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At least 487 records · Page 27Linked to original sources

USGS2021

Linking decomposition rates of soil organic amendments to their chemical composition

The stock of organic carbon contained within a soil represents the balance between inputs and losses. Inputs are defined by the ability of vegetation to capture and retain carbon dioxide, effects that management practices have on the proportion of captured carbon that is added to soil and the application organic amendments. The proportion of organic amendment carbon retained is defined by its rate of mineralisation. In this study, the rate of carbon mineralisation from 85 different potential soil organic amendments (composts, manures, plant residues and biosolids) was quantified under controlled environmental conditions over a 547 day incubation period. The composition of each organic amendment was quantified using nuclear magnetic resonance and mid- and near-infrared spectroscopies. Cumulative mineralisation of organic carbon from the amendments was fitted to a two-pool exponential model. Multivariate chemometric algorithms were derived to allow the size of the fast and slow cycling pools of carbon to be predicted from the acquired spectroscopic data. However, the fast and slow decomposition rate constants could not be predicted suggesting that prediction of the residence time of organic amendment carbon in soil would likely require additional information related to soil type, environmental conditions, and management practices in use at the site of application.

Soil Research↗

USGS2006

Tetracycline residues and tetracycline resistance genes in groundwater impacted by swine production facilities

Antibiotics are used at therapeutic levels to treat disease; at slightly lower levels as prophylactics; and at low, subtherapeutic levels for growth promotion and improvement of feed efficiency. Over 88% of swine producers in the United States gave antimicrobials to grower/finisher pigs in feed as a growth promoter in 2000. It is estimated that ca . 75% of antibiotics are not absorbed by animals and are excreted in urine and feces. The extensive use of antibiotics in swine production has resulted in antibiotic resistance in many intestinal bacteria, which are also excreted in swine feces, resulting in dissemination of resistance genes into the environment. To assess the impact of manure management on groundwater quality, groundwater samples have been collected near two swine confinement facilities that use lagoons for manure storage and treatment. Several key contaminant indicators-including inorganic ions, antibiotics, and antibiotic resistance genes-were analyzed in groundwater collected from the monitoring wells. Chloride, ammonium, potassium, and sodium were predominant inorganic constituents in the manure samples and served as indicators of groundwater contamination. Based on these analyses, shallow groundwater has been impacted by lagoon seepage at both sites. Liquid chromatography-mass spectroscopy (LC-MS) was used to measure the dissolved concentrations of tetracycline, chlortetracycline, and oxytetracycline in groundwater and manure. Although tetracyclines were regularly used at both facilities, they were infrequently detected in manure samples and then at relatively trace concentrations. Concentrations of all tetracyclines and their breakdown products in the groundwater sampled were generally less than 0.5 ??g/L.</ p> Bacterial tetracycline resistance genes served as distinct genotypic markers to indicate the dissemination and mobility of antibiotic resistance genes that originated from the lagoons. Applying PCR to genomic DNA extracted from the lagoon and groundwater samples, four commonly occurring tetracycline (tet) resistance genes-tet(M), tet(O), tet(Q), and tet(W)-were detected. The detection frequency of tet genes was much higher in wells located closer to and down-gradient from the lagoons than in wells more distant from the lagoons. These results suggested that in the groundwater underlying both facilities tetracycline resistance genes exist and are somewhat persistent, but that the distribution and potentially the flux for each tet gene varied throughout the study period.

Animal Biotechnology↗

USGS2008

Compound-specific isotope analysis: Questioning the origins of a trichloroethene plume

Stable carbon isotope ratios of trichloroethene (TCE), cis-1,2- dichloroethene, and trans-1,2-dichloroethene were determined by use of gas chromatography-combustion-isotope ratio mass spectroscopy to determine whether compound-specific stable carbon isotopes could be used to help understand the origin and history of a TCE groundwater plume in Fort Worth, TX. Calculated ??13C values for total chlorinated ethenes in groundwater samples, which can approximate the ??13C of a spilled solvent if all degradation products are accounted for, were useful for determining whether separate lobes of the plume resulted from different sources. Most notably, values for one lobe, where tetrachloroethene (PCE) has been detected periodically, were outside the range for manufactured TCE but within the range for manufactured PCE, whereas values for a separate lobe, which is downgradient of reported TCE spills, were within the range for manufactured TCE. Copyright ?? Taylor & Francis Group, LLC.

