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USGS2016

Physical, chemical, and biological characteristics of selected headwater streams along the Allegheny Front, Blair County, Pennsylvania, July 2011–September 2013

The Altoona Water Authority (AWA) obtains all of its water supply from headwater streams that drain western Blair County, an area underlain in part by black shale of the Marcellus Formation. Development of the shale-gas reservoirs will require new access roads, stream crossing, drill-pad construction, and pipeline installation, activities that have the potential to alter existing stream channel morphology, increase runoff and sediment supply, alter streamwater chemistry, and affect aquatic habitat. The U.S. Geological Survey, in cooperation with Altoona Water Authority and Blair County Conservation District, investigated the water quality of 12 headwater streams and biotic health of 10 headwater streams. Channel morphology was characterized at 10 of 12 stream sites using 500-foot (minimum) longitudinal profiles, four cross-sections each, and pebble counts. Channel slopes ranged from 0.008 in Poplar Run near Newry to 0.045 in Mill Run. In general, streams draining watersheds of 5 square miles or less and at higher elevation had the steepest slopes. On the basis of the median particle size, determined during pebble counts, the streambed substrate can be characterized as cobble (Mill Run, Bells Gap Run, Tipton Run, and Sink Run), a mix of gravel and cobble (South Poplar Run, Dry Gap Run, Glenwhite Run, Sugar Run, Blair Gap Run), and gravel (Poplar Run, Newry). Daily mean values of gage height were determined, and continuous (30-minute interval) data consisting of specific conductance and water temperature were collected, at four sites; each site showed typical seasonal fluctuations and the effects of precipitation. Streamflow affected discrete water-quality. Dissolved oxygen always increased with increased streamflow. Most cations (including barium and strontium), along with pH, specific conductance, and total dissolved solids, decreased with greater streamflow, reflecting the dilution effect of moderately acidic surface runoff and precipitation on groundwater discharge (base flow) into the stream channels. Concentrations of trace elements varied by constituent and streamflow. On the basis of the results of water-quality analyses for the selected constituents, the water quality in 9 of the 12 streams can be considered fair or attaining with no measured constituent exceeding a U.S. Environmental Protection Agency maximum or secondary contaminant level. Abandoned mine drainage (AMD) affects Glenwhite Run, Blair Gap Run, and Sugar Run. For Sugar Run, the AMD is reflected in the elevated iron concentration (greater than 300 micrograms per liter). Manganese concentrations greater than 50 micrograms per liter were measured in Glenwhite Run, Sugar Run, and Blair Gap Run. A mixing curve based upon chloride/bromide ratios for two end points—precipitation and deicing salts—indicate that deicing salt is migrating to the streams. A similar curve representative of late-emerging flowback water from Marcellus gas wells indicated that the surface-water samples had not been influenced by such brines. On the basis of the concentration of major ions, the streams in the study area generally had mixed cation and anion compositions. Calcium is the dominant cation in one stream. Carbonate and bicarbonate are the dominant anions for two streams, and sulfate is dominant in three streams. The remaining six streams do not have a dominant ion. Biotic health was characterized at 10 of 12 stream sites; the two sites excluded were established late in the study period (May 2013) for refinement of water quality in the headwaters of Poplar Run and the location of Marcellus Formation gas wells. On the basis of the Maryland Index of Biotic Integrity (MdIBI) for fish assemblages, 8 of 10 streams can be considered in fair health. Tipton Run had the highest MdIBI score (3.75) and the greatest number of native species. South Poplar Run had the lowest MdIBI score (1.75); pollution tolerant blacknose dace was dominant. On the basis of the Pennsylvania Department of Environmental Protection macroinvertebrate index of biotic integrity, 9 of 10 streams were characterized as attaining, with scores as high as 88.9 at Tipton Run. Only Sugar Run was characterized as impaired, with a score of 40.4.

Pennsylvania↗

USGS2015

Flooding in the Northeastern United States, 2011

Flooding in the Northeastern United States during 2011 was widespread and record setting. This report summarizes peak streamflows that were recorded by the U.S. Geological Survey (USGS) during separate flooding events in February, March, April, May, July, August, and September. The flooding of late April, which combined snowmelt and heavy rain and the floods associated with the tropical storms of late August and September, were the most severe and widespread. Precipitation totals from March to May for Pennsylvania, New York, and Vermont were documented as being the highest totals in 117 years of record. In late August, the heavy rains associated with Hurricane Irene produced widespread flooding in many parts of the Northeastern United States, which resulted in damage estimates in excess of $7 billion and approximately 45 deaths. In September, Tropical Storm Lee produced 6–12 inches of rain in parts of the Northeastern United States adding to the growing total of record peak streamflows set in 2011. The annual exceedance probability (AEP) for 327 streamgages in the Northeastern United States were computed using annual peak streamflow data through 2011 and are included in this report. The 2011 peak streamflow for 129 of those streamgages was estimated to have an AEP of less than or equal to 1 percent. Almost 100 of these peak streamflows were a result of the flooding associated with Hurricane Irene in late August 2011. More extreme than the 1-percent AEP, is the 0.2-percent AEP. The USGS recorded peak streamflows at 31 streamgages that equaled or exceeded the estimated 0.2-percent AEP during 2011. Collectively, the USGS recorded peak streamflows having estimated AEPs of less than 1 percent in Connecticut, Delaware, Maine, Maryland, Massachusetts, Ohio, Pennsylvania, New Hampshire, New Jersey, New York, and Vermont and new period-of-record peak streamflows were recorded at more than 180 streamgages resulting from the floods of 2011.

Connecticut, Delaware, Maine, Maryland, Massachuse↗

USGS2015

Water quality of groundwater and stream base flow in the Marcellus Shale Gas Field of the Monongahela River Basin, West Virginia, 2011-12

