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Introduction

The National Coal Resource Assessment (NCRA) team of the U.S. Geological Survey (USGS) has assessed the quantity and quality of coal beds and zones that could be mined during the next 20 years or more. Geologic, geochemical, and resource information was collected and compiled for the five major coal-producing regions of the United States: the Appalachian Basin, Illinois Basin, Northern Rocky Mountains and Great Plains, Colorado Plateau, and the Gulf of Mexico Coastal Plain, (Gulf Coast) (Figure 1). In particular, the NCRA assessed coal-quality information and characterized environmentally significant trace elements, such as arsenic and mercury, that are defined in and administered by 1990 Clean Air Act Amendments (U.S. Environmental Protection Agency, 1990). The results of various USGS coal assessment efforts may be found at: http://energy.cr.usgs.gov/coal/coal_assessments/index.html, and a summary of the results from all assessment areas can be found in Ruppert et al. (2002) and Dennen (2009).

Louisiana, Texas

Aquatic ecosystems in Central Colorado are influenced by mineral forming processes and historical mining

Stream water and sediment toxicity to aquatic insects were quantified from central Colorado catchments to distinguish the effect of geologic processes which result in high background metals concentrations from historical mining. Our sampling design targeted small catchments underlain by rocks of a single lithology, which allowed the development of biological and geochemical baselines without the complication of multiple rock types exposed in the catchment. By accounting for geologic sources of metals to the environment, we were able to distinguish between the environmental effects caused by mining and the weathering of different mineralized areas. Elevated metal concentrations in water and sediment were not restricted to mined catchments. Impairment of aquatic communities also occurred in unmined catchments influenced by hydrothermal alteration. Hydrothermal alteration style, deposit type, and mining were important determinants of water and sediment quality and aquatic community structure. Weathering of unmined porphyry Cu-Mo occurrences resulted in water (median toxic unit (TU) = 108) and sediment quality (TU = 1.9) that exceeded concentrations thought to be safe for aquatic ecosystems (TU = 1). Metalsensitive aquatic insects were virtually absent from streams draining catchments with porphyry Cu-Mo occurrences (1.1 individuals/0.1 m2 ). However, water and sediment quality (TU = 0.1, 0.5 water and sediment, respectively) and presence of metalsensitive aquatic insects (204 individuals/0.1 m2 ) for unmined polymetallic vein occurrences were indistinguishable from that for unmined and unaltered streams (TU = 0.1, 0.5 water and sediment, respectively; 201 individuals/0.1 m2 ). In catchments with mined quartz-sericite-pyrite altered polymetallic vein deposits, water (TU = 8.4) and sediment quality (TU = 3.1) were degraded and more toxic to aquatic insects (36 individuals/0.1 m2 ) than water (TU = 0.4) and sediment quality (TU = 1.7) from mined propylitically altered polymetallic vein deposits. The sampling approach taken in this study distinguishes the effects of different mineral deposits on ecosystems and can be used to more accurately quantify the effect of mining on the environment.

Conference Paper

Report on the U.S. Geological Survey's evaluation program for standard reference samples distributed in October 1993 : T-127 (trace constituents), M-128 (major constituents), N-40 (nutrients), N-41 (nutrients), P-21 (low ionic strength), Hg-17 (mercury), AMW-3 (acid mine water), and WW-1 (whole water)

This report presents the results of the U.S. Geological Survey's analytical evaluation program for eight standard reference samples--T-127 (trace constituents), M-128 (major constituents), N-40 (nutrients), N-41 (nutrients), P-21 (low ionic strength), Hg-17 (mercury), AMW-3 (acid mine water), and WW-1 (whole water)--that were distributed in October 1993 to 158 laboratories registered in the U.S. Geological Survey sponsored interlaboratory testing program. Analytical data that were received from 145 of the laboratories were evaluated with respect to: overall laboratory performance and relative laboratory performance for each analyte in the eight reference samples. Results of these evaluations are presented in tabular form. Also presented are tables and graphs summarizing the analytical data provided by each laboratory for each analyte in the eight standard reference samples. The most probable value for each analyte was determined using nonparametric statistics.

