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At least 523 records · Page 29Linked to original sources

Depositional controls on detrital zircon provenance: An example from upper Cretaceous strata, southern Patagonia

Understanding how depositional environments within a sedimentary system redistribute and sequester sediment is critical for interpreting basin-scale provenance trends. However, sedimentary source-to-sink models commonly examine temporal changes and do not consider how variation in sedimentation processes across a dispersal pathway may result in contrasting provenance signatures. In this paper, we demonstrate a down-paleoslope shift in detrital zircon provenance signatures correlated with shallow-marine lithofacies patterns from the Upper Cretaceous La Anita Formation and underlying continental slope lithofacies of the Alta Vista Formation (Magallanes-Austral Basin, southern Patagonia). New stratigraphic, sedimentologic, and lithofacies analysis results from the La Anita Formation suggest an upward shoaling succession, from a (i) storm-influenced shoreface, (ii) fluvially-dominated, wave-influenced delta, and a (iii) high-energy, gravelly foreshore. Stratigraphic sections are paired with U-Pb detrital zircon sandstone samples (N = 20; n = 5219), which provide both maximum depositional ages and provenance characteristics. While all samples contain abundant zircon derived from the Andean volcanic arc (ca. 145–75 Ma), the amount from both Jurassic distal volcanic massifs (ca. 188–162 Ma) and recycled orogenic sources exhumed during the advance of the Cretaceous fold-and-thrust belt (>200 Ma; 157–142 Ma) vary with changes in depositional environment. We argue that down-paleoslope, systematic enriching of local fold-and-thrust belt material within the La Anita Formation is reflective of progressive mixing of grains transported via shallow-marine processes, while distally enriched fluvio-deltaic transported zircons were sourced from large, regional catchments. This suggests that competition between transport processes across a shallow and marginal marine sequence of rocks affects the resulting provenance signatures recorded within a single stratigraphic succession. These data also detail the degree of sediment pathway connectivity between shallow-marine sources and deep-marine sinks. Detrital zircon results from muddy continental slope facies of the Alta Vista Formation are made up entirely locally derived material, while zircon results from deep-water, sand-rich channel facies of the Formation are indistinguishable from coeval fluvio-deltaic zircon signatures. This implies that continental shelf-to-slope connectivity in a sediment dispersal system, via submarine canyons or shelf-edge delta progradation, is necessary for detrital zircon distributions from the shallow-marine realm to propagate into the deeper marine.

Patagonia

Assessing environmental change associated with early Eocene hyperthermals in the Atlantic Coastal Plain, USA

Eocene transient global warming events (hyperthermals) can provide insight into a future warmer world. While much research has focused on the Paleocene–Eocene Thermal Maximum (PETM), hyperthermals of a smaller magnitude can be used to characterize climatic responses over different magnitudes of forcing. This study identifies two events, namely the Eocene Thermal Maximum 2 (ETM2 and H2), in shallow marine sediments of the Eocene-aged Salisbury Embayment of Maryland, based on magnetostratigraphy, calcareous nannofossil, and dinocyst biostratigraphy, as well as the recognition of negative stable carbon isotope excursions (CIEs) in biogenic calcite. We assess local environmental change in the Salisbury Embayment, utilizing clay mineralogy, marine palynology, δ 18 O of biogenic calcite, and biomarker paleothermometry (TEX 86 ). Paleotemperature proxies show broad agreement between surface water and bottom water temperature changes. However, the timing of the warming does not correspond to the CIE of the ETM2 as expected from other records, and the highest values are observed during H2, suggesting factors in addition to p CO 2 forcing have influenced temperature changes in the region. The ETM2 interval exhibits a shift in clay mineralogy from smectite-dominated facies to illite-rich facies, suggesting hydroclimatic changes but with a rather dampened weathering response relative to that of the PETM in the same region. Organic walled dinoflagellate cyst assemblages show large fluctuations throughout the studied section, none of which seem systematically related to CIE warming. These observations are contrary to the typical tight correspondence between climate change and assemblages across the PETM, regionally and globally, and ETM2 in the Arctic Ocean. The data do indicate very warm and (seasonally) stratified conditions, likely salinity-driven, across H2. The absence of evidence for strong perturbations in local hydrology and nutrient supply during ETM2 and H2, compared to the PETM, is consistent with the less extreme forcing and the warmer pre-event baseline, as well as the non-linear response in hydroclimates to greenhouse forcing.