Environmental Forensics↗

USGS2018

Method to characterize inorganic particulates in lung tissue biopsies using field emission scanning electron microscopy

Humans accumulate large numbers of inorganic particles in their lungs over a lifetime. Whether this causes or contributes to debilitating disease over a normal lifespan depends on the type and concentration of the particles. We developed and tested a protocol for in situ characterization of the types and distribution of inorganic particles in biopsied lung tissue from three human groups using field emission scanning electron microscopy (FE-SEM) combined with energy dispersive spectroscopy (EDS). Many distinct particle types were recognized among the 13 000 particles analyzed. Silica, feldspars, clays, titanium dioxides, iron oxides and phosphates were the most common constituents in all samples. Particles were classified into three general groups: endogenous , which form naturally in the body; exogenic particles, natural earth materials; and anthropogenic particles, attributed to industrial sources. These in situ results were compared with those using conventional sodium hypochlorite tissue digestion and particle filtration. With the exception of clays and phosphates, the relative abundances of most common particle types were similar in both approaches. Nonetheless, the digestion/filtration method was determined to alter the texture and relative abundances of some particle types. SEM/EDS analysis of digestion filters could be automated in contrast to the more time intensive in situ analyses.

Toxicology Mechanisms and Methods↗

USGS2016

Observing outer planet satellites (except Titan) with the James Webb Space Telescope: Science justification and observational requirements

The James Webb Space Telescope ( JWST ) will allow observations with a unique combination of spectral, spatial, and temporal resolution for the study of outer planet satellites within our Solar System. We highlight the infrared spectroscopy of icy moons and temporal changes on geologically active satellites as two particularly valuable avenues of scientific inquiry. While some care must be taken to avoid saturation issues, JWST has observation modes that should provide excellent infrared data for such studies.

Publications of the Astronomical Society of the Pa↗

USGS2014

Characterization of Lone Pine, California, tremolite asbestos and preparation of research material

Well-characterized amphibole asbestos mineral samples are required for use as analytical standards and in future research projects. Currently, the National Institute for Standards and Technology Standard Reference Material samples of asbestos are listed as ‘Discontinued’. The National Institute for Occupational Safety and Health (NIOSH) has a goal under the Asbestos Roadmap of locating and characterizing research materials for future use. Where an initial characterization analysis determines that a collected material is appropriate for use as a research material in terms of composition and asbestiform habit, sufficient amounts of the material will be collected to make it publicly available. An abandoned mine near Lone Pine, California, contains a vein of tremolite asbestos, which was the probable source of a reference material that has been available for the past 17 years from the Health and Safety Laboratory (HSL) in the UK. Newly collected fibrous vein material from this mine was analyzed at Research Triangle Institute (RTI International) with some additional analysis by the US Geological Survey’s Denver Microbeam Laboratory. The analysis at RTI International included: (i) polarized light microscopy (PLM) with a determination of principal optical properties; (ii) X-ray diffraction; (iii) transmission electron microscopy, including energy dispersive X-ray spectroscopy and selected-area electron diffraction; and (iv) spindle stage analysis using PLM to determine whether individual fibers and bundles of the samples were polycrystalline or single-crystal cleavage fragments. The overall findings of the study indicated that the material is tremolite asbestos with characteristics substantially similar to the earlier distributed HSL reference material. A larger quantity of material was prepared by sorting, acid-washing and mixing for sub-division into vials of ~10g each. These vials have been transferred from NIOSH to RTI International, from where they can be obtained on request.

California↗

USGS2023

Targeted metabolomics characterizes metabolite occurrence and variability in stable freshwater mussel populations

Freshwater mussels (order Unionida) play a key role in freshwater systems as ecosystem engineers and indicators of aquatic ecosystem health. The fauna is globally imperilled due to a diversity of suspected factors; however, causes for many population declines and mortality events remain unconfirmed due partly to limited health assessment tools. Mussel-monitoring activities often rely on population-level measurements, such as abundance and age structure, which reflect delayed responses to environmental conditions. Measures of organismal health would enable preemptive detection of declining condition before population-level effects manifest. Metabolomic analysis can identify shifts in biochemical pathways in response to stressors and changing environmental conditions; however, interpretation of the results requires information on inherent variability of metabolite concentrations in mussel populations. We targeted metabolites in the haemolymph of two common mussels, Lampsilis cardium and Lampsilis siliquoidea , from three Indiana streams (USA) using ultra-high-performance liquid chromatography combined with quadrupole time-of-flight mass spectroscopy. The influence of species, stream and sex on metabolite variability was examined with distance-based redundancy analysis. Metabolite variability was most influenced by species, followed by site and sex. Inter- and intraspecies metabolite variability among sexes was less distinct than differences among locations. We further categorized metabolites by occurrence and variability in mussel populations. Metabolites with high occurrence (Categories 1 and 2) included those indicative of energy status (catabolism versus anabolism; arginine, proline, carnitine, nicotinic acid, pantothenic acid), oxidative stress (proline, glutamine, glutamate) and protein metabolism (thymidine, cytidine, inosine). Metabolites with lower occurrence (Category 3) are constituents of assorted metabolic pathways and can be important biomarkers with additional temporal sampling to characterize their variability. These data provide a reference for future temporal (before/after) monitoring and for studies of stressor–metabolite linkages in freshwater mussels.

