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At least 487 records · Page 27Linked to original sources
USGS2026

Utilization of multiple geochronology techniques to constrain the age of laterization and mineralization of the world-class Mount Weld rare earth element deposit, Western Australia

Pervasive chemical weathering on stable cratons may form thick regoliths and elemental enrichment, but constraining the age of regolith formation is challenging. In this study we utilize multiple geochronological techniques on different minerals from the world-class Mount Weld rare earth element (REE) deposit, formed by lateritic weathering of a carbonatite, to constrain the age of formation and provide insight into landscape evolution. The oldest dates, ca. 100 to 38 Ma, are from Lu-Hf dating of churchite [HREE(PO 4 )·2(H 2 O)], a heavy REE phosphate mineral. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane [K(Mn 4+ ,Mn 2+ )₈O₁₆] yielded dates from ca. 40 to 27 Ma. Similarly, (U-Th)/He geochronology of goethite [FeO(OH)] yielded dates ranging from ca. 45 to 19 Ma. Integrating results into regional constraints, suggests 1) churchite formed by mineral saturation in a karst-like setting below the water table from ca. 100 to 40 Ma, 2) with minor uplift and erosion, cryptomelane and goethite formed at or near the water table between ca. 45 and 19 Ma, 3) after ca. 15 to 10 Ma chemical weathering within the profile had ended. Other studies document that the region experienced minimal uplift and a wet, warm climate from ca. 100 Ma to 15 Ma. These conditions and the high carbonate content of the carbonatite promote extensive chemical weathering, a deep weathering profile, and the preservation of the weathered section. This study highlights the use of multiple geochronological techniques utilizing different minerals to provide insight into how laterites form and to constrain the timing and history of the formation of this important mineral deposit.

Western Australia↗
USGS2026

Trace element heterogeneity and crystallization history of the Plesovice zircon: Implications for its use as a U–Pb LA-ICP-MS reference material

Zircon crystals from Plešovice hyperpotassic granulite (HPG) have been widely used as a reference material for LA-ICP-MS dating. Detailed cathodoluminescence (CL) imaging and trace element analysis reveal a complex internal structure of Plešovice zircon linked to extreme chemical heterogeneity, which allows us to distinguish different zircon domains formed during its crystallization: (i) rare low-CL cores enriched in U, Nb, HREE and Y; (ii) dominant sector-zoned to oscillatory-zoned domains, and (iii) CL-bright rims poor in trace elements. Relic fine oscillatory zoned areas are chemically homogeneous, whereas coarsened and blurred areas, and CL-dark replacement domains, are heterogeneous. Based on these data we suggest a complex and protracted zircon evolution: (i) crystallization of metamorphic zircon in anatectic calc-alkaline granulite; (ii) magmatic zircon crystallization at high temperature and pressure in a dry ultrapotassic melt at presence of peritectic garnet; (iii) coupled zircon dissolution-precipitation processes triggered by percolating hydrous residual melt; and (iv) coarsening and replacement of the pre-existing zircon due to prolonged exposure to a reactive fluid/hydrous melt. New CA-ID-TIMS U Pb dates between 337.167 ± 0.080 and 337.840 ± 0.080 Ma confirm crystallization age for HPG zircon at around 337.4 Ma and suggest that previously published dates of 336.37 Ma were biased by non-mitigated lead loss. We thus confirm the U/Pb homogeneity of Plešovice reference zircon despite its chemical heterogeneity. We further discuss the implications of using the chemically extremely heterogeneous Plešovice reference zircon as primary or secondary standard for in-situ LA-ICP-MS geochronology, in particular for quantification of the chemical matrix-dependence of the relative sensitivity factor ( β ) of laser ablation.

