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Discussion of “a comparison of several heat and mass transfer networks of interest in water conservation”

The use of electrical networks to describe heat‐ and mass‐transfer problems is an interesting concept and undoubtedly will be of considerable value in future water‐loss investigations, provided the processes involved can be represented, electrically, with sufficient accuracy. Although it is true that errors in measurement of water‐surface temperature may arise when there are steep gradients in the fluid, such a temperature profile will not be associated with high evaporation rates, as implied by Poppendiek and Tribus. High evaporation is associated with appreciable wind and a resultant stirring or mixing of the upper part of the fluid. Hence the possibility of making large errors in water‐surface temperature measurements during periods of high evaporation rates are minimized. The results of the first three months of operation at Lake Hefner, Oklahoma City, Okla. [Anderson, Anderson, and Marciano, 1950] indicate that any error in evaporation computed from either the mass‐transfer or the energy‐budget equations due to errors in the measurement of the water‐surface temperature are insignificant when total evaporation over a 24‐hour period is considered.

Eos, Transactions, American Geophysical Union

Reconnaissance of Volatile Synthetic Organic Chemicals at Public Water Supply Wells Throughout Puerto Rico, November 1984-May 1985

INTRODUCTION Ground water is the principal source of drinking water for about 850,000 people in Puerto Rico (National Water Summary, 1985). Ground-water withdrawals for public supply, agricultural, and industrial water uses in Puerto Rico are about 250 million gallons per day (Mgal/d) (Torres-Sierra and Aviles, 1985). The development of the most accessible surface water supplies will result in an increasing demand for ground water. Recent investigations conducted by the U. S. Geological Survey, WRD (USGS) have shown the presence of toxic synthetic organic chemicals in ground water throughout Puerto Rico (Gomez-Gomez and Guzman-Rios, 1982). Volatile synthetic organic chemicals (VOC's) have been detected in water from public water supply wells in concentrations ranging from 1 to 500 micrograms per liter (Guzman-Rios and Quinones-Marquez, 1984 and Guzman-Rios and Quinones-Marquez, 1985). As result of these findings, pumpage was discontinued at 6 wells operated by the Puerto Rico Aqueduct and Sewer Authority (PRASA), the Commonwealth of Puerto Rico agency responsible for public-water supply. Monitoring of 10 additional wells in the vicinity of those wells is being conducted by the USGS in cooperation with PRASA. In 1985, the USGS began a comprehensive islandwide study of VOC's in drinking water. The study was conducted in cooperation with the Puerto Rico Department of Health (PRDOH) and PRASA. Samples were collected from 243 public-water supply wells operated by PRASA (flgure 1). The authors wish to acknowledge the support, assistance and cooperation of the PRASA staff throughout Puerto Rico in the sample collection effort. The authors are especially grateful to Engineer Carlos Garcia-Troche from the PRASA main office in San Juan.

Open-File Report

Water resources data, South Carolina, water year 2001

Water resources data for the 2001 water year for South Carolina consist of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and ground-water levels. This report contains discharge records for 121 gaging stations; stage-only records for 44 gaging stations; stage and co ntents for 14 lakes and reservoirs; water quality for 47 gaging stations; and water levels for 43 observation wells. Als o included are data for 52 crest-stage partial-record stations and discharge measurements at 7 miscellaneous sites. Add itional water data were collected at various sites, not part of the systematic data collection program, and are publish ed as miscellaneous investigations of water quality. These data represent that part of the National Water Data System co llected by the U.S. Geological Survey and cooperating State and Federal agencies in South Carolina.

