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At least 523 records · Page 29Linked to original sources
USGS2004

Mineral resource of the month: molybdenum

Molybdenum is a metallic element that is most frequently used in alloy and stainless steels, which together represent the single largest market for molybdenum. Molybdenum has also proven invaluable in carbon steel, cast iron and superalloys. Its alloying versatility is unmatched because its addition enhances material performance under high-stress conditions in expanded temperature ranges and in highly corrosive environments. The metal is also used in catalysts, other chemicals, lubricants and many other applications.

Geotimes↗
USGS1977

Geologic interpretation of a radioactivity anomaly near the west fork of the Buckland River, western Alaska

A large part of western Alaska has been included in a uranium- thorium metallogenic province (Clark and others, 1974; Miller and Bunker, 1976; Miller, 1976) chiefly because of the occurrence of uraniferous plutonic rocks with local concentrations of uranium minerals. Recently, however, anomalous amounts of uranium and thorium have been found by the Geological Survey in volcanic and volcaniclastic rocks near the headwaters of the West Fork of the Buckland River in the central Candle quadrangle (fig. 1). This occurrence is apparently in a different geologic environment than previously noted uranium occurrences in western Alaska. An increase in radioactivity was noted in this general area and three airborne gamma-ray survey traverses, done as part of an ERDA-sponsored reconnaissance survey of western Alaska, cross the area (figs. 1, 2) and confirm the existence of a radioactivity anomaly (U.S. Energy Research and Development Administration, 1975, report GJO-1653).

Alaska↗
USGS1987

Macrofauna and environment of the Nanpil-Kiepw River, Ponape, Eastern Caroline Islands

The first comprehensive evaluation of stream fauna in the Eastern Caroline Islands resulted from collections on Ponape, a 334-km- island having more than 40 streams, many of which arise along 700-m-high interior ridges. Field surveys centered on the Nanpil-Kiepw River below 170 m elevation, a bouldery reach with water of low mineral content and frequent surging flows. Faunal specimens were collected by electrofishing, rotenone treatment, netting, and hand picking. Discharge character of the Nanpil-Kiepw River is similar to but more extreme than that of other streams of Oceania with which it was compared. Drastic flow surges appeared to be a major factor affecting community structure. At least 44 faunal species were present, 36 of them representing taxons primarily of marine origin that are characteristic of oceanic islands: 15 fishes (5 families), 10 decapod crustaceans (3 families), and 11 snails (2 families). Larvae of aquatic moths were the only insects of significance. Four sicydiine gobies are new species possibly endemic to Ponape or the Eastern Caroline Islands. Based on numbers of species within prominent taxons and diadromous groups, Ponape’s faunal diversity exceeds that of Samoa, Guam, and Hawaii, but is lower than that of Palau. Similarities of Ponape's identified fish species to those of Palau suggest that Ponape was colonized from the west along the “Caroline conduit.”

Pohnpei↗
USGS2010

Organic petrology of subbituminous carbonaceous shale samples from Chalāw, Kabul Province, Afghanistan: Considerations for paleoenvironment and energy resource potential

Neogene (?) subbituminous carbonaceous shale deposits from Chalāw, Afghanistan, were investigated through organic petrology techniques and standard coal analyses to determine paleoenvironment and potential for resource utilization. The Chalāw deposit, approximately 30 km southeast of Kabul, currently is exploited for brick making and domestic heating and cooking. Three multiple-bench channel samples of the mined bed at Chalāw were collected and evaluated. The presence of significant huminite (ranging from 0.2 to 59.0 vol.%, mineral-inclusive basis) is suggestive of a terrestrial lignin-rich precursor plant material. Measured reflectance values of 0.38–0.55% indicate subbituminous rank. This rank suggests burial depths of approximately 1500 m and maximum temperatures of approximately 50 °C. Structured liptinite macerals generally are absent except for some fluorescing morphologies interpreted to be poorly-preserved root cork suberinite. Sponge spicule bioliths including gemmoscleres and megascleres are common. These petrographic observations, in addition to high mineral matter content (33 to > 95 vol.%), medium to high sulfur content (2.1–11.5 wt.%, dry basis; db), and the presence of common gastropod? shell fragments and an aragonite-needle chalk bed are consistent with, but not directly indicative of, a marginal marine or estuarine mangrove depositional environment. However, additional data are necessary to confirm this hypothesis and deposition in a freshwater environment cannot be ruled out at this time. Commercial-scale development and utilization of the Chalāw deposit as a thermal fuel resource may be possible using a fluidized bed combustion system which could accept the low-quality mine product currently produced. Samples examined herein contain high-ash yield (45–90 wt.%, db), high total moisture content (17–39 wt.%), low calorific value (980–6860 Btu/lb, m,mmf), and have poor agglomerating properties (FSI = 0), consistent with fuels utilized in fluidized bed combustors. However, delineation of the extent of the deposit through field investigation will be necessary to make a quantified resource estimate for mine planning.

