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Lunar "dunite", "pyroxenite" and "anorthosite"

Monomineralic aggregates of olivine, clinopyroxene, orthopyroxene and plagioclase with granoblastic textures are widespread minor constituents of Apollo 14 breccias. Recrystallization is commonly incomplete within these aggregates, leaving relict material that clearly indicates single-mineral-grain sources for the aggregates. The aggregates are not, therefore, properly characterized by igneous rock names, nor can any conclusions regarding differentiation be drawn from them. Average sizes of the aggregates indicate source rocks with grain sizes mostly larger than 1 to 5 mm, a few clasts of which occur in the breccias; the proportions of the different types of aggregates suggest dominantly feldspathic source rocks.

Earth and Planetary Science Letters

Revised values for the Gibbs free energy of formation of [Al(OH)4 aq-], diaspore, boehmite and bayerite at 298.15 K and 1 bar, the thermodynamic properties of kaolinite to 800 K and 1 bar, and the heats of solution of several gibbsite samples

Solution calorimetric measurements compared with solubility determinations from the literature for the same samples of gibbsite have provided a direct thermochemical cycle through which the Gibbs free energy of formation of [Al(OH) 4 aq − ] can be determined. The Gibbs free energy of formation of [Al(OH) 4 aq − ] at 298.15 K is −1305 ± 1 kJ/mol. These heat-of-solution results show no significant difference in the thermodynamic properties of gibbsite particles in the range from 50 to 0.05 μm. The Gibbs free energies of formation at 298.15 K and 1 bar pressure of diaspore, boehmite and bayerite are −9210 ± 5.0, −918.4 ± 2.1 and −1153 ± 2 kJ/mol based upon the Gibbs free energy of [A1(OH) 4 aq − ] calculated in this paper and the acceptance of −1582.2 ± 1.3 and −1154.9 ± 1.2 kJ/mol for the Gibbs free energy of formation of corundum and gibbsite, respectively. Values for the Gibbs free energy formation of [Al(OH) 2 aq + ] and [AlO 2 aq − ] were also calculated as −914.2 ± 2.1 and −830.9 ± 2.1 kJ/mol, respectively. The use of [AlC 2 aq − ] as a chemical species is discouraged. A revised Gibbs free energy of formation for [H 4 SiO 4aq 0 ] was recalculated from calorimetric data yielding a value of −1307.5 ± 1.7 kJ/mol which is in good agreement with the results obtained from several solubility studies. Smoothed values for the thermodynamic functions C P 0 , ( H T 0 - H 298 0 ) T "> HT0- H2980)T , ( G T 0 - H 298 0 ) T "> (GT0- H2980)T , S T 0 - S 0 0 , ΔH ƒ,298 0 ">ƒ ΔHƒ,2980 kaolinite are listed at integral temperatures between 298.15 and 800 K. The heat capacity of kaolinite at temperatures between 250 and 800 K may be calculated from the following equation: C P 0 = 1430.26 − 0.78850 T + 3.0340 × 10 −4 T 2 −1.85158 × 10 −4 T 2 1 2 + 8.3341 × 10 6 T −2 "> 12+ 8.3341 × 106T−2 . The thermodynamic properties of most of the geologically important Al-bearing phases have been referenced to the same reference state for Al, namely gibbsite.

Geochimica et Cosmochimica Acta

Statistical analyses of soil properties on a quaternary terrace sequence in the upper sava river valley, Slovenia, Yugoslavia

Alpine glaciations, climatic changes and tectonic movements have created a Quaternary sequence of gravely carbonate sediments in the upper Sava River Valley, Slovenia, Yugoslavia. The names for terraces, assigned in this model, Günz, Mindel, Riss and Würm in order of decreasing age, are used as morphostratigraphic terms. Soil chronosequence on the terraces was examined to evaluate which soil properties are time dependent and can be used to help constrain the ages of glaciofluvial sedimentation. Soil thickness, thickness of Bt horizons, amount and continuity of clay coatings and amount of Fe and Me concretions increase with soil age. The main source of variability consists of solutions of carbonate, leaching of basic cations and acidification of soils, which are time dependent and increase with the age of soils. The second source of variability is the content of organic matter, which is less time dependent, but varies more within soil profiles. Textural changes are significant, presented by solution of carbonate pebbles and sand, and formation is silt loam matrix, which with age becomes finer, with clay loam or clayey texture. The oldest, Günz, terrace shows slight deviation from general progressive trends of changes of soil properties with time. The hypothesis of single versus multiple depositional periods of deposition was tested with one-way analysis of variance (ANOVA) on a staggered, nested hierarchical sampling design on a terrace of largest extent and greatest gravel volume, the Würm terrace. The variability of soil properties is generally higher within subareas than between areas of the terrace, except for the soil thickness. Observed differences in soil thickness between the areas of the terrace could be due to multiple periods of gravel deposition, or to the initial differences of texture of the deposits.

