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At least 487 records · Page 27Linked to original sources

Variable contributions of mercury from groundwater to a first-order urban coastal plain stream in New Jersey, USA

Filtered total mercury (FTHg) concentrations in a rapidly urbanizing area ranged from 50 to 250 ng/L in surface waters of the Squankum Branch, a tributary to a major river (Great Egg Harbor River (GEHR)) traversing both urban and forested/wetland areas in the Coastal Plain of New Jersey. An unsewered residential area with Hg-contaminated well water (one of many in the region) is adjacent to the stream’s left bank. Although the region’s groundwater contains total Hg (THg) at background levels of <10 ng/L, water from about 700 domestic wells in urbanized areas completed in the acidic, quartzose unconfined aquifer typically at depths 20 to 30 m below land surface has been found to exceed 2,000 ng/L (the USEPA maximum contaminant level). Within urbanized areas, THg concentrations in shallow groundwater (<20 m below land surface at or near the water table) and the potential for Hg transport were not well known, representing a considerable knowledge gap. Sampling of streamwater in, and groundwater discharge to, the Squankum Branch watershed revealed that concentrations of THg generally were in the range of 1 to 10 ng/L, but narrow plumes (“plumelets”) of shallow groundwater discharging to the stream from the opposing banks contained FTHg at a concentration > 5,000 ng/L (left bank) and nearly 2,000 ng/L (right bank). The Hg content of bankside soils and sediments was high (up to 12 mg/kg) and mostly acid leachable where groundwater with high Hg concentrations discharged, indicating contributions of Hg by both runoff and shallow groundwater. Elevated concentrations of nutrients and chloride in some groundwater plumelets likely indicated inputs from septic-system effluent and (or) fertilizer applications. The Hg probably derives mainly from mercurial pesticide applications to the former agricultural land being urbanized. The study results show that soil disturbance and introduction of anthropogenic substances can mobilize Hg from soils to shallow groundwater and the Hg contamination travels in narrow plumelets to discharge points such as stream tributaries. In the entire GEHR watershed, THg concentrations in groundwater discharging to streams in urban areas tended to be higher than concentrations in water discharging to streams of forested areas, consistent with the results from this small watershed. Other areas with similar quartzose coastal aquifers, land-use history, and hydrogeology may be similarly vulnerable to Hg contamination of shallow groundwater and associated surface water.

New Jersey

Comparing laser-based open- and closed-path gas analyzers to measure methane fluxes using the eddy covariance method

Closed- and open-path methane gas analyzers are used in eddy covariance systems to compare three potential methane emitting ecosystems in the Sacramento-San Joaquin Delta (CA, USA): a rice field, a peatland pasture and a restored wetland. The study points out similarities and differences of the systems in field experiments and data processing. The closed-path system, despite a less intrusive placement with the sonic anemometer, required more care and power. In contrast, the open-path system appears more versatile for a remote and unattended experimental site. Overall, the two systems have comparable minimum detectable limits, but synchronization between wind speed and methane data, air density corrections and spectral losses have different impacts on the computed flux covariances. For the closed-path analyzer, air density effects are less important, but the synchronization and spectral losses may represent a problem when fluxes are small or when an undersized pump is used. For the open-path analyzer air density corrections are greater, due to spectroscopy effects and the classic Webb–Pearman–Leuning correction. Comparison between the 30-min fluxes reveals good agreement in terms of magnitudes between open-path and closed-path flux systems. However, the scatter is large, as consequence of the intensive data processing which both systems require.