Indiana↗

USGS2023

Mussel mass mortality in the Clinch River, USA: Metabolomics detects affected pathways and biomarkers of stress

Biologists monitoring freshwater mussel (order Unionida) populations rely on behavioral, often subjective, signs to identify moribund (“sick”) or stressed mussels, such as gaping valves and slow response to probing, and they lack clinical indicators to support a diagnosis. As part of a multi-year study to investigate causes of reoccurring mortality of pheasantshell ( Ortmanniana pectorosa; synonym Actinonaias pectorosa ) in the Clinch River, Virginia and Tennessee, USA, we analyzed the hemolymph metabolome of a subset of mussels from the 2018 sampling period. Mussels at the mortality sites were diagnosed in the field as affected (case) or unaffected (control) based on behavioral and physical signs. Hemolymph was collected in the field by non-lethal methods from the anterior adductor muscle for analysis. We used ultra-high-performance liquid chromatography with quadrupole time-of-flight mass spectroscopy to detect targeted and untargeted metabolites in hemolymph and compared metabolomic profiles by field assessment of clinical status. Targeted biomarker analysis found 13 metabolites associated with field assessments of clinical status. Of these, increased gamma-linolenic acid and N -methyl- L -alanine were most indicative of case mussels, while adenine and inosine were the best indicators of control mussels. Five pathways in the targeted analysis differed by clinical status; two of these, purine metabolism and glycerophospholipid metabolism, were also indicated in the untargeted analysis. In the untargeted nalysis, 22 metabolic pathways were associated with clinical status. Many of the impacted pathways in the case group were catabolic processes, such as degradation of amino acids and fatty acids. Hierarchical clustering analysis matched clinical status in 72% (18 of 25) of mussels, with control mussels more frequently (5 of 16) not matching clinical status. Our study demonstrated that metabolomic analysis of hemolymph is suitable for assessing mussel condition and complements field-based indicators of health.

Tennessee, Virginia↗

USGS2020

Generation of calc-alkaline magmas during crystallization at high oxygen fugacity: An experimental and petrologic study of tephras from Buldir Volcano, western Aleutian Arc, Alaska, USA

