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Precipitation-runoff processes in the Merced River Basin, Central California, with prospects for streamflow predictability, water years 1952–2013

The U.S. Geological Survey, in cooperation with the California Department of Water Resources (DWR), has constructed a new spatially detailed Precipitation-Runoff Modeling System (PRMS) model for the Merced River Basin, California, which is a tributary of the San Joaquin River in California. Operated through an Object User Interface (OUI) with Ensemble Streamflow Prediction (ESP) and daily climate distribution preprocessing functionality, the model is calibrated primarily to simulate (and eventually, forecast) year-to-year variations of inflows to Lake McClure during the critical April–July snowmelt season. The model is intended to become part of a suite of methods used by DWR for estimating daily streamflow from the Merced River Basin, especially during the snowmelt season. This study describes the results of the application of an analysis tool that simulates responses to climate and land-use variations at a higher spatial resolution than previously available to DWR. A geographic information system was used to delineate the model domain, that is, areas draining to a single outlet at U.S. Geological Survey streamflow-gaging station 11270900, Merced River below Merced Falls Dam, near Snell, CA (also known as California Data Exchange Center station MRC), and subdrainage areas, including four draining to internal gages used as calibration targets. Using this delineation, three contiguous subbasins were recognized and, along with the model domain and nested calibration targets, are the simulation units evaluated in this report. An auto-calibration tool, LUCA (Let Us CAlibrate), was used for each calibration node, from headwaters to basin outlet, and then parameters were manually adjusted to complete the calibration. The main objective was to match April–July snowmelt seasonal discharge values of simulated streamflow to observed (measured or reconstructed) discharge values. Calibration or validation periods used site-specific streamflows—mostly from October 1, 1988, through September 30, 2013—but differed according to the period-of-record available for the measurements collected at internal gages or reconstructed flows for the single outlet. The accuracy of the Merced PRMS streamflow simulations varied seasonally, as compared to observed values. Based on statistical results, the Merced PRMS model satisfactorily simulated snowmelt seasonal streamflows. April–July calibrations for all areas had small negative bias (not greater than 7 percent) and low relative error (less than 8 percent). Less satisfactory performance for other seasons was attributed to several factors: (1) high uncertainty in low or zero flows in summer and fall, (2) lack of accounting for basin withdrawals and anthropogenic water use, (3) unavailability and (or) inaccuracy of observed (measured) meteorological input data, and (4) uncertainty in reconstructed streamflow data. With some additional refinement, the Merced PRMS model may be used for forecasting seasonal and longer-term streamflow variations; evaluating forecasted and past climate and land cover changes; providing water-resource managers with a consistent and documented method for estimating streamflow at ungaged sites within the basin; and aiding environmental studies, hydraulic design, water management, and water-quality projects in the Merced River Basin.

California

Marine latitudinal diversity gradients, niche conservatism and out of the tropics and Arctic: Climatic sensitivity of small organisms

Aim The latitudinal diversity gradient (LDG) is a consequence of evolutionary and ecological mechanisms acting over long history, and thus is best investigated with organisms that have rich fossil records. However, combined neontological‐palaeontological investigations are mostly limited to large, shelled invertebrates, which keeps our mechanistic understanding of LDGs in its infancy. This paper aims to describe the modern meiobenthic ostracod LDG and to explore the possible controlling factors and the evolutionary mechanisms of this large‐scale biodiversity pattern. Location Present‐day Western North Atlantic. Taxon Ostracoda. Methods We compiled ostracod census data from shallow‐marine environments of the western North Atlantic Ocean. Using these data, we documented the marine LDG with multiple metrics of alpha, beta (nestedness and turnover) and gamma diversity, and we tested whether macroecological patterns could be governed by different environmental factors, including temperature, salinity, dissolved oxygen, pH and primary productivity. We also explored the geologic age distribution of ostracod genera to investigate the evolutionary mechanisms underpinning the LDG. Results Our results show that temperature and climatic niche conservatism are important in setting LDGs of these small, poorly dispersing organisms. We also found evidence for some dispersal‐driven spatial dynamics in the ostracod LDG. Compared to patterns observed in marine bivalves, however, dispersal dynamics were weaker and they were bi‐directional, rather than following the ‘out‐of‐the‐tropics’ model. Main conclusions Our detailed analyses revealed that meiobenthic organisms, which comprise two‐thirds of marine diversity, do not always follow the same rules as larger, better‐studied organisms. Our findings suggest that the understudied majority of biodiversity may be more sensitive to climate than well‐studied, large organisms. This implies that the impacts of ongoing Anthropocene climatic change on marine ecosystems may be much more serious than presently thought.