Agricultural and Forest Meteorology

Component identification of solid biomass fuels using reflected light microscopy: Interlaboratory study 2

As nations transition toward sustainable energy systems , biomass has become a vital component of global energy portfolios. Derived from organic materials such as wood, agricultural residues, forestry byproducts, and organic waste, biomass is a renewable energy source with significant environmental and economic benefits. Responsible biomass energy production can improve waste management, reduce emissions of greenhouse gases, and mitigate environmental pollution. However, as the diversity of biomass-derived fuels increases, robust quality assessment methods are essential to ensure their efficiency, safety, and minimal environmental impact. Reflected light microscopy (RLM) is one such technique with the potential to complement conventional physico-chemical analyses by enabling a rapid identification of material constituents and impurities. To refine this methodology and evaluate the reproducibility of solid biomass component identification using RLM, an interlaboratory study (ILS) was conducted. The study involved the recognition of 58 components across 45 photomicrographs, with the participation of 65 scientists and students from 25 countries. The participants faced high difficulty identifying some of the marked components, and as a result, the percentage of correct answers ranged from 19.0 % to 98.3 %, with an average correct identification rate of 62.7 %. The most challenging aspects of the identification process included distinguishing between woody and non-woody (agro) biomass, accurately identifying petroleum-derived materials, and differentiating agro biomass from inorganic matter. The results suggest that while RLM is an important tool for characterizing solid biomass, further development of methodology guidelines and training are necessary to enhance its effectiveness. Future research should prioritize preparing detailed, image-rich, microscopic morphological descriptions of biomass fuel components, which could improve the accuracy and reliability of using RLM in biomass fuel characterization.

International Journal of Coal Geology

Sharing the floodplain: Mediated modeling for environmental management

Complex ecosystems, such as the Upper Mississippi River (UMR), present major management challenges. Such systems often provide a range of ecosystem services that are differentially valued by stakeholders representing distinct interests (e.g., agriculture, conservation, navigation) or institutions (e.g., federal and state agencies). When no single entity has the knowledge or authority to resolve conflicts over shared resource use, stakeholders may struggle to jointly understand the scope of the problem and to reach reasonable compromises. This paper explores mediated modeling as a group consensus building process for understanding relationships between ecological, economic and cultural well-being in the UMR floodplain. We describe a workshop structure used to engage UMR stakeholders that may be extended to resource use conflicts in other complex ecosystems. We provide recommendations for improving on these participatory methods in structuring future efforts. In conclusion, we suggest that tools which facilitate collaborative learning, such as mediated modeling, need to be incorporated at an institutional level as a vital element of integrated ecosystem management. ?? 2008 Elsevier Ltd.

Environmental Modelling and Software

Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland

The history and fate of groundwater nitrate (NO 3 − ) contamination were compared in 2 small adjacent agricultural watersheds in the Atlantic coastal plain by combined use of chronologic (CCl 2 F 2 , 3 H), chemical (dissolved solids, gases), and isotopic (δ 15 N,δ 13 C, δ 34 S) analyses of recharging groundwaters, discharging groundwaters, and surface waters. The results demonstrate the interactive effects of changing agricultural practices, groundwater residence times, and local geologic features on the transfer of NO 3 − through local flow systems. Recharge dates of groundwaters taken in 1990–1992 from the surficial aquifer in the Chesterville Branch and Morgan Creek watersheds near Locust Grove, Maryland, ranged from pre-1940 to the late 1980’s. When corrected for localized denitrification by use of dissolved gas concentrations, the dated waters provide a 40-year record of the recharge rate of NO 3 − , which increased in both watersheds by a factor of 3–6, most rapidly in the 1970's. The increase in groundwater NO 3 − over time was approximately proportional to the documented increase in regional N fertilizer use, and could be accounted for by oxidation and leaching of about 20–35% of the fertilizer N. Groundwaters discharging upward beneath streams in both watersheds had measured recharge dates from pre-1940 to 1975, while chemical data for second-order reaches of the streams indicated average groundwater residence times in the order of 20+ years. At the time of the study, NO 3 − discharge rates were less than NO 3 − recharge rates for at least two reasons: (1) discharge of relatively old waters with low initial NO 3 − concentrations, and (2) local denitrification. In the Chesterville Branch watershed, groundwaters remained oxic throughout much of the surficial aquifer and discharged relatively unaltered to the stream, which had a relatively high NO 3 − concentration (9–10 mg/L as N). In the Morgan Creek watershed, groundwaters were largely reduced and denitrified before discharging to the stream, which had a relatively low NO 3 − concentration (2–3 mg/L as N). Chemical and isotopic data indicate that quantitative denitrification occurred within buried calcareous glauconitic marine sediments that are present at relatively shallow depths beneath the Morgan Creek watershed. NO 3 − removal by forests, wetlands, and shallow organic-rich soils in near-stream environments was largely avoided by groundwaters that followed relatively deep flow paths before converging and discharging rapidly upward to the streams.