South Carolina

The solubility of quartz in water in the temperature interval from 25° to 300° C

The solubility of quartz in water was investigated by three sets of experiments at 1000 atm P H 2 O and temperatures ranging from 45° to 300°C at water pressures appropriate for the coexistence of three phases, gaseous water, liquid, and quartz, at temperatures ranging from 69° to 240°C a long term study of the dissolution of quartz grains which were continuously tumbled in water at room temperature. Saturated silica solutions in equilibrium with quartz were obtained in a few days at temperatures above 100°C. Equilibrium is shown by reproducible results for runs of different durations and by the precipitation of quartz from initially supersaturated solutions. The differential heat of solution derived from the data obtained at 1000 atm pressure is 5.38 kcal/mole. At room temperature and pressure, highly supersaturated silica solutions were obtained by continuously rotating quartz grains and water in plastic bottles at 75 rev/min. In one run the amount of silica in solution increased to a maximum value of 395 p.p.m. after 370 days. Another run reached 80 p.p.m. silica after 386 days and then dropped to 6 p.p.m. silica. It is concluded that quartz was precipitated at room temperature from this supersaturated solution and that 6 p.p.m. is essentially the true solubility of quartz at 25°C. In contrast to the runs rotated at 75 rev/min, quartz grains, and also silica glass grains, continuously rotated in water at rev/min, each contributed less than 1 p.p.m. colorimetric silica into solution after 1 year. Thus, vigorous agitation of the liquid is necessary to remove dissolved silica from the vicinity of surfaces of both quartz and glass. Two significant factors that may have contributed to the formation of supersaturated silica solutions in the runs rotated at 75 rev/min at room temperature are stresses and structural irregularities at the surfaces of the crushed quartz grains, which contributed silica into solution more readily than well crystallized quartz the very slow rate at which dissolved silica polymerizes to species appropriate to act as nuclei for quartz growth. At the termination of the runs rotated at 75 rev/min, spikelike projections were present on many of the quartz grains. These are interpreted as indicating that abrasion was not the dominant cause for the great supersaturations which were obtained.

Geochimica et Cosmochimica Acta

Variations in water clarity and bottom albedo in Florida Bay from 1985 to 1997

Following extensive seagrass die-offs of the late 1980s and early 1990s, Florida Bay reportedly had significant declines in water clarity due to turbidity and algal blooms. Scant information exists on the extent of the decline, as this bay was not investigated for water quality concerns before the die-offs and limited areas were sampled after the primary die-off. We use imagery from the Advanced Very High Resolution Radiometer (AVHRR) to examine water clarity in Florida Bay for the period 1985 to 1997. The AVHRR provides data on nominal water reflectance and estimated light attenuation, which are used here to describe turbidity conditions in the bay on a seasonal basis. In situ observations on changes in seagrass abundance within the bay, combined with the satellite data, provide additional insights into losses of seagrass. The imagery shows an extensive region to the west of Florida Bay having increased reflectance and light attenuation in both winter and summer begining in winter of 1988. These increases are consistent with a change from dense seagrass to sparse or negligible cover. Approximately 200 km 2 of these offshore seagrasses may have been lost during the primary die-off (1988 through 1991), significantly more than in the bay. The imagery shows the distribution and timing of increased turbidity that followed the die-offs in the northwestern regions of the bay, exemplified in Rankin Lake and Johnson Key Basin, and indicates that about 200 km 2 of dense seagrass may have been lost or severely degraded within the bay from the start of the die-off. The decline in water clarity has continued in the northwestern bay since 1991. The area west of the Everglades National Park boundaries has shown decreases in both winter turbidity and summer reflectances, suggestive of partial seagrass recovery. Areas of low reflectance associated with a major Syringodium filiforme seagrass meadow north of Marathon (Vaca Key, in the Florida Keys) appear to have expanded westward toward Big Pine Key, indicating changes in the bottom cover from before the die-off. The southern and eastern sections of the Bay have not shown significant changes in water clarity or bottom albedo throughout the entire time period.