Plešovice quarry↗
USGS2006

Accumulation of As, Cd and selected trace elements in tubers of Scirpus aritimus L. from Doñana marshes (South Spain)

The collapse of a pyrite-mining, tailing dam on 1998 contaminated an area of 4286 ha along the Agrio and Guadiamar river valleys in southern Spain. Over 2700 ha of the Doñana marshes, an important wintering area for wetland European birds, were contaminated. This study reports analyses of the tubers of Scirpus maritimus (an important food for greylag geese, Anser anser ) collected in 2000 in the “Entremuros” (spill-affected area) and in nearby unaffected Doñana marshes (control areas). In the spill-affected area mean tuber tissue concentrations of Cd (0.25 mg kg −1 ) and Zn (61 mg kg −1 ) were greater than in those tubers from the control area (0.02 mg kg −1 for Cd, and 22 mg kg −1 for Zn); values of Cd and Zn in “Entremuros” (samples collected two years after the mine spill) were much smaller than those reported only a few months after the accident. Trace elements (As, Fe, Mn and Tl, and to a lesser extent Cd and Pb) showed a preferential accumulation in the outer skin of tubers. Surprisingly, concentrations of As and Fe were greater in tubers from some marsh sites not affected by the mine-spill than in tubers from the “Entremuros”. We suggest that relic river channels within the Doñana marshes may be contaminated by trace elements from historic mining activities. An exhaustive study of macrophytes and other plant species in this area is recommended to identify potential risks to wildlife.

Chemosphere↗
USGS2010

Abundances and distribution of minerals and elements in high-alumina coal fly ash from the Jungar Power Plant, Inner Mongolia, China

The fly ash from the Jungar Power Plant, Inner Mongolia, China, is unique because it is highly enriched in alumina (Al 2 O 3 >50%). The fly ash mainly consists of amorphous glass and mullite and trace amounts of corundum, quartz, char, calcite, K-feldspar, clay minerals, and Fe-bearing minerals. The mullite content in fly ash is as high as 37.4% because of high boehmite and kaolinite contents in feed coal. Corundum is a characteristic mineral formed during the combustion of boehmite-rich coal.Samples from the economizer were sieved into six size fractions (<120, 120-160, 160-300, 300-360, 360-500, and >500 mesh) and separated into magnetic, mullite+corundum+quartz (MCQ) and glass phases for mineralogical and chemical analysis. The corundum content increases but amorphous glass decreases with decreasing particle size. Fractions of small particle sizes are relatively high in mullite, probably because mullite was formed from fine clay mineral particles under high-temperature combustion condition. Similarly, fine corundum crystals formed in the boiler from boehmite in feed coal. The magnetic phase consists of hematite, magnetite, magnesioferrite, and MgFeAlO 4 crystals. The MCQ phase is composed of 89% mullite, 6.1% corundum, 4.5% quartz, and 0.5% K-feldspar.Overall, the fly ash from the power plant is significantly enriched in Al 2 O 3 with an average of 51.9%, but poor in SiO 2 , Fe 2 O 3 , CaO, MgO, Na 2 O, P 2 O 5 , and As. Arsenic, TiO 2 , Th, Al 2 O 3 , Bi, La, Ga, Ni, and V are high in mullite, and the magnetic matter is enriched in Fe 2 O 3 , CaO, MnO, TiO 2 , Cs, Co, As, Cd, Ba, Ni, Sb, MgO, Zn, and V. The remaining elements are high in the glass fraction. The concentration of K 2 O, Na 2 O, P 2 O 5 , Nb, Cr, Ta, U, W, Rb, and Ni do not clearly vary with particle size, while SiO 2 and Hg decrease and the remaining elements clearly increase with decreasing particle size. ?? 2009 Elsevier B.V.

International Journal of Coal Geology↗
USGS2013

Partitioning of selected trace elements in coal combustion products from two coal-burning power plants in the United States