Maryland

DIN retention-transport through four hydrologically connected zones in a headwater catchment of the Upper Mississippi River

Dissolved inorganic nitrogen (DIN) retention-transport through a headwater catchment was synthesized from studies encompassing four distinct hydrologic zones of the Shingobee River Headwaters near the origin of the Mississippi River. The hydrologic zones included: (1) hillslope ground water (ridge to bankside riparian); (2) alluvial riparian ground water; (3) ground water discharged through subchannel sediments (hyporheic zone); and (4) channel surface water. During subsurface hillslope transport through Zone 1, DIN, primarily nitrate, decreased from ∼3 mg-N/l to <0.1 mg-N/l. Ambient seasonal nitrate:chloride ratios in hillslope flow paths indicated both dilution and biotic processing caused nitrate loss. Biologically available organic carbon controlled biotic nitrate retention during hillslope transport. In the alluvial riparian zone (Zone 2) biologically available organic carbon controlled nitrate depletion although processing of both ambient and amended nitrate was faster during the summer than winter. In the hyporheic zone (Zone 3) and stream surface water (Zone 4) DIN retention was primarily controlled by temperature. Perfusion core studies using hyporheic sediment indicated sufficient organic carbon in bed sediments to retain ground water DIN via coupled nitrification-denitrification. Numerical simulations of seasonal hyporheic sediment nitrification-denitrification rates from perfusion cores adequately predicted surface water ammonium but not nitrate when compared to 5 years of monthly field data (1989-93). Mass balance studies in stream surface water indicated proportionally higher summer than winter N retention. Watershed DIN retention was effective during summer under the current land use of intermittently grazed pasture. However, more intensive land use such as row crop agriculture would decrease nitrate retention efficiency and increase loads to surface water. Understanding DIN retention capacity throughout the system, including special channel features such as sloughs, wetlands and floodplains that provide surface water-ground water connectivity, will be required to develop effective nitrate management strategies.

Minnesota

Rocky Mountain snowpack physical and chemical data for selected sites, 2010

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region, from New Mexico to Montana, to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition on freshwater systems. Scientists with the U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, annually collected and analyzed snow-pack samples at 48 or more sites in the Rocky Mountain region during 1993-2010. Sixty-three snowpack-sampling sites were each sampled once in 2010, and those data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2010 also are included.

Rocky Mountains

Organic Compounds in Running Gutter Brook Water Used for Public Supply near Hatfield, Massachusetts, 2003-05

The 258 organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including pesticides, solvents, gasoline hydrocarbons, personal-care and domestic-use products, and pavement and combustion-derived compounds. Of these 258 compounds, 26 (about 10 percent) were detected at least once among the 31 samples collected approximately monthly during 2003-05 at the intake of a flowthrough reservoir on Running Gutter Brook in Massachusetts, one of several community water systems on tributaries of the Connecticut River. About 81 percent of the watershed is forested, 14 percent is agricultural land, and 5 percent is urban land. In most source-water samples collected at Running Gutter Brook, fewer compounds were detected and their concentrations were low (less than 0.1 micrograms per liter) when compared with compounds detected at other stream sites across the country that drain watersheds that have a larger percentage of agricultural and urban areas. The relatively few compounds detected at low concentrations reflect the largely undeveloped land use at Running Gutter Brook. Despite the absence of wastewater discharge points on the stream, however, the compounds that were detected could indicate different sources and uses (point sources, precipitation, domestic, and agricultural) and different pathways to drinking-water supplies (overland runoff, groundwater discharge, leaking of treated water from distribution lines, and formation during treatment). Six of the 10 compounds detected most commonly (in at least 20 percent of the samples) in source water also were detected commonly in finished water (after treatment but prior to distribution). Concentrations in source and finished water generally were below 0.1 micrograms per liter and always less than humanhealth benchmarks, which are available for about one-half of the compounds detected. On the basis of this screening-level assessment, adverse effects to human health are expected to be negligible (subject to limitations of available humanhealth benchmarks).

