report↗

Geophysical Interpretations of the Southern Espanola Basin, New Mexico, That Contribute to Understanding Its Hydrogeologic Framework

The southern Espanola basin consists of a westward- and northward-thickening wedge of rift fill, composed primarily of Santa Fe Group sediments, that serves as an important aquifer for the city of Santa Fe and surrounding areas. Detailed aeromagnetic surveys were flown to better understand ground-water resources in this aquifer. This report presents a synthesis of these data with gravity data and other constraints. The interpretations were accomplished using qualitative interpretation, state-of-art data analysis techniques, and two- and three-dimensional modeling. The results depict the presence of and depth to many geologic features that have hydrogeologic significance, including shallow faults, different types of igneous units, and basement rocks. The results are presented as map interpretations, geophysical profile models, and a digital surface that represents the base and thickness of Santa Fe Group sediments, as well as vector files of some volcanic features and faults.

Professional Paper↗

Simulation of zones of groundwater contribution to wells south of the Naval Weapons Industrial Reserve Plant in Bethpage, New York

A steady-state three-dimensional groundwater-flow model that simulates present conditions was coupled with the particle-tracking program MODPATH to delineate zones of contribution to wells pumping from the Magothy aquifer near a chlorinated volatile organic compound (VOC) plume. This modeling was part of a study by the U.S. Geological Survey in cooperation with the Naval Facilities Engineering Command to delineate groundwater near the Naval Weapons Industrial Reserve Plant in Bethpage, New York. Because rates of advection within the coarse-grained sediments typically exceed 0.1 foot per day, transport by dispersion and (or) diffusion was assumed to be negligible. Resulting zones of contribution are complex shapes, influenced by hydrogeologic features including confining beds and a basal gravel zone, and the interplay of nearby hydrologic stresses. The use of two particle tracking techniques identified zones of contribution to wells. Particles are backtracked from pumping well screens, and particles are forward tracked from the location of a VOC plume, as defined by surfaces of equal total VOC concentration. During any period of 5 years or less, about 1 to 3 percent of particles backtracked from pumping wells within a focus area intersected the 5-part per billion (ppb) VOC plume shell, indicating that the vast majority of particles were not sourced from the plume. During 5 years or less, none of the particles backtracked from pumping wells intersected the 50-ppb VOC plume shell. Forward-tracking techniques identified the fate of water within the VOC plume after 5 years as it moves toward ultimate well capture and (or) discharge to model constant head and drain boundaries. Out of 4,813 forward tracked particles started within the 50-ppb VOC plume shell, 1 forward-tracked particle was captured by well ANY8480. Out of 22,958 forward tracked particles started within the 5-ppb VOC plume shell, 100 were captured by production wells (less than 1 percent). The subset of forward pathlines that represent well plume capture are similar in number and shape to those of backtracked pathlines. Model simulations were conducted to assess uncertainties and improve understanding of how variability in hydraulic properties, pumpage rates, and maximum particle traveltime affect delineation of zones of contribution. By use of driller’s’ logs, a transitional probability approach generated nine alternative realizations of heterogeneity within the Magothy aquifer to assess uncertainty in model representation. Fine-grained sediments with low hydraulic conductivity were realized as laterally discontinuous, thickening towards the south, and comprising about 27 percent of the total aquifer volume within the transitional probability subgrid. Model simulations with alternative pumpage rates, porosity terms, and alternative maximum particle traveltime were also used to demonstrate how the size and shape of zones of contribution may vary.

New York↗

Assessing the presence of current-use pesticides in mid-elevation Sierra Nevada streams using passive samplers, California, 2018–19

Passive sampler devices were deployed in six northern California streams five times between November 2018 and December 2019 to measure the presence or absence of current-use pesticides in surface water. In the targeted areas, there are reported pesticide uses for agriculture, commercial forestry, and rights of way maintenance along with unreported pesticide use at private residences and cannabis grow sites. The sites sampled in this study were not previously monitored for current-use pesticides. Streams in the Sierra Nevada foothills of northern California are important habitats for many sensitive species including salmonids, but the logistics of sampling these areas can be difficult using traditional water-quality sampling techniques, especially when sampling watersheds where contaminant transport is episodic. Chemcatcher passive sampling devices and silicone bands were deployed in these areas to concentrate pesticides for days to weeks at a time. The U.S. Geological Survey, in cooperation with the Central Valley Regional Water Quality Control Board, was responsible for developing passive sampler field deployment and laboratory analytical methods for current-use pesticides, providing pesticide measurements from streams in the study region, and determining how well passive samplers detect pesticides in these environments. Six sites were monitored during the study, and passive sampler extracts were analyzed for a total 155 current-use pesticides in this study. A total of 19 out of the 155 pesticides including 9 insecticides, 5 fungicides, and 5 herbicides were detected in extracts from passive samplers. The most frequently detected pesticides were the herbicides hexazinone and dithiopyr, the insecticides bifenthrin and methoxyfenozide, and the fungicide azoxystrobin.

