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USGS1999

Hydrology and geochemistry of carbonate springs in Mantua Valley, northern Utah

Water chemistry, tritium data, precipitation-discharge relations, geology, topography, and dye tracing were used to determine recharge areas, ground-water residence times, factors influencing ground-water flow, and aquifer characteristic for five springs that discharge from Paleozoic limestones and dolostones along the margin of Manuta Valley, northern Utah. Temperature of Mantua Valley spring water ranged between 6.0 and 15.0 degrees Celsius. Spring-water temperature indicates that depth of circulation of ground water could be as shallow as 80 feet (25 meters) to as much as 1,150 feet (350 meters). Dissolved-solids concentration in the water from springs ranged from 176 to 268 milligrams per liter. Average total hardness of spring water ranged from 157 to 211 milligrams per liter. Water from all of the springs is a calcium-magnesium-bicarbonate type that generally is undersaturated with respect to calcite and dolomite. The molar calcium/magnesium ratio in spring water ranged from 1.21 to 1.88, and indicates that ground water flows through impure dolostone or a mixed limestone and dolostone terrace. Discharge from carbonate springs in Mantua Valley ranges from about to 10 to 4,300 gallons per minute (0.6 to 271 liters per second). Seasonal variations in chemical parameters and discharge indicate that the aquifers supplying water to most of these springs are predominantly diffuse-flow systems that have been locally enhanced by bedrock dissolution. Estimated recharge area for th springs ranges from 2.7 to 7 square miles (7 to 18 square kilometers). On the basis of tritium age dating, the mean residence time of ground water discharges from Olsens-West Hallins and Maple Springs was determined to be from 3 to 9, and from 4 to 15 years, respectively. Dye tracing from point sources 2.65 miles (4.26 kilometers) southeast of Maple Spring, however, indicates a substantially faster component of flow during snowmelt runoff, with a travel time of about 5 days, or an average ground-water velocity of about 2,700 feet per day (823 meters per day).

Utah↗

USGS1997

Toxicity of alkalinity to Hyalella azteca

Toxicity testing and chemical analyses of sediment pore water have been suggested for use in sediment quality assessments and sediment toxicity identification evaluations. However, caution should be exercised in interpreting pore-water chemistry and toxicity due to inherent chemical characteristics and confounding relationships. High concentrations of alkalinity, which are typical of sediment pore waters from many regions, have been shown to be toxic to test animals. A series of tests were conducted to assess the significance of elevated alkalinity concentrations to Hyalella azteca, an amphipod commonly used for sediment and pore-water toxicity testing. Toxicity tests with 14-d old and 7-d old animals were conducted in serial dilutions of sodium bicarbonate (NaHCO3) solutions producing alkalinities ranging between 250 to 2000 mg/L as CaCO3. A sodium chloride (NaCl) toxicity test was also conducted to verify that toxicity was due to bicarbonate and not sodium. Alkalinity was toxic at concentrations frequently encountered in sediment pore water. There was also a significant difference in the toxicity of alkalinity between 14-d old and 7-d old animals. The average 96-h LC50 for alkalinity was 1212 mg/L (as CaCO3) for 14-d old animals and 662 mg/L for the younger animals. Sodium was not toxic at levels present in the NaHCO3 toxicity tests. Alkalinity should be routinely measured in pore-water toxicity tests, and interpretation of toxicity should consider alkalinity concentration and test-organism tolerance.

Bulletin of Environmental Contamination and Toxico↗

USGS2009

Evaluating the spatial variation of total mercury in young-of-year yellow perch (Perca flavescens), surface water and upland soil for watershed-lake systems within the southern Boreal Shield

The primary objective of this research is to investigate relationships between mercury in upland soil, lake water and fish tissue and explore the cause for the observed spatial variation of THg in age one yellow perch ( Perca flavescens ) for ten lakes within the Superior National Forest. Spatial relationships between yellow perch THg tissue concentration and a total of 45 watershed and water chemistry parameters were evaluated for two separate years: 2005 and 2006. Results show agreement with other studies where watershed area, lake water pH, nutrient levels (specifically dissolved NO 3 − -N) and dissolved iron are important factors controlling and/or predicting fish THg level. Exceeding all was the strong dependence of yellow perch THg level on soil A-horizon THg and, in particular, soil O-horizon THg concentrations (Spearman ρ = 0.81). Soil B-horizon THg concentration was significantly correlated (Pearson r = 0.75) with lake water THg concentration. Lakes surrounded by a greater percentage of shrub wetlands (peatlands) had higher fish tissue THg levels, thus it is highly possible that these wetlands are main locations for mercury methylation. Stepwise regression was used to develop empirical models for the purpose of predicting the spatial variation in yellow perch THg over the studied region. The 2005 regression model demonstrates it is possible to obtain good prediction (up to 60% variance description) of resident yellow perch THg level using upland soil O-horizon THg as the only independent variable. The 2006 model shows even greater prediction ( r 2 = 0.73, with an overall 10 ng/g [tissue, wet weight] margin of error), using lake water dissolved iron and watershed area as the only model independent variables. The developed regression models in this study can help with interpreting THg concentrations in low trophic level fish species for untested lakes of the greater Superior National Forest and surrounding Boreal ecosystem.