Atlantic Coastal Plain

Cretaceous biostratigraphy in the Wyoming thrust belt.

In the Cretaceous section of the thrust belt, fossils are especially useful for dating and correlating repetitive facies of different ages in structurally complex terrain. The biostratigraphic zonation for the region is based on megafossils (chiefly ammonites) , which permit accurate dating and correlation of outcrop sections, and which have been calibrated with the radiometric time scale for the Western Interior. Molluscan and vertebrate zone fossils are difficult to obtain from the subsurface, however, and ammonites are restricted to rocks of marine origin. Palynomorphs (plant microfossils) have proven to be the most valuable fossils in the subsurface because they can be recovered from drill cuttings. Palynomorphs also are found in both marine and nonmarine rocks and can be used for correlation between facies. Stratigraphic ranges of selected Cretaceous marine and nonmarine palynomorphs in previously designated reference sections in Fossil Basin, Wyoming are correlated with the occurrence of ammonites and other zone fossils in the same sections. These correlations can be related to known isotopic ages, and they contribute to the calibration of palynomorph ranges in the Cretaceous of the Western Interior. -from Authors

Mountain Geologist

The campi flegrei (Italy) geothermal system: A fluid inclusion study of the mofete and San Vito fields

A fluid inclusion study of core from the Mofete 1, Mofete 2, Mofete 5, San Vito 1, and San Vito 3 geothermal wells (Campi Flegrei, Campania, Italy) indicates that the hydrothermal minerals were precipitated from aqueous fluids (??CO2) that were moderately saline (3-4 wt.% NaCl equiv.) to hypersaline (> 26 wt.% NaCl equiv.) and at least in part, boiling. Three types of primary fluid inclusions were found in authigenic K-feldspar, quartz, calcite, and epidote: (A) two-phase [liquid (L) + vapor (V)], liquid-rich inclusions with a range of salinity; (B) two-phase (L + V), vaporrich inclusions with low salinity; and (C) three-phase [L + V + crystals (NaCL)], liquid-rich inclusions with hypersalinity. Results of microthermometric and crushing studies are reported for twenty drill core samples taken from the lower portions of the five vertical wells. Data presented for selected core samples reveal a general decrease in porosity and increase in bulk density with increasing depth and temperature. Hydrothermal minerals commonly fill fractures and pore-spaces and define a zonation pattern, similar in all five wells studied, in response to increasing depth (pressure) and temperature. A greenschist facies assemblage, defined by albite + actinolite, gives way to an amphibolite facies, defined by plagioclase (andesine) + hornblende, in the San Vito 1 well at about 380??C. The fluid inclusion salinity values mimic the saline and hypersaline fluids found by drilling. Fluid inclusion V/L homogenization temperatures increase with depth and generally correspond to the extrapolated down-hole temperatures. However, fluid inclusion data for Mofete 5 and mineral assemblage data for San Vito 3, indicate fossil, higher-temperature regimes. A limited 87Sr/86Sr study of leachate (carbonate) and the leached cores shows that for most samples (except San Vito 3) the carbonate deposition has been from slightly 87Sr-enriched fluids and that Sr isotopic exchange has been incomplete. However, San Vito 3 cores show an approach to fluid/rock Sr equilibrium with a fluid similar to modern ocean water in 87Sr/86Sr ratio. The Campi Flegrei volcanic system has evolved undersaturated products, mostly trachyte, and defines a large (??? 12 km) caldera. The hydrothermal system developed in this location can be used as an analog for fossil systems in similar trachytic environments. The potential for ore mineralization is expressed by the recognition, from fluid inclusion and drilling data, of ore-forming environments such as boiling and brine stratification. ?? 1989.