Samples of feed coal (FC), bottom ash (BA), economizer fly ash (EFA), and fly ash (FA) were collected from power plants in the Central Appalachian basin and Colorado Plateau to determine the partitioning of As, Cr, Hg, Pb, and Se in coal combustion products (CCPs). The Appalachian plant burns a high-sulfur (about 3.9 wt.%) bituminous coal from the Upper Pennsylvanian Pittsburgh coal bed and operates with electrostatic precipitators (ESPs), with flue gas temperatures of about 163 °C in the ESPs. At this plant, As, Pb, Hg, and Se have the greatest median concentrations in FA samples, compared to BA and EFA. A mass balance (not including the FGD process) suggests that the following percentages of trace elements are captured in FA: As (48%), Cr (58%), Pb (54%), Se (20%), and Hg (2%). The relatively high temperatures of the flue gas in the ESPs and low amounts of unburned C in FA (0.5% loss-on-ignition for FA) may have led to the low amount of Hg captured in FA. The Colorado Plateau plant burns a blend of three low-S (about 0.74 wt.%) bituminous coals from the Upper Cretaceous Fruitland Formation and operates with fabric filters (FFs). Flue gas temperatures in the baghouses are about 104 °C. The elements As, Cr, Pb, Hg, and Se have the greatest median concentrations in the fine-grained fly ash product (FAP) produced by cyclone separators, compared to the other CCPs at this plant. The median concentration of Hg in FA (0.0983 ppm) at the Colorado Plateau plant is significantly higher than that for the Appalachian plant (0.0315 ppm); this higher concentration is related to the efficiency of FFs in Hg capture, the relatively low temperatures of flue gas in the baghouses (particularly in downstream compartments), and the amount of unburned C in FA (0.29% loss-on-ignition for FA).

International Journal of Coal Geology↗
USGS2009

Relationships between hepatic trace element concentrations, reproductive status, and body condition of female greater scaup

We collected female greater scaup ( Aythya marila ) on the Yukon–Kuskokwim Delta, Alaska during two breeding seasons to determine if concentrations of 18 trace elements in livers and eggs were elevated and if hepatic concentrations correlated with body condition or affected reproductive status. Fifty-six percent, 5%, and 42% of females, respectively, had elevated hepatic cadmium (Cd: >3 μg g −1 dry weight [dw]), mercury (Hg: >3 μg g −1 dw), and selenium (Se: >10 μg g −1 dw). Somatic protein and lipid reserves were not correlated with hepatic Cd or Hg, but there was a weak negative correlation between protein and Se. Hepatic Cd, Hg, and Se were similar in females that had and had not initiated egg production. In a sample of six eggs, 33% and 100%, respectively, contained Se and Hg, but concentrations were below embryotoxicity thresholds. We conclude that trace element concentrations documented likely were not adversely impacting this study population.

Environmental Pollution↗
USGS2005

Systematics of halogen elements and their radioisotopes in thermal springs of the Cascade Range, Central Oregon, Western USA

This study quantifies the cycling of halogen elements through the Cascadia subduction zone based on the chemistry of thermal springs in the Central Oregon Cascade Range and of a mineral spring in the forearc (Willamette Valley). Considerations based on mass balances, element ratios, and 36 Cl/Cl and 129 I/I ratios suggest that halogens discharged through the thermal springs in the Cascade Range are probably derived from magma degassing. Our results indicate that < 35% of the subducted Cl and < 20% of the subducted Br and I could be transported through arc volcanism and the thermal springs, a considerably lower percentage than estimated for other volcanic arcs along the Pacific Rim. A likely explanation for this difference is that a large fraction of the halogens is released from the slab at shallow depths into the serpentinized sub-forearc mantle because of the relatively high temperatures in the subducting Juan de Fuca plate. The small fraction of halogens subducted to depth probably also indicates a low rate of water transport, which is consistent with the observation that the Cascade Range sub-arc mantle is relatively dry and has a low degree of volcanic vigor, compared with other arcs.

Oregon↗
USGS2004

Massive sulfide deposition and trace element remobilization in the Middle Valley sediment-hosted hydrothermal system, northern Juan de Fuca Rdge