Science of the Total Environment↗

USGS2020

Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore

Widespread application of neonicotinoids has led to their proliferation in waters. Despite low neonicotinoid hydrophobicity, our prior studies implicated granular activated carbon (GAC) in neonicotinoid removal. Based on known receptor binding characteristics, we hypothesized that the insecticidal pharmacophore influences neonicotinoid sorption. Our objectives were to illuminate drivers of neonicotinoid sorption for parent neonicotinoids (imidacloprid, clothianidin, thiamethoxam, and thiacloprid) and pharmacophore-altered metabolites (desnitro-imidacloprid and imidacloprid urea) to GAC, powdered activated carbon, and carbon nanotubes (CNTs). Neonicotinoid sorption to GAC was extensive and largely irreversible, with significantly greater sorption of imidacloprid than desnitro-imidacloprid. Imidacloprid and imidacloprid urea (electronegative pharmacophores) sorbed most extensively to nonfunctionalized CNTs, whereas desnitro-imidacloprid (positive pharmacophore) sorbed most to COOH-CNTs, indicating the importance of charge interactions and/or hydrogen bonding between the pharmacophore and carbon surface. Water chemistry parameters (temperature, alkalinity, ionic strength, and humic acid) inhibited overall neonicotinoid sorption, suggesting that pharmacophore-driven sorption in real waters may be diminished. Analysis of a full-scale drinking water treatment plant GAC filter influent, effluent, and spent GAC attributes neonicotinoid/metabolite removal to GAC under real-world conditions for the first time. Our results demonstrate that the neonicotinoid pharmacophore not only confers insecticide selectivity but also impacts sorption behavior, leading to less effective removal of metabolites by GAC filters in water treatment.

Environmental Science and Technology↗

USGS2007

Cautions and suggestions for geochemical sampling in fractured rock

Collecting water samples for geochemical analyses in open bedrock boreholes or in discrete intervals of boreholes intersected by multiple fractures is likely to yield ambiguous results for ground water chemistry because of the variability in the transmissivity, storativity, and hydraulic head of fractures intersecting the borehole. Interpreting chemical analyses of water samples collected in bedrock boreholes requires an understanding of the hydraulic conditions in the borehole under the ambient flow regime in the aquifer as well as during sampling. Pumping in open boreholes, regardless of the pumping rate and the location of the pump intake, first draws water from the borehole and then from fractures intersecting the borehole. The time at which the volumetric rate of water entering the borehole from fractures is approximately equal to the pumping rate can be identified by monitoring the logarithm of drawdown in the borehole as a function of the logarithm of time. Mixing of water entering the borehole from fractures with water in the borehole must be considered in estimating the time at which the pump discharge is representative of aquifer water. In boreholes intersected by multiple fractures, after the contribution from the borehole volume has diminished, the contribution of fractures to the pump discharge will be weighted according to their transmissivity, regardless of the location of the pump intake. This results in a flux‐averaged concentration in the pump discharge that is biased by the chemical signature of those fractures with the highest transmissivity. Under conditions where the hydraulic head of fractures varies over the length of the borehole, open boreholes will be subject to ambient flow in the water column in the borehole. In some instances, the magnitude of the ambient flow may be similar to the designated pumping rate for collecting water samples for geochemical analyses. Under such conditions, the contributions to the pump discharge from individual fractures will be a function not only of the transmissivity of the fractures, but also of the distribution of hydraulic head in fractures intersecting the borehole. To reduce or eliminate the deleterious effects of conducting geochemical sampling in open boreholes, a straddle‐packer apparatus that isolates a single fracture or a series of closely spaced fractures is recommended. It is also recommended that open boreholes be permanently outfitted with borehole packers or borehole liners in instances where maintaining the hydraulic and chemical stratification in the aquifer is of importance. In a field example, a comparison of results from sampling in an open borehole and in discrete intervals of the same borehole showed dramatic differences in the concentrations of chemical constituents in the water samples, even though chemical field parameters stabilized prior to both open borehole and discrete interval sampling.