Despite agreement that calc-alkaline volcanism occurs at subduction zones and is responsible for the genesis of continental landmasses, there is no consensus on the source of the Fe-depleted signature hallmark to calc-alkaline volcanism. In this study, we utilize mafic tephras collected from Buldir Volcano to address the genesis of strongly calc-alkaline volcanic rocks (those with a low Tholeiitic Index; ≤0·7) in a segment of the western Aleutian Arc to determine if the eruptions are plausibly part of a liquid line of descent, if they are mixtures of crustal melts and parental magmas, or if they are mixtures of melts of the mantle and the subducting slab. We conducted a series of H 2 O-saturated phase equilibrium experiments (1175–1000°C; 100 MPa) in a rapid-quench cold-seal (MHC) apparatus on the most primitive natural lava from Buldir (9·34 wt % MgO) at oxidizing conditions near the Re–ReO 2 buffer. We confirmed that all experiments equilibrated 0·3 ± 0·23 log units above the Re–ReO 2 buffer (ΔQFM ∼ +2·8) using X-ray Absorption Near Edge Structure (XANES) spectroscopy. Chromite is the liquidus phase, followed by olivine, then plagioclase, then clinopyroxene, and finally hornblende. Once clinopyroxene saturates, spinel composition shifts to magnetite. We compared our experimental results to the major element geochemistry and petrology of six tephras (51·9–54·8 wt % SiO 2 ) from Buldir collected during the 2015 field season of the GeoPRISMS shared platform. Tephras contain olivine + plagioclase + clinopyroxene + spinel ± hornblende; plagioclase comprises most of the crystalline volume, followed by either olivine or hornblende. Spinel is ubiquitous; with Cr-rich spinel inclusions in olivine and hornblende, and magnetite in the groundmass. Variations in phenocryst assemblages and compositions between samples can be attributed to differences in pre-eruptive temperatures, where hotter samples are devoid of hornblende, and contain Fo-rich olivine and plagioclase with lower An-contents, owing to the position of the mineral-in curves at fluid-saturated conditions. Experimental glasses match the depletion in FeO T observed in the tephra whole rock compositions. The continuous depletion in FeO T is attributable to saturation of spinel as a liquidus phase (initially as chromite) and continuous crystallization through the experimental series (changing to magnetite at colder temperatures). In contrast to the natural samples, the experiments show enrichment in TiO 2 with decreasing MgO, suggesting that differentiation did not occur at 100 MPa on Buldir. The TiO 2 depletion in volcanic rocks from Buldir can be accounted for if hornblende crystallization occurs close to the liquidus of a parental magma; a condition that is met at higher pressures and hydrous conditions. The emerging picture for Buldir Island is that (1) oxidizing conditions are required to drive the observed depletions in FeO T via crystallization of spinel, and (2) elevated H 2 O contents and high pressures are required to saturate hornblende close to the liquidus to reproduce the entire suite of major elements. Our study provides a mechanism to generate the calc-alkaline trends observed at Buldir without requiring mixing of slab and mantle melts. We conclude that calc-alkaline volcanic rocks with extremely low Tholeiitic Indices (0·7), like those from Buldir, cannot be generated in absence of high oxygen fugacity, even at high pressure and/or elevated water pressures.

Alaska↗

USGS1999

Utility of EXAFS in characterization and speciation of mercury-bearing mine wastes

Extensive mining of large mercury deposits located in the California Coast Range has resulted in mercury contamination of both the local environment and water supplies. The solubility, dispersal, and ultimate fate of mercury are all affected by its chemical speciation, which can be most readily determined in a direct fashion using EXAFS spectroscopy. EXAFS spectra of mine wastes collected from several mercury mines in the California Coast Range with mercury concentrations ranging from 230 to 1060 mg/kg (ppm) have been analyzed using a spectral database of mercury minerals and sorbed mercury complexes. While some calcines have been found to consist almost exclusively of mercuric sulfide, HgS, others contain additional, more soluble mercury phases, indicating a greater potential for the release of mercury into solution. This experimental approach can provide a quantitative measurement of the mercury compounds present and may serve as an indicator of the bioavailability and toxicity levels of mercury mine wastes.

Journal of Synchrotron Radiation↗

USGS1987

BOREHOLE NEUTRON ACTIVATION: THE RARE EARTHS.

Neutron-induced borehole gamma-ray spectroscopy has been widely used as a geophysical exploration technique by the petroleum industry, but its use for mineral exploration is not as common. Nuclear methods can be applied to mineral exploration, for determining stratigraphy and bed correlations, for mapping ore deposits, and for studying mineral concentration gradients. High-resolution detectors are essential for mineral exploration, and by using them an analysis of the major element concentrations in a borehole can usually be made. A number of economically important elements can be detected at typical ore-grade concentrations using this method. Because of the application of the rare-earth elements to high-temperature superconductors, these elements are examined in detail as an example of how nuclear techniques can be applied to mineral exploration.

IEEE Transactions on Nuclear Science↗

USGS2021

Mineral Mapping of the Battle Mountain District, Nevada, USA, Using AVIRIS-Classic and SpecTIR Inc. AisaFENIX 1K Imaging Spectrometer Datasets

Imaging spectroscopy (hyperspectral imaging) has been used to successfully map minerals at the outcrop, deposit, district, and regional scale. This contribution presents spectral-based mineral maps of the Battle Mountain mining district, Nevada, USA, generated using multi-scale airborne imaging and ground-based point spectrometers. Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and AisaFENIX 1K imaging spectrometer data were processed using Atmospheric and Topographic Correction (ATCOR-4) software with an empirical correction multiplier derived from field data. Data were used to generate spectral-based mineral maps with spatial resolutions of 13.5 and 1.8 m. A comparison of the various radiative transfer models used to convert radiance data to reflectance indicated that the ATCOR4 rugged model performed best for these datasets. These mineral maps were then used to spectrally characterize two potential porphyry mineral targets in the district.