Journal of Volcanology and Geothermal Research

Sedimentology of Permian upper part of the Minnelusa Formation, eastern Powder River Basin, Wyoming, and a comparison to the subsurface

Describes dolomite, gypsum, and sandstone units deposited in transgressive-regressive cycles. Three depositional cycles are partly exposed. The cycles observed in outcrop were informally labelled cycle 1, cycle 2, and cycle 3 in ascending stratigraphic order. West Mellott field represents a subsurface example of the facies and facies relationships observed in outcrop. The eolian-dune sandstone of the C cycle, which was partially reworked by the transgression of the B cycle, produces oil at West Mellott. The draping of dolomite and anhydrite of the B cycle on the eolian-dune sandstone of the C cycle is analogous to the draping gypsum on dune sand in cycle 2 in outcrop. -from Authors

Mountain Geologist

Holocene sedimentation and coastal wetlands response to rising sea level at the Aucilla river mouth, a low energy coast in the Big Bend area of Florida

The shallow dip of the Florida carbonate platform results in low wave energy on Florida ???Big Bend??? coasts. Therefore sedimentation is dominated by river-and tidal-hydrodynamics near the Aucilla River mouth. Where present, Holocene sediments are thin and unconformably overlie Oligocene-aged Suwannee Limestone. The oldest unlithified sediments include reworked carbonate rubble with clay and wood fragments (seven thousand years old or less, based on wood radio-carbon dating). Although this basal sequence is observed in most areas, the sediments that overlie it vary. Sediment sequences from the outer littoral to submarine environments include organic-rich sands, oyster biotherm remains, and cleaner sands with organic-filled burrows. Inner littoral (salt-marsh) sequences generally consist of sandy, fining-upwards sequences in which dry weights of fine-grained clastics and organic components increase up-sequence at similar rates. Offshore sediments preserve greatly attenuated fluvial and salt-marsh facies, if these facies are preserved at all. With sea-level rise, erosion can result from insufficient sediment supply and down-cutting by tidal currents (Dolotov, 1992; and Dalrymple et al., 1992). Dolotov (1992) attributes displacement of original coastal stratigraphy to insufficient sediments for beach profile maintenance, while Dalrymple et al. (1992) attribute erosional truncation (ravinement) or complete removal of portions of typical estuarine sequences to headward migration of tidal channels.

Conference Paper

Ramah Member of the Crevasse Canyon Formation - A new stratigraphic unit in the Zuni Basin, west-central New Mexico

Nonmarine deposition accompanying and following a regression of the Cretaceous Interior Seaway during late Turonian time left a sedimentary sequence consisting of fluvial channel sandstones, thin overbank sandstones, and paludal shales containing thin coal beds. This unit is herein designated the Ramah Member of the Crevasse Canyon Formation. The Ramah Member is locally well exposed in the Zuni Basin of west-central New Mexico where it rests on the Gallup Sandstone (marine) and is overlain by the distinctive, feldspathic Torrivio Member of the Crevasse Canyon Formation (formerly of the Gallup Sandstone) Near Ramah, New Mexico the sequence overlies the F member of the Gallup but northward it overlies progressively younger members. These younger members are discrete sand-stone units associated with minor oscillations of relative sea level during a major regional-scale regression. North and east of Puerco Gap, near Gallup. New Mexico, the Ramah Member thins appreciably, and where unmappable it may be included with the Torrivio Member Southward from Gallup in the Zuni Basin. the Ramah locally approaches 150 ft in thickness and contains minable coal beds. The interval was previously referred to as the coal-bearing member of the Gallup (Mapel and Yesberger, 1985) or the Ramah unit (Anderson and Stricker, 1904). In the northern part of the Zuni Basin a problem may exist locally in determinig the top of the Ramah Member. This is due to the presence of fluviel sandstone with coarse-grained facies that looks much the s ame as the Torrivio Member, but underlines it Two criteria may be employed to distiguish the lower sandstone from the Torrivio and properly place it in the strartigraphic succession: (1) the lower sandstone is generally not as feldspathic as the Torrivio nor do the coarse-grained facies contain pebble-size material; and (2) the lower sandstone is not nearly as widespread as the overlying Torrivio. which has a blanket geometry. The type section of the Ramah Member is in the SE1/4 NW1/4 sec. 16 T10N R16W approximately 4 mi southwest of the town of Ramah. The principal coal lies near the top of the member and was mined during the 1920s to supply coal for the Zuni Pueblo schools.

