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Geologic framework studies of South Carolina's Long Bay from Little River Inlet to Winyah Bay, 1999-2003: Geospatial data release

The northern South Carolina coast is a heavily developed region that supports a thriving tourism industry, large local populations and extensive infrastructure (Figure 1). The economic stability of the region is closely tied to the health of its beaches: primarily in providing support for local tourism and protection from storm events. Despite relatively low long-term shoreline erosion rates, and the implied stability of the beaches, the economic impact of storm events to coastal communities has been costly. For example, Hurricane Hugo made landfall on the central South Carolina coast in 1989. High winds and storm surge inflicted roughly $6 billion in property loss and damages, and Hugo remains the costliest storm event in South Carolina history. Localized erosion, commonly occurring around tidal inlets and erosion "hot spots", has also proved costly. Construction and maintenance of hard structures and beach nourishment, designed to mitigate the effects of erosion, have become annual or multi-annual expenditures. Providing a better understanding of the physical processes controlling coastal erosion and shoreline change will allow for more effective management of coastal resources. In 1999, the U.S. Geological Survey (USGS), in partnership with the South Carolina Sea Grant Consortium (SCSGC), began a study to investigate inner continental shelf and shoreface processes. The objectives of the USGS/SCSGC cooperative program are: 1) to provide a regional synthesis of the shallow geologic framework underlying the shoreface and inner continental shelf, and to define its role in coastal evolution and modern beach behavior; 2) to identify and model the physical processes affecting coastal ocean circulation and sediment transport, and to define their role in shaping the modern shoreline; and 3) to identify sediment sources and transport pathways in order to develop a regional sediment budget. This report contains the geospatial data used to define the geologic framework offshore of the northern South Carolina coast. The digital data presented herein accompany USGS Open-File Reports OFR 2004-1013 and OFR 2005-1345, describing the stratigraphic framework and modern sediment distribution within Long Bay, respectively. Direct on-line links to these publications are available within 'References' on the navigation bar to the left. Additional links to other publications and web sites are also available.

South Carolina

The USGS Abandoned Mine Lands Initiative: Protecting and restoring the environment near abandoned mine lands

The Abandoned Mine Lands (AML) Initiative is part of a larger strategy of the U.S. Department of the Interior and the U.S. Department of Agriculture to clean up Federal lands contaminated by abandoned mines. Thousands of abandond hard-rock metal mines (such as gold, copper, lead, and zinc) have left a dual legacy across the Western United States. They reflect the historic development of the west, yet at the same time represent a possible threat to human health and local ecosystems. Abandoned Mine Lands (AML) are areas adjacent to or affected by abandoned mines. AML's often contain unmined mineral deposits, mine dumps (the ore and rock removed to get to the ore deposits), and tailings (the material left over from the ore processing) that contaminate the surrounding watershed and ecosystem. For example, streams near AML's can contain metals and (or) be so acidic that fish and aquatic insects cannot live in them. Many of these abandoned hard-rock mines are located on or adjacent to public lands administered by the Bureau of Land Management, National Park Service, and U.S. Forest Service. These federal land management agencies and the USGS are committed to mitigating the adverse effects that AML's can have on water quality and stream habitats. The USGS AML Initiative began in 1997 and will continue through 2001 in two pilot watersheds - the Boulder River basin in southwestern Montana and the upper Animas River basin in southwestern Colorado. The USGS is providing a wide range of scientific expertise to help land managers minimize and, where possible, eliminate the adverse environmental effects of AML's. USGS ecologists, geologists, water quality experts, hydrologists, geochemists, and mapping and digital data collection experts are collaborating to provide the scientific knowledge needed for an effective cleanup of AML's.

Arizona, California, Colorado, Idaho, Montana, New

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Kendrick Reclamation Project Area, Wyoming, 1986-87

A reconnaissance investigation of the Kendrick Reclamation Project in central Wyoming was conducted during 1986-87 to determine if irrigation drainage has caused or has the potential to cause harmful effects on human health, fish, and wildlife, or other water uses. The investigation of the Kendrick Reclamation Project is one of nine similar investigations being conducted in the western conterminous United States as part of the Department of the Interior 's Irrigation Drainage Program. Samples of surface water were collected at 10 sites and ground water at 5 sites. Surface-water analyses included trace elements, radiochemicals, and pesticides. Concentrations in the water generally were less than national standards for public water supplies, with the exception of selenium. The median concentration of dissolved selenium was 7.5 microgm/L in 24 samples of surface and groundwater. Of the 11 samples that contained dissolved- selenium concentrations greater than the national standard for public water supplies of 10 microgm/L, 10 of the samples were collected at sites on streams that are not used for public water supplies; the eleventh sample was collected from a shallow well. Dissolved-selenium concentrations ranged from less than 1 to 300 microgm/L. Concentrations of dissolved selenium in the North Platte River, which supplies drinking water for several municipalities, ranged from less than 1 to 4 microgm/L. The dissolved-selenium concentration and selenium discharge in the North Platte River increased in the downstream direction. The four principal tributaries that receive drainage from the Kendrick Reclamation Project contributed substantially to the increase in selenium concentration and discharge in the North Platte River. Bottom-sediment samples from the North Platte River contained selenium contents of 1.2 microgm/g or less. (Author 's abstract)

Water-Resources Investigations Report

Groundwater quality data for the Tahoe-Martis study unit, 2007: Results from the California GAMA Program