Kabul Province↗
USGS2011

Porphyry Cu indicator minerals in till as an exploration tool: Example from the giant Pebble porphyry Cu-Au-Mo deposit, Alaska, USA

Porphyry Cu indicator minerals are mineral species in clastic sediments that indicate the presence of mineralization and hydrothermal alteration associated with porphyry Cu and associated skarn deposits. Porphyry Cu indicator minerals recovered from shallow till samples near the giant Pebble Cu-Au-Mo porphyry deposit in SW Alaska, USA, include apatite, andradite garnet, Mn-epidote, visible gold, jarosite, pyrite, and cinnabar. Sulphide minerals other than pyrite are absent from till, most likely due to the oxidation of the till. The distribution of till samples with abundant apatite and cinnabar suggest sources other than the Pebble deposit. With three exceptions, all till samples up-ice of the Pebble deposit contain <10 grains/10kg of garnet (0.25-0.5 mm). Samples in the immediate vicinity of the Pebble deposit contain 10-20 grains, whereas samples with the most grains (>40grains/10kg) are in close proximity to smaller porphyry and skarn occurrences in the region. The distribution of Mn-epidote closely mimics the distribution of garnet in the till samples and further supports the interpretation that these minerals most likely reflect skarns associated with the porphyry deposits. All but two till samples, including those up-ice from the deposit, contain some gold grains. However, tills immediately west and down-ice of Pebble contain more abundant gold grains, and the overall number of grains decreases in the down-ice direction. Furthermore, all samples in the immediate vicinity of Pebble contain more than 65% pristine and modified grains compared to mostly re-shaped grains in distal samples. The pristine gold in till reflects short transport distances and/or liberation of gold during in-situ weathering of transported chalcopyrite grains. Jarosite is also abundant (1-2 500 grains/10kg) in samples adjacent to and up to 7 km down-ice from the deposit. Most jarosite grains are rounded and preliminary Ar/Ar dates suggest the jarosite formed prior to glaciation and it implies that a supergene cap existed over Pebble West. Assuming this interpretation is accurate, it suggests a shallow level of erosion of the Pebble deposit by glacial processes. Overall the results of this study indicate that porphyry Cu indicator minerals in till samples may be useful in the exploration for porphyry deposits in SW Alaska.

Alaska↗
USGS1988

The ecology of the soft-bottom benthos of San Francisco Bay: a community profile

This profile, part of a series of profiles concerning coastal habitats of the United States, is a detailed examination of the soft-bottom benthos of San Francisco Bay. A U.S. Fish and Wildlife Service and California Department of Fish and Game report (1979) entitled "Protection and Restoration of San Francisco Bay Fish and Wildlife Habitat" provides clear recognition of the importance of intertidal and subtidal soft-bottom habitats and their associated organisms to the bay's birds and fishes and to the overall functioning of the estuary. The purpose of this profile is to provide a description of the structure and functioning of the benthic community in San Francisco Bay (exclusive of its tidal marshes, which are discussed by M. Josselyn [1983] in another profile). The habitats covered in this volume include all nonvegetated soft-bottom intertidal and subtidal areas of the bay between the Golden Gate and the mouths of the Sacramento and San Joaquin Rivers to the northeast, and to the southern extremity of the bay. The profile provides a reference to the scientific information concerning the animals and plants of the bay's benthic communities, their importance to the bay ecosystem, and their value as a resource measured in human terms. Because there have been few process-oriented studies of the benthos of San Francisco Bay (e.g., field and laboratory rate-measurement experiments), the material presented herein is largely descriptive. Nonetheless, we have described the processes that interconnect the various physical, chemical, and biological components of the benthic environment, and the important couplings between this environment and the water column above, with reference to research results from other estuaries where necessary. We consider the role of the benthic community as a food source for fish, aquatic birds, and humans; as a consumer or degrader of organic materials including wastes; as a recycler of minerals and nutrients; and as an accumulator of pollutants.