Journal of Biogeography

Recent (2008-10) water quality in the Barton Springs segment of the Edwards aquifer and its contributing zone, central Texas, with emphasis on factors affecting nutrients and bacteria

The Barton Springs zone, which comprises the Barton Springs segment of the Edwards aquifer and the watersheds to the west that contribute to its recharge, is in south-central Texas, an area with rapid growth in population and increasing amounts of land area affected by development. During November 2008-March 2010, an investigation of factors affecting the fate and transport of nutrients and bacteria in the Barton Springs zone was conducted by the U.S. Geological Survey (USGS), in cooperation with the Texas Commission on Environmental Quality. The primary objectives of the study were to characterize occurrence of nutrients and bacteria in the Barton Springs zone under a range of flow conditions; to improve understanding of the interaction between surface-water quality and groundwater quality; and to evaluate how factors such as streamflow variability and dilution affect the fate and transport of nutrients and bacteria in the Barton Springs zone. The USGS collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge and Buda), and the main orifice of Barton Springs in Austin, Texas. During the period of the study, during which the hydrologic conditions transitioned from exceptional drought to wetter than normal, water samples were collected routinely (every 3 to 4 weeks) from the streams, wells, and spring and, in response to storms, from the streams and spring. All samples were analyzed for major ions, nutrients, the bacterium Escherichia coli, and suspended sediment. During the dry period, the geochemistry of groundwater at the two wells and at Barton Springs was dominated by flow from the aquifer matrix and was relatively similar and unchanging at the three sites. At the onset of the wet period, when the streams began to flow, the geochemistry of groundwater samples from the Marbridge well and Barton Springs changed rapidly, and concentrations of most major ions and nutrients and densities of Escherichia coli became more similar to those of samples from the streams relative to concentrations and densities during the dry period. Geochemical modeling indicated that the proportion of Barton Springs discharge composed of stream recharge increased from about 0-8 percent during the dry period to about 80 percent during the wet period. The transition from exceptional drought to wetter-than-normal conditions resulted in a number of marked changes that highlight factors affecting the fate and transport of nutrients and bacteria and the strong influence of stream recharge on water quality in the Barton Springs segment of the Edwards aquifer and had a pronounced effect on the fate of nitrogen species. Organic nitrogen loaded to and stored in soils during the dry period was nitrified to nitrate when the soils were rewetted, resulting in elevated concentrations of nitrate plus nitrite in streams as these constituents were progressively leached during continued wet weather. Estimated mean monthly loads of organic nitrogen and nitrate plus nitrite in stream recharge and Barton Springs discharge, which were relatively low and constant during the dry period, increased during the wet period. Loads of organic nitrogen, on average, were about six times greater in stream recharge than in Barton Springs discharge, indicating that organic nitrogen likely was being converted to nitrate within the aquifer. Loads of total nitrogen (organic nitrogen plus ammonia and nitrate plus nitrite) in stream recharge (162 kilograms per day) and in Barton Springs discharge (157 kilograms per day) for the period of the investigation were not significantly different. Dilution was not an important factor affecting concentrations of nitrate plus nitrite in the streams or in Barton Springs during the period of this investigation: Concentrations of nitrate plus nitrite did not decrease in streams with increasing stream discharge, and nitrate plus nitrite concentrations measured at Barton

Scientific Investigations Report

Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2014

Seepage investigations have been conducted annually by the U.S. Geological Survey from 1988 to 1998 and from 2004 to the present (2014) along a 64-mile reach of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, as part of the Mesilla Basin monitoring program. Results of the investigation conducted in 2014 are presented in this report. The 2014 seepage investigation was conducted on February 11, 2014, during the low-flow conditions of the non-irrigation season. During the 2014 investigation, discharge was measured at 23 sites along the main-stem Rio Grande and 19 inflow sites within the study reach. Because of extended drought conditions affecting the basin, many sites along the Rio Grande (17 main-stem and 9 inflow) were observed to be dry in February 2014. Water-quality samples were collected during the seepage investigation at sites with flowing water as part of a long-term monitoring effort in the region. Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2014 was 16.0 plus or minus 2.9 cubic feet per second.

New Mexico, Texas

Seepage investigation of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, 2015

Seepage investigations have been conducted annually by the U.S. Geological Survey from 1988 to 1998 and from 2004 to the present (2015) along a 64-mile reach of the Rio Grande from below Leasburg Dam, Leasburg, New Mexico, to above American Dam, El Paso, Texas, as part of the Mesilla Basin monitoring program. Results of the investigation conducted in 2015 are presented in this report. The 2015 seepage investigation was conducted on February 10, 2015, during the low-flow conditions of the non-irrigation season. During the 2015 investigation, discharge was measured at 23 sites along the main-stem Rio Grande and 19 inflow sites within the study reach. Because of extended drought conditions affecting the basin, many sites along the Rio Grande (17 main-stem and 10 inflow) were observed to be dry in February 2015. Net seepage gain or loss was computed for each subreach (the interval between two adjacent measurement locations along the river) by subtracting the discharge measured at the upstream location from the discharge measured at the closest downstream location along the river and then subtracting any inflow to the river within the subreach. An estimated gain or loss was determined to be meaningful when it exceeded the cumulative measurement uncertainty associated with the net seepage computation. The cumulative seepage loss in the 64-mile study reach in 2015 was 17.3 plus or minus 2.6 cubic feet per second. Gaining and losing reaches identified in this investigation generally correspond to seepage patterns observed in previous investigations conducted during dry years, with the gaining reaches occurring primarily at the southern (downstream) end of the basin.