The Bent Hill massive sulfide deposit and ODP Mound deposit in Middle Valley at the northernmost end of the Juan de Fuca Ridge are two of the largest modern seafloor hydrothermal deposits yet explored. Trace metal concentrations of sulfide minerals, determined by laser-ablation ICP-MS, were used in conjunction with mineral paragenetic studies and thermodynamic calculations to deduce the history of fluid-mineral reactions during sulfide deposition. Detailed analyses of the distribution of metals in sulfides indicate significant shifts in the physical and chemical conditions responsible for the trace element variability observed in these sulfide deposits. Trace elements (Mn, Co, Ni, As, Se, Ag, Cd, Sb, Pb, and Bi) analyzed in a representative suite of 10 thin sections from these deposits suggest differences in conditions and processes of hydrothermal alteration resulting in mass transfer of metals from the center of the deposits to the margins. Enrichments of some trace metals (Pb, Sb, Cd, Ag) in sphalerite at the margins of the deposits are best explained by dissolution/reprecipitation processes consistent with secondary remineralization. Results of reaction-path models clarify mechanisms of mass transfer during remineralization of sulfide deposits due to mixing of hydrothermal fluids with seawater. Model results are consistent with patterns of observed mineral paragenesis and help to identify conditions (pH, redox, temperature) that may be responsible for variations in trace metal concentrations in primary and secondary minerals. Differences in trace metal distributions throughout a single deposit and between nearby deposits at Middle Valley can be linked to the history of metal mobilization within this active hydrothermal system that may have broad implications for sulfide ore formation in other sedimented and unsedimented ridge systems. ?? 2004 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗
USGS2017

Rare earth element behavior during groundwater – seawater mixing along the Kona Coast of Hawaii

Groundwater and seawater samples were collected from nearshore wells and offshore along the Kona Coast of the Big Island of Hawaii to investigate rare earth element (REE) behavior in local subterranean estuaries. Previous investigations showed that submarine groundwater discharge (SGD) is the predominant flux of terrestrial waters to the coastal ocean along the arid Kona Coast of Hawaii. Groundwater and seawater samples were filtered through 0.45 μm and 0.02 μm pore-size filters to evaluate the importance of colloidal and soluble (i.e., truly dissolved ionic species and/or low molecular weight [LMW] colloids) fractions of the REEs in the local subterranean estuaries. Mixing experiments using groundwater collected immediately down gradient from a wastewater treatment facility (WWTF) proximal to the Kaloko-Hanokohau National Historic Park, and more “pristine” groundwater from a well constructed in a lava tube at Kiholo Bay, were mixed with local seawater to study the effect of solution composition (i.e., pH, salinity) on the concentrations and fractionation behavior of the REEs as groundwater mixes with seawater in Kona Coast subterranean estuaries. The mixed waters were also filtered through 0.45 or 0.02 μm filters to ascertain the behavior of colloidal and soluble fractions of the REEs across the salinity gradient in each mixing experiment. Concentrations of the REEs were statistically identical (two-tailed Student t -test, 95% confidence) between the sequentially filtered sample aliquots, indicating that the REEs occur as dissolved ionic species and/or LMW colloids in Kona Coast groundwaters. The mixing experiments revealed that the REEs are released to solution from suspended particles or colloids when Kona Coast groundwater waters mix with local seawater. The order of release that accompanies increasing pH and salinity follows light REE (LREE) > middle REE (MREE) > heavy REE (HREE). Release of REEs in the mixing experiments is driven by decreases in the free metal ion activity in solution and the concomitant increase in the amount of each REE that occurs in solution as dicarbonato complexes [i.e., Ln(CO 3 ) 2 - ] as pH increases across the salinity gradient. Input-normalized REE patterns of Kona Coast groundwater and coastal seawater are nearly identical and relatively flat compared to North Pacific seawater, indicating that SGD is the chief source of these trace elements to the ocean along the Kona Coast. Additionally, REE concentrations of the coastal seawater are between 10 and 50 times higher than previously reported open-ocean seawater values from the North Pacific, further demonstrating the importance of SGD fluxes of REEs to these coastal waters. Taken together, these observations indicate that large-scale removal of REEs, which characterizes the behavior of REEs in the low salinity reaches of many surface estuaries, is not a feature of the subterranean estuary along the Kona Coast. A large positive gadolinium (Gd) anomaly characterizes groundwater from the vicinity of the WWTF. The positive Gd anomaly can be traced to the coastal ocean, providing further evidence of the impact of SGD on the coastal waters. Estimates of the SGD fluxes of the REEs to the coastal ocean along the Kona Coast (i.e., 1.3 – 2.6 mmol Nd day -1 ) are similar to recent estimates of SGD fluxes of REEs along Florida’s east coast and to Rhode Island Sound, all of which points to the importance of SGD as significant flux of REEs to the coastal ocean.

