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USGS1999

External quality-assurance results for the National Atmospheric Deposition Program/National Trends Network, 1995-96

The U.S. Geological Survey operated four external quality-assurance programs for the National Atmospheric Deposition Program/National Trends Network (NADP/NTN) in 1995 and 1996: the intersite-comparison program, the blind-audit program, the interlaboratory- comparison program, and the collocated-sampler program. The intersite-comparison program assessed the precision and bias of pH and specific-conductance determinations made by NADP/NTN site operators. The analytical bias introduced during routine handling, processing, and shipping of wet-deposition samples and precision of analyte values was estimated using a blind-audit program. An interlaboratory-comparison program was used to evaluate differences between analytical results and to estimate the analytical precision of five North American laboratories that routinely analyzed wet deposition. A collocated-sampler program estimated the precision of the overall precipitation collection and analysis system from initial sample collection through final storage of the data. Results of two intersite-comparison studies completed in 1995 indicated 94.6 and 94.4 percent of the onsite pH determinations met the NADP/NTN accuracy goals, whereas 97.2 and 98.3 percent of the specific-conductance determinations were within the established limits. The percentages of onsite determinations that met the accuracy goals in 1996 were slightly less for both pH and specific-conductance than in 1995. In 1996, 93.2 and 87.5 percent of onsite pH determinations met the accuracy goals, whereas the percentage of onsite specific-conductance measurements that met the goals was 93.9 and 94.9 percent.The blind audit program utilizes a paired sample design to evaluate the effects of routine sample handling, processing and shipping on the chemistry of weekly precipitation samples. The portion of the blind audit sample subject to all of the normal onsite handling and processing steps of a regular weekly precipitation sample is referred to as the bucket portion, whereas the portion receiving only minimal handling is referred to as the bottle portion. Throughout the report, the term positive bias in regard to blind-audit results indicates that the bucket portion had a higher concentration than the bottle portion. The paired t-test of 1995 blind-audit data indicated that routine sample handling, processing, and shipping introduced a very small positive bias (a=0.05) for hydrogen ion and specific conductance and a slight negative bias (a =0.05) for ammonium and sodium. In 1995, the median paired differences between the bucket and bottle portions ranged from -0.02 milligram per liter for both ammonium and nitrate to +0.002 milligram per liter for calcium. Although the paired t-test indicated a very small positive bias for hydrogen ion, the median paired difference between the bucket and bottle portions was 0.00 microequivalents per liter, whereas for specific conductance, the median paired difference between the bucket and bottle portions was 0.200 microsiemens per centimeter in 1995. The paired t-test of blind-audit results in 1996 indicated statistically significant bias for 6 of the 10 analytes. Only chloride, nitrate, hydrogen ion, and specific conductance were not biased in 1996. However, the magnitude of the bias in 1996 was very small and only of limited importance from the viewpoint of an analytical chemist or data user. The median paired differences between the bucket and bottle portions ranged from -0.02 milligram per liter for both ammonium and chloride to +0.006 milligram per liter for calcium. For hydrogen ion, the median paired difference between the bucket and bottle portions was -0.357 microequivalent per liter; for specific conductance, the median paired difference between the bucket and bottle portions was 0.00 microsiemens per centimeter in 1996. Surface-chemistry effects due to different amounts of precipitation contacting the sample collection and shipping container surfac

Water-Resources Investigations Report↗

USGS1997

Water-quality trends for streams and reservoirs in the Research Triangle area of North Carolina, 1983-95

Water-quality and streamflow monitoring data, collected from 1983 to 1995, were analyzed for 34 stream and reservoir sites in a seven-county region within the upper Neuse and upper Cape Fear River Basins. Early data (1983-88) were compiled from U.S. Geological Survey water-quality studies and from the ambient water-quality monitoring network of the North Carolina Department of Environment, Health, and Natural Resources. Analyses of major ions, nutrients, metals, trace elements, and synthetic organic compounds were compiled from samples collected by the U.S. Geological Survey from 1988 to 1995 as part of a continuing project to monitor the water quality of surface-water supplies in the Research Triangle area of North Carolina, and from the North Carolina Department of Environment, Health, and Natural Resources ambient water-quality monitoring network. This report presents the results of analysis of consistently increasing or decreasing trends in concentrations of nitrogen and phosphorus species, suspended sediment, suspended solids, sodium, chloride, iron, manganese, zinc, and chlorophyll a from seasonal Kendall trend analysis on flow-adjusted concentrations for streams and concentrations in lakes. Total phosphorus concentrations also were tested for a step decrease in concentration (step trend) associated with the North Carolina phosphate-detergent ban of 1988. For some other constituents, insufficient data or values below laboratory detection limits precluded trend analysis. A regionwide decrease in total phosphorus, ranging from 25 to 81 percent, was observed that coincided with increased phosphorus removal efforts at municipal wastewater-treatment facilities in the region and the statewide phosphate-detergent ban. Most sites had stable or decreasing trends in nitrogen concentrations; however, increasing trends occurred in the Neuse River near Clayton and at Smithfield, both of which are downstream from the developing Raleigh-Durham area. Chlorophyll a concentrations have increased by 17 to 52 percent per year at monitored reservoirs, except at Cane Creek Reservoir and Lake Michie where there was no trend. No significant trends in suspended-sediment concentrations were observed. Long-term sodium concentrations were available for only a few sites. Of these, decreasing concentrations were observed in the Neuse River at Smithfield and Cane Creek near Orange Grove, and an increasing concentration was observed in University Lake. At most sites, concentrations of manganese, iron, and zinc were stable. Decreasing iron trends were observed in Little River and Cane Creek Reservoirs and Lake Michie. Cane Creek Reservoir also had a decreasing manganese trend. Seven sites, all downstream from wastewater-treatment facilities, were analyzed for zinc trends. A decreasing trend was observed in two of these--Knap of Reeds Creek and Little Lick Creek.

