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USGS1956

Some limitations on the possible composition of the ore-forming fluid

The activity rations of various important anions (S, CO 3 , SO 4 , OH, F, and Cl) in hydrothermal solutions at the time of deposition are evaluated using a simple thermodynamic technique. The rations are interpreted in the light of the mineralogy of ore deposits and limites are placed on the variability of each ratio in hydrothermal solutions. All of the calculations are made for 25°C and cautious extrapolation to higher temperatures seems justified; however, additional data for elevated temperatures and pressures are needed before more than approximate values may be assigned to these ratios in the ore-forming fluid. The calculated partial pressure of CO 2 in the ore fluid is generally less than one atmosphere, which suggests that a dense CO 2 phase cannot be considered an importatn ore fluid for most deposits. The partial pressure of H 2 S is usually less than 10 -4 atmospheres which makes it extremely difficult to defend the heory that metals (other than the easily complexible mercury, arsenic, antimony, and perhaps fols and silver) are transported in quantity as complex sulfide and hydrosulfides. The sulfate to sulfide ration is such that the oxidation potential at the time of deposition is defined by the following equation: Eh (in volts) = 0.22 ± 0.04 - 0.059 pH.

Trace Elements Investigations↗
USGS1956

Geology of the Midnite Mine area, Spokane Indian Reservation, Stevens County, Washington

The Midnite mine is on the Spokane Indian Reservation, Stevens County, Wash. Geologic mapping and reconnaissance in the vicinity of the mine indicate metasedimentary rocks of probable Precambrian age have been intruded by two varieties of quartz monzonite of probable Cretaceous age. Porphyritic quartz monzonite underlies about three-fourths of the mapped area, and equigranular quartz monzonite underlies about one-thirtieth of the area. Metasedimentary rocks have been thermally metamorphosed in the vicinity of the intrusives. Uranium minerals are restricted to the vicinity of the contact between porphyritic quartz monzonite and schistose or spotted phyllite. The largest and richest uranium deposits are where the contact is relatively steeply dipping and highly irregular in detail. Uranium minerals are most abundant in brecciated and fractured or jointed schist but are also present along joints and grain boundaries in the adjacent quartz monzonite. Secondary uranium minerals comprise all known ore deposits; uraninite was found only in one diamond-drill core from the Midnite property. The origin of the deposits is not known, but several features suggest a hydrothermal origin.

Washington↗
USGS1956

Detailed mineral and chemical relations in two uranium-vanadium ores

Channel samples from two mines on the Colorado Plateau have been studied in detail both mineralogically and chemically. A channel sample from the Mineral Joe No. 1 mine, Montrose County, Colo., extends from unmineralized rock on one side, through a zone of variable mineralization, into only weakly mineralized rock. The unmineralized rock is a fairly clean quartz sand cemented with gypsum and contains only minor amounts of clay minerals. One boundary between unmineralized and mineralized rock is quite sharo and is nearly at right angles to the bedding. Vanadium clay minerals, chiefly mixed layered mica-montmorillonite and chlorite-monmorillonite, are abundant throughout the mineralized zone. Except in the dark "eye" of the channel sample, the vanadium clay minerals are accompanied by hewettite, carnotite, tyuyamunite, and probably unidentified vanadates. In the dark "eye," paramontroseite, pyrite, and marcasite are abundant, and bordered on each side by a zone containing abundant corvusite. No recognizable uranium minerals were seen in the paramontroseite zone although uranium is abundant there. Coaly material is recognizable throughout all of the channel but is most abundant in and near the dark "eye." Detailed chemical studies show a general increase in Fe, Al, U, and V, and a decrease in SO 4 toward the "eye" of the channel. Reducing capacity studies indicate that V(IV) and Fe(II) are present in the clay mineral throughout the channel, but only in and near the "eye" are other V(IV) minerals present (paramontroseite and corvusite). The uranium is sexivalent, although its state of combination is conjectural where it is associated with paramontroseite. Where the ore boundary is sharp, the boundary of introduced trace elements is equally sharp. Textural and chemical relations leave no doubt that the "eye: is a partially oxidized remnant of a former lower-valence ore, and the remainder of the channel is a much more fully oxidized remnant. A channel sample from the Virgin No. 3 mine, Montrose County, Colo., extends from weakly mineralized sandstone on both sides through a strongly mineralized central zone. The weakly mineralized zone is a poorly sorted sandstone with common detrital clay partings; chlorite and mixed layer mica-montmorrillonite are abundant interstitial to the quartz grains. No distinct vanadium or uranium minerals are recognizable, although the clay minerals are vanadium bearing. Euherdral pyrite grains and selenian galena are present but rare. The strongly mineralized rock is separated from the weakly mineralized rock by a narrow transition zone which only apporiximates the bedding planes. It contains abundant vanadium-bearing clay minerals (predominantly chlorite) interstitial to the quartz grains, and apparently replacing them. Paramontroseite is common and is intergrown with the clay minerals. Pyrite and marcasite are present, chiefly in or near the abundant blebs and fragments of carbonaceous material. Selenian galena is rarely present, and generally in or near carbonaceous material. Coffinite is the only uranium mineral idenitified; it is extremely fine grained and was identified only in X-ray diffraction patterns of heavy separates. Distribution of trace elements is not clear; some are consistently high in the strongly mineralized rocks, and some are consistently low. The trace element composition of the unmineralized rock is not known. Chemical studies show a very abrupt rise in the total U, V, and Fe from the weakly mineralized to strongly mineralized rock. Reducing-capacity studies indicate that most of the vanadium is present as V(IV), but some is present as V(V); that iron is present as both Fe(II) and Fe(III), the latter believed to have been present in the primary clays of the unmineralized rock; and that come of the uranium is present as U(VI) in addition to the U(IV) in the coffinite. All evidence points to weak oxidation of an ore once having a somewhat lower valence state. The channel samples from both the Mineral Joe No. 1 mine and the Virgin No. 3 mine are believe to have been essentially identical in mineralogy prior to oxidation by weathering: vanadium was present as V(III) in montroseite and V(IV) in the vanadium clays; uranium was present largely as U(IV) in coffinite and/or uraninite. The Mineral Joe No. 1 mine channel sample is now more fully oxidized. Vanadium clays are unquestionably formed abundantly during the primary mineralization, and they persist with a minimum of alteration during much of the weathering. They suggest that the vanadium is carried as V(IV) in the ore-forming fluids; it seems likely too that the uranium is carried as a U(VI) ion.

