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At least 487 records · Page 27Linked to original sources
USGS1992

The stable isotope geochemistry of acid sulfate alteration

Acid sulfate wall-rock alteration, characterized by the assemblage alunite + kaolinite + quartz + or - pyrite, results from base leaching by fluids concentrated in H 2 SO 4 . Requisite amounts of H 2 SO 4 can be generated by different mechanisms in three principal geologic environments: (1) by atmospheric oxidation of sulfides in the supergene environment, (2) by atmospheric oxidation at the water table in the steam-heated environment of H 2 S released by deeper, boiling fluids, and (3) by the disproportionation of magmatic SO 2 to H 2 S and H 2 SO 4 during condensation of a magmatic vapor plume at intermediate depths in magmatic hydrothermal environments in silicic and andesitic volcanic terranes. In addition, coarse vein alunite may form in a magmatic steam environment from rapid release of an SO 2 -rich magmatic vapor phase at high temperature and low pressure or from the oxidation of a more reduced magmatic vapor by entrained atmospheric oxygen in the carapace of a volcanic edifice.Alunite [KAl 3 (SO 4 ) 2 (OH) 6 ] contains four stable isotope sites and complete analyses (delta D, delta 18 O (sub SO 4 ) , delta 18 O OH , and delta 34 S) are now possible. Except for delta 18 O OH in magmatic hydrothermal alunites, primary values are usually retained. In cooperation with many colleagues, over 500 measurements have been made on nearly 200 samples of alunite and associated minerals from 23 localities, and 55 additional analyses have been taken from the literature. This survey confirms that kinetic factors play an important role in the stable isotope systematics of alunite and acid sulfate alteration. To a very large extent they form the isotopic basis for distinguishing between environments of acid sulfate alteration, and they provide important insights into attendant processes. Stable isotope analyses of alunite, often in combination with those on associated sulfides and kaolinite, permit recognition of environments of formation and provide information on origins of components, processes (including rates), physical-chemical environments, and temperatures of formation.Supergene acid sulfate alteration may form over any sulfide zone when it is raised above the water table by tectonics or exposed by erosion. It may overprint earlier acid sulfate assemblages, particularly the magmatic hydrothermal assemblages which are pyrite rich such as at El Salvador, Chile; Rodalquilar, Spain; and Goldfield, Nevada. Supergene alunite normally has delta 34 S values virtually identical to precursor sulfides unless bacteriogenic reduction of aqueous sulfate takes place in standing pools of water. delta D values are close to that of local meteoric water unless extensive evaporation occurs. delta D and delta 18 O OH values of supergene alunites from a range of latitudes fall in a broad zone parallel to the meteoric water line much the way delta D and delta 18 O values of associated halloysite-kaolinite fall near the kaolinite line of Savin and Epstein (1970). delta 18 O (sub SO 4 ) values are kinetically controlled and will reflect the hydro-geochemistry of the environment. delta 18 O (sub SO 4 -OH) alues are grossly out of equilibrium and large negative values are definitive of a supergene origin.In steam-heated environments, such as those at the Tolfa district, Italy, and Marysvale, Utah, and numerous modern geothermal systems, acid sulfate alteration zones are characterized by pronounced vertical zoning. Such acid sulfate alteration may occur over adularia-sericite-type base and precious metal ore deposits such as the one at Buckskin, Nevada. Initial delta 18 O (sub SO 4 ) and delta 34 S values are kinetically controlled, but delta 18 O (sub SO 4 ) values usually reach equilibrium with fluids, and even delta 34 S values may reflect partial exchange with H 2 S where the residence time of aqueous sulfate is sufficient. Most alunites of steam-heated origin have delta 34 S values the same as those of precursor H 2 S (and as related sulfides, if present) and delta D values similar to that of local meteoric water. In the samples analyzed, most delta 18 O (sub SO 4 -OH) values give reasonable temperatures of 90 degrees to 160 degrees C, indicating that delta 18 O (sub SO 4 ) and delta 18 O OH values reflect a close approach to equilibrium with the fluid. The delta 18 O (sub SO 4 ) and delta 18 O OH values also reflect the degree of exchange of the meteoric fluids with wall rock. Coeval kaolinites typically have delta 18 O and delta D values to the left of the kaolinitc line.Magmatic hydrothermal, acid sulfate alteration zones in near-surface epithermal deposits such as Summitville, Colorado. Julcani, Peru, and Red Mountain and Lake City, Colorado, are characterized by vertical orientation and horizontal zoning, the presence of coeval pyrite, PO 4 analogues of alunite, zunyite, and later gold, pyrite and enargite, and often other Cu-As-Sb-S minerals. Acid sulfate alteration assemblages also occur as late stages in the porphyry-copper deposit at E1 Salvador, Chile. In the examples studied, magmatic hydrothermal alunites have delta D values close to those for magmatic water. delta 34 S values are 16 to 28 per mil larger than those for associated pyrite, reflecting equilibrium between aqueous H 2 S and SO 4 formed by the disproportionation of magmatically derived SO 2 . delta 18 O (sub SO 4 ) values are usually 8 to 18 per mil and vary systematically with delta 34 S values, reflecting variations in temperature and/or H 2 S/SO 4 fluid ratios. Further variation in delta 18 O (sub SO 4 ) values may result if SO 2 condenses in mixed magmatic meteoric water fluids. delta 18 O (sub SO (sub 4-) OH) values of magmatic hydrothermal alunites are generally unsuitable for temperature determinations because of retrograde exchange in the OH site, but delta 34 S (sub alunite-pyrite) values provide reliable temperature estimates.Magmatic steam environments appear to occur over a range of depths and are characterized by monomineralic veins of coarse alunite in variably alunitized and kaolinized wall rocks containing minor pyrite. Alunite formed in the magmatic steam environment can usually be recognized by delta 34 S near delta 34 S (sub Sigma S) values and delta D and delta 18 O (sub SO 4 ) values near magmatic values. Magmatic steam alunite differs from magmatic hydrothermal alunite by having delta 34 S close to delta 34 S (sub Sigma S) values of the system. delta 18 O (sub SO (sub 4-) OH) values of most magmatic steam alunite give temperatures ranging from 90 degrees to 210 degrees C but, for reasons which are not understood, some temperatures as well as calculated delta 18 O (sub H 2 O) values are too low for presumed precipitation from a magmatic vapor phase. Magmatic steam environments may occur over porphyry-type mineralization as at Red Mountain, Colorado, and Alunite Ridge, Utah, and over or adjacent to adularia-sericite-type deposits in volcanic domes as at Cactus, California.

