Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Minerals and the Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 505 records · Page 28Linked to original sources
USGS2006

Beyond the obvious limits of ore deposits: The use of mineralogical, geochemical, and biological features for the remote detection of mineralization

Far field features of ore deposits include mineralogical, geochemical, or biological attributes that can be recognized beyond the obvious limits of the deposits. They can be primary, if formed in association with mineralization or alteration processes, or secondary, if formed from the interaction of ore deposits with the hydrosphere and biosphere. This paper examines a variety of far field features of different ore deposit types and considers novel applications to exploration and discovery. Primary far field features include mineral and rock chemistry, isotopic or element halos, fluid pathways and thermal anomalies in host-rock sequences. Examples include the use of apatite chemistry to distinguish intrusive rocks permissive for iron oxide copper gold (IOCG) and porphyry deposits; resistate mineral (e.g., rutile, tourmaline) chemistry in exploration for volcanogenic massive sulfide (VMS), orogenic gold, and porphyry deposits; and pyrite chemistry to vector toward sedimentary exhalative (sedex) deposits. Distinctive whole-rock geochemical signatures also can be recognized as a far field feature of porphyry deposits. For example, unique Sr/Y ratios in whole-rock samples, used to distinguish barren versus fertile magmas for Cu mineralization, result from the differentiation of oxidized hydrous melts. Anomalous concentrations of halogen elements (Cl, Br, and I) have been found for distances of up to 200 m away from some mineralized centers. Variations in isotopic composition between ore-bearing and barren intrusions and/or systematic vertical and lateral zonation in sulfur, carbon, or oxygen isotope values have been documented for some deposit types. Owing to the thermal aureole that extends beyond the area of mineralization for some deposits, detection of paleothermal effects through methods such as conodont alteration indices, vitrinite or bitumen reflectance, illite crystallinity, and apatite or zircon thermochronology studies also can be valuable, particularly for deposits with a low-temperature thermal history. A number of newly investigated secondary far field features include the development of reduced columns by electrochemical processes in transported overburden, geochemical dispersion related to the expulsion of groundwater from tectonic and seismic compression, dispersion of vapor above ore deposits, and geochemical dispersion related to biological processes. Redox gradients have been found between underlying reduced and overlying oxidized environments associated with sulfide bodies, which result in mass transfer through electro-chemical dispersion. Recent studies have characterized the pH, oxidation-reduction potential (ORP), and self potential (SP) in overburden overlying sulfide-hosted gold and VMS deposits. Lateral migration of metals in groundwater is well understood from normal groundwater flow, but the processes responsible for vertical mass transfer of groundwater and its dissolved components have been recognized only recently. One process, termed cyclical dilatancy pumping, expels groundwater during and after earthquake events, which can cause the redistribution of metals around deposits in some environments. Soil gases are of interest owing to their high degree of mobility through the vadose zone in transported overburden. Numerous soil gas species (CO2, O2, Hg, Rn, He, sulfur compounds, and light hydrocarbons) have been measured and interpreted as diagnostic of some buried mineral deposits, and some evidence suggests a possible link between vapor dispersion and metal enrichment in soil. Geochemical enrichment in plant material and soils through successive growth-death cycles is well established, but the important role of microorganisms is now increasingly evident. Microorganisms significantly enhance the kinetics of sulfide oxidation and influence the distribution of metals around ore deposits. The presence of metal-resistant bacteria and enhanced concentrations of sulfate-reducing bacteria in exotic overburd

Economic Geology↗
USGS2016

A microbial arsenic cycle in sediments of an acidic mine impoundment: Herman Pit, Clear Lake, California

The involvement of prokaryotes in the redox reactions of arsenic occurring between its +5 [arsenate; As(V)] and +3 [arsenite; As(III)] oxidation states has been well established. Most research to date has focused upon circum-neutral pH environments (e.g., freshwater or estuarine sediments) or arsenic-rich “extreme” environments like hot springs and soda lakes. In contrast, relatively little work has been conducted in acidic environments. With this in mind we conducted experiments with sediments taken from the Herman Pit, an acid mine drainage impoundment of a former mercury (cinnabar) mine. Due to the large adsorptive capacity of the abundant Fe(III)-rich minerals, we were unable to initially detect in solution either As(V) or As(III) added to the aqueous phase of live sediment slurries or autoclaved controls, although the former consumed added electron donors (i.e., lactate, acetate, hydrogen), while the latter did not. This prompted us to conduct further experiments with diluted slurries using the live materials from the first incubation as inoculum. In these experiments we observed reduction of As(V) to As(III) under anoxic conditions and reduction rates were enhanced by addition of electron donors. We also observed oxidation of As(III) to As(V) in oxic slurries as well as in anoxic slurries amended with nitrate. We noted an acid-tolerant trend for sediment slurries in the cases of As(III) oxidation (aerobic and anaerobic) as well as for anaerobic As(V) reduction. These observations indicate the presence of a viable microbial arsenic redox cycle in the sediments of this extreme environment, a result reinforced by the successful amplification of arsenic functional genes ( aioA , and arrA ) from these materials.

