Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Chemistry”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 505 records · Page 28Linked to original sources
USGS2002

Chemistry of selected high-elevation lakes in seven national parks in the western United States

A chemical survey of 69 high-altitude lakes in seven national parks in the western United States was conducted during the fallof 1999; the lakes were previously sampled during the fall of 1985, as part of the Western Lake Survey. Lakes in parks in the Sierra/southern Cascades (Lassen Volcanic, Yosemite, Sequoia/Kings Canyon National Parks) and in the southern RockyMountains (Rocky Mountain National Park) were very dilute; medianspecific conductance ranged from 4.4 to 12.2 μS cm -1 andmedian alkalinity concentrations ranged from 32.2 to 72.9 μeqL -1 . Specific conductances and alkalinity concentrations were substantially higher in lakes in the central and northernRocky Mountains parks (Grand Teton, Yellowstone, and GlacierNational Parks), probably due to the prevalence of more reactivebedrock types. Regional patterns in lake concentrations of NO 3 and SO 4 were similar to regional patterns in NO 3 and SO 4 concentrations in precipitation, suggestingthat the lakes are showing a response to atmospheric deposition.Concentrations of NO 3 were particularly high in Rocky Mountain National Park, where some ecosystems appear to be undergoing nitrogen saturation.

Water, Air, and Soil Pollution: Focus↗
USGS2004

Hydrologic variability, water chemistry, and phytoplankton biomass in a large flood plain of the Sacramento River, CA, U.S.A.

The Yolo Bypass, a large, managed floodplain that discharges to the headwaters of the San Francisco Estuary, was studied before, during, and after a single, month-long inundation by the Sacramento River in winter and spring 2000. The primary objective was to identify hydrologic conditions and other factors that enhance production of phytoplankton biomass in the floodplain waters. Recent reductions in phytoplankton have limited secondary production in the river and estuary, and increased phytoplankton biomass is a restoration objective for this system. Chlorophyll a was used as a measure of phytoplankton biomass in this study. Chlorophyll a concentrations were low (<4 μg l −1 ) during inundation by the river when flow through the floodplain was high, but concentrations rapidly increased as river inflow decreased and the floodplain drained. Therefore, hydrologic conditions in the weeks following inundation by river inflow appeared most important for producing phytoplankton biomass in the floodplain. Discharges from local streams were important sources of water to the floodplain before and after inundation by the river, and they supplied dissolved inorganic nutrients while chlorophyll a was increasing. Discharge from the floodplain was enriched in chlorophyll a relative to downstream locations in the river and estuary during the initial draining and later when local stream inflows produced brief discharge pulses. Based on the observation that phytoplankton biomass peaks during drainage events, we suggest that phytoplankton production in the floodplain and biomass transport to downstream locations would be higher in years with multiple inundation and draining sequences.

California↗
USGS2004

Chemistry of burning the forest floor during the FROSTFIRE experimental burn, interior Alaska, 1999

Wildfires represent one of the most common disturbances in boreal regions, and have the potential to reduce C, N, and Hg stocks in soils while contributing to atmospheric emissions. Organic soil layers of the forest floor were sampled before and after the FROSTFIRE experimental burn in interior Alaska, and were analyzed for bulk density, major and trace elements, and organic compounds. Concentrations of carbon, nutrients, and several major and trace elements were significantly altered by the burn. Emissions of C, N, and Hg, estimated from chemical mass balance equations using Fe, Al, and Si as stable constituents, indicated that 500 to 900 g C and up to 0 to 4 ?? 10-4 g Hg/M2 were lost from the site. Calculations of nitrogen loss range from -4 to +6 g/m2 but were highly variable (standard deviation 19), with some samples showing increased N concentrations post-burn potentially from canopy ash. Noncombustible major nutrients such as Ca and K also were inherited from canopy ash. Thermogravimetry indicates a loss of thermally labile C and increase of lignin-like C in char and ash relative to unburned counterparts. Overall, atmospheric impacts of boreal fires include large emissions of C, N and Hg that vary greatly as a function of severe fire weather and its access to deep organic layers rich in C, N, and Hg. In terrestrial systems, burning rearranges the vertical distribution of nutrients in fuels and soils, the proximity of nutrients and permafrost to surface biota, and the chemical composition of soil including its nutrient and organic constituents, all of which impact C cycling. Copyright 2004 by the American Geophysical Union.