North Carolina↗

USGS1998

Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado↗

USGS2003

Trends in concentrations of polychlorinated biphenyls in fish tissue from selected sites in the Delaware River basin in New Jersey, New York, and Pennsylvania, 1969-98

Polychlorinated biphenyl (PCB) concentrations in fish tissue collected during the 1990's from selected sites in the Delaware River Basin were compared with concentrations in fish tissue collected during 1969-88. Data collected by State and Federal agencies on concentrations in whole-body common carp ( Cyprinus carpio ) and white sucker ( Catostomus commersoni ), and edible portions of American eel ( Anguilla rostrata ), smallmouth bass ( Micropterus dolomieu ), and channel catfish ( Ictalurus punctatus ) during 1969-98 were compiled to define temporal trends in concentrations of PCBs in fish tissue from selected segments of the Delaware River, Lehigh River, Schuylkill River, and Brandywine Creek. The Delaware River in the vicinity of Trenton, New Jersey and Yardley, Pennsylvania (above the tidal influence) had the largest long-term data set among the sites considered for this study and was the only site with sufficient data for statistical analysis. A general pattern of decline in PCB concentrations during 1969-98 was apparent for this river segment. PCB concentrations in whole-body white sucker from this lower Delaware River segment declined during 1969-98 from a highest concentration of 7 micrograms per gram ( μ g/g, wet weight) in a sample collected during 1972 to 0.26 μ g/g (wet weight) in a sample collected during 1998. PCB concentration was negatively correlated with year (Spearman rank correlation -0.46, p < 0.08, n = 15); especially after removal of a sample from 1977 with an unusually low concentration (Spearman rank correlation -0.53, p = 0.05, n = 14). PCB concentrations in edible flesh of American eel declined during 1975-95, from a highest concentration of 3.8 μ g/g (wet weight) in a sample collected during 1976 to less than the reporting limit of 0.26 μ g/g (wet weight) in samples collected during 1993 and 1995. PCB concentrations in most samples (for species considered in this study) collected from the lower Delaware River exceeded the National Academy of Sciences and National Academy of Engineering (NAS/NAE) wildlife guideline level of 0.5 μ g/g during the 1970's and 1980's, and decreased to below this level during the 1990's. No samples of edible portions of game fish exceeded the U.S. Food and Drug Administration (FDA) tolerance level by the mid 1980's. However, the PCB concentration in a smallmouth bass fillet sample that was collected during 1998 (0.37 μ g/g) exceeded the Pennsylvania fish-consumption advisory level of 0.06 μ g/g, and the concentrations in whole-body common carp and white sucker collected during 1998 (1.10 μ g/g and 0.26 μ g/g, respectively) exceeded the New York State Department of Environmental Conservation wildlife criterion concentration of 0.11 μ g/g. (The concentration in carp also exceeded the 1973 NAS/NAE wildlife guideline concentration of 0.5 μ g/g.) Graphical analysis of PCB concentrations in whole white sucker and (or) edible portions of American eel from the upper Delaware River, lower Delaware River, middle Schuylkill River, and Brandywine Creek indicate a decline from the 1970's and (or) 1980's to the middle to late 1990's. Temporal trends in PCB concentrations in white sucker samples from the lower Lehigh and Schuylkill Rivers during 1979-98 are less clear; the PCB concentration (wet-weight basis) from a sample collected in 1998 from the lower Lehigh River was similar to that from a sample collected in 1979, and concentrations actually increased during 1982-98. Similarly, PCB concentrations in samples of white sucker and American eel from the lower Schuylkill River were highly variable over time.

New Jersey, New York, Pennsylvania↗

USGS1996

Trends in nutrients and suspended solids at the Fall Line of five tributaries to the Chesapeake Bay in Virginia, July 1988 through June 1995

Water-quality samples were collected at the Fall Line of five tributaries to the Chesapeake Bay in Virginia during a 6- to 7-year period. The water-quality data were used to estimate loads of nutrients and suspended solids from these tributaries to the non-tidal part of Chesapeake Bay Basin and to identify trends in water quality. Knowledge of trends in water quality is required to assess the effectiveness of nutrient manage- ment strategies in the five basins. Multivariate log-linear regression and the seasonal Kendall test were used to estimate flow-adjusted trends in constituent concentration and load. Results of multivariate log-linear regression indicated a greater number of statistically significant trends than the seasonal Kendall test; how-ever, when both methods indicated a significant trend, both agreed on the direction of the trend. Interpre- tation of the trend estimates for this report was based on results of the parametric regression method. No significant trends in total nitrogen concentration were detected at the James River monitoring station from July 1988 through June 1995, though total Kjeldahl nitrogen concen- tration decreased slightly in base-flow samples. Total phosphorus concentration decreased about 29 percent at this station during the sampling period. Most of the decrease can be attributed to reductions in point-source phosphorus loads in 1988 and 1989, especially the phosphate detergent ban of 1988. No significant trends in total suspended solids were observed at the James River monitoring station, and no trends in runoff- derived constituents were interpreted for this river. Significant decreases were detected in concentrations of total nitrogen, total Kjeldahl nitrogen, dissolved nitrite-plus-nitrate nitrogen, and total suspended solids at the Rappahannock River monitoring station between July 1988 and June 1995. A similar downward trend in total phosphorus concentration was significant at the 90-percent confidence level, but not the 95-percent confidence level. These decreases can be attributed primarily to reductions in nonpoint nutrient and sediment loads, and may have been partially caused by implementation of best management practices on agricultural and silvicultural land. Flow-adjusted trends observed at the Appomattox, Pamunkey, and Mattaponi monitoring stations were more difficult to explain than those at the James and Rappahannock stations. Total Kjeldahl nitrogen and total phosphorus increased 16 and 23 percent, respectively, at the Appomattox River monitoring station from July 1989 through June 1995. Total phosphorus concentration increased about 46 percent at the Pamunkey River monitoring station between July 1989 and June 1995. At the Mattaponi River monitoring station, decreases in dissolved nitrite-plus-nitrate nitrogen were offset by increases in total Kjeldahl nitrogen, resulting in no net change in total nitrogen concentration from October 1989 through June 1995.