Groundwater Monitoring & Remediation↗

USGS2016

Groundwater-quality data in the Monterey–Salinas shallow aquifer study unit, 2013: Results from the California GAMA Program

Groundwater quality in the 3,016-square-mile Monterey–Salinas Shallow Aquifer study unit was investigated by the U.S. Geological Survey (USGS) from October 2012 to May 2013 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project. The GAMA Monterey–Salinas Shallow Aquifer study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the shallow-aquifer systems in parts of Monterey and San Luis Obispo Counties and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The shallow-aquifer system in the Monterey–Salinas Shallow Aquifer study unit was defined as those parts of the aquifer system shallower than the perforated depth intervals of public-supply wells, which generally corresponds to the part of the aquifer system used by domestic wells. Groundwater quality in the shallow aquifers can differ from the quality in the deeper water-bearing zones; shallow groundwater can be more vulnerable to surficial contamination. Samples were collected from 170 sites that were selected by using a spatially distributed, randomized grid-based method. The study unit was divided into 4 study areas, each study area was divided into grid cells, and 1 well was sampled in each of the 100 grid cells (grid wells). The grid wells were domestic wells or wells with screen depths similar to those in nearby domestic wells. A greater spatial density of data was achieved in 2 of the study areas by dividing grid cells in those study areas into subcells, and in 70 subcells, samples were collected from exterior faucets at sites where there were domestic wells or wells with screen depths similar to those in nearby domestic wells (shallow-well tap sites). Field water-quality indicators (dissolved oxygen, water temperature, pH, and specific conductance) were measured, and samples for analysis of inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids, and alkalinity) were collected at all 170 sites. In addition to these constituents, the samples from grid wells were analyzed for organic constituents (volatile organic compounds, pesticides and pesticide degradates), constituents of special interest (perchlorate and N -nitrosodimethylamine, or NDMA), radioactive constituents (radon-222 and gross-alpha and gross-beta radioactivity), and geochemical and age-dating tracers (stable isotopes of carbon in dissolved inorganic carbon, carbon-14 abundances, stable isotopes of hydrogen and oxygen in water, and tritium activities). Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 11 percent of the wells in the Monterey–Salinas Shallow Aquifer study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. With the exception of trace elements, blanks rarely contained detectable concentrations of any constituent, indicating that contamination from sample-collection procedures was not a significant source of bias in the data for the groundwater samples. Low concentrations of some trace elements were detected in blanks; therefore, the data were re-censored at higher reporting levels. Replicate samples generally were within the limits of acceptable analytical reproducibility. The median values of matrix-spike recoveries were within the acceptable range (70 to 130 percent) for the volatile organic compounds (VOCs) and N -nitrosodimethylamine (NDMA), but were only approximately 64 percent for pesticides and pesticide degradates. The sample-collection protocols used in this study were designed to obtain representative samples of groundwater. The quality of groundwater can differ from the quality of drinking water because water