Groundwater quality in the approximately 460-square-mile Tahoe–Martis study unit was investigated in June through September 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw groundwater used for public water supplies within the Tahoe–Martis study unit (Tahoe–Martis) and to facilitate statistically consistent comparisons of groundwater quality throughout California. Samples were collected from 52 wells in El Dorado, Placer, and Nevada Counties. Forty-one of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 11 were selected to aid in evaluation of specific water-quality issues (understanding wells). The groundwater samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N -nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, strontium isotope ratio, and stable isotopes of hydrogen and oxygen of water), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 240 constituents and water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at 12 percent of the wells, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate of compliance or noncompliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from the Tahoe–Martis wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides) were detected in about 40 percent of the samples from grid wells, and most concentrations were less than 1/100th of regulatory and nonregulatory health-based thresholds, although the conentration of perchloroethene in one sample was above the USEPA maximum contaminant level (MCL-US). Concentrations of all trace elements and nutrients in samples from grid wells were below regulatory and nonregulatory health-based thresholds, with five exceptions. Concentrations of arsenic were above the MCL-US in 20 percent of the samples from grid wells. Gross alpha particle activity (MCL-US), boron (CDPH notification level, NL-CA), and molybdenum (USEPA lifetime health advisory, HAL-US) were each detected above thresholds in two of the samples from grid wells, and radon (proposed alternative MCL-US) was detected above the threshold in one sample from a grid well. Most of the samples from Tahoe–Martis grid wells had concentrations of major elements, total dissolved solids, and trace elements below the CDPH secondary maximum contaminant levels, nonenforceable thresholds set for aesthetic and technical concerns. Fifteen percent of the samples from grid wells contained iron, manganese, or total dissolved solids at concentrations above these levels.

California, Nevada

Integrated science strategy for assessing and monitoring water availability and migratory birds for terminal lakes across the Great Basin, United States

Executive Summary In 2022, the U.S. Geological Survey (USGS) established the Saline Lake Ecosystems Integrated Water Availability Assessment (IWAAs) to monitor and assess the hydrology of terminal lakes in the Great Basin and the migratory birds and other wildlife dependent on those habitats. Scientists from across the USGS (with specialties in water quantity, water quality, limnology, avian biology, data science, landscape ecology, and science communication) formed the Saline Lake Ecosystems IWAAs Team. The team has developed this regional strategic science plan to guide data collection and assessment activities at terminal lakes in the Great Basin. The U.S. Congress requested the USGS to establish the Saline Lake Ecosystems IWAAs in response to historically low water levels at terminal lakes and associated wetlands across the Great Basin. Not all Great Basin terminal lakes have high salinity; however, all terminal lakes occur in endorheic, closed, basins with no surface-water outflow. Low lake levels across the Great Basin are the result of increased water use for agriculture and municipalities, drought conditions, and a warming climate. Great Basin terminal lake water extents have decreased by as much as 90 percent over the last 150 years, and terminal lake wetlands have decreased in area by as much as 47 percent since 1984. Lake elevations and wetland areas are primarily supported by freshwater inputs from snowmelt feeding upgradient rivers, streams, and springs. These freshwater inputs have been severely reduced because of continued and increased surface-water diversions and surface-water capture through groundwater pumping for agriculture, mining, and public supply as well as unprecedented drought conditions and warming temperatures related to climate change. Water quality, specifically salinity, is highly variable for terminal lakes of the Great Basin, and this variability is a result of the balance between freshwater inflow and evaporation. Variability of salinity at each of the terminal lakes can be affected by lake morphology, hydrogeologic features of the basin, annual variability in weather patterns, and changes in upgradient water use. Hypersaline terminal lakes provide abundant food resources such as brine shrimp and brine flies that support nesting and migrating birds. The density and composition of invertebrates are closely tied to lake salinity. Increased salinity can exceed the tolerance of invertebrates, severely limiting their biomass. In contrast, decreased salinity can lead to altered invertebrate community composition, reducing the abundance of optimal avian prey resources. Great Basin terminal lake ecosystems, including open-water and adjacent aquatic and terrestrial environments, provide resources necessary to sustain many animal populations throughout the year. Although a variety of taxa use terminal lakes, these ecosystems are of acute importance for the millions of migratory waterbirds (for example, shorebirds, wading birds, and waterfowl) dependent on the network of terminal lakes and their associated wetlands. Migratory birds transiting the Pacific and Central Flyways use Great Basin terminal lake ecosystems throughout the year to feed, nest, and transit between wintering and breeding ranges. As such, successful conservation of birds and their habitats requires coordinated management of water and habitats across the Great Basin network of terminal lakes and wetlands. The linkages between water availability and ecosystem vulnerability of terminal lakes in the Great Basin are not well understood. The vulnerability of terminal lakes is related to the factors driving change and adaptive capacity of the lake ecosystem. Saline lake ecosystems are vulnerable when changes in water quantity affect ecosystem function. Water quantity affects salinity, which affects food webs and habitat; these linkages can be investigated with water-quality and food web monitoring. Water quantity also affects inundated habitat, which can be quantified through remote sensing. It is necessary to quantify hydroclimatic and water use controls on water availability to terminal lakes to assess the response of the ecosystems. Remotely sensed data can provide a broad-scale and long-term synoptic view of terminal lake hydrologic characteristics, but ground observations are required to interpret changes in water quality and ecological functions. Some terminal lake basins have ongoing monitoring and modeling efforts within the Great Basin (for example, Great Salt Lake, Carson River Basin), yet most monitoring locations are hydrologically upgradient and too far away from lake inflows to provide an accurate assessment of hydrological trends for the lake ecosystems. Other terminal lakes have no long-term hydrological monitoring in their respective watersheds (for example, Lake Abert). Ecological data collection in the Great Basin is also insufficient to understand how many birds exist on the landscape, how birds use the mosaic of terminal-lake habitats as an interconnected system, and how Great Basin terminal lakes are linked to the larger continental system of the Pacific and Central Flyways. Across agencies and organizations, tracking bird movement, abundance, and diversity is inconsistent, with some lakes having once- or twice-a-year bird survey efforts and a few locations having more intensive ecological data-gathering efforts (for example, Great Salt Lake, Lake Abert). Bridging hydrological and ecological information gaps will improve understanding of the trends in water supply and water quality, habitat availability and usage, and impacts on vulnerable waterbird species, all of which would be used by managers in coordinated conservation of this unique network of terminal-lake habitats. The terminal lakes of the Great Basin are part of the Basin and Range physiographic province that extends from the Colorado Plateau on the east to the Sierra Nevada on the west, and from the Snake River Plain on the north to the Garlock fault and the Mojave block on the south. The Great Basin is larger than 650,000 square kilometers and encompasses most of the State of Nevada but also extends to western Utah, eastern California, southeastern Idaho, southwestern Wyoming, and southeastern Oregon. The climate is arid to semiarid with a hydrologic regime that is snowmelt dominated, providing as much as 75 percent of total annual runoff for the region. Terminal lakes of the Great Basin occupy the lowest areas of closed (endorheic) drainage basins, such that lake levels and water quality respond rapidly to surface-water inflow. Terminal lakes provide local and regional economic value to the States in the Great Basin, including mineral extraction, aquaculture, public works, and recreational uses. As an example, assessments of Great Salt Lake’s ecological health and economic impact find hemispheric importance for the former and regional importance for the latter. Great Salt Lake creates about 7,000 jobs and $2 billion of economic output per year, most of which would be lost with further declines in lake level. The objectives of this Science Strategy are threefold: (1) to identify how changing water availability affects the quality, diversity, and abundance of habitats supporting continental waterbird populations; (2) to highlight the scientific monitoring and assessment needs of Great Basin terminal lakes; and (3) to support coordinated management and conservation actions to benefit those ecosystems, migratory birds, and other wildlife. There are long-term hydrological, ecological, and societal challenges associated with terminal lakes ecosystems in the Great Basin. This Science Strategy benefits partners by providing a conceptual model, nested at different spatial extents, that identifies key scientific information needs to inform coordinated implementation of management and conservation plans within and among hydrologic basins to address these complex challenges.