Water-Resources Investigations Report↗

USGS1999

Occurrence of organochlorine compounds in whole fish tissue from streams of the lower Susquehanna River Basin, Pennsylvania and Maryland, 1992

Tissue samples of whole body white sucker ( Catostomus commersoni ) were collected at 15 sites and smallmouth bass ( Micropterus dolomieu ) were collected at 5 sites during 1992 in the Lower Susquehanna River Basin to determine the occurrence and distribution of 28 selected organochlorine compounds as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. Only 12 of the 28 compounds occurred at concentrations greater than the 5 µg/kg reporting limit (total PCB’s reporting limit is ‹50 µg/kg and toxaphene is ‹200 µg/kg). The most frequently reported compounds were p,p ’-DDE (reported in all tissue samples), total polychlorinated biphenyls (PCB’s), and trans-nonachlor. High concentrations of p,p’ -DDE and low concentrations of the other DDT metabolites for the Lower Susquehanna River sites indicate no recent influx of DDT. Comparison with historical data from the Lower Susquehanna River Basin shows a decline of organochlorine concentrations within the basin. In 1987, Quittapahilla Creek had the highest concentrations of p,p’ -DDE in a national survey of contaminant occurrence in fish tissue conducted by the U.S. Environmental Protection Agency. This stream ranked the highest for total DDT of the 20 NAWQA studies started nationally in 1991. Total DDT concentrations were higher in agriculture-dominated (>50 percent) sites than in forest-dominated (>50 percent) sites with the exception of Deer Creek and Big Beaver Creek. These two sites are located more in grazing areas that lack a substantial crop-land use. Concentrations of total PCB’s were highest in basins with greater than 10 percent urban land use excluding the larger river sites. Concentrations of total chlordane were highest at sites with greater than 70 percent agricultural and 10 percent urban land use. Regional comparisons of total DDT, total PCB’s, and total chlordane in white sucker tissue from the Lower Susquehanna, Hudson (in New York), and Connecticut River Basins showed that median concentrations of total DDT were different (p=0.05), with the Lower Susquehanna Basin being the lowest. Total PCB’s and total chlordane medians were similar. Comparison of the data from national and regional studies with data from this local study showed concentrations of p,p’ -DDE in the Lower Susquehanna River Basin are similar to those nationwide and lower than the concentrations measured in the Northeast. PCB concentrations in the Lower Susquehanna River Basin and the Northeast were higher than those nationwide.

Water-Resources Investigations Report↗

USGS1995

Relation of fracture orientation to linear terrain features, anisotropic transmissivity, and seepage to streams in the karst Prairie du Chien Group, southeastern Minnesota

Ground-water flow in the karst-terrane aquifers of southeastern Minnesota is not well defined. Variable fracture patterns in the bedrock affect permeability. Techniques to predict the effects of fracture patterns on ground-water flow in the karst-terrane aquifers of southeastern Minnesota are unavailable. The use of such techniques may be useful to officials responsible for the management and protection of ground water in these aquifers, which have a high susceptibility to contamination. The U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources and the Legislative Commission on Minnesota Resources, investigated fracture patterns, anisotropic transmissivity, and seepage to streams from the Prairie du Chien Group, which is the karst portion of the St. Peter-Prairie du Chien-Jordan aquifer, to improve the understanding of ground-water flow through karst-terrane aquifers in southeastern Minnesota. This report presents the results of testing hypotheses that (1) the major axes of linear terrain features correlate with the major axes of subsurface fractures in the Prairie du Chien Group, and that (2) the major axes of subsurface fractures in the Prairie du Chien Group correlate with seepage from the Prairie du Chien Group. The first hypothesis was tested by comparison of linear terrain features to fracture orientation measurements. Fracture orientations in 10 exposures of the Prairie du Chien Group at quarries, road cuts, and natural outcrops showed statistically significant directional trends at 8 of 10 sites. Directional trends of linear terrain features identified from 1:80,000 aerial photographs were significant in four of the ten 60-square mile areas that surround these sites. The fracture orientation measurements correlate with the local linear terrain features in 2 of the 10 sites. The second hypothesis was tested by analyzing the correlation between seepage rates into streams hydraulically connected to the Prairie du Chien Group and surrounding linear terrain features that were mapped in approximately 300 square mile areas. Data from Riceford Creek support this hypothesis; data from Crow Creek and Middle Fork of the Whitewater River and from Duschee Creek are inconclusive. This hypothesis could not be tested by the data from the Middle Fork of the Zumbro River, the South Branch of the Root River, and the South Branch of the Middle Fork of the Zumbro River because the surrounding linear terrain features lack directional trends. The transmissivity of the karst portion of the St. Peter-Prairie du Chien-Jordan aquifer is anisotropic at an aquifertest site in the study area. Results of the aquifer test indicate that the major axis of transmissivity is along a line N95°E. The aquifer-test results indicate that the principal axis of joint fractures at the test site is slightly clockwise from an east-west line because this axis is assumed to correlate with the major axis of horizontal transmissivity.