chemistry can change as a result of contact with plumbing systems or the atmosphere; because of treatment, disinfection, or blending with water from other sources; or some combination of these. Water quality in domestic wells is not regulated in California, however, to provide context for the water-quality data presented in this report, results were compared to benchmarks established for drinking-water quality. The primary comparison benchmarks were maximum contaminant levels established by the U.S. Environmental Protection Agency and the State of California (MCL-US and MCL-CA, respectively). Non-regulatory benchmarks were used for constituents without maximum contaminant levels (MCLs), including Health Based Screening Levels (HBSLs) developed by the USGS and State of California secondary maximum contaminant levels (SMCL-CA) and notification levels. Most constituents detected in samples from the Monterey–Salinas Shallow Aquifer study unit had concentrations less than their respective benchmarks. Of the 148 organic constituents analyzed in the 100 grid-well samples, 38 were detected, and all concentrations were less than the benchmarks. Volatile organic compounds were detected in 26 of the grid wells, and pesticides and pesticide degradates were detected in 28 grid wells. The special-interest constituent NDMA was detected above the HBSL in three samples, one of which also had a perchlorate concentration greater than the MCL-CA. Of the inorganic constituents, 6 were detected at concentrations above their respective MCL benchmarks in grid-well samples: arsenic (5 grid wells above the MCL of 10 micrograms per liter, μg/L), selenium (3 grid wells, MCL of 50 μg/L), uranium (4 grid wells, MCL of 30 μg/L), nitrate (16 grid wells, MCL of 10 milligrams per liter, mg/L), adjusted gross alpha particle activity (10 grid wells, MCL of 15 picocuries per liter, pCi/L), and gross beta particle activity (1 grid well, MCL of 50 pCi/L). An additional 4 inorganic constituents were detected at concentrations above their respective HBSL benchmarks in grid-well samples: boron (1 grid well above the HBSL of 6,000 μg/L), manganese (8 grid wells, HBSL of 300 μg/L), molybdenum (6 grid wells, HBSL of 40 μg/L), and strontium (6 grid wells, HBSL of 4,000 μg/L). Of the inorganic constituents, 4 were detected at concentrations above their non-health based SMCL benchmarks in grid-well samples: iron (9 grid wells above the SMCL of 300 μg/L), chloride (7 grid wells, SMCL of 500 mg/L), sulfate (14 grid wells, SMCL of 500 mg/L), and total dissolved solids (27 grid wells, SMCL of 1,000 mg/L). Of the inorganic constituents analyzed in the 70 shallow-well tap sites, 10 were detected at concentrations above the benchmarks. Of the inorganic constituents, 3 were detected at concentrations above their respective MCL benchmarks in shallow-well tap sites: arsenic (2 shallow-well tap sites above the MCL of 10 μg/L), uranium (2 shallow-well tap sites, MCL of 30 μg/L), and nitrate (24 shallow-well tap sites, MCL of 10 mg/L). An additional 3 inorganic constituents were detected above their respective HBSL benchmarks in shallow-well tap sites: manganese (4 shallow-well tap sites above the HBSL of 300 μg/L), molybdenum (4 shallow-well tap sites, HBSL of 40 μg/L), and zinc (2 shallow-well tap sites, HBSL of 2,000 μg/L). Of the inorganic constituents, 4 were detected at concentrations above their non-health based SMCL benchmarks in shallow-well tap sites: iron (6 shallow-well tap sites above the SMCL of 300 μg/L), chloride (1 shallow-well tap site, SMCL of 500 mg/L), sulfate (9 shallow-well tap sites, SMCL of 500 mg/L), and total dissolved solids (15 shallow-well tap sites, SMCL of 1,000 mg/L).