Nevada↗

USGS2021

Multiscale hyperspectral imaging of hydrothermal alteration in Yellowstone National Park, USA

Imaging spectroscopy (hyperspectral imaging) data have mainly been used to map surface materials covering relatively small areas from airborne sensors over the past 20+ years. As part of the U.S. Geological Survey Integrated hyperspectral, geophysical and geochemical studies of Yellowstone National Park hydrothermal systems project, we have collected multiscale imaging spectrometer data including borehole core, field, and airborne data. These data give us the unique opportunity to map subsurface and surface alteration of shallow epithermal systems at scales ranging from microns to meters per pixel. Airborne Visible and Infrared Imaging Spectrometer (AVIRIS), Corescan HCI-3, HySpex VNIR-1800 and SWIR-384 imaging spectrometers, and a Riegl VZ-2000i terrestrial lidar system were used in this study. Maps utilizing spectral analysis of multiscale hyperspectral data indicate the presence of mineral assemblages consistent with epithermal deposits. Minerals such as alunite, hydrated silica, and kaolinite typically form in steam-heated cap systems and can be found in core and AVIRIS data. At depth, higher temperature fluids that are less acidic produce mixed-layer kaolinite with clay/muscovite and then montmorillonite and muscovite towards the bottom of the borehole. This transition can be seen in AVIRIS and field data at the Grand Canyon of the Yellowstone and in borehole Corescan data at Y-12 Norris-Ii R874. Instrument specifications, collection parameters, and setup for data acquisition will be discussed as well as mapping software and preliminary results.

Idaho, Montana, Wyoming↗

USGS2021

Biodiversity effects on grape quality depend on variety and management intensity

Interactions between plants can be beneficial, detrimental or neutral. In agricultural systems, competition between crop and spontaneous vegetation is a major concern. We evaluated the relative support for three non-exclusive ecological hypotheses about interactions between crop and spontaneous plants based on competition, complementarity or facilitation. The study was conducted in Swiss vineyards with different vegetation management intensities. In all, 33 vineyards planted with two different grape varieties were studied over 3 years to determine whether low-intensity vegetation management might provide benefits for grape quality parameters. Management intensity varied with the degree of control of spontaneous inter-row vegetation. Features of spontaneous vegetation measured included total cover, total species richness and abundance of nitrogen-fixing plants. Grape quality parameters of known importance to wine making (yeast assimilable nitrogen, sugars, tartaric acid and malic acid) were determined by Fourier-transform infrared spectroscopy (FTIR). Using structural equation modelling, we evaluated hypotheses about the multivariate responses of grape quality parameters as well as the direct and indirect (plant-mediated) effects of management. Observed effects of management differed between grape varieties. Management intensity and abundance of N-fixing plants significantly influenced grape quality parameters while total richness of spontaneous plants did not have detectable effects. Abundance of N-fixing plants was enhanced by low-intensity management resulting in increased N content in the red grape variety Pinot noir , potentially enhancing grape quality, while measured soil N content did not explain the increase. Synthesis and applications . Our study shows that crop quality can be enhanced by spontaneous plants, in this case by the abundance of a key functional group (N-fixers), most likely through plant–plant or plant–microbe facilitation. However, beneficial interactions may have a high specificity in terms of facilitation partners and may have contrasting effects at low taxonomic resolutions such as crop varieties. Generally, increasing plant biodiversity in agricultural systems may increase competition with crops. Thus, the identification of suitable interaction partners and a careful balance between crop variety and spontaneous plant species may be necessary to utilize beneficial interactions and to reduce the trade-off between agricultural production and biodiversity to achieve a sustainable ecological benefit in agricultural systems.

Canton of Valais↗

USGS2015

Dominance of 'Gallionella capsiferriformans' and heavy metal association with Gallionella -like stalks in metal-rich pH 6 mine water discharge