California, Idaho, Nevada, Oregon, Utah, Wyoming

Flood of June 2008 in Southern Wisconsin

In June 2008, heavy rain caused severe flooding across southern Wisconsin. The floods were aggravated by saturated soils that persisted from unusually wet antecedent conditions from a combination of floods in August 2007, more than 100 inches of snow in winter 2007-08, and moist conditions in spring 2008. The flooding caused immediate evacuations and road closures and prolonged, extensive damages and losses associated with agriculture, businesses, housing, public health and human needs, and infrastructure and transportation. Record gage heights and streamflows occurred at 21 U.S. Geological Survey streamgages across southern Wisconsin from June 7 to June 21. Peak-gage-height data, peak-streamflow data, and flood probabilities are tabulated for 32 USGS streamgages in southern Wisconsin. Peak-gage-height and peak-streamflow data also are tabulated for three ungaged locations. Extensive flooding along the Baraboo River, Kickapoo River, Crawfish River, and Rock River caused particularly severe damages in nine communities and their surrounding areas: Reedsburg, Rock Springs, La Farge, Gays Mills, Milford, Jefferson, Fort Atkinson, Janesville, and Beloit. Flood-peak inundation maps and water-surface profiles were generated for the nine communities in a geographic information system by combining flood high-water marks with available 1-10-meter resolution digital-elevation-model data. The high-water marks used in the maps were a combination of those surveyed during the June flood by communities, counties, and Federal agencies and hundreds of additional marks surveyed in August by the USGS. The flood maps and profiles outline the extent and depth of flooding through the communities and are being used in ongoing (as of November 2008) flood response and recovery efforts by local, county, State, and Federal agencies.

Scientific Investigations Report

Selenium in waters in and adjacent to the Kendrick Project, Natrona County, Wyoming