Minnesota↗

USGS2003

Water-quality trend analysis and sampling design for streams in North Dakota, 1971-2000

This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the North Dakota Department of Health, to analyze historical water-quality trends in selected dissolved major ions, nutrients, and dissolved trace metals for 10 streams in southwestern and eastern North Dakota and to develop an efficient sampling design to monitor future water-quality trends. A time-series model for daily streamflow and constituent concentration was used to identify significant concentration trends, separate natural hydroclimatic variability in concentration from variability that could have resulted from anthropogenic causes, and evaluate various sampling designs to monitor future water-quality trends. The interannual variability in concentration as a result of variability in streamflow, referred to as the annual concentration anomaly, generally was high for all constituents and streams used in the trend analysis and was particularly sensitive to the severe drought that occurred in the late 1980's and the very wet period that began in 1993 and has persisted to the present (2002). Although climatic conditions were similar across North Dakota during the trend-analysis period (1971-2000), significant differences occurred in the annual concentration anomalies from constituent to constituent and location to location, especially during the drought and the wet period. Numerous trends were detected in the historical constituent concentrations after the annual concentration anomalies were removed. The trends within each of the constituent groups (major ions, nutrients, and trace metals) showed general agreement among the streams. For most locations, the largest dissolved major-ion concentrations occurred during the late 1970's and concentrations in the mid- to late 1990's were smaller than concentrations during the late 1970's. However, the largest concentrations for three of the Missouri River tributaries and one of the Red River of the North tributaries occurred during the mid- to late 1990's. Concentration trends for total ammonia plus organic nitrogen showed close agreement among the streams for which that constituent was evaluated. The largest concentrations occurred during the early 1980's, and the smallest concentrations occurred during the early 1990's. Nutrient data were not available for the early 1970's or late 1990's. Although a detailed analysis of the causes of the trends was beyond the scope of this report, a preliminary analysis of cropland, livestock-inventory, and oil-production data for 1971-2000 indicated the concentration trends may be related to the livestock-inventory and oil-production activities in the basins. Dissolved iron and manganese concentrations for the southwestern North Dakota streams generally remained stable during 1971-2000. However, many of the recorded concentrations for those streams were less than the detection limit, and trends that were masked by censoring may have occurred. Several significant trends were detected in dissolved iron and manganese concentrations for the eastern North Dakota streams. Concentrations for those streams either remained stable or increased during most of the 1970's and then decreased rapidly for about 2 years beginning in the late 1970's. The concentrations were relatively stable from the early 1980's to 2000 except at two locations where dissolved iron concentrations increased during the early 1990's. The most efficient overall sampling designs for the detection of annual trends (that is, trends that occur uniformly during the entire year) consisted of balanced designs in which the sampling dates and the number of samples collected remained fixed from year to year and in which the samples were collected throughout the year rather than in a short timespan. The best overall design for the detection of annual trends consisted of three samples per year, with samples collected near the beginning of December, April, and August. That design had acceptable sensitivity for the detection of trends in most constituents at all locations. Little improvement in sensitivity was achieved by collecting more than three samples per year. The sampling designs that were first evaluated for annual trends also were evaluated with regard to their sensitivity to detect seasonal trends that occurred during three seasons--April through August, August through December, and December through April. Design results indicated that an average of one extra sample per station per year resulted in an efficient design for detecting seasonal trends. However, allocation of the extra samples varied depending on the station, month, and constituent group (major ions, nutrients, and trace metals).

North Dakota↗

USGS1998

Depth-duration frequency of precipitation for Texas

The U.S. Geological Survey, in cooperation with the Texas Department of Transportation, conducted a study of the depth-duration frequency of precipitation for Texas. Depth-duration frequency is an estimate of the depth of precipitation for a specified duration and frequency or recurrence interval. For this report, precipitation durations of 15, 30, and 60 minutes; 1, 2, 3, 6, 12, and 24 hours; and 1, 2, 3, 5, and 7 days were investigated. The recurrence intervals for the frequencies range from 2 to 500 years. The time series of precipitation annual maxima for 173 fifteen-minute, 274 hourly, and 865 daily National Weather Service precipitation stations with at least 10 years of record in Texas provide the basis of depth-duration frequency for each identified duration. In total, about 3,030; 10,160; and 38,120 cumulative years of record are available for the 15-minute, hourly, and daily stations, respectively. L-moment statistics of the precipitation annual maxima were calculated for each duration and for each station using unbiased L-moment estimators. The statistics calculated were the mean, L-scale, L-coefficient of variation, L-skew, and L-kurtosis. The mean for each station and duration was corrected for the bias associated with fixed-interval recording of precipitation. The generalized logistic distribution was determined, using L-moment ratio diagrams, as an appropriate probability distribution for modeling the frequency of annual maxima for durations of 15 minutes to 24 hours; whereas, the generalized extreme-value distribution was determined as appropriate for durations of 1 to 7 days. The location, scale, and shape parameters of the distributions for each duration and each station were calculated from the L-moments. These parameters were contoured using spatial interpolation, based on the geostatistical method of kriging, to produce 37 maps that depict the spatial variation and magnitude of each parameter. Contour maps of the shape parameter for the generalized extreme-value distribution for durations of 1 to 7 days are not presented; the root mean square errors of preliminary maps for 1- to 7-day shape parameters were not appreciably smaller than the statewide standard deviation. Therefore, a single statewide mean shape parameter was used for 1- to 7-day durations. The depth-duration frequency for any location in Texas can be estimated using the contour maps and the equation of the corresponding distribution.