New Mexico Geology

Depositional sequence stratigraphy and architecture of the cretaceous ferron sandstone: Implications for coal and coalbed methane resources - A field excursion

This Field Excursion will visit outcrops of the fluvial-deltaic Upper Cretaceous (Turonian) Ferron Sandstone Member of the Mancos Shale, known as the Last Chance delta or Upper Ferron Sandstone. This field guide and the field stops will outline the architecture and depositional sequence stratigraphy of the Upper Ferron Sandstone clastic wedge and explore the stratigraphic positions and compositions of major coal zones. The implications of the architecture and stratigraphy of the Ferron fluvial-deltaic complex for coal and coalbed methane resources will be discussed. Early works suggested that the southwesterly derived deltaic deposits of the the upper Ferron Sandstone clastic wedge were a Type-2 third-order depositional sequence, informally called the Ferron Sequence. These works suggested that the Ferron Sequence is separated by a type-2 sequence boundary from the underlying 3rd-order Hyatti Sequence, which has its sediment source from the northwest. Within the 3rd-order depositional sequence, the deltaic events of the Ferron clastic wedge, recognized as parasequence sets, appear to be stacked into progradational, aggradational, and retrogradational patterns reflecting a generally decreasing sediment supply during an overall slow sea-level rise. The architecture of both near-marine facies and non-marine fluvial facies exhibit well defined trends in response to this decrease in available sediment. Recent studies have concluded that, unless coincident with a depositional sequence boundary, regionally extensive coal zones occur at the tops of the parasequence sets within the Ferron clastic wedge. These coal zones consist of coal seams and their laterally equivalent fissile carbonaceous shales, mudstones, and siltstones, paleosols, and flood plain mudstones. Although the compositions of coal zones vary along depositional dip, the presence of these laterally extensive stratigraphic horizons, above parasequence sets, provides a means of correlating and defining the tops of depositional parasequence sets in both near-marine and non-marine parts of fluvial-deltaic depositional sequences. Ongoing field studies, based on this concept of coal zone stratigraphy, and detailed stratigraphic mapping, have documented the existence of at least 12 parasequence sets within the Last Chance delta clastic wedge. These parasequence sets appear to form four high frequency, 4th-order depositional sequences. The dramatic erosional unconformities, associated with these 4th-order sequence boundaries, indicate that there was up to 20-30 m of erosion, signifying locally substantial base-level drops. These base-level drops were accompanied by a basin ward shift in paleo-shorelines by as much as 5-7 km. These 4th-order Upper Ferron Sequences are superimposed on the 3rd-order sea-level rise event and the 3rd-order, sediment supply/accommodation space driven, stratigraphie architecture of the Upper Ferron Sandstone. The fluvial deltaic architecture shows little response to these 4th-order sea-level events. Coal zones generally thicken landward relative to the mean position of the landward pinch-out of the underlying parasequence set, but after some distance landward, they decrease in thickness. Coal zones also generally thin seaward relative to the mean position of the landward pinch-out of the underlying parasequence set. The coal is thickest in the region between this landward pinch-out and the position of maximum zone thickness. Data indicate that the proportion of coal in the coal zone decreases progressively landward from the landward pinch-out. The effects of differential compaction and differences in original pre-peat swamp topography have the effect of adding perturbations to the general trends. These coal zone systematics have major impact on approaches to exploration and production, and the resource accessment of both coal and coalbed methane.

Brigham Young University Geology Studies

Biostratigraphy and dolomite porosity trends of the Lisburne Group

This preliminary study is based on measured and carefully collected sections of the Lisburne Group (fig. 1, sees. 1-29). The outcrops extend from Cape Lisburne (sec. 1) in the west to Egaksrak River (sec. 29) in northeastern Alaska and are used as the basic building blocks for the carbonate facies maps and the cross section. Lithologic and foraminifera samples were collected at 10-foot intervals and rugose corals were collected within each section where found. The rock material was cut into thin section, and petrographic and microfossil studies were made to determine environments of deposition, facies, diagenetic changes, and microfossil content. Coral collections were studied in thin section.