The Marcellus Shale gas field underlies portions of New York, Pennsylvania, Ohio, Virginia, Maryland, Tennessee, and West Virginia. Development of hydraulic fracturing and horizontal drilling technology led to extensive development of gas from the Marcellus Shale beginning about 2007. The need to identify and monitor changes in water-quality conditions related to development of the Marcellus Shale gas field prompted the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management, to document water quality for comparison with water quality in samples collected at a future date. The identification of change in water-quality conditions over time is more difficult if baseline water-quality conditions have not been documented. U.S. Geological Survey personnel sampled groundwater and surface water in West Virginia’s Monongahela River Basin during 2011–12. A groundwater survey, in which 39 wells and 2 springs were sampled, was conducted during June through September 2011. A base-flow survey was conducted during July through October 2012; 50 stream sites were sampled under base-flow conditions in this survey. Because additives to hydraulic fracturing fluids are variable and decrease in flowback water over a relatively short time, water-quality analyses for this study focused on documenting the water-quality characteristics typical of water from shallow aquifers; water derived from contact with the Marcellus Shale (flowback from hydraulic fracturing or formation water); and water with constituents from conventional oil and gas development, sewage effluent, and coal-mine drainage. All samples were analyzed for field properties (water temperature, pH, specific conductance, dissolved oxygen, and turbidity), major ions, trace elements, naturally occurring radioactive materials, and stable isotopes. In addition to documenting baseline water-quality conditions for an area of shale-gas development, these data were examined for patterns in water quality. Groundwater and base-flow survey data were compared to historical data from the Monongahela River Basin in West Virginia. Additionally, groundwater- and base-flow survey samples were grouped by Marcellus Shale gas production in the subbasin in which that sampling site was located. The comparisons of data collected as part of this study with historical data identified few differences. No significant difference was found in a comparison of groundwater survey data and historical data. Base-flow survey samples differed significantly from historical data for pH, chloride, and strontium, all of which had higher concentrations in the base-flow survey samples. Differences in pH are likely related to changes in mining regulation beginning in 1977. Concentrations of chloride and strontium elevated above background concentrations may be related to saline groundwater; saline water is within 300 feet of the land surface in parts of the study area. In the comparison of base-flow survey samples grouped by shale-gas-production setting, significant differences were found for fluoride and barium. Concentrations of fluoride and barium were higher in stream subbasins with active Marcellus Shale production than in subbasins not near active Marcellus Shale production. Elevated fluoride and barium are associated with deep brines. Generally, naturally occurring radioactive materials were not found in elevated concentrations in either groundwater or base-flow samples. Only 3 samples, 2 from the groundwater survey and one from the base-flow survey, exceeded the U.S. Environmental Protection Agency maximum contaminant level for radium isotopes of 5.0 picocurie per liter for either a single isotope or a combined value of radium-226 and radium-228. Stable isotope composition indicates broad similarity among surface water, shallow groundwater, and precipitation in the region. Neither shallow groundwater nor surface water showed a marked similarity with the deep brines associated with shale gas. In most of the groundwater survey samples, 38 of 41 samples, dissolved gas profiles were similar to those previously found in samples from shallow, domestic wells in the region. This study provides a baseline of water-quality conditions in the Monongahela River Basin in West Virginia during the early phases of development of the Marcellus Shale gas field. Although not all inclusive, the results of this study provide a set of reliable water-quality data against which future data sets can be compared and the effects of shale-gas development may be determined.

West Virginia↗

USGS2013

Investigations of groundwater system and simulation of regional groundwater flow for North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

Groundwater in the vicinity of several industrial facilities in Upper Gwynedd Township and vicinity, Montgomery County, in southeast Pennsylvania has been shown to be contaminated with volatile organic compounds (VOCs), the most common of which is the solvent trichloroethylene (TCE). The 2-square-mile area was placed on the National Priorities List as the North Penn Area 7 Superfund site by the U.S. Environmental Protection Agency (USEPA) in 1989. The U.S. Geological Survey (USGS) conducted geophysical logging, aquifer testing, and water-level monitoring, and measured streamflows in and near North Penn Area 7 from fall 2000 through fall 2006 in a technical assistance study for the USEPA to develop an understanding of the hydrogeologic framework in the area as part of the USEPA Remedial Investigation. In addition, the USGS developed a groundwater-flow computer model based on the hydrogeologic framework to simulate regional groundwater flow and to estimate directions of groundwater flow and pathways of groundwater contaminants. The study area is underlain by Triassic- and Jurassic-age sandstones and shales of the Lockatong Formation and Brunswick Group in the Mesozoic Newark Basin. Regionally, these rocks strike northeast and dip to the northwest. The sequence of rocks form a fractured-sedimentary-rock aquifer that acts as a set of confined to partially confined layers of differing permeabilities. Depth to competent bedrock typically is less than 20 ft below land surface. The aquifer layers are recharged locally by precipitation and discharge locally to streams. The general configuration of the potentiometric surface in the aquifer is similar to topography, except in areas affected by pumping. The headwaters of Wissahickon Creek are nearby, and the stream flows southwest, parallel to strike, to bisect North Penn Area 7. Groundwater is pumped in the vicinity of North Penn Area 7 for industrial use, public supply, and residential supply. Results of field investigations by USGS at the site and results from other studies support, and are consistent with, a conceptual model of a layered leaky aquifer where the dip of the beds has a strong control on hydraulic connections in the groundwater system. Connections within and (or) parallel to bedding tend to be greater than across bedding. Transmissivities of aquifer intervals isolated by packers ranged over three orders of magnitude [from about 2.8 to 2,290 square feet per day (ft 2 /d) or 0.26 to 213 square meters per day (m 2 /d)], did not appear to differ much by mapped geologic unit, but showed some relation to depth being relatively smaller in the shallowest and deepest intervals (0 to 50 ft and more than 250 ft below land surface, respectively) compared to the intermediate depth intervals (50 to 250 ft below land surface) tested. Transmissivities estimated from multiple-observation well aquifer tests ranged from about 700 to 2,300 ft 2 /d (65 to 214 m 2 /d). Results of chemical analyses of water from isolated intervals or monitoring wells open to short sections of the aquifer show vertical differences in concentrations; chloride and silica concentrations generally were greater in shallow intervals than in deeper intervals. Chloride concentrations greater than 100 milligrams per liter (mg/L), combined with distinctive chloride/bromide ratios, indicate a different source of chloride in the western part of North Penn Area 7 than elsewhere in the site. Groundwater flow at a regional scale under steady-state conditions was simulated by use of a numerical model (MODFLOW-2000) for North Penn Area 7 with different layers representing saprolite/highly weathered rock near the surface and unweathered competent bedrock. The sedimentary formations that underlie the study area were modeled using dipping model layers for intermediate and deep zones of unweathered, fractured rock. Horizontal cell model size was 100 meters (m) by 100 meters (328 ft by 328 ft), and model layer thickness ranged from 6 m (19.7 ft) representing shallow weathered rock and saprolite up to 200 m (656 ft) representing deeper dipping bedrock. The model did not include detailed structure to account for local-scale differences in hydraulic properties, with the result that local-scale groundwater flow may not be well simulated. Additional detailed multi-well aquifer tests would be needed to establish the extent of interconnection between intervals at the local scale to address remediation of contamination at each source area. This regional groundwater-flow model was calibrated against measured groundwater levels (1996, 2000, and 2005) and base flow estimated from selected streamflow measurements by use of nonlinear-regression parameter-estimation algorithms to determine hydraulic conductivity and anisotropy of hydraulic conductivity, streambed hydraulic conductivity, and recharge during calibration periods. Results of the simulation using the calibrated regional model indicate that the aquifer appears to be anisotropic where hydraulic conductivity is greatest parallel to the orientation of bedding of the formations underlying the area and least in the cross-bed direction. The maximum hydraulic conductivity is aligned with the average regional strike of the formations, which is “subhorizontal” in the model because the altitudes of the beds and model cells vary in the strike, as well as dip, direction. Estimated subhorizontal hydraulic conductivities (in strike direction parallel to dipping beds) range from 0.001 to 1.67 meters per day (0.0032 to 5.5 feet per day). The ratio of minimum (dip direction) to maximum (strike direction) subhorizontal hydraulic conductivity ranges from 1/3.1 to 1/8.6, and the ratio of vertical to horizontal hydraulic conductivity ranges from 1/1 to 1/478. However, limited available field data precluded rigorous calibration of vertical anisotropy in the model. Estimated recharge rates corresponding to calibration periods in 1996, 2000, and 2005 are 150, 109, and 124 millimeters per year (5.9, 4.3, and 4.9 inches per year), respectively. The calibrated groundwater-flow model was used to simulate groundwater flow under steady-state conditions during periods of relatively high withdrawals (pumpage) (1990) and relatively low withdrawals (2000 and 2005). Groundwater-flow paths originating from recharge areas near known areas of soil contamination (sources) were simulated. Pumped industrial and production wells captured more groundwater from several of these sources during 1990 than after 1990 when pumping declined or ceased and greater amounts of contaminated groundwater moved away from North Penn Area 7 Superfund site to surrounding areas. Uncertainty in simulated groundwater-flow paths from contaminant sources and contributing areas, resulting from uncertainty in estimated hydraulic properties of the model, was illustrated through Monte Carlo simulations. The effect of uncertainty in the vertical anisotropy was not included in the Monte Carlo simulations. Contributing areas indicating the general configuration of groundwater flow towards production well MG-202 (L-22) in the study area also were simulated for the different time periods; as simulated, the flow paths do not pass through any identified contaminant source in North Penn Area 7. However, contributing areas to wells, such as MG-202, located near many pumped wells are particularly complex and, in some cases, include areas that contribute flow to streams that subsequently recharge the aquifer through stream loss. In these cases, water-quality constituents, including contaminants that are present in surface water may be drawn into the aquifer to nearby pumped wells. Results of a simulated shutdown of well MG-202 under steady-state 2005 conditions showed that the area contributing recharge for nearby production well MG-76 (L-17), when MG-202 is not pumping, shifts downstream and is similar to the area contributing recharge for MG-202 when both wells are pumping. Concentrations of constituents in groundwater samples collected in fall 2005 or spring 2006 were compared to simulated groundwater-flow paths for the year 2005 to provide a qualitative assessment of model results. The observed spatial distribution of selected constituents, including TCE, CFC-11, and CFC-113 in groundwater in 2005 and the chloride/bromide mass ratios in 2006, generally were consistent with the model results of the simulated 2005 groundwater-flow paths at North Penn Area 7, indicating the presence of several separate sources of contaminants within North Penn Area 7.

