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USGS2020

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗
USGS1963

Geology of the Jewel Cave SW Quadrangle, Custer County, South Dakota

The Jewel Cave SW quadrangle is in the southwestern part of the Black Hills in Custer County, S. Dak., about midway between Edgemont, S. Dak., and Newcastle, Wyo. All the rocks that crop out within the quadrangle are of sedimentary origin and range in age from Pennsylvanian to Early Cretaceous. The Minnesota Formation of Pennsylvania and Permian age, which is about 1,000 feet thick, was studied in outcrop and from two diamond-drill cores. In the subsurface the upper part of the formation consists of gray sandstone, very fine grained dolomite, and anhydrite. The anhydrite has been leached from the formation near the outcrop, perhaps in the early part of the Cenozoic Era, and the resulting subsidence has produced collapse breccias in the Minnelusa and milder deformation in the overlying units. In the collapse breccias the rocks have been oxidized and are red, whereas in the subsurface they are gray. The anhydrite cement of the subsurface sandstone has been replaced by calcite, and the dolomite beds have been partially converted to limestone. The Opeche Formation of Permian age consists of 75 to 115 feet of red siltstone and shale and two thin gypsum beds. The Minnekahta Limestone of Permian age is about 40 feet thick. The Spearfish Formation of Permian and Triassic age is about 550 feet thick and consists of red siltstone red sandstone, dolomite, and gypsum. The dolomite and gypsum beds are restricted to the lower half of the formation. In the northeast corner of the quadrangle the gypsum beds have been dissolved by ground water. The Sundance Formation of Late Jurassic age is divided into five members that have a total thickness of about 360 feet. The Morrison Formation of Late Jurassic age ranges in thickness from 60 to 120 feet. It consists of blocky weathering noncarbonaceous mudstone and subordinate beds of limestone and sandstone. The Inyan Kara Group of Early Cretaceous age has been subdivided into the Lakota Formation and the Fall River Formation. The Lakota Formation consists of 200 to 300 feet of carbonaceous siltstone blocky-weathering claystone, and fine-grained to conglomeratic sandstone. These rocks were deposited in stream channels, flood plains, and ponds. The Fall River Formation is about 110 to 130 feet thick. Along the northeast side of the outcrop the formation consists of fine- to medium-grained sandstone, which forms an elongate body at least 1-1/2 miles wide and more than 25 miles long. To the southwest the formation consists of thinly stratified interbedded sandstone, carbonaceous siltstone, and varicolored mudstone. The Skull Creek and Mowry Shales of Early Cretaceous age consist of black fissile shale. The Mowry contains abundant fish scales and weathers to a silver gray. Alluvium fills the bottom of many intermittent streams, and small gravel-covered terraces mark the former high levels of these streams. Gravel, which caps hills at altitudes of 4,460 to 4,620 feet, is believed to have been deposited by a Pleistocene stream that drained southeastward toward the town of Minnekahta. Many landslides are present along the northward- and eastward-facing scarp of the Inyan Kara hogback. The Dewey fault, trending N. 75 deg E., crosses the quadrangle. It is probably a vertical dip-slip fault, and has an apparent displacement of 250 to 440 feet. Two northwest-trending anticlines are in the quadrangle - one extends from the Edgemont NE quadrangle to near the center of the Jewel Cave SW quadrangle, and the other is limited to the center of the Jewel Cave SW quadrangle. Collapse structures, which were produced by the solution of anhydrite, are (a) breccias in the Minnelusa Formation, (b) limestone-dolomite breccias in the Spearfish Formation, (c) undulations and normal faults in the formations overlying the Minnelusa and (d) breccia pipes that extend upward from the Minnelusa to at least as high as the Lakota Formation. The leaching probably occurred in early Cenozoic time. Minor deformationa

Bulletin↗
USGS2005

Environmental setting, water budget, and stream assessment for the Broad Run watershed, Chester County, Pennsylvania