Florida

Water, energy, and biogeochemical budget research at Sleepers River Research Watershed, Vermont

The U.S. Geological Survey has selected the Sleepers River Research Watershed (Sleepers River) near Danville, Vt., as one of five sites for the investigation of Water, Energy, and Biogeochemical Budgets (WEBB). Sleepers River was chosen because it is a well-designed outdoor laboratory with a long history of hydrologic data collection and research, and also because it provides an ideal opportunity for collaboration among the U.S. Geological Survey, other Federal agencies, and universities at the site. The multiple subwatersheds at Sleepers River present a unique opportunity to investigate hydrologic, energy, and biogeochemical processes over a variety of spatial scales. This WEBB study builds on fundamental research on process mechanisms and rates at the plot scale (in this case, a hillslope). Results then are scaled up to interpret the hydrochemical response of first- and higher- order basins. Five research elements make up the Sleepers River WEBB project. Individually, each of the five elements is designed to investigate specific WEBB processes (such as CO2 efflux through a snowpack), address specific WEBB issues (such as scaling and flowpaths), or apply specific WEBB approaches (such as integrated chemical and physical study of a hillslope). The research elements overlap so that many of the processes investigated will be assessed in more than one way, thus allowing independent verification of research results. For example, flowpath information will be derived separately by use of isotopic tracers, conservative chemical solutes, and soil-moisture fluxes. Collectively, the five elements constitute an integrated approach to a comprehensive understanding of WEBB processes needed for the prediction of the effects of global change.

Open-File Report

Simulation of ground-water flow in the Albuquerque Basin, central New Mexico, 1901-95, with projections to 2020

The ground-water-flow model of the Albuquerque Basin (Kernodle, J.M., McAda, D.P., and Thorn, C.R., 1995, Simulation of ground-water flow in the Albuquerque Basin, central New Mexico, with projections to 2020: U.S. Geological Survey Water-Resources Investigations Report 94-4251, 114 p.) was updated to include new information on the hydrogeologic framework (Hawley, J.W., Haase, C.S., and Lozinsky, R.P., 1995, An underground view of the Albuquerque Basin: Proceedings of the 39th Annual New Mexico Water Conference, November 3-4, 1994, p. 37-55). An additional year of ground-water-withdrawal data was appended to the simulation of the historical period and incorporated into the base for future projections to the year 2020. The revised model projects the simulated ground-water levels associated with an aerally enlarged occurrence of the relatively high hydraulic conductivity in the upper part of the Santa Fe Group east and west of the Rio Grande in the Albuquerque area and north to Bernalillo. Although the differences between the two model versions are substantial, the revised model does not contradict any previous conclusions about the effect of City of Albuquerque ground-water withdrawals on flow in the Rio Grande or the net benefits of an effort to conserve ground water. Recent revisions to the hydrogeologic model (Hawley, J.W., Haneberg, W.C., and Whitworth, P.M., in press, Hydrogeologic investigations in the Albuquerque Basin, central New Mexico, 1992-1995: Socorro, New Mexico Bureau of Mines and Mineral Resources Open- File Report 402) of the Albuquerque Basin eventually will require that this model version also be revised and updated.

Open-File Report

Discharge data collection and analysis and implications for surface-water/groundwater interactions in the lower Las Vegas Wash, Clark County, Nevada, 2016–18

The lower Las Vegas Wash represents the terminal surface drainage for the Las Vegas Valley in southern Nevada. In 1997, high concentrations of perchlorate were found in seeps contributing to discharge in this area and traced to an industrial byproduct from manufacturing operations in the mid-1900s at the nearby Basic Magnesium, Incorporated, plant. The discovery prompted a water-resources investigation by the Nevada Department of Environmental Protection (NDEP) to develop an understanding of the nearby groundwater flow system and the dynamics associated with surface-water flow in the Wash. In 2016, the U.S. Geological Survey was tasked with evaluating surface-water discharge in the lower Las Vegas Wash near locations where perchlorate concentrations from the groundwater system had been detected. Results of this study will assist NDEP with identifying areas of groundwater and surface-water interaction and help guide future cleanup and monitoring efforts. Streamflow discharge is evaluated along a 4-mile section of the lower Las Vegas Wash (referred to as the Wash) and used to describe surface-water and groundwater interactions between the Wash channel and bank sediments. Continuous discharge data were collected during a 2-year period (2016–18) at 5 gaging stations along the Wash. Additionally, multiple discrete measurements between gaging stations were collected during 4 synoptic sampling events between 2016 and 2018. A diurnal discharge pattern, controlled by upstream treated wastewater releases, provided high- and low-discharge markers that are used to compute downstream time-lags of peak and minimum flows. Computed time-lags are used to establish travel times between measurement sites, and difference in upstream and time-lagged downstream hydrographs are used to compute increases (gain) or decreases (loss) in discharge between gaging stations or between gaging stations and discrete measurements. Tributary surface-water inflows to the lower Las Vegas Wash from wastewater discharge, remediation efforts, and periodic flooding from rainfall runoff are included in computing differences in discharge. Differences between discharge data from delineated reaches are used to define locations of daily, monthly, and yearly streamflow gains from or losses to adjacent bank sediments. Construction of additional channel-stabilization weirs have occurred since the completion of this study and the associated change to streamflow dynamics may limit study results to the period analyzed; however, methods and processes described in this report can be used in future evaluations.