Pennsylvania↗

USGS2011

A national plan for assisting states, federal agencies, and tribes in managing white-nose syndrome in bats

White-nose syndrome (WNS) is a disease responsible for unprecedented mortality in hibernating bats in the northeastern U.S. This previously unrecognized disease has spread very rapidly since its discovery in January 2007, and poses a considerable threat to hibernating bats throughout North America. As WNS spreads, the challenges for understanding and managing the disease continue to increase. Given the escalating complexity of these challenges, a highly coordinated effort is required for State, Federal, and Tribal wildlife agencies, and private partners to respond effectively to WNS and conserve species of bats. The plan proposed herein details the elements that are critical to the investigation and management of WNS, identifies key action items to address stated goals, and outlines the role(s) of agencies and entities involved in this continental effort.

Report↗

USGS1997

Ground Water Atlas of the United States: Segment 11, Delaware, Maryland, New Jersey, North Carolina, Pennsylvania, Virginia, West Virginia

Segment 11 consists of the States of Delaware, Maryland, New Jersey, North Carolina, West Virginia, and the Commonwealths of Pennsylvania and Virginia. All but West Virginia border on the Atlantic Ocean or tidewater. Pennsylvania also borders on Lake Erie. Small parts of northwestern and north-central Pennsylvania drain to Lake Erie and Lake Ontario; the rest of the segment drains either to the Atlantic Ocean or the Gulf of Mexico. Major rivers include the Hudson, the Delaware, the Susquehanna, the Potomac, the Rappahannock, the James, the Chowan, the Neuse, the Tar, the Cape Fear, and the Yadkin-Peedee, all of which drain into the Atlantic Ocean, and the Ohio and its tributaries, which drain to the Gulf of Mexico. Although rivers are important sources of water supply for many cities, such as Trenton, N.J.; Philadelphia and Pittsburgh, Pa.; Baltimore, Md.; Washington, D.C.; Richmond, Va.; and Raleigh, N.C., one-fourth of the population, particularly the people who live on the Coastal Plain, depends on ground water for supply. Such cities as Camden, N.J.; Dover, Del.; Salisbury and Annapolis, Md.; Parkersburg and Weirton, W.Va.; Norfolk, Va.; and New Bern and Kinston, N.C., use ground water as a source of public supply. All the water in Segment 11 originates as precipitation. Average annual precipitation ranges from less than 36 inches in parts of Pennsylvania, Maryland, Virginia, and West Virginia to more than 80 inches in parts of southwestern North Carolina (fig. 1). In general, precipitation is greatest in mountainous areas (because water tends to condense from moisture-laden air masses as the air passes over the higher altitudes) and near the coast, where water vapor that has been evaporated from the ocean is picked up by onshore winds and falls as precipitation when it reaches the shoreline. Some of the precipitation returns to the atmosphere by evapotranspiration (evaporation plus transpiration by plants), but much of it either flows overland into streams as direct runoff or enters streams as base flow (discharge from one or more aquifers). The distribution of average annual runoff (fig. 2) is similar to the distribution of precipitation; that is, runoff is generally greatest where precipitation is greatest. Runoff rates range from more than 50 inches per year in parts of western North Carolina to less than 12 inches in parts of North Carolina, Virginia, and West Virginia. Parts of the seven following physiographic provinces are in Segment 11: the Coastal Plain, the Piedmont, the Blue Ridge, the New England, the Valley and Ridge, the Appalachian Plateaus, and the Central Lowland. The provinces generally trend northeastward (fig. 3). The northeastern terminus of the Blue Ridge Province is in south-central Pennsylvania, and the southwestern part of the New England Province, the Reading Prong, ends in east-central Pennsylvania. The topography, lithology, and water-bearing characteristics of the rocks that underlie the Blue Ridge Province and the Reading Prong are similar. Accordingly, for purposes of this study, the hydrology of the Reading Prong is discussed with that of the Blue Ridge Province. The Coastal Plain Province is a lowland that borders the Atlantic Ocean. The Coastal Plain is as much as 140 miles wide in North Carolina but narrows northeastward to New Jersey where it terminates in Segment 11 at the south shore of Raritan Bay. Although it is generally a flat, seaward-sloping lowland, this province has areas of moderately steep local relief, and its surface locally reaches altitudes of 350 feet in the southwestern part of the North Carolina Coastal Plain. The Coastal Plain mostly is underlain by semiconsolidated to unconsolidated sediments that consist of silt, clay, and sand, with some gravel and lignite. Some consolidated beds of limestone and sandstone are present. The Coastal Plain sediments range in age from Jurassic to Holocene and dip gently toward the ocean. The boundary between the Coastal Plain and the Piedmont Provinces is called the Fall Line (fig. 3) because falls and rapids commonly form where streams cross the contact between the consolidated rocks of the Piedmont (fig. 4) and the soft, semiconsolidated to unconsolidated sediments of the Coastal Plain. The increase in stream gradient at the Fall Line provided favorable locations for mills and other installations that harnessed water power during the early years of the Industrial Revolution, and on most major rivers, the Fall Line coincides with the head of navigation. The Piedmont Province is an area of varied topography that ranges from lowlands to peaks and ridges of moderate altitude and relief. The metamorphic and igneous rocks of this province range in age from Precambrian to Paleozoic and have been sheared, fractured, and folded. Included in this province, however, are sedimentary basins that formed along rifts in the Earth's crust and contain shale, sandstone, and conglomerate of early Mesozoic age, interbedded locally with basaltic lava flows and minor coal beds. The sedimentary rocks and basalt flows are intruded in places by diabase dikes and sills. The mountain belt of the Blue Ridge Province forms the