The Broad Run watershed lies almost entirely in West Bradford Township, Chester County, Pa., and drains 7.08 square miles to the West Branch Brandywine Creek. Because of the potential effect of encroaching development and other stresses on the Broad Run watershed, West Bradford Township, the Chester County Water Resources Authority, and the Chester County Health Department entered into a cooperative study with the U.S. Geological Survey to complete an annual water budget and stream assessment of overall conditions. The annual water budget quantified the basic parameters of the hydrologic cycle for the climatic conditions present from April 1, 2003, to March 31, 2004. These water-budget data identified immediate needs and (or) deficits that were present within the hydrologic cycle during that period, if present; however, an annual water budget encompassing a single year does not identify long-term trends. The stream assessment was conducted in two parts and assessed the overall condition of the watershed, an overall assessment of the fluvial-geomorphic conditions within the watershed and an overall assessment of the stream-quality conditions. The data collected will document present (2004) conditions and identify potential vulnerabilities to future disturbances. For the annual period from April 1, 2003, to March 31, 2004, determination of an annual water budget indicated that of the 67.8 inches of precipitation that fell on the Broad Run watershed, 38.8 inches drained by way of streamflow to the West Branch Brandywine Creek. Of this 38.8 inches of streamflow, local-minimum hydrograph separation techniques determined that 7.30 inches originated from direct runoff and 31.5 inches originated from base flow. The remaining precipitation went into ground-water storage (1.71 inches) and was lost to evapotranspiration (27.3 inches). Ground-water recharge for this period-35.2 inches-was based on these values and an estimated ground-water evapotranspiration rate of 2 inches. Assessment of fluvial-geomorphic conditions included large-scale mapping of stream classes within the Broad Run watershed and in-depth study of three representative stream reaches also within the Broad Run watershed. Based on the total distance of all stream reaches classified within the Broad Run watershed, 61 percent were classified as C-class, 14 percent as E-class, 13 percent as B-class, 5 percent as F-class, 4 percent as undifferentiated B- and F-class, 2 percent as G-class, and less than 1 percent as A-class. The map of stream classes indicates that the Broad Run watershed currently has no large-scale areas of stream impairment and that, generally, the stream is not entrenched and the main branch of the Broad Run has an available, functioning flood plain. Smaller tributary streams, however, showed signs of localized entrenchment due to site-specific influences such as natural stream-channel evolution, localized channelization, localized contraction due to road and driveway crossings, and (or) increased localized runoff. For example, one small reach along a tributary channel was observed to become entrenched due to runoff originating from a new housing development. Entrenched stream reaches are merely located by large-scale mapping and require individual assessment to determine potential causes of entrenchment and (or) future restorative actions. Three in-depth geomorphic study sites showed that the Broad Run can currently be considered graded or in a state of dynamic equilibrium. The sites did, however, identify certain vulnerabilities to future changes within the watershed. These vulnerabilities included disruption of the present sediment supply, including both increases and (or) reductions in the current sediment loads within the Broad Run; increases in both magnitude and duration of storm-water runoff; encroachment of development onto present flood-plain areas, and (or) alterations to riparian zones. Assessment of stream-quality conditions includ

Scientific Investigations Report↗
USGS2011

Development of flood-inundation maps for the West Branch Susquehanna River near the Borough of Jersey Shore, Lycoming County, Pennsylvania

Streamflow data, water-surface-elevation profiles derived from a Hydrologic Engineering Center River Analysis System hydraulic model, and geographical information system digital elevation models were used to develop a set of 18 flood-inundation maps for an approximately 5-mile reach of the West Branch Susquehanna River near the Borough of Jersey Shore, Pa. The inundation maps were created by the U.S. Geological Survey in cooperation with the Susquehanna River Basin Commission and Lycoming County as part of an ongoing effort by the National Oceanic and Atmospheric Administration's National Weather Service to focus on continued improvements to the flood forecasting and warning abilities in the Susquehanna River Basin and to modernize flood-forecasting methodologies. The maps, ranging from 23.0 to 40.0 feet in 1-foot increments, correspond to river stage at the U.S. Geological Survey streamgage 01549760 at Jersey Shore. The electronic files used to develop the maps were provided to the National Weather Service for incorporation into their Advanced Hydrologic Prediction Service website. The maps are displayed on this website, which serves as a web-based floodwarning system, and can be used to identify areas of predicted flood inundation associated with forecasted flood-peak stages. During times of flooding or predicted flooding, these maps can be used by emergency managers and the public to take proactive steps to protect life and reduce property damage caused by floods.

Pennsylvania↗
USGS1950

Ground-water problems in the Philadelphia area [Pennsylvania]