Rio Grande

Generalized hydrogeologic framework and groundwater budget for a groundwater availability study for the glacial aquifer system of the United States

The glacial aquifer system groundwater availability study seeks to quantify (1) the status of groundwater resources in the glacial aquifer system, (2) how these resources have changed over time, and (3) likely system response to future changes in anthropogenic and environmental conditions. The glacial aquifer system extends from Maine to Alaska, although the focus of this report is the part of the system in the conterminous United States east of the Rocky Mountains. The glacial sand and gravel principal aquifer is the largest source of public and self-supplied industrial supply for any principal aquifer and also is an important source for irrigation supply. Despite its importance for water supply, water levels in the glacial aquifer system are generally stable varying with climate and only locally from pumping. The hydrogeologic framework developed for this study includes the information from waterwell records and classification of material types from surficial geologic maps into likely aquifers dominated by sand and gravel deposits. Generalized groundwater budgets across the study area highlight the variation in recharge and discharge primarily driven by climate.

Glacial Aquifer System

Outcrop descriptions and fossils from the Upper Cretaceous Frontier Formation, Wind River Basin and adjacent areas, Wyoming: Chapter 11 in Petroleum systems and geologic assessment of oil and gas resources in the Wind River Basin Province, Wyoming

The Wind River Basin of central Wyoming trends west-northwest from near the community of Alcova to near the town of Dubois (fig. 1). On the perimeter of the basin, outcrops of the Frontier Formation were examined and described during the years 1972-1975. Invertebrate fossils were collected from those outcrops during the years 1972-1996, in places with the assistance of other earth scientists (see Acknowledgments). The Frontier Formation in the Wind River Basin, ranging in thickness from 650 to 1,000 ft thick, consists mainly of sandstone, siltstone, shale, and bentonite of early Late Cretaceous age. The Frontier conformably overlies the Mowry Shale and is conformably overlain by the Cody Shale. A basal unit of the Cody, a sequence of marine noncalcareous shale, is named the Sage Breaks Member. The Frontier consists of two or three members, separated by disconformities; in ascending order, the Belle Fourche, Emigrant Gap, and Wall Creek. At several localities, the Emigrant Gap Member is missing. The formation was deposited mainly in marine environments, although nonmarine beds are conspicuous in the western part of the basin. Strata of the Frontier record a succession of marine regressions and transgressions. Molluscan fossils from the marine beds were identified and related to the chronostratigraphic chart shown in figure 2. The absolute ages on the chart were determined and supplied by J.D. Obradovich (Cobban and others, 2006). In this region, the Belle Fourche is of Cenomanian age, the Emigrant Gap is of early middle Turonian age, and the Wall Creek is of late Turonian and early Coniacian ages. The main purpose of this report is to present biostratigraphic information from studies of the Frontier Formation in the Wind River Basin that could be useful for future stratigraphic investigations of the formation throughout Wyoming. Locations of outcrop sections and associated fossil collections are depicted on accompanying maps and aerial photographs. Graphic descriptions of strata in the outcrops and identifications of fossils from nearby localities also are presented. Those fossils named on the graphic sections commonly have the most restricted time-spans. Fossils collected near the outcrops studied are not always named on the enclosed graphic sections because (1) the specimens are less useful for dating the enclosing beds, (2) the specimens are duplicates, or (3) the specimens could not be related to specific strata in the sections. The names, locations, and members of the outcrop sections and the approximate ages of the constituent strata are summarized in table 1. The index maps used to show locations of outcrop sections and fossil collections are from scanned versions of U.S. Geological Survey topographic maps of various scales and were obtained from TerraServer®. The portion of each map used depended on the areal distribution of the localities involved. The named quadrangles used for locality descriptions, however, all refer to 7½-minute, 1:24,000-scale quadrangles (for example, “Alcova”). The aerial photographs also are from TerraServer®; http://www.terraserver.com/.

Wyoming

Water-table and Potentiometric-surface altitudes in the Upper Glacial, Magothy, and Lloyd aquifers beneath Long Island, New York, April-May 2010