California↗
USGS2015

Conceptual models of the formation of acid-rock drainage at road cuts in Tennessee

Pyrite and other minerals containing sulfur and trace metals occur in several rock formations throughout Middle and East Tennessee. Pyrite (FeS2) weathers in the presence of oxygen and water to form iron hydroxides and sulfuric acid. The weathering and interaction of the acid on the rocks and other minerals at road cuts can result in drainage with low pH (< 4) and high concentrations of trace metals. Acid-rock drainage can cause environmental problems and damage transportation infrastructure. The formation and remediation of acid-drainage from roads cuts has not been researched as thoroughly as acid-mine drainage. The U.S Geological Survey, in cooperation with the Tennessee Department of Transportation, is conducting an investigation to better understand the geologic, hydrologic, and biogeochemical factors that control acid formation at road cuts. Road cuts with the potential for acid-rock drainage were identifed and evaluated in Middle and East Tennessee. The pyrite-bearing formations evaluated were the Chattanooga Shale (Devonian black shale), the Fentress Formation (coal-bearing), and the Precambrian Anakeesta Formation and similar Precambrian rocks. Conceptual models of the formation and transport of acid-rock drainage (ARD) from road cuts were developed based on the results of a literature review, site reconnaissance, and the initial rock and water sampling. The formation of ARD requires a combination of hydrologic, geochemical, and microbial interactions which affect drainage from the site, acidity of the water, and trace metal concentrations. The basic modes of ARD formation from road cuts are; 1 - seeps and springs from pyrite-bearing formations and 2 - runoff over the face of a road cut in a pyrite-bearing formation. Depending on site conditions at road cuts, the basic modes of ARD formation can be altered and the additional modes of ARD formation are; 3 - runoff over and through piles of pyrite-bearing material, either from construction or breakdown material weathered from shale, and 4 - the deposition of secondary-sulfate minerals can store trace metals and, during rainfall, result in increased acidity and higher concentrations of trace metals in storm runoff. Understanding the factors that control ARD formation and transport are key to addressing the problems associated with the movement of ARD from the road cuts to the environment. The investigation will provide the Tennessee Department of Transportation with a regional characterization of ARD and provide insights into the geochemical and biochemical attributes for the control and remediation of ARD from road cuts.

Tennessee↗
USGS2012

Lineament analysis of mineral areas of interest in Afghanistan

During a preliminary mineral resource assessment of Afghanistan (Peters and others, 2007), 24 mineralized areas of interest (AOIs) were highlighted as the focus for future economic development throughout various parts of the country. In addition to located mineral resources of value, development of a viable mining industry in Afghanistan will require the location of suitable groundwater resources for drinking, processing of mineral ores for use or for export, and for agriculture and food production in areas surrounding and supporting future mining enterprises. This report and accompanying GIS datasets describe the results of both automated and manual mapping of lineaments throughout the 24 mineral occurrence AOIs described in detail by Peters and others (2007; 2011). For this study, we define lineaments as "mappable linear or curvilinear features of a surface whose parts align in a straight or slightly curving relationship that may be the expression of a fault or other linear zones of weakness" as derived from remote sensing sources such as optical imagery, radar imagery or digital elevation models (DEMs) (Sabins, 2007). Water wells in bedrock aquifers are generally more productive where boreholes intersect fractures or fracture zones. Lineament identification and analysis have long been used as a reconnaissance tool to identify such favorable conditions for groundwater resources in carbonate bedrock environments (Lattman and Parizek, 1964; Siddiqui and Parizek, 1971). More recently, lineament analysis has been used to identify areas of greater well yields in other bedrock settings, such as crystalline bedrock (Mabee and other, 1994; Moore and others, 2002). Lineaments provide an indication of bedrock areas that warrant further investigation for optimal water well placement. They may also indicate areas of preferential flow and storage of groundwater, and, thus, areas with a greater density of lineaments may indicate greater secondary porosity. Lineaments may indicate structurally trending mineralized areas (for example, Mars and Rowan, 2007), or locations of near-surface water resources, especially when surface vegetation growth coincides with lineaments. The purpose of this report and accompanying GIS data is to provide lineament maps that give one indication of areas that warrant further investigation for optimal bedrock water-well placement within 24 target areas for mineral resources (Peters and others, 2011). These data may also support the identification of faults related to modern seismic hazards (for example, Wheeler and others, 2005; Ruleman and others, 2007), as well as support studies attempting to understand the relationship between tectonic and structural controls on hydrothermal fluid flow, subsequent mineralization, and water-quality issues near mined and unmined mineral deposits (for example, Eppinger and others, 2007).