California↗
USGS2008

Understanding contaminants associated with mineral deposits

Interdisciplinary studies by the U.S. Geological Survey (USGS) have resulted in substantial progress in understanding the processes that control the release of metals and acidic water from inactive mines and mineralized areas, the transport of metals and acidic water to streams, and the fate and effect of metals and acidity on downstream ecosystems. The potential environmental effects associated with abandoned and inactive mines, resulting from the complex interaction of a variety of chemical and physical processes, is an area of study that is important to the USGS Mineral Resources Program. Understanding the processes contributing to the environmental effects of abandoned and inactive mines is also of interest to a wide range of stakeholders, including both those responsible for managing lands with historically mined areas and those responsible for anticipating environmental consequences of future mining operations. The recently completed (2007) USGS project entitled 'Process Studies of Contaminants Associated with Mineral Deposits' focused on abandoned and inactive mines and mineralized areas in the Rocky Mountains of Montana, Colorado, New Mexico, Utah, and Arizona, where there are thousands of abandoned mines. Results from these studies provide new information that advances our understanding of the physical and biogeochemical processes causing the mobilization, transport, reaction, and fate of potentially toxic elements (including aluminum, arsenic, cadmium, copper, iron, lead, and zinc) in mineralized near-surface systems and their effects on aquatic and riparian habitat. These interdisciplinary studies provide the basis for scientific decisionmaking and remedial action by local, State, and Federal agencies charged with minimizing the effects of potentially toxic elements on the environment. Current (2007) USGS research highlights the need to understand (1) the geologic sources of metals and acidity and the geochemical reactions that release them from their sources, (2) the pathways that facilitate transport from those sources, and (3) the processes that control the fate of the elements once released from the sources. Experts in the fields of economic geology, structural geology, mineralogy, geophysics, geochemistry, hydrology, ground-water modeling, microbiology, and toxicology came together for a series of studies that address these relationships on scales ranging from the microscopic to the watershed. This Circular presents results and highlights from the detailed, interdisciplinary studies that include investigations in both mining-affected areas and mineralized but unmined areas. The first section of the Circular describes laboratory and site-scale field investigations that primarily focus on mineralogic and biologic controls on the source and release of metals and acidity from mine-waste rock and hydrothermally altered areas. The second section describes a set of basin- to watershed-scale studies that not only investigate the source and release of metals and acidity but also the transport of these constituents away from the source areas. The third section is a summary of results from postremediation ecosystem monitoring. For more information on these and other project-related studies, please visit the project Web site at http://minerals.cr.usgs.gov/projects/contaminants/index.html. The Web site includes a complete bibliography and detailed descriptions of each interdisciplinary study.

Circular↗
USGS1996

Record of middle Pleistocene climate change from Buck Lake, Cascade Range, southern Oregon - Evidence from sediment magnetism, trace-element geochemistry, and pollen