Alaska

Holocene sand shoals offshore of the Mississippi River delta plain

Offshore of the Mississippi River delta plain lies a series of Holocene sand shoals marking the position of ancient submerged shorelines associated with younger shelf-phase delta plains. These submerged shorelines represent positions when sea level stood lower than present. Short periods of rapid sea level rise during the Holocene transgression, in combination with subsidence, led to the submergence of these sandy shorelines, which can be recognized at the -33 ft (-10 m) and -66 ft (-20 m) isobaths on the Louisiana continental shelf The -33 ft (-10 m) shoreline trend is represented by Trinity Shoal and Ship Shoal, which are associated with the late Holocene Mississippi River delta plain. Trinity Shoal is derived from the Cypremont-Sale delta complex and is located 12 mi (20 km) offshore of Marsh Island. This shoal is 22 mi (35 km) long, 5 mi (8 km) wide, and 16 - 20 ft (5 - 6 m) thick. The facies relationships indicate that Trinity Shoal is a submerged barrier system in the initial stages of shoreface reworking. To the east is Ship Shoal which is associated with the Maringouin-Teche delta complex. This shoal is located 12 mi (20 km) offshore of the Isles Dernieres and is 31 mi (50 km) long, 5 - 6 mi (8 - 10 km) wide, and 13 - 20 ft (4 - 6 m) thick. The facies relationships indicate that Ship Shoal is a marine sand body derived from shoreface reworking of a submerged barrier island. The -66 ft (-20 m) shoreline trend is represented by the Outer Shoal and St. Bernard Shoals, which are associated with the early Mississippi River delta plain. The Outer Shoal is a low relief sand body, which lies seaward of Ship Shoal immediately west of the Mississippi Canyon. The eastern continuation of the -66 ft (-20 m) shoreline trend is the St. Bernard Shoals, which lie 16 mi (25 km) offshore of the Chandeleur Islands. In contrast to the other shoal systems, the St. Bernard Shoals form a shore-parallel zone of more than seven smaller sand shoals which, in many respects, are similar to a shore-oblique sand-ridge field. Collectively, these sand shoals represent a large potential source of aggregate for shoreline restoration and erosion control as well as possible hard mineral resources. Scientifically, these shoals provide insight into the processes which control coastal evolution and shelf sand development under the condition of relative sea level rise.

Mississippi River

Inner shelf deposits of the Louisiana-Mississippi-Alabama region, Gulf of Mexico

The late Quaternary morphology, shallow stratigraphy and sediment distribution of the Louisiana-Mississippi-Alabama inner shelf region are the product of transgressive and regressive sedimentary processes. Shelf sedimentary facies were deposited by deltaic progradation, followed by shoreface erosion and submergence. This information is based on interpretations and synthesis of more than 4,160 mi (6,700 km) of high resolution seismic profiles, 75 grab samples, and 77 vibracores. The shelf can be divided into two main depositional regions. The southwestern region, east and south of the Mississippi River plain, was formed by early Holocene delta complexes, overlying a late Wisconsinan delta. Deposits of the late Wisconsinan delta consist of well-defined coarsening-upward sequences and represent deltaic progradation during low sea level stands. The relatively recent Mississippi delta complexes have deposits which consist of fine-grained sands, silt and clay. With the late Holocene rise in sea level, asymmetrical sand ridges (16 ft, or 5 m, relief) have formed due to marine reworking of shoreline features. The northeastern region, offshore of the Mississippi-Alabama barrier islands, was formed by Pleistocene fluvial systems and Recent shoreface erosion and ravinement. Underlying the relatively thin Holocene sediment cover are relict fluvial sands which were deposited during the late Wisconsinan lowstand. Subsequent sea level rise allowed marine processes to rework and redistribute sediments forming the nearshore fine-grained facies and shelf sands sheet.

Gulf of Mexico

Devonian of the Southwestern United States

The structural framework that controlled Devonian deposition consisted of, from west to east: (1) a eugeosynclinal area in northern California and western Nevada; (2) a miogeosynclinal area in southeastern California, eastern Nevada, and western Utah; and (3) a cratonic area in Arizona, eastern Utah, Colorado, New Mexico, and western Texas, east of a northeast-trending hinge line (Wasatch line). The eugeosyncline contains a fragmentary record of Middle Devonian rocks at least 4,000 feet thick characterized by thin-bedded chert, siliceous mudstone, and some limestone and volcanic rocks. The original thickness, however, probably exceeded 6,000 feet and probably included Lower and Upper Devonian rocks. The miogeosyncline contains Lower, Middle, and Upper Devonian rocks as much as 6,000 feet thick characterized by thick units of dolomite and limestone and some local interbeds of sandstone. A transitional zone perhaps 50 miles wide separates the eugeosynclinal and miogeosynclinal facies. The craton contains mostly Upper Devonian rocks, generally less than 1,000 feet thick, characterized by dolomite and limestone and local interbeds of sandstone and mudstone. Widespread crustal movements occurred during Late Devonian time. The Antler orogeny in Nevada initiated a culm facies in the geosyncline. Eugeosynclinal and transitional rocks including those of Devonian age were uplifted to form the Antler orogenic belt, and then were thrust eastward over autochthonous miogeosynclinal rocks in latest Devonian or earliest Mississippian time. Folding and faulting, and subsequent erosion on local uplifts, produced clastic deposits of Late Devonian age in Utah and southwestern Colorado. Devonian rocks in many parts of the geosynclinal area have been moved since Devonian time by large-scale, generally eastward thrusting, oroflexural bending and strike-slip faulting. Four major subdivisions of the Devonian System and related rocks are treated separately: 1) Lower Devonian (Gedinnian, Siegenian, Emsian) and related Upper Silurian (Ludlovian) rocks. 2) Middle Devonian (Eifelian and Givetian) rocks. 3) Lower Upper Devonian (Frasnian, to I ) rocks. 4) Upper Upper Devonian (Famennian, to II-VI ) and related lowermost Mississippian (Tournaisian, cu I ) rocks.