Texas↗

USGS1985

Cost effectiveness of stream-gaging program in Michigan

This report documents the results of a study of the cost effectiveness of the stream-gaging program in Michigan. Data uses and funding sources were identified for the 129 continuous gaging stations being operated in Michigan as of 1984. One gaging station was identified as having insufficient reason to continue its operation. Several stations were identified for reactivation, should funds become available, because of insufficiencies in the data network. Alternative methods of developing streamflow information based on routing and regression analyses were investigated for 10 stations. However, no station records were reproduced with sufficient accuracy to replace conventional gaging practices. A cost-effectiveness analysis of the data-collection procedure for the ice-free season was conducted using a Kalman-filter analysis. To define missing-record characteristics, cross-correlation coefficients and coefficients of variation were computed at stations on the basis of daily mean discharge. Discharge-measurement data were used to describe the gage/discharge rating stability at each station. The results of the cost-effectiveness analysis for a 9-month ice-free season show that the current policy of visiting most stations on a fixed servicing schedule once every 6 weeks results in an average standard error of 12.1 percent for the current $718,100 budget. By adopting a flexible servicing schedule, the average standard error could be reduced to 11.1 percent. Alternatively, the budget could be reduced to $700,200 while maintaining the current level of accuracy. A minimum budget of $680,200 is needed to operate the 129-gaging-station program; a budget less than this would not permit proper service and maintenance of stations. At the minimum budget, the average standard error would be 14.4 percent. A budget of $789,900 (the maximum analyzed) would result in a decrease in the average standard error to 9.07 percent. Owing to continual changes in the composition of the network and the changes in the uncertainties of streamflow accuracy at individual stations, the cost-effectiveness analysis will need to be updated regularly if it is to be used as a management tool. Cost of these updates need to be considered in decisions concerning the feasibility of flexible servicing schedules.

Michigan↗

USGS2000

Laboratory performance in the Sediment Laboratory Quality-Assurance Project, 1996-98

This report describes the results of the first 3 years of an ongoing study of sediment laboratories used by the U.S. Geological Survey (USGS). The sediment laboratories currently in operation constitute the entire USGS national laboratory system for sediment analyses. As with all environmental data, physical sediment data can be expected to contain a certain amount of difference, whether the difference resulted from the collecting, transporting, or analyzing of the sample. Because it is important to know how each laboratory is performing, the USGS initiated the Sediment Laboratory Quality-Assurance (SLQA) project in August 1996. From August 1996 through June 1998, five studies were made, the results of which are the basis of this report. The focus of the project is on quantitative analyses done on water-sediment mixtures to derive suspended-sediment concentrations, sediment-mass determinations, and sand/fine separations. For the purpose of this report, all mass determinations are net values—the tare weight of the container is excluded. The fine-size material is defined as particles sieved to a size of less than 62 micrometers (µm) and sand-size material is defined as particles sieved to a size of between 63 and 125 µm. Also, in this report, class 1 samples are defined as samples containing 50 to 100 milligrams (mg) of fine-size material, class 2 samples are defined as samples containing 101 to 300 mg of fine-size material, and class 3 samples are defined as samples containing 2,200 to 3,200 mg of fine-size material. In studies 96-1 through 98-1, the amount of sand added to each sample ranged from 9 to 28 percent of the mass of fine-size material in each sample class. Analytical results from all sediment quality-control samples are compiled and statistically summarized by the USGS, Branch of Quality Systems, both on an intra- and interlaboratory basis. When evaluating these data, the reader needs to keep in mind that every measurement has an error component associated with it. It is premature to use the data from the first five SLQA studies to judge any of the laboratories as performing in an unacceptable manner. There were, however, some notable differences in the results for the 12 laboratories that participated in the five SLQA studies. For example, the overall median percent difference for suspended-sediment concentration on an individual laboratory basis ranged from –18.04 to –0.33 percent. Five of the 12 laboratories had an overall median percent difference for suspended-sediment concentration of –2.02 to –0.33 percent. There was less variability in the median difference for the measured fine-size material mass. The overall median percent difference for fine-size material mass ranged from –10.11 to –4.27 percent. Except for one laboratory, the median difference for fine-size material mass was within a fairly narrow range of –6.76 to –4.27 percent. The median percent difference for sand-size material mass differed among laboratories more than any other physical sediment property measured in the study. The overall median percent difference for the sand-size material mass ranged from –1.49 percent to 26.39 percent. Five of the nine laboratories that do sand/fine separations had overall median percent differences that ranged from –1.49 to 2.98 percent for sand-size material mass. Careful review of the data reveals that certain laboratories consistently produced data within statistical control limits for some or all of the physical sediment properties measured in this study, whereas other laboratories occasionally produced data that exceeded the control limits.

Water-Resources Investigations Report↗

USGS2003

Trends in suspended-sediment concentration at selected stream sites in Kansas, 1970–2002