Sava River, Yugoslavia

Lunar nomenclature: A dissenting note

This note reviews the nature of the traditional (Mädler) lunar nomenclature and the recent developments based on the use of more than 2000 named provinces. It appears that the new nomenclature is less efficient than the old in many cases and may lead to an impossible publication situation. The unnecessary break with the past is especially critized.

Icarus

Sedimentary evolution of the Pliocene and Pleistocene Ebro margin, northeastern Spain

The Pliocene and Pleistocene deposits of the Spanish Ebro margin overlie a regional unconformity and contain a major disconformity. These unconformities, named Reflector M and Reflector G, mark the bases of two seismic sequences. Except for close to the upper boundary where a few small channel deposits are recognized, the lower sequence lacks channels. The upper sequence contains nine channel-levee complexes as well as base-of-slope aprons that represent the proximal part of the Valencia turbidite system. Diverse geometries and variations in seismic units distinguish shelf, slope, base-of-slope and basin-floor facies. Four events characterize the late Miocene to Pleistocene evolution of the Ebro margin: (a) formation of a paleodrainage system and an extensive erosion-to-depositional surface during the latest Miocene (Messinian), (b) deposition of hemipelagic units during the early Pliocene, (c) development of canyons during the late Pliocene to early Pleistocene, and (d) deposition of slope wedges, channel-levee complexes, and base-of-slope aprons alternating with hemipelagic deposition during the Pleistocene. Sea-level fluctuations influenced the evolution of the sedimentary sequences of the Ebro margin, but the major control was the sediment supply from the Ebro River.

Marine Geology

Remote sensing data of SP Mountain and SP Lava flow in north-central Arizona

Multifrequency airborne radar image data of SP Mountain [Official name of feature (U.S. Geological Survey, 1970)] and SP flow (and vicinity) in north-central Arizona were obtained in diverse viewing directions and direct and cross-polarization, then compared with surface and aerial photography, LANDSAT multispectral scanner data, airborne thermal infrared imagery, surface geology, and surface roughness statistics. The extremely blocky, basaltic andesite of SP flow is significantly brighter on direct-polarization K-band (0.9-cm wavelength) images than on cross-polarized images taken simultaneously. Conversely, for the longer wavelength (25 cm) L-band radar images, the cross-polarization image returns from SP flow are brighter than the direct-polarized image. This effect is explained by multiple scattering and the strong wavelength dependence of polarization effects caused by the rectilinear basaltic andesite scatters. Two distinct types of surface relief on SP flow, one extremely blocky, the other subdued, are found to be clearly discriminated on the visible and thermal wavelength images but are separable only on the longer wavelength L-band radar image data. The inability of the K- and X- (3-cm wavelength) band radars to portray the differences in roughness between the two SP flow surface units is attributed to the radar frequency dependence of the surface-relief scale, which, described as the Rayleigh criterion, represents the transition between quasispecular and primarily diffuse backscatter.

Arizona

The logic of multispectral classification and mapping of land

The use of multispectral reflectance data as surrogates for land attributes must be done within strict rules of logic and with a recognition of judgmental factors such as the use of a priori or a posteriori classification schemes. The naming and describing of spectral classes as surrogates of information classes is a critical element in the logic of mapping and must be complete and logically consistent. Maps of information classes derived from multispectral data should be portrayed without class boundaries so as to indicate the degree of homogeneity or heterogeneity of classes on maps in which these characteristics are of major importance.