Global Biogeochemical Cycles↗
USGS2008

The 2005 catastrophic acid crater lake drainage, lahar, and acidic aerosol formation at Mount Chiginagak volcano, Alaska, USA: Field observations and preliminary water and vegetation chemistry results

A mass of snow and ice 400-m-wide and 105-m-thick began melting in the summit crater of Mount Chiginagak volcano sometime between November 2004 and early May 2005, presumably owing to increased heat flux from the hydrothermal system, or possibly from magma intrusion and degassing. In early May 2005, an estimated 3.8??10 6 m 3 of sulfurous, clay-rich debris and acidic water, with an accompanying acidic aerosol component, exited the crater through a tunnel at the base of a glacier that breaches the south crater rim. Over 27 km downstream, the acidic waters of the flood inundated an important salmon spawning drainage, acidifying Mother Goose Lake from surface to depth (approximately 0.5 km 3 in volume at a pH of 2.9 to 3.1), killing all aquatic life, and preventing the annual salmon run. Over 2 months later, crater lake water sampled 8 km downstream of the outlet after considerable dilution from glacial meltwater was a weak sulfuric acid solution (pH = 3.2, SO 4 = 504 mg/L, Cl = 53.6 mg/L, and F = 7.92 mg/L). The acid flood waters caused severe vegetation damage, including plant death and leaf kill along the flood path. The crater lake drainage was accompanied by an ambioructic flow of acidic aerosols that followed the flood path, contributing to defoliation and necrotic leaf damage to vegetation in a 29 km 2 area along and above affected streams, in areas to heights of over 150 m above stream level. Moss species killed in the event contained high levels of sulfur, indicating extremely elevated atmospheric sulfurcontent. The most abundant airborne phytotoxic constituent was likely sulfuric acid aerosols that were generated during the catastrophic partial crater lake drainage event. Two mechanisms of acidic aerosol formation are proposed: (1) generation of aerosol mist through turbulent flow of acidic water and (2) catastrophic gas exsolution. This previously undocumented phenomenon of simultaneous vegetationdamaging acidic aerosols accompanying drainage of an acidic crater lake has important implications for the study of hazards associated with active volcanic crater lakes. Copyright 2008 by the American Geophysical Union.

Geochemistry, Geophysics, Geosystems↗
USGS2011

Development of pan-Arctic database for river chemistry

More than 10% of all continental runoff flows into the Arctic Ocean. This runoff is a dominant feature of the Arctic Ocean with respect to water column structure and circulation. Yet understanding of the chemical characteristics of runoff from the pan-Arctic watershed is surprisingly limited. The Pan- Arctic River Transport of Nutrients, Organic Matter, and Suspended Sediments ( PARTNERS) project was initiated in 2002 to help remedy this deficit, and an extraordinary data set has emerged over the past few years as a result of the effort. This data set is publicly available through the Cooperative Arctic Data and Information Service (CADIS) of the Arctic Observing Network (AON). Details about data access are provided below.

Eos, Transactions, American Geophysical Union↗
USGS2019

Assessing the chemistry and bioavailability of dissolved organic matter from glaciers and rock glaciers