Economic Geology↗
USGS1971

Structure and petrology of the alpine-type peridotite at Burro Mountain, California, U.S.A.

The alpine-type peridotite at Burro Mountain is a partially serpentinized harzburgite-dunite body approximately 2 km in diameter. It lies in a chaotic mélange derived from the Franciscan Formation (Upper Jurassic to Upper Cretaceous) of the southern Coast Ranges of California. The peridotite is bounded on the east by a vertical fault in the Nacimiento fault zone that brings sedimentary rocks of Taliaferro's (1943 b ) Asuncion Group (Upper Cretaceous) into contact with the peridotite. The peridotite appears to be one of a number of tectonic lenses, having a wide range in size, that make up the mélange . These lenses include metagraywacke, metachert, greenstone, amphibolite, and blueschist, as well as ultramafic rocks, and represent a wide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinite zone 10–15 m thick. The peridotite was tectonically emplaced at its present level as a cold solid mass and had little effect on the mineral assemblages of the Franciscan Formation. Local development of lawsonite and aragonite in shear zones may be related to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of the peridotite. It is a lithologically uniform rock that has an olivine: orthopyroxene ratio of approximately 75:25. Accessory clinopyroxene and chromian spinel generally make up less than 5 per cent of the harzburgite. Dunite, composed of olivine, accessory chromian spinel (< 5 per cent), and trace amounts of pyroxene, makes up approximately 40 per cent of the peridotite and occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositional variations and chromian spinel shows a large range in the cation ratio Cr/(Cr+Al+ Fe 3+ ). The compositional variations in these minerals are related to original differences in bulk chemical composition. The following compositional ranges were determined for minerals in the harzburgite: olivine, Fo 91.1 −Fo 91.4 ; orthopyroxene, En 89.8 −En 91.1 ; clinopyroxene, Ca 47.0 Mg 50.0 Fe 3.0 −Ca 48.7 Mg 48.2 Fe 3.1 ; chromian spinel, Cr/(Cr+Al+Fe 3+ ) 0.37−0.55. The pyroxenes have a range in A1 2 O 3 content of 1.3−3.0 wt per cent. Olivine from dunite ranges from Fo 91 to Fo 92 7 and the chromian spinel has a range in the Cr/(Cr+Al+Fe 3+ ) ratio of 0.30−0.75. Although all the dunites are lithologically similar, three distinct types are recognized on the basis of composition of coexisting olivine and chromian spinel. Structural relations between the three types of dunite suggest three periods of emplacement (possibly overlapping) of dunite into harzburgite. The evidence indicates that the dunite, and probably also the harzburgite crystallized from an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotite was subjected to a deep-seated plastic deformation and recrystallization. The first phase of the deformation produced a pervasive, planar structural element (S 1 ) that crosscuts many harzburgite-dunite contacts. It is probable that some of the dunite sills were emplaced during this deformation. The foliation, S 1 , is defined by layers of different orthopyroxene content in harzburgite, and by discontinuous layers of chromian spinel in dunite. Flow or slip along S 1 produced slip folds in harzburgite—dunite contacts with axial planes parallel to S 1 . At a later stage, isoclinal folds developed in S 1 , and the present olivine microfabric was probably formed by recrystallization in the stress field that produced the isoclinal folding. In the olivine microfabric, X tends to be perpendicular to the axial planes (S 2 ) of the isoclinal folds and Y and Z tend to form double maxima in S 2 approximately 90° apart. Mg−Fe 2+ distribution between coexisting mineral pairs yields a calculated temperature of formation of approximately 1200 °C. Although this temperature is only a nominal value, it indicates that the mineral pairs equilibrated at a significantly high temperature. In view of the deformation and recrystallization, the calculated temperature possibly represents subsolidus re-equilibration of the minerals during this event. The deformation and recrystallization probably occurred shortly after crystallization while the peridotite was still at a high temperature. A later deep-seated deformation produced small scattered kink folds in S 1 that tend to disrupt the major olivine microfabric. The kink folding was accompanied or followed by the development of kink bands in olivine that reflect intragranular gliding on the system T = [ Okl ], t = [100]. The kink bands probably formed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took place in the mantle, the peridotite mass was tectonically detached and moved upward to its present level in the crust. Cleavages, joints, and faults provided channels for water to pervade the peridotite and allow alteration of the primary minerals.

California↗
USGS1960

Stratigraphic and geotectonic relationships in northern Vermont and southern Quebec