Trace Elements Investigations↗
USGS1956

Host rocks and their alterations as related to uranium-bearing veins in the United States

This paper, dealing with the different kinds of host rocks and their alterations associated with uranium-bearing veins in the United States, is a chapter of a comprehensive report entitled , "Geology of uranium-bearing vein deposits in the United States," in preparation by George W. Walker, Frank W. Osterwald, and others. The comprehensive report will include detailed information on tectonic and structural setting, kinds of host rocks, wall-rock alteration, mineralogy, physical characteristics, processes of deposition, and concepts of origin of uraniferous veins; but, because it will not be completed until sometime in the future, some chapters of the report are being transmitted as they are finished. Part of an introductory chapter to the comprehensive report entitled, "Classification and distribution of uranium-bearing veins in the United States" (Walker and Osterwald, 1956) has already been transmitted; several of the terms used herein are defined in the introductory chapter. Data included in this chapter demonstrate that uranium-bearing veins are: 1) in rocks of nearly all textural, chemical, and mineralogic types; 2) most abundant in holocrystalline, commonly equigranular, igeneous and metamorphic rocks characterized by a moderate to high silica content and and by similar physical properties. Although some of the physiochemical properties of the host rocks are discussed in terms of favorability or nonfavoribility for uranium deposition, the principal purpose of this chapter is to establish the petroloic environment in which uranium-bearing veins have been found. Because favorability or nonfavorability of host rocks is related complexly to the chemistry of ore solutions and to methods or uranium transport and deposition, several hypothetical processes of transport and deposition have been referred to briefly; these and other hypotheses will be outlines and discussed in greater detail in a subsequent chapter. The compilation of data leading to this report and its preparation by a member of the Uranium Research and Resource Section, U.S. Geological Survey, was done on behalf of the Division of Raw Materials, U.S. Atomic Energy Commission. The report is based on both published and unpublished information collected principally by personnel of the U.S. Geological Survey, the U.S. Atomic Energy Commission or its predecessor organization, the Manhattan Engineer District, and to a lesser extent by staff members of other Federal or State agencies and by geologists in private industry. Information concerning foreign uranium-bearing vein deposits has been extracted almost exclusively from published reports; references to these and other data are included at appropriate places.

Trace Elements Investigations↗
USGS1957

Reconnaissance of beryl-bearing pegmatites in the Ruby Mountains, other areas in Nevada, and northwestern Mohave County, Arizona