Conference Paper

Geochemistry and geochronology of carbonate-hosted base metal deposits in the southern Brooks Range, Alaska: Temporal association with VMS deposits and metallogenic implications

The Brooks Range contains enormous accumulations of zinc and copper, either as VMS or sediment-hosted deposits. The Ruby Creek and Omar deposits are Cu-Co stratabound deposits associated with dolomitic breccias. Numerous volcanogenic Cu-Zn (+/-Ag, Au) deposits are situated ~20 km north of the Ruby Creek deposit. The carbonate-hosted deposits consist of chalcopyrite and bornite that fill open spaces, replace the matrix of the breccias, and occur in later cross-cutting veins. Cobaltiferous pyrite, chalcocite, minor tennantite-tetrahedrite, galena, and sphalerite are also present. At Ruby Creek, phases such as carrollite, renierite, and germanite occur rarely. The deposits have undergone post-depositional metamorphism (Ruby Creek, low greenschist facies; Omar, blueschist facies). The unusual geochemical signature includes Cu-Co +/- Ag, As, Au, Bi, Ge, Hg, Sb, and U with sporadic high Re concentrations (up to 2.7 ppm). New Re-Os data were obtained for chalcopyrite, bornite, and pyrite from the Ruby Creek deposit (analyses of sulfides from Omar are in progress). The data show extremely high Re abundances (hundreds of ppb, low ppm) and contain essentially no common Os. The Re-Os data provide the first absolute ages of ore formation for the Ruby Creek deposit and demonstrate that the Re-Os systematics of pyrite, chalcopyrite, and bornite are unaffected by greenschist metamorphism. The Re-Os data show that the main phase of Cu mineralization occurred at 384 +/-4.2 Ma, which coincides with zircon U-Pb ages from igneous rocks that are spatially and genetically associated with VMS deposits. This suggests a temporal link between regional magmatism and hydrothermal mineralization.

Alaska

Stratigraphy, age, and depositional setting of the Miocene Barstow Formation at Harvard Hill, central Mojave Desert, California

New detailed geologic mapping and geochronology of the Barstow Formation at Harvard Hill, 30 km east of Barstow, CA, help to constrain Miocene paleogeography and tectonics of the central Mojave Desert. A northern strand of the Quaternary ENE-striking, sinistral Manix fault divides the Barstow Formation at Harvard Hill into two distinct lithologic assemblages. Strata north of the fault consist of: a green rhyolitic tuff, informally named the Shamrock tuff; lacustrine sandstone; partially silicified thin-bedded to massive limestone; and alluvial sandstone to pebble conglomerate. Strata south of the fault consist of: lacustrine siltstone and sandstone; a rhyolitic tuff dated at 19.1 Ma (U-Pb); rock-avalanche breccia deposits; partially silicified well-bedded to massive limestone; and alluvial sandstone and conglomerate. Our U-Pb zircon dating of the Shamrock tuff by SHRIMP-RG yields a peak probability age of 18.7 ± 0.1 Ma. Distinctive outcrop characteristics, mineralogy, remanent magnetization, and zircon geochemistry (Th/U) suggest that the Shamrock tuff represents a lacustrine facies of the regionally extensive Peach Spring Tuff (PST). Here we compare zircon age and geochemical analyses from the Shamrock tuff with those of the PST at Stoddard Wash and provide new insight into the age of zircon crystallization in the PST rhyolite. Results of our field studies show that Miocene strata at Harvard Hill mostly accumulated in a lacustrine environment, although depositional environments varied from a relatively deep lake to a very shallow lake or even onshore setting. Rock-avalanche breccias and alluvial deposits near the base of the exposed section indicate proximity to a steep basin margin and detrital studies suggest a southern source for coarse-grained deposits; therefore, we may infer a southern basin-margin setting at Harvard Hill during the early Miocene. Our geochronology demonstrates that deposition of the Barstow Formation at Harvard Hill extended from before ~19.1 Ma until well after ~18.7 Ma, similar to timing of Barstow Formation lake deposition in the Calico Mountains but at least 3 million years older than comparable lacustrine facies in the Mud Hills type section. These observations are consistent with either of two paleogeographic models: westward transgression of lacustrine environments within a single large basin, or sequential development of geographically distinct eastern and western sub-basins.