Selenium in concentrations exceeding the maximum limit, 0.01 milligrams per liter or 10 micrograms per liter, recommended by the U.S. Public Health Service in 'Drinking-Water Standards, 1962,' Public Health Pub. 956, is present in waters in areas near Casper, Wyo. Some streams containing selenium flow into the North Platte River upstream from several municipalities that obtain water from the river and the alluvium along the river. The area of this investigation includes about 725 square miles in Natrona County in central Wyoming. Study effort was most intensive within the area bounded by the North Platte River, Casper Creek, and Casper Canal, the approximate boundaries of the Kendrick irrigation project. Geologic formations in the area contain selenium that may have been derived from deposits of seleniferous material or from volcanic emanations brought down by rain. Formations older than Cretaceous age were not considered as important sources of selenium in waters of the area, because no irrigation water is applied to areas underlain by these rocks. The selenium concentration in 82 samples of Cretaceous rocks ranged from less than 10 to 4,200 ?g/kg (micrograms per kilogram of sample); no correlation was found between selenium concentration and the depth at which the sample was collected. Of four samples of Tertiary rocks analyzed, three contained no selenium and one had a selenium concentration of 40 ?g/kg. The selenium concentration in 93 samples of Quaternary rocks ranged from less than 10 to 52.0 ?g/kg, and the highest selenium concentration was generally found at depths less than 4 feet. No geologic formation has consistently high concentrations of selenium, but high concentrations were found at points throughout the study area. Probably the rocks in any locality could be the source of selenium in the water in the surrounding vicinity. The selenium concentration in water from some wells fluctuates widely. It is concluded that the selenium concentrations in the ground water in these areas have not reached a state of equilibrium in the aquifer. It is possible that such nonequilibrium conditions exist in aquifers throughout much of the area. If so, statements in this report concerning- trends of selenium concentration in ground water are somewhat speculative.Poison Spring Creek, Poison Spider Creek, Oregon Trail Drain, and Casper Creek are the principal tributaries that contribute selenium to the North Platte River. The selenium load, expressed in pounds per day, in Poison Spring Creek and Poison Spider Creek decreased slightly during the first year of sampling and increased slightly during the second year of sampling. The selenium load in Oregon Trail Drain is greatest in late winter and early spring during the period of low flow; the selenium load in Casper Creek varies, but shows no correlation with season and little correlation with stream discharge. The North Platte River above and below the irrigation project had consistently low selenium concentrations, 10 ?g/l (micrograms per liter) or less, in the period April 1968 through June 1969. The total selenium load contributed to the North Platte River from tributaries in the study area is almost undetectable after mixing with the river water. From the fall of 1968 .to the spring of 1969, results of water sampling in areas influenced by irrigation show that the selenium concentration increased at 29 percent of the locations (average net increase of 64 ?g/l), decreased at 34 percent of the locations (average net decrease of 80 ?g/l), and had little (10 ?g/l or .less) or no change at 37 percent of the locations. As a comparison, results of water sampling in areas not influenced by irrigation showed that the selenium concentration increased at 2 percent of the locations (average net increase of 30 ?g/l), decreased at 26 percent of the locations (average net decrease of 30?g/l), and had little or no change at 72 percent of the locations. It is not possible to

Water Supply Paper

Arsenic and uranium occurrence in private wells in Connecticut, 2013–18—A spatially weighted and bedrock geology assessment

The U.S. Geological Survey, in cooperation with the Connecticut Department of Public Health, conducted a study to determine the presence of arsenic and uranium in private drinking water wells in Connecticut. Samples were collected during 2013–18 from wells completed in 115 geologic units, with 2,433 samples analyzed for arsenic and 2,191 samples analyzed for uranium. The study concluded four major findings. In a spatially weighted analysis of groundwater samples collected from more than 2,000 private wells in bedrock aquifers in Connecticut, 3.9 percent of collected samples contained arsenic concentrations greater than the U.S. Environmental Protection Agency’s (EPA) maximum contaminant level (MCL) of 10 micrograms per liter (µg/L), and 4.7 percent of collected samples contained uranium concentrations greater than the EPA MCL of 30 µg/L. Of the 2,433 water samples collected and analyzed from bedrock aquifers in Connecticut, 4.2 percent (102) contained arsenic concentrations at greater than 10 µg/L, and of the 2,191 water samples collected and analyzed from bedrock aquifers in Connecticut, 5.4 percent (118) contained uranium concentrations greater than 30 µg/L. Uranium concentrations greater than or equal to 1 µg/L are relatively ubiquitous across the State of Connecticut, with these concentrations present in 44.9 percent of the State, according to spatially weighted statewide-scale proportion analysis. Of the 115 geologic units studied, 44 had at least one sample with arsenic or uranium concentrations that exceeded the respective constituent’s EPA MCL.

Connecticut

An economic value of remote-sensing information—Application to agricultural production and maintaining groundwater quality

Does remote-sensing information provide economic benefits to society, and can a value be assigned to those benefits? Can resource management and policy decisions be better informed by coupling past and present Earth observations with groundwater nitrate measurements? Using an integrated assessment approach, the U.S. Geological Survey (USGS) applied an established conceptual framework to answer these questions, as well as to estimate the value of information (VOI) for remote-sensing imagery. The approach uses moderate-resolution land-imagery (MRLI) data from the Landsat and Advanced Wide Field Sensor satellites that has been classified by the National Agricultural Statistics Service into the Cropland Data Layer (CDL). Within the constraint of the U.S. Environmental Protection Agency's public health threshold for potable groundwater resources, the USGS modeled the relation between a population of the CDL's land uses and dynamic nitrate (NO3-) contamination of aquifers in a case study region in northeastern Iowa. Employing various multiscaled, multitemporal geospatial datasets with MRLI to maximize the value of agricultural production, the approach develops and uses multiple environmental science models to address dynamic nitrogen loading and transport at specified distances from specific sites (wells) and at landscape scales (for example, across 35 counties and two aquifers). In addition to the ecosystem service of potable groundwater, this effort focuses on the use of MRLI for the management of the major land uses in the study region-the production of corn and soybeans, which can impact groundwater quality. Derived methods and results include (1) economic and dynamic nitrate-pollution models, (2) probabilities of the survival of groundwater, and (3) a VOI for remote sensing. For the northeastern Iowa study region, the marginal benefit of the MRLI VOI (in 2010 dollars) is $858 million ±$197 million annualized, which corresponds to a net present value of $38.1 billion ±$8.8 billion for that flow of benefits in perpetuity. Given that these economic estimates are derived from one case study in a part of only one State, the estimates provide a lower estimate related to the potential value of the Landsat Data Continuity Mission.