Hawaii↗
USGS2020

Zircon-hosted melt inclusion record of silicic magmatism in the Mesoproterozoic St. Francois Mountains terrane, Missouri: Origin of the Pea Ridge iron oxide-apatite rare earth element deposit and implications for regional crustal pathways of mineralization

Voluminous silicic magmatism was coeval with iron ore mineralization in the St. Francois Mountains terrane in southeast Missouri, part of the broader Mesoproterozoic Granite-Rhyolite province along the eastern margin of Laurentia. Some of the iron deposits contain extraordinary endowments of critical elements, such as the Pea Ridge iron oxide-apatite (IOA) deposit, which has an average grade of ~12 wt% rare earth oxides in breccia pipes that flank the ore body. To assess the role of silicic magmatism in the genesis of the Pea Ridge deposit, we present a high-spatial resolution study of zirconhosted melt inclusions from rhyolitic ash-flow tuffs. Melt inclusion data are combined with textural, geochemical, and geochronological analyses of zircon hosts to elucidate the magmatic-hydrothermal evolution of the Pea Ridge system. Two contemporaneous silicic igneous centers in the St. Francois Mountains terrane, Bourbon and Eminence, were studied for comparison. Pea Ridge melt inclusions are trachydacitic to rhyolitic (~63-79 wt% SiO2, ~5.6-11.7 wt% Na2O+K2O) with very high Cl in the least-evolved and most alkaline melt inclusions (~2,000-5,000 ppm Cl). Rare earth elements (REE) in melt inclusions have identical chondrite-normalized patterns to the mineralized breccia pipes, but with systematically lower absolute concentrations. Haplogranite ternary pressures range from ~0.5-10 kbar, with an average of ~2-3 kbar (7-12 km depth), and liquidus temperatures are ~850-950 °C, with an average of ~920 °C. Silicate and phosphate mineral inclusions have compositions that overlap minerals from the iron ore body and breccia pipes, recording a transition from igneous to hydrothermal zircon growth. Igneous iron oxide inclusions have compositions that indicate Pea Ridge magmas were reduced to moderately oxidized (log fO2 of -0.8 to -1.84 NNO). Zircons from two Pea Ridge samples have 207Pb/206Pb concordia ages of 1456 ± 9 Ma and 1467 ± 13 Ma that overlap published ages for the breccia pipes and iron ore zones of the Pea Ridge deposit. A population of texturally and chemically disrupted zircons have discordant domains that correspond to high Fe, U, and REE concentrations, consistent with the unique geochemical attributes of the IOA-REE ore body. Inherited cores in Pea Ridge and Bourbon zircons have concordant 207Pb/206Pb dates of 1550-1618 Ma, providing direct evidence of cratonic basement beneath these centers. Oxygen isotope data for inherited and autocrystic igneous zircons span from mantle to crustal values (18Ozircon=5.5-7.9‰). Our data are consistent with a model in which metasomatized mantle components were mixed with cratonic and accreted crustal material in a back-arc or rifted segment of a volcanic arc, with ore fluids derived from Cl-rich melts to transport Fe and REE in a long-lived (tens of Myr), pulsed, magmatic-hydrothermal system. Bourbon, which also possesses IOA mineralization, shares key petrologic similarities with the Pea Ridge system, whereas Eminence, which is not mineralized, has disparate geochemical and isotopic signatures that indicate it formed in a different crustal setting. The location of Pea Ridge and Bourbon along a cratonic margin may have been important in focusing silicic melts and mineralization in the upper crust, serving as a guide for future exploration efforts.