California↗

USGS1984

Flow characteristics of the Snake River and water budget for the Snake River plain, Idaho and eastern Oregon

This report is one in a series resulting from the U.S. Geological Survey's Snake River Plain Rasa (Regional Aquifer System Analysis) study that was initiation in October 1979. Purposes of the RASA study were to (1) refine knowledge of the regional ground-water flow system, (2) determine effects of conjunctive use of ground water and surface water, and (3) describe water chemistry. This purpose of this report is to describe flow characteristics of the Snake River and tributaries and to develop a water budget for the Snake River Plain. Data and interpretation in this report will be used in development of ground-water flow models.

Idaho, Oregon↗

USGS2022

Surface-water-quality data to support implementation of revised freshwater aluminum water-quality criteria in Massachusetts, 2018–19

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed a study to inform the development of the department’s guidelines for the collection and use of water-chemistry data to support calculation of site-dependent aluminum criteria values. The U.S. Geological Survey collected and analyzed discrete water-quality samples at four wastewater-treatment facilities and seven water-treatment facilities in eastern and central Massachusetts from April 2018 through May 2019. For each of the 11 facilities considered, water-quality samples were collected from treatment-plant effluent and receiving-water bodies. Samples were collected for laboratory analysis of major ions (calcium and magnesium ions are used to calculate total hardness), dissolved organic carbon (DOC), total organic carbon (TOC), and total recoverable aluminum. Field parameters for pH, temperature, and specific conductance were measured in situ concurrently with sample collection. Water-quality conditions differed among monitoring stations. The highest pH values were observed for stations on the Assabet River that receive effluent discharges from wastewater-treatment facilities (the Westborough, Marlborough, Hudson, and Maynard wastewater-treatment facilities). High DOC concentrations (greater than 10 mg/L) were measured in water bodies associated with large areas of riparian wetlands—Lily Pond (Cohasset) and Third Herring Brook (Hanover), and low DOC concentrations (less than 2.5 mg/L) were measured at three water bodies in central Massachusetts—Hocomonco Pond (Westborough), Wyman Pond (Fitchburg), and Monoosnoc Brook (Leominster). Wyman Pond (Fitchburg), Monoosnoc Brook (Leominster), and Lily Pond (Cohasset) also had low pH values and low total hardness concentrations. The monthly discrete pH, DOC, and total hardness data for selected stations on receiving-water bodies were used in the U.S. Environmental Protection Agency Aluminum Criteria Calculator Version 2.0 to estimate site-dependent total recoverable aluminum concentrations that—if not exceeded—would be expected to protect fish, invertebrates, and other aquatic life from adverse effects associated with acute and chronic aluminum exposures. The U.S. Environmental Protection Agency Calculator output provides values for the acute criterion, defined as the criterion maximum concentration (CMC), an estimate of the highest aluminum concentration in surface water to which an aquatic community can be exposed briefly without resulting in an unacceptable effect. This output also provides values for the chronic criterion, defined as the criterion continuous concentration (CCC), an estimate of the highest concentration of aluminum in surface water to which an aquatic community can be exposed indefinitely without resulting in an unacceptable effect. To determine aluminum criteria values typically evaluated for use as protective water-quality criteria, the monthly instantaneous CMC and CCC values were used to calculate the minimum, 5th percentile, and 10th percentile CMC and CCC values for selected monitoring stations. The monthly instantaneous aluminum CMC and CCC values generated using the EPA Calculator varied among stations. Aluminum CMC and CCC values were highest for four ambient (upstream) stations on the Assabet River associated with wastewater-treatment facilities (Westborough, Marlboro, Hudson, and Maynard). Aluminum CMC and CCC values were lower for stations associated with water-treatment facilities, and lowest for selected ambient stations on Lily Pond, Monoosnoc Brook, and Wyman Pond associated with water-treatment facilities in Cohasset, Leominster, and Fitchburg, respectively. For many stations, the highest CMC and CCC instantaneous aluminum criteria values generated using the U.S. Environmental Protection Agency Calculator were for months during the growing season for algae and aquatic macrophytes (April or May through September or October) and the lowest values were for months during the nongrowing season (October or November through March or April), indicating the importance of collecting water-quality data during the nongrowing season. Aluminum CMC and CCC values generated by the U.S. Environmental Protection Agency Calculator are sensitive to variations in the input parameters (pH, DOC, and total hardness). Aluminum solubility is particularly affected by pH. To characterize diel and seasonal variations in pH, multiparameter water-quality monitors recording continuous (15-minute interval) water temperature and pH were installed in the receiving-water body for one station near each facility upstream from the effluent discharge (in rivers) or at a station outside the immediate effect of effluent discharge (in ponds). Continuous water temperature and pH data were collected from April or May 2018 through November or December 2018. Continuous pH data indicated that the pond stations and Assabet River stations had large diel variations in pH during the growing season. Continuous pH data were used together with discrete DOC and total hardness data to evaluate the potential effect of diel variations in pH on calculated site-dependent aluminum criteria values. For the 11 stations, diel variations in pH were determined to correspond to differences in the 10th percentile of CMC values by a median of 160 μg/L, ranging from 0 to 610 μg/L, and differences in the 10th percentile of CCC values by a median of 40 μg/L, ranging from 15 to 210 μg/L. The low monthly instantaneous CMC and CCC values that have the greatest effect on the minimum, 5th percentile, and 10th percentile aluminum values tend to result during the nongrowing season (October or November through March or April) when the range of diel variations in pH is small, thus minimizing the effect of diel variations in pH on the lowest CMC and CCC values. Historical water-quality data on organic carbon in Massachusetts streams were investigated using data retrieved from the USGS National Water Information System database. An assessment of the availability of historical pH, DOC, and hardness data indicated that more data were available for TOC than for DOC. A linear regression equation was developed for the relation between DOC and TOC concentrations to inform the potential use of available data to evaluate water-quality conditions at additional sites across Massachusetts where only pH, hardness, and TOC data are available. DOC and TOC concentrations were well correlated in the 223 samples in which both constituents were analyzed, and the equation had a coefficient of determination ( R 2 ) equal to 0.93.

Massachusetts↗

USGS2013

U.S. Geological Survey science for the Wyoming Landscape Conservation Initiative: 2011 annual report