Knowledge of erosion, transport, and deposition of sediment relative to streams and impoundments is important to those involved directly or indirectly in the development and management of water resources. Monitoring the quantity of sediment in streams and impoundments is important because: (1) sediment may degrade the water quality of streams for such uses as municipal water supply, (2) sediment is detrimental to the health of some species of aquatic animals and plants, and (3) accumulation of sediment in water-supply impoundments decreases the amount of storage and, therefore, water available for users. One of the objectives of the Kansas Water Plan is to reduce the amount of sediment in Kansas streams by 2010. During the last 30 years, millions of dollars have been spent in Kansas watersheds to reduce sediment transport to streams. Because the last evaluation of trends in suspended-sediment concentrations in Kansas was completed in 1985, 14 sediment sampling sites that represent 10 of the 12 major river basins in Kansas were reestablished in 2000. The purpose of this report is to present the results of time-trend analyses at the reestablished sediment data-collection sites for the period of about 1970–2002 and to evaluate changes in the watersheds that may explain the trends. Time-trend tests for 13 of 14 sediment sampling sites in Kansas for the period from about 1970 to 2002 indicated that 3 of the 13 sites tested had statistically significant decreasing suspended-sediment concentrations; however, only 2 sites, Walnut River at Winfield and Elk River at Elk Falls, had trends that were statistically significant at the 0.05 probability level. Increasing suspended-sediment concentrations were indicated at three sites although none were statistically significant at the 0.05 probability level. Samples from five of the six sampling sites located upstream from reservoirs indicated decreasing suspended-sediment concentrations. Watershed impoundments located in the respective river basins may contribute to the decreasing suspended-sediment trends exhibited at most of the sampling sites because the impoundments are designed to trap sediment. Both sites that exhibited statistically significant decreasing suspended-sediment concentrations have a large number of watershed impoundments located in their respective drainage basins. The relation between percentage of the watershed affected by impoundments and trend in suspended-sediment concentration for 11 sites indicated that, as the number of impoundments in the watershed increases, suspended-sediment concentration decreases. Other conservation practices, such as terracing of farm fields and contour farming, also may contribute to the reduced suspended-sediment concentrations if their use has increased during the period of analysis. Regression models were developed for 13 of 14 sediment sampling sites in Kansas and can be used to estimate suspended-sediment concentration if the range in stream discharge for which they were developed is not exceeded and if time trends in suspended-sediment concentrations are not significant. For those sites that had a statistically significant trend in suspended-sediment concentration, a second regression model was developed using samples collected during 2000–02. Past and current studies by the U.S. Geological Survey have shown that regression models can be developed between in-stream measurements of turbidity and laboratory-analyzed sediment samples. Regression models were developed for the relations between discharge and suspended-sediment concentration and turbidity and suspended-sediment concentration for 10 sediment sampling sites using samples collected during 2000–02.

Kansas↗

USGS1995

Characteristics, transport, and yield of sediment in Juday Creek, St. Joseph County, Indiana, 1993-94

Juday Creek is a tributary of the St. Joseph River in St. Joseph County, north-central Indiana. The creek has been identified as one of the few streams in the State that can support a naturally reproducing brown trout population. A recent study of benthic invertebrates shows a decline in the production rate of insect species and suggests that this decline may be caused by increased sedimen- tation. This report presents the results of a study of the sediment conditions in Juday Creek from April 1993 through June 1994. Measurements of streamflow, suspended sediment, and bedload were made at six sampling sites during three storms and a period of low flow. A total of 11 samples were collected during storms, and 1 sample was collected during low flow at each site. Bed-material samples were collected at the six sites. Sediment cores were collected from the delta of an instream pond and at a sediment trap near the mouth of the stream. Scour and fill at the six sites were monitored by means of scour chains and surveyed cross sections. The instream pond was surveyed twice, and the volume weight of the sediment was determined to estimate the yield of sediment for the upper reach of Juday Creek. Particle-size distributions indicate that the bed material is predominantly sand and gravel and that very little of the bed material is silt or finer (less than 0.062 millimeter). Analysis of sediment cores showed that most of the sediment deposited in the sediment trap and instream pond was sand. Sediment sampling during a period of low flow detected only minimal concentrations of suspended sediment; the maximum concentration was 6 milligrams per liter, equivalent to a daily load of 0.32 ton. Bedload ranged from 5.2 to 76.7 grams per cross- channel sampling, equivalent to 0.11 to 1.70 tons per day. Sediment sampling during the storms indicates that bedload discharge is the primary mode of sediment transport. Suspended-sediment concentration ranged from 4 to 67 milligrams per liter; the median was 17 milligrams per liter. Bedload ranged from 3.4 to 862 grams per cross- channel sampling; the median was 109 grams. Only 15 percent of the samples were less than 50 grams. Scour chains and surveyed cross sections documented some scour and fill at most of the sites.Scour and fill tended to balance out; after a 1-year period, the net change in the streambed altitude was minimal. Some infilling was the net result at most of the sites. Surveys of the instream pond determined that the volume of sediment delivered to the pond from April 1993 to April 1994 was approximately 26,500 cubic feet. The average volume weight of the sediment was determined to be 102 pounds per cubic foot. The sediment yield for the upper reach of Juday Creek from April 1993 to April 1994 was estimated to be 48 tons per square mile.

Indiana↗

USGS2002

Standard errors of annual discharge and change in reservoir content data from selected stations in the lower Colorado River streamflow-gaging station network, 1995-99