Comparison of systematic variations in sediment magnetic properties to changes in pollen assemblages in middle Pleistocene lake sediments from Buck Lake indicates that the magnetic properties are sensitive to changes in climate. Buck Lake is located in southern Oregon just east of the crest of the Cascade Range. Lacustrine sediments, from 5.2 to 19.4 m in depth in core, contain tephra layers with ages of ≈300–400 ka at 9.5 m and ≈400–470 ka at 19.9 m. In these sediments magnetic properties reflect the absolute amount and relative abundances of detrital Fe-oxide minerals, titanomagnetite and hematite. The lacustrine section is divided into four zones on the basis of magnetic properties. Two zones (19.4–17.4 m and 14.5–10.3 m) of high magnetic susceptibility contain abundant Fe oxides and correspond closely to pollen zones that are indicative of cold, dry environments. Two low-susceptibility zones (17.4–14.5 m and 10.3–5.3 m) contain lesser amounts of Fe oxides and largely coincide with zones of warm-climate pollen. Transitions from cold to warm climate based on pollen are preceded by sharp changes in magnetic properties. This relation suggests that land-surface processes responded to these climate changes more rapidly than did changes in vegetation as indicated by pollen frequencies. Magnetic properties have been affected by three factors: (1) dissolution of Fe oxides, (2) variation in heavy-mineral content, and (3) variation in abundance of fresh volcanic rock fragments. Trace-element geochemistry, employing Fe and the immobile elements Ti and Zr, is utilized to detect postdepositional dissolution of magnetic minerals that has affected the magnitude of magnetic properties with little effect on the pattern of magnetic-property variation. Comparison of Ti and Zr values, proxies for heavy-mineral content, to magnetic properties demonstrates that part of the variation in the amount of magnetite and nearly all of the variation in the amount of hematite are due to changes in heavy-mineral content. Variation in the quantity of fresh volcanic rock fragments is the other source of change in magnetite content. Magnetic-property variations probably arise primarily from changes in peak runoff. At low to moderate flows magnetic properties reflect only the quantities of heavy minerals derived from soil and highly weathered rock in the catchment. At high flows, however, fresh volcanic rock fragments may be produced by breaking of pebbles and cobbles, and such fragments greatly increase the magnetite content of the resulting sediment. Climatically controlled factors that would affect peak runoff levels include the accumulation and subsequent melting of winter snow pack, the seasonality of precipitation, and the degree of vegetation cover of the land surface. Our results do not distinguish among the possible contributions of these disparate factors.

Oregon↗
USGS1990

Relationships among macerals, minerals, miospores and paleoecology in a column of Redstone coal (Upper Pennsylvanian) from north-central West Virginia (U.S.A.)

Two distinct paleoenvironments are represented in vertical succession in a column of Redstone coal in north-central West Virginia as indicated by a study of 37 consecutive 3-cm (0.1 ft) increments analyzed for ash yield, petrographic composition, low-temperature ash mineralogy and palynomorph abundances. Abundance profiles were constructed for ash, 12 petrographic components, 3 minerals and 5 miospore assemblages. The profiles and calculated correlation coefficients show close relationships between several constituents. Components that increased in abundance upward in the coal bed were a collinite type > 50 microns in thickness, cutinite, and miospores affiliated with calamites, herbaceous lycopods, cordaites and herbaceous ferns. Components that decreased in abundance upward were a collinite type < 50 microns in thickness, inertodetrinite, tree fern miospores, quartz, illite and ash yield. Components were correlated with ash yield to infer the swamp geochemical conditions that contributed to the low-ash (7%) upper one-third of the coal bed and the higher-ash (16%) lower two-thirds of the coal bed. Components that correlate positively with increased ash were the collinite type < 50 μ m thickness, inertodetrinite, tree fern miospores, illite and quartz. Components that correlate negatively with increased ash were the collinite type > 50 μ m in thickness, cutinite, calamite and cordaite miospores and kaolinite. Significant correlations occurred between ash yield and the collinite types > 50 and < 50 μ m in thickness but no significant correlation was found between ash yield and total vitrinite-group content. This is interpreted to show that division of vitrinite macerals by size is important in petrographic paleoenvironmental studies. Paleoecologic interpretations based upon these correlations suggest that two distinct, planar, probably topogenous paleoecologic environments are represented in this column of the Redstone coal. The lower two-thirds of the coal bed was interpreted to have accumulated in a planar swamp in which significant introduction of detrital or dissolved mineral matter, and significant anaerobic and moderate oxidative degradation of the peat occurred. The flora of this paleoenvironment was dominated by tree ferns. The paleoenvironment during accumulation of the upper one-third of the coal bed was also interpreted to have been a planar swamp, but one in which moderate to low introduction of detrital or dissolved mineral matter, and minor anaerobic and oxidative degradation of the peat occurred. The dominant flora of this paleoenvironment consisted mainly of calamites with fewer cordaites and herbaceous ferns. This study shows that valuable paleoecologic information may be obtained by sampling closely spaced vertical increments. No mixing of detrital sediments with the peat was observed in coal layers immediately adjacent to the parting or the overlying sandstone unit.