Fact Sheet

New papers related to remote sensing of the earth

Worldwide experience of many individuals and organizations with remote sensing data acquired from space, primarily Landsat-1, -2, and -3, has demonstrated its utility for land use classification, agricultural assessment, energy and resource exploration, and many other applications. There has been some reluctance to adopt these systems in operational programmes because of a lack of assured continuity of data collection, continuing changes in the systems, and some dissatisfaction with the types of data made available to users. Nevertheless, there is sufficient conviction of the value of satellite remote sensing so that new systems will be developed by several countries in the decade of the 1980's. The status changes continuously as studies are completed, and budgets are adjusted. This review presents the situation at the beginning of 1982.

Open-File Report

Digital data used to relate nutrient inputs to water quality in the Chesapeake Bay watershed

Digital data sets were compiled by the U. S. Geological Survey (USGS) and used as input for a collection of Spatially Referenced Regressions On Watershed attributes for the Chesapeake Bay region. These regressions relate streamwater loads to nutrient sources and the factors that affect the transport of these nutrients throughout the watershed. A digital segmented network based on watershed boundaries serves as the primary foundation for spatially referencing total nitrogen and total phosphorus source and land-surface characteristic data sets within a Geographic Information System. Digital data sets of atmospheric wet deposition of nitrate, point-source discharge locations, land cover, and agricultural sources such as fertilizer and manure were created and compiled from numerous sources and represent nitrogen and phosphorus inputs. Some land-surface characteristics representing factors that affect the transport of nutrients include land use, land cover, average annual precipitation and temperature, slope, and soil permeability. Nutrient input and land-surface characteristic data sets merged with the segmented watershed network provide the spatial detail by watershed segment required by the models. Nutrient stream loads were estimated for total nitrogen, total phosphorus, nitrate/nitrite, amonium, phosphate, and total suspended soilds at as many as 109 sites within the Chesapeake Bay watershed. The total nitrogen and total phosphorus load estimates are the dependent variables for the regressions and were used for model calibration. Other nutrient-load estimates may be used for calibration in future applications of the models.

Open-File Report

Collaborative modelling and integrated decision support system analysis of a developed terminal lake basin

A terminal lake basin in west-central Nevada, Walker Lake, has undergone drastic change over the past 90 yrs due to upstream water use for agriculture. Decreased inflows to the lake have resulted in 100 km 2 decrease in lake surface area and a total loss of fisheries due to salinization. The ecologic health of Walker Lake is of great concern as the lake is a stopover point on the Pacific route for migratory birds from within and outside the United States. Stakeholders, water institutions, and scientists have engaged in collaborative modeling and the development of a decision support system that is being used to develop and analyze management change options to restore the lake. Here we use an integrated management and hydrologic model that relies on state-of-the-art simulation capabilities to evaluate the benefits of using integrated hydrologic models as components of a decision support system. Nonlinear feedbacks among climate, surface-water and groundwater exchanges, and water use present challenges for simulating realistic outcomes associated with management change. Integrated management and hydrologic modeling provides a means of simulating benefits associated with management change in the Walker River basin where drastic changes in the hydrologic landscape have taken place over the last century. Through the collaborative modeling process, stakeholder support is increasing and possibly leading to management change options that result in reductions in Walker Lake salt concentrations, as simulated by the decision support system.