As glaciers thaw in response to warming, they release dissolved organic matter (DOM) to alpine lakes and streams. The United States contains an abundance of both alpine glaciers and rock glaciers. Differences in DOM composition and bioavailability between glacier types, like rock and ice glaciers, remain undefined. To assess differences in glacier and rock glacier DOM we evaluated bioavailability and molecular composition of DOM from four alpine catchments each with a glacier and a rock glacier at their headwaters. We assessed bioavailability of DOM by incubating each DOM source with a common microbial community and evaluated chemical characteristics of DOM before and after incubation using untargeted gas chromatography–mass spectrometry‐based metabolomics. Prior to incubations, ice glacier and rock glacier DOM had similar C:N ratios and chemical diversity, but differences in DOM composition. Incubations with a common microbial community showed that DOM from ice glacier meltwaters contained a higher proportion of bioavailable DOM and resulted in greater bacterial growth efficiency. After incubation, DOM composition from each source was statistically indistinguishable. This study provides an example of how MS‐based metabolomics can be used to assess effects of DOM composition on differences in bioavailability of DOM. Furthermore, it illustrates the importance of microbial metabolism in structuring composition of DOM. Even though rock glaciers had significantly less bioavailable DOM than ice glaciers, both glacial types still have potential to be important sources of bioavailable DOM to alpine headwaters over the coming decades.

Colorado↗
USGS2019

Heterogeneity in hyporheic flow, pore water chemistry, and microbial community composition in an alpine streambed

The hyporheic zone, where surface water and groundwater mix, is an important microbial habitat where biogeochemical reactions influence water quality. We show that spatial variability in hyporheic flow in the East River near Crested Butte, Colorado, drives heterogeneity in streambed geochemical conditions and microbial community assemblages, but the diversity of assemblages remains nearly constant throughout the reach. In July 2018, we collected approximately 100 pore water samples at 20 cm depth and analyzed them for anions, cations, dissolved organic carbon, dissolved organic matter (DOM) quality, and basic water quality parameters. Vertical hydraulic head gradients were also measured to assess the potential for upward or downward flow, and heat tracing was used to quantify vertical flux rates at a subset of locations. We found that regions of the streambed that are more groundwater-dominated contain less dissolved oxygen, higher concentrations of reduced metals, and more microbially-processed, recalcitrant DOM, while more surface water-dominated locations contain higher dissolved oxygen concentrations and terrestrially-derived, labile DOM. 16S rRNA gene sequencing of extracted DNA revealed that microbial community composition varies with geochemical gradients related to hyporheic flow. These findings provide a better understanding of hyporheic controls on streambed biogeochemistry during the baseflow season, which is expected to lengthen with climate change in alpine watersheds due to earlier snowmelt onset and reduced snowpack.

Colorado↗
USGS2021

Seasonality of solute flux and water source chemistry in a coastal glacierized watershed undergoing rapid change: Wolverine Glacier watershed, Alaska

As glaciers around the world rapidly lose mass, the tight coupling between glaciers and downstream ecosystems is resulting in widespread impacts on global hydrologic and biogeochemical cycling. However, a range of challenges make it difficult to conduct research in glacierized systems and our knowledge of seasonally changing hydrologic processes and solute sources and signatures is limited. This in turn hampers our ability to make predictions on solute composition and flux. We conducted a broad water sampling campaign in order to understand the present-day partitioning of water sources and associated solutes in Alaska’s Wolverine Glacier watershed. We established a relationship between electrical conductivity (EC) and streamflow at the watershed outlet to divide the melt season into four hydroclimatic periods. Across hydroclimatic periods, we observed a shift in off-glacier source waters from snowmelt-dominated overland and shallow subsurface flow paths to deeper groundwater flow paths. We also observed the shift from a low- to high-efficiency subglacial drainage network and the associated flushing of water stored sub-glacially with higher solute loads. We used calcium, the dominant dissolved ion, from watershed outlet samples to estimate solute fluxes for each hydroclimatic period across two melt seasons. We found between 40 and 55 percent of Ca2+ export occurred during the late season rainy period. This partitioning of the melt season coupled with a characterization of the chemical makeup and magnitude of solute export provides new insight into a rapidly changing watershed and creates a framework to quantify and predict changes to solute fluxes across a melt season.