International Journal of Coal Geology↗
USGS2004

Uranium mill tailings: Nuclear waste and natural laboratory for geochemical and radioecological investigations

Uranium mill tailings (UMT) are a high volume, low specific activity radioactive waste typically disposed in surface impoundments. This review focuses on research on UMT and related earth materials during the past decade relevant to the assessment of: (1) mineral hosts of radionuclides; (2) the use of soil analogs in predicting long-term fate of radionuclides; (3) microbial and diagenetic processes that may alter radionuclide mobility in the surficial environment; (4) waste-management technologies to limit radionuclide migration; and (5) the impact of UMT on biota.

Journal of Environmental Radioactivity↗
USGS1999

Design approaches in quarrying and pit-mining reclamation

Reclaimed mine sites have been evaluated so that the public, industry, and land planners may recognize there are innovative designs available for consideration and use. People tend to see cropland, range, and road cuts as a necessary part of their everyday life, not as disturbed areas despite their high visibility. Mining also generates a disturbed landscape, unfortunately one that many consider waste until reclaimed by human beings. The development of mining provides an economic base and use of a natural resource to improve the quality of human life. Equally important is a sensitivity to the geologic origin and natural pattern of the land. Wisely shaping out environment requires a design plan and product that responds to a site's physiography, ecology, function, artistic form, and publication perception. An examination of selected sites for their landscape design suggested nine approaches for mining reclamation. The oldest design approach around is nature itself. Humans may sometimes do more damage going to an area in the attempt to repair it. Given enough geologic time, a small-site area, and stable adjacent ecosystems, disturbed areas recover without mankind's input. Visual screens and buffer zones conceal the facility in a camouflage approach. Typically, earth berms, fences, and plantings are used to disguise the mining facility. Restoration targets social or economic benefits by reusing the site for public amenities, most often in urban centers with large populations. A mitigation approach attempts to protect the environment and return mined areas to use with scientific input. The reuse of cement, building rubble, macadam meets only about 10% of the demand from aggregate. Recognizing the limited supply of mineral resources and encouraging recycling efforts are steps are steps in a renewable resource approach. An educative design approach effectively communicates mining information through outreach, land stewardship, and community service. Mine sites used for art show a celebration of beauty and experience -- abstract geology. The last design approach combines art and science in a human-nature ecosystem termed integration. With environmental concerns, an operating or reclaimed mine site can no longer be considered isolated from its surroundings. Site analysis of mine works needs to go beyond site-specific information and relate to the regional context of the greater landscape. Understanding design approach can turn undesirable features (mines and pits) into something perceived as desirable by the public.

Book↗
USGS2016

Marine phosphorites as potential resources for heavy rare earth elements and yttrium

Marine phosphorites are known to concentrate rare earth elements and yttrium (REY) during early diagenetic formation. Much of the REY data available are decades old and incomplete, and there has not been a systematic study of REY distributions in marine phosphorite deposits that formed over a range of oceanic environments. Consequently, we initiated this study to determine if marine phosphorite deposits found in the global ocean host REY concentrations of high enough grade to be of economic interest. This paper addresses continental-margin (CM) and open-ocean seamount phosphorites. All 75 samples analyzed are composed predominantly of carbonate fluorapatite and minor detrital and authigenic minerals. CM phosphorites have low total REY contents (mean 161 ppm) and high heavy REY (HREY) complements (mean 49%), while seamount phosphorites have 4–6 times higher individual REY contents (except for Ce, which is subequal; mean ΣREY 727 ppm), and very high HREY complements (mean 60%). The predominant causes of higher concentrations and larger HREY complements in seamount phosphorites compared to CM phosphorites are age, changes in seawater REY concentrations over time, water depth of formation, changes in pH and complexing ligands, and differences in organic carbon content in the depositional environments. Potential ore deposits with high HREY complements, like the marine phosphorites analyzed here, could help supply the HREY needed for high-tech and green-tech applications without creating an oversupply of the LREY.