Stratified rocks of early and middle Paleozoic age form a belt of northeast-trending anticlinoria and synclinoria of middle Paleozoic age, in northern Vermont and adjacent parts of southern Quebec . The foreland margin of this belt, in the Champlain and St. Lawrence valleys to the west, is cut by eastward-dipping thrust faults of middle Paleozoic age and by later northeast-trending normal faults. The Green Mountain anticlinorium, which is the dominant structure of the region, is flanked to the west, on the foreland, by the St. Albans-Hinesburg-Middlebury synclinorium and to the east, in the midst of the folded belt, by the Connecticut Valley-Gaspe synclinorium. The principal thrust faults, notably the Champlain and Philipsburg thrusts, are in the west limb of the St. Albans-Hinesburg-Middlebury synclinorium. East of the Connecticut Valley-Gaspe synclinorium is the Boundary Mountain anticlinorium, in eastern Vermont and adjacent New Hampshire and along the international boundary between Quebec and Maine. Two contrasting intergradational lithic assemblages, the graywacke-shale assemblage and the carbonate-quartzite assemblage, characterize the protolith of the bedded rocks. The graywacke-shale assemblage includes thick sections of lower Paleozoic strata, portions of which lap both gradationally and unconformably westward on the foreland, particularly in Quebec ; it also includes middle Paleozoic strata that offlap eastward away from the foreland. The carbonate-quartzite assemblage laps both unconformably and gradationally eastward over the graywacke-shale assemblage in sections of the middle Paleozoic east of the axis of the Green Mountain anticlinorium. Stratigraphic correlation has become well established in the foreland belt where numerous distinctive and fossiliferous strata, chiefly of the carbonate-quartzite assemblage, have escaped metamorphism. It is also fairly clear in sections in the eastern foreland and western part of the Green Mountain anticlinorium, where the strata of the carbonate-quartzite assemblage extend eastward and interfinger with rocks of the graywacke-shale terrane. Rocks that are entirely of the graywacke-shale assemblage have been correlated in the present study. The stratified rocks west of the axis of the Green Mountain anticlinorium are of Cambrian(?), Cambrian, and Ordovician age; those to the east range in age from Cambrian to Devonian. The geotectonic setting of the region is the once mobile belt of the Appalachian orthogeosyncline, which is at the southeastern margin of the stable continental block, or craton, of North America. The orthogeosyncline was a belt, chiefly of subsidence, that embraced two parallel and adjoining longitudinal zones: the eugeosynclinal zone, which was more mobile, and the miogeosynclinal zone, which was less mobile. Second- and third-generation geosynclines are superimposed not only on the orthogeosyncline but also on adjoining parts of the craton. Uplift, and finally folding, gradually superseded subsidence in the orthogeosyncline. Local uplift, chiefly within the eugeosynclinal zone, provided most of the clastic sediments, principally those of the graywacke-shale assemblage. General stabilization of the western part of the orthogeosyncline at the end of the Ordovician was accompanied by eastward migration of the miogeosynclinal zone. Localized uplift within the eastern part of the orthogeosyncline at this time is marked by unconformities referred to the Taconic disturbance. Folding and uplift after the Early Devonian is shown by angular unconformities referred to the Acadian and Appalachian orogenies. The interpretation of the geotectonic relations of the bedded rocks is aided by critical features of the magmatic activity that began with, accompanied, and followed the diastrophism.

Vermont, Quebec↗
USGS2005

Alunite in the Pascua-Lama high-sulfidation deposit: Constraints on alteration and ore deposition using stable isotope geochemistry

The Pascua-Lama high-sulfidation system, located in the El Indio-Pascua belt of Chile and Argentina, contains over 16 million ounces (Moz) Au and 585 Moz Ag. The deposit is hosted primarily in granite rocks of Triassic age with mineralization occurring in several discrete Miocene-age phreatomagmatic breccias and related fracture networks. The largest of these areas is Brecha Central, which is dominated by a mineralizing assemblage of alunite-pyrite-enargite and precious metals. Several stages of hydrothermal alteration related to mineralization are recognized, including all types of alunite-bearing advanced argillic assemblages (magmatic-hydrothermal, steam-heated, magmatic steam, and supergene). The occurrence of alunite throughout the paragenesis of this epithermal system is unusual and detailed radiometric, mineralogical, and stable isotope studies provide constraints on the timing and nature of alteration and mineralization of the alunite-pyrite-enargite assemblage in the deposit. Early (preore) alteration occurred prior to ca. 9 Ma and consists of intense silicic and advanced argillic assemblages with peripheral argillic and widespread propylitic zones. Alunite of this stage occurs as fine intergrowths of alunite-quartz ± kaolinite, dickite, and pyrophyllite that selectively replaced feldspars in the host rock. Stable isotope systematics suggest a magmatic-hydrothermal origin with a dominantly magmatic fluid source. Alunite is coeval with the main stage of Au-Ag-Cu mineralization (alunite-pyrite-enargite assemblage ore), which has been dated at approximately 8.8 Ma. Ore-stage alunite has an isotopic signature similar to preore alunite, and Δ 34 S alun-py data indicate depositional temperatures of 245° to 305°C. The δ D and δ 18 O data exclude significant involvement of meteoric water during mineralization and indicate that the assemblage formed from H 2 S-dominated magmatic fluids. Thick steam-heated alteration zones are preserved at the highest elevations in the deposit and probably formed from oxidation of H 2 S during boiling of the magmatic ore fluids. Coarsely crystalline magmatic steam alunite (8.4 Ma) is restricted to the near-surface portion of Brecha Central. Postmineral alunite ± jarosite were previously interpreted to be supergene crosscutting veins and overgrowths, although stable isotope data suggest a mixed magmatic-meteoric origin for this late-stage alteration. Only late jarosite veinlets (8.0 Ma) associated with fine-grained pseudocubic alunite have a supergene isotopic signature. The predominance of magmatic fluids recorded throughout the paragenesis of the Pascua system is atypical for high-sulfidation deposits, which typically involve significant meteoric water in near-surface and peripheral alteration and, in some systems, even ore deposition. At Pascua, the strong magmatic signature of both alteration and main-stage (alunite-pyrite-enargite assemblage) ore is attributed to limited availability of meteoric fluids. This is in agreement with published data for the El Indio-Pascua belt, indicating an event of uplift and subsequent pediment incision, as well as a transition from semiarid to arid climatic conditions, during the formation of the deposit in the mid to late Miocene.

Economic Geology↗
USGS2005

U-Pb zircon ages and Pb isotope geochemistry of gold deposits in the Carolina slate belt of South Carolina