Nevada

Water resources data Mississippi water year 2004

Water resources data for this water year for Mississippi consists of records of surface water and ground water in the State. Specifically, it contains: (1) Discharge records for 90 streamflow-gaging stations, stage records for 18 of these gaging stations, discharge records for 97 partial-record stations or miscellaneous streamflow sites, including 6 flood hydrograph partial-record stations, 91 crest-stage partial-record stations and 0 special study and miscellaneous sites; (2) stage only at 1 gaging station; (3) water-quality records for 12 streamflow-gaging stations, 0 stage-only stations, 13 water-quality monitor stations, 0 partial-record stations or miscellaneous sites, 0 short-term study sites, and 26 wells; and (4) water-level records for 19 observation wells. Records obtained from water-resources investigations are also included in special sections of the report. Records included for stream stages are only a small fraction of those obtained during the water year.

Water Data Report

Detection and mapping of fractures and cavities using borehole radar

Borehole radar can be used in a single-hole reflection mode or in a cross-hole tomography mode. In the reflection mode, radar provides an image of discontinuities in the bedrock surrounding a borehole, including bedding planes, lithologic contacts, fractures, and cavities. The measurements are either directional or omni-directional, depending upon the type of equipment and antennas. In the tomography mode, where the transmitter and receiver are in separate boreholes, radar provides an image of the planar section between the boreholes. The radius of investigation depends on the antenna frequency and the electrical conductivity of the bedrock. For a central frequency of 100 megahertz, in the reflection mode the ranges are typically 10 to 40 meters in resistive solid rock and less than 5 meters in conductive, clay-rich, or silty rock. Single-hole and cross-hole radar also have been used for water-supply investigations in the northeast-ern United States. Borehole radar was used to investigate crystalline bedrock in two rapidly developing com-munities that rely on water resources in the bedrock. The surveys were conducted and interpreted along with data from other borehole geophysical tools. The borehole radar surveys were used to identify the location and orientation of reflectors, locate the primary pathways of flow to the supply wells, and identify aquifer character-istics that may be useful in siting a production well and protecting high-yielding wells in crystalline rocks. Borehole radar has been used to investigate fractures, cavities, and lithologic changes at several sites in Europe. The radar data has been interpreted in conjuction with the results of modeling of borehole-radar re-sponse. At the Grimsel nuclear waste laboratory in Switzerland, single-hole reflection and tomography methods were used to characterize the rock in inclined boreholes. At numerous geotechnical sites in Belgium, France, and the Netherlands, borehole radar has been used to characterize the rock and identify fractures and cavities.

Conference Paper

U.S. Geological Survey Federal-State Cooperative Water-Resources Program fiscal year 1994

The Federal-State Cooperative Program is a major U.S. Geological Survey (USGS) activity for the collection, analysis, and reporting of information on the quantity, quality, and use of the Nation's water resources. The fundamental characteristic of the program is that most of the work is undertaken by the USGS through joint-funding agreements, with State, regional, and local agencies providing at least one-half the funds. The main objectives of the program are (1) to collect, on a systematic basis, data needed for the continuing determination and evaluation of the quantity, quality, and use of the Nation's water resources; and (2) to appraise the availability and the physical, chemical, and biological characteristics of surface and ground water through data analysis and interpretive water-resources investigations and research. During fiscal year (FY)1994, Cooperative Program activities were underway in offices in every State, Puerto Rico, and several territories in concert with about 1,100 cooperating agencies. In FY 1994, Federal funding of $63.5 million was matched by cooperating agencies, which also provided more than $25 million unmatched for a total program of about $152 million. This amounted to nearly 40 percent of the total funds for the USGS's water-resources activities. This report presents examples of FY 1994 investigations, as well as updated information on hydrologic data collection activities.

Open-File Report

Water, energy, and biogeochemical budgets investigation at Panola Mountain research watershed, Stockbridge, Georgia; A research plan

The Panola Mountain Research Watershed (PMRW), located in the Panola Mountain State Conservation Park near Stockbridge, Georgia has been selected as a core research watershed under the Water, Energy and Biogeochemical Budgets (WEBB) research initiative of the U.S. Geological Survey (USGS) Global Climate Change Program. This research plan describes ongoing and planned research activities at PMRW from 1984 to 1994. Since 1984, PMRW has been studied as a geochemical process research site under the U.S. Acid Precipitation Thrust Program. Research conducted under this Thrust Program focused on the estimation of dry atmospheric deposition, short-term temporal variability of streamwater chemistry, sulfate adsorption characteristics of the soils, groundwater chemistry, throughfall chemistry, and streamwater quality. The Acid Precipitation Thrust Program continues (1993) to support data collection and a water-quality laboratory. Proposed research to be supported by the WEBB program is organized in 3 interrelated categories: streamflow generation and water-quality evolution, weathering and geochemical evolution, and regulation of soil-water chemistry. Proposed research on streamflow generation and water-quality evolution will focus on subsurface water movement, its influence in streamflow generation, and the associated chemical changes of the water that take place along its flowpath. Proposed research on weathering and geochemical evolution will identify the sources of cations observed in the streamwater at Panola Mountain and quantify the changes in cation source during storms. Proposed research on regulation of soil-water chemistry will focus on the poorly understood processes that regulate soil-water and groundwater chemistry. (USGS)

Georgia

Population and habitat analyses for greater sage-grouse (Centrocercus urophasianus) in the bi-state distinct population segment—2018 update