Nevada

Detection and measurement of land subsidence using interferometric synthetic aperture radar and Global Positioning System, San Bernardino County, Mojave Desert, California

Land subsidence associated with ground-water-level declines has been recognized as a potential problem in parts of the Mojave Desert, California. Ground water has been the primary source of domestic, agricultural, and municipal water supplies in the desert since the early 1900s. Pumping of ground water from the Mojave River and Morongo ground-water basins in the southwestern Mojave Desert resulted in water-level declines of more than 30 meters (100 feet) between the 1950s and the 1990s. A Global Positioning System (GPS) survey of a geodetic network was used to determine the location, extent, and magnitude of vertical land-surface changes in Lucerne Valley in the Morongo ground-water basin. The GPS survey was conducted in 1998 to estimate historical elevation changes by comparing GPS-derived elevations with historical elevations (which were available for some of the monuments in the network as early as 1944) and to establish baseline values that can be used for comparisons with future GPS surveys. The GPS measurements indicated that about 600 millimeters (2 feet) [plus or minus 1,500 millimeters (5 feet)] of subsidence occurred at three of the monuments between 1969 and 1998 but that very little to no vertical change in position occurred at seven other monuments in the network. Water levels in the area of subsidence in Lucerne Valley declined about 15 meters (50 feet) during 1970-98. Interferometric synthetic aperture radar (InSAR) methods were used to characterize vertical land-surface changes in the Mojave River and Morongo ground-water basins during various intervals of time between 1992 and 1999. Interferograms, InSAR-generated displacement maps, show that subsidence ranging from 45 to 90 mm (0.15 to 0.3 ft) occurred in four areas of these two ground-water basins--the El Mirage, Lockhart-Harper Lake (dry), Newberry Springs, and Lucerne Valley areas. Some of the InSAR measurements were affected by the earthquakes at Landers and Hector Mine, California, and by atmospheric artifacts. Water-level data were examined for areas undergoing vertical land-surface changes to determine whether the vertical land-surface changes may be related to aquifer-system compaction caused by ground-water-level changes. Temporally relevant water-level data were sparse for some areas, particularly the El Mirage and Lockhart-Harper Lake (dry) areas. Water levels in wells proximate to the subsiding areas generally declined between 1992 and 1999; water levels in some wells proximate to the subsiding areas experienced seasonal periods of declines and recoveries.

California

Method for estimating potential wetland extent by utilizing streamflow statistics and flood-inundation mapping techniques: Pilot study for land along the Wabash River near Terre Haute, Indiana

Potential wetland extents were estimated for a 14-mile reach of the Wabash River near Terre Haute, Indiana. This pilot study was completed by the U.S. Geological Survey in cooperation with the U.S. Department of Agriculture, Natural Resources Conservation Service (NRCS). The study showed that potential wetland extents can be estimated by analyzing streamflow statistics with the available streamgage data, calculating the approximate water-surface elevation along the river, and generating maps by use of flood-inundation mapping techniques. Planning successful restorations for Wetland Reserve Program (WRP) easements requires a determination of areas that show evidence of being in a zone prone to sustained or frequent flooding. Zone determinations of this type are used by WRP planners to define the actively inundated area and make decisions on restoration-practice installation. According to WRP planning guidelines, a site needs to show evidence of being in an "inundation zone" that is prone to sustained or frequent flooding for a period of 7 consecutive days at least once every 2 years on average in order to meet the planning criteria for determining a wetland for a restoration in agricultural land. By calculating the annual highest 7-consecutive-day mean discharge with a 2-year recurrence interval (7MQ2) at a streamgage on the basis of available streamflow data, one can determine the water-surface elevation corresponding to the calculated flow that defines the estimated inundation zone along the river. By using the estimated water-surface elevation ("inundation elevation") along the river, an approximate extent of potential wetland for a restoration in agricultural land can be mapped. As part of the pilot study, a set of maps representing the estimated potential wetland extents was generated in a geographic information system (GIS) application by combining (1) a digital water-surface plane representing the surface of inundation elevation that sloped in the downstream direction of flow and (2) land-surface elevation data. These map products from the pilot study will aid the NRCS and its partners with the onsite inundation-zone verification in agricultural land for a potential restoration and will assist in determining at what elevation to plant hardwood trees for increased survivability on ground above frequently flooded terraces.