The U.S. Geological Survey (USGS), in cooperation with State and local agencies, systematically collects groundwater data at varying measurement frequencies to monitor the hydrologic conditions on Long Island, New York. Each year during April and May, the USGS conducts a synoptic survey of water levels to define the spatial distribution of the water table and potentiometric surfaces within the three main water-bearing units underlying Long Island—the upper glacial, Magothy, and Lloyd aquifers (Smolensky and others, 1989)—and the hydraulically connected Jameco (Soren, 1971) and North Shore aquifers (Stumm, 2001). These data and the maps constructed from them are commonly used in studies of Long Island’s hydrology and are used by water managers and suppliers for aquifer management and planning purposes. Water-level measurements made in 503 monitoring wells, a network of observation and supply wells, and 16 streamgage locations across Long Island during April–May 2010 were used to prepare the maps in this report. Measurements were made by the wetted-tape method to the nearest hundredth of a foot. Water-table and potentiometric-surface altitudes in these aquifers were contoured by using these measurements. The water-table contours were interpreted by using water-level data collected from 16 streamgages, 349 observation wells, and 1 supply well screened in the upper glacial aquifer and (or) shallow Magothy aquifer; the Magothy aquifer’s potentiometric-surface contours were interpreted from measurements at 67 observation wells and 27 supply wells screened in the middle to deep Magothy aquifer and (or) the contiguous and hydraulically connected Jameco aquifer. The Lloyd aquifer’s potentiometric-surface contours were interpreted from measurements at 55 observation wells and 4 supply wells screened in the Lloyd aquifer or the contiguous and hydraulically connected North Shore aquifer. Many of the supply wells are in continuous operation and, therefore, were turned off for a minimum of 24 hours before measurements were made so that the water levels in the wells could recover to the level of the potentiometric head in the surrounding aquifer. Full recovery time at some of these supply wells can exceed 24 hours; therefore, water levels measured at these wells are assumed to be less accurate than those measured at observation wells, which are not pumped (Busciolano, 2002). In this report, all water-level altitudes are referenced to the National Geodetic Vertical Datum of 1929 (NGVD 29). Hydrographs are included on these maps for selected wells that are instrumented with recording equipment. These hydrographs are representative of the 2010 water year1 to show the changes that have occurred throughout that period. The synoptic survey water level measured at the well is included on each hydrograph.

New York

Water-table and potentiometric-surface altitudes in the Upper Glacial, Magothy, and Lloyd aquifers of Long Island, New York, April-May 2013

The U.S. Geological Survey (USGS), in cooperation with State and local agencies, systematically collects groundwater data at varying measurement frequencies to monitor the hydrologic conditions on Long Island, New York. Each year during April and May, the USGS conducts a synoptic survey of water levels to define the spatial distribution of the water table and potentiometric surfaces within the three main water-bearing units underlying Long Island—the upper glacial, Magothy, and Lloyd aquifers (Smolensky and others, 1989)—and the hydraulically connected Jameco (Soren, 1971) and North Shore aquifers (Stumm, 2001). These data and the maps constructed from them are commonly used in studies of Long Island's hydrology and are utilized by water managers and suppliers for aquifer management and planning purposes. Water-level measurements made in 502 monitoring wells (observation and supply wells) and 16 streamgage locations across Long Island during April–May 2013 were used to prepare the maps in this report. Groundwater measurements were made by the wetted-tape method to the nearest hundredth of a foot. Contours of water-table and potentiometric-surface altitudes were created by using the groundwater measurements. The water-table contours were interpreted by using water-level data collected from 16 streamgages, 334 observation wells, and 1 supply well screened in the upper glacial aquifer or the shallow Magothy aquifer; the Magothy aquifer's potentiometric-surface contours were interpreted from measurements at 70 observation wells and 31 supply wells screened in the middle to deep Magothy aquifer and the contiguous and hydraulically connected Jameco aquifer. The Lloyd aquifer's potentiometric-surface contours were interpreted from measurements at 58 observation wells and 8 supply wells screened in the Lloyd aquifer and the contiguous and hydraulically connected North Shore aquifer. Many of the supply wells are in continuous operation and therefore, were turned off for a minimum of 24 hours before measurements were made to allow the water levels in the wells to recover to ambient (non-pumping) conditions. Full recovery time at some of these supply wells can exceed 24 hours; therefore, water levels measured at these wells are assumed to be less accurate than those measured at observation wells, which are not pumped (Busciolano, 2002). In addition to pumping stresses, elevated chloride concentrations (saline water) also lower the water levels measured in certain wells. This reduction in water level is the result of saline water being denser than freshwater (Lusczynski, 1961). In this report, all water-level altitudes are referenced to the National Geodetic Vertical Datum of 1929 (NGVD 29). The land surface or topography was downloaded from the National Map portal (http://nationalmap.gov), which represents the most currently available terrain representation as a 10-meter digital elevation model (DEM). The National Map terrain representation was combined with additional land surface terrain models of Suffolk County and New York City, which were collected using lidar to produce a high accuracy three-dimensional land surface altitude model based on the geospatial product for coastal flood mapping. The datum for land surface altitude is North American Vertical Datum of 1988 (NAVD 88). On Long Island NAVD 88 is approximately 1-foot lower than NGVD 29. Hydrographs are included on these maps for selected wells that have digital recording equipment. These hydrographs are representative of the 2013 water year to show the changes that have occurred throughout that period. The synoptic survey water level measured at the well is included on each hydrograph.