Executive Summary The Bi-State Distinct Population Segment (Bi-State DPS) of greater sage-grouse ( Centrocercus urophasianus , hereinafter “sage-grouse”) represents a genetically distinct and geographically isolated population that straddles the border between Nevada and California. The primary threat to these sage-grouse populations is the expansion of single-leaf pinyon ( Pinus monophylla ) and Utah juniper ( Juniperus osteosperma ) into sagebrush ecosystems, which fragments and reduces population connectivity and survival. Other important threats include low water availability during brood-rearing, particularly during drought, and increased predation by common ravens ( Corvus corax ), a generalist predator often associated with anthropogenic resource subsidies. Although the Bi-State DPS occurs at high elevations relative to sage-grouse range-wide, changes in historical wildfire cycles and the conversion of native shrubs to invasive annual grasslands still threaten these populations. The Bi-State DPS has undergone multiple federal status assessments and associated litigation. For example, in October of 2013, the Bi-State DPS was proposed for listing as threatened under the Endangered Species Act of 1973 by the U.S. Fish and Wildlife Service (USFWS), then withdrawn in April 2015. The withdrawal decision was challenged, and in May 2018, a Federal district court ordered the withdrawal decision to be vacated, and USFWS was required to re-open the October 2013 listing evaluation. In response, the U.S. Geological Survey (USGS), with State and Federal collaborators, embarked on a multipronged analysis to provide current and best available science regarding population status of sage-grouse within the Bi-State DPS. Using data from a long-term monitoring program, we carried out four analytical study objectives, and here, we provide preliminary results of these analyses. First, we used integrated population modeling (IPM) to predict annual population abundance and annual finite rate of population change for the Bi-State DPS, as a whole, and for each subpopulation between 1995 and 2018. Because sage-grouse exhibit population cycles (periodic increases and decreases in abundance across approximately 6- to 10-year wavelengths), we estimated trends across three nested temporal scales that represent one (11 years), two (18 years), and three (24 years) complete population cycles. These estimates of relatively long-term averaged population change account for temporal (that is, interannual) variation. Our model predicted population abundance for the Bi-State DPS during 2018 at 3,305 individuals (2,247–4,683), with the majority occupying Bodie Hills and Long Valley. The model also predicted cyclic dynamics in abundance through time with evidence of 24-year population growth and slight trends of decline over the past 18 years. Specifically, across the Bi-State DPS as a whole, we estimated annual average at 0.99, 0.99, and 1.02 over the one, two, and three population cycles, which equated to a 10.5 percent, 16.6 percent decrease, and 60.0 percent increase in abundance over the 11-, 18-, and 24-year cycles. Estimated abundance in 2018 had not reached numbers lower than those predicted during 1995. However, we found spatial variation in population trends across the three cycles. Bodie Hills subpopulation comprised the greatest (1,521) and exhibited average annual greater than 1.0 across all periods resulting in average annual increases of 7 percent. This relatively large subpopulation has grown 5 times larger than what was predicted in 1995 while experiencing cyclical dynamics within that period. Conversely, other smaller subpopulations within the Bi-State DPS exhibited average annual equal to or less than 1.0 resulting in estimated 10-year risks of extirpation ranging from 2.0 to 76.1 percent. In general, evidence of decline among smaller subpopulations was greatest for the most recent period (2008–18) compared to a period that encompassed three full population cycles (24-year). This difference coincides with an intense period of drought that began in 2012. For comparative purposes as part of this first objective, we conducted a similar analysis for populations of sage-grouse within Nevada and California but outside the Bi-State DPS. We developed a region-wide and distance-weighted IPM using lek count from Nevada Department of Wildlife (NDOW) and California Department of Fish and Wildlife (CDFW) databases and with telemetry data collected by USGS across 12 sage-grouse subpopulations. Our models predicted similar patterns in population cycling outside the Bi-State DPS but with much stronger evidence of long-term declines across 24 years. Specifically, median averaged across each year of the 11-, 18-, and 24-year periods resulted in average annual values of 0.94, 0.97, and 0.99, respectively. These values equate to 41.0 percent, 38.5 percent, and 21.3 percent declines over the corresponding periods. Second, we used lek count data in a state-space modeling framework to compare trends in population abundance across different spatial scales (that is, leks versus Bi-State DPS). This hierarchical framework allowed us to disentangle declines associated with climate conditions as opposed to other local level factors that might signal the need for management intervention. Specifically, we identified 7 leks that were both declining and recently decoupled from larger spatial scale trends, typically governed by climatic conditions (referred to as soft or hard signals). The goal of this analysis was to provide an early warning system that might have implications for conservation actions at local scales. Third, we developed phenological (spring, summer–fall, and winter) and reproductive life stage (nesting, early brood-rearing, and late-brood rearing) based resource selection functions using various environmental covariates. We report rankings of variable importance for each season and life stage, developed maps of habitat selection indices (HSI), binned categories representing low, moderate, and high classes of quality (where any category greater than or equal to low indicated selected habitat) for each phenological season and life stage, and produced composite maps by selected phenological and reproductive stage to estimate annual habitat. Fourth, we used for each lek within the Bi-State DPS to carry out a spatial analysis that quantified substantial changes in the distribution of occupied habitat across long- (24-year) and short- (11-year) term periods. Owing to differences among available datasets, the long-term analysis primarily reflected spatial shifts among subpopulations comprising the majority of the Bi-State DPS (that is, Bodie Hills and Long Valley) while the short-term analysis also quantified changes among subpopulations along the periphery. Over long and short-term periods, the overall distribution of occupied habitat (as measured by 99 percent utilization distributions intersecting any quantified habitat) was reduced by 20,573 ha and 55,492 ha, respectively. Occupied core areas (as measured by 50 percent utilization distributions intersecting any quantified habitat) over long-term periods were solely located in Bodie Hills and Long Valley. Although nearly all subpopulations experienced contractions in occupied overall and core distribution, Bodie Hills experienced spatial expansion that occurred with concomitant spatial contraction at Long Valley over both periods. Subpopulations at the northern (Pine Nuts), central (Sagehen) and southern (White-Mountains) extents of the Bi-State DPS also experienced spatial contraction over the short-term period. These findings, coupled with those of population trends, indicate long-term patterns in redistribution of sage-grouse from Long Valley and peripheral subpopulations to Bodie Hills. That is, sage-grouse subpopulations at the periphery are declining while the largest population at the core is increasing, which could have meaningful impacts on overall metapopulation persistence. We provide evidence for loss of occupied habitat (reduced distribution) given local extirpation of subpopulations. Fifth, we calculated percentages of selected phenological, life stage, and annual habitat that each subpopulation contributed to the Bi-State DPS. We then intersected these maps with a composite estimate of occupied habitat from the fourth objective and calculated percentages of selected habitat likely occupied by sage-grouse that each subpopulation contributed to the Bi-State DPS. These values provide evidence for loss of occupied habitat and subsequent reductions in spatial distribution given reductions in abundance and, in some cases, extirpation of leks within subpopulations. Lastly, we carried out an initial in-depth analysis of selection for irrigated pastures and wet meadows during the brood-rearing stage for the Long Valley subpopulation. We chose this subpopulation because it represents a population core, representing 26.5 percent of total sage-grouse within the Bi-State DPS, and has exhibited long-term declines in abundance and distribution. This subpopulation is highly sensitive to precipitation and other factors that influence water availability. Models predicted higher use of the interior portions of irrigated pastures and wet meadows during late brood-rearing period, which represented a potentially risky use of habitat that was exacerbated during periods of low moisture (for example, drought, reduced water delivery, or both). Sage-grouse typically used edges of riparian areas and pastures, largely because the interior of these mesic areas consisted of considerably less overhead concealment cover (for example, shrubs) that likely resulted in a higher risk of mortality. We found that a lack of water delivery to pastures in the form of overwinter precipitation or diversion ditches increased the movements of sage-grouse to the interior of pastures. Although further investigation of water delivery impacts on chick survival are warrented, our initial findings regarding resource selection may explain recent declines in population growth at Long Valley.

California, Nevada

U.S. Geological Survey programs in Florida, 1999

The safety, health, and economic well-being of Florida?s citizens are important to the U.S. Geological Survey (USGS), which is involved in water-related, geologic, biological, land use, and mapping issues in many parts of the State. The USGS office in Tallahassee acts as the liaison for all studies conducted by USGS scientists in Florida. Water resources activities are conducted not only from the office in Tallahassee, but also from offices in Miami, Tampa, and Altamonte Springs (Orlando). Scientists in these offices investigate surface water, ground water and water quality in Florida, working in cooperation with other Federal, State and local agencies and organizations. The USGS Center for Coastal Geology and Regional Marine Studies was established in St. Petersburg in 1988, in cooperation with the University of South Florida. The Center conducts a wide variety of research on mineral resources and on coastal and regional marine problems, including coastal erosion, climate change, wetlands deterioration, and coastal pollution. A USGS mapping office is located in St. Petersburg. Also, the Earth Science Information Center (ESIC) in Tallahassee provides USGS information to customers and directs inquiries to the appropriate USGS office or State agency on earth science topics, particularly those related to cartography, geography, aerial photography, and digital data. Biologists at the USGS Florida Caribbean Science Center, located in Gainesville, conduct biological and ecosystem studies in Florida, Puerto Rico, and the Virgin Islands.