Pegmatite occurs widely in Nevada and northwestern Arizona, but little mining has been done for such pegmatite minerals as mica, feldspar, beryl, and lepidolite. Reconnaissance for beryl-bearing pegmatite in Nevada and in part of Mohave County, Ariz., and detailed studies in the Dawley Canyon area, Elko County, Nev., have shown that beryl occurs in at least 11 districts in the region. Muscovite has been prospected or mined in the Ruby Mountains and the Virgin Mountains, Nevada, and in Mohave County, Ariz. Feldspar has been mined in the southern part of the region near Kingman, Ariz., and in Clark County, Nev. The pegmatites in the region range in age from Precambrian to late Mesozoic or Tertiary. Among the pegmatite minerals found or reported in the districts studied are beryl, chrysoberyl, scheelite, wolframite, garnet, tourmaline, fluorite, apatite, sphene, allanite, samarskite, euxenite, gadolinite, monazite, autunite, columbite-tantalite, lepidolite, molybdenite, and pyrite and other sulfide minerals. The principal beryl-bearing pegmatites examined are in the Oreana and Lakeview (Humboldt Canyon) areas, Pershing County; the Dawley Canyon area in the Ruby Mountains, Elko County, Nev.; and on the Hummingbird claims in the Virgin Mountains, Mohave County, Ariz. Beryl has also been reported in the Marietta district, Mineral County; the Sylvania district, Esmeralda County; near Crescent Peak and near Searchlight, Clark County, Nev.; and in the Painted Desert area near Hoover Dam, Mohave County, Ariz. Pegmatites are abundant in the Ruby Mountains, chiefly in the area north of the granite stock at Harrison Pass. In the Dawley Canyon area of 2.6 square miles at least 350 pegmatite dikes more than a foot thick were mapped and beryl was found in small quantities in at least 100 of these dikes. Four of these dikes exceed 20 feet in thickness, and one is 55 feet thick. A few pegmatites were also examined in the Corral Creek, Gilbert Canyon, and Hankins Canyon areas in the Ruby Mountains. The pegmatite dikes in the Dawley Canyon area intrude granite and metamorphic rocks which consist chiefly of quartzite and schist of probable Early Cambrian age. The granite is of two types: a biotite-muscovite granite that forms the main mass of the stock and muscovite granite that occurs in the metamorphic rocks near the borders of the stock. The pegmatites were emplaced chiefly along fractures in the granite and along schistosity or bedding planes in the metamorphic rocks. Many of the Dawley Canyon pegmatite dikes are zoned, having several rock units of contrasting mineralogy or grain size successively from the walls inward. Aplitic units occur either as zones or in irregular positions in the pegmatite dikes and are a distinctive feature of the Dawley Canyon pegmatites. Some of the aplitic and fine-grained pegmatite units are characterized by thin layers of garnet crystals, forming many parallel bands on outcrop surfaces. The occurrence of aplitic and pegmatitic textural varieties in the same dike presumably indicates abrupt changes in physical-chemical conditions during crystallization, such as changes in viscosity and in content of volatile constituents. Concentrations of 0.1 percent or more beryl, locally more than 1 percent, occur in certain zones or parts of zones in the Dawley Canyon pegmatites. Spectrographic analyses of 23 samples indicate that the BeO content ranges from 0.0017 to 0.003 percent in the muscovite granite, from 0.0013 to 0.039 percent in aplitic zones in pegmatite, from 0.0005 to 0.10 percent in coarse-grained pegmatite, and from less than 0.0001 to 0.0004 percent in massive quartz veins. The scheelite-beryl deposits at Oreana and in Humboldt Canyon, Pershing County., are rich in beryllium. Twelve samples from the Humboldt Canyon (Lakeview) deposit range from 0.018 to 0.11 percent BeO, but underground crosscuts have failed to intersect similar rock at depth. Beryl locally constitutes as much as 10 percent of the pegmati tic ore at Oreana. The beryl was not recovered during tungsten mining at Oreana and is now in the tailings of the mill at Toulon, Nevada, in lower percentages than the Oreana ore because of dilution by tailings from other ores milled at Toulon. Beryl has been found in numerous pegmatite dikes in the Virgin Mountains. Both beryl and chrysoberyl occur in dikes in the Hummingbird claims, north of Virgin Peak, in Mohave County, Ariz. Spectra graphic analyses of five representative samples of the principal dike on the Hummingbird claims range from 0.055 to 0.11 percent BeO.

Arizona, Nevada↗
USGS1958

Airborne radioactivity surveys in geologic exploration

The value of airborne radioactivity surveys in guiding uranium exploration has been well established. Recent improvements in circuitry and development of semiquantitative analytical techniques permit a more comprehensive evaluation of the geologic distribution of radioactive materials that may prove useful in exploration for other minerals and in regional geologic studies. It is shown that placer deposits of heavy minerals can be detected from the air, and that the geometric configuration and average grade of the surficial part of the deposit can be approximated. Uranium-bearing phosphorite deposits may be similarly evaluated. Airborne surveys over the Coastal Plain area, Texas, show that the radioactivity profiles in some instances reflect the lithologic character of the underlying rocks. The sandstones are generally low in radioactivity (≈ 10 ppm equivalent uranium), the clays and tuffaceous rocks relatively higher. The intrinsic radioactivity of some lithologic units is sufficiently uniform and distinctive in character to permit their identification and lateral correlation on the airborne survey records. The results suggest that airborne surveys may thereby provide useful guidance in delineating lithologic continuity where the geology is poorly known or obscured.

Trace Elements Investigations↗