New York

Hydrologic and hydraulic analyses of Great Meadow wetland, Acadia National Park, Maine

The U.S. Geological Survey completed hydrologic and hydraulic analyses of Cromwell Brook and the Sieur de Monts tributary in Acadia National Park, Maine, to better understand causes of flooding in complex hydrologic and hydraulic environments, like those in the Great Meadow wetland and Sieur de Monts Spring area. Regional regression equations were used to compute peak flows with from 2 to 100-year recurrence intervals at seven locations. Light detection and ranging data were adjusted for bias caused by dense vegetation in the Great Meadow wetland; and then combined with local ground surveys used to define the underwater topography and hydraulic structures in the study area. Hydraulic modeling was used to evaluate flood response in the study area to a variety of hydrologic and hydraulic scenarios. Hydraulic modeling indicates that enlarging the culvert at Park Loop Road could help mitigate flooding near the Sieur de Monts Nature Center that is caused by streamflows with large recurrence intervals; however, hydraulic modeling also indicates that the Park Loop Road culvert does not aggravate flooding near the Nature Center caused by the more frequent high intensity rainstorms. That flooding is likely associated with overland flow resulting from (1) quick runoff from the steep Dorr Mountain hitting the lower gradient Great Meadow wetland area and (2) poor drainage aggravated by beaver dams holding water in the wetland. Rapid geomorphic assessment data collected in June 2015 and again in April 2016 indicate that Cromwell Brook has evidence of aggradation, degradation, and channel widening throughout the drainage basin. Two of five reference cross sections developed for this report also indicate channel aggradation.

Maine

Geology and ground water in north-central Santa Cruz County, California

North-central Santa Cruz County is underlain mainly by folded sedimentary rocks of Tertiary and Cretaceous age that have been highly fractured by movements in the San Andreas fault system. Ground water is stored in fractures within shale and mudstone formations and in intergranular pore spaces within fine- to very fine-grained sandstone and siltstone formations. Fewer than 10% of the wells yield more than 15 gallons of water per minute. The water in most wells is moderately hard to very hard, is generally of a sodium bicarbonate or calcium bicarbonate type, and commonly has excessive concentrations of iron or manganese. Of the many geologic units in the study area, only the Purisima Formation of Pliocene age has the potential to sustain well yields greater than 100 gallons per minute. (USGS)

California

Status of study of the frequency and magnitude of floods by the Mississippi Valley Committee of the Public Works Administration in collaboration with the United States Geological Survey

Active work under the recently authorized project relating to floods and their frequencies began in March, and such progress as may be reported at this time is largely that of organization and preliminary planning. One of the outstanding and impressive features of the organization is the provision for cooperative effort, whereby the mature judgment and possibly diverse viewpoints of various committees and consultants may be utilized to the fullest advantage. This arrangement should provide the necessary safeguard against adoption of immature individual views or favorite methods of analysis, to the exclusion of others of equal or greater merit. On the other hand, it is conceivable that too much of the limited time might be consumed in preliminary discussions of basic principles, methods of analysis, and formulas dealing with either magnitude or frequency of floods, if unanimity of opinion among several professional groups must precede the main work under the project authorized. In effect, such a procedure would require a practical and workable solution before the basic data had become available. To avoid such delays, a definite line of procedure has beer, proposed for consideration.

Eos, Transactions, American Geophysical Union

A fundamental role of carbonate–sulfate melts in the formation of iron oxide–apatite deposits

Genetic models for iron oxide–apatite deposits are controversial and span a spectrum from orthomagmatic to hydrothermal endmembers. This lack of consensus is rooted in uncertainties as to the nature and origin of ore-forming fluids in these systems. Here, we present a fluid-inclusion study of mineralizing fluids at two iron oxide–apatite deposits (Buena Vista, Nevada and Iron Springs, Utah). We found that the inclusions in both systems comprise both aqueous brine and ubiquitous iron-rich carbonate–sulfate melts. These melts were found throughout the paragenesis of both deposits and show a tremendous capacity to transport ferric iron. Hence, we argue that orthomagmatic fluids played a role in mineralization at both Buena Vista and Iron Springs, and that the main ore-forming fluid was an iron-rich carbonate–sulfate melt formed by the assimilation and anatexis of evaporite-bearing carbonate rocks. The geological conditions that give rise to carbonate–sulfate melts are also a common feature of other classic iron oxide–apatite systems worldwide. Hence, we argue that the process of assimilation, anatexis and immiscibility of carbonate–sulfate melts is fundamental to iron oxide–apatite formation and provides a common link between iron oxide–apatite systems in different geological settings.

Nature Geoscience

A chronicle of organochlorine contamination in Clear Creek, Galveston and Harris Counties, Texas, 1960-2002, as recorded in sediment cores

Clear Creek flows through the Texas Coastal Plain from its headwaters southeast of Houston, Texas, to Clear Lake, which empties into Galveston Bay. Segments of Clear Creek were on the State of Texas 303(d) list for 1998, 1999, and 2000 as a result of a fish consumption advisory issued by the Texas Department of Health. One of the contaminants for which the fish consumption advisory was issued is the organochlorine pesticide chlordane. Chlordane is a hydrophobic (“waterfearing”) contaminant; that is, it adsorbs to sediment at concentrations much greater than those found in water. The study described here sought to answer three questions: Does chlordane occur in Clear Creek sediments at present? Is there current loading of chlordane to Clear Creek? How has occurrence of chlordane in Clear Creek changed over time? To answer these questions, the U.S. Geological Survey (USGS), in cooperation with the U.S. Environmental Protection Agency (USEPA), collected and analyzed sediment cores from Clear Creek (fig. 1). Sediment cores sometimes can be used to reconstruct historical trends in concentrations of hydrophobic contaminants (Eisenreich and others, 1989; Van Metre and others, 1997). Cores were collected from five ponds connected to Clear Creek but out of the main channel (fig. 1). Cesium-137 ( 137 Cs) was analyzed in the cores to determine if the sediments in the cores were undisturbed and if the cores reached sediment predating 1964. The two cores that appeared most undisturbed on the basis of 137 Cs profiles (see sidebar, p. 2) were further subsampled and additional samples analyzed for 137 Cs, organic carbon, selected organochlorine pesticides (including chlordane), and total polychlorinated biphenyls (PCB).