Florida

Progress report: Ground-water appraisal of Cuyama Valley, California

Ground-water withdrawals in Cuyama Valley (fig. 1) have increased about 500 percent since the early forties, and since about 1947 annual withdrawal has exceeded the estimated perennial yield of the basin. This has caused a general decline of water levels in the valley, and a well-defined cone of depression about 2 by 6 miles in area, reflecting a maximum water-level decline of about 140 feet, has developed near Cuyama. Continued overdraft will increase pumping lifts until pumping costs are no longer economical. The U.S. Geological Survey, in cooperation with the Santa Barbara County Water Agency, has been engaged in a water-resources investigation of the area during the past year. Preliminary findings are summarized in this progress report, which has been prepared at the request of the Santa Barbara County Water Agency. Ground water in Cuyama Valley is replenished mostly by rain on a watershed of about 700 square miles (fig. 2). Most of that area, at altitudes from 2,000 to 5,000 feet above sea level, receives less than 14 inches of precipitation a year. Somewhat greater precipitation, about 24 to 30 inches, occurs in the headwater region of the Cuyama River and on the crest of the Sierra Madre Mountains, where altitudes exceed 7,000 feet. However, only a small part of the drainage from these highland areas reaches the Cuyama ground-water basin. In the valley itself the average annual rainfall is less than 10 inches. The average annual rainfall for the 21-year period (1945-65) at Cuyama is 5.79 inches (fig. 3). Most of the rain falls in winter and spring.

California

Hydrogeologic data for the Farmington River basin, Connecticut

This report contains hydrologic and geologic data collected and compiled as part of a water resources investigation of the Farmington River basin, Connecticut. The study was made by the U.S. Geological Survey in fiscal cooperation with the Connecticut Department of Environmental Protection. A companion report, Connecticut Water Resources Bulletin No. 29 (in preparation), contains the interpretation of ground-water, quality-of-water, and surfacewater data collected for the study.

Connecticut

A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN

Secondary water quality impacts can result from a broad range of coupled reactions triggered by primary groundwater contaminants. Data from a crude-oil spill research site near Bemidji, MN provide an ideal test case for investigating the complex interactions controlling secondary impacts, including depleted dissolved oxygen and elevated organic carbon, inorganic carbon, CH 4 , Mn, Fe, and other dissolved ions. To better understand these secondary impacts, this study began with an extensive data compilation of various data types, comprising aqueous, sediment, gas, and oil phases, covering a 260 m cross-sectional domain over 30 years. Mass balance calculations are used to quantify pathways that control secondary components, by using the data to constrain the sources and sinks for the important redox processes. The results show that oil constituents other than BTEX (benzene, toluene, ethylbenzene, o -, m - and p -xylenes), including n -alkanes and other aromatic compounds, play significant roles in plume evolution and secondary water quality impacts. The analysis underscores previous results on the importance of non-aqueous phases. Over 99.9% of the Fe 2+ plume is attenuated by immobilization on sediments as Fe(II) and 85–95% of the carbon biodegradation products are outgassed. Gaps identified in carbon and Fe mass balances and in pH buffering mechanisms are used to formulate a new conceptual model. This new model includes direct out-gassing of CH 4 and CO 2 from organic carbon biodegradation, dissolution of directly produced CO 2 , and sorption with H + exchange to improve pH buffering. The identification of these mechanisms extends understanding of natural attenuation of potential secondary impacts at enhanced reductive dechlorination sites, particularly for reduced Fe plumes, produced CH 4 , and pH perturbations.

Minnesota

Alteration of reactive mineral surfaces by ground water

Two different investigations of shallow sandy aquifers inform our thinking about the role of reactive iron minerals in hydrogeological systems. Ground water in a number of settings has been described as having elevated concentrations of dissolved iron in anoxic portions of contaminant plumes (e.g. Baedecker et al., 1993; Lyngkilde and Christensen, 1992), and the coupling of microbial reduction of Fe(III) to the degradation of organic compounds links the study of the biogeochemistry of iron to our desire to understand processes influencing contaminated aquifers. Questions about the transport and fate of reactive constituents in ground water are linked to the study of iron through recognition of the importance of sorption processes on sesquioxide mineral surfaces common in sedimentary aquifers limiting the migration of metals, anions, and bacteria. We have been grappling with questions related to the stability of iron mineral phases in contaminated aquifers and the role of Fe(III)- bearing minerals and grain coatings as sorption substrates

Conference Paper