Volcanic rocks of the Persimmon Fork Formation host the largest known gold mines of the Carolina slate belt. U-Pb (SHRIMP) zircon ages have been obtained from rocks closely associated with pyrite-enargite-gold deposits at Brewer (quartz-topaz rhyolite breccia from the argillic alteration zone in the Brewer pit and felsic ash-flow tuff from the quartz sericite alteration zone), from the disseminated and semimassive pyrite-gold deposits at Haile (crystal lithic rhyolitic ash-flow tuffs from the Champion pit), and from the Ridgeway deposit (felsic ash-flow tuff from the stratigraphic host of the North pit gold deposit). Generally, the zircons are fine grained, fractured, and contain crystal imperfections (corrosion, inclusions, and pits). 206 Pb/ 238 U zircon spot ages for all deposits span a wide range, mostly from 400 to 760 Ma. Inclusions and cores indicative of inherited domains in the zircons were not found, and only a few analyses range from 1.1 to 1.8 Ga. A distinct xenocrystic zircon population was not identified. The 206 Pb/ 238 U weighted age averages of zircon indicate the following crystallization dates for the volcanic and volcaniclastic rocks closely associated with the gold deposits: 550 &plusmn; 3 Ma for Brewer, 553 &plusmn; 2 Ma for Haile, and 556 &plusmn; 2 Ma for the Ridgeway deposit. These zircon crystallization ages represent close estimates of the age of the original gold mineralizing events. Younger zircon spot ages can be attributed to the effects of Paleozoic regional metamorphism. Pb isotope compositions of sulfide minerals (galena, pyrite, enargite, sphalerite, chalcopyrite, and molybdenite) and silicate minerals (K-feldspar, and sericite) in the gold deposits help to constrain the sources of fluids and metals during the mineralizing events. The deposits are pyrite rich, containing multiple generations of pyrite, including early-crystallized pyrite that is closely associated with the original gold mineralizing event, as well as recrystallized pyrite formed in response to Paleozoic metamorphism. Pb isotope compositions of pyrite span a wide range, including the most radiogenic values for the sulfides. Galena and K-feldspar are not abundant but where present they are typically the least radiogenic minerals. Galena has a limited range of Pb isotope compositions that are representative of the gold deposits as a group ( 206 Pb/ 204 Pb = 18.020&ndash;18.326, 207 Pb/ 204 Pb = 15.550&ndash;15.639, 208 Pb/ 204 Pb = 37.605&ndash;38.286). Values of 207 Pb/ 204 Pb straddle the average crustal Pb growth curve, consistent with contributions involving the mantle and continental crust. Whole-rock Pb isotope compositions of volcanic and volcaniclastic rocks of the Persimmon Fork Formation nearly match the range for sulfides in the gold deposits. Subtle regional contrasts in Pb isotope compositions exist among the deposits. Sulfide minerals from Barite Hill (e.g., galena 206 Pb/ 204 Pb < 18.077) in southern South Carolina are generally less radiogenic than sulfides from Ridgeway ( 206 Pb/ 204 Pb > 18.169), Haile ( 206 Pb/ 204 Pb > 18.233), and Brewer ( 206 Pb/ 204 Pb > 18.311) in northern South Carolina. Because Pb isotope compositions of basement rocks from Grenville massifs in the southern Appalachians and sulfide minerals from the gold deposits do not match, a direct genetic connection cannot be established. Diversity in values of 206 Pb/ 204 Pb and the relatively high values of 207 Pb/ 204 Pb suggest that the deposits evolved adjacent to or closely related to continental blocks, perhaps linked to a back-arc tectonic setting. Among potential younger analogues of the slate belt gold deposits are the sulfide deposits of the Okinawa trough in the western Pacific. Mantle-derived isotopic contributions were more important at Barite Hill in southern South Carolina, the least radiogenic among the deposits where oceanic crust had developed, than at Brewer, Haile, and Ridgeway in northern South Carolina where rifting thinned the continental crust.

Georgia, North Carolina, South Carolina, Virginia↗
USGS2005

Gold enrichment and the Bi-Au association in pyrrhotite-rich massive sulfide deposits, Escanaba trough, Southern Gorda Ridge

High gold contents (to 10.1 ppm, avg 1.4 ppm, n = 34) occur in pyrrhotite-rich massive sulfide samples from the sediment-covered floor of the Escanaba trough, the slow-spreading, southernmost segment of Gorda Ridge. These concentrations reflect the presence of primary gold, formed during high-temperature hydrothermal activity in mounds and chimneys, and secondary gold deposited during sea-floor weathering of massive sulfide. Primary gold occurs as fine-grained (<2 ??m) gold, electrum, maldonite (Au2Bi), and a rare unnamed mineral (AuBi5S4) and is texturally and temporally associated with sulfarsenides (arsenopyrite, glaucodot, alloclastite, and cobaltite), arsenides (lo??llingite and safflorite), Bi minerals (native bismuth, Bi tellurides, Bi-Te sulfides, and bismuthinite), and galena. Larger (>2 ??m) secondary gold grains have a porous, flaky morphology and occur in samples in which pyrrhotite is oxidized and replaced by Fe oxyhydroxides, Fe sulfate, and sulfur. Mounds and chimneys dominated by pyrrhotite and containing lesser amounts of isocubanite, chalcopyrite, and Fe-rich sphalerite were formed by high-temperature (estimated range 325??-275??C), reduced, low-sulfur vent fluids. The mineral and fluid compositions during this main stage of hydrothermal venting reflect subsurface interaction between circulating hydrothermal fluids and turbiditic sediment containing as much as 1.1 percent organic carbon. As the deposition of pyrrhotite, Cu-Fe sulfides, and sphalerite waned, a volumetrically minor suite of sulfarsenide, arsenide, Bi, and Au minerals was deposited from highly reduced, late main-stage fluids diffusing through mounds and chimneys. The low solubility of Au as a bisulfide complex and the absence of fluid mixing during this stage of hydrothermal activity apparently inhibited the precipitation of gold directly from solution. Instead, gold precipitation is thought to be linked to elevated concentrations of Bi in the late main-stage fluids. The textural relationships of Au and Bi minerals in pyrrhotite-rich samples, low melting point of native bismuth (271.4??C), and recent experimental results on Au and Bi in hydrothermal fluids contribute to the hypothesis that gold was effectively scavenged from the Escanaba trough vent fluids by coexisting droplets of liquid bismuth. Additional phase relationships of alloys in the Au-Bi system indicate that deposition of native bismuth and maldonite occurred at temperatures as low as 241??C. Bismuth droplets trapped in void space between main-stage mineral grains scavenged gold from ambient hydrothermal fluid to a greater extent than bismuth enclosed by late-forming pyrrhotite. The limited solid solution of Au in Bi can explain the apparent exsolution texture in which gold blebs are hosted by native bismuth. The electrum, native bismuth (with gold inclusions), and galena represent the last traces of gold mineralization from late main-stage fluids. During sea-floor weathering and the oxidation of pyrrhotite in the mounds and chimneys, secondary gold formed as aggregates of colloidal particles along pH gradients between acidic pore waters and ambient seawater. Gold was mobilized from earlier formed primary gold minerals and transported as aqueous chloride complexes. The reduction of Au(III) by residual Fe2+ in partly altered pyrrhotite and adsorption of colloids by Fe oxyhydroxides may have influenced the location of secondary gold grains within the alteration front. Solubility differences between gold and silver chloride complexes at low temperature account for the low Ag content of secondary gold grains. The high concentrations of Bi, and thus the association of Au and Bi minerals in pyrrhotite-rich massive sulfide, can be ascribed to the extensive interaction of hydrothermal fluids with sediment in the Escanaba trough. In contrast, the absence of the Au-Bi association in massive sulfides at other ridges, including other sediment-covered sites at Middle Valley and the Guaymas basin