Remote Sensing of Environment

Paleolimnology of Lake Tubutulik, an iron-meromictic Eocene Lake, eastern Seward Peninsula, Alaska

Sideritic lacustrine mudstone was found in drill core from a uranium deposit in the Death Valley area in the eastern part of the Seward Peninsula, Alaska. The precursor sediments for this rock were deposited in an unusual “iron-meromictic” Eocene lake, herein named Lake Tubutulik, which occupied part of the Boulder Creek basin, a structural graben that is probably a southern extension of the larger Death Valley basin. The Boulder Creek basin is bounded on the west by granite of the Late Cretaceous Darby Pluton, on the east by Precambrian to Paleozoic metasedimentary rocks. The lake basin was formed by basaltic flows that dammed the river valley of the ancestral Tubutulik River in early Eocene time. Lake Tubutulik contained a nearshore facies of fine-grained organic mud and an offshore facies of laminated sideritic mud. The offshore (profundal) laminated mudstone consists of alternating layers of authigenic siderite and detrital layers containing mostly quartz and clay minerals. Both lacustrine facies contain turbidities. The lacustrine sediments graded laterally into an onshore facies of colluvial and fluvial sandstone, paludal mudstone, and coal. The ancient lake apparently occupied a small deep basin in a tectonically active area of high relief. Meromixus was probably stabilized by reduced iron and bicarbonate dissolved in the monimolimnion. The intensity of meromixus decreased as the lake became shallower from sediment filling. The source of the iron, abundant in the monimolimnion of Lake Tubutulik, was probably the Eocene basalt. Based on carbon isotope analysis of the siderite, the dissolved bicarbonate in the profundal facies was largely inorganic. Sideritic carbon in one sample from the onshore paludal facies has an isotopic signature ( δ 13 C = +16.9) consistent with residual carbon formed during methanogenic fermentation.

Alaska

Resource data bases-Resource assessment

The U.S. Geological Survey's Office of Resource Analysis is developing computer methods for the handling of mineral-resources data in order to provide improved means for addressing and manipulating data. These methods include: computerized data files and predictive resource models. Data files contain the raw or disaggregated information on mineral deposits and commodities. One operational data file is CRIB (Computerized Resources Information Bank) which is a general purpose inventory and reference file on metallic and nonmetallic mineral deposits. A computer file on resources should contain detailed information on the following main categories: record identification, name and location, description of deposit, analytical data, and production/reserves. A resource model employs postulates and inferences in conjunction with the data to make predictions about resources-as key variables concerning a mineral commodity are changed. The objective is to estimate the availability of minerals including: geological availability (occurrence models), technological availability (exploration and beneficiation models), and economic availability (economics models). ?? 1976.

Computers & Geosciences

A microcomputer program for energy assessment and aggregation using the triangular probability distribution

A general risk-analysis method was developed for petroleum-resource assessment and other applications. The triangular probability distribution is used as a model with an analytic aggregation methodology based on probability theory rather than Monte-Carlo simulation. Among the advantages of the analytic method are its computational speed and flexibility, and the saving of time and cost on a microcomputer. The input into the model consists of a set of components (e.g. geologic provinces) and, for each component, three potential resource estimates: minimum, most likely (mode), and maximum. Assuming a triangular probability distribution, the mean, standard deviation, and seven fractiles (F100, F95, F75, F50, F25, F5, and F0) are computed for each component, where for example, the probability of more than F95 is equal to 0.95. The components are aggregated by combining the means, standard deviations, and respective fractiles under three possible siutations (1) perfect positive correlation, (2) complete independence, and (3) any degree of dependence between these two polar situations. A package of computer programs named the TRIAGG system was written in the Turbo Pascal 4.0 language for performing the analytic probabilistic methodology. The system consists of a program for processing triangular probability distribution assessments and aggregations, and a separate aggregation routine for aggregating aggregations. The user's documentation and program diskette of the TRIAGG system are available from USGS Open File Services. TRIAGG requires an IBM-PC/XT/AT compatible microcomputer with 256kbyte of main memory, MS-DOS 3.1 or later, either two diskette drives or a fixed disk, and a 132 column printer. A graphics adapter and color display are optional. ?? 1991.