Alaska↗
USGS2024

Chemistry, growth, and fate of the unique, short-lived (2019–2020) water lake at the summit of Kīlauea Volcano, Hawaii

Less than a year after the 2018 Kīlauea caldera collapse and eruption, water appeared in newly deepened Halemaʻumaʻu crater. The lake—unprecedented in the written record—grew to a depth of ∼50 m before lava from the December 2020 eruption boiled it away. Surface water heightened concerns of potential phreatic or phreatomagmatic explosions but also offered a new means of possibly identifying eruption precursors. The U.S. Geological Survey Hawaiian Volcano Observatory (HVO) monitored the lake via direct visual observation, webcams, thermal imaging, colorimetry, and laser rangefinders. HVO also employed uncrewed aircraft systems to sample the water and measure near-lake gas composition. The lake's δD and δ 18 O indicate a groundwater source with substantial evaporation. The initial sample had a salinity (total dissolved solids concentration) of 71,000 mg/L and was rich in sulfate (∼53,000 mg/L), iron (∼500 mg/L), and magnesium (∼10,000 mg/L). Subsequent samples were slightly more dilute. The water's pH (∼4), δ 34 S (+4.3‰), and surface temperatures (up to 85°C) suggest, rather than significant scrubbing of magmatic volatiles, leaching of basalt and reactions with sulfate minerals resulted in high concentrations of sulfate and other solutes. Thermodynamic modeling and precipitate mineralogy indicate that water composition was controlled by iron oxidation and sulfate dissolution. Although the lake exhibited no detectable precursors before the next eruption, and phreatic or phreatomagmatic explosions did not materialize, our multi-parameter approach to monitoring yielded an enhanced understanding of the hydrologic, geologic, and magmatic conditions that led to the formation of the unique and short-lived lake.

Hawaii↗
USGS2012

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: applications to the physics and chemistry of the lower mantle

The electronic structure of magnesiowustite is investigated using self-consistent field X α scattered wave (SCF- X α-SW) molecular orbital calculations on (FeO 6 ) 10− and (FeMg 12 O 14 ) 2− clusters. Calculated one-electron transition energies are used to interpret the optical spectrum of (Mg, Fe)O. The results are applied to the electrical and thermal conductivity of the lower mantle. The spin pairing of Fe 2+ and the effect of pressure on bonding in magnesiowustite, with some inferences regarding the incorporation of oxygen in the outer core, is also addressed. The approach used here appears to give a reliable description of the energy and pressure dependence of the spin-allowed 5 T 2 g → 5 E g ligand field transition and the spin-pairing transition of Fe 2+ in (Mg, Fe)O. However, the oxygen to metal charge transfer transitions in (Mg, Fe)O are not as reliably determined insofar as the p - d band gap varies with cluster size and the energies of the charge transfer states cannot be found without including configurational interaction. Nevertheless, it is argued that the charge transfer transitions that are intrinsic to (Fe, Mg)O are of a sufficiently high energy to be irrelevant to the electrical and thermal conductivity of the lower mantle. This is especially true if Fe 2+ adopts the low-spin configuration. The geophysically significant properties of (Fe, Mg)O probably result from defect Fe 3+ .

Journal of Geophysical Research↗
USGS1998

Chemistry of unsaturated zone gases sampled in open boreholes at the crest of Yucca Mountain, Nevada: Data and basic concepts of chemical and physical processes in the mountain

Boreholes open to the unsaturated zone at the crest of Yucca Mountain, Nevada, were variously sampled for CO 2 (including 13 C and 14 C), CH 4 , N 2 , O 2 , Ar, CFC-11, CFC-12, and CFC-113 from 1986 to 1993. Air enters the mountain in outcrops, principally on the eastern slope, is enriched in CO 2 by mixing with soil gas, and is advected to the mountain crest, where it returns to the atmosphere. The CFC data indicate that travel times of the advecting gas in the shallow Tiva Canyon hydrogeologic unit are ≤5 years. The 14 C activities are postbomb to depths of 100 m, indicating little retardation of 14 CO 2 in the shallow flow systems. The 14 C activities from 168 to 404 m in the Topopah Spring hydrogeologic unit are 85–90 pMC at borehole USW-UZ6. The CFC data show that the drilling of USW-UZ6 in 1984 has altered the natural system by providing a conduit through the Paintbrush Nonwelded unit, allowing flow from Topopah Spring outcrops in Solitario Canyon on the west to USW-UZ6, upward in the borehole through the Paintbrush, to the shallow Tiva Canyon flow systems, and out of the mountain.