This is the fourth report produced by the U.S. Geological Survey (USGS) for the Wyoming Landscape Conservation Initiative (WLCI) to detail annual work activities. In FY2011, there were 37 ongoing, completed, or new projects conducted under the five major multi-disciplinary science and technical-assistance activities: (1) Baseline Synthesis, (2) Targeted Monitoring and Research, (3) Data and Information Management, (4) Integration and Coordination, and (5) Decisionmaking and Evaluation. The four new work activities were (1) development of the Western Energy Citation Clearinghouse, a Web-based energy-resource database of references for literature and on-line resources focused on energy development and its effects on natural resources; (2) a study to support the Sublette County Conservation District in ascertaining potential water-quality impacts to the New Fork River from energy development in the Pinedale Anticline Project Area; (3) a study to test the efficacy of blending high-frequency temporal data provided by Moderate Resolution Imaging Spectroradiometer (MODIS) sensors and high-resolution Landsat data for providing the fine-resolution data required to evaluate habitat responses to management activities at the landscape level; and (4) a study to examine the seasonal water chemistry of Muddy Creek, including documenting salinity patterns and providing a baseline for assessing potential effects of energy and other development on water quality in the Muddy Creek watershed. Two work activities were completed in FY2011: (1) the assessment of rancher perceptions of energy development in Southwest Wyoming and (2) mapping aspen stands and conifer encroachment using classification and regression tree (CART) analysis for effectiveness monitoring. The USGS continued to compile data, develop geospatial products, and upgrade Web-based products in support of both individual and overall WLCI efforts, including (1) ranking and prioritizing proposed conservation projects, (2) developing the WLCI integrated assessment, (3) developing the WLCI 5-year Conservation Action Plan, and (4) continuing to upgrade the content and improve the functionality of the WLCI Web site. For the WLCI FY2012 annual report, a decision was made to greatly reduce the overall length of the annual report, which will be accomplished by simplifying the report format and focusing on the take-home messages of each work activity for WLCI partners.

Wyoming↗

USGS2017

Challenges in recovering resources from acid mine drainage

Metal recovery from mine waters and effluents is not a new approach but one that has occurred largely opportunistically over the last four millennia. Due to the need for low-cost resources and increasingly stringent environmental conditions, mine waters are being considered in a fresh light with a designed, deliberate approach to resource recovery often as part of a larger water treatment evaluation. Mine water chemistry is highly dependent on many factors including geology, ore deposit composition and mineralogy, mining methods, climate, site hydrology, and others. Mine waters are typically Ca-Mg-SO4±Al±Fe with a broad range in pH and metal content. The main issue in recovering components of these waters having potential economic value, such as base metals or rare earth elements, is the separation of these from more reactive metals such as Fe and Al. Broad categories of methods for separating and extracting substances from acidic mine drainage are chemical and biological. Chemical methods include solution, physicochemical, and electrochemical technologies. Advances in membrane techniques such as reverse osmosis have been substantial and the technique is both physical and chemical. Biological methods may be further divided into microbiological and macrobiological, but only the former is considered here as a recovery method, as the latter is typically used as a passive form of water treatment.

Conference Paper↗

USGS2007

Geothermometer calculations for geothermal assessment

Geothermal exploration programs have relied on the calculation of geothermometers from hot spring chemistry as an early estimation of geothermal reservoir temperatures. Calibration of the geothermometers has evolved from experimental determinations of mineral solubility as a function of temperature to calibration from analyses of water chemistry from known depths and temperatures in thermal wells. Most of the geothermometers were calibrated from analyses of sodium-chloride type waters, and the application of some geothermometers should be restricted to waters of the chemical types that were used in their calibration. Chemical analyses must be determined to be reliable before they are used to calculate geothermometers. The USGS Geothermal Resource Assessment will rely on the silica geothermometer developed by Giggenbach that approximates the transition between chalcedony at 20??C and quartz at 200??C. Above 200??C, the assessment will rely on the quartz geothermometer. In addition, the assessment will also rely on the potassium-magnesium geothermometer.

Conference Paper↗

USGS2003

New studies initiated by the U.S. Geological Survey - Effects of nutrient enrichment on stream ecosystems

In 2001, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program began an intensive study of nutrient enrichment elevated concentrations of nitrogen and phosphorus in streams in five agricultural basins across the Nation (see map, p. 2). This study is providing nationally consistent and comparable data and analyses of nutrient conditions, including how these conditions vary as a result of natural and human-related factors, and how nutrient conditions affect algae and other biological communities. This information will benefit stakeholders, including the U.S. Environmental Protection Agency (USEPA) and its partners, who are developing nutrient criteria to protect the aquatic health of streams in different geographic regions. Nutrient enrichment is one of five national priority topics addressed by NAWQA in its second decade of studies, which began in 2001. During its first round of assessments in 51 major river basins (referred to as “Study Units”), NAWQA scientists collected data on water chemistry, stream hydrology and habitat, and biological communities; currently, NAWQA is revisiting selected basins and focusing on (1) trends, (2) factors that affect water quality and aquatic health, and (3) national priority water issues related to, for example, the development of nutrient criteria, source-water protection strategies, and stream restoration plans. The nutrient enrichment study has four major objectives that address nutrient conditions, dissolved oxygen, aquatic communities, and geographic and landscape features in agricultural basins (see inset). The focus on agricultural streams is a starting point. As the study progresses, streams draining other land uses, such as those in residential and urban areas, will likely be added.