Minerals↗
USGS2023

Earth’s mantle composition revealed by mantle plumes

Mantle plumes originate at depths near the core−mantle boundary (~2,800 km). As such, they provide invaluable information about the composition of the deep mantle and insight into convection, crustal formation, and crustal recycling, as well as global heat and volatile budgets. In this Review, we discuss the effectiveness and challenges of using isotopic analyses of plume-generated rocks to infer mantle composition and to constrain geodynamic models. Isotopic analyses of plume-derived ocean island basalts, including radiogenic (Sr, Nd, Pb, Hf, W, noble gas) and stable isotopes (Li, C, O, S, Fe, Tl), permit determination of mantle plume composition, which in turn generate insight into mantle plume origins, dynamics, mantle heterogeneities, early-formed mantle reservoirs, crustal recycling processes, core−mantle interactions and mantle evolution. Nevertheless, the magmatic flux, temperature, tectonic environment and compositions of mantle plumes can vary. Consequently, plumes and their melts are best evaluated along a spectrum that acknowledges their different properties, particularly mantle flux, before making interpretations about the interior of the Earth. To provide insight into specific mantle and plume processes, future work should document correlations across elemental and isotopic data sets on the same sample powder, coordinate targeting sampling strategies, and refine stable isotopic fractionation factors through experiments. Such work will benefit from collaboration across geochemical laboratories, as well as among geochemists, mineral physicists, seismologists and geodynamicists.

Nature Reviews in Earth and Environment↗
USGS1986

Maps and interpretation of geochemical anomalies, Chuckwalla Mountains Wilderness Study Area, Riverside County, California

In March 1982, as part of the mineral resource investigations of the area, the U.S. Geological Survey conducted a reconnaissance geochemical survey of the Chuckwalla Mountains Wilderness Study Area (WSA), Riverside County, California. The survey involved collecting 196 heavy-mineral (panned) concentrates from stream sediment (the basis for these maps and the chief basis for the interpretations), the same number of sieved stream-sediment samples, and 25 samples of fresh, altered, or mineralized rocks. A broad regional geochemical framework for mineral resource evaluation was established by sampling a few miles beyond the boundaries of the WSA to include all of the Chuckwalla and Little Chuckwalla Mountains. These geochemical maps are therefore regional maps but of sufficient detail to allow valid conclusions about geochemical anomalies in the WSA. The geochemical data were evaluated in three phases: (1) determining enrichment above background amounts for ore-forming and pathfinder (ore-associated) elements; (2) determining the dispersion patterns of the anomalous elements; and (3) relating the dispersion patterns to geologic environments favorable to ore deposition. This report discusses and interprets geochemical results as they are seen at the reconnaissance stage. Analytical results for all samples collected are released in a U.S. Geological Survey Open-File Report (Adrian and others, 1985). A statistical summary of the data from heavy-mineral concentrates and sieved stream sediments is shown in table 1. The analytical results for selected elements in rock samples are shown in table 2.

California↗
USGS2007

Unique microbial community in drilling fluids from Chinese continental scientific drilling

Circulating drilling fluid is often regarded as a contamination source in investigations of subsurface microbiology. However, it also provides an opportunity to sample geological fluids at depth and to study contained microbial communities. During our study of deep subsurface microbiology of the Chinese Continental Scientific Deep drilling project, we collected 6 drilling fluid samples from a borehole from 2290 to 3350 m below the land surface. Microbial communities in these samples were characterized with cultivation-dependent and -independent techniques. Characterization of 16S rRNA genes indicated that the bacterial clone sequences related to Firmicutes became progressively dominant with increasing depth. Most sequences were related to anaerobic, thermophilic, halophilic or alkaliphilic bacteria. These habitats were consistent with the measured geochemical characteristics of the drilling fluids that have incorporated geological fluids and partly reflected the in-situ conditions. Several clone types were closely related to Thermoanaerobacter ethanolicus, Caldicellulosiruptor lactoaceticus , and Anaerobranca gottschalkii , an anaerobic metal-reducer, an extreme thermophile, and an anaerobic chemoorganotroph, respectively, with an optimal growth temperature of 50–68°C. Seven anaerobic, thermophilic Fe(III)-reducing bacterial isolates were obtained and they were capable of reducing iron oxide and clay minerals to produce siderite, vivianite, and illite. The archaeal diversity was low. Most archaeal sequences were not related to any known cultivated species, but rather to environmental clone sequences recovered from subsurface environments. We infer that the detected microbes were derived from geological fluids at depth and their growth habitats reflected the deep subsurface conditions. These findings have important implications for microbial survival and their ecological functions in the deep subsurface.

Geomicrobiology Journal↗
USGS1987

Methods for geochemical analysis

The laboratories for analytical chemistry within the Geologic Division of the U.S. Geological Survey are administered by the Office of Mineral Resources. The laboratory analysts provide analytical support to those programs of the Geologic Division that require chemical information and conduct basic research in analytical and geochemical areas vital to the furtherance of Division program goals. Laboratories for research and geochemical analysis are maintained at the three major centers in Reston, Virginia, Denver, Colorado, and Menlo Park, California. The Division has an expertise in a broad spectrum of analytical techniques, and the analytical research is designed to advance the state of the art of existing techniques and to develop new methods of analysis in response to special problems in geochemical analysis. The geochemical research and analytical results are applied to the solution of fundamental geochemical problems relating to the origin of mineral deposits and fossil fuels, as well as to studies relating to the distribution of elements in varied geologic systems, the mechanisms by which they are transported, and their impact on the environment.

Bulletin↗
USGS2019

Tectono-magmatic evolution of porphyry belts in the central Tethys region of Turkey, the Caucasus, Iran, western Pakistan, and southern Afghanistan

Exploration in the central Tethys region of Turkey, Armenia, Azerbaijan, Georgia, Iran, and weste rn Pakistan has led to the identification of the giant Reko Diq (24 Mt Cu and 1300 t Au), Sar Cheshmeh (8.9 Mt Cu and 0.46 Mt Mo), Sungun (5.1 Mt Cu and 0.20 Mt Mo), and Kadjaran (4.6 Mt Cu, 0.94 Mt Mo, and 1100 t Au), and 10 other large (1–2 Mt Cu) porphyry deposits including Saindak, Cevizlidere, Teghout, Meiduk, and Halilağa. Continued exploration efforts have also resulted in the development of porphyry-related gold deposits such as Kişladağ (9.6 Moz Au), Çöpler (3.7 Moz Au), Aği Daği (1.7 Moz Au), and Sary Gunay (3.0 Moz Au), and in the generation of several other promising exploration projects. The distribution in space and time of porphyry deposits in the central Tethys region was shaped by complex pre- to post-mineral tectonic, igneous, collisional, uplift and burial events. These events are represented by a partially-overlapping and variably exhumed and covered collage of twenty-six Early Jurassic to Holocene magmatic belts permissive for the occurrence of porphyry deposits (porphyry tracts and sub-tracts). Twelve tracts or sub-tracts are characterized by compressional continental arcs that formed on drifting terranes or continental margins, 10 developed in compressional to extensional intra-oceanic arc and backarc-rift settings, and 4 formed in extensional post-collisional environments over amalgamated terranes. Eight of these belts were variably affected by coeval and younger metamorphic, fold-and-thrust, and extensional faulting events. Fifty-four porphyry Au-(Cu), Cu-Au, Cu-Mo, Mo-Cu deposits, 15 porphyry-related Au, Au-(Mo) and W-(Mo-Au) deposits, 239 porphyry prospects, and 68 other porphyry-related mineral sites were identified in the study region. Of the 376 porphyry and porphyry-related sites, about 11% formed in island arc, 42% in continental arc, 20% in backarc, and 27% in post-collisional settings. Of the 69 porphyry and porphyry-related deposits, 7% developed in intra-oceanic arc, 41% in continental arc, 27% in backarc, and 25% in post-collisional settings. The largest occur in either compressional continental arc (18 deposits including the Reko Diq and Sar Cheshmeh giants) or post-collisional (13 deposits including the Kadjaran and Sungun giants) environments. Ninety percent of the largest porphyry or porphyry-related deposits occur in only 9 of the 26 permissive porphyry tracts or sub-tracts. Moreover, 88, 90, and 77% of the identified Cu, Mo, and Au resources are contained in porphyry deposits that occur in only 4 of these 9 tracts. Of these 4 tracts, 3 outline arc settings, and one delimits a post-collisional environment. The compositional diversity of porphyry intrusions in these tectono-magmatic environments generally varies from island arc settings with the most restricted range (partly alkaline but mainly calc-alkaline dioritic to granodioritic-tonalitic), to continental arc (calc-alkaline dioritic-quartz dioritic, granodioritic, quartz monzonitic-granitic, and less commonly mildly alkaline), to backarc (mildly alkaline and calc-alkaline dioritic to granitic), to post-collisional settings with the most expansive range (alkaline and calc-alkaline mafic to felsic, and weakly peraluminous). Metal associations also vary broadly as a function of porphyry intrusion composition from weakly peraluminous to metaluminous felsic (Mo[±W ± Cu]; <2% of porphyry-related systems [i.e., Tyrnyauz]), to metaluminous felsic and intermediate (Cu-Mo[±Au]; 85% [i.e., Cevizlidere, Haft Cheshmeh, Kahang, Sar Cheshmeh, Sungun, Teghout, Reko Diq, Saindak]), to mildly alkaline felsic and intermediate (Cu-Au[±Mo] [i.e., Agarak, Kadjaran, Kale Kafi]) and mafic (Au-Cu; 12% [i.e., Çöpler]), and to alkaline felsic (Au-Mo; 1% of porphyry-related systems [i.e., Kişladağ). Tectonic changes were critical in triggering the formation of large porphyry deposits in the region. Large porphyry deposits were preferentially emplaced in continental arc settings shortly before major collisional events (Dar Alu, Kahang, Meiduk, Now Chun, and the giant Sar Cheshmeh and Reko Diq deposits), or in post-subduction environments shortly after collision (Bakirçay, Güzelyayla, Haft Cheshmeh, Masjed Daghi, and the giant Kadjaran and Sungun deposits) or during periods of prominent extension (Aği Daği, Halilağa, Kişladağ, Sari Gunay, and Zarshuran porphyry-related deposits). Collision-induced uplift, erosion, and removal of coeval volcanic rocks favorably exposed the hypabyssal level of subduction-related porphyry deposits. Extensional structures that developed parallel and orthogonal to the compressional principal stress component along transtensional or transpressional strike-slip faults or in pull-apart basins commonly controlled porphyry-related deposits in post-collisional settings. The latter deposits typically exhibit shallow epithermal levels of emplacement because of preservation by burial. Seventeen porphyry deposits and one porphyry-related deposit in the study region are reported to contain significant supergene resources. Relatively mature levels of secondary copper enrichment in dominantly granodioritic to granitic porphyry deposits occur in areas where large pyrite-rich quartz-sericite alteration zones have been preserved and exposed to surface oxidation (Güzelyayla and Ulutaş in northeastern Turkey; Agarak, Ankavan, Dastakert, Kadjaran, and Teghout in Armenia; Ali Javad in northern Iran; Kale Kafi in central Iran; Darreh Zar, Meiduk, Now Chun, and Sar Cheshmeh in southeastern Iran; and Tanjeel in southwestern Pakistan). Chalcocite blankets also developed over porphyry deposits in regions where significant post-mineral faulting has occurred (Muratdere and Sarıçayıryayla in western Turkey). Normal faulting also enhanced secondary enrichment of gold in the Halilağa porphyry and Sary Gunay porphyry-related deposits located respectively in western Turkey and northern Iran. Evaluation of provincial as well as local controls strongly suggests that continued exploration in the region will lead to the identification of additional porphyry and porphyry-related deposits. These deposits will likely be found under younger cover formations in porphyry belts that are already known, and in association with superjacent high- and intermediate-sulfidation epithermal deposits, or increasingly peripheral skarn, carbonate-replacement, and sediment-hosted deposits. Application of suitable exploration techniques to detect concealed and/or deformed deposits in porphyry belts that remain under-explored may also prove productive.

Tethys region↗
USGS1968

Environment of ore deposition at the Mex-Tex deposits, Hansonburg District, New Mexico, from studies of fluid inclusions

These deposits , in Pennsylvanian limestone and shale, contain barite, fluorite, low-silver galena with "J-type" lead, and quartz, and only minor amounts of other minerals. Mineralization occurs in veins, in blankets of bedded, rhythmically banded "coontail" ore , and in vuggy, coarsely crystalline open-space fillings in tectonic and solution channels in limestone adjacent to faults. Except for widespread silicification, the mineralization is very similar to that of the southern Illinois deposits . The main stages of hypogene mineralization are: 1) sphalerite, pyrite, galena and chalcopyrite; 2) five easily recognizable substages of fluorite with intermittent quartz and barite; and 3) late calcite.More than 500 primary and 2,500 pseudosecondary inclusions , mainly from fluorite, were studied on the freezing and heating microscope stages. Some primary inclusions contain organic matter. Gross supercooling indicates slow ore - fluid movement. Recognizable planes of pseudo-secondaries (each containing 20-200 inclusions ) yield data essentially identical with coeval primaries, but the few planes of presumed secondaries do not.The first three substages of fluorite formed from fluids that were essentially constant in temperature at 186°-205° C (assumed pressure correction +10° C), but increased in salinity from aproximately 10 up to 15 weight percent salts. Succeeding substages formed at gradually decreasing temperatures (to about 140° C) and increasing salinity (maximum 17%), with breaks marking several individual substages. A few inclusions in an early barite have anomalously low homogenization temperatures. Coarse selenite has primary inclusions full of fresh water and hence is presumed to be supergene.These data do not prove any given theory or origin for the fluids or the deposits , but they do place some limits on possible mechanisms of origin.

New Mexico↗
USGS1990

National Coastal Geology Program: a plan of geologic research on coastal erosion, coastal wetlands, polluted sediments, and coastal hard-mineral resources

More than 50 percent of the U.S. population currently live within 50 miles of an ocean, Great Lake, or major estuary. According to forecasts, the concentration of people along our coastlines will continue to increase into the 21st century. In addition to residential and commercial buildings and facilities worth tens of billions of dollars, the coasts and associated wetlands are natural resources of tremendous value, with estimates in excess of $13 billion per year for commercial and recreational fisheries alone. Human activities and natural processes are stressing the coastal environment. * Each of the coastal states and island territories is suffering problems related to coastal erosion. * Deterioration of wetlands is widespread and of great public concern. * Pollutants carried by rivers or runoff are discharged directly into coastal waters and accumulate in the sediments on the sea floor, in some areas causing damage to living resources and presenting a threat to public health. * Onshore sources for hard-mineral resources, such as sand and gravel used for construction purposes, are becoming increasingly difficult to find. New sources are being sought in coastal waters. Coastal issues will become even more important into the next century if sea level is significantly influenced by climate change and other factors.

Monograph↗
USGS2021

The trajectory of soil development and its relationship to soil carbon dynamics

It has been postulated that the amount of soil organic carbon (SOC) associated with soil minerals exhibits a threshold relationship in response to effective soil moisture (estimated as precipitation less evapotranspiration). To better characterize the role of moisture in influencing mechanisms of SOC storage during pedogenesis, we compare soils from two different chronosequence sites: the Santa Cruz and Mattole River marine terraces that together form a soil age-by-climate gradient (i.e., climo-chronosequence). Our results demonstrate how variation in the effective soil moisture may drive soil development along divergent pedogenic trajectories, resulting in variations in the form and depth distribution of secondary weathering products. In particular, the residual metals Fe and Al are directly related to the type of secondary minerals that accumulate during weathering, and these variations are coupled to differences in the storage and long-term preservation of SOC both within and between soils. Over time, these differences in soil development may lead to ‘pedogenic thresholds’ that further differentiate soil characteristics and influence SOC dynamics. In this case, the pedogenic threshold takes the form of clay-rich argillic horizons that once formed, inhibit aqueous transport, decouple shallow and deep soil environments, and potentially limit SOC inputs and increase microbial recycling in deep soils. Our data suggest argillic horizon development is favorable in the drier Santa Cruz soils, where kaolinite is the dominant secondary weathering product. In contrast, greater available moisture in soils of the Mattole chronosequence drive a different weathering trajectory characterized by the accumulation of more amorphous secondary minerals. As a result, the Mattole soils and do not exhibit argillic horizon development but are instead characterized by greater accumulation of SOC across all depths sampled. Overall, our results illustrate how the interaction of climate (i.e., moisture) and time may shape the trajectory of soil development and the dynamics of SOC storage and preservation.

California↗
USGS2015

Long-term anoxia and release of ancient, labile carbon upon thaw of Pleistocene permafrost

The fate of permafrost carbon upon thaw will drive feedbacks to climate warming. Here we consider the character and context of dissolved organic carbon (DOC) in yedoma permafrost cores from up to 20 m depth in central Alaska. We observed high DOC concentrations (4 to 129 mM) and consistent low molecular weight organic acid concentrations in three cores. We estimate a DOC production rate of 12 µmol DOC m −2 yr −1 based on model ages of up to ~200 kyr derived from uranium isotopes. Acetate C accounted for 24 ± 1% of DOC in all samples. This proportion suggests long-term anaerobiosis and is likely to influence thaw outcomes due to biolability of acetate upon release in many environments. The combination of uranium isotopes, ammonium concentrations, and calcium concentrations explained 86% of the variation in thaw water DOC concentrations, suggesting that DOC production may be related to both reducing conditions and mineral dissolution over time.

Geophysical Research Letters↗
USGS2026

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas↗