Open-File Report↗
USGS2023

Insights into the metamorphic history and origin of flake graphite mineralization at the Graphite Creek graphite deposit, Seward Peninsula, Alaska, USA

Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ 13 C VPDB values of − 30 to − 12‰ and pyrrhotite δ 34 S VCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.

Alaska↗
USGS2017

Use of raw materials in the United States from 1900 through 2014

The economic growth of an industrialized nation such as the United States requires raw materials for construction (buildings, bridges, highways, and so forth), defense, and processing and manufacture of goods and services. Since the beginning of the 20th century, the types and quantities of raw materials used have increased and changed significantly. This fact sheet quantifies the amounts of raw materials (other than food and fuel) that have been used in the U.S. economy annually for a period of 115 years, from 1900 through 2014. It provides a broad overview of the quantity (weight) of nonfood and nonfuel materials used in the economy and illustrates the use and significance of raw nonfuel minerals in particular as building blocks of society. These data have been compiled to help the public and policymakers understand the changing annual flow of raw materials put into use in the United States. Such information can be helpful in assessing the potential effects of materials use on the environment, assessing materials’ intensity of use, and examining the role that these materials play in the economy. The data presented indicate the substitution and shift in materials usage from renewable to nonrenewable materials during the 20th century. The disaggregated quantities by commodity (not shown in this fact sheet) may be tested against supply adequacy and end of life issues.

Fact Sheet↗
USGS2002

Physical and stable-isotope evidence for formation of secondary calcite and silica in the unsaturated zone, Yucca Mountain, Nevada

Calcite and silica form coatings on fracture footwalls and cavity floors in the welded tuffs at Yucca Mountain, the potential site of a high-level radioactive waste repository. These secondary mineral deposits are heterogeneously distributed in the unsaturated zone (UZ) with fewer than 10% of possible depositional sites mineralized. The paragenetic sequence, compiled from deposits throughout the UZ, consists of an early-stage assemblage of calcite??fluorite??zeolites that is frequently capped by chalcedony??quartz. Intermediate- and late-stage deposits consist largely of calcite, commonly with opal on buried growth layers or outermost crystal faces of the calcite. Coatings on steep-dipping fractures usually are thin (??? 3 mm) with low-relief outer surfaces whereas shallow-dipping fractures and lithophysal cavities typically contain thicker, more coarsely crystalline deposits characterized by unusual thin, tabular calcite blades up to several cms in length. These blades may be capped with knobby or corniced overgrowths of late-stage calcite intergrown with opal. The observed textures in the fracture and cavity deposits are consistent with deposition from films of water fingering down fracture footwalls or drawn up faces of growing crystals by surface tension and evaporated at the crystal tips. Fluid inclusion studies have shown that most early-stage and some intermediate-stage calcite formed at temperatures of 35 to 85??C. Calcite deposition during the past several million years appears to have been at temperatures < 30??C. The elevated temperatures indicated by the fluid inclusions are consistent with temperatures estimated from calcite ??18O values. Although others have interpreted the elevated temperatures as evidence of hydrothermal activity and flooding of the tuffs of the potential repository, the authors conclude that the temperatures and fluid-inclusion assemblages are consistent with deposition in a UZ environment that experienced prolonged heat input from gradual cooling of nearby plutons. The physical restriction of the deposits (and, therefore, fluid flow) to fracture footwalls and cavity floors and the heterogeneous and limited distribution of the deposits provides compelling evidence that they do not reflect flooding of the thick UZ at Yucca Mountain. The textures and isotopic and chemical compositions of these mineral deposits are consistent with deposition in a UZ setting from meteoric waters percolating downward along fracture flow paths.

Applied Geochemistry↗
USGS1990

Monitoring long-term effects of offshore oil and gas development along the Southern California outer continental shelf and slope: Background environmental conditions in the Santa Maria Basin