Professional Paper

Groundwater withdrawals and regional flow paths at and near Willow Grove and Warminster, Pennsylvania—Data compilation and preliminary simulations for conditions in 1999, 2010, 2013, 2016, and 2017

In 2014, groundwater samples from residential and public supply wells in the vicinity of two former U.S. Navy bases at Willow Grove and Warminster, and an active Air National Guard Station at Horsham, Bucks and Montgomery Counties, Pennsylvania, were found to have concentrations of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), which are per- and polyfluoroalkyl substances (PFAS), above U.S. Environmental Protection Agency (EPA) provisional health advisory (HA) levels for drinking water. Five supply wells near the bases were shut down because of PFAS contamination. In 2016, after EPA established a Lifetime HA for PFAS in drinking water that is lower than the provisional HA in place in 2014, at least 13 additional supply wells near the bases were shut down because of PFAS contamination. At the request of the U.S. Navy, and in consultation with other Federal and State agencies and local stakeholders, the U.S. Geological Survey used historical and recent data on well withdrawals, recharge rates, aquifer properties, groundwater levels, and stream base flow to evaluate regional groundwater-flow paths from identified areas of PFAS groundwater contamination or potential PFAS sources at the bases. Groundwater withdrawals near the bases from public supply and other large wells decreased substantially from the 1990s to 2017, increasing the proportion of groundwater recharge that discharged to local streams. A preliminary groundwater-flow model, calibrated using 1,009 groundwater levels and 17 stream base flow estimates, simulated regional flow paths from the bases and showed that recharge at the bases discharged to withdrawal wells and local streams, generally within a mile or two of the bases. Supply and remediation wells at the bases captured some of the recharge on base areas of possible PFAS contamination, whereas other base recharge was simulated to flow to nearby public supply wells and streams, depending on water use and aquifer recharge conditions between 1999 and 2017. The locations of many residential wells near the bases that were identified by the Navy and Air National Guard as having elevated PFAS concentrations were generally consistent with the simulated flow paths from possible sources at the bases. However, there are some areas of observed PFAS contamination where no flow paths from base sources were simulated. Additionally, no data were available on PFAS concentrations in groundwater in some areas of simulated flow paths from base sources. Data and models used for this study are provided in this report and in digital data releases to support further investigations and model revisions.

Pennsylvania

Nitrogen in the Chesapeake Bay watershed—A century of change, 1950–2050

Foreword Sustaining the quality of the Nation’s water resources and the health of our diverse ecosystems depends on the availability of sound water-resources data and information to develop effective, science-based policies. Effective management of water resources also brings more certainty and efficiency to important economic sectors. Taken together, these actions lead to immediate and long-term economic, social, and environmental benefits that will make a difference to the lives of the almost 400 million people projected to live in the United States by 2050. The Chesapeake Bay is the largest and most productive estuary in the United States and is a vital environmental and economic resource. Approximately half of the water volume of the Chesapeake Bay originates from streams and rivers that drain the 64,243 mi 2 Chesapeake Bay watershed. The Bay and its tributaries have been degraded by excessive nutrients, such as nitrogen, from contributing watersheds. Inputs of nitrogen to the Bay lead to increased algal growth, decreased dissolved oxygen, and declining fisheries. In 2000, the Chesapeake Bay was listed as impaired under the Clean Water Act and Total Maximum Daily Loads (TMDLs) for nutrients and sediment have been established to assist with management actions aimed at nutrient reductions. Effective nutrient management requires an understanding of past, present, and future nutrient sources, fate, and transport in the watershed. The Chesapeake Bay community has been a pioneer in science, management, and regulation to improve water quality. Factors like climate, hydrology, source inputs, and management controls play a vital role in determining the delivery and magnitude of nitrogen inputs to the Bay. Science in the form of monitoring data, predictive tools, and interpretive reports can help inform decisions to better balance the use and control of nitrogen in coastal areas. The findings in this report can contribute to effective management of the Bay and its watershed by providing a synthesis of the understanding of how human activities and environmental change in the watershed in the past, present, and future will influence the export of nitrogen to the Bay. We hope this publication will provide you with insights and information to meet your water resource needs and will foster increased civilian awareness and involvement in the protection and restoration of our Nation’s waters. The information in this report is intended primarily for those interested or involved in resource management and protection, conservation, regulation, and policymaking at the regional and national levels.