The Bureau of Reclamation is currently (1995–2001) testing the Lower Colorado River Accounting System as a method to estimate the consumptive use of Colorado River water by diverters from Hoover Dam to Mexico. Consumptive use is estimated in the Lower Colorado River Accounting System method, in part, on the basis of the annual discharge or annual change in reservoir contents, as well as the variance of estimate of the annual discharge or the annual change in reservoir contents at several surface-water gaging stations in the lower Colorado River stream-gaging network. The standard error and the variance of estimate were determined for the annual discharge at 14 streamflow-gaging stations and for the annual change in content at 2 reservoir-content gaging stations used in the Lower Colorado River Accounting System for calendar years 1995–99. The standard error of the annual discharge was determined by using modifications to an existing method that assumes that the uncertainty in the discharge-rating shift is the main source of uncertainty in computed discharges and that the discharge-rating shift behaves as a first-order Markovian process. The method uses Kalman filtering of a first-order Markovian process as a statistical analogy to computing streamflow with a shifted discharge rating. Temporally unbiased residuals from a discharge rating are used as a surrogate for the actual shifts used to compute discharge. The standard error of the annual discharge is determined by using Kalman-filter theory and estimates of four parameters: (1) the measurement variance of the discharge measurements used to determine the discharge-rating shift, (2) the process variance of the discharge-rating residuals, (3) the serial correlation of the discharge-rating residuals, and (4) the frequency of the discharge measurements. The existing methodology was improved by estimating the measurement variance from a semivariogram of the discharge-rating residuals, rather than on the basis of empirically derived error estimates for discharge measurements. The process variance and serial correlation of the discharge-rating residuals are estimated from the semivariogram, rather than a variogram, of the discharge-rating residuals. The empirically derived estimates are based on characteristics of the discharge measurements such as number of depth and velocity observation sections, type of current meter, and bed material composition and stability. Measurement variance determined from the semivariograms was site specific and is therefore considered a better estimate than measurement variance determined from the empirically-derived estimates. The method of estimating the standard error of the annual discharge requires the assumption of unbiased discharge-rating residuals, and for this reason, the standard errors presented in this report only represent the random error in the annual discharge data. Estimates of the standard error of the annual change in reservoir content were determined on the basis of the reservoir-surface area and the standard error of reservoir-stage readings. The standard error of the annual discharge, as a percentage, ranged from 0.11 percent for the All- American Canal near Imperial Dam in 1998 to 12.3 percent for the Colorado River below Imperial Dam in 1996. The standard error of the annual discharge was less than 2 percent for all 5 years for 11 of the 14 streamflow-gaging stations. In terms of flow volume, the standard error of the annual discharge ranged from 97 acre-feet for the Mittry Lake Diversions in 1995 to 77,000 acre-feet for the Colorado River at the northerly international boundary with Mexico in 1998. In general, the standard error of the annual discharge, as a percentage, was smallest at streamflow-gaging stations on the main stem of the Colorado River; however, the standard error of the annual discharge in acre-feet was largest at these stations because of the large annual discharge on the main stem. The standard error of the annual change in content for the two reservoirs ranged from 1,590 acre-feet for Lake Havasu in 1996 to 2,790 acre-feet for Lake Mohave in 1995. The variance of estimate of the annual discharge for a streamflow-gaging station can be reduced by making additional discharge measurements; either by increasing the number of discharge measurements made per site visit, or by increasing the frequency of site visits. Measurement error can be reduced by using the average shift for two or more discharge measurements made during a site visit. For a streamflow-gaging station where measurement error is much greater than process error and the serial correlation of the discharge-rating residuals is high, an improved gaging strategy would involve making multiple discharge measurements per site visit. In contrast, for a streamflow-gaging station where process error is much greater than measurement error and the serial correlation of discharge-rating residuals is low, the gaging strategy would consist of several single discharge-measurement site visits. For a given operating cost or for a given variance of estimate of the annual discharge at a streamflow-gaging station, the optimal site-visit and discharge-measurement strategy can be determined, providing that the travel costs as well as the measurement variance, process variance, and serial correlation of discharge-rating residuals are known.

Arizona;California↗

USGS2003

Main-channel slopes of selected streams in Iowa for estimation of flood-frequency discharges

This report describes a statewide study conducted to develop main-channel slope (MCS) curves for 138 selected streams in Iowa with drainage areas greater than 100 square miles. MCS values determined from the curves can be used in regression equations for estimating floodfrequency discharges. Multivariable regression equations previously developed for two of the three hydrologic regions defined for Iowa require the measurement of MCS. Main-channel slope is a difficult measurement to obtain for large streams using 1:24,000-scale topographic maps. The curves developed in this report provide a simplified method for determining MCS values for sites located along large streams in Iowa within hydrologic Regions 2 and 3. The curves were developed using MCS values quantified for 2,058 selected sites along 138 selected streams in Iowa. A geographic information system (GIS) technique and 1:24,000-scale topographic data were used to quantify MCS values for the stream sites. The sites were selected at about 5-mile intervals along the streams. River miles were quantified for each stream site using a GIS program. Data points for river-mile and MCS values were plotted and a best-fit curve was developed for each stream. An adjustment was applied to all 138 curves to compensate for differences in MCS values between manual measurements and GIS quantifications. The multivariable equations for Regions 2 and 3 were developed using manual measurements of MCS. A comparison of manual measurements and GIS quantifications of MCS indicates that manual measurements typically produce greater values of MCS compared to GIS quantifications. Median differences between manual measurements and GIS quantifications of MCS are 14.8 and 17.7 percent for Regions 2 and 3, respectively. Comparisons of percentage differences between flood-frequency discharges calculated using MCS values of manual measurements and GIS quantifications indicate that use of GIS values of MCS for Region 3 substantially underestimate flood discharges. Mean and median percentage differences for 2- to 500-year recurrence- interval flood discharges ranged from 5.0 to 5.3 and 4.3 to 4.5 percent, respectively, for Region 2 and ranged from 18.3 to 27.1 and 12.3 to 17.3 percent for Region 3. The MCS curves developed from GIS quantifications were adjusted by 14.8 percent for streams located in Region 2 and by 17.7 percent for streams located in Region 3. Comparisons of percentage differences between flood discharges calculated using MCS values of manual measurements and adjusted-GIS quantifications for Regions 2 and 3 indicate that the flood-discharge estimates are comparable. For Region 2, mean percentage differences for 2- to 500-year recurrence- interval flood discharges ranged between 0.6 and 0.8 percent and median differences were 0.0 percent. For Region 3, mean and median differences ranged between 5.4 to 8.4 and 0.0 to 0.3 percent, respectively. A list of selected stream sites presented with each curve provides information about the sites including river miles, drainage areas, the location of U.S. Geological Survey streamflowgaging stations, and the location of streams crossing hydrologic region boundaries or the Des Moines Lobe landform region boundary. Two examples are presented for determining river-mile and MCS values, and two techniques are presented for computing flood-frequency discharges.