northwestern margin of the Piedmont in most of Segment 11. This belt consists mostly of igneous and high-rank metamorphic rocks but also includes low-rank metamorphic rocks of late Precambrian age and small areas of sedimentary rocks of Early Cambrian age along its western margin. In this report, the Reading Prong of the New England Province, which is an upland that extends from east of the Susquehanna River in Pennsylvania northeastward into New Jersey (fig. 3), is treated as part of the Blue Ridge Province. Part of the Reading Prong in Pennsylvania and New Jersey and a small part of the Piedmont Province in northeastern New Jersey have been glaciated. Glacial deposits completely or partly fill some of the valleys, and the eroding action of the glacial ice removed some of the rock from the ridges. Thus, the glaciated parts of the province have a smoother topography and less relief than other parts. The Valley and Ridge Province is characterized by layered sedimentary rock that has been complexly folded and locally thrust faulted. As the result of repeated cycles of uplift and erosion, resistant layers of well-cemented sandstone and conglomerate form elongate mountain ridges and less resistant, easily eroded layers of limestone, dolomite, and shale form valleys. The rocks of the province range in age from Cambrian to Pennsylvanian. Parts of this province from central Pennsylvania into New Jersey have been glaciated, and glacial deposits fill or partially fill some of the valleys. The Appalachian Plateaus Province is underlain by rocks that are continuous with those of the Valley and Ridge Province, but in the Appalachian Plateaus the layered rocks are nearly flat-lying or gently tilted and warped, rather than being intensively folded and faulted. The boundary between the two provinces is a prominent southeast-facing scarp called the Allegheny Front in most of the northern part of Segment 11 (fig_ 5) and the Cumberland Escarpment in the southern part. The scarp faces the Valley and Ridge Province, and throughout most of the segment, the eastern edge of the Appalachian Plateaus Province is higher than the ridges in the Valley and Ridge. Like parts of the Reading Prong and the Valley and Ridge Province, the northern part of the Appalachian Plateaus Province in Pennsylvania has been glaciated. In the glaciated section, the surface is mantled by glacial drift, and the valleys are partly filled with glacial deposits. The northwestern corner of Segment 11 contains a small part of the Central Lowland Province. This flat lowland is underlain by gently dipping sedimentary rocks, some of which are the same geologic formations as those of the Appalachian Plateaus Province. The two provinces are separated by a northwest- facing scarp. Because of the small area of the Central Lowland Province within the segment and the similarity of aquifer properties with those of the glaciated part of the Appalachian Plateaus Province, the two provinces are discussed together in this report.

Delaware, Maryland, New Jersey, North Carolina, Pe↗

USGS2005

Base flow in the Great Lakes Basin

Hydrograph separations were performed using the PART, HYSEP 1, 2, and 3, BFLOW and UKIH methods on 104,293 years of daily streamflow records from 3,936 streamflow-gaging stations in Ontario, Canada and the eight Great Lakes States of Illinois, Indiana, Michigan, Minnesota, New York, Ohio, Pennsylvania, and Wisconsin to estimate base-flow index (BFI) and base flow. BFI ranged an average of 0.24 BFI depending on which hydrograph-separation method was used. BFI data from 959 selected streamflow-gaging stations with a combined 28,784 years of daily streamflow data were used to relate BFI to surficial geology and the proportion of surface water within the gaged watersheds. This relation was then used to derive estimates of BFI throughout the Great Lakes, Ottawa River, and upper St. Lawrence River Basins at a scale of 8-digit hydrologic unit code (HUC) watersheds for the U.S. and tertiary watersheds in Canada. This process was repeated for each of the six hydrograph-separation methods used. When applied to gaged watersheds, model results predicted observed base flow within 0.2 BFI up to 94 percent of the time. Estimates of long-term (length of streamflow record) average annual streamflow in each HUC and tertiary watershed were calculated and used to determine average annual base flow from BFI estimates. Possibilities for future study based on results from this study include long-term trend analysis of base flow and improving the scale at which base-flow estimates can be made.

Great Lakes Basin↗

USGS1977

Ground-water resources of Chester County, Pennsylvania

Fifty gallons per minute (3 liters per second) or more may be obtained from wells in almost all parts of the county, but not at all locations. Adequate exploration to find fracture or solution openings is required. Five hundred gallons per minute (30 liters per second) or more may be obtained from some of the carbonate rocks. Linear features are visible on 1:1,000,000-to 1:24,000-scale aerial imagery. Many linear features, but not all, have geologic or hydrologic significance, and some may indicate fractured rock that might be tapped by wells. Dissolved-solids concentration of most ground water is less than 500 milligrams per liter. Chemical-quality problems are predominantly caused by acidity, iron and manganese, or nitrate. Base (ground-water) runoff during a near-average year, 1968, was about 420 million gallons per day (18 cubic meters per second).

Pennsylvania↗

USGS1975

Landsliding in Allegheny County, Pennsylvania

Man should proceed with caution if modifications such as loading, excavation, or changes of the water regime are contemplated for slopes in Allegheny County, especially those slopes described on the map as highly sensitive to disturbance by man. Features indicative of unstable slope conditions include: cracks in buildings, yard walls, and pools; doors and windows that jam; fences and other linear features bowed out of line; tilted trees and utility poles; cracks and steplike ground features; hummocky ground; and water seeps. Geologic factors related to the landsliding process include rock types, layering, fracturing, and attitude; nature of soil cover; permeability of rocks and soils; and steepness of slope.