Computers & Geosciences

The geology of selected peat-forming environments in temperate and tropical latitudes

We studied peat in several geologic and climatic settings: (1) a glaciated terrain in cold-temperate Maine and Minnesota, U.S.A.; (2) an island in a temperate maritime climate in the Atlantic Ocean off the coast of Maine, U.S.A., where sea level is rising rapidly and changing the environment of peat accumulation; (3) swamps along the warm-temperate U.S. Atlantic and Gulf Coastal Plains, where sea level has changed often, thus creating sites for accumulation; and (4) in a tropical climate along the coast of Sarawak, Malaysia, and the delta of the Batang Hari River, Sumatra, Indonesia (Figs. 1 and 2). With the exception of the deposits on the Atlantic and Gulf Coastal Plains, most of the deposits described are domed bogs in which peat accumulation continued above the surface of the surrounding soil. The bogs of the U.S. Atlantic and Gulf Coastal Plains have almost level surfaces. All domed bogs are not entirely ombrotrophic (watered only from precipitation); multidomed bogs that rise from irregular or hilly surfaces may be crossed by streams that supply water to the bogs. The geologic processes or organic sedimentation, namely terrestrialization and paludification, are similar in all peat deposits considered here. Differences in geomorphology affecting the quantity and that quality of peat that has ash contents of less than 25%, which are desirable for commercial purposes, depend chiefly on: (1) high humidity, which is favorable to luxuriant growth of peat-forming vegetation; (2) a depositional setting that permits extensive accumulation relatively free from inorganic contamination from sea water and streams and from dust and volcanic ash; and (3) a stable regional water table that controls the rate of decomposition under aerobic conditions and protects the deposit against the ravages of fire. Differences in peat textures are due to the type of vegetation and to the degree of decomposition. The rate of decomposition is largely the result of the amount of oxidation and aerobic microbial activity. Stratigraphic distribution of various textures and amounts of inorganic components within a peat deposit is largely determined by the vertical positions occupied by peat-forming environments, such as pond, marsh, swamp and heath where vegetation accumulated, and the depth to zones of unoxygenated water. Peat also differs in the rate of accumulation. On the basis of carbon-14 dating, an estimated 8 m of peat in the tropical Batang Hari River deposit in Sumatra has been accumulating at the rate of about 1.5 m/1,000 yr, whereas peat in the cold-temperate deposit in Maine has been accumulating at the rate of 0.66 m/1,000 yr. Accumulation rates in domed deposits such as these are affected not only by factors controlling volume of biomass and aerobic decay but also by stream erosion and fires that remove peat. Such disconformities (see Fig. 2) within the deposit may be recognized by sudden vertical changes in degree of decomposition and/or the presence of charcoal. The trace-element content of peat deposits is affected by the environments of their settings. Samples of peat that have an ash content of less than 25% dry weight and that are from small, almost level swamp deposits along the Atlantic Coastal Plain of North Carolina were compared with similar samples from small domed bogs in Maine, a glaciated area. Samples from Nort Carolina, which are from deposits in thick fluvial and nearshore marine sediments far from the bedrock source, are generally higher in Ti, Cr and Pb. The Maine samples from deposits in glacial drift close to the bedrock source contain more Zn, Mn, P, Ca, Na and Fe. The kind and amount of trace elements within the deposits appear to relate largely to depositional setting, to kinds of bedrock source, and to the modes of transportation from source to peat swamp. Trace-element concentrations in the extensive Sumatra peat deposit, which represents a potentially commercial coal bed, are similar to those found in Appalachian coals except for As and Au, which are higher in the former. This similarity most likely implies that geochemical controls on mineral matter controlled the concentrations in both. Most peat deposits found in the world today are not precursors of economic coal beds because they are too local in extent, lack beds of commercial-quality peat greater than 6 m thick, and/or are too far from sea level to be rapidly by marine or marginal marine sediments before destruction by erosion and decomposition. However, the two domed deposits in Sarawak and Sumatra described above are parts of extensive, thick, low-sulfur, fuel-quality peat deposits, which have bases below the levels of rivers on coastal deltas. These are likely to be preserved in their lower part and to become precursors of tropical coal seams of potential economic importance. The lenticular and tabular peat deposits of the Atlantic and Gulf Coastal Plains, which have little chance of survival, have features resembling those in Tertiary peat deposits in alluvial settings of western North America. The quality, shape, and extent of modern and ancient peat deposits are controlled by the same factors - humidity, vegetation type, ground- and surface-water regimes, and physiographic and geologic setting. Thus, a study of modern peat deposits may help in studies of the areal distribution and the thickness and quality of ancient coal beds.