Missouri↗
USGS2021

A reactive transport approach to modeling cave seepage water chemistry II: Elemental signatures

Karst systems are useful for examining spatial and temporal variability in Critical Zone processes because they provide a window into the subsurface where waters have interacted with vegetation, soils, regolith, and bedrock across a range of length and timescales. These hydrologic pathways frequently include the precipitation of speleothems, which provide long-term archives of climate and environmental change. Trace element ratios in speleothems (Mg/Ca, Sr/Ca, Ba/Ca) have the potential to provide information about past changes in rainfall and infiltration, but controls on them can be complex and their interpretation must be based on an understanding of the modern cave system. Here we integrate observations of surface conditions, bedrock, soil, and drip water chemistry of Blue Spring Cave in Tennessee, USA with the reactive transport model CrunchTope, which we have calibrated for karst systems to investigate the primary controls on trace element variations in cave seepage waters. We find that measured drip water Mg/Ca and Sr/Ca are captured within the model through variable amounts of limestone dissolution followed by precipitation of secondary calcite that happens within the cave rather than the host limestone. However, strong spatial controls on drip water Mg/Ca and Sr/Ca likely reflect seepage water interactions with variable amounts of diagenetic phases in the host rock. In contrast, Ba/Ca values are consistent across the cave and vary with effective rainfall, suggesting that this parameter may be the most consistent metric for limestone dissolution and prior calcite precipitation and can act as a proxy for rainfall and infiltration in this cave system. Our findings emphasize the importance of evaluating spatial heterogeneity in cave drip waters and outline a novel modeling approach for determining the dominant controls on drip water chemistry in support of the interpretations of paleoclimate records.

Geochimica et Cosmochimica Acta↗
USGS2019

Selected trace-elements in alluvium and rocks, western Mojave Desert, southern California

Concentrations of twenty-seven elements, including naturally-occurring water-quality contaminants arsenic, chromium, and uranium, were measured in 217 samples of alluvium and rock from the western Mojave Desert, southern California, using portable (pXRF) and laboratory (LXRF) X-ray fluorescence. Comparison of measurements with NIST-traceable standards was good, although pXRF overestimated iron compared to LXRF. Results suggest pXRF survey data are sufficiently accurate to assess regional geochemical differences in geologic-source terrains. Principal component analysis showed rubidium and potassium were associated with alluvium eroded from felsic terrain, while iron, copper, chromium, and to a lesser extent titanium, manganese, and nickel were associated with alluvium eroded from mafic terrain. Zinc, vanadium, and arsenic were associated with alluvium eroded from hydrothermal terrain. Elemental assemblages associated with different source terrains were traced spatially to identify the source and composition of alluvium composing aquifers pumped for water supply. Changes in geologic source terrain to the Mojave River, associated with movement along the San Andreas Fault over the past one to five million years, reduced the mafic fraction and increased the felsic fraction of alluvium deposited to the regionally important floodplain aquifer along the Mojave River—lowering chromium concentrations in alluvium through geologic time. Comparison of pXRF and sequential extraction data from 40 samples showed arsenic and uranium were more abundant on the surfaces of mineral grains, while chromium and vanadium remained mostly within unweathered mineral grains—suggesting arsenic and uranium may be more readily mobilized into groundwater with changes in pH, redox, or ionic strength than chromium or vanadium.

California↗
USGS2024

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration↗
USGS2009

Comparisons of physical experiment and discrete element simulations of sheared granular materials in an annular shear cell

In this study, we report a direct comparison between a physical test and a computer simulation of rapidly sheared granular materials. An annular shear cell experiment was conducted. All parameters were kept the same between the physical and the computational systems to the extent possible. Artificially softened particles were used in the simulation to reduce the computational time to a manageable level. Sensitivity study on the particle stiffness ensured such artificial modification was acceptable. In the experiment, a range of normal stress was applied to a given amount of particles sheared in an annular trough with a range of controlled shear speed. Two types of particles, glass and Delrin, were used in the experiment. Qualitatively, the required torque to shear the materials under different rotational speed compared well with those in the physical experiments for both the glass and the Delrin particles. However, the quantitative discrepancies between the measured and simulated shear stresses were nearly a factor of two. Boundary conditions, particle size distribution, particle damping and friction, including a sliding and rolling, contact force model, were examined to determine their effects on the computational results. It was found that of the above, the rolling friction between particles had the most significant effect on the macro stress level. This study shows that discrete element simulation is a viable method for engineering design for granular material systems. Particle level information is needed to properly conduct these simulations. However, not all particle level information is equally important in the study regime. Rolling friction, which is not commonly considered in many discrete element models, appears to play an important role. ?? 2009 Elsevier Ltd.