Circular↗

USGS2014

Thermal maturity patterns (conodont color alteration index and vitrinite reflectance) in Upper Ordovician and Devonian rocks of the Appalachian basin: A major revision of USGS Map I-917-E using new subsurface collections

Introduction The conodont color alteration index (CAI) introduced by Epstein and others (1977) and Harris and others (1978) is an important criterion for estimating the thermal maturity of Ordovician to Mississippian rocks in the Appalachian basin. Consequently, the CAI isograd maps of Harris and others (1978) are commonly used by geologists to characterize the thermal and burial history of the Appalachian basin and to better understand the origin and distribution of oil and gas resources in the basin. The main objectives of this report are to present revised CAI isograd maps for Ordovician and Devonian rocks in the Appalachian basin and to interpret the geologic and petroleum resource implications of these maps. The CAI isograd maps presented herein complement, and in some areas replace, the CAI-based isograd maps of Harris and others (1978) for the Appalachian basin. The CAI data presented in this report were derived almost entirely from subsurface samples, whereas the CAI data used by Harris and others (1978) were derived almost entirely from outcrop samples. Because of the different sampling methods, there is little geographic overlap of the two data sets. The new data set is mostly from the Allegheny Plateau structural province and most of the data set of Harris and others (1978) is from the Valley and Ridge structural province, east of the Allegheny structural front (fig. 1). Vitrinite reflectance, based on dispersed vitrinite in Devonian black shale, is another important parameter for estimating the thermal maturity in pre-Pennsylvanian-age rocks of the Appalachian basin (Streib, 1981; Cole and others, 1987; Gerlach and Cercone, 1993; Rimmer and others, 1993; Curtis and Faure, 1997). This chapter also presents a revised percent vitrinite reflectance (%R 0 ) isograd map based on dispersed vitrinite recovered from selected Devonian black shales. The Devonian black shales used for the vitrinite studies reported herein also were analyzed by RockEval pyrolysis and total organic carbon (TOC) content in weight percent. Although the RockEval and TOC data are included in this chapter (table 1), they are not shown on the maps. The revised CAI isograd and percent vitrinite reflectance isograd maps cover all or parts of Kentucky, New York, Ohio, Pennsylvania, Virginia, and West Virginia (fig. 1), and the following three stratigraphic intervals: Upper Ordovician carbonate rocks, Lower and Middle Devonian carbonate rocks, and Middle and Upper Devonian black shales. These stratigraphic intervals were chosen for the following reasons: (1) they represent target reservoirs for much of the oil and gas exploration in the Appalachian basin; (2) they are stratigraphically near probable source rocks for most of the oil and gas; (3) they include geologic formations that are nearly continuous across the basin; (4) they contain abundant carbonate grainstone-packstone intervals, which give a reasonable to good probability of recovery of conodont elements from small samples of drill cuttings; and (5) the Middle and Upper Devonian black shale contains large amounts of organic matter for RockEval, TOC, and dispersed vitrinite analyses. Thermal maturity patterns of the Upper Ordovician Trenton Limestone are of particular interest here, because they closely approximate the thermal maturity patterns in the overlying Upper Ordovician Utica Shale, which is the probable source rock for oil and gas in the Upper Cambrian Rose Run Sandstone (sandstone), Upper Cambrian and Lower Ordovician Knox Group (Dolomite), Lower and Middle Ordovician Beekmantown Group (dolomite or Dolomite), Upper Ordovician Trenton and Black River Limestones, and Lower Silurian Clinton/Medina sandstone (Cole and others, 1987; Jenden and others, 1993; Laughrey and Baldassare, 1998; Ryder and others, 1998; Ryder and Zagorski, 2003). The thermal maturity patterns of the Lower Devonian Helderberg Limestone (Group), Middle Devonian Onondaga Limestone, and Middle Devonian Marcellus Shale-Upper Devonian Rhine street Shale Member-Upper Devonian Ohio Shale are of interest, because they closely approximate the thermal maturity patterns in the Marcellus Shale, Upper Devonian Rhinestreet Shale Member, and Upper Devonian Huron Member of the Ohio Shale, which are the most important source rocks for oil and gas in the Appalachian basin (de Witt and Milici, 1989; Klemme and Ulmishek, 1991). The Marcellus, Rhinestreet, and Huron units are black-shale source rocks for oil and (or) gas in the Lower Devonian Oriskany Sandstone, the Upper Devonian sandstones, the Middle and Upper Devonian black shales, and the Upper Devonian-Lower Mississippian(?) Berea Sandstone (Patchen and others, 1992; Roen and Kepferle, 1993; Laughrey and Baldassare, 1998).

Appalachian basin↗

USGS2023

Prolonged influence of urbanization on landslide susceptibility

Landslides pose a threat to life and infrastructure and are influenced by anthropogenic modifications associated with land development. These modifications can affect susceptibility to landslides, and thus quantifying their influence on landslide occurrence can help design sustainable development efforts. Although landslide susceptibility has been shown to increase following urban expansion, the long-lasting effect of urbanization on landslide susceptibility remains largely unquantified. Hence, susceptibility maps developed based on inventories from non-urbanized areas may incorrectly evaluate the hazard in urbanized areas. To quantify this effect, we analyzed a landslide inventory from southwestern Pennsylvania, where the pulse of urbanization occurred more than a decade before the inventory was created. Using road density as a proxy for urbanization, the study area was divided into urbanized and non-urbanized areas. Susceptibility patterns were computed using statistical analyses of a post-urbanization landslide inventory together with maps of topographic, land cover, and geologic factors. A pre-urbanization landslide inventory was used as a control. Our findings indicate that urbanization has a decades-long effect on landslide susceptibility, where urbanized areas are generally more susceptible to landslides. In urbanized areas landslides are strongly associated with distance from roads and topographic curvature, whereas in non-urbanized landslides are strongly associated with stratigraphic formation and distance from streams. The consistent differences in susceptibility patterns between urbanized and non-urbanized areas indicate that urbanization has a long-lasting effect on landslide susceptibility and that susceptibility estimates should be made separately for these different environments to account for the persistent influence of urbanization.

Pennsylvania↗

USGS2013

Statistical classification of hydrogeologic regions in the fractured rock area of Maryland and parts of the District of Columbia, Virginia, West Virginia, Pennsylvania, and Delaware

Hydrogeologic regions in the fractured rock area of Maryland were classified using geographic information system tools with principal components and cluster analyses. A study area consisting of the 8-digit Hydrologic Unit Code (HUC) watersheds with rivers that flow through the fractured rock area of Maryland and bounded by the Fall Line was further subdivided into 21,431 catchments from the National Hydrography Dataset Plus. The catchments were then used as a common hydrologic unit to compile relevant climatic, topographic, and geologic variables. A principal components analysis was performed on 10 input variables, and 4 principal components that accounted for 83 percent of the variability in the original data were identified. A subsequent cluster analysis grouped the catchments based on four principal component scores into six hydrogeologic regions. Two crystalline rock hydrogeologic regions, including large parts of the Washington, D.C. and Baltimore metropolitan regions that represent over 50 percent of the fractured rock area of Maryland, are distinguished by differences in recharge, Precipitation minus Potential Evapotranspiration, sand content in soils, and groundwater contributions to streams. This classification system will provide a georeferenced digital hydrogeologic framework for future investigations of groundwater availability in the fractured rock area of Maryland.