Large quantities of ground water are used by the Philadelphia Naval Base and many industries in south Philadelphia, as well as by municipalities near Philadelphia in both Pennsylvania and New Jersey. The areal contact between unconsolidated sand, gravel, and clay strata of the Atlantic Coastal Plain and consolidated rocks of the Piedmont province extends in a northeast-southwest line through central Philadelphia. This line of contact, the so-called Fall Line, sharply separates the area of highly productive sand and gravel aquifers of the Coastal Plain from the less productive bedrock aquifers of the Piedmont Plateau. The daily withdrawal of ground water from sand and gravel in the Philadelphia area, including Bristol, Pa., and Trenton, N. J., is approximately 110 million gallons. Wells around Philadelphia yield an additional 13 million gallons a day from consolidated rocks of the Piedmont province. The Raritan formation of Cretaceous age is the principal aquifer for wells in south Philadelphia and the adjacent Camden area. The large quantity of water pumped and the limited extent of this aquifer in the area provide a potentially serious interstate water problem. Ground-water levels in the strategically important Naval Base area have not declined seriously as yet, but increasing withdrawal planned in adjacent New Jersey is expected to lower water levels in south Philadelphia The Delaware and Schuylkill Rivers are believed to be the chief sources of recharge to the Raritan formation, even though heavy pumping on either side of the Delaware River may be expected to affect water levels on the other side. Recharge appears to be adequate generally for present rates of withdrawal, but further studies are needed for an evaluation of the safe maximum yield of the area. The chemical quality of ground water pumped from the Raritan formation is satisfactory for most purposes, but periodic analyses indicate that the concentration of dissolved solids is increasing. This deterioration of the chemical quality probably is due to the character of the water and bottom sediments of the Delaware and Schuylkill Rivers. Shallow aquifers in south Philadelphia contain large amounts of gases generated by the decay of river silts and city refuse occupying low areas. The States of Pennsylvania and New Jersey, together with the municipalities concerned, are coordinating their efforts for a practical solution to the ground-water problems of the Philadelphia area.

Pennsylvania↗
USGS1912

Pawpaw-Hancock folio, Maryland-West Virginia-Pennsylvania

The Pawpaw and Hancock quadrangles embrace parts of eastern West Virginia, western Maryland, and southern Pennsylvania between parallels 39° 30' abd 39° 45' and meridians 78° and 78° 30', and contain 460 square miles. (See fig. 1.) Parts of eight counties are included in the area, Morgan, Berkeley, and Hampshire in West Virginia, Washington and Allegany in Maryland, and Bedford, Fulton, and Franklin in Pennsylvania. Hancock, Md., the the largest town in the area, Pawpaw, Great Cacapon, and Berkeley Springs, W. Va., being next in importance.

Maryland, Pennsylvania, West Virginia↗
USGS2014

Index map of cross sections through parts of the Appalachian basin (Kentucky, New York, Ohio, Pennsylvania, Tennessee, Virginia, West Virginia)

Ten cross sections and three seismic profiles of regional extent through the subsurface of the Appalachian basin are presented in chapter E of this volume (fig. 1). These cross sections and seismic profiles are subdivided into four groups: (1) five restored cross sections through Cambrian and Ordovician rocks, (2) three restored cross sections through Lower and Upper (part) Silurian rocks, (3) two geologic (structural) cross sections through the entire preserved section of Paleozoic rocks, and (4) three seismic profiles through the entire preserved section of Paleozoic rocks. The stratigraphic units in the restored cross sections are constructed with respect to a horizontal lithologic datum, whereas the stratigraphic units in the geologic (structural) cross sections are constructed with respect to sea level. The control points for the cross sections are exploratory wells drilled for oil and gas, and many of these wells reached igneous and metamorphic basement rocks of Mesoproterozoic age. Each cross section is illustrated in detail and discussed at length in its respective chapter. The cross sections and seismic profiles included in this volume were previously published between 1991 and 2009 as U.S. Geological Survey publications; some of these publications were subsequently revised. The earliest cross sections (chapters E.2.1 to E.2.4) refer to an unpublished cross section ( A–A′ ); that cross section was never published later and is not the A–A′ included here as chapter E.3.3. The cross sections are included in this volume in their original form to provide support for assessments and research studies in the Appalachian basin. There are two additional USGS publications that are not included in this volume but may be useful for research studies: Ryder and others (1996) and Ryder and others (2012). The appendixes in chapters E.4.1 and E.4.2 include (1) Log ASCII Standard (LAS) files, which encode gamma-ray, neutron, density, and other logs in text files that can be used by most well-logging software programs; and (2) graphic well-log traces. In the appendix to chapter E.4.1, the well-log traces are accompanied by lithologic descriptions with formation tops.

Appalachian basin↗
USGS1984

GEOLOGIC APPLICATIONS OF SIDE-LOOKING AIRBORNE RADAR DATA IN THE CENTRAL APPALACHIAN MOUNTAINS.

Side-looking airborne radar has provided a sufficiently detailed synoptic view of the central Appalachian Mountains that the images give an unparalleled representation of the size and nature of the folds within the Valley and Ridge province. The radar data show that fold wavelengths decrease abruptly south of the region of the Pennsylvania, Maryland, and West Virginia State lines. Concomittantly, this decrease in fold wavelength is accompanied by an increase in both frequency and length of disturbed zones. The model predicted by the combination of the radar images and field observations suggests a broad lateral ramp, perpendicular to the strike of the fold-belt, connecting a deeper decollement level north of the Pennsylvania, Maryland and West Virginia State lines with a shallower decollement to the south. Recently, the first author has located a field example of a lateral ramp approximately one kilometer north of Mathias, West Virginia. This lateral ramp shows an up-to-the-north configuration and the extensions both northwestward and southeastward can be seen on the radar images as a series of cross-strike lineaments.