California↗

Evaluation of the hydrologic system and selected water-management alternatives in the Owens Valley, California

The Owens Valley, a long, narrow valley along the east side of the Sierra Nevada in east-central California, is the main source of water for the city of Los Angeles. The city diverts most of the surface water in the valley into the Owens River-Los Angeles Aqueduct system, which transports the water more than 200 miles south to areas of distribution and use. Additionally, ground water is pumped or flows from wells to supplement the surface-water diversions to the river- aqueduct system. Pumpage from wells needed to supplement water export has increased since 1970, when a second aqueduct was put into service, and local residents have expressed concerns that the increased pumping may have a detrimental effect on the environment and the native vegetation (indigenous alkaline scrub and meadow plant communities) in the valley. Native vegetation on the valley floor depends on soil moisture derived from precipitation and from the unconfined part of a multilayered ground-water system. This report, which describes the evaluation of the hydrologic system and selected water-management alternatives, is one in a series designed to identify the effects that ground-water pumping has on native vegetation and evaluate alternative strategies to mitigate any adverse effects caused by pumping. The hydrologic system of the Owens Valley can be conceptualized as having three parts: (1) an unsaturated zone affected by precipitation and evapotranspiration; (2) a surface-water system composed of the Owens River, the Los Angeles Aqueduct, tributary streams, canals, ditches, and ponds; and (3) a saturated ground-water system contained in the valley fill. Analysis of the hydrologic system was aided by development of a ground-water flow model of the "aquifer system," which is defined as the most active part of the ground-water system and which includes nearly all of the Owens Valley except for the area surrounding the Owens Lake. The model was calibrated and verified for water years 1963-88 and used to evaluate general concepts of the hydrologic system and the effects of past water-management practices. The model also was used to evaluate the likely effects of selected water-management alternatives designed to lessen the adverse effects of ground-water pumping on native vegetation. Results of the model simulations confirm that a major change in the hydrologic system was caused by the additional export of water from the valley beginning in 1970. Average ground-water pumpage increased by a factor of five, discharge from springs decreased almost to zero, reaches of the Owens River that previously had gained water from the aquifer system began losing water, and total evapotranspiration by native plants decreased by about 35 percent. Water-management practices as of 1988 were defined and evaluated using the model. Simulation results indicate that increased ground-water pumpage since 1985 for enhancement and mitigation projects within the Owens Valley has further stressed the aquifer system and resulted in declines of the water table and reduced evapotranspiration. Most of the water-table declines are beneath the western alluvial fans and in the immediate vicinity of production wells. The water-table altitude beneath the valley floor has remained relatively constant over time because of hydrologic buffers, such as evapotranspiration, springs, and permanent surface-water features. These buffers adjust the quantity of water exchanged with the aquifer system and effectively minimize variations in water-table altitude. The widespread presence of hydrologic buffers is the primary reason the water-table altitude beneath the valley floor has remained relatively constant since 1970 despite major changes in the type and location of ground-water discharge. Evaluation of selected water-management alternatives indicates that long-term variations in average runoff to the Owens Valley of as much as 10 percent will not have a significant effect on the water-table altitude. However, reductions in pumpage to an average annual value of about 75,000 acre-ft/yr are needed to maintain the water table at the same altitude as observed during water year 1984. A 9-year transient simulation of dry, average, and wet conditions indicates that the aquifer system takes several years to recover from increased pumping during a drought, even when followed by average and above-average runoff and recharge. Increasing recharge from selected tributary streams by additional diversion of high flows onto the alluvial fans, increasing artificial recharge near well fields, and allocating more pumpage to the Bishop area may be useful in mitigating the adverse effects on native vegetation caused by drought and short-term increases in pumpage. Analysis of the optimal use of the existing well fields to minimize drawdown of the water table indicates no significant lessening of adverse effects on native vegetation at any of the well fields at the end of a 1-year simulation. Some improvement might result from pumping from a few high-capacity wells in a small area, such as the Thibaut-Sawmill well field; pumping from the upper elevations of alluvial fans, such as the Bishop well field; or pumping in an area surrounded by irrigated lands, such as the Big Pine well field. Use of these water-management techniques would provide some flexibility in management from one year to another, but would not solve the basic problem that increased ground-water pumpage causes decreases in evapotranspiration and in the biomass of native vegetation. Furthermore, the highly transmissive and narrow aquifer system will transmit the effects of pumping to other more sensitive areas of the valley within a couple of years. Other possible changes in water management that might be useful in minimizing the short-term effects of pumping on native vegetation include sealing well perforations in the unconfined part of the aquifer system; rotating pumpage among well fields; continuing or renewing use of unlined surface-water features such as canals and ditches; developing recharge and extraction facilities in deeper volcanic deposits near Big Pine or in alluvial fan deposits along the east side of the valley; installing additional wells along the west side of the Owens Lake; and conjunctively using other ground-water basins between the Owens Valley and Los Angeles to store exported water for subsequent extraction and use during droughts.

Water Supply Paper↗

Intersection of wildfire and legacy mining poses risk to water quality

Mining and wildfires are both landscape disturbances that pose elevated and substantial hazards to water supplies and ecosystems due to increased erosion and transport of sediment, metals, and debris to downstream waters. The risk to water supplies may be amplified when these disturbances occur in the same watershed. This work describes mechanisms by which the intersection of mining and wildfire may lead to elevated metal concentrations in downstream waters: (1) conveyance of metal-rich ash and soil to surface waters, (2) increased dissolution and transport of dissolved metals due to direct contact of precipitation with mine waste, (3) increased erosion and transport of metal-rich sediment from mining waste, (4) remobilization of previously deposited metal-contaminated floodplain sediment by higher postfire flood flows, and (5) increased metal transport from underground mine workings. Predicted increases in wildfire size, frequency, and burn severity, together with the ongoing need for metal resources, indicate that improved mapping, monitoring, modeling, and mitigation techniques are needed to manage the geochemical hazard of the intersection of wildfire and mining and implications for water availability.

Environmental Science and Technology↗