Delaware;District of Columbia;Maryl;Pennsylvania;V↗

USGS2004

Geology of the National Capital Region: Field trip guidebook

The 2004 Joint Northeast-Southeast Section Meeting of the Geological Society of America is the fourth such meeting and the third to be held in or near Washington, D.C. This guidebook and the field trips presented herein are intended to provide meeting participants, as well as other interested readers, a means to understand and enjoy the rich geological and historical legacy of the National Capital Region. The field trips cover all of the major physiographic and geologic provinces of the central Appalachians in the Mid-Atlantic region. Trip 1 outlines the tectonic history of northern Virginia along an east-to-west transect from the Coastal Plain province to the Blue Ridge province, whereas the other field trips each focus on a specific province. From west to east, these excursions investigate the paleoclimate controls on the stratigraphy of the Paleozoic rocks of the Allegheny Plateau and Valley and Ridge province in West Virginia, Pennsylvania, and Maryland (Trip 3); Eocene volcanic rocks that intrude Paleozoic rocks in the westernmost Valley and Ridge province in Virginia and West Virginia (Trip 4); age, petrology, and structure of Mesoproterozoic gneisses and granitoids located in the Blue Ridge province within and near Shenandoah National Park, Virginia (Trip 2); the use of argon data to unravel the complex structural and thermal history of the metamorphic rocks of the eastern Piedmont province in Maryland and Virginia (Trip 5); the use of cosmogenic isotopes to understand the timing of bedrock incision and formation of terraces along the Potomac River in the eastern Piedmont province near Great Falls, Virginia and Maryland (Trip 6); the nature of the boundary between rocks of the Goochland and Chopawamsic terranes in the eastern Piedmont of Virginia (Trip 7); the role of bluffs and fluvial terraces of the Coastal Plain in the Civil War Battle of Fredericksburg, Virginia (Trip 8); and the Tertiary lithology and paleontology of Coastal Plain strata around the Chesapeake Bay of Virginia and Maryland (Trip 9). Some of the field trips present new geochronological research that uses isotopic techniques to unravel Earth history and processes, including U-Pb dating to determine the timing of metamorphism and igneous activity associated with the Mesoproterozoic Grenville orogeny (Trip 2); argon (4DAr/39Ar) analysis to understand the complex Paleozoic history of deformation and metamorphism in the Piedmont (Trip 5); and cosmogenic beryllium-10 data to derive exposure ages of landforms and deposits of the Potomac River valley (Trip 6). Several trips shed insight on significant or enigmatic geologic features of the region. Trip 3 presents evidence for global paleoclimate controls on the Paleozoic stratigraphy of the Appalachian basin, including evidence for Late Devonian glacial deposits. Trip 4 investigates unusual Eocene igneous rocks in the Eastern United States, and Trip 2 visits several local ductile high-strain zones, offering geologists opportunities to consider the importance of such structures relative to the poorly understood Rockfish Valley fault zone in the Blue Ridge province. In the Piedmont province, Trip 7 focuses on a controversial terrane boundary, whereas Trip 5 crosses several lithologic belts with distinct thermotectonic histories that suggest terrane boundaries. Trip 6 sheds new light on the erosional history of a major river gorge cut into crystalline rocks in the Fall Zone. Four trips are recommended for Earth science teachers and are cosponsored by the National Association of Geologic Teachers (NAGT). These trips focus on the tectonic history of northern Virginia (Trip 1), terraces of the Potomac River at Great Falls and cosmogenic isotope analysis to date the terraces and the incision history (Trip 6), and Tertiary lithology and paleontology of the Chesapeake Bay region (Trip 9). Trip 8 takes advantage of the rich Civil War history of this region to look at the role that geology played in the strategies and outcome of the Battle of Fredericksburg. This guidebook is the result of much hard work by many individuals. The editors wish to thank the field trip leaders and authors, the technical reviewers, and Nancy Stamm of ths USGS Geologic Names Committee. We also owe a very special thanks to Linda Gundersen, Chief Scientist, Geologic Discipline, USGS, who provided funding for the guidebook.

Maryland, Virginia, Washington DC↗

USGS2006

Changes in streamflow and water quality in selected nontidal basins in the Chesapeake Bay Watershed, 1985-2004

As part of an annual evaluation of water-quality conditions by the Chesapeake Bay Program, water-quality and streamflow data from 32 sites in nontidal parts of the Chesapeake Bay watershed were analyzed to document annual nutrient and sediment trends for 1985 through 2004. This study also formalized different trend tests and methodologies used in assessing the effectiveness of man-agement actions in reducing nutrients and sediments to the Chesapeake Bay. Trends in streamflow were tested at multiple time scales (daily, seasonal, and annual), resulting in only one significant trend (annual-mean streamflow for the Choptank River near Greensboro, Md.). Total freshwater flow entering the bay for the July-August-September 'summer' season 2004 was the highest ever estimated for that 3-month period (1937-2004). Observed (unbiased) concentration summaries indi-cate higher ranges in total-nitrogen concentrations in the northern major river basins, those in Pennsylvania, Maryland, and northern Virginia, compared to the more southern basins in Virginia. Almost half of the monitoring sites in the northern basins exhibited significant downward trends in total nitrogen with time. Comparisons with total phosphorus and sediment showed similar results to total nitrogen. Monthly and annual loads were available for the River Input Monitoring Program sites from the U.S. Geological Survey. Although loads were significantly reduced from 2003, in 2004, the combined estimated total nitrogen loads were the third highest since 1990, whereas total phosphorus and sediment loads were the fifth highest. A flow-weighted concentration (FWC) is useful in evaluating changes through time. Combined annual mean total nitrogen FWC from the 9 River Input Monitoring Program sites indicated a downward tendency from 1985 through 1998 and an upward tendency since 2001. From 1990 to 2004, the mean concentrations of total nitrogen, total phosphorus, and sediment were 1.58, 0.085, and 51 milligrams per liter, respectively. Flow-weighted concentrations for phosphorus and sediment were lower in the Susquehanna River at Conowingo, Md., most likely due to the trapping efficiency of three large reservoirs upstream from the sampling point. Trends in concentrations, not adjusted for flow, identified 10 statistically significant upward trends, and 50 statistically significant downward trends in concentration for the period 1985 through 2004. Trends in concentrations, when adjusted for flow, can be used as an indicator of human activity and management actions. The flow-adjusted trends indicated significant downward trends at approx-imately 72, 81, and 43 percent of the sites for total nitrogen, total phosphorus, and sediment, respectively. This indicates that management actions are having some effect in reducing nutrients and sediments.