Conference Paper↗
USGS1998

Review of Aquifer Test Results for the Lansdale Area, Montgomery County, Pennsylvania, 1980–95

Aquifer and aquifer-isolation test results in and around North Penn Area 6 Superfund site, Lansdale, Montgomery County, Pennsylvania are reviewed to provide estimated aquifer properties for use in a numerical model of ground-water flow. This review was made to support of remedial action investigations by U.S. Environmental Protection Agency (USEPA), Region III, Philadelphia. The data reviewed are from files of the U.S. Geological Survey, USEPA, and water companies, and from unpublished consultant reports prepared for USEPA and corporations in the Lansdale area. Tested wells are in fractured sedimentary rocks of the Brunswick Formation, which are Triassic-aged, dipping shales and sandstones. Review procedures include, in some cases, new analyses of drawdown during pumping and recovery by use of analytical models of flow to wells. Estimated aquifer transmissivities (T) range from zero to about 1,300 m 2 /d (meters squared per day); most tests indicate T between 10 and 100 m 2 /d. Aquifer-isolation testing results indicate that most flow enters wells at a few discrete zones, probably fractures or bedding-plane openings. The vertical connection between the zones in a single borehole with multiple producing zones commonly is negligible. This suggests that the formation is vertically anisotropic; the hydraulic conductivity is much larger in the horizontal direction than in the vertical direction. Some evidence of well-field-scale horizontal anisotropy exists, with maximum transmissivity aligned with the regional northeast strike of bedding, but this evidence is weak because of the small number of observation wells, particularly wells screened in isolated depth intervals. Analysis of recovery data after constant-pumping-rate aquifer tests and of drawdown during step tests suggests that a significant fraction, perhaps as much as 85 percent, of the drawdown in some production wells is due to well loss or skin effects in or very near the pumped well and is not caused by resistance to flow in the surrounding formations.

Pennsylvania↗
USGS2007

Effects of Historical Coal Mining and Drainage from Abandoned Mines on Streamflow and Water Quality in Newport and Nanticoke Creeks, Luzerne County, Pennsylvania, 1999-2000

This report characterizes the effects of historical mining and abandoned mine drainage (AMD) on streamflow and water quality and evaluates potential strategies for AMD abatement in the 14-square-mile Newport Creek Basin and 7.6-square-mile Nanticoke Creek Basin. Both basins are mostly within the Northern Anthracite Coal Field and drain to the Susquehanna River in central Luzerne County, Pa. The U.S. Geological Survey (USGS), in cooperation with the Earth Conservancy, conducted an assessment from April 1999 to September 2000 that included (1) continuous stage measurement at 7 sites; (2) synoptic water-quality and flow sampling at 21 sites on June 2-4, 1999, and at 24 sites on October 7-8, 1999; and (3) periodic measurement of flow and water quality at 26 additional sites not included in the synoptic sampling effort. Stream water and surface runoff from the unmined uplands drain northward to the valley, where most of the water is intercepted and diverted into abandoned underground mines. Water that infiltrates into the mine workings becomes loaded with acidity, metals, and sulfate and later discharges as AMD at topographically low points along lower reaches of Newport Creek, Nanticoke Creek, and their tributaries. Differences among streamflows in unmined and mined areas of the watersheds indicated that (1) intermediate stream reaches within the mined area but upgradient of AMD sites generally were either dry or losing reaches, (2) ground water flowing to AMD sites could cross beneath surface-drainage divides, and (3) AMD discharging to the lower stream reaches restored volumes lost in the upstream reaches. The synoptic data for June and October 1999, along with continuous stage data during the study period, indicated flows during synoptic surveys were comparable to average values. The headwaters upstream of the mined area generally were oxygenated (dissolved oxygen range was 4.7 to 11.0 mg/L [milligrams per liter]), near-neutral (pH range was 5.8 to 7.6), and net alkaline (net alkalinity range was 2.0 to 25.0 mg/L CaCO3), with relatively low concentrations of sulfate (6.40 to 24.0 mg/L) and dissolved metals (less than 500 ug/L [micrograms per liter] of iron, manganese, and aluminum). In contrast, the AMD discharges and downstream waters were characterized by elevated concentrations of sulfate and dissolved metals that exceeded Federal and State regulatory limits. The largest AMD sources were the Susquehanna Number 7 Mine discharge entering Newport Creek near its mouth (flow range was 4.7 to 19 ft3/s [cubic feet per second]), the Truesdale Mine Discharge (Dundee Outfall) entering Nanticoke Creek about 0.5 mile upstream of Loomis Park (flow range was 0.00 to 38 ft3/s), and a mine-pit overflow entering near the midpoint of Newport Creek (flow range was 4.0 to 6.9 ft3/s). The three large discharges were poorly oxygenated (dissolved oxygen concentration range was <0.05 to 6.4 mg/L) and had elevated concentrations of sulfate (range was 710 to 890 mg/L) and low concentrations of dissolved aluminum (less than 25 ug/L), but they had distinctive concentrations of net alkalinity and dissolved iron and manganese. Effluent from the Susquehanna Number 7 Mine was near-neutral (pH range was 5.9 to 6.6) and net alkaline (net alkalinity range was 12.0 to 42.0 mg/L CaCO3) with elevated concentrations of sulfate (718 to 1,170 mg/L), dissolved iron (52,500 to 77,400 ug/L), and manganese (5,200 to 5,300 ug/L). Effluent from the Truesdale Mine also was near-neutral (pH range was 5.9 to 6.3) but had variable net alkalinity (-19.0 to 57.0 mg/L CaCO3) with elevated concentrations of sulfate (571 to 740 mg/L), dissolved iron (30,500 to 43,000 ug/L), and manganese (3,600 to 5,200 ug/L). Effluent from the mine-pit overflow in Newport Creek Basin was acidic (pH range was 4.3 to 5.0; net alkalinity range was -42 to -38 mg/L CaCO3) with elevated concentrations of sulfate (800 to 840 mg/L), iron (13,000 to 16,000 ug/L), and manganese (6,800 to 7,000 ug