Fact Sheet↗

USGS2000

Effects of wastewater-lagoon discharge through wetlands on water quality in Bonifas Creek, Gogebic County, Michigan

The Lac Vieux Desert Band of the Superior Chippewa (LVD) recently constructed a wastewater-treatment facility that discharges effluent twice annually from settling lagoons to wooded wetland areas adjoining the channel of Bonifas Creek, a small stream that flows near the LVD community in Watersmeet, Michigan. This report describes the hydrology of the site and the results of analyses of water samples from Bonifas Creek and the settling lagoons. Water samples were collected from sites on the creek upstream and downstream of the effluent-receiving area, before and after discharge from the lagoons. The concentrations of calcium, magnesium, and bicarbonate increased from the upstream to the downstream site, but the concentrations of sodium, chloride, and sulfate decreased. These changes in water chemistry, however, were similar both before and after the release from the lagoons, and are consistent with known pattern of influxes of ground water into Bonifas Creek. Therefore, it appears that the discharge of wastewater into the area adjoining Bonifas Creek is unlikely to have any immediate effect on the quality of water in the creek.

Michigan↗

USGS1999

Water quality and habitat conditions in upper Midwest streams relative to riparian vegetation and soil characteristics, August 1997 : study design, methods, and data

Water-chemistry, biological, and habitat data were collected from 70 sites on Midwestern streams during August 1997 as part of an integrated, regional water-quality assessment by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. The study area includes the Corn Belt region of southern Minnesota, eastern Iowa, and west-central Illinois, one of the most intensive and productive agricultural regions of the world. The focus of the study was to evaluate the condition of woodedriparian zones and the influence of basin soildrainage characteristics on water quality and biological-community responses. This report includes a description of the study design and site-characterization process, sample-collection and processing methods, laboratory methods, quality-assurance procedures, and summaries of data on nutrients, herbicides and metabolites, stream productivity and respiration, biological communities, habitat conditions, and agriculturalchemical and land-use information.

Open-File Report↗

USGS2018

Temporal trends in water-quality constituent concentrations and annual loads of chemical constituents in Michigan watersheds, 1998–2013

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began the Water Chemistry Monitoring Program for select streams in the State of Michigan. Objectives of this program were to provide assistance with (1) statewide water-quality assessments, (2) the National Pollutant Discharge Elimination System permitting process, and (3) water-resource management decisions. As part of this program, water-quality data collected from 1998 to 2013 were analyzed to identify potential trends for select constituents that were sampled. Sixteen water-quality constituents were analyzed at 32 stations throughout Michigan. Trend analysis on the various water-quality data was done using either the uncensored Seasonal Kendall test or through Tobit regression. In total, 79 trends were detected in the constituents analyzed for 32 river stations sampled for the study period—53 downward trends and 26 upward trends were detected. The most prevalent trend detected throughout the State was for ammonia, with 11 downward trends and 1 upward trend estimated. In addition to trends, constituent loads were estimated for 31 stations from 2002 to 2013 for stations that were sampled 12 times per year. Loads were computed using the Autobeale load computation program, which used the Beale ratio estimator approach to estimate an annual load. Constituent loads were the largest in large watershed streams with the highest annual flows such as the Saginaw and Grand Rivers. Likewise, constituent loads were the smallest in smaller tributaries that were sampled as part of this program such as the Boardman and Thunder Bay Rivers.

Michigan↗

USGS2025

Geochemistry and Soils of the Big Smoky Valley Fens, Nevada

Fens are groundwater-fed wetlands that can provide habitat for plants and animals. Due to anthropogenic activities and climate change, many fens around the world are at risk. This paper presents the results of a study of the hydrology and geochemistry of fens in Big Smoky Valley, central Nevada to support the Bureau of Land Management’s activities in the area. A water sample from the largest fen in the study area was analyzed for its water chemistry and compared to a nearby alluvial aquifer and hot spring. The high SiO 2 concentration of the fen sample implies that the fen water may originate from geothermal water. A soil core was taken to analyze radiocarbon age and soil type. A majority of the core was composed of silt and clay interlayered with water-filled voids. Changes in the character of the clay with depth suggest that there may have been changes in the depositional environment over time. Radiocarbon dating of Ruppia seeds showed longevity of the fen, with the minimum 14 C age of the core as 4,375±40 years. This paper provides reconnaissance-level information on the Big Smoky Valley fens, but further information would be needed to better understand the source of water to the fens or how the fen environment has changed over time with climate.