Delaware, Maryland, New York, Pennsylvania↗

USGS1961

Geologic summary of the Appalachian Basin, with reference to the subsurface disposal of radioactive waste solutions

The Appalachian basin is an elongate depression in the crystalline basement complex which contains a great volume of predominantly sedimentary stratified rocks. As defined in this paper it extends from the Adirondack Mountains in New York to central Alabama. From east to west it extends from the west flank of the Blue Ridge Mountains to the crest of the Findlay and Cincinnati arches and the Nashville dome. It encompasses an area of about 207,000 square miles, including all of West Virginia and parts of New York, New Jersey, Pennsylvania, Ohio, Maryland, Virginia, Kentucky, Tennessee, North Carolina, Georgia, and Alabama. The stratified rocks that occupy the basin constitute a wedge-shaped mass whose axis of greatest thickness lies close to and parallel to the east edge of the basin. The maximum thickness of stratified rocks preserved in any one part of the basin today is between 35,000 and 40,000 feet. The volume of the sedimentary rocks is approximately 510,000 cubic miles and of volcanic rocks is a few thousand cubic miles. The sedimentary rocks are predominantly Paleozoic in age, whereas the volcanic rocks are predominantly Late Precambrian. On the basis of gross lithology the stratified rocks overlying the crystalline basement complex can be divided into nine vertically sequential units, which are designated "sequences" in this report. The boundaries between contiguous sequences do not necessarily coincide with the commonly recognized boundaries between systems or series. All sequences are grossly wedge shaped, being thickest along the eastern margin of the basin and thinnest along the western margin. The lowermost unit the Late Precambrian stratified sequence is present only along part of the eastern margin of the basin, where it lies unconformably on the basement complex. It consists largely of volcanic tuffs and flows but contains some interbedded sedimentary rocks. The Late Precambrian sequence is overlain by the Early Cambrian clastic sequence. Where the older sequence is absent, the Early Cambrian sequence rests on the basement complex. Interbedded fine- to coarse-grained noncarbonate detrital rocks comprise the bulk of the sequence, but some volcanic and carbonate rocks are included. Next above is the Cambrian-Ordovician carbonate sequence which consists largely of limestone and dolomite. Some quartzose sandstone is present in the lower part in the western half of the basin, and much shale is present in the upper part in the southeast part of the basin. The next higher sequence is the Late Ordovician clastic sequence, which consists largely of shale, siltstone, and sandstone. Coarse-grained light-gray to red rocks are common in the sequence along the eastern side of the basin, whereas fine-grained dark-gray to black calcareous rocks are common along the west side. The Late Ordovician clastic sequence is overlain unconformably in many places by the Early Silurian clastic sequence. The latter comprises a relatively thin wedge of coarse-grained clastic rocks. Some of the most prolific oil- and gas-producing sandstones in the Appalachian basin are included. Among these are the "Clinton" sands of Ohio, the Medina Sandstones of New York and Pennsylvania, and the Keefer or "Big Six" Sandstone of West Virginia and Kentucky. Conformably overlying the Early Silurian clastic sequence is the Silurian-Devonian carbonate sequence, which consists predominantly of limestone and dolomite. It also contains a salt-bearing unit in the north-central part of the basin and a thick wedge of coarse-grained red beds in the northeastern part. The sequence is absent in much of the southern part of the basin. Large volumes of gas and much oil are obtained from some of its rocks, especially from the Oriskany Sandstone and the Huntersville Ghert. The Silurian-Devonian carbonate sequence is abruptly overlain by the Devonian clastic sequence a thick succession of interbedded shale, mudrock, siltstone, and sandstone. Colors range from predominantly purple and red in the northeastern part of the basin to predominantly dark gray and black in the southwestern part. Many rocks in the upper part contain hydrocarbons in commercial quantities. The next higher sequence is a heterogeneous succession that comprises most rocks of Mississippian age in the basin. It is composed largely of fine-grained to very coarse-grained noncalcareous clastic rocks in the northern half of the basin, and largely of carbonate rocks in the southern part. Large quantities of oil and gas are produced from the sequence. The youngest sequence consists of coarse-grained clastic rocks largely of Pennsylvanian age. In the center of the basin a relatively small volume of lithologically similar rocks of Permian age are included. The sequence has been intensively mined for coal throughout most of its extent. The waste-disposal possibilities of the stratified rocks in the Appalachian basin are considered in terms of the following: 1) gross lithology of the sequences; 2) general lithology of the rock units composing the sequences; and 3) the structural attitudes of the sequences in different parts of the basin. The degree of exploitation of economically significant mineral* resources is considered briefly where such exploitation may affect waste-disposal possibilities. Hydrologic aspects are not in general considered. Based largely on consideration of the above geologic factors the following types of reservoirs associated with particular geologic environments offer some prospects for the disposal of radioactive waste solutions. They are: 1) artificially created cavities in thick salt beds; 2) artificially fractured thin lenticular sandstone bodies isolated in shale or mudrock sequences; 3) portions of thick noncarbonate clastic sequences possessing appreciable natural porosity and permeability; 4) thin clastic units (with natural or artificially created openings) in the plate of a thrust fault overlain by impermeable strata. Considered in its entirety the Late Ordovician clastic sequence appears to have a greater number of favorable geologic factors for waste-disposal purposes than the others. The Early Silurian clastic sequence, the Silurian-Devonian carbonate sequence, and the Devonian clastic sequence offer fewer possibilities. The Late Precambrian stratified sequence, Early Cambrian, and the Cambrian-Ordovician carbonate sequence offer few possibilities. The Mississippian and Pennsylvanian sequences appear to be generally unsuitable.

Appalachian Basin↗

USGS1961

Geologic summary of the Appalachian basin, with reference to the subsurface disposal of radioactive waste solutions

Appalachian Basin↗

USGS2009

Water-level conditions in selected confined aquifers of the New Jersey and Delaware coastal plain, 2003