Potential environmental impacts of materials discharged from oil and gas development and production platforms off the coast of southern California (Santa Maria Basin) are being monitored during an ongoing, long-term (fiveyear) field program. The study combines hypothesis testing of platform effects with basic research on the structure and dynamics of the regional ecosystem over a time series encompassing both seasonal and repeated annual scales. Oceanographic features and processes that are being measured focus on the benthos and include biological community indices and species abundances for hard-bottom and soft-bottom (macroinfauna and meiofauna) assemblages; levels and distributions of trace metals and hydrocarbons in bottom sediments, suspended particulates, animal tissues, and pore waters; water currents and otherphysical-oceanographicfeatures; various sedimentological properties (sediment grain size, total organic carbon, shear strength, distribution of mineral types, radioisotope profiles, and degrees of sediment mixing as a result of bioturbation); sediment and pollutant-transport processes; and animal-sediment-pollutant interactions. Synoptic measurement of these different environmental variables over the extended sampling period provides an opportunity to examine long-term variability in the benthic environment with respect to both natural and anthropogenic causes. Efforts to distinguish between natural variability and low-level cumulative impacts of drilling are given special attention. Results obtained during the first two years of sampling provide a basis for beginning to understand environmental processes and relations important in detecting and interpreting any subsequent impacts caused by drilling activities in this complex and productive region of the California outer continental shelf and slope. Background chemical, physical, and biological data generated during this period demonstrate that impacts of discharges from oil and gas operations should be detectable, if they occur, and should be distinguishable from natural environmental variability. Small inputs of barium and petroleum hydrocarbons have been detected and appear to be associated with the minor drilling activities that have occurred in the area thus far, however, these initial inputs have not led to any noticeable biological impacts. These initial results are hopefully of value for two reasons: (1) in providing a summary of basic chemical, physical, and biological features of the benthic environment within the Santa Maria Basin; and (2) in presenting information on research strategies that should be considered in designing studies dealing with similar resource-management problems in other parts of the world.

California↗
USGS2024

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis↗
USGS2008

View_SPECPR: Software for plotting spectra (installation manual and user's guide, version 1.2)

This document describes procedures for installing and using the 'View_SPECPR' software system to plot spectra stored in SPECPR (SPECtrum Processing Routines) files. The View_SPECPR software is comprised of programs written in IDL (Interactive Data Language) that run within the ENVI (ENvironment for Visualizing Images) image processing system. SPECPR files are used by earth-remote-sensing scientists and planetary scientists for storing spectra collected by laboratory, field, and remote sensing instruments. A widely distributed SPECPR file is the U.S. Geological Survey (USGS) spectral library that contains thousands of spectra of minerals, vegetation, and man-made materials (Clark and others, 2007). SPECPR files contain reflectance data and associated wavelength and spectral resolution data, as well as meta-data on the time and date of collection and spectrometer settings. Furthermore, the SPECPR file automatically tracks changes to data records through its 'history' fields. For more details on the format and content of SPECPR files, see Clark (1993). For more details on ENVI, see ITT (2008). This program has been updated using an ENVI 4.5/IDL7.0 full license operating on a Windows XP operating system and requires the installation of the iTools components of IDL7.0; however, this program should work with full licenses on UNIX/LINUX systems. This software has not been tested with ENVI licenses on Windows Vista or Apple Operating Systems.

Open-File Report↗
USGS2011

Assessment and distribution of antimony in soils around three coal mines, Anhui, China

Thirty-three soil samples were collected from the Luling, Liuer, and Zhangji coal mines in the Huaibei and Huainan areas of Anhui Province, China. The samples were analyzed for antimony (Sb) by inductively coupled plasma-optical emission spectrometry (ICP-OES) method. The average Sb content in the 33 samples was 4 mg kg −1 , which is lower than in coals from this region (6.2 mg kg −1 ). More than 75% of the soils sampled showed a significant degree of Sb pollution (enrichment factors [EFs] 5–20). The soils collected near the gob pile and coal preparation plant were higher in Sb content than those collected from residential areas near the mines. The gob pile and tailings from the preparation plant were high in mineral matter content and high in Sb. They are the sources of Sb pollution in surface soils in the vicinity of coal mines. The spatial dispersion of Sb in surface soil in the mine region shows that Sb pollution could reach out as far as 350 m into the local environment conditions. Crops in rice paddies may adsorb some Sb and reduce the Sb content in soils from paddyfields. Vertical distribution of Sb in two soil profiles indicates that Sb is normally relatively immobile in soils.