Economic Geology↗
USGS2005

Geochemistry and jasper beds from the Ordovician Løkken ophiolite, Norway: origin of proximal and distal siliceous exhalites

Stratiform beds of jasper (hematitic chert), composed essentially of SiO 2 (69–95 wt %) and Fe 2 O 3 (3–25 wt %), can be traced several kilometers along strike in the Ordovician Løkken ophiolite, Norway. These siliceous beds are closely associated with volcanogenic massive sulfide (VMS) deposits and are interpreted as sea-floor gels that were deposited by fallout from hydrothermal plumes in silica-rich seawater, in which plume-derived Fe oxyhydroxide particles promoted flocculation and rapid settling of large (~200 μm) colloidal particles of silica-iron oxyhydroxide. Concentrations of chalcophile elements in the jasper beds are at the parts per million level implying that sulfide particle fallout was insignificant and that the Si-Fe gel-forming plumes were mainly derived from intermediate- (100°–250°C) to high-temperature (>250°C) white smoker-type vents with high Fe/S ratios. The interpreted setting is similar to that of the Lau basin, where high-temperature (280°–334°C) white smoker venting alternates or overlaps with sulfide mound-forming black smoker venting. Ratios of Al, Sc, Th, Hf, and REE to iron are very low and show that the detrital input was <0.1 percent of the bulk jasper. Most jasper beds are enriched in U, V, P, and Mo relative to the North American Shale Composite, reflecting a predominantly seawater source, whereas REE distribution patterns (positive Eu and negative Ce anomalies) reflect variable mixing of hydrothermal solutions with oxic seawater at dilution ratios of ~10 2 to 10 4 . Trace element variations in the gel precursor to the jasper are thought to have been controlled by coprecipitation and/or adsorption by Fe oxyhydroxide particles that formed by the oxidation of hydrothermal Fe 2+ within the variably seawater-diluted hydrothermal plume(s). Thick jasper layers near the Høydal VMS orebody show distinct positive As/Fe and Sb/Fe anomalies that are attributed to near-vent rapid settling of Si-Fe particles derived from As- and Sb-rich hydrothermal fluids prior to extensive mixing with seawater in the buoyant plume. Particles that formed later in the highly diluted nonbuoyant plume formed relatively As and Sb poor distal jasper. The large particle sizes and accordingly high settling rates of the particles, together with mass-balance calculations based on modern vent field data, suggest that individual meter-thick jasper beds formed within a plume lifetime of 200 years or less. The lack of thick jasper beds near the Løkken VMS orebody, which is larger than the Høydal orebody by more than two orders of magnitude, probably reflects a shift to anoxic conditions during Løkken mineralization. This environment limited oxidation of iron in the hydrothermal plume and formation of the ferric oxyhydroxides necessary for the flocculation of silica and sea-floor deposition of the gel precursor of the jasper beds. Distal pyritic and iron-poor cherts are more common than jasper in ancient VMS-hosting sequences. The origin of these other types of siliceous exhalite is enigmatic but at least in some cases involved sulfidation, reduction to magnetite, or dissolution of the original ferric iron in precursor Si-rich gels, either by hydrothermal or diagenetic processes.

Economic Geology↗
USGS2001

Marine chemistry of the permian phosphoria formation and basin, Southeast Idaho

Major components in the Meade Peak Member of the Phosphoria Formation are apatite, dolomite, calcite, organic matter, and biogenic silica-a marine fraction; and aluminosilicate quartz debris-a terrigenous fraction. Samples from Enoch Valley, in southeast Idaho, have major element oxide abundances of Al2O3, Fe2O3, K2O, and TiO2 that closely approach the composition of the world shale average. Factor analysis further identifies the partitioning of several trace elements-Ba, Ga, Li, Sc, and Th and, at other sites in southeast Idaho and western Wyoming, B, Co, Cs, Hf, Rb, and Ta-totally into this fraction. Trace elements that fail to show such correlations or factor loadings include Ag, As, Cd, Cr, Cu, Mo, Ni, Se, the rare earth elements (REE), U, V, and Zn. Their terrigenous contribution is determined from minimum values of trace elements versus the terrigenous fraction. These minima too define trace element concentrations in the terrigenous fraction that approximately equal their concentrations in the world shale average. The marine fraction of trace elements represents the difference between the bulk trace element content of a sample and the terrigenous contribution. Of the trace elements enriched above a terrigenous contribution, Ag, Cr, Cu, Mo, and Se show strong loadings on the factor with an organic matter loading and U and the REE on the factor with a strong apatite loading. Cd, Ni, V, and Zn do not show a strong correlation with any of the marine components but are, nonetheless, strongly enriched above a terrigenous contribution. Interelement relationships between the trace elements identify two seawater sources-planktonic debris and basinal bottom water. Relationships between Cd, Cu, Mo, Zn, and possibly Ni and Se suggest a solely biogenic source. Their accumulation rates, and that of PO3-4, further identify the level of primary productivity as having been moderate and the residence time of water in the basin at 4.5 yr. Enrichments of Cr, U, V, and the REE, above both terrigenous and biogenic contributions, define bottom-water redox conditions as having been oxygen depleted, that is, denitrifying but not sulfate reducing.

Economic Geology↗
USGS2001

Remnant colloform pyrite at the haile gold deposit, South Carolina: A textural key to genesis

Auriferous iron sulfide-bearing deposits of the Carolina slate belt have distinctive mineralogical and textural features-traits that provide a basis to construct models of ore deposition. Our identification of paragenetically early types of pyrite, especially remnant colloform, crustiform, and layered growth textures of pyrite containing electrum and pyrrhotite, establishes unequivocally that gold mineralization was coeval with deposition of host rocks and not solely related to Paleozoic tectonic events. Ore horizons at the Haile deposit, South Carolina, contain many remnants of early pyrite: (1) fine-grained cubic pyrite disseminated along bedding; (2) fine- grained spongy, rounded masses of pyrite that may envelop or drape over pyrite cubes; (3) fragments of botryoidally and crustiform layered pyrite, and (4) pyritic infilling of vesicles and pumice. Detailed mineral chemistry by petrography, microprobe, SEM, and EDS analysis of replaced pumice and colloform structures containing both arsenic compositional banding and electrum points to coeval deposition of gold and the volcanic host rocks and, thus, confirms a syngenetic origin for the gold deposits. Early pyrite textures are present in other major deposits of the Carolina slate belt, such as Ridgeway and Barite Hill, and these provide strong evidence for models whereby the sulfide ores formed prior to tectonism. The role of Paleozoic metamorphism was to remobilize and concentrate gold and other minerals in structurally prepared sites. Recognizing the significance of paragenetically early pyrite and gold textures can play an important role in distinguishing sulfide ores that form in volcanic and sedimentary environments from those formed solely by metamorphic processes. Exploration strategies applied to the Carolina slate belt and correlative rocks in the eastern United States in the Avalonian basement will benefit from using syngenetic models for gold mineralization.