International Journal of Coal Geology

Regional and economic geology of Pennsylvanian age coal beds of West Virginia

West Virginia is the only place in the United States where an entire section of Pennsylvanian age (Upper Carboniferous) strata can be seen. These strata occur within a wedge of rock that thins to the north and west from the southeastern part of the State. The progressive north-northwesterly termination of older Pennsylvanian geologic units beneath younger ones prominently outlines the center of the Appalachian basin of West Virginia. Over most of West Virginia, Lower and/or Middle Pennsylvanian strata unconformably overly Upper Mississippian (Lower Carboniferous) strata. Sediment deposition was accomplished by a complex system of deltas prograding north and west from an eastern and southeastern source area. More than 100 named coal beds occur within the Lower, Middle, and Upper Pennsylvanian rocks of West Virginia and at least 60 of these have been or are currently being mined commercially. Collectively, these coal beds account for original in-ground coal resources of almost 106.1×10 9 t (117×10 9 tons). West Virginia ranks fourth in the United States in demonstrated coal reserves. In 1988, West Virginia produced 131.4×10 6 t (144.9×10 6 T) of coal, third highest in the United States. Of this annual production, 75% was from underground mines. In 1988, West Virginia led the nation in the number of longwall mining sections currently in place. West Virginia's low-volatile coal beds are known worldwide as important metallurgical-grade coals, while the higher-volatile coal beds are utilized primarily for steam production.

International Journal of Coal Geology

The glycoprotein genes and gene junctions of the fish rhabdoviruses spring viremia of carp virus and hirame rhabdovirus: Analysis of relationships with other rhabdoviruses

The nucleotide sequences of the glycoprotein genes and all of the internal gene junctions of the fish pathogenic rhabdoviruses spring viremia of carp virus (SVCV) and hirame rhabdovirus (HIRRV) have been determined from cDNA clones generated from viral genomic RNA. The SVCV glycoprotein gene sequence is 1588 nucleotides (nt) long and encodes a 509 amino acid (aa) protein. The HIRRV glycoprotein gene sequence comprises 1612 nt, coding for a 508 aa protein. In sequence comparisons of 15 rhabdovirus glycoproteins, the SVCV glycoprotein gene showed the highest amino acid sequence identity (31.2-33.2%) with vesicular stomatitis New Jersey virus (VSNJV), Chandipura virus (CHPV) and vesicular stomatitis Indiana virus (VSIV). The HIRRV glycoprotein gene showed a very high amino acid sequence identity (74.3%) with the glycoprotein gene of another fish pathogenic rhabdovirus, infectious hematopoietic necrosis virus (IHNV), but no significant similarity with glycoproteins of VSIV or rabies virus (RABV). In phylogenetic analyses SVCV was grouped consistently with VSIV, VSNJV and CHPV in the Vesiculovirus genus of Rhabdoviridae. The fish rhabdoviruses HIRRV, IHNV and viral hemorrhagic septicemia virus (VHSV) showed close relationships with each other, but only very distant relationships with mammalian rhabdoviruses. The gene junctions are highly conserved between SVCV and VSIV, well conserved between IHNV and HIRRV, but not conserved between HIRRV/IHNV and RABV. Based on the combined results we suggest that the fish lyssa-type rhabdoviruses HIRRV, IHNV and VHSV may be grouped in their own genus within the family Rhabdoviridae. Aquarhabdovirus has been proposed for the name of this new genus.