Chesapeake Bay watershed

Occurrence of per- and polyfluoroalkyl substances and inorganic analytes in groundwater and surface water used as sources for public water supply in West Virginia

Per- and polyfluoroalkyl substances (PFAS) are widely observed anthropogenic compounds found in water supplies worldwide and increasingly linked with adverse health effects in humans. In 2019, the West Virginia Legislature recognized the contamination risk to public source-water supplies posed by PFAS and passed a resolution that required a statewide PFAS study. The purpose of the resolution was to understand the occurrence and distribution of PFAS contamination throughout the State’s rivers, lakes, and groundwater aquifers. The U.S. Geological Survey has worked in cooperation with the West Virginia Department of Environmental Protection and West Virginia Department of Health and Human Resources to collect raw-water samples at 279 public-water systems across West Virginia. Public-water systems sampled for this study were identified by the West Virginia Department of Health and Human Resources and included all community water systems in the State and all daycares and schools that operate their own water systems. Raw source water was sampled for both groundwater and surface-water sites at the first available tap in the public-water system, prior to any treatment. One hundred and seventy-three samples were collected from groundwater sources and 106 samples were collected from surface-water sources. Parameters collected at the time of sampling included pH, specific conductance, water temperature, dissolved oxygen, turbidity, and alkalinity. PFAS was analyzed at all 279 sites, major ions and trace elements were analyzed at 272 sites, and nutrients were analyzed at 270 sites. The type of source water used for public supply in West Virginia is generally dependent on geology with more groundwater sites sampled in high-yield aquifers such as karst and alluvium. Surface-water sites were more evenly distributed throughout the State and are often the only source used in areas underlain by lower-yielding fractured-rock aquifers. Twenty-four percent of the sites sampled for this study had at least 1 PFAS detected, 47 of which were in groundwater sources and 20 in surface-water sources. Five sites exceeded the U.S. Environmental Protection Agency’s health advisory for combined perfluorooctanoate and perfluorooctanesulfonate concentrations of 70 nanograms per liter. These sites were located in highly susceptible karst and alluvial groundwater aquifers on the east and west sides of the State. Higher PFAS concentrations were more commonly found in groundwater than surface-water sources, and high concentrations and PFAS detections were generally concentrated in the Ohio River Valley and West Virginia’s eastern panhandle. PFAS was rarely detected in groundwater sites in fractured-rock aquifers and abandoned underground coal-mine aquifers in the Appalachian Plateaus Physiographic Province had very little PFAS detected. These data represent a baseline summary of source water in West Virginia. Additional studies may be needed to understand exposure to private homeowners with domestic-water sources, variability of PFAS concentrations over time, and PFAS in finished drinking water as evaluated by current and future drinking-water regulations.

West Virginia

Field manual for the investigation of fish kills

Preface Fish kills are graphic evidence of serious problems in a lake or stream. If the kill is related to the presence of toxic chemicals, there may be human health concerns, in addition to the obvious damage to the ecosystem and the fisheries resources. Depending on the cause of a fish kill, legal and economic ramifications may be involved. If the kill is cause by human or corporate actions, litigation is likely to follow, with possible court-awarded damages and assessed costs for cleanup and restoration. Federal and State agencies have expressed the need for a compendium of known and accepted methods and techniques that should be followed by anyone investigation a fish kill. This manual is an attempt to fill that need. It addresses the many facets involved in a fish kill investigation and provides instruction, guidance, examples, and sample forms that can be used. The U.S. Fish and Wildlife Service is pleased to provide this manual to help fisheries biologists and others prepare for a fish kill investigation. Research and Development (Region 8) has cooperated with the Division of Environmental Contaminants in Fish and Wildlife Enhancement to provide expertise and funds. We hope that the manual proves to be useful for interpreting evidence at the site of a fish kill, and corrective actions, and preparing for appearance as a court witness.

Resource Publication

Water-quality indicators of surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia

The U.S. Geological Survey, in cooperation with the West Virginia Department of Health and Human Resources, studied surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia for the purpose of understanding the influence of surface water on groundwater chemistry. Public groundwater supplies obtained from these aquifers receive substantial recharge from surface-water sources and are highly susceptible to degradation from water-soluble contaminants. Water samples were collected from 4 sites in the Ohio River and 23 groundwater wells in the alluvial aquifer from June 2019 to January 2020. Surface-water influence was assessed through characterization of groundwater quality, determination of recharge sources, estimation of groundwater age, and estimation of the fraction of Ohio River water entering groundwater pumped by wells in the alluvial aquifers. Hydrogeochemical processes controlling solute concentrations in the Ohio River alluvial aquifer were evaluated with multivariate statistical analysis and identified to be primarily controlled by redox processes, input from sources of salinity, and carbonate dissolution. Meteoric recharge from the Ohio River and precipitation on the alluvium are the main sources of water entering the aquifer. The age of groundwater in the system was determined to be primarily from a modern source. Groundwater samples from every well included in this study had detections for at least one geochemical indicator of surface-water influence, and every well was determined to be susceptible and vulnerable to contamination from surface sources. Results from binary mixing models and inverse geochemical models showed that sulfate, silica, and bicarbonate concentrations predict the fraction of Ohio River water entering alluvial wells for preliminary determination of surface-water influence when compared to fractions predicted using a numerical groundwater-flow model. In the absence of extensive analytes and geochemical or groundwater modeling capabilities, preliminary assessment of the fraction of Ohio River water entering groundwater wells in the Ohio River alluvium can be estimated for most sites using a linear relation between the equivalent ratio of bicarbonate to sulfate and the fraction of water computed by the average of the three geochemical models presented in this report. This approximation of the fraction of Ohio River water, coupled with information on the hydrogeological framework and geochemical indicators of surface-water influence, may be sufficient for preliminary assessment of surface-water influence in the absence of more detailed site information or reaction-transport models.