Economic Geology↗
USGS2001

Miocene and early Pliocene epithermal gold-silver deposits in the northern Great Basin, western United States: Characteristics, distribution, and relationship to Magmatism

Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basalt-rhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich tholeiitic series formed during continental rifting. Rocks in the bimodal assemblage consist mostly of basalt to andesite and rhyolite compositions that generally contain anhydrous and reduced mineral assemblages (e.g., quartz + fayalite rhyolites). Eruptive forms include mafic lava flows, dikes, cinder and/or spatter cones, shield volcanoes, silicic flows, domes, and ash-flow calderas. Fe-Ti oxide barometry indicates oxygen fugacities between the magnetite-wustite and fayalite-magnetite-quartz oxygen buffers for this magmatic assemblage. The western andesite assemblage is a high K calc-alkaline series that formed a continental-margin are related to subduction of oceanic crust beneath the western coast of North America. In the northern Great Basin, most of the western andesite assemblage was erupted in the Walker Lane belt, a zone of transtension and strike-slip faulting. The western andesite assemblage consists of stratovolcanoes, dome fields, and subvolcanic plutons, mostly of andesite and dacite composition. Biotite and hornblende phenocrysts are abundant in these rocks. Oxygen fugacities of the western andesite assemblage magmas were between the nickel-nickel oxide and hematite-magnetite buffers, about two to four orders of magnitude greater than magmas of the bimodal assemblage. Numerous low-sulfidation Au-Ag deposits in the bimodal assemblage include deposits in the Midas (Ken Snyder), Sleeper, DeLamar, Mule Canyon, Buckhorn, National, Hog Ranch, Ivanhoe, and Jarbidge districts; high-sulfidation gold and porphyry copper-gold deposits are absent. Both high- and low-sulfidation gold-silver and porphyry copper-gold deposits are affiliated with the western andesite assemblage and include the Comstock Lode, Tonopah, Goldfield, Aurora, Bodie, Paradise Peak, and Rawhide deposits. Low-sulfidation Au-Ag deposits in the bimodal assemblage formed under relatively low oxygen and sulfur fugacities and have generally low total base metal (Cu + Pb + Zn) contents, low Ag/Au ratios, and notably high selenide mineral contents compared to temporally equivalent low-sulfidation deposits in the western andesite assemblage. Petrologic studies suggest that these differences may reflect variations in the magmatic-tectonic settings of the associated magmatic assemblages-deposits in the western andesite assemblage formed from oxidized, water-rich, subduction-related calc-alkaline magmas, whereas deposits in the bimodal assemblage were associated with reduced, water-poor tholeiitic magmas derived from the lithospheric mantle during continental extension. The contrasting types and characteristics of epithermal deposits and their affinities with associated igneous rocks suggest that a genetic relationship is present between these Au-Ag deposits and their temporally associated magmatism, although available data do not prove this relationship for most low-sulfidation deposits.

Economic Geology↗
USGS2002

Relationship of epithermal gold deposits to large-scale fractures in northern Nevada

Geophysical maps of northern Nevada reveal at least three and possibly six large-scale arcuate features, one of which corresponds to the northern Nevada rift that possibly extends more than 1,000 km from the Oregon- Idaho border to southern Nevada. These features may reflect deep discontinuities within the earth's crust, possibly related to the impact of the Yellowstone hot spot. Because mid-Miocene epithermal gold deposits have been shown to correlate with the northern Nevada rift, we investigate the association of other epithermal gold deposits to other similar arcuate features in northern Nevada. Mid-Miocene and younger epithermal gold- silver deposits also occur along two prominent aeromagnetic anomalies west of the northern Nevada rift. Here, we speculate that mid-Miocene deposits formed along deep fractures in association with mid-Miocene rift- related magmatism and that younger deposits preferentially followed these preexisting features. Statistical analysis of the proximity of epithermal gold deposits to these features suggests that epithermal gold deposits in northern Nevada are spatially associated with large-scale crustal features interpreted from geophysical data.

Economic Geology↗
USGS2004

Hydrothermal alteration, ore fluid characteristics, and gold depositional processes along a trondhjemite-komatiite contact at Tarmoola, Western Australia