Scientific Investigations Report↗
USGS1984

Causes of acidification of four streams on Laurel Hilld in southwestern Pennsylvania

Atmospheric deposition, soils developed from bedrock, a natural bog, gas wells, and a ski area were all investigated as possible sources of water quality degradation for four streams on Laurel Hill in southwestern Pennsylvania where fish kills have been reported since 1960. An intensive study of the chemistry of atmospheric deposition, soil leachate, and stream water and fish populations was conducted on these basins during 1980&ndash;1981 with emphasis on dormant season periods with runoff from snowmelt and rain. Although bedrock geology was found to control the natural buffering capacity of these streams, only acid precipitation could be linked to sharp drops in pH and increases in total Al concentrations observed during stormflows in the poorly buffered streams. Three poorly buffered streams exhibited drops to pH 4.4 to 4.5 and increases in total Al concentrations up to 1.5 mg/L during observed peak flows. Mineral soil leachate from the three major soil series on the basins during this time exhibited a low pH of 4.3 and mean total Al concentrations of 3.6 mg/L, indicating stream response during storms was closely linked to chemistry of soil leachate. Poorly buffered streams did not support reproducing populations of trout ( Salmonidae sp.) or other fishes. In contrast, one well-buffered stream (20 mg/L CaCO 3 ) exhibited drops to pH 5.5 during peak flow and supported reproducing trout and sculpin ( Cottus bairdi ) populations. The acidification of the four streams studied was attributed to atmospheric deposition.

Journal of Environmental Quality↗
USGS1995

Radium and radon in ground water in the Chickies Quartzite, southeastern Pennsylvania