Texas

Preliminary report on the geology and hydrology of Mortandad Canyon near Los Alamos, New Mexico, with reference to disposal of liquid low-level radioactive waste

The U.S. Geological Survey, in cooperation with the U.S. Atomic Energy Commission and the Los Alamos Scientific Laboratory, selected the upper part of Mortandad Canyon near Los Alamos, New Mexico for a site for disposal of treated liquid low-level radioactive waste. This report summarizes the part of a study of the geology and hydrology that was done from October 1960 through June 1961. Additional work is being continued. Mortandad Canyon is a narrow east-southeast-trending canyon about 9? miles long that heads on the central part of the Pajarito Plateau at an altitude of about 7,340 feet. The canyon is tributary to the Rio Grande. The drainage area of the part of Mortandad Canyon that was investigated is about 2 square miles, and the total drainage area is about 4.9 square miles. The Pajarito Plateau is capped by the Bandelier Tuff of Pleistocene age. Mortandad Canyon is cut in the Bandelier, and alluvium covers the floor of the canyon to depths ranging from less than 1 foot to as much as 100 feet. The Bandelier is underlain by silt, sand, conglomerate, and interbedded basalt of the Santa Fe Group of Miocene, Pliocene, and Pleistocene(?) age. Some ground water is perched in the alluvium in the canyon; however, the top of the main aquifer is in the Santa Fe Group at a depth of about 990 feet below the canyon floor. Joints in the Bandelier Tuff probably were caused by shrinkage of the tuff during cooling. The joints range in width from hairline cracks to fissures several inches wide. Water can infiltrate along the open joints where the Bandelier is at the surface; however, soil, alluvial fill, and autochthonous clay inhibit infiltration on the tops of mesas and probably in the alluvium-floored canyons also. Thirty-three test holes, each less than 100 feet deep, were drilled in 10 lies across Mortandad Canyon from the western margin of the study area to just west of the Los Alamos-Santa Fe County line. Ten of the holes were cased for observation wells to measure water levels and collect water samples from the alluvium. Twenty-three of the holes were cased to seal out water and were used as access tubes to accommodate a neutron-neutron probe for determining the moisture content of the alluvium and tuff. The source of recharge for the perched ground-water body in the alluvium in Mortandad Canyon is the precipitation in the drainage area of the canyon. During the winter of 1960-61, a snowpack 1-2 feet thick accumulated in the narrow shaded upper part of the canyon. The alluvium below the snowpack received some recharge because of diurnal melting during the winter. In March 1961 the snowmelt water saturated most of the thin alluvium in the upper part of the canyon, and a surface stream began to flow on the alluvium. The maximum flow of the stream was about 250 gpm (gallons per minute). Water from the stream infiltrated the alluvium at the front of the stream and in the reach upstream from the front. A ground-water mound was formed beneath the channel by water infiltrating from the stream. The front of the stream and the front of the ground-water mound advanced eastward to about the middle of the area studied. From this point eastward, the alluvium was thick enough to absorb and transmit the amount of flow in 1961. Late in April the front of the stream retreated, and by the first of May the flow stopped. During and after this period the ground-water mound decayed, and ground-water levels declined in the upper part of the canyon as water drained into the channel and downgradient through the alluvium. The amount of recharge was small in the wide lower part of the canyon during the period of study. The rise in ground-water levels and the increase in moisture content of the alluvium in the lower part of the canyon indicate that water moved downgradient by underflow through the alluvium from the recharge area in the upper part of the canyon. Moisture measurements indicate that only a little water moved into the underlyin

Open-File Report

Lithogeochemistry of Carlin-type gold mineralization in the Gold Bar district, Battle Mountain-Eureka trend, Nevada