Tarmoola is a structurally controlled Archean orogenic gold deposit hosted in greenschist facies metamorphosed komatiite and trondhjemite in the Leonora district of the Eastern Goldfields province, Yilgarn craton. High-grade (>1 g/t Au) orebodies are located in komatiite wall rock adjacent to the eastern and northeastern margins of the asymmetrical, north-south-striking, Tarmoola trondhjemite intrusion. Gold-bearing veins post-date trondhjemite emplacement (ca. 2700 Ma), quartz diorite dikes (ca. 2667 Ma), and regional greenschist facies metamorphism. Textures and crosscutting relationships in gold-bearing veins indicate two stages of hydrothermal fluid infiltration associated with a single gold-related hydrothermal event: a volumetrically dominant, but gold-poor, stage I fluid and a gold-rich stage II fluid. Gold-bearing veins contain stage I milky quartz and pyrite that are overprinted by stage II quartz-ankerite-muscovite-chalcopyrite-sphalerite-galena-gold-tellurides ?? albite ?? chlorite ?? fuchsite ?? epidote ?? scheelite. Stage I hydrothermal alteration assemblages are different in trondhjemite and komatiite due to contrasting reactions between a common ore fluid and disparate wall-rock chemistry. Stage II fluid-wall rock interaction was minor compared to stage I and is indicated by the overprinting of stage I mineral assemblages by stage II microveins. Wall-rock alteration proximal to veins in trondhjemite is characterized by replacement of igneous plagioclase, amphibole, biotite, and metamorphic chlorite by hydrothermal quartz, muscovite, ankerite, calcite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold, whereas in proximal alteration in komatiite, metamorphic chlorite and talc are replaced by ankerite, quartz, muscovite, albite, chlorite, fuchsite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold. The stage II fluid was enriched in H2O, CO2, Si, Ca, K, Na, S, Au, Ag, Cu, Pb, W, Bi, As, Mo, Zn, and Te. Based on fluid inclusion studies and stage II mineral equilibria, gold deposited from a homogeneous, neutral to slightly alkaline (pH 5.1-5.5), reduced, low-salinity (<5.5 wt % NaCl equiv) fluid that had a bulk composition of 78 mole percent H2O and 21 mole percent CO2, and trace amounts of CH4, C2H6, H2, Ar, H2S, and He. Gold deposition occurred at 300?? ?? 50??C and 0.5 to 3.0 kbars. Assuming lithostatic fluid pressures, gold precipitated at a 2- to 10-km depth. Stage II gray quartz ??18Ofluid values range from 5.9 to 7.5 per mil, whereas ??Dfluid values calculated from the dehydration of muscovite grains and measured directly from bulk fluid inclusion analyses of stage II gray quartz have ranges of -9 to -35 and -27 to -28 per mil, respectively. Hydrothermal ore fluids were transported from greater crustal depths to the site of gold deposition during the district-scale D3 event by shallowly W dipping, reverse brittle-ductile shear zones in supracrustal rock and along the steeply east dipping trondhjemite contact. Associated subhorizontal east-west shortening caused the reactivation of the eastern trondhjemite margin and subparallel foliation, which facilitated the transport of hydrothermal fluids and the generation of gold-bearing veins and hydrothermal alteration zones in komatiite. East-west-striking fractures in trondhjemite aided the lateral migration of ore fluids away from trondhjemite margins and the formation of east-west-striking gold-bearing veins and broad alteration zones. Gold was most likely transported in the stage II fluid as bisulfide complexes. The sulfidation of trondhjemite and komatiite wall rock by the stage II fluid caused the destabilization of An bisulfide complexes and gold deposition. Potassium, Ca, and CO2 metasomatism of komatiite wall rock may have enhanced gold deposition via the acidification of the stage II fluid. The physicochemical characteristics of the Tarmoola ore fluid and relative timing of gold mineralization are consistent with the Yilgarn-wide,

Economic Geology↗
USGS2004

The late cretaceous Donlin Creek gold deposit, Southwestern Alaska: Controls on epizonal ore formation

The Donlin Creek gold deposit, southwestern Alaska, has an indicated and inferred resource of approximately 25 million ounces (Moz) Au at a cutoff grade of 1.5 g/t. The ca. 70 Ma deposit is hosted in the Late Cretaceous Kuskokwim flysch basin, which developed in the back part of the arc region of an active continental margin, on previously accreted oceanic terranes and continental fragments. A hypabyssal, mainly rhyolitic to rhyodacitic, and commonly porphyritic, 8- × 3-km dike complex, part of a regional ca. 77 to 58 Ma magmatic arc, formed a structurally competent host for the mineralization. This deposit is subdivided into about one dozen distinct prospects, most of which consist of dense quartz ± carbonate veinlet networks that fill north-northeast–striking extensional fractures in the northeast-trending igneous rocks. The sulfide mineral assemblage is dominated by arsenopyrite, pyrite, and, typically younger, stibnite; gold is refractory within the arsenopyrite. Sericitization, carbonatization, and sulfidation were the main alteration processes. Fluid inclusion studies of the quartz that hosts the resource indicate dominantly aqueous ore fluids with also about 3 to 7 mol percent CO 2 ± CH 4 and a few tenths to a few mole percent NaCl + KCl. The gold-bearing fluids were mainly homogeneously trapped at approximately 275° to 300°C and at depths of 1 to 2 km. Some of the younger stibnite may have been deposited by late-stage aqueous fluids at lower temperature. Measured δ 18 O values for the gold-bearing quartz range between 11 and 25 per mil; the estimated δ 18 O fluid values range from 7 to12 per mil, suggesting a mainly crustally derived fluid. A broad range of measured δ D values for hydrothermal micas, between –150 and –80 per mil, is suggestive of a contribution from devolatilization of organic matter and/or minor amounts of mixing with meteoric fluids. Gold-associated hydrothermal sulfide minerals are characterized by δ 34 S values mainly between –16 and –10 per mil, with the sulfur derived from diagenetic pyrite and organic matter within the flysch basin. A smaller group of δ 34 S measurements, which shows values as depleted as –27 per mil, suggests a different local sulfur reservoir in the basin for the later hydrothermal episode dominated by stibnite. Initial ϵ Nd of –8.7 to –3.1 and 87 Sr/ 86 Sr measurements of 0.706 to 0.709 for the ore-hosting dikes also indicate a crustal reservoir for some of the Late Cretaceous magmatism. Overlapping lead isotope data for these intrusive rocks and for sulfide minerals suggest a crustal contribution for the lead in both. Copper- and gold-bearing stockwork veinlets in hornfels occur at Dome, a prospect located at the northern end of the Donlin Creek deposit. These stockworks are cut by the younger auriferous gold veins that define the main Donlin Creek gold mineralization. Highly saline, gas-rich, heterogeneously trapped fluids deposited the stockworks at temperatures approximately 100°C hotter than those of the main gold-forming event at Donlin Creek. The genetic relationship of the Dome prospect to the main Donlin Creek gold resource is equivocal. The epizonal Donlin Creek deposit shows affinities to the gold systems interpreted by various workers as orogenic or intrusion related; it shows important differences from typical epithermal and Carlin-like deposits. The ore-forming fluids were derived by either broad-scale metamorphic devolatilization above rising mantle melts or exsolution from a magma that was dominated by a significant flysch melt component.