Indiana

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania

Landscape factors influencing the spatial distribution and abundance of mosquito vector Culex quinquefasciatus (Diptera: Culicidae) in a mixed residential-agricultural community in Hawai'i

Mosquito-borne avian diseases, principally avian malaria (Plasmodium relictum Grassi and Feletti) and avian pox (Avipoxvirus sp.) have been implicated as the key limiting factor associated with recent declines of endemic avifauna in the Hawaiian Island archipelago. We present data on the relative abundance, infection status, and spatial distribution of the primary mosquito vector Culex quinquefasciatus Say (Diptera: Culicidae) across a mixed, residential-agricultural community adjacent to Hawai'i Volcanoes National Park on Hawai'i Island. We modeled the effect of agriculture and forest fragmentation in determining relative abundance of adult Cx. quinquefasciatus in Volcano Village, and we implement our statistical model in a geographic information system to generate a probability of mosquito capture prediction surface for the study area. Our model was based on biweekly captures of adult mosquitoes from 20 locations within Volcano Village from October 2001 to April 2003. We used mixed effects logistic regression to model the probability of capturing a mosquito, and we developed a set of 17 competing models a priori to specifically evaluate the effect of agriculture and fragmentation (i.e., residential landscapes) at two spatial scales. In total, 2,126 mosquitoes were captured in CO 2-baited traps with an average probability of 0.27 (SE = 0.10) of capturing one or more mosquitoes per trap night. Twelve percent of mosquitoes captured were infected with P. relictum. Our data indicate that agricultural lands and forest fragmentation significantly increase the probability of mosquito capture. The prediction surface identified areas along the Hawai'i Volcanoes National Park boundary that may have high relative abundance of the vector. Our data document the potential of avian malaria transmission in residential-agricultural landscapes and support the need for vector management that extends beyond reserve boundaries and considers a reserve's spatial position in a highly heterogeneous landscape.

Journal of Medical Entomology

Ecoregional-scale monitoring within conservation areas, in a rapidly changing climate

Long-term monitoring of ecological systems can prove invaluable for resource management and conservation. Such monitoring can: (1) detect instances of long-term trend (either improvement or deterioration) in monitored resources, thus providing an early-warning indication of system change to resource managers; (2) inform management decisions and help assess the effects of management actions, as well as anthropogenic and natural disturbances; and (3) provide the grist for supplemental research on mechanisms of system dynamics and cause-effect relationships (Fancy et al., 2009). Such monitoring additionally provides a snapshot of the status of monitored resources during each sampling cycle, and helps assess whether legal standards and regulations are being met. Until the last 1-2 decades, tracking and understanding changes in condition of natural resources across broad spatial extents have been infrequently attempted. Several factors, however, are facilitating the achievement of such broad-scale investigation and monitoring. These include increasing awareness of the importance of landscape context, greater prevalence of regional and global environmental stressors, and the rise of landscape-scale programs designed to manage and monitor biological systems. Such programs include the US Forest Service's Forest Inventory and Analysis (FIA) Program (Moser et al., 2008), Canada's National Forest Inventory, the 3Q Programme for monitoring agricultural landscapes of Norway (Dramstad et al., 2002), and the emerging (US) Landscape Conservation Cooperatives (USDOI Secretarial Order 3289, 2009; Anonymous, 2011). This Special Section explores the underlying design considerations, as well as many pragmatic aspects associated with program implementation and interpretation of results from broad-scale monitoring systems, particularly within the constraints of high-latitude contexts (e.g., low road density, short field season, dramatic fluctuations in temperature). Although Alaska is the focus of most papers in this Special Section, we posit that many of the issues that characterize the remote, relatively undisturbed ecosystems of high northern latitudes are widespread and thus applicable to natural-resource management and conservation across northern portions of the Holarctic ecozone and indeed anywhere broad-scale monitoring is contemplated.

Biological Conservation

Simulation-optimization aids in resolving water conflict: Temecula Basin, Southern California

The productive agricultural areas of Pajaro Valley, California have exclusively relied on ground water from coastal aquifers in central Monterey Bay. As part of the Basin Management Plan (BMP), the Pajaro Valley Water Management Agency (PVWMA) is developing additional local supplies to replace coastal pumpage, which is causing seawater intrusion. The BMP includes an aquifer storage and recovery (ASR) system, which captures and stores local winter runoff, and supplies it to growers later in the growing season in lieu of ground-water pumpage. A Coastal Distribution System (CDS) distributes water from the ASR and other supplemental sources. A detailed model of the Pajaro Valley is being used to simulate the coupled supply and demand components of irrigated agriculture from 1963 to 2006. Recent upgrades to the Farm Process in MODFLOW (MF2K-FMP) allow simulating the effects of ASR deliveries and reduced pumping for farms in subregions connected to the CDS. The BMP includes a hierarchy of monthly supply alternatives, including a recovery well field around the ASR system, a supplemental wellfield, and onsite farm supply wells. The hierarchy of delivery requirements is used by MF2K-FMP to estimate the effects of these deliveries on coastal ground-water pumpage and recovery of water levels. This integrated approach can be used to assess the effectiveness of the BMP under variable climatic conditions, and to test the impacts of more complete subscription by coastal farmers to the CDS deliveries. The model will help managers assess the effects of new BMP components to further reduce pumpage and seawater intrusion.

California

Landscape level reforestation priorities for forest breeding landbirds in the Mississippi Alluvial Valley

Thousands of ha of cleared wetlands are being reforested annually in the Mississippi Alluvial Valley (MAV). Despite the expansive and long-term impacts of reforestation on the biological communities of the MAV, there is generally a lack of landscape level planning in its implementation. To address this deficiency we used raster-based digital data to assess the value of forest restoration to migratory landbirds for each ha within the MAV. Raster themes were developed that reflected distance from 3 existing forest cover parameters: (1) extant forest, (2) contiguous forest patches between 1,012 and 40,000 ha, and (3) forest cores with contiguous area <5,200 ha. Forest core habitat was any forest habitat >1 km from an agricultural, urban, or pastoral edge. Two additional raster themes were developed that combined information on the proportion of forest cover and average size of forest patches, respectively, within landscapes of 50,000, 100,000, 150,000, and 200,000 ha. Data from these 5 themes were amalgamated into a single raster using a weighting system that gave increased emphasis to existing forest cores, larger forest patches, and moderately forested landscapes while deemphasizing reforestation near small or isolated forest fragments and within largely agricultural landscapes. This amalgamated raster was then modified by the geographic location of historical forest cover and the current extent of public land ownership to assign a reforestation priority score to each ha in the MAV. However, because reforestation is not required on areas with extant forest cover and because restoration is unlikely on areas of open water and urban communities, these lands were not assigned a reforestation priority score. These spatially explicit reforestation priority scores were used to simulate reforestation of 368,000 ha (5%) of the highest priority lands in the MAV. Targeting restoration to these high priority areas resulted in a 54% increase in forest core - an area of forest core that exceeded the area of simulated reforestation. Bird Conservation Regions, developed within the framework of the Partners in Flight: Mississippi Alluvial Valley Bird Conservation Plan, encompassed a large proportion (circa 70%) of the area with highest priority for reforestation. Similarly, lands with high reforestation priority often were enrolled in the Wetland Reserve Program.

Book chapter