The Gold Bar district contains five Carlin-type gold deposits and four resources for a combined gold endowment of 1.6 M oz [50 t]. The gold deposits are hosted in Devonian carbonate rocks below parautochthonous and allochthonous Paleozoic siliciclastic rocks emplaced during the Early Mississippian Antler orogeny. The district is in the Battle Mountain-Eureka trend, a long-lived structural feature that localized intrusions and ore deposits of different types and ages. The whole-rock geochemistry of four different mineralized and unmineralized Devonian carbonate rock units (two favorable and two unfavorable) were determined and interpreted in the context of the regional geology. A combination of basic statistics, R-mode factor analysis, isocon plots, and alteration diagrams were utilized to (1) identify favorable geochemical attributes of the host rocks, (2) characterize alteration and associated element enrichments and depletions, and (3) identify the mechanism of gold precipitation. This approach also led to the recognition of other types of alteration and mineralization in host rocks previously thought to be solely affected by Carlin-type mineralization. Unit 2 of the Upper Member of the Denay Formation, with the highest Al2O3, Fe2O3 and SiO2 contents and the lowest CaO content, is the most favorable host rock. Based on the high regression coefficients of data arrays on X-Y plots that project toward the origin, Al2O3 and TiO2 were immobile and K2O and Fe2O3 were relatively immobile during alteration and mineralization. Specific element associations identified by factor analysis are also prominent on isocon diagrams that compare the composition of fresh and altered equivalents of the same rock units. The most prominent associations are: Au, As, Sb, SiO2, TI, -CaO and -LOI, the main gold mineralizing event and related silicification and decalcification; Cd, Zn, Ag, P, Ni and Tl, an early base metal event; and MgO, early dolomitization. Alteration diagrams, consisting of X-Y plots of SiO2/Al2O3, K2O/Al2O3, CO2/Al2O3, that documented in classic Carlin-type gold deposits in the region, but the size of the deposits and the intensity of alteration and mineralization are less. The presence of other types of mineralization in the Gold Bar district is also common to most of the other Carlin-type districts located in major mineral belts. The approach used in this study is well suited to the interpretation of multi-element geochemical data from other study areas with superimposed alteration and mineralization. ?? 2002 Elsevier Science B.V. All rights reserved.

Ore Geology Reviews

Borehole geophysical investigation of a formerly used defense site, Machiasport, Maine, 2003-2006

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, collected borehole geophysical logs in 18 boreholes and interpreted the data along with logs from 19 additional boreholes as part of an ongoing, collaborative investigation at three environmental restoration sites in Machiasport, Maine. These sites, located on hilltops overlooking the seacoast, formerly were used for military defense. At each of the sites, chlorinated solvents, used as part of defense-site operations, have contaminated the fractured-rock aquifer. Borehole geophysical techniques and hydraulic methods were used to characterize bedrock lithology, fractures, and hydraulic properties. In addition, each geophysical method was evaluated for effectiveness for site characterization and for potential application for further aquifer characterization and (or) evaluation of remediation efforts. Results of borehole geophysical logging indicate the subsurface is highly fractured, metavolcanic, intrusive, metasedimentary bedrock. Selected geophysical logs were cross-plotted to assess correlations between rock properties. These plots included combinations of gamma, acoustic reflectivity, electromagnetic induction conductivity, normal resistivity, and single-point resistance. The combined use of acoustic televiewer (ATV) imaging and natural gamma logs proved to be effective for delineating rock types. Each of the rock units in the study area could be mapped in the boreholes, on the basis of the gamma and ATV reflectivity signatures. The gamma and mean ATV reflectivity data were used along with the other geophysical logs for an integrated interpretation, yielding a determination of quartz monzonite, rhyolite, metasedimentary units, or diabase/gabbro rock types. The interpretation of rock types on the basis of the geophysical logs compared well to drilling logs and geologic mapping. These results may be helpful for refining the geologic framework at depth. A stereoplot of all fractures intersecting the boreholes indicates numerous fractures, a high proportion of steeply dipping fractures, and considerable variation in fracture orientation. Low-dip-angle fractures associated with unloading and exfoliation are also present, especially at a depth of less than 100 feet below the top of casing. These sub-horizontal fractures help to connect the steeply dipping fractures, making this a highly connected fracture network. The high variability in the fracture orientations also increases the connectivity of the fracture network. A preliminary comparison of all fracture data from all the boreholes suggests fracturing decreases with depth. Because all the boreholes were not drilled to the same depth, however, there is a clear sampling bias. Hence, the deepest boreholes are analyzed separately for fracture density. For the deepest boreholes in the study, the intensity of fracturing does not decline significantly with depth. It is possible the fractures observed in these boreholes become progressively tighter or closed with depth, but this is difficult to verify with the borehole methods used in this investigation. The fact that there are more sealed fractures at depth (observed in optical televiewer logs in some of the boreholes) may indicate less opening of the sealed fractures, less water moving through the rock, and less weathering of the fracture infilling minerals. Although the fracture orientation remained fairly constant with depth, differences in the fracture patterns for the three restoration sites indicate the orientation of fractures varies across the study area. The fractures in boreholes on Miller Mountain predominantly strike northwest-southeast, and to a lesser degree they strike northeast. The fractures on or near the summit of Howard Mountain strike predominantly east-west and dip north and south, and the fractures near the Transmitter Site strike northeast-southwest and dip northwest and southeast. The fracture populations for the boreholes on or near the summit of Howard Mountain show more variation than at the other two sites. This variation may be related to the proximity of the fault, which is northeast of the summit of Howard Mountain. In a side-by-side comparison of stereoplots from selected boreholes, there was no clear correspondence between fracture orientation and proximity to the fault. There is, however, a difference in the total populations of fractures for the boreholes on or near the summit of Howard Mountain and the boreholes near the Transmitter Site. Further to the southwest and further away from the fault, the fractures at the Transmitter Site predominantly strike northeast-southwest and northwest-southeast.Heat-pulse flowmeter (HPFM) logging was used to identify transmissive fractures and to estimate the hydraulic properties along the boreholes. Ambient downflow was measured in 13 boreholes and ambient upflow was measured in 9 boreholes. In nine other bedrock boreholes, the HPFM did not detect measurable vertical flow. The observed direction of vertical flow in the boreholes generally was consistent with the conceptual flow model of downward movement in recharge locations and upward flow in discharge locations or at breaks in the slope of land surface. Under low-rate pumping or injection rates [0.25 to 1 gallon per minute (gal/min)], one to three inflow zones were identified in each borehole. Two limitations of HPFM methods are (1) the HPFM can only identify zones within 1.5 to 2 orders of magnitude of the most transmissive zone in each borehole, and (2) the HPFM cannot detect flow rates less than 0.010 + or - 0.005 gal/min, which corresponds to a transmissivity of about 1 foot squared per day (ft2/d). Consequently, the HPFM is considered an effective tool for identifying the most transmissive fractures in a borehole, down to its detection level. Transmissivities below that cut-off must be measured with another method, such as packer testing or fluid-replacement logging. Where sufficient water-level and flowmeter data were available, HPFM results were numerically modeled. For each borehole model, the fracture location and measured flow rates were specified, and the head and transmissivity of each fracture zone were adjusted until a model fit was achieved with the interpreted ambient and stressed flow profiles. The transmissivities calculated by this method are similar to the results of an open-hole slug test; with the added information from the flowmeter, however, the head and transmissivity of discrete zones also can be determined. The discrete-interval transmissivities ranged from 0.16 to 330 ft2/d. The flowmeter-derived open-hole transmissivity, which is the combined total of each of the transmissive zones, ranged from 1 to 511 ft2/d. The whole-well open-hole transmissivity values determined with HPFM methods were compared to the results of open-hole hydraulic tests. Despite the fact that the flowmeter-derived transmissivities consistently were lower than the estimates derived from open-hole hydraulic tests alone, the correlation was very strong (with a coefficient of determination, R2, of 0.9866), indicating the HPFM method provides a reasonable estimate of transmissivities for the most transmissive fractures in the borehole. Geologic framework, fracture characterization, and estimates of hydraulic properties were interpreted together to characterize the fracture network. The data and interpretation presented in this report should provide information useful for site investigators as the conceptual site groundwater flow model is refined. Collectively, the results and the conceptual site model are important for evaluating remediation options and planning or implementing the design of a well field and borehole completions that will be adequate for monitoring flow, remediation efforts, groundwater levels, and (or) water quality. Similar kinds of borehole geophysical logging (specifically the borehole imaging, gamma, fluid logs, and HPFM) should be conducted in any newly installed boreholes and integrated with interpretations of any nearby boreholes. If boreholes are installed close to existing or other new boreholes, cross-hole flowmeter surveys may be appropriate and may help characterize the aquifer properties and connections between the boreholes.