Economic Geology↗
USGS2004

Depositional settings, correlation, and age carboniferous rocks in the western Brooks Range, Alaska

The Kuna Formation (Lisburne Group) in northwest Alaska hosts the Red Dog and other Zn-Pb-Ag massive sulfide deposits in the Red Dog district. New studies of the sedimentology and paleontology of the Lisburne Group constrain the setting, age, and thermal history of these deposits. In the western and west-central Brooks Range, the Lisburne Group includes both deep- and shallow-water sedimentary facies and local volcanic rocks that are exposed in a series of thrust sheets or allochthons. Deep-water facies in the Red Dog area (i.e., the Kuna Formation and related rocks) are found chiefly in the Endicott Mountains and structurally higher Picnic Creek allochthons. In the Red Dog plate of the Endicott Mountains allochthon, the Kuna consists of at least 122 m of thinly interbedded calcareous shale, calcareous spiculite, and bioclastic supportstone (Kivalina unit) overlain by 30 to 240 m of siliceous shale, mudstone, calcareous radiolarite, and calcareous lithic turbidite (Ikalukrok unit). The Ikalukrok unit in the Red Dog plate hosts all massive sulfide deposits in the area. It is notably carbonaceous, is generally finely laminated, and contains siliceous sponge spicules and radiolarians. The Kuna Formation in the Key Creek plate of the Endicott Mountains allochthon (60–110 m) resembles the Ikalukrok unit but is unmineralized and has thinner carbonate layers that are mainly organic-rich dolostone. Correlative strata in the Picnic Creek allochthon include less shale and mudstone and more carbonate (mostly calcareous spiculite). Conodonts and radiolarians indicate an age range of Osagean to early Chesterian (late Early to Late Mississippian) for the Kuna in the Red Dog area. Sedimentologic, faunal, and geochemical data imply that most of the Kuna formed in slope and basin settings characterized by anoxic or dysoxic bottom water and by local high productivity.

Alaska↗
USGS2004

Origin of the Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska: Evidence from regional Pb and Sr isotope sources

Pb and Sr isotope data were obtained on the shale-hosted Zn-Pb-Ag Red Dog deposits (Qanaiyaq, Main, Aqqaluk, and Paalaaq), other shale-hosted deposits near Red Dog, and Zn-Pb-Ag sulfide and barite deposits in the western and central Brooks Range. The Red Dog deposits and other shale-hosted Zn-Pb-Ag deposits near Red Dog are hosted in the Mississippian Kuna Formation, which is underlain by a sequence of marine-deltaic clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. Ag-Pb-Zn vein-breccias are found in the Endicott Group. Galena formed during the main mineralization stages in the Red Dog deposits and from the Anarraaq and Wulik deposits have overlapping Pb isotope compositions in the range 206Pb/204Pb = 18.364 to 18.428, 207Pb/204Pb = 15.553 to 15.621, and 208Pb/204Pb = 38.083 to 38.323. Galena and sphalerite formed during the main ore-forming stages in the Red Dog deposits define a narrow field on standard uranogenic and thorogenic Pb isotope diagrams. Lead in sulfides of the Red Dog district is less radiogenic (238U/204Pb: ?? = 9.51-9.77) than is indicated by the average crustal lead evolution model (?? = 9.74), a difference consistent with a long history of evolution at low ratios of ?? before the Carboniferous. The homogeneous regional isotopic reservoir of Pb may indicate large-scale transport and leaching of minerals with various ?? ratios and Th/Pb ratios. Younger and genetically unrelated fluids did not significantly disturb the isotopic compositions of galena and sphalerite after the main mineralization event in the Red Dog district. Some pyrite shows evidence of minor Pb remobilization. The overall lead isotope homogeneity in the shale-hosted massive sulfide deposits is consistent with three types of control: a homogeneous regional source, mixing of lead during leaching of a thick sedimentary section and fluid transport, or mixing at the site of deposition. Isotopic variability of the hydrothermal fluids, as represented by galena in the Red Dog district, appears to be consistent with a simple mixing system. Evidence indicates that galena was deposited from largely similar hydrothermal solutions throughout the Red Dog district. A shared regional isotopic reservoir is also supported by the correspondence of Pb isotope compositions of galena in deposits of the Red Dog district and galena in clastic rocks (vein-breccias). Leaching of metals and progressive extraction of radiogenic lead from the clastic rocks in the Endicott Group may account for the trend of increasing 206Pb/204Pb in galena of the Red Dog district. Galena in the Red Dog deposits is unlikely to have been derived entirely from the same isotopic reservoir as that represented by the lead in the Kuna Formation or from the igneous rocks in the Red Dog district. Sr isotope data for barite, calcite, and witherite from the Red Dog deposits are compared with data from regional barite that is associated with sulfides and from barite in sulfide-poor occurrences. Fluids with heterogeneous Sr isotope signatures are indicated. Barite in the Main deposit extends to higher ratios of 87Sr/86Sr (0.709034-0.709899) than barite in the Anarraaq deposit (0.708615-0.709256). All barite is more radiogenic than Carboniferous seawater. Other Mississippian(?) shale-hosted deposits and mineral occurrences containing barite in the Red Dog district and barite in regional occurrences east of Red Dog in the western and central Brooks Range also have heterogeneous 87Sr/86Sr ratios. Carbonate (87Sr/86Sr = 0.710319-0.713637) and witherite (87 Sr/86 Sr = 0.710513) in the Main deposit are more radiogenic than barite. In contrast, carbonate (87Sr/86Sr = 0.708196-0.709740) intergrown with massive sulfides at Anarraaq has isotopic compositions similar to that of barite. Paragenetic and isotop ic studies suggest that early barite is similar to barite typically formed in cold seeps along continental margins. This early fine-grained barite formed before the main mineralizat

Economic Geology↗
USGS2011

Book review: Hollowed ground—Copper mining and community building on Lake Superior, 1840s–1990s

In 1843, six years before the Forty-niners headed west for the goldfields of California, the United States’ first great mineral rush began to a land that was, as Patrick Henry told Congress, “beyond the most distant wilderness and remote as the moon.” He was referring to the Keweenaw Peninsula of northern Michigan. This rush was not for gold or silver, but for copper. And not just any copper, but native copper, so pure it required little refining before use. The early horde of fortune-seekers came with visions of finding mountains of solid copper, spurred on by stories of large masses of “float copper” that included the famous Ontonagon Boulder, a large mass of native copper originally found lying 32 km up the steep and rugged valley of the Ontonagon River (and now gathering dust in the Smithsonian Museum).

Economic Geology↗