The Chickies Quartzite, a Lower Cambrian-age formation compromised of quartzite and slate overlying a basal conglomerate, forms a narrow ridges and crops out discontinuously over 112 square miles in the Piedmont physiographic province of southeastern Pennsylvania. The formation is a low-yielding, fractured- rock, water-table aquifer recharged primarily by local precipitation. It is the sole source of water supply for thousands of domestic users. Ground water in the Chickies Quartzite generally is soft and acidic. During 1986-88, the U.S. Geological Survey sampled water from 160 wells that penetrate the Chickies Quartzite to determine the magnitude and distribution of radium-226 (Ra-226), radium-228 (Ra-228), and radon-222 (Rn-222) activities in ground water in the formation and to characterize the geochemical environmental associated with elevated activities of radium (Ra). In addition, 28 wells penetrating adjacent geologic units and 1 well in the Hardyston Quartzite were sampled to determine relative background Ra and RN-222 activities in ground water. Analyses included determination of activities of dissolved Ra-226, Ra-228, and RN-222, and concentrations of dissolved uranium (U), dissolved organic carbon (DOC), and major and minor dissolved inorganic ions. Rock samples were analyzed for U and thorium (Th) and geophysical logs were run to determine sources of Ra and RN-222 in the Chickies Quartzite. Activities of up to 41 pCi/L (picocuries per liter) for Ra-226, 160 pCi/L for Ra-228, and 32,300 pCi/L for RN-222 were measured in ground water in the Chickies Quartzite. Forty-seven percent of the samples contained Ra-226 and Ra-228 activities greater than 5 pCi/L. Median activities measured were 1.2 pCi/L for Ra-226, 2.6 pCi/L for Ra-228, 4.2 pCi/L for combined Ra-226 and Ra-228, and 2,400 pCi/L for RN-222 Ra-228 activity exceeded Ra-226 activity in about 92 percent of 100 water samples; the median Ra-228/Ra226 activity ratio was 2.4. Ra-228/Ra-226 activity ratios commonly were greater in ground water than calculated Th/U ratios in rock samples, suggesting perferential leaching of Ra-228 from aquifer solids. Of ground water in the adjacent geologic units, the highest activities (up to 2.9 pCi/L for Ra-226, 12 pCi/L for Ra-228, and 25,300 pCi/L for RN-222) were measured in ground water in the Harpers Phyllite and Antietam Quartzite. Nonparametric (Spearman rho test) statistical correlations show that the activity of dissolved Ra is inversely related to pH and directly related to concentrations of total dissolved solids, DOC, barium, and sulfate. Low pH decreases absorption of Ra onto the aquifer matrix. The other factors may favor Ra mobility by enhancing complexation or increasing solubility. RN-222 activity does not correlate with and is not supported by the activity of its parent, Ra-226, in solution. Ra-226 activity correlates positively, but weakly, with U concentrations. Ra-226 does not appear to be supported by its parent, U-238, in solution. Observed distributions of Ra-228, Ra-226, and RN-222 activities in ground water in different lithologies of the Chickies Quartzite reflect different geochemical controls on absorption and distribution of parent thorium-232 (Th-232) and uranium-238 (U-238) in the formation. Radium activities were greatest in acidic ground water in the conglomerate and quartzite (median pH of 5.0 and 5.2, respectively) and least in the more neutral water in the slate (median pH of 6.4). For ground water in the conglomerate, quartzite, and slate, respectively, median activities measured were 1.3, 1.5, and .02 pCi/L for Ra-226; and 3.7, 2.5, and 1.0 pCi/L for Ra-228. Natural-gamma-ray geophysical logs and results of rock analyses indicate that the conglomerate may contain more Th and U than the quartzite and that the conglomerate may be more enriched in Th with respect to U than the quartzite; Th and U distribution in both lithogies is variable. Median RN-222 activities in gro

Water-Resources Investigations Report↗
USGS2008

Effects of Land-Use Changes and Ground-Water Withdrawals on Stream Base Flow, Pocono Creek Watershed, Monroe County, Pennsylvania

The Pocono Creek watershed drains 46.5 square miles in eastern Monroe County, Pa. Between 2000 and 2020, the population of Monroe County is expected to increase by 70 percent, which will result in substantial changes in land-use patterns. An evaluation of the effect of reduced recharge from land-use changes and additional ground-water withdrawals on stream base flow was done by the U.S. Geological Survey (USGS) in cooperation with the U.S. Environmental Protection Agency (USEPA) and the Delaware River Basin Commission as part of the USEPA?s Framework for Sustainable Watershed Management Initiative. Two models were used. A Soil and Water Assessment Tool (SWAT) model developed by the USEPA provided areal recharge values for 2000 land use and projected full buildout land use. The USGS MODFLOW-2000 ground-water-flow model was used to estimate the effect of reduced recharge from changes in land use and additional ground-water withdrawals on stream base flow. This report describes the ground-water-flow-model simulations. The Pocono Creek watershed is underlain by sedimentary rock of Devonian age, which is overlain by a veneer of glacial deposits. All water-supply wells are cased into and derive water from the bedrock. In the ground-water-flow model, the surficial geologic units were grouped into six categories: (1) moraine deposits, (2) stratified drift, (3) lake deposits, (4) outwash, (5) swamp deposits, and (6) undifferentiated deposits. The unconsolidated surficial deposits are not used as a source of water. The ground-water and surface-water systems are well connected in the Pocono Creek watershed. Base flow measured on October 13, 2004, at 27 sites for model calibration showed that streams gained water between all sites measured except in the lower reach of Pocono Creek. The ground-water-flow model included the entire Pocono Creek watershed. Horizontally, the modeled area was divided into a 53 by 155 cell grid with 6,060 active cells. Vertically, the modeled area was discretized into four layers. Layers 1 and 2 represented the unconsolidated surficial deposits where they are present and bedrock where the surficial deposits are absent. Layer 3 represented shallow bedrock and was 200 ft (feet) thick. Layer 4 represented deep bedrock and was 300 ft thick. A total of 873 cells representing streams were assigned to layer 1. Recharge rates for model calibration were provided by the USEPA SWAT model for 2000 land-use conditions. Recharge rates for 2000 for the 29 subwatersheds in the SWAT model ranged from 6.11 to 22.66 inches per year. Because the ground-water-flow model was calibrated to base-flow data collected on October 13, 2004, the 2000 recharge rates were multiplied by 1.18 so the volume of recharge was equal to the volume of streamflow measured at the mouth of Pocono Creek. During model calibration, adjustments were made to aquifer hydraulic conductivity and streambed conductance. Simulated base flows and hydraulic heads were compared to measured base flows and hydraulic heads using the root mean squared error (RMSE) between measured and simulated values. The RMSE of the calibrated model for base flow was 4.7 cubic feet per second for 27 locations, and the RMSE for hydraulic heads for 15 locations was 35 ft. The USEPA SWAT model was used to provide areal recharge values for 2000 and full buildout land-use conditions. The change in recharge ranged from an increase of 37.8 percent to a decrease of 60.8 percent. The ground-water-flow model was used to simulate base flow for 2000 and full buildout land-use conditions using steady-state simulations. The decrease in simulated base flow ranged from 3.8 to 63 percent at the streamflow-measurement sites. Simulated base flow at streamflow-gaging station Pocono Creek above Wigwam Run near Stroudsburg, Pa. (01441495), decreased 25 percent. This is in general agreement with the SWAT model, which estimated a 30.6-percent loss in base flow at the streamflow-gaging station.

Scientific Investigations Report↗
USGS2009

Evaluation of Water-Chemistry and Water-Level Data at the Henderson Road Superfund Site, Upper Merion Township, Montgomery County, Pennsylvania, 1991-2008

Several shutdown-rebound tests have been conducted at the Henderson Road Superfund Site, which has been on the U.S. Environmental Protection Agency's National Priorities List since 1984. For a given test, the extraction wells are turned off, and water samples are collected from selected monitor wells at regular intervals before and during cessation of pumping to monitor for changes in chemical concentrations. A long-term shutdown-rebound test began on July 17, 2006. In support of this test, the U.S. Geological Survey conducted this study to determine the effects of shutting down on-site extraction wells on concentrations of selected contaminants and water levels. Concentrations were compared to ARARs (applicable relevant and appropriate requirements), which were set as remediation goals in the Henderson Road Site Record of Decision. Water from 10 wells in and near the source area and to the north, northeast, and northwest of the source area sampled in 2008 exceeded the 5.52 ug/L (micrograms per liter) ARAR for benzene. The greatest changes in benzene concentration between pre-shutdown samples collected in July 2006 and samples collected in February and March 2008 (19 months after the shutdown) were for wells in and north of the source area; increases in benzene concentration ranged from 1.5 to 164 ug/L. Water from five wells in the source area and to the north and northwest of the source area sampled in 2008 exceeded the 60 ug/L ARAR for chlorobenzene. The greatest changes in chlorobenzene concentration between pre-shutdown samples collected in July 2006 and samples collected in February and March 2008 were for wells north of the source area; increases in chlorobenzene concentration ranged from 6.9 to 99 ug/L. The highest concentrations of chlorobenzene were near or outside the northern site boundary, indicating chlorobenzene may have moved north away from the source area; however, no monitor well clusters are on the northern side of the Pennsylvania Turnpike, which is about 190 feet north of the source area. A much larger area was affected by chlorobenzene than benzene. Chlorobenzene concentrations decreased in the source area and increased at and beyond the site boundary. Water from four wells in and northeast of the source area sampled in 2008 exceeded the 5.06 ug/L ARAR for 1,1-dichloroethane (1,1-DCA). Increases in 1,1-DCA concentration between pre-shutdown samples collected in July 2006 and samples collected in February 2008 ranged from 0.4 to 20 ug/L. Water from two wells in the source area sampled in 2008 exceeded the 175 ug/L ARAR for total xylene. The 1,1-DCA and xylene plumes appear to extend in an east-northeast direction from the source area. Large drawdowns in the Upper Merion Reservoir during droughts in 1998 and 2001 affected water levels in the Chester Valley and at the Henderson Road Site, except for well HR-17-170. After the drought of 2001, water levels in the Chester Valley showed a protracted recovery lasting from September 2001 until June 2005 (46 months). Water-level data were evaluated temporally for 1997-2008 and spatially for (1) June 16, 2003, when the extraction wells were pumping at the full rate prior to the start of the June 2003 shutdown test; (2) July 10, 2006, during the period of reduced pumping after the June 2003 shutdown test; and (3) February 25-29, 2008, when the extraction wells were not pumping. Except for well HR-5-195, wells were categorized as shallow, intermediate-depth, and deep wells. The potentiometric surface for shallow wells did not appear to be affected by pumping of the extraction wells. The general direction of ground-water flow was to the north. The potentiometric surface for intermediate-depth wells showed a cone of depression when the extraction wells were pumping at the full rate but did not show a cone of depression when the extraction wells were pumping at the reduced rate. The ground-water-flow direction was toward the north and northeast, similar to

Scientific Investigations Report↗
USGS2011

Simulations of flow and prediction of sediment movement in Wymans Run, Cochranton Borough, Crawford County, Pennsylvania

In small watersheds, runoff entering local waterways from large storms can cause rapid and profound changes in the streambed that can contribute to flooding. Wymans Run, a small stream in Cochranton Borough, Crawford County, experienced a large rain event in June 2008 that caused sediment to be deposited at a bridge. A hydrodynamic model, Flow and Sediment Transport and Morphological Evolution of Channels (FaSTMECH), which is incorporated into the U.S. Geological Survey Multi-Dimensional Surface-Water Modeling System (MD_SWMS) was constructed to predict boundary shear stress and velocity in Wymans Run using data from the June 2008 event. Shear stress and velocity values can be used to indicate areas of a stream where sediment, transported downstream, can be deposited on the streambed. Because of the short duration of the June 2008 rain event, streamflow was not directly measured but was estimated using U.S. Army Corps of Engineers one-dimensional Hydrologic Engineering Centers River Analysis System (HEC-RAS). Scenarios to examine possible engineering solutions to decrease the amount of sediment at the bridge, including bridge expansion, channel expansion, and dredging upstream from the bridge, were simulated using the FaSTMECH model. Each scenario was evaluated for potential effects on water-surface elevation, boundary shear stress, and velocity.

Pennsylvania↗
USGS2009

National assessment of historical shoreline change: a pilot study of historical coastal bluff retreat in the Great Lakes, Erie, Pennsylvania

Coastal bluff retreat is a chronic problem along many high-relief coastlines in the United States. As coastal populations continue to grow and community infrastructures are threatened by erosion, there is increased demand for accurate information regard-ing trends and rates of bluff retreat. There is also a need for a comprehensive analysis that is consistent from one coastal region to another. To address these national needs, the U.S. Geological Survey (USGS), as part of the National Assessment of Coastal Change Hazards Project, conducted a pilot study of bluff retreat along the Lake Erie, Pa., coastline to assess the feasibility of undertaking a larger, multi-state analysis in the Great Lakes region. This report provides an overview of the pilot-study location and bluff geomorphology, the data sources and methodology, results of the analysis, and a discussion of the feasibility of undertaking a similar analysis along eroding bluffs in other Great Lakes states. This pilot study is part of an ongoing effort by the USGS to provide a comprehensive analysis of historical shoreline change and cliff and bluff retreat along open-ocean coastlines of the conterminous United States and parts of Hawaii, Alaska, and the Great Lakes. One purpose of the work is to develop standard, repeatable methods for mapping and analyzing coastal change so that systematic and consistent periodic updates of coastal erosion can be made nationally. Bluff-retreat evaluations are conducted by comparing the location of a historical bluff edge digitized from aerial photographs with those of recent bluff edges interpreted from both aerial photographs and lidar topographic surveys. The historical bluff edge is from 1938, whereas the more recent bluff edges are from 1998 and 2006 lidar data. Long-term (68-year) rates of retreat are calculated using the available bluff-edge data. The rates of retreat presented in this report represent conditions from the 1930s to 1998/2006, and are not intended for predicting future bluff-edge positions or rates of retreat. The report presents bluff-retreat rates for 32 km of a 60-km stretch along the Lake Erie, Pa., coastline. Data are discontinuous due to gaps in source data and lack of continuous bluffs. The average rate of coastal bluff retreat for the Lake Erie, Pa., bluffs was -0.3 +- 0.1 m/yr (retreat rates are presented as negative numbers in this report), based on rates averaged from 1,595 individual transects. Retreat rates generally were lowest where bedrock outcrops are exposed as the basal unit in the bluff. The highest rates are associated with anthropogenic activities, including jetties that trap littoral sediment, depleting a source of material for the natural replenishment of protective beaches downcoast, and extensive irrigation of farmlands on the tops of the bluffs, which can destabilize bluffs by enhancing ground-water outflow.

Pennsylvania↗
USGS1973

Aeromagnetic discovery of a Baltimore Gneiss dome in the Piedmont of northwestern Delaware and southeastern Pennsylvania

In the central Appalachian Piedmont the “basement complex” is an assemblage of 1,100- to 1,300-m.y.-old gneisses, migmatites, and amphibolites that crops out in “domes” mantled by younger meta-sedimentary rocks of the Glenarm Series. Aeromagnetic data and reconnaissance field work indicate that a previously unknown Baltimore Gneiss dome, here called the Mill Creek dome, is present in southeastern Pennsylvania and northwestern Delaware. The discovery of previously unknown domes of Baltimore Gneiss has bearing on the thickness, structure, and regional relations of the Glenarm Series.

Delaware, Pennsylvania↗
USGS2025

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey↗