Maine

Geophysical investigations at Hidden Dam, Raymond, California: Summary of fieldwork and data analysis

Geophysical field investigations have been carried out at the Hidden Dam in Raymond, California for the purpose of better understanding the hydrogeology and seepage-related conditions at the site. Known seepage areas on the northwest right abutment area of the downstream side of the dam are documented by Cedergren. Subsequent to the 1980 seepage study, a drainage blanket with a subdrain system was installed to mitigate downstream seepage. Flow net analysis provided by Cedergren suggests that the primary seepage mechanism involves flow through the dam foundation due to normal reservoir pool elevations, which results in upflow that intersects the ground surface in several areas on the downstream side of the dam. In addition to the reservoir pool elevations and downstream surface topography, flow is also controlled by the existing foundation geology as well as the presence or absence of a horizontal drain within the downstream portion of the dam. The purpose of the current geophysical work is to (1) identify present-day seepage areas that may not be evident due to the effectiveness of the drainage blanket in redirecting seepage water, and (2) provide information about subsurface geologic structures that may control subsurface flow and seepage. These tasks are accomplished through the use of two complementary electrical geophysical methods, self-potentials (SP) and direct-current (DC) electrical resistivity, which have been commonly utilized in dam-seepage studies. SP is a passive method that is primarily sensitive to active subsurface groundwater flow and seepage, whereas DC resistivity is an active-source method that is sensitive to changes in subsurface lithology and groundwater saturation. The focus of this field campaign was on the downstream area on the right abutment, or northwest side of the dam, as this is the main area of interest regarding seepage. Two exploratory self-potential lines were also collected on the downstream left abutment of the dam to identify potential seepage in that area. This report is primarily a summary of the field geophysical data acquisition, with some preliminary results and interpretation. Further work will involve a more rigorous analysis of the geophysical datasets and an examination of a large dataset of historical observations of water levels in a number of observation wells and piezometers compared with reservoir elevation. In addition, a partially saturated flow model will be developed to better understand seepage patterns given the available information about dam construction, geophysical results, and data from installed observation wells and piezometers.

California