Heavy metal-contaminated, pH 6 mine water discharge created new streams and iron-rich terraces at a creek bank in a former uranium-mining area near Ronneburg, Germany. The transition from microoxic groundwater with ~5 m m Fe(II) to oxic surface water may provide a suitable habitat for microaerobic iron-oxidizing bacteria (FeOB). In this study, we investigated the potential contribution of these FeOB to iron oxidation and metal retention in this high-metal environment. We (i) identified and quantified FeOB in water and sediment at the outflow, terraces, and creek, (ii) studied the composition of biogenic iron oxides ( Gallionella -like twisted stalks) with scanning and transmission electron microscopy (SEM, TEM) as well as confocal laser scanning microscopy (CLSM), and (iii) examined the metal distribution in sediments. Using quantitative PCR, a very high abundance of FeOB was demonstrated at all sites over a 6-month study period. Gallionella spp. clearly dominated the communities, accounting for up to 88% of Bacteria , with a minor contribution of other FeOB such as Sideroxydans spp. and ‘ Ferrovum myxofaciens ’. Classical 16S rRNA gene cloning showed that 96% of the Gallionella -related sequences had ≥97% identity to the putatively metal-tolerant ‘ Gallionella capsiferriformans ES-2’, in addition to known stalk formers such as Gallionella ferruginea and Gallionellaceae strain R-1. Twisted stalks from glass slides incubated in water and sediment were composed of the Fe(III) oxyhydroxide ferrihydrite, as well as polysaccharides. SEM and scanning TEM-energy-dispersive X-ray spectroscopy revealed that stalk material contained Cu and Sn, demonstrating the association of heavy metals with biogenic iron oxides and the potential for metal retention by these stalks. Sequential extraction of sediments suggested that Cu (52–61% of total sediment Cu) and other heavy metals were primarily bound to the iron oxide fractions. These results show the importance of ‘ G. capsiferriformans ’ and biogenic iron oxides in slightly acidic but highly metal-contaminated freshwater environments.

Geobiology↗

USGS2018

Trace element characterisation of MAD‐559 zircon reference material for ion microprobe analysis

We document the composition of a natural zircon gemstone sourced from Madagascar, MAD‐559 – a new reference material for calibrating trace element mass fractions in zircon measured by SIMS. The composition of MAD‐559 was quantified by calibration relative to the well‐documented zircon reference material 91500, for which we compiled existing published data (Mg, Al, Y, rare earth elements, Hf, U, Th) and performed new measurements to characterise the mass fraction of less commonly measured elements (Li, Be, B, F, Na, P, K, Ca, Sc, Ti, Fe, Nb). Measurement results of SL13, CZ3 and MAD‐1 zircons and NIST SRM glasses were performed as quality control materials to test measurement bias and repeatability. We show the intermediate precision for most trace element measurement results of MAD‐559 to be between ± 3% and ± 5% RSD based on 139 measurements by SIMS on twenty‐five individual polished zircon chips measured during a 24‐h period, as well as repeat measurements performed over five separate analytical sessions. Trace element mass fractions were also measured by LA‐ICP‐MS in two different laboratories, and major element compositions measured by electron microprobe, to compare with results measured by SIMS. Based on laser Raman and hyperspectral cathodoluminescence spectroscopy, we show MAD‐559 to have high crystal disorder due to radiation damage relative to crystalline zircon (e.g., SL13 and 91500 zircon). Although the high cumulative alpha dose of MAD‐559 zircon makes it a poor reference material for geochronology, the consistency of the trace element mass fraction results measured in multiple sessions and by various measurement methods shows that it is an ideal reference material for microanalytical trace element mass fraction quantification of zircon.

Geostandards and Geoanalytical Research↗

USGS2025

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research↗

USGS2008

NMR and mass spectrometry of phosphorus in wetlands

There is at present little information on the long-term stability of phosphorus sequestered in wetlands. Phosphorus sequestered during high loading periods may be relatively unstable and easily remobilized following changes in nutrient status or hydrological regime, but the chemical forms of sequestered phosphorus that do remobilize are largely unknown at this time. A lack of suitable analytical techniques has contributed to this dearth of knowledge regarding the stability of soil organic phosphorus. We analysed phosphorus in soils from the 'head' of Rescue Strand tree island and an adjacent marsh in the Florida Everglades by 31P nuclear magnetic resonance (NMR) spectroscopy and high-resolution mass spectrometry. Tree islands are important areas of biodiversity within the Everglades and offer a unique opportunity to study phosphorus sequestration because they are exposed to large phosphorus loads and appear to be natural nutrient sinks. The 31P NMR profiling of extracts from surface and sediment samples in the tree island indicates that phosphorus input to Rescue Strand tree island soils is mostly in the form of inorganic ortho-phosphate and is either refractory when deposited or rapidly recycled by the native vegetation into a stable phosphorus pool largely resistant to re-utilization by plants or microbes. Mass spectrometry revealed the presence of inositol hexakisphosphate, a common organic monophosphate ester not previously observed in Everglades' soils. ?? 2008 The Authors.

European Journal of Soil Science↗