Mechanics of Materials↗
USGS2022

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗
USGS2021

Improving ChemCam LIBS long-distance elemental compositions using empirical abundance trends

The ChemCam instrument on the Curiosity rover provides chemical compositions of Martian rocks and soils using remote laser-induced breakdown spectroscopy (LIBS). The elemental calibration is stable as a function of distance for Ti, Fe, Mg, and Ca. The calibration shows small, systematically increasing abundance trends as a function of distance for Al, Na, K, and to some extent, Si. The distance effect is known to be due to a dependence with distance on the relative strengths of atomic transition lines. Emission lines representing transitions from relatively low energy levels remain intense at longer distances while emission lines representing transitions from higher energy levels decrease in intensity more rapidly as a function of distance. The multivariate algorithms used to determine elemental compositions rely on a large number of emission lines in many cases, so rather than trying to correct all emission lines, a study was made of the predicted compositions as a function of distance, in order to determine an empirical correction. Abundance trends can be well approximated by a linear trend with distance within the ranges of abundances and distances observed up to ~6 m. Data from 11 distinct geological members and data groups of the Murray formation in Gale crater, Mars, were used to form the model, selecting the members and data groups yielding the best statistics. The model was tested using data from several targets observed from two different distances, and using data from the Kimberley formation, the composition of which is significantly different from the Murray formation, showing that the model works on other compositions beyond those used to build the model. For long-distance observations up to ~6 m, corrections can be made back to an equivalent composition at the median distance of ChemCam observations (2.6 m). The model has been validated up to 6.2 m, although ChemCam is able to observe bedrock targets to >7 m, and iron meteorites to distances of >9 m.

Spectrochimica Acta Part B: Atomic Spectroscopy↗
USGS2008

Determining annual suspended sediment and sediment-associated trace element and nutrient fluxes

Suspended sediment is a major factor in the biological and geochemical cycling of trace elements and nutrients in aquatic systems. The design of effective studies involving the collection, processing, and subsequent chemical analysis of suspended sediment requires a clear understanding of the problems associated with using this sample medium. This review summarizes the current state of knowledge relative to the various issues/problems associated with the collection of representative suspended sediment samples in fluvial systems. It also addresses issues associated with accurately determining the concentrations and fluxes of sediment-associated trace elements and nutrients.

Science of the Total Environment↗
USGS2008

The effects of land use on fluvial sediment chemistry for the conterminous U.S. - Results from the first cycle of the NAWQA Program: Trace and major elements, phosphorus, carbon, and sulfur

In 1991, the U.S. Geological Survey (USGS) began the first cycle of its National Water Quality Assessment (NAWQA) Program. The Program encompassed 51 river basins that collectively accounted for more than 70% of the total water use (excluding power generation), and 50% of the drinking water supply in the U.S. The basins represented a variety of hydrologic settings, rock types (geology), land-use categories, and population densities. One aspect of the first cycle included bed sediment sampling; sites were chosen to represent baseline and important land-use categories (e.g., agriculture, urban) in each basin. In total, over 1200 bed sediment samples were collected. All samples were size-limited (< 63????m) to facilitate spatial and/or temporal comparisons, and subsequently analyzed for a variety of chemical constituents including major (e.g., Fe, Al,) and trace elements (e.g., Cu, Zn, Cd), nutrients (e.g., P), and carbon. The analyses yielded total (??? 95% of the concentrations present), rather than total-recoverable chemical data. Land-use percentages, upstream underlying geology, and population density were determined for each site and evaluated to asses their relative influence on sediment chemistry. Baseline concentrations for the entire U.S. also were generated from a subset of all the samples, and are based on material collected from low population (??? 27??p km- 2) density, low percent urban (??? 5%), agricultural or undeveloped areas. The NAWQA baseline values are similar to those found in other national and global datasets. Further, it appears that upstream/underlying rock type has only a limited effect (mostly major elements) on sediment chemistry. The only land-use category that appears to substantially affect sediment chemistry is percent urban, and this result is mirrored by population density; in fact, the latter appears more consistent than the former.

Science of the Total Environment↗