California

The source of hydrothermal solutions at Puerto Maunabo and its bearing on the base-metal-potassium feldspar association in Puerto Rico

A quartz oligoclase porphyry exposed near Puerto Maunabo may provide evidence to further our understanding of the base-metal-potassium feldspar association known to occur in many of the porphyry-type copper deposits of Puerto Rico. The porphyry appears to be a magmatic differentiate on the border of the San Lorenzo batholith that may represent a source of mineralizing hydrothermal solutions. The porphyry intrudes an albitized quartz diorite border phase of the batholith that contains large roof pendants of metavolcanic rock. These roof pendants are mostly metamorphosed to greenschist metamorphic facies, but in the vicinity of Puerto Maunabo south of the porphyry, they reach amphibolite metamorphic facies; north of the porphyry, similar xenolithic lenses of metavolcanic rock appear to have been converted entirely to an oligoclase quartz felsite. The layered albitized quartz felsite has the same composition and texture as irregular veinlets in the albitized quartz diorite and as the groundmass in the porphyry. The K + ions arid basic ions of Fe +2 , Cu +2 , Mg +2 apparently were mobilized during final magmatic crystallization and then escaped as hydrothermal solutions that followed open conduits within a zone of structural weakness which also permitted the emplacement of the porphyry. The volcanic rock of Cerro Piedra Hueca, in contact with the albitized quartz diorite, and generally along strike west of the porphyry, has been altered to a quartz sericite rock entirely devoid of mafic silicates. This is the southeasternmost exposure of hydrothermally altered volcanic rock in the regional zone of northwest-trending faults that contains the principal porphyry-type copper deposits of Puerto Rico. The texture, mineralogy, and geologic environment of the porphyry at Puerto Maunabo are similar to those of the ore-bearing porphyries but differ in one important aspect. Most ore-bearing porphyries contain hydrothermal potassium feldspar and reddish-brown biotite intimately associated with the base-metal sulfides. In the porphyry of Puerto Maunabo, potassium feldspar is conspicuously absent, and only a trace of biotite is present; the only sulfide present is pyrite. The physical and chemical environment required to precipitate K + ions, either as potassium feldspar or biotite, apparently is very similar to that required to precipitate base-metal sulfides. At Puerto Maunabo, these conditions evidently did not prevail, and potassium and the base metals may have been carried in solution to a more favorable environment.

Puerto Maunabo

Water quality and chemical evolution of ground water within the north coast limestone aquifers of Puerto Rico

Waters within the north coastal limestone aquifers are suitable for public supply, industrial and agricultural uses. For the artesian aquifer and the updip parts of the water table aquifer, calcium and bicarbonate are the dominant ionic species with total dissolved solids and chloride concentrations below 500 and 250 mg/L, respectively. In coastal areas of the water table aquifer, where a freshwater-saltwater mixing zone occurs, the calcium bicarbonate facie grade to a sodium-chloride facie. Within this zone, concentrations of total dissolved solids and chloride are greater than 250 and 500 mg/L respectively, affecting the suitability of the water for some uses. Geochemical models were constructed to determine the physical and chemical reasons for the prevailing water quality patterns of the north coast limestone aquifers . Models indicate that calcite and carbon dioxide dissolution, precipitation or degassing are the primary processes. The mixing of recharge water or saltwater with aquifer waters is an important feature within the water table aquifer. The models provide further evidence that support the circulation of groundwater within the north coast limestone.

Conference Paper

Palynostratigraphic correlation of the Fort Union formation (Paleocene) in the Wind River Reservation and Waltman Area, Wind River Basin, Wyoming

Palynologic samples of the Fort Union Formation (Paleocene) were collected from selected composite measured sections and a drill hole in the Wind River Basin. Intervals studied are in outcrop in the Wind River Reservation in the Shotgun Butte area and near Hudson, Wyoming, and in the subsurface in the Muddy Ridge field. Age determinations were made using the palynostratigraphic zonation originally developed near Waltman, Wyoming, in the northeastern part of the basin. Although parts of the zonation have been called into question by other recent work in the basin, only the basal Paleocene biozone (P1) is in need of modification, and the zonation remains an effective tool for age determination and correlation in these rocks. Age control is sparse in parts of some sections studied, mostly because of a dominance of sandstone and conglomerate facies, but palynostratigraphy permits correlation of the study areas with each other and with the Waltman reference section. Palynology supports the following correlations: The lower unnamed member of the Fort Union Formation in the Shotgun Butte area correlates stratigraphically and chronologically with the lower part of the formation in the subsurface at Muddy Ridge field, with a short interval in the Hudson area, and with the lower and middle parts of the unnamed member in the Waltman area. The Shotgun Member correlates chronologically with the coal-bearing upper part of the Fort Union Formation in the subsurface at Muddy Ridge field and with the upper part of the unnamed member and Waltman Shale Member in the Waltman area. These correlations show that significant coal deposits in the subsurface have little or no expression in outcrop because of changes in facies.

Conference Paper

Lateral trends and vertical sequences in estuarine sediments, Willapa Bay, Washington

Willapa Bay is a sizable estuary on the southern coast of Washington- Relatively unmodified in a geologic sense by human activity the bay provides an excellent example of modern depositional facies in an estuarine setting. Studies of these deposits indicate that consistent lateral trends exist in sediment texture and sedimentary structures. The texture changes from sandy at the mouth of the bay to muddy in its upper parts. In any part of the bay , sediment is coarsest in the channel bottoms, where lag deposits accumulate. The sediment tends to fine in an upslope direction and is finest in supratidal flat deposits of silt and clay. The nature of sedimentary structures depends on the combination of physical and biological processes and sediment textures. Bedforms exist wherever the bed is sandy. In the main tidal channels sandwaves and dunes up to 4 meters high occur. In tributary channels and at the margins of the main channel, at shallower depths and under less intense currents , the structures are generally less than a meter high. Current ripples occur in t he sandy bed of all of the tidal channels and in runoff channels cross the tidal flat. Symmetric long-crested ripples are produced by wave action over the sandy intertidal flat. Internal structures in the bay's sediment depend not only on the nature of the bedform but also on the rate of bioturbation relative to physical processes. Under fields of large sandwaves or dunes, medium- to large-scale tabular and trough crossbedding predominates. This crossbedding generally is unidirectional, reflecting the locally dominant current (ebb or flood). Ripple bedding predominates elsewhere in sandy sediment within the channels. Where sand transport is diminished, as on the floor of the upper tributary channels, bioturbation exceeds the rate of production of physical structures and bedding is destroyed. The depositional banks in such areas tend to be sites of rapid sediment accumulation and bedding in the form of interlayered sand (commonly ripple bedded) and mud persists. On intertidal flats the sediment accumulates slowly and bioturbation erases nearly all physical structures. Bedding is preserved only where deposition is locally rapid , as in topographic depressions or on the depositional banks of runoff channels, or where faunal activity is inhibited, as beneath mounds of blue-green algae. The rate of sedimentation is slower still on the supratidal flats, but the general paucity of faunal activity allows the preservation of thin alternations of fine sand , silt or clay. The lateral migration of the tidal channels produces vertical sequences in which topographically higher facies are superposed on one another. Near the mouth of the estuary the upward sequence: lag deposit — crossbedded sand — ripple or planar-bedded sand is typical. The crossbedding shows a general upward decrease in thickness and a progression from trough to tabular units. In the main tidal channel - in the central estuary and in sandy tributary channels, the typical vertical sequence resembles that near the mouth , with the exception that the sequence is capped by bioturbated sandy or muddy tide flat deposits. In the upper estuary , where muddy sediment predominates, a typical sequence shows the progression-. bioturbated lag deposit — gently dipping interlaminated sand and mud layers of the accretionary bank — bioturbated mud flat deposits — thinly laminated fine supratidal deposits.

Oregon, Washington