Virus Research

Catastrophic eruptions of the directed-blast type at Mount St. Helens, Bezymianny and Shiveluch volcanoes

This paper describes catastrophic eruptions of Mount St. Helens (1980), Bezymianny (1955–1956), and Shiveluch (1964) volcanoes. A detailed description of eruption stages and their products, as well as the quantitative characteristics of the eruptive process are given. The eruptions under study belong to the directed-blast type. This type is characterized by the catastrophic character of the climatic stage during which a directed blast, accompanied by edifice destruction, the profound ejection of juvenile pyroclastics and the formation of pyroclastic flows, occur. The climatic stage of all three eruptions has similar characteristics, such as duration, kinetic energy of blast (10 17 −10 18 J), the initial velocity of debris ejection, morphology and size of newly-formed craters. But there are also certain differences. At Mount St. Helens the directed blast was preceeded by failure of the edifice and these events produced separable deposits, namely debris avalanche and directed blast deposits which are composed of different materials and have different volumes, thickness and distribution. At Bezymianny, failure did not precede the blast and the whole mass of debris of the old edifice was outburst only by blast. The resulting deposits, represented by the directed blast agglomerate and sand facies, have characteristics of both the debris avalanche and the blast deposit at Mount St. Helens. At Shiveluch directed-blast deposits are represented only by the directed-blast agglomerate; the directed-blast sand facies, or blast proper, seen at Mount St. Helens is absent. During the period of Plinian activity, the total volumes of juvenile material erupted at Mount St. Helens and at Besymianny were roughly comparable and exceeded the volume of juvenile material erupted at Shiveluch, However, the volume of pyroclastic-flow deposits erupted at Mount St. Helens was much less. The heat energy of all three eruptions is comparable: 1.3 × 10 18 , 3.8−4.8 × 10 18 and 1 × 10 17 J for Shiveluch, Bezymianny, and Mount St. Helens, respectively.

Journal of Geodynamics

A 7 year record of above-ground net primary production in a southeastern Mexican mangrove forest

Spatial and temporal variations in net above-ground primary production (NPP) and litter turnover rate were studied, from 1987 to 1993, in a mangrove forest bordering Laguna de Terminos, Mexico. NPP, the sum of total litter fall and wood production, was measured over the entire study period in three zones in a basin forest: zone I, where Rhizophora mangle (red mangrove) occurs but Avicennia germinans (black mangrove) is the dominant species; zone II, a scrub forest of A. germinans ; zone III, where larger A. germinans trees occur. In 1991, a fringe zone dominated by A. germinans and R. mangle was added to the study. Three distinctive climatic seasons occur in the region: rainy, dry, and cold front (locally named ‘nortes’). Average total litter fall in the fringe zone (793 g m −2 year −1 ) was significantly higher than in the basin forest (496, 307, and 410 g m −2 year −1 for basin zones I, II, and III, respectively). All zones showed significant differences among seasons with the norte season having significantly lower litter fall. Litter turnover rates were about 7 months in zones I and II and 10 months in zone III, reflecting the low tidal range that occurs in the basin forest. Low litter turnover rates in the basin forest were reflected in a high organic matter standing crop. Annual average stem growth was significantly higher in zones I and III (1.27 and 1.36 kg per tree year −1 , respectively) than in zone II (0.62 kg per tree year −1 ). Above-ground NPP rates in the basin forest (399–695 g m −2 year −1 ) were lower than in fringe and riverine forests, reflecting patterns of litter fall and wood production. There was no seasonal variation in soil salinity but the basin forest had significantly higher soil salinity than the fringe forest. Spatially, mean soil salinity was inversely related to litter fall. Long-term patterns in soil salinity, precipitation and air temperature explained 74% of the inter-annual litter fall variability. Over the 7 year study, productivity in zone II was more variable than in zones I and III, and productivity (litter fall and wood growth) were less variable than litter standing crop and turnover.

Campeche

Geochemical soil sampling for deeply-buried mineralized breccia pipes, northwestern Arizona

Thousands of solution-collapse breccia pipes crop out in the canyons and on the plateaus of northwestern Arizona; some host high-grade uranium deposits. The mineralized pipes are enriched in Ag, As, Ba, Co, Cu, Mo, Ni, Pb, Sb, Se, V and Zn. These breccia pipes formed as sedimentary strata collapsed into solution caverns within the underlying Mississippian Redwall Limestone. A typical pipe is approximately 100 m (300 ft) in diameter and extends upward from the Redwall Limestone as much as 1000 m (3000 ft). Unmineralized gypsum and limestone collapses rooted in the Lower Permian Kaibab Limestone or Toroweap Formation also occur throughout this area. Hence, development of geochemical tools that can distinguish these unmineralized collapse structures, as well as unmineralized breccia pipes, from mineralized breccia pipes could significantly reduce drilling costs for these orebodies commonly buried 300–360 m (1000–1200 ft) below the plateau surface. Design and interpretation of soil sampling surveys over breccia pipes are plagued with several complications. (1) The plateau-capping Kaibab Limestone and Moenkopi Formation are made up of diverse lithologies. Thus, because different breccia pipes are capped by different lithologies, each pipe needs to be treated as a separate geochemical survey with its own background samples. (2) Ascertaining true background is difficult because of uncertainties in locations of poorly-exposed collapse cones and ring fracture zones that surround the pipes. Soil geochemical surveys were completed on 50 collapse structures, three of which are known mineralized breccia pipes. Each collapse structure was treated as an independent geochemical survey. Geochemical data from each collapse feature were plotted on single-element geochemical maps and processed by multivariate factor analysis. To contrast the results between geochemical surveys (collapse structures), a means of quantifying the anomalousness of elements at each site was developed. This degree of anomalousness, named the “correlation value”, was used to rank collapse features by their potential to overlie a deeply-buried mineralized breccia pipe. Soil geochemical results from the three mineralized breccia pipes (the only three of the 50 that had previously been drilled) show that: (1) Soils above the SBF pipe contain significant enrichment of Ag, Al, As, Ba, Ga, K, La, Mo, Nd, Ni, Pb, Sc, Th, U and Zn, and depletion in Ca, Mg and Sr, in contrast to soils outside the topographic and structural rim; (2) Soils over the inner treeless zone of the Canyon pipe show Mo and Pb enrichment anf As and Ga depletion, in contrast to soils from the surrounding forest; and (3) The soil survey of the Mohawk Canyon pipe was a failure because of the rocky terrane and lack of a B soil horizon, or because the pipe plunges. At least 11 of the 47 other collapse structures studied contain anomalous soil enrichments similar to the SBF uranium ore-bearing pipe, and thus have good potential as exploration targets for uranium. One of these 11, #1102, does contain surface mineralized rock. These surveys suggest that soil geochemical sampling is a useful tool for the recognition of many collapse structures with underlying ore-bearing breccia pipes.

Arizona

Estimates of ion sources in deciduous and coniferous throughfall

Estimates of external and internal sources of ions in net througfall deposition were derived for a deciduous and coniferous canopy by use of multiple regression. The external source component appears to be dominated by dry deposition of Ca 2+ , SO 2 and NO 3 − during dormant and growing seasons for the two canopy types. Increases in the leaching rates of K + and Mg 2+ during the growing season reflect the presence of leaves in the deciduous canopy and increased physiological activity in both canopies. Internal leaching rates for SO 4 2− doubled during the growing season presumably caused by increased physiological activity and uptake of SO 2 through stomates. Net deposition of SO 4 2− in throughfall during the growing season appears highly dependent on stomatal uptake of SO 2 . Estimates of SO 2 deposition velocities were 0.06 cm s −1 and 0.13 cm s −1 for the deciduous and coniferous canopies, respectively, during the dormant seasons, and 0.30 cm s −1 and 0.43 cm s −1 for the deciduous and coniferous canopies, respectively, during the growing season. For the ions of major interest with respect to ecosystem effects, namely H + , NO 3 − and SO 4 2− , precipitation inputs generally outweighed estimates of dry deposition input. However, net throughfall deposition of NO 3 − and SO 4 2− accounted for 20–47 and 34–50 per cent, respectively, of total deposition of those ions. Error estimates of ion sources were at least 50–100 per cent and the method is subject to several assumptions and limitations.

Virginia

Program to prepare standard figures for grade-tonnage models on a Macintosh

Grade-tonnage models are frequency distributions of deposit tonnage and grades of mineral deposits of a specific type. The program described here allows users to prepare standard figures of grade and tonnage distributions and display the deposit name associated with any of the data points. Titles and scales appropriate for most deposit types are plotted automatically for tonnage, Cu, Ni, Sn, Nb, W, Au, Hg, Mo, Zn, Pb, Ag, Co, Pt, Pd, Sb, Fe, Cr, Mn, and Ba.

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