West Virginia

Organic Compounds in Truckee River Water Used for Public Supply near Reno, Nevada, 2002-05

Organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including, in part, pesticides, solvents, gasoline hydrocarbons, personal care and domestic-use products, and refrigerants and propellants. Of 258 compounds measured, 28 were detected in at least 1 source water sample collected approximately monthly during 2002-05 at the intake of the Chalk Bluff Treatment Plant, on the Truckee River upstream of Reno, Nevada. The diversity of compounds detected indicate various sources and uses (including wastewater discharge, industrial, agricultural, domestic, and others) and different pathways (including point sources from treated wastewater outfalls upstream of the sampling location, overland runoff, and groundwater discharge) to drinking-water supply intakes. Three compounds were detected in more than 20 percent of the source-water intake samples at low concentrations (less than 0.1 microgram per liter), including caffeine, p-cresol (a wood preservative), and toluene (a gasoline hydrocarbon). Sixteen of the 28 compounds detected in source water also were detected in finished water (after treatment, but prior to distribution; 2004-05). Additionally, two disinfection by-products not detected in source water, bromodichloromethane and dibromochloromethane, were detected in all finished water samples. Two detected compounds, cholesterol and 3-beta-coprostanol, are among five naturally occurring biochemicals analyzed in this study. Concentrations for all detected compounds in source and finished water generally were less than 0.1 microgram per liter and always less than human-health benchmarks, which are available for about one-half of the compounds. Seven compounds (toluene, chloroform, bromodichloromethane, dibromodichloromethane, bisphenol A, cholesterol, and 3-beta-coprostanol) were measured at concentrations greater than 0.1 microgram per liter. On the basis of this screening-level assessment, adverse effects to human health are expected to be negligible (subject to limitations of available human-health benchmarks).

Fact Sheet

Multi-Disciplinary Approach to Trace Contamination of Streams and Beaches

Concentrations of fecal-indicator bacteria in urban streams and ocean beaches in and around Santa Barbara occasionally can exceed public-health standards for recreation. The U.S. Geological Survey (USGS), working with the City of Santa Barbara, has used multi-disciplinary science to trace the sources of the bacteria. This research is helping local agencies take steps to improve recreational water quality. The USGS used an approach that combined traditional hydrologic and microbiological data, with state-of-the-art genetic, molecular, and chemical tracer analysis. This research integrated physical data on streamflow, ground water, and near-shore oceanography, and made extensive use of modern geophysical and isotopic techniques. Using those techniques, the USGS was able to evaluate the movement of water and the exchange of ground water with near-shore ocean water. The USGS has found that most fecal bacteria in the urban streams came from storm-drain discharges, with the highest concentrations occurring during storm flow. During low streamflow, the concentrations varied as much as three-fold, owing to variable contribution of non-point sources such as outdoor water use and urban runoff to streamflow. Fecal indicator bacteria along ocean beaches were from both stream discharge to the ocean and from non-point sources such as bird fecal material that accumulates in kelp and sand at the high-tide line. Low levels of human-specific Bacteroides, suggesting fecal material from a human source, were consistently detected on area beaches. One potential source, a local sewer line buried beneath the beach, was found not to be responsible for the fecal bacteria.

Fact Sheet

New York Water-Use Program and data, 2000

The U.S. Geological Survey (USGS) has been publishing estimates of water use every five years since 1950 in the Estimated use of water in the United States circular series. In 1978, the Congress expanded the water-use activities of the USGS by establishing the National Water-Use Information Program (NWUIP). The water-use program in New York is part of the NWUIP and is based on a cooperative agreement between the USGS and the New York State Department of Environmental Conservation (NYSDEC). Together, the NYSDEC and USGS collect, compile, and store water-use data to provide a data base that is useful for water-resources management. The New York State Department of Health (NYSDOH) collects a wide variety of data elements relating to public-water supplies such as the name and location of the suppliers and the amount of water withdrawn. This valuable information is provided to the water-use program. The information summarized in this fact sheet has been published in U.S. Geological Survey Circular 1268, Estimated use of water in the United States in 2000 which can be accessed at http://water.usgs.gov/watuse . The 2000 data (by county) as well as previous years data can also be found at that site. Water withdrawal refers to the removal of water from the ground or its diversion from a surface-water source for use. Withdrawals of fresh and saline surface water and fresh ground water during 2000 were included in this study. The categories considered in this data compilation are public-water supply; deliveries to domestic from public-water suppliers and domestic self-supplied; industrial; thermoelectric-power generation; and irrigation. Saline withdrawals were included for the categories of industrial, mining, and thermoelectric-power generation. Saline water is a significant percentage of total withdrawals for the category of thermoelectric-power generation. The categories of withdrawal for which data were compiled for the 2000 calendar year do not include some of the categories that were addressed in 1995 and published in USGS Circular 1200, Estimated use of water in the United States in 1995. For the 2000 compilation, emphasis was placed on ensuring the quality of data that were collected, rather than attempting to address all categories and data elements on a national scale. Categories that were included in 1995 but not in 2000 are commercial; livestock; mining; the non-withdrawal categories of hydroelectric-power generation, wastewater treatment and public-water supply deliveries to commercial and industrial users. Any comparison made between 1995 and 2000 data need to be made with these category differences in mind. In 1995, the categories of commercial, livestock, and mining were about 280 Mgal/d (million gallons per day) of freshwater and 2.7 percent of total freshwater withdrawals. In addition, the report, New York water-use program and data, 1995, U. S. Geological Survey Fact Sheet 014-02, concentrated on freshwater and did not include saline-surface water withdrawals in the figures. Any comparison between the 1995 and 2000 figures need to be made with this in mind. In 2000, about 12,100 Mgal/d (million gallons per day) of fresh surface and ground water and saline surface water were withdrawn from New York's rivers, streams, lakes, estuaries, bays, and aquifers for the categories addressed. Freshwater withdrawals comprised about 7,080 Mgal/d of this total. With a total population of 18,980,000 people in New York State, the total freshwater withdrawals represent an average of more than 370 gal/d (gallons per day) per capita. The amounts of fresh surface water, ground water, saline surface water, and total amounts of water withdrawn by categories of water use in New York during 2000 are shown. Many of New York's large population centers have developed along major rivers and lakes; as a result, more than 87 percent of the freshwater withdrawals in 2000 were from surface-water bodies (6,190 Mgal/d). More than 65 percent of fresh surface-water withdrawals were for thermoelectric-power generation, and about 32 percent were by public-water suppliers. Of the 890 Mgal/d of ground water withdrawn in 2000 statewide, 65 percent was withdrawn by public-water suppliers, and about 16 percent each by industrial and domestic users. More freshwater is withdrawn by thermoelectric plants than for any other water-use category. Of the freshwater withdrawals within New York, about 57 percent were made by fossil-fuel and nuclear powerplants; about 36 percent were for public-water supply; about 4.2 percent was by industrial users, 2.0 percent by domestic users, and about 0.5 percent was for irrigation. Total withdrawals, total surface-water and fresh ground-water withdrawals, in New York are plotted, by county. The categories of public-water supply and thermoelectric power account for the withdrawals that exceed 100 Mgal/d per county. The counties that have public-water supply withdrawals that exceed 100 Mgal/d are: Delaware (453 Mgal/d), Ulster, Nassau, Erie, Sullivan, Westchester, Suffolk, Putnam, and Schoharie (115 Mgal/d). These large withdrawals are from surface water except in Nassau and Suffolk Counties on Long Island, where groundwater is the sole source of freshwater. Delaware, Putnam, Schoharie, Sullivan, Ulster, and Westchester Counties, in the southeastern part of the State, provide surface water to the aqueducts that supply drinking water to New York City. In 2000, the average amount of water delivered to New York City from these counties averaged 1,260 Mgal/d. Erie County, in western New York, had withdrawals totaling 176 Mgal/d of fresh surface water for public-water supply. More freshwater and more total water is withdrawn for the generation of thermoelectric power than for any other water-use category. All of the withdrawals are of surface water. Seven counties have total thermoelectric withdrawals that exceed 500 Mgal/d: Queens (1,690 Mgal/d), Westchester, Oswego, Suffolk, Erie, Orange, and Rockland (560 Mgal/d). The counties of Oswego, Erie, and Orange withdrew only fresh surface water for thermoelectric plants. Their sources of water were Lake Ontario (Oswego County), Niagara River (Erie County), and the Hudson River (Orange County). Queens, Westchester, Suffolk, and Rockland withdraw only saline surface water for the production of thermoelectric power. The sources of saline surface water for the thermoelectric plants in the counties of Queens, Westchester, Suffolk, and Rockland are the estuaries of the Hudson River and East River and bays of the Atlantic Ocean (Long Island Sound and the eastern shore of Jamaica Bay). New York ranked eighth in the United States in 2000 in total withdrawals (fresh and saline water); the States that exceeded New York in total withdrawals are those that have large populations (such as California and Texas) and (or) use large quantities of water for irrigation (such as Florida and Idaho). Of the categories considered for the 2000 compilation, New York did not have nationally significant withdrawals for either irrigation or industrial water use. New York ranked third after California and Texas in withdrawals of freshwater for public supply, in the withdrawal of fresh surface water for public-water supply, in total population, and in number of people served by public-water supplies. New York ranked sixth in total withdrawals for the generation of thermoelectric power and total surface-water withdrawals. Finally, New York ranked fourth in withdrawals of ground water for public supply.

Open-File Report

2017 Monitoring and tracking wet nitrogen deposition at Rocky Mountain National Park

The Colorado Department of Public Health and Environment (CDPHE), the National Park Service (NPS), and the U.S. Environmental Protection Agency (EPA) issued the Nitrogen Deposition Reduction Plan (NDRP) in 2007 to address the effects and trends of nitrogen deposition at Rocky Mountain National Park (RMNP). The agencies chose a glidepath approach to reduce wet nitrogen deposition to a level of 1.5 kilograms of nitrogen per hectare per year (kg N/ha/yr) by the year 2032 to protect sensitive ecosystems within RMNP from adverse effects. Another goal of the NDRP is to “reverse the trend of increasing nitrogen deposition at the park.” Trends in wet deposition data were analyzed at three sites in RMNP and three regional sites outside of the park. Wet nitrogen deposition (5-year rolling average) at Loch Vale in RMNP was 3.3 kg N/ha/yr, which is above the glidepath (2.4 kg N/ha/yr) in 2017. Wet nitrogen deposition has not decreased at RMNP or other sites in the region over the long-term. Ammonium concentrations showed a statistically significant increasing trend at all sites and nitrate concentrations showed a significant decreasing trend at four of the five sites over the period of record. In more recent years (2011-2017), wet nitrogen deposition showed no significant trend at monitoring sites in RMNP. Ammonium concentrations also showed no significant trend over the short-term, however nitrate concentrations did significantly decrease at two of the six sites.

Colorado