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 2 million people. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression. In addition to decreasing water supplies, declining water levels in the confined aquifers have led to reversals in natural hydraulic gradients that have, in some areas, induced the flow of saline water from surface-water bodies and adjacent aquifers to freshwater aquifers. In 1978, the U.S. Geological Survey began mapping the potentiometric surfaces of the major confined aquifers of New Jersey every 5 years in order to provide a regional assessment of ground-water conditions in multiple Coastal Plain aquifers concurrently. In 1988, mapping of selected potentiometric surfaces was extended into Delaware. During the fall of 2003, water levels measured in 967 wells in New Jersey, Pennsylvania, northeastern Delaware, and northwestern Maryland were used estimate the potentiometric surface of the principal confined aquifers in the Coastal Plain of New Jersey and five equivalent aquifers in Delaware. Potentiometric-surface maps and hydrogeologic sections were prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Vincentown aquifer, and the Englishtown aquifer system in New Jersey, as well as for the Piney Point aquifer, the Wenonah-Mount Laurel aquifer, and the Upper Potomac-Raritan-Magothy, the Middle and undifferentiated Potomac-Raritan-Magothy, and the Lower Potomac-Raritan-Magothy aquifers in New Jersey and their equivalents in Delaware. From 1998 to 2003, water levels in many Coastal Plain aquifers in New Jersey remained stable or had recovered, but in some areas, water levels continued to decline as a result of pumping. In the Cohansey aquifer in Cape May County, water levels near the center of the cone of depression underlying the southern part of the peninsula remained about the same as in 1998. To the south, recoveries up to 8 feet were observed in southern Lower Township as withdrawals had decreased since 1998. In the northern part of Cape May County, water levels had not changed substantially from historic conditions. In the Rio Grande water-bearing zone, water levels rose by as much as 13 ft at the Rio Grande well field; elsewhere across the aquifer, little change had occurred. In the Atlantic City 800-foot sand, water-level changes were greatest in southern Cape May County; at the Cape May desalination wells, water levels were as much as 32 ft lower in 2003 than in 1998. In contrast, water levels at the center of a regional cone of depression near Atlantic City rose by as much as 10 ft. Within the Piney Point aquifer water levels rose by 46 ft near Seaside Park. Similarly, water levels increased by more than 30 ft in and around the major cone of depression underlying Dover, Delaware. In the Vincentown aquifer, water levels stabilized or recovered by 2 ft to 6 ft from 1998 to 2003 in most of the wells measured; the exception is near Adelphia in Monmouth County, where water levels rose by as much as 18 ft. From 1998 to 2003, water levels near the center of a large cone of depression that extends from Monmouth to Ocean County recovered by as much as 20 ft in the Wenonah-Mount Laurel aquifer. Concurrently, ground-water levels within the Englishtown aquifer system declined by as much as 13 ft in the same area. Water levels across much of the Upper Potomac-Raritan-Magothy aquifer in the northern Coastal Plain remained about the same as 5 years previous, except in northern Ocean County where ground-water levels declined 10 ft to 33 ft. Water levels in the Middle Potomac-Raritan-Magothy aquifer declined from 5 to 9 ft along the border between Monmouth and Middlesex County. Elsewhere, across the northern part of the Coastal Plain, water levels stabilized within the Cretaceous-a

Delaware, New Jersey↗

USGS2012

Total nitrogen and suspended-sediment loads and identification of suspended-sediment sources in the Laurel Hill Creek watershed, Somerset County, Pennsylvania, water years 2010-11

Laurel Hill Creek is a watershed of 125 square miles located mostly in Somerset County, Pennsylvania, with small areas extending into Fayette and Westmoreland Counties. The upper part of the watershed is on the Pennsylvania Department of Environmental Protection 303(d) list of impaired streams because of siltation, nutrients, and low dissolved oxygen concentrations. The objectives of this study were to (1) estimate the annual sediment load, (2) estimate the annual nitrogen load, and (3) identify the major sources of fine-grained sediment using the sediment-fingerprinting approach. This study by the U.S. Geological Survey (USGS) was done in cooperation with the Somerset County Conservation District. Discharge, suspended-sediment, and nutrient data were collected at two streamflow-gaging stations—Laurel Hill Creek near Bakersville, Pa., (station 03079600) and Laurel Hill Creek at Ursina, Pa., (station 03080000)—and one ungaged stream site, Laurel Hill Creek below Laurel Hill Creek Lake at Trent (station 03079655). Concentrations of nutrients generally were low. Concentrations of ammonia were less than 0.2 milligrams per liter (mg/L), and concentrations of phosphorus were less than 0.3 mg/L. Most concentrations of phosphorus were less than the detection limit of 0.02 mg/L. Most water samples had concentrations of nitrate plus nitrite less than 1.0 mg/L. At the Bakersville station, concentrations of total nitrogen ranged from 0.63 to 1.3 mg/L in base-flow samples and from 0.57 to 1.5 mg/L in storm composite samples. Median concentrations were 0.88 mg/L in base-flow samples and 1.2 mg/L in storm composite samples. At the Ursina station, concentrations of total nitrogen ranged from 0.25 to 0.92 mg/L in base-flow samples; the median concentration was 0.57 mg/L. The estimated total nitrogen load at the Bakersville station was 262 pounds (lb) for 11 months of the 2010 water year (November 2009 to September 2010) and 266 lb for the 2011 water year. Most of the total nitrogen loading was from stormflows. The stormflow load accounted for 76.6 percent of the total load for the 2010 water year and 80.6 percent of the total load for the 2011 water year. The estimated monthly total nitrogen loads were higher during the winter and spring (December through May) than during the summer (June through August). For the Bakersville station, the estimated suspended-sediment load (SSL) was 17,700 tons for 11 months of the 2010 water year (November 2009 to September 2010). The storm beginning January 24, 2010, provided 34.4 percent of the annual SSL, and the storm beginning March 10, 2010, provided 31.9 percent of the annual SSL. Together, these two winter storms provided 66 percent of the annual SSL for the 2010 water year. For the 2011 water year, the estimated annual SSL was 13,500 tons. For the 2011 water year, the SSLs were more evenly divided among storms than for the 2010 water year. Seven of 37 storms with the highest SSLs provided a total of 65.7 percent of the annual SSL for the 2011 water year; each storm provided from 4.6 to 12.3 percent of the annual SSL. The highest cumulative SSL for the 2010 and 2011 water years generally occurred during the late winter. Stormflows with the highest peak discharges generally carried the highest SSL. The sediment-fingerprinting approach was used to quantify sources of fine-grained suspended sediment in the watershed draining to the Laurel Hill Creek near Bakersville streamflow-gaging station. Sediment source samples were collected from five source types: 20 from cropland, 9 from pasture, 18 from forested areas, 20 from unpaved roads, and 23 from streambanks. At the Bakersville station, 10 suspended-sediment samples were collected during 6 storms for sediment-source analysis. Thirty-five tracers from elemental analysis and 4 tracers from stable isotope analysis were used to fingerprint the source of sediment for the 10 storm samples. Statistical analysis determined that cropland and pasture could not be discriminated by the set of tracers and were combined into one source group—agriculture. Stepwise discriminant function analysis determined that 11 tracers best described the 4 sources. An "unmixing" model applied to the 11 tracers showed that agricultural land (cropland and pasture) was the major source of sediment, contributing an average of 53 percent of the sediment for the 10 storm samples. Streambanks, unpaved roads, and forest contributions for the 10 storm samples averaged 30, 17, and 0 percent, respectively. Agriculture was the major contributor of sediment during the highest sampled stormflows. The highest stormflows also produced the highest total nitrogen and suspended-sediment loads.

Pennsylvania↗