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Geologic Mapping and Mineral Resource Assessment of the Healy and Talkeetna Mountains Quadrangles, Alaska Using Minimal Cloud- and Snow-Cover ASTER Data

On July 8, 2003, ASTER acquired satellite imagery of a 60 km-wide swath of parts of two 1:250,000 Alaska quadrangles, under favorable conditions of minimal cloud- and snow-cover. Rocks from eight different lithotectonic terranes are exposed within the swath of data, several of which define permissive tracts for various mineral deposit types such as: volcanic-hosted massive sulfides (VMS) and porphyry copper and molybdenum. Representative rock samples collected from 13 different lithologic units from the Bonnifield mining district within the Yukon-Tanana terrane (YTT), plus hydrothermally altered VMS material from the Red Mountain prospect, were analyzed to produce a spectral library spanning the VNIR-SWIR (0.4 - 2.5 ?m) through the TIR (8.1 - 11.7 ?m). Comparison of the five-band ASTER TIR emissivity and decorrelation stretch data to available geologic maps indicates that rocks from the YTT display the greatest range and diversity of silica composition of the mapped terranes, ranging from mafic rocks to silicic quartzites. The nine-band ASTER VNIR-SWIR reflectance data and spectral matched-filter processing were used to map several lithologic sequences characterized by distinct suites of minerals that exhibit diagnostic spectral features (e.g. chlorite, epidote, amphibole and other ferrous-iron bearing minerals); other sequences were distinguished by their weathering characteristics and associated hydroxyl- and ferric-iron minerals, such as illite, smectite, and hematite. Smectite, kaolinite, opaline silica, jarosite and/or other ferric iron minerals defined narrow (< 250 m diameter) zonal patterns around Red Mountain and other potential VMS targets. Using ASTER we identified some of the known mineral deposits in the region, as well as mineralogically similar targets that may represent potential undiscovered deposits. Some known deposits were not identified and may have been obscured by vegetation- or snow-cover, or were too small to be resolved.

Open-File Report

Insights into the metamorphic history and origin of flake graphite mineralization at the Graphite Creek graphite deposit, Seward Peninsula, Alaska, USA

Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ 13 C VPDB values of − 30 to − 12‰ and pyrrhotite δ 34 S VCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.

Alaska

Environmental geochemistry of shale-hosted Ag-Pb-Zn massive sulfide deposits in northwest Alaska: Natural background concentrations of metals in water from mineralized areas

Red Dog, Lik and Drenchwater are shale-hosted stratiform Ag-Pb-Zn massive sulfide deposits in the northwestern Brooks Range. Natural background concentrations of metals in waters from the undisturbed (unmined) Drenchwater prospect and Lik deposit were compared to pre-mining baseline studies conducted at Red Dog. The primary factors affecting water chemistry are the extent of exposure of the deposits, the grade of mineralization, the presence of carbonate reeks in the section, and the proportion of Fe-sulfide in the ore. Surface water samples from the Drenchwater prospect, which has pyrite-dominant mineralization exposed in outcrop, have pH values as low as 2.8 and high dissolved concentrations of metals including as much as 95 mg 1-1 Al, 270 mg 1-1 Fe, 8 ??1-1 Cd, 10 ??1-1 Pb, and 2600 ??1-1 Zn, with As up to 26 ??g1-1. Surface waters from the Red Dog deposit prior to mining were also acidic and metal-rich, however, dissolved metal concentrations in Red Dog waters were many times greater. The higher metal concentrations in Red Dog waters reflect the high Zn grades and the abundant sphalerite, pyrite, and galena that were present in outcrop prior to mining. In contrast, despite significant mineralization at the Lik deposit, carbonate rocks in the section buffer the system, resulting in less acidic, mostly near-neutral pH values with low concentrations of most metals except Zn.

Applied Geochemistry