Iowa↗

USGS1993

Estimating design-flood discharges for streams in Iowa using drainage-basin and channel-geometry characteristics

Drainage-basin and channel-geometry multiple-regression equations are presented for estimating design-flood discharges having recurrence intervals of 2, 5, 10, 25, 50, and 100 years at stream sites on rural, unregulated streams in Iowa. Design-flood discharge estimates determined by Pearson Type-Ill analyses using data collected through the 1990 water year are reported for the 188 streamflow-gaging stations used in either the drainage-basin or channel-geometry regression analyses. Ordinary least-squares multiple-regression techniques were used to identify selected drainage-basin and channel-geometry characteristics and to delineate two channel-geometry regions. Weighted least-squares multiple-regression techniques, which account for differences in the variance of flows at different gaging stations and for variable lengths in station records, were used to estimate the regression parameters. Statewide drainage-basin equations were developed from analyses of 164 streamflow-gaging stations. Drainage-basin characteristics were quantified using a geographic-informationsystem procedure to process topographic maps and digital cartographic data. The significant characteristics identified for the drainage-basin ^equations included contributing drainage area, relative relief, drainage frequency, and 2-year, 24-hour precipitation intensity. The average standard errors of prediction for the drainagebasin equations ranged from 38.6 to 50.2 percent. The geographic-information-system procedure expanded the capability to quantitatively relate drainage-basin characteristics to the magnitude and frequency of floods for stream sites in Iowa and provides a flood-estimation method that is independent of hydrologic regionalization. Statewide and regional channel-geometry regression equations were developed from analyses of 157 streamflow-gaging stations. Channel-geometry characteristics were measured onsite and on topographic maps. Statewide and regional channel-geometry regression equations that are dependent on whether a stream has been channelized were developed on the basis of bankfull and active-channel characteristics. The significant channel-geometry characteristics identified for the statewide and regional regression equations included bankfull width and bankfull depth for natural channels unaffected by channelization, and active-channel width for stabilized channels affected by channelization. The average standard errors of prediction ranged from 41.0 to 68.4 percent for the statewide channel-geometry equations and from 30.3 to 70.0 percent for the regional channel-geometry equations. Procedures provided for applying the drainage-basin and channel-geometry regression equations depend on whether the design-flood discharge estimate is for a site on an ungaged stream, an ungaged site on a gaged stream, or a gaged site. When both a drainage-basin and a channel-geometry regression-equation estimate are available for a stream site, a procedure is presented for determining a weighted average of the two flood estimates. The drainage-basin regression equations are applicable to unregulated rural drainage areas less than 1,060 square miles, and the channel-geometry regression equations are applicable to unregulated rural streams in Iowa with stabilized channels.

Iowa↗

USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Fish communities at selected sites, 1993-95

Fish communities at 10 sites in the Rio Grande Basin were sampled during low-flow periods between 1993 and 1995 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The ecology of fish communities is one of several lines of evidence used to characterize water-quality conditions. This report describes the fish communities at selected sites in the Rio Grande Basin and relates the structure of these fish communities to the physical and chemical characteristics of the streams. Twenty-nine species of fish representing 10 families were identified in 25 samples collected during this study. Species richness ranged from 1 to 13. Cluster analysis of the 25 samples collected during this study delineated four groups of sites that were based on the similarity of the fish communities. The first two groups were individual sites with low species richness. The third group contained the most samples, and the fourth group consisted of samples from the Rio Grande at Isleta, New Mexico, and the Rio Grande at El Paso, Texas. The shift in community structure of samples from group 3 to group 4 reflects changes from predominantly coldwater fishes to warmwater fishes. Four metrics of biotic integrity (percentages of introduced individuals, omnivores, tolerant individuals, and anomalies) were used in this study to provide a broad overview of the community structure. The relative percentages of introduced species at the Rio Grande near Del Norte, Colorado; Saguache Creek near Saguache, Colorado; Rio Grande below Taos Junction Bridge, near Taos, New Mexico; and Rio Grande at Isleta are indicative of biological stress on the communities at these sites. The dominance of omnivores in samples from the Rio Grande below Taos Junction Bridge, near Taos; Rio Chama near Chamita, New Mexico; Rio Grande at Isleta; and Rio Grande at El Paso is an indication of environmental stress at these sites. In 1995, tolerant species accounted for the entire fish community at the Rio Grande at Isleta. In all samples the occurrence of anomalies was less than 2 percent of the individuals, with the exception of the sample from the Rio Grande at Isleta. On the basis of the relative percentages of introduced individuals, omnivores, tolerant individuals, and anomalies, the biotic integrity at the Rio Grande at Isleta appears to be the most impaired of all sites and shows indications of potential chemical and physical perturbations. Fish communities from three reaches at the Santa Fe River above Cochiti Lake, New Mexico, and the Rio Grande at Isleta were sampled in 1995 to assess small-scale spatial patterns in the structure of fish communities. The spatial pattern at these sites might be associated with natural variability of the fish communities or with the presence of habitat features such as pools. The total number of individuals and relative abundance in a sample varied at sites sampled yearly during this study. All sites, with the exception of the Rio Grande near Del Norte, had a decline in total number of individuals in a sample. The temporal decline in the total number of individuals at these site might be associated with the natural variability within the fish communities.

Colorado, New Mexico, Texas↗

USGS2001

Numerical simulation of streamflow distribution, sediment transport, and sediment deposition along Long Beach Creek in Northeast Missouri

This report presents the results of a study conducted by the U.S. Geological Survey in cooperation with the Missouri Department of Conservation to describe the hