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Methods for estimating magnitude and frequency of 1-, 3-, 7-, 15-, and 30-day flood-duration flows in Arizona

Large floods have historically caused extensive damage in Arizona. Although peak-flow frequency estimates are required for managing the risk posed by floods, estimates of the frequency of sustained flood flow (flood-duration flow) are also useful for planning and assessing the adequacy of retention and conveyance structures and for water-resource planning. This report presents a flood-duration flow frequency analysis for selected durations (1 day, 3 day, 7 day, 15 day, and 30 day) at 173 streamgaging stations throughout Arizona and in western New Mexico. For each n -day duration, a log-Pearson type III distribution was fitted to the annual series of n -day flood-duration flows using the expected moments algorithm with a multiple Grubbs-Beck low-outlier test. Regional skews were developed independently for each n -day duration using a hybrid weighted least squares/generalized least squares method. No basin characteristics were found to adequately explain variation in skew among stations and a constant statewide skew model was used for all n -day durations. The regional skewness coefficient is negative for all n -day durations and becomes increasingly negative for longer n -day durations. Uncertainty associated with the skewness coefficient is estimated using a Bayesian generalized least squares technique. Regression equations, which allow predictions of n -day flood-duration flows for selected annual exceedance probabilities at ungaged sites, were developed using generalized least-squares regression and flood-duration flow frequency estimates at 56 streamgaging stations within a single, relatively uniform physiographic region in the central part of Arizona, between the Colorado Plateau and Basin and Range Province, called the Transition Zone. Drainage area explained most of the variation in the n -day flood-duration annual exceedance probabilities, but mean annual precipitation and mean elevation were also significant variables in the regression models. Standard error of prediction for the regression equations varies from 28 to 53 percent and generally decreases with increasing n -day duration. Outside the Transition Zone there are insufficient streamgaging stations to develop regression equations, but flood-duration flow frequency estimates are presented at select streamgaging stations.

Arizona

Methods for estimating magnitude and frequency of floods in Arizona, developed with unregulated and rural peak-flow data through water year 2010

Flooding is among the worst natural disasters responsible for loss of life and property in Arizona, underscoring the importance of accurate estimation of flood magnitude for proper structural design and floodplain mapping. Twenty-four years of additional peak-flow data have been recorded since the last comprehensive regional flood frequency analysis conducted in Arizona. Periodically, flood frequency estimates and regional regression equations must be revised to maintain the accurate estimation of flood frequency and magnitude. Annual peak-flow data collected through water year 2010 were compiled from 448 unregulated streamflow-gaging stations, hereafter referred to as streamgages, in Arizona having a minimum of 10 years of record. Flood frequency estimates were first computed with station (or at-site) skew using the Expected Moments Algorithm with a multiple Grubbs-Beck test to identify multiple potentially influential low flows to fit a Pearson Type III distribution. Next, a multiple step Bayesian least-squares-regression approach was used to determine a new statewide regional skew of −0.09. No basin characteristics analyzed were statistically significant in explaining the variation in skew and as a result, the constant model was chosen as the best regional skew model for the Arizona study area. The mean square error used in Bulletin 17B (B17B) of the Interagency Advisory Committee on Water Data is used to describe the precision of the regional skew. The constant model had a mean square error equal to 0.08, which corresponds to an effective record length of 85 years. This is a marked improvement over a previous Arizona regional skew analysis, with a reported mean square error of 0.31, for a corresponding effective record length of around 17 years. Thus the new regional model had almost five times the information content (as measured by effective record length) of that calculated in USGS Water Supply Paper 2433, published in 1997, or the value of 0.302 reported in the B17B generalized skew map. The flood frequency estimates were recalculated using a weighted skew of the station and regional skew. Station flood frequency estimates for each streamgage are presented for the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities. Geographical information systems were used to compute basin characteristic information for each streamgage for the purpose of developing regional equations to estimate flood statistics at ungaged basins. Five hydrologic flood regions in Arizona were defined in a multivariate regionalization process based on mean basin elevation, mean annual precipitation, and soil permeability. A regional generalized least-squares-regression analysis was used to develop five sets of equations from 344 nonredundant streamgages, corresponding to five regions, for estimating the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities at ungaged basins in Arizona. The regression equations developed for these five regions were based on one or more of the statistically significant explanatory variables: drainage area, mean basin elevation, and mean annual precipitation. Average standard errors of prediction for the regression regions for the five regions ranged from 27 to 122 percent and the pseudo-coefficients of determination (pseudo-R 2 ), a measure of the proportion of peak-flow variation that is explained by the basin characteristics, ranged from 68 to 98 percent. Regression equations for Central Highlands (region 4) had the lowest model error and the greatest pseudo-R 2 metrics. The equations for Colorado Plateau (region 2) regression equations generally had greater model error and lower pseudo-R 2 metrics. The improvement of regional regression equation model error and pseudo-R 2 metrics was related to higher numbers of streamgages, longer period of record, and even spatial coverage within a region. The regional regression equations were integrated into the U.S. Geological Survey’s StreamStats program. The StreamStats program is a national map-based web application that allows the public to easily access published flood frequency and basin characteristic statistics. The interactive web application allows a user to select a point within a watershed (gaged or ungaged) and retrieve flood-frequency estimates derived from the current regional regression equations and geographic information system data within the selected basin. StreamStats provides users with an efficient and accurate means for retrieving the most up to date flood frequency and basin characteristic data. StreamStats is intended to provide consistent statistics, minimize user error, and reduce the need for large datasets and costly geographic information system software.

Arizona

Characterization of Big Chino subbasin hydrogeology near Paulden, Arizona, using controlled source audio-frequency magnetotelluric surveys

The Big Chino subbasin is located in central-northwest Arizona in the transition zone between the Colorado Plateau and the Basin and Range Province. The controlled source audio-frequency magnetotelluric (CSAMT) geophysical method, a low-impact, non-intrusive, electrical resistance sounding technique, was used to evaluate the subsurface hydrogeology of the southern third of the Big Chino subbasin. The Big Chino subbasin is a northwest-trending, late Tertiary graben bordered by the Big Chino Fault along its northeast flank where there is as much as 1,100 meters of displacement. The main water-bearing stratigraphic unit of the basin is Tertiary alluvial-fill sediment. The Devonian Martin Formation provides water to wells near Drake and the Mississippian Redwall Limestone provides water to wells east of the basin and in the Paulden area. The purpose of the CSAMT surveys was to improve the conceptual model of the aquifer by constraining the basin geometry and identifying stratigraphic units and their subsurface extents. CSAMT methods were used to map the subsurface along 100 kilometers (62 miles) of survey lines across the southern third of the subbasin. Of 21 survey lines, 14 were west of the town of Paulden and another 7 were east of Paulden. Data were cleaned and prepared for entry into Zonge SCS2D software and then inverted to provide a two-dimensional resistivity profile for each survey line. Final inversion models representing the best fit to measured data were compared to driller’s logs or borehole data where present. Data from the CSAMT lines west and north of Paulden are consistent with thicker alluvial basin deposits that range from 100 meters thick to a few hundred meters thick. Data from the CSAMT lines east of Paulden are consistent with thinner alluvial and basalt deposits overlying Paleozoic Martin Formation and Redwall Limestone, Tapeats Sandstone, and Precambrian granite and schist.

Arizona

Carnotite resources in the Charles T. area and vicinity, San Miguel County, Colorado

Between November 1947 and September 1949, the United States Geological Survey, at the request of the Atomic Energy Commission, conducted an exploratory drilling program in the Charles T. area and vicinity. The purpose of the exploration was to discover new carnotite deposits to support milling operations on the Colorado Plateau, and to appraise the uranium and vanadium resources of the area explored.

Colorado

Carnotite resources of Club Mesa, Montrose County, Colorado

Club Mesa is 1 mile west of Uravan, Montrose County, Colo. About 200,000 short tons of carnotite ore containing an estimated 0.45 percent U 3 O 8 and 2.1 percent V 2 O 5 has been mined from the mesa. This production represents about one-fifth of the carnotite ore mined from the Colorado Plateau. All the principal deposits on the mesa are in the main ore-bearing sandstone which is in the top part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are in tabular masses of uneven thickness lying more or less parallel to the enclosing strata. The ore consists mainly of sandstone impregnated with carnotite and vanadiferous clay minerals. The sandstone near the deposits is generally over 30 feet in thickness, contains noticeable quantities of carbon, and vivid patches of limonite (?) stain. Also near ore deposits, the mudstone in contact with the sandstone is altered from red to gray or green through a thickness of 3 or 4 feet. Certain linear features of the ore bodies and of favorable parts of the main ore-bearing sandstone offer clues by their orientation to extensions of known ore bodies and of favorable ground. These features on Club Mesa trend mostly east to northeast. Between March 6, 1948, and January 22, 1952, the U.S. Geological Survey drilled 651 holes for a total of 167,495 feet. As a result of this drilling, 18 deposits were discovered and partly outlined. These range in size from 200 to 55,000 short tons of indicated ore reserves and are in layers 1 foot or more thick containing 0.10 percent or more U 3 O 8 or 1.0 percent or more V 2 O 5 . About 85 percent of this ore is in public land; the remainder is in claims owned by the United States Vanadium Co. Reserves in deposits known from drill holes or exposures are classed as indicated or inferred, and those in deposits that are predicted solely on geologic evidence are classed as potential. The tons of indicated and inferred reserves and the pounds of contained U 3 O 8 and V 2 O 5 are summarized in table 1. These reserves are subdivided also by thickness and grade cutoffs. At the higher grade cutoff, reserve figures express approximately the tonnage and grade of material that might actually be mined from these deposits under 1951 conditions. Indicated and inferred reserves of this type total 198,000 short tons, averaging 0.35 percent U 3 O 8 and 1.8 percent V 2 O 5, and contain 1,1,372,000 pounds of U 3 O 8 and 7,260,000 pounds of V 2 O 5. These reserves are based on Geological Survey drilling. Potential reserves are predicted to total about 40,000 short tons, averaging about 0.35 percent U 3 O 8 and 1.9 percent V 2 O 5 . No additional exploration on Club Mesa is planned by the Geological Survey, but exploration by private companies is recommended.

Colorado

Present and past ground-water conditions in the Morrison Formation in southwestern Colorado and southeastern Utah

Field and laboratory studies of ground-water conditions in the carnotite-bearing Morrison formation in southwestern Colorado and southeastern Utah were undertaken to determine possible relations between ground waters and the carnotite deposits. The ore-bearing sandstone consists of lenticular sandstone strata, interbedded within discontinuous layers of mudstone; these strata were deposited in a stream environment. The porosity and permeability of the ore-bearing sandstone in one area are relatively low, porosity averaging about 15 percent and permeability ranging between 30 and 3300 millidarcys. Permeability studies in this same area show that sandstone classed as favorable for ore is slightly more permeable than and has nearly twice the transmissibility of sandstone classed as semifavorable; outcrop studies also suggest a lower transmissibility for sandstone that is unfavorable. Samples of water from the ore-bearing and associated strata show considerable variation in chemical charter. These water samples are generally low in uranium, vanadium, copper, and lead, most samples containing less than 1 part per million (ppm) of each metal. General geologic relations suggest that ground-water movement probably was active through the ore-bearing strata during their deposition and shortly afterward. Movement during this time probably occurred largely through the more permeable sand strata and in the general direction of initial dip and stream flow. During Cretaceous time, when several thousand feet of marine sediments accumulated over the Morrison, the water contained in the ore-bearing strata probably was immobile or nearly so and was protected from escape or contamination. Following Tertiary deformation and erosion, active ground-water circulation no doubt was restored, but because of the low permeability and the lenticular character and therefore low transmissibility of the ore-bearing sandstone, ground-water movement probably was slow. Faulting probably also influenced the direction and rate of ground-water movement during Tertiary time. Movement and localization of ground water would permit the concentration of metal-bearing solutions during Salt Wash and early Brushy Basin time in the beds that now contain ore deposits. It is more difficult to explain the formation of these deposits, which have a wide geographic distribution at a restricted stratigraphic position, from solutions circulating through the rocks at a later date. Whatever mode of origin is used to explain the deposits, geologists almost without exception, agree that the metals were transported by solutions that have migrated through the sediments for considerable distances. For this reason, a study of the horizontal and vertical transmissibility characteristics of all exposed sedimentary formations on the Colorado Plateau is planned.

Colorado, Utah

Search for uranium in western United States

The search for uranium in the United States is one of the most intensive ever made for any metal during our history. The number of prospectors and miners involved is difficult to estimate but some measure of the size of the effort is indicated by the fact that about 500 geologists are employed by government and industry in the work--more than the total number of geologists engaged in the study of all other minerals together except oil. The largest part of the effort has been concentrated in the western states. No single deposit of major importance by world standards has been discovered but the search has led to the discovery of important minable deposits of carnotite and related minerals on the Colorado Plateau; of large, low grade deposits of uranium in phosphates in the northwestern states and in lignites in the Dakotas, Wyoming, Idaho and New Mexico; and of many new and some promising occurrences of uranium in carnotite-like deposits and in vein deposits. Despite the fact that a large number of the districts considered favorable for the occurrence of uranium have already been examined, the outlook for future discoveries is bright, particularly for uranium in vein and in carnotite-like deposits in the Rocky Mountain States.

Trace Elements Investigations

Present investigations of radioactive raw materials by the Geological Survey and a recommended program for future work

The Geological Survey's program of investigation of radioactive raw materials is presented herewith under present investigations, plans for future investigations, plan of operation, and cost of operation. This report was prepared at the request of the Atomic Energy Commission. Present investigations are summarized to show the scope of the present Trace Elements program, grouping individual projects into related types of investigations. Plans for future investigations on an expanded scale are outlined. These should provide sufficient data and knowledge of the occurrence and availability of uranium, thorium, and related elements, to permit a more complete evaluation of domestic resources. Reconnaissance projects are designed to discover possible new sources of uranium and thorium and to select areas and materials warranting further investigation. Typical projects leading to the estimation of reserves are the investigation of the carnotite ores of the Colorado Plateau by geologic mapping, exploratory drilling, and related research, and investigation of asphaltic sandstone in Emery County, Utah. Extensive research will be undertaken to establish the principles governing the geological and geochemical relations of uranium, thorium, and associated elements as an essential guide in appraising domestic resources. Particular emphasis will be placed on phosphatic rocks and black shales which offer ultimate resources of uranium far greater than carnotite ores. All the foregoing investigations will be accompanied by chemical, gephysical, and mineralogical research and analytical work. Under plan of operation is discussed the organization of the Trace Elements Unit, space requirements for laboratory and office, the scheduling of investigations, and other related problems. The proposed scheduling of work calls for approximately 109, 173, and 203 man years in fiscal years 1948, 1949, and 1950 respectively. Definite plans have been formulated only for the next three fiscal years, by which time it is assumed the program will reach stable proportions or can be altered as experience dictates. Under cost of operation is set forth the funds available in fiscal year 1947, the status of funds transferred from Atomic Services (14-217/80920), and funds necessary in succeeding fiscal years. The estimate for fiscal year 1948 inclues a non-recurring item of $1,025,000 for establishing adequate laboratories for chemical, physical, spectrographic and mineralogic research and analytical work. The total funds required in fiscal years 1948, 1949, and 1950 to support the proposed program will be $2,440,000, $2,161,000 and $2,198,000 respectively. The Geological survey anticipates contributing from its appropriation in fiscal years 1948, 1949 and 1950 approximately $243,000, $350,000, and $400,000 respectively; the balance of the necessary funds to be contributed by the Atomic Energy Commission in fiscal years 1948, 1949, and 1950 will be approximately $2,196,900, $1,811,000, and $1,798,000 respectively.

Trace Elements Investigations

Uranium deposits at Shinarump Mesa and some adjacent areas in the Temple Mountain district, Emery County, Utah

Deposits of uraniferous hydrocarbons are associated with carnotite in the Shinarump conglomerate of Triassic age at Shinarump Mesa and adjacent areas of the Temple Mountain district in the San Rafael Swell of Emery County, Utah. The irregular ore bodies of carnotite-bearing sandstone are genetically related to lenticular uraniferous ore bodies containing disseminated asphaltitic and humic hydrocarbon in permeable sandstones and were localized indirectly by sedimentary controls. Nearly non-uraniferous bitumen commonly permeates the sandstones in the Shinarump conglomerate and the underlying Moekopi formation in the area. The ore deposits at Temple Mountain have been altered locally by hydrothermal solutions, and in other deposits throughout the area carnotite has been transported by ground and surface water. Uraniferous asphaltite is thought to be the non-volatile residue of an original weakly uraniferous crude oil that migrated into the San Rafael anticline; the ore metals concentrated in the asphaltite as the oil was devolatilized and polymerized. Carnotite is thought to have formed from the asphaltite by ground water leaching. It is concluded that additional study of the genesis of the asphaltitic uranium ores in the San Rafael Swell, of the processes by which the hydrocarbons interact and are modified (such as heat, polymerization, and hydrogenation under the influence of alpha-ray bombardment), of petroleum source beds, and of volcanic intrusive rocks of Tertiary age are of fundamental importance in the continuing study of the uranium deposits on the Colorado Plateau.

Utah

Duttonite, a new quadrivalent vanadium oxide from the Peanut mine, Montrose County, Colorado

Duttonite, a new quadrivalent vanadium oxide from the Peanut mine, Montrose County, Colo., has the formula VO(OH) 2 . The mineral occurs as crusts and coatings of pale-brown transparent platy crystals, as one of the first oxidation products of montroseite ore. It is associated with melanovanadite and abundant crystals of hexagonal native selenium. Duttonite is biaxial positive, 2V is about 60°, dispersion is r < v , moderate; X = a , pale pinkish brown; Y = c , pale yellow-brown; Z = b , pale brown; α = 1.810 ± 0.003, β = 1.900 ± 0.003, γ > 2.01. The hardness is about 2.5; the calculated specific gravity is 3.24. The chemical analysis shows, in percent: V 2 o 3 2.6, V 2 O 4 75.3, FeO 0.4, H 2 O 18.1, insoluble 4.2, total 100.6. Duttonite is monoclinic, a o = 8.80 ± 0.02A, b o - 3.95 ± 0.01A, c o - 5.96 ± 0.02A, β = 90°40 1 ± 5 1 . The space group is I 2/ c , ( C 6 2 h ); the cell contents are 4[VO(OH) 2 ]. The crystals are strongly pseudo-orthorhombic, and the structure departs only slightly from the space group Imcm . Duttonite is named for Captain Clarence Edward Dutton (1841-1912). A detailed study of the geology, geochemistry, and mineralogy of the vanadium-uranium ore at the Peanut mine, Montrose County, Colo., was begun early in 1954 by Carl H. Roach of the U. S. Geological Survey. A number of rare and new minerals were found in the ore and the study of these samples was undertaken by Mary E. Thompson. Duttonite is the first new vanadium mineral to be described from the Peanut mine. It is named for Captain Clarence Edward Dutton (1841-1912), who was one of the first geologists to work in the Colorado Plateau region and who was a member of the U. s. Geological Survey from 1879-91. We are indebted to the following members of the Geological Surbey: K. E. Valentine for spectrographic analyses of duttonite, and M. E. Mrose and H. T. Evans, Jr., for measurement of the unit cell constants. This work is part of a program being conducted by the U. S. Geological Survey on behalf of the Division of Raw Materials of the U. S. Atomic Energy Commission.

Colorado

Oxidation potential and state of some vanadium ores and the relation of woody material to their deposition

Oxidation potential studies with a multiple pH-potential recorder designed and constructed for this purpose demonstrated that some uranium-vanadium ores in the Colorado Plateau were in a reduced state when deposited. Any oxidation which took place occurred after deposition. Experimental and theoretical reducing studies on fresh wood, wood degraded by burial for 450 years, and lignite, indicate that such ores may have been deposited by reduction of oxidized vanadium solutions by woody material. A vanadium (III) mineral, V 2 O(OH) 4 , was prepared synthetically by reduction of a vanadium (V) solution with wood. This is the only reported synthesis of any reduced vanadium mineral by any method. It was shown that the origin of almost all vanadium deposits currently of commercial importance involves life processes and products.

Utah

Electrical properties of sandstones of the Morrison Formation

The electrical properties of the Morrison formation in the Uravan mineral belt of the Colorado Plateau have been studied to determine if there are anomalous variations in these properties in and near zones of uranium-vanadium minerals which might serve as a target for geophysical prospecting. Measurements of electrical properties of the Morrison formation in place were obtained by the electric logging of 147 drill holes, and measurements were made of the resistivity and porosity of 440 drill cores in the laboratory to aid in the interpretation of the electric logs. The resistivity of the sandstone members of the Morrison formation is highest in areas that are most favorable for the occurrence of ore. This increase in resistivity is probably due to a lower water saturation or a lower salinity of the water in the favorable areas.

Colorado;Utah

Areal geology of the Little Cone quadrangle, Colorado

The Little Cone quadrangle includes an area of about 59 square miles in eastern San Miguel County in southwestern Colorado. It lies within and adjacent to the northeastern boundary of the Colorado Plateau physiographic province. The precipitous front of the San Juan Mountains lies a few miles to the east and northeast, and an outlier of the San Juans, the San Miguel Mountains, lies about a mile to the south. The quadrangle contains features characteristic of both the plateaus and the mountains, and has been affected by geologic events and processes of two different geologic environments.

Colorado

Botanical prospecting for uranium in the Circle Cliffs area, Garfield County, Utah

Astragalus pattersoni and Stanleya pinnata broadly define some uraniferous localities adjacent to the contact of the Moenkopi formation and the Shinarump member of the Chinle formation, but the general paucity of Astragalus in the Circle Cliffs area limits the usefulness of this genus. Astragalus pattersoni , Stanleya pinnata , and Aster venustus (?) may serve as guides to mineralized parts of the Salt Wash sandstone member of the Morrison formation in the Circle Cliffs area. Thick and thin sandstones of the Shinarump member generally can be distinguished by pinyon-juniper ration studies. These studies may supplement drilling to define channel-fill sandstones which are associated with ore deposits in the Circle Cliffs area. Ratio studies appear to be applicable to other areas throughout the Colorado Plateau where similar geological and ecological conditions exist.

Utah

Comparison of thickness, grade, and depth of radioactive layers as determined by gamma-ray logging and by core sampling

Thickness, grade, and depth data were obtained by analyzing gamma-ray logs and core samples from 56 diamond drill holes penetrating uranium deposits in the Colorado Plateau. The data from the two methods were compared to determine variations found in gamma-ray log interpretation and chemical and radiometric analyses of the drill core. Correlations within each parameter varied among the drilling areas analyzed. Gamma-ray interpretations of grade compared to chemical analyses were within the range of -10 to +25 percent. Most depth measurements determined by gamma-ray log interpretation compared to drill core measurement were within 0.5 percent. Results of the study indicate a need for better thickness definition in both gamma-ray logging and core scanning equipment.

Trace Elements Investigations

Detailed mineral and chemical relations in two uranium-vanadium ores

Channel samples from two mines on the Colorado Plateau have been studied in detail both mineralogically and chemically. A channel sample from the Mineral Joe No. 1 mine, Montrose County, Colo., extends from unmineralized rock on one side, through a zone of variable mineralization, into only weakly mineralized rock. The unmineralized rock is a fairly clean quartz sand cemented with gypsum and contains only minor amounts of clay minerals. One boundary between unmineralized and mineralized rock is quite sharo and is nearly at right angles to the bedding. Vanadium clay minerals, chiefly mixed layered mica-montmorillonite and chlorite-monmorillonite, are abundant throughout the mineralized zone. Except in the dark "eye" of the channel sample, the vanadium clay minerals are accompanied by hewettite, carnotite, tyuyamunite, and probably unidentified vanadates. In the dark "eye," paramontroseite, pyrite, and marcasite are abundant, and bordered on each side by a zone containing abundant corvusite. No recognizable uranium minerals were seen in the paramontroseite zone although uranium is abundant there. Coaly material is recognizable throughout all of the channel but is most abundant in and near the dark "eye." Detailed chemical studies show a general increase in Fe, Al, U, and V, and a decrease in SO 4 toward the "eye" of the channel. Reducing capacity studies indicate that V(IV) and Fe(II) are present in the clay mineral throughout the channel, but only in and near the "eye" are other V(IV) minerals present (paramontroseite and corvusite). The uranium is sexivalent, although its state of combination is conjectural where it is associated with paramontroseite. Where the ore boundary is sharp, the boundary of introduced trace elements is equally sharp. Textural and chemical relations leave no doubt that the "eye: is a partially oxidized remnant of a former lower-valence ore, and the remainder of the channel is a much more fully oxidized remnant. A channel sample from the Virgin No. 3 mine, Montrose County, Colo., extends from weakly mineralized sandstone on both sides through a strongly mineralized central zone. The weakly mineralized zone is a poorly sorted sandstone with common detrital clay partings; chlorite and mixed layer mica-montmorrillonite are abundant interstitial to the quartz grains. No distinct vanadium or uranium minerals are recognizable, although the clay minerals are vanadium bearing. Euherdral pyrite grains and selenian galena are present but rare. The strongly mineralized rock is separated from the weakly mineralized rock by a narrow transition zone which only apporiximates the bedding planes. It contains abundant vanadium-bearing clay minerals (predominantly chlorite) interstitial to the quartz grains, and apparently replacing them. Paramontroseite is common and is intergrown with the clay minerals. Pyrite and marcasite are present, chiefly in or near the abundant blebs and fragments of carbonaceous material. Selenian galena is rarely present, and generally in or near carbonaceous material. Coffinite is the only uranium mineral idenitified; it is extremely fine grained and was identified only in X-ray diffraction patterns of heavy separates. Distribution of trace elements is not clear; some are consistently high in the strongly mineralized rocks, and some are consistently low. The trace element composition of the unmineralized rock is not known. Chemical studies show a very abrupt rise in the total U, V, and Fe from the weakly mineralized to strongly mineralized rock. Reducing-capacity studies indicate that most of the vanadium is present as V(IV), but some is present as V(V); that iron is present as both Fe(II) and Fe(III), the latter believed to have been present in the primary clays of the unmineralized rock; and that come of the uranium is present as U(VI) in addition to the U(IV) in the coffinite. All evidence points to weak oxidation of an ore once having a somewhat lower valence state. The channel samples from both the Mineral Joe No. 1 mine and the Virgin No. 3 mine are believe to have been essentially identical in mineralogy prior to oxidation by weathering: vanadium was present as V(III) in montroseite and V(IV) in the vanadium clays; uranium was present largely as U(IV) in coffinite and/or uraninite. The Mineral Joe No. 1 mine channel sample is now more fully oxidized. Vanadium clays are unquestionably formed abundantly during the primary mineralization, and they persist with a minimum of alteration during much of the weathering. They suggest that the vanadium is carried as V(IV) in the ore-forming fluids; it seems likely too that the uranium is carried as a U(VI) ion.

Trace Elements Investigations

Preliminary statement of the analyses of ground water from the Morrison Formation, southwestern Colorado and southeastern Utah

As part of a study of the carnotite deposits of the Colorado Plateau,, samples of ground water from the Salt Wash sandstone and Brushy Basin shale members of the Morrison formation have been analyzed to determine their chemical character and metal content. The Salt Wash ground water is largely a bicarbonate solution with variable amounts of calcium and magnesium ions; that from the Brushy Basin is either a sulfate or bicarbonate solution with sodium, The ground water from the Salt Wash and Brushy Basin members is generally weakly alkaline In most samples, the metal ions of uranium, vanadium, copper, lead, and selenium are present in amounts of less than 1 part per million. It is concluded that if the ground water responsible for introduction of the uranium and vanadium metals into the Salt Wash was comparable to the recent ground water, it contained very small amounts of the metal ions.

Colorado;Utah