Nevada↗

USGS1989

Effects of controlled agricultural practices on water quality in the Minnesota sand-plain aquifer

Recent studies of Minnesota's sand plains indicate that ground-water chemistry is related to agricultural practices. Surficial sand-plain aquifers cover 8,000,000 acres of Minnesota and are a major source of water for domestic use, irrigation, and some municipal systems. The sand-plain aquifers consist of sand and gravel deposits that are from 20 to greater than 100 feet thick and are covered by a thin sandy loam that generally is less than 2 feet thick. Sand-plain aquifers are recharged by the downward percolation of precipitation through the soil root zone and the unsaturated zone in the sand to the water table. The water table is the upper surface of the zone of saturation and forms the top of the sand-plain aquifer. Sand-plain aquifers are susceptible to contamination by agricultural chemicals (fertilizers and pesticides), if downward-percolating recharge water contains these chemicals. The concentrations of nitrate, pesticides, and some other chemical constituents fluctuate seasonally and differ with depth below the water table (Anderson, 1989). Despite the availability of water-quality data for about 260 wells that were collected during previous studies in three U.S. Geological Survey (USGS) project areas in Minnesota, it is not known how concentrations of agricultural chemicals in ground water relate to the rate and timing of fertilizer and pesticide application or to the tillage practices used. Field-scale research is needed to determine the effects of different farming practices on the concentrations of nitrate, pesticides, and other agricultural chemicals in ground water in the unsaturated and saturated zones.

Minnesota↗

USGS2001

Shallow ground-water quality beneath rice areas in the Sacramento Valley, California, 1997

In 1997, the U.S. Geological Survey installed and sampled 28 wells in rice areas in the Sacramento Valley as part of the National Water-Quality Assessment Program. The purpose of the study was to assess the shallow ground-water quality and to determine whether any effects on water quality could be related to human activities and particularly rice agriculture. The wells installed and sampled were between 8.8 and 15.2 meters deep, and water levels were between 0.4 and 8.0 meters below land surface. Ground-water samples were analyzed for 6 field measurements, 29 inorganic constituents, 6 nutrient constituents, dissolved organic carbon, 86 pesticides, tritium (hydrogen- 3), deuterium (hydrogen-2), and oxygen-18. At least one health-related state or federal drinking-water standard (maximum contaminant or long-term health advisory level) was exceeded in 25 percent of the wells for barium, boron, cadmium, molybdenum, or sulfate. At least one state or federal secondary maximum contaminant level was exceeded in 79 percent of the wells for chloride, iron, manganese, specific conductance, or dissolved solids. Nitrate and nitrite were detected at concentrations below state and federal 2000 drinking-water standards; three wells had nitrate concentrations greater than 3 milligrams per liter, a level that may indicate impact from human activities. Ground-water redox conditions were anoxic in 26 out of 28 wells sampled (93 percent). Eleven pesticides and one pesticide degradation product were detected in ground-water samples. Four of the detected pesticides are or have been used on rice crops in the Sacramento Valley (bentazon, carbofuran, molinate, and thiobencarb). Pesticides were detected in 89 percent of the wells sampled, and rice pesticides were detected in 82 percent of the wells sampled. The most frequently detected pesticide was the rice herbicide bentazon, detected in 20 out of 28 wells (71 percent); the other pesticides detected have been used for rice, agricultural, and non-agricultural purposes. All pesticide concentrations were below state and federal 2000 drinking-water standards. The relation of the ground-water quality to natural processes and human activities was tested using statistical methods (Spearman rank correlation, Kruskal?Wallis, or rank-sum tests) to determine whether an influence from rice land-use or other human activities on ground-water chemistry could be identified. The detection of pesticides in 89 percent of the wells sampled indicates that human activities have affected shallow ground-water quality. Concentrations of dissolved solids and inorganic constituents that exceeded state or federal 2000 drinking-water standards showed a statistical relation to geomorphic unit. This is interpreted as a relation to natural processes and variations in geology in the Sacramento River Basin; the high concentrations of dissolved solids and most inorganic constituents did not appear to be related to rice land use. No correlation was found between nitrate concentration and pesticide occurrence, indicating that an absence of high nitrate concentrations is not a predictor of an absence of pesticide contamination in areas with reducing ground-water conditions in the Sacramento Valley. Tritium concentrations, pesticide detections, stable isotope data, and dissolved-solids concentrations suggest that shallow ground water in the ricegrowing areas of the Sacramento Valley is a mix of recently recharged ground water containing pesticides, nitrate, and tritium, and unknown sources of water that contains high concentrations of dissolved solids and some inorganic constituents and is enriched in oxygen-18. Evaporation of applied irrigation water, which leaves behind salt, accounts for some of the elevated concentrations of dissolved solids. More work needs to be done to understand the connections between the land surface, shallow ground water, deep ground water, and the drinking-water supplies in the Sacramento Valley.

Water-Resources Investigations Report↗