Nevada↗
USGS2012

Chemistry of hydrothermal solutions from the southern Juan de Fuca Ridge

Fluids from three vent fields on the southern Juan de Fuca Ridge were sampled in September 1984 using the DSRV Alvin. The fluids are uniquely high in both chloride, which ranges up to twice the seawater value, and in metal content. Simple vapor-liquid phase separation could not have produced both the high chlorinity and gas concentrations observed in these fluids. The cause of the elevated chlorinity can not be uniquely identified but may be the result of either or a combination of two processes: (1) subsurface formation of a degassed brine and subsequent mixing of a small amount of this brine with a hydrothermal seawater which has not undergone a phase separation and (2) dissolution of a chloride-rich phase combined with a possible small loss of gas during sampling procedures. Although measured temperatures were all less than 300°C, quartz geothermometry suggests that the fluids have equilibrated at greater than 340°C. Quartz geobarometry is also in agreement with geophysical estimates of depth to the local magma chamber.

Journal of Geophysical Research B: Solid Earth↗
USGS2012

Chemistry and geothermometry of brine produced from the Salton Sea Scientific drill hole, Imperial Valley, California

The December 29–30, 1985, flow test of the State 2–14 well, also known as the Salton Sea Scientific drill hole, produced fluid from a depth of 1865–1877 m at a reservoir temperature of 305° ± 5°C. Another flow test at a depth of 3170 m produced brine contaminated by drilling fluid and diesel oil. Therefore we focus on the first flow test. Samples were collected at five different flashing pressures. The brines are Na-Ca-K-Cl-type waters with very high metal and low SO 4 and HCO 3 contents. Compositions of the flashed brines were normalized relative to the 25°C densities of the solutions, and an ionic charge balance was achieved by adjusting the Na concentration. The composition of the preflashed reservoir fluid was calculated using enthalpy-chloride relations applied to the normalized and charge-balanced brines. The calculated total dissolved solids in the preflashed reservoir fluid ranges from about 24.8 wt %, assuming insignificant thermal losses from the erupting fluid before sampling, to 26.0 wt %, assuming a 10% enthalpy loss by conduction of thermal energy through casing and surface piping. The preferred total dissolved solids of the reservoir fluid is 25.05 wt %. The calculated specific density of the preflashed reservoir fluid at 305°C and 1870 m depth ranges from 0.9980 (no thermal loss prior to sampling) to 1.0107 ± 0.0023 g cm −3 (10% thermal loss). Of the various cation geothermometers that are now in common use, the Na-K-Ca method gives a temperature (310°C) closest to the measured temperature (305°C) in the production horizon. Calculated Na/K geothermometer temperatures, using equations suggested by different investigators, range from 326° to 364°C. The Mg/K 2 method gives a temperature of about 350°C, Mg/Li 2 about 282°, and Na/Li 395°–418°C.

Journal of Geophysical Research Solid Earth↗
USGS2014

Report of the committee on chemistry of natural waters, 1933–34

The personnel of this Committee during the past year, practically the same as during the previous year, has been as follows: C. S. Howard, Chairman—United States Geological Survey, Washington, D.C. L. C. Case—Gypsy Oil Company, Tulsa, Oklahoma. W. D. Collins—United States Geological Survey, Washington, D.C. H. F. Flynn—United States Engineer Office, 35 South Ninth Street, Philadelphia, Pennsylvania. W. P. Kelley—University of California, Riverside, California. Alfred C. Lane—Tufts College, Tufts College, Massachusetts. Augustus Locke—477 Mills Building, San Francisco, California. R. D. Leitch—United States Bureau of Mines, Pittsburgh, Pennsylvania. H. T. Logan—United States Bureau of Standards, Washington, D.C. Thomas S. Lovering—United States Geological Survey, Washington, D.C. Thomas E. Means—111 Sutter Street, San Francisco, California. F. B. Plummer—University of Texas, Austin, Texas. J. W. Sale—United States Food and Drug Administration, Washington, D.C. C S. Scofield—Bureau of Plant Industry, Department of Agriculture, Washington, D.C. Thomas G. Thompson—University of Washington, Seattle, Washington.