Open-File Report

Geologic setting, petrology, and geochemistry of zoned tungsten-bearing skarns at the Strawberry Mine, central Sierra Nevada, California

The Strawberry mine, 90 km northeast of Fresno, California, occurs on the margin of a small roof pendant of Early Jurassic metasedimentary rocks and middle Cretaceous metaigneous rocks. Middle Cretaceous granitic intrusions surround and intrude the roof pendant. Adjacent to one granodiorite intrusion, several subvertical marble layers are replaced by scheelite-bearing skarns. The skarns form spears that project as much as 300 m upward and into the marble layers. Between the marble and granodiorite, the skarns comprise a metasomatic column and are subdivided into four zones: (1) wollastonite skarn, adjacent to and replacing marble, and containing wollastonite, grossularite, idocrase, and diopside; (2) garnet skarn, containing andradite-grossularite, diopside-hedenbergite, and scheelite; (3) pyroxene skarn containing hedenbergite-diopside, plagioclase, magnetite, and scheelite; and (4) hornblende skarn, adjacent to granodiorite, and containing hornblende, plagioclase, microcline, magnetite, and scheelite. Important features of the skarn zonation are: sharp contacts between skarn zones; relative constancy of whole-rock, mineral, and modal compositions within each skarn zone; major changes in whole-rock, mineral, and modal compositions across contacts between skarn zones; and systematic replacement between skarn zones, with any given skarn zone replaced by the next lower and adjacent skarn zone toward the granodiorite. Volume remained approximately constant in the replacement of marble by various skarn zones. Marble and skarn exhibit uniformly low porosity. Data on mineral paragenesis and mineral composition indicate that in the replacement of any skarn the most calcic mineral is consumed and the residual calc-silicate minerals in the replacing skarn increase in abundance and are richer in total Fe and MnO. This mineral paragenesis can be related to systematic variations in whole-rock composition. From the marble to the granodiorite, skarns are progressively depleted in CaO and CO 2 , and progressively enriched in SiO 2 , total Fe, MgO, MnO, Al 2 O 3 , Na 2 O, K 2 O, and WO 3 . The skarns probably formed when an aqueous fluid containing a solute fraction relatively depleted in Ca and CO 2 , and relatively enriched in Si, Fe, Mg, Mn, Al, Na, K, and W, was expelled from a granitic magma into country rock. The tendency toward local equilibrium between fluid and marble resulted in formation of skarns with systematic stepwise changes in mineral and rock composition at contacts between skarns. Achievement of local equilibrium occurred mainly by infiltration metasomatism with a possible minor component of diffusion metasomatism.

California

Estimating natural background groundwater chemistry, Questa molybdenum mine, New Mexico

This 2 1/2 day field trip will present an overview of a U.S. Geological Survey (USGS) project whose objective was to estimate pre-mining groundwater chemistry at the Questa molybdenum mine, New Mexico. Because of intense debate among stakeholders regarding pre-mining groundwater chemistry standards, the New Mexico Environment Department and Chevron Mining Inc. (formerly Molycorp) agreed that the USGS should determine pre-mining groundwater quality at the site. In 2001, the USGS began a 5-year, multidisciplinary investigation to estimate pre-mining groundwater chemistry utilizing a detailed assessment of a proximal natural analog site and applied an interdisciplinary approach to infer pre-mining conditions. The trip will include a surface tour of the Questa mine and key locations in the erosion scar areas and along the Red River. The trip will provide participants with a detailed understanding of geochemical processes that influence pre-mining environmental baselines in mineralized areas and estimation techniques for determining pre-mining baseline conditions.

New Mexico

Reconnaissance study of the geology of U.S. vermiculite deposits: Are asbestos minerals common constituents?

Unusually high incidences of asbestos-related mortality and respiratory disease in the small town of Libby, Montana, have been linked to amphibole mineral fibers intergrown with the vermiculite deposits mined and milled near the town from 1923 to 1990. A study conducted by the U.S. Agency for Toxic Substances and Disease Registry concluded that mortality due to asbestosis in Libby mine and mill workers and residents during 1979 to 1998 was much higher than expected for a similar Montana or United States population group. Recent medical testing of past and present mineworkers and residents of Libby showed lung abnormalities in nearly one-fifth of the adult study participants. The U.S. Environmental Protection Agency, under Superfund authority, is completing sampling and cleanup of asbestos-bearing materials in the mine, mill, and town sites. The U.S. Geological Survey is conducting a study, reviewed herein, to investigate the mineral content of other U.S. vermiculite deposits and to determine if the amphibole asbestos minerals like those found in the Libby deposits are common in other vermiculite deposits.

Montana

Geology, petrology, and chemistry of the Leadville Dolomite: host for uranium at the Pitch Mine, Saguache County, Colorado

Newly documented uranium ore in the Pitch Mine occurs chiefly in brecciated Mississippian Leadville Dolomite along the Chester reverse fault zone, and to a lesser extent in sandstone, siltstone, and carbonaceous shale of the Pennsylvanian Belden Formation and in Precambrian granitic rocks and schist. Uranium-mineralized zones are generally thicker, more consistent, and of higher grade in dolomite than in other hosts, and roughly 50 percent of the new reserves are in dolomite. Strong physical control by dolomite is evident, as this is the only lithology that is pervasively brecciated within the fault slices that make up the footwall of the reverse fault zone. Other lithologies tend to either remain unbroken or undergo ductile deformation. Chemical controls are subtle and appear to involve chiefly formation of FeS2 as pyrite and marcasite, which accompany uranium. Leadville Dolomite in the area is about 130 m thick and is predominantly nonfossiliferous dolomicrite. In the Pitch Mine, Leadville Dolomite is bound by faults and maximum known thickness is about 17 m. Mud texture, paucity of fossils and other allochems, thin laminations, and probable algal mat structures suggest sedimentation in a tidal-flat (possibly supratidal) environment. Preservation of mud texture and lack of replacement features indicate that dolomitization was an early, prelithification process, as in modern tidal flats, and produced a chemically and texturally uniform rock over tens of meters with relatively few limestone beds surviving. The sedimentary and diagenetic environment of the tidal-flat dolomite, apparently most favorable for uranium deposits, probably obtained over a large area and should consistute an exploration target over a broad area of central Colorado. Carbonate rocks of the Belden Formation, in contrast to those of the Leadville, contain calcite in great excess of dolomite, more than 5 percent silt-size quartz and clay, and abundant fossils and oolites. Belden limestones (sandy micrite and sandy wackestone) probably were deposited in an intertidal or subtidal environment. Very little uranium ore occurs in these rocks. Chemical aspects, such as the iron, sulfur, and organic carbon contents, are very similar to those of Leadville dolomites, and hence seem favorable, but Belden limestones generally are only mildly fractured. The minor-element content of ore-bearing dolomites is generally normal judging from the relatively scarce data yet published for comparable rocks. Elements enriched in ore include iron, sulfur, molybdenum, and lead. One surface expression of ore in dolomite is ocher-colored, leached, porous gossan that is characterized by residual silica and limonite and by high radioactivity but low chemical uranium content.

Open-File Report

Mapping the extent and methods of small-scale emerald mining in the Panjshir Valley, Afghanistan

Emerald mining in the Panjshir Valley, Afghanistan, has occurred for thousands of years, yet few records exist documenting the detailed spatial extent, techniques, or productivity of small-scale miners. This study proposes new methods to map and monitor the extent and changes in small-scale mining in remote and inaccessible terrain by integrating multispectral remote sensing analysis with archival geologic data and three-dimensional topographic change detection to examine emerald deposit zones and mining activity in the Panjshir Valley. Specifically, previously mapped geologic units known to host emeralds were re-analyzed using Landsat multispectral analysis to investigate the potential distribution of mining activity. Interpretation of very fine-resolution satellite imagery showed that mining activity is becoming more concentrated and transitioning from traditional tunneling methods to mechanized surface excavation. Finally, topographic change analysis of mechanized mine sites was combined with archival grade data to estimate production and consider improved recovery methods by small-scale miners.

Panjshir Valley

The Magnet Cove Rutile Company mine, Hot Spring County, Arkansas

The Magnet Cove Rutile Company mine was mapped by the U.S. Geological Survey in November 1944. The pits are on the northern edge of Magnet Cove and have been excavated in the oxidized zone of highly weathered and altered volcanic agglomerate. The agglomerate is composed of altered mafic igneous rocks in a matrix of white to gray clay, a highly altered tuff. The agglomerate appears layered and is composed of tuffaceous clay material below and igneous blocks above. The agglomerate is cut by aplite and lamprophyre dikes. Alkalic syenite dikes crop out on the ridge north of the pits. At the present stage of mine development the rutile seems to be concentrated in a narrow zone beneath the igneous blocks of the agglomerate. Rutile, associated with calcite and pyrite, occurs as disseminated acicular crystals and discontinuous vein-like masses in the altered tuff. Thin veins of rutile locally penetrate the mafic igneous blocks of the agglomerate.

Open-File Report

Geologic framework, regional aquifer properties (1940s-2009), and spring, creek, and seep properties (2009-10) of the upper San Mateo Creek Basin near Mount Taylor, New Mexico

The U.S. Geological Survey, in cooperation with the U.S. Forest Service, examined the geologic framework, regional aquifer properties, and spring, creek, and seep properties of the upper San Mateo Creek Basin near Mount Taylor, which contains areas proposed for exploratory drilling and possible uranium mining on U.S. Forest Service land. The geologic structure of the region was formed from uplift of the Zuni Mountains during the Laramide Orogeny and the Neogene volcanism associated with the Mount Taylor Volcanic Field. Within this structural context, numerous aquifers are present in various Paleozoic and Mesozoic sedimentary formations and the Quaternary alluvium. The distribution of the aquifers is spatially variable because of the dip of the formations and erosion that produced the current landscape configuration where older formations have been exhumed closer to the Zuni Mountains. Many of the alluvial deposits and formations that contain groundwater likely are hydraulically connected because of the solid-matrix properties, such as substantive porosity, but shale layers such as those found in the Mancos Formation and Chinle Group likely restrict vertical flow. Existing water-level data indicate topologically downgradient flow in the Quaternary alluvium and indiscernible general flow patterns in the lower aquifers. According to previously published material and the geologic structure of the aquifers, the flow direction in the lower aquifers likely is in the opposite direction compared to the alluvium aquifer. Groundwater within the Chinle Group is known to be confined, which may allow upward migration of water into the Morrison Formation; however, confining layers within the Chinle Group likely retard upward leakage. Groundwater was sodium-bicarbonate/sulfate dominant or mixed cation-mixed anion with some calcium/bicarbonate water in the study area. The presence of the reduction/oxidation-sensitive elements iron and manganese in groundwater indicates reducing conditions at some time or in some location(s) in most aquifers. Frequent detections of zinc in the alluvium aquifer may represent anthropogenic influences such as mining. Along the mesas in the upper San Mateo Creek Basin, springs that form various creeks, including El Rito and San Mateo Creeks, discharge from the basalt-cap layer and the upper Cretaceous sedimentary layers. Streamflow in El Rito and San Mateo Creeks flows down steep gradients near the mesas sustained by groundwater discharges, and this streamflow transitions to shallow groundwater contained within the valley alluvium through infiltration where the subsequent groundwater is restricted from downward migration by the shaly Menefee Formation. This shallow groundwater reemerges at seeps where the land surface has been eroded below the groundwater level. Spring- and creek-water samples contained small amounts of dissolved solutes, and seep water contained substantially larger amounts of dissolved solutes. The pH of water within the creeks was neutral to alkaline, and all locations exhibited well-oxygenated conditions, although typically at substantially less than saturated levels. Changes in the stable-isotope ratios of water between spring and summer samples indicate differences in source-water inputs that likely pertain to seasonal recharge sources. Results of the water-isotope analysis and geochemical modeling indicate little evaporation and chemical weathering at the spring and creek sites but stronger evaporation and chemical weathering by the time the water reaches the seep locations in the center of the upper San Mateo Creek Basin.

New Mexico

Volcanic activity at Magnet Cove, Arkansas

The igneous rocks and the minerals of Magnet Cove, Arkansas, have long interested geologists and mineralogists, but in much of the area rock‐exposures are so sparse that many of the geologic, relations have remained obscure. However, recent prospecting and the mining of titanium ores have uncovered rocks that throw new light on the geology of the region. The regional rocks of the area are sandstones, slates, and novaculite of Paleozoic age. They were folded and underwent metamorphism in late Paleozoic time. In Cretaceous time they were intruded by a series of igneous rocks. ©1938. American Geophysical Union. All Rights Reserved.

Arkansas

U.S. Geological Survey heavy metals program progress report 1968 - Field studies

The Heavy Metals program of the U.S. Geological Survey and the U.S. Bureau of Mines began in mid-1966 and thus at the end of calendar year 1968 was halfway through its third year. This progress report summarizes field studies carried out under the Geological Survey's part of the program during 1968. Topical studies for 1968 are summarized in U.S. Geological Survey Circular 622. Background of the program and results during 1966 and 1967 were reported in U.S. Geological Survey Circular 560 and will not be further discussed herein.

Circular

Earth Mapping Resources Initiative protocols—Sampling hard-rock mine waste and perpetual mine water sources

Supporting the overarching goal to evaluate critical minerals nationwide, the mine waste characterization effort in the U.S. Geological Survey (USGS) Earth Mapping Resources Initiative has created a series of protocols to standardize sampling carried out under this effort by the participating State geological surveys and their cooperators. The protocols are based on published, reviewed methods that can be deployed in the field. The protocols include (1) collecting and processing composite samples of mine and mill waste, including tailings, waste rock, gangue, heap leach piles, ore stockpiles, slag, or other mineralized and processed materials and (2) collecting and preserving water samples from perpetual or long-term mine water sources. The protocols also specify information to document on field sheets and detail the collection of geospatial data. The analytical methods used by the USGS and USGS contract laboratories are described in this report, including the data delivery pathway for USGS-derived data.

Scientific Investigations Report

Mineral resource assessment of mafic and ultramafic rocks in the Greenville 1° x 2° quadrangle, South Carolina, Georgia, and North Carolina

Mineral resources of the Greenville 1° x 2° quadrangle, South Carolina, Georgia, and North Carolina, were assessed between 1984 and 1990 under the Conterminuous United States Mineral Assessment Program (CUSMAP) of the U.S. Geological Survey (USGS). The mineral resource assessments were made on the basis of geologic, geochemical, and geophysical investigations and on the distribution of mines, prospects and mineral occurrences reported in the literature. This report is an assessment of the mineral resources associated with mafic and ultramafic rocks in the Greenville quadrangle. It is based on the geology as mapped by Nelson and others (1987, 1989), on geochemistry of rock samples collected for this and other studies, on data available for known mines and prospects, and on the published geologic literature.

Georgia;North Carolina;South Carolina

Stitching the western Piedmont of Virginia: Early Paleozoic tectonic history of the Ellisville Pluton and the Potomac and Chopawamsic Terranes

The theme of the 2014 Virginia Geological Field Conference is the tectonic development, economic geology, and seismicity of the western Piedmont of Louisa County, Virginia. It is timely for the conference to turn its attention here, for during the past decade these aspects of western Piedmont geology have garnered the renewed attention of researchers. In terms of regional tectonics, it has been hypothesized that the major structure in the region, the Chopawamsic fault system, represents the most significant boundary in the Appalachian orogen, the main Iapetan suture (Hibbard et al., 2014). Economically, recent elevated market values of metals— particularly that of gold—has spurred reconsideration of the economic geology of the western Piedmont. Finally, the August 23, 2011, M5.8 earthquake, with its epicenter in our field area, startled the North American east coast and has revived awareness of the seismic potential of the region. This renewed interest in the geology of the western Piedmont of north-central Virginia has led to new detailed bedrock mapping, detailed surficial mapping, high-resolution UPb TIMS zircon geochronology, U-Pb LA-ICPMS detrital zircon geochronology, radiogenic isotope geochemistry, major/minor/REE geochemistry, and geophysical studies (e.g. Bailey et al., 2005, 2008; Bailey and Owens, 2012: Berti et al., 2012; Burton et al., 2014; Burton, in progress; Harrison, 2012; Horton et al., 2010, in press; Hughes, 2010, 2014; Hughes et al., 2013a, 2013b, 2014, in press a, in press b; Malenda, in progress; Owens et al., 2013; Spears and Gilmer 2012; Spears et al. 2013, Terblanche, 2013; Terblanche and Nance, 2012). A host of institutions have taken part in the research, including North Carolina State University, the Virginia Department of Mines, Minerals, and Energy, the U.S. Geological Survey, Virginia Tech, Lehigh University, and the College of William and Mary. Many of these investigations remain active. The majority of the data presented herein is the product of research conducted from 2010 to 2014 by geologists at North Carolina State University. This field trip guide is intended to complement a Geological Society of America field guide (Hughes et al., 2014) that covers the western Piedmont geology along strike to the northeast in the vicinity of Fredericksburg. Geologic mapping and geochronologic and geochemical sampling were coordinated between these two areas as part of a study funded in part by the National Science Foundation and the USGS EDMAP program. Some of the stops in this guide have previously been written up in past field guides (Hughes, 2010; Burton et al., 2014) and are reused here because of their ease of access for large groups and because of new data that update the context and our understanding of the outcrops.

Virginia

Ground-water data for the Hanna and Carbon basins, south-central Wyoming, through 1980

Groundwater resources in the Hanna and Carbon Basins of Wyoming were assessed in a study from 1974 through 1980 because of the development of coal mining in the area. Data collected from 105 wells during that study, including well-completion records, lithologic logs, and water levels, are presented. The data are from stock wells, coal-test holes completed as observation wells by the U.S. Geological Survey. The data are mostly from mined coal-bearing formations: the Tertiary Hanna Formation and the Tertiary and Cretaceous Ferris Formation. Well-completion data and lithologic logs were collected on-site during drilling of the wells or from U.S. Geological Survey files, company records, Wyoming State Engineer well-permit files, and published reports. (USGS)

Open-File Report

Evolution of thought on ore controls in east Tennessee

All early students of the zinc and barite deposits of East Tennessee, noting the geographic coincidence of the principal mining area with complex late Paleozoic geologic structure, concluded that (1) the ore-bearing breccias were produced by Appalachian tectonic forces and that (2) mineralizing solutions gained access through fault-produced channelways. In 1931, Ulrich suggested that the breccias were produced by collapse and fragmentation resulting from solution of the carbonate rocks. This idea was promptly rejected by most geologists, and for the next 15 years nearly all papers on these deposits contained refutations of Ulrich's hypothesis and "proof" of the late Paleozoic tectonic origin of the breccias. Recognition by Odell in 1950 of a spatial association between thinning of the lime-stone zone of the Kingsport Formation and the presence of ore bodies, plus the observation that all identifiable blocks in the breccias were displaced downward as much as 30 to 50 feet, led him to suggest that foundering of the rocks over solution-thinned zones produced the breccias. Hydrothermal fluids, rather than ordinary ground water, were thought to be the dissolving agent.Kendall, in 1960, described a stratified "varved" matrix with detrital sphalerite grains in many breccias at Jefferson City, in which lamination is parallel to bedding of the host Kingsport Formation, indicating that both brecciation and mineralization occurred while the rocks were horizontal. Ruskell about 1960 pointed out the similarity between cross sections of southwest Wisconsin ore bodies and those of East Tennessee when the latter were rotated to a horizontal position. Detailed studies of the post-Knox unconformity led to recognition of a paleokarst topography of considerable relief developed on this surface. Regional stratigraphic studies of the Knox Group by Harris demonstrated the probability of pre-Middle Ordovician exposure of the Kingsport somewhere to the north or northwest, providing a recharge area for ground waters at that time. Detailed mapping of ore bodies, barren areas, and related structures by the mining-company geologists, plus application of the principles of ground-water hydrology and rock mechanics, has led to the theory, generally accepted in the district, of solution-collapse origin of the breccias, probably during Ordovician time.

Tennessee