Anhui↗
USGS2017

Formation of Fe-Mn crusts within a continental margin environment

This study examines Fe-Mn crusts that form on seamounts along the California continental-margin (CCM), within the United States 200 nautical mile exclusive economic zone. The study area extends from approximately 30° to 38° North latitudes and from 117° to 126° West longitudes. The area of study is a tectonically active northeast Pacific plate boundary region and is also part of the North Pacific Subtropical Gyre with currents dominated by the California Current System. Upwelling of nutrient-rich water results in high primary productivity that produces a pronounced oxygen minimum zone. Hydrogenetic Fe-Mn crusts forming along the CCM show distinct chemical and mineral compositions compared to open-ocean crusts. On average, CCM crusts contain more Fe relative to Mn than open-ocean Pacific crusts. The continental shelf and slope release both Fe and Mn under low-oxygen conditions. Silica is also enriched relative to Al compared to open-ocean crusts. This is due to the North Pacific silica plume and enrichment of Si along the path of deep-water circulation, resulting in Si enrichment in bottom and intermediate waters of the eastern Pacific. The CCM Fe-Mn crusts have a higher percentage of birnessite than open-ocean crusts, reflecting lower dissolved seawater oxygen that results from the intense coastal upwelling and proximity to zones of continental slope pore-water anoxia. Carbonate fluorapatite (CFA) is not present and CCM crusts do not show evidence of phosphatization, even in the older sections. The mineralogy indicates a suboxic environment under which birnessite forms, but in which pH is not high enough to facilitate CFA deposition. Growth rates of CCM crusts generally increase with increasing water depth, likely due to deep-water Fe sources mobilized from reduced shelf and slope sediments. Many elements of economic interest including Mn, Co, Ni, Cu, W, and Te have slightly or significantly lower concentrations in CCM crusts relative to crusts from the Pacific Prime Crust Zone and other open-ocean basins. However, concentrations of total rare earth elements and yttrium average only slightly lower contents and in the future may be a strategic resource for the U.S.

California↗
USGS2021

Weakening of peridotite sheared at hydrothermal conditions

We conducted triaxial friction tests at hydrothermal conditions (25°C–350°C) on gouges of peridotite and its principal mineral constituents olivine and orthopyroxene. Pore-fluid chemistry was varied by the use of peridotite, granite, or quartzite driving blocks (representing wall rock) housing the gouge layer. Samples sheared at slow rates initially strengthen to a peak value, and then weaken toward a residual strength. The transition is accompanied by a change from velocity-weakening to velocity-strengthening behavior marked by a series of small stress drops. The extent of weakening varies with the ultramafic mineralogy and with the chemical environment established by the driving block lithology. The strengths of olivine and olivine-rich peridotite gouges decrease substantially (to μ ∼ 0.25–0.30), and that of orthopyroxene to a lesser extent, at temperatures ≥200°C when sheared between crustal driving blocks. Less weakening is observed in the peridotite-block experiments; the minimum strength of the peridotite gouges ( μ ∼ 0.5) occurs at 250°C, the temperature at which olivine hydration rates are near their maximum in ultramafic rocks. The strength reductions in all experiments are attributed to solution-transfer (pressure solution) processes that come to predominate over cataclastic mechanisms during shear. The lower pH of fluids in contact with silica-saturated crustal rocks enhances the weakening of olivine-rich gouges. In these short-duration experiments, secondary phyllosilicate mineral growth was of a limited extent and varied with gouge and wall-rock mineralogy and with temperature. Over geologic time spans, however, the alteration assemblages will assume an increasingly important role in fault-zone behavior.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Silica in a Mars analog environment: Ka u Desert, Kilauea Volcano, Hawaii

Airborne Visible/Near-Infrared Imaging Spectrometer (AVIRIS) data acquired over the Ka u Desert are atmospherically corrected to ground reflectance and used to identify the mineralogic components of relatively young basaltic materials, including 250-700 and 200-400 year old lava flows, 1971 and 1974 flows, ash deposits, and solfatara incrustations. To provide context, a geologic surface units map is constructed, verified with field observations, and supported by laboratory analyses. AVIRIS spectral endmembers are identified in the visible (0.4 to 1.2 ??m) and short wave infrared (2.0 to 2.5 ??m) wavelength ranges. Nearly all the spectral variability is controlled by the presence of ferrous and ferric iron in such minerals as pyroxene, olivine, hematite, goethite, and poorly crystalline iron oxides or glass. A broad, nearly ubiquitous absorption feature centered at 2.25 ??m is attributed to opaline (amorphous, hydrated) silica and is found to correlate spatially with mapped geologic surface units. Laboratory analyses show the silica to be consistently present as a deposited phase, including incrustations downwind from solfatara vents, cementing agent for ash duricrusts, and thin coatings on the youngest lava flow surfaces. A second, Ti-rich upper coating on young flows also influences spectral behavior. This study demonstrates that secondary silica is mobile in the Ka u Desert on a variety of time scales and spatial domains. The investigation from remote, field, and laboratory perspectives also mimics exploration of Mars using orbital and landed missions, with important implications for spectral characterization of coated basalts and formation of opaline silica in arid, acidic alteration environments. Copyright 2010 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