Eos, Transactions, American Geophysical Union↗
USGS2014

Report of the committee on chemistry of natural waters, 1935–36

The membership of this Committee was not changed during the past year. A publication has appeared during the year giving the analytical data assembled for and used as a basis for Bulletin 40 of the Department of Public Works, California. This new publication, printed as 40‐A, is entitled “Detailed analyses showing qualities of irrigation‐waters.” Analyses are given for both surface‐ and ground‐waters.

Eos, Transactions, American Geophysical Union↗
USGS2014

Report of the committee on chemistry of natural waters, 1938–39

The membership of this Committee is as follows: C. S. Howard (Chairman), United States Geological Survey, Washington, D.C. I. A. Denison, National Bureau of Standards, Washington, D.C. W. P. Kelley, 119 Hilgard Hall, University of California, Berkeley, California A. C. Lane, 22 Arlington Street, Cambridge, Massachusetts C. S. Scofield, Bureau of Plant Industry, United States Department of Agriculture, Washington, D.C. D. G. Thompson, United States Geological Survey, Washington, D.C. T. G. Thompson, University of Washington, Seattle, Washington Studies on the corrosion of metals and soils have been continued at the National Bureau of Standards and a report of the recent findings was published under the title “Correlation of the electrolytic corrosion test with the active corrosiveness of soils,” by I. A. Denison and R. B. Darnielle [J. Res., Nation. Bur. Stan., No. 21, pp. 819‐830, December, 1938], Another paper on this subject by Kirk H. Logan was published under the title “Engineering significance of National Bureau of Standards soil corrosion data” [J. Res. Nation. Bur. Stan., pp. 109–125, January. 1939].

Eos, Transactions, American Geophysical Union↗
USGS2014

Committee on chemistry of natural waters, 1939–40

The membership of this Committee is as follows: I. A. Dennison, National Bureau of Standards, Washington, D.C.; C. S. Scofield, Bureau of Plant Industry, Department of Agriculture, Washington, D.C.; D. G. Thompson, United States Geological Survey, Washington, D.C.; Prof. T. G. Thompson, University of Washington, Seattle, Washington; and C. S. Howard (Chairman), United States Geological Survey, Washington, D.C. The Committee arranged for the presentation of the following five papers at the 1940 Spring meeting: (1) Salt‐water intrusion in the Connecticut River, by C. S. Howard, United States Geological Survey; (2) Salinity‐movement and its causes in the Delaware River Estuary, by William D. Mason and Wallace R. Pietsch, Sun Oil Company; (3) Salinity of, lower Savannah River in relation to tidal action and stream‐flow, by William L. Lamar, United States Geological Survey; (4) Corrosion of ferrous and nonferrous metals and the behavior of metallic coatings in tidal marsh, by I. A. Dennison, National Bureau of Standards; (5) The contamination of underground waters by salt water near Parlin, New Jersey, by H. C. Barksdale, United States Geological Survey.

Eos, Transactions, American Geophysical Union↗
USGS2014

Report of committee on the chemistry of natural waters, 1840–41

The membership of the Committee during the past year was as follows: I. A. Dennison. Bureau of Standards; C. S. Scofield, Department of Agriculture; D. G. Thompson, Geological Survey; T. G. Thompson, University of Washington, Seattle, Washington; and C. S. Howard, United States Geological Survey, Washington, D.C. (Chairman).

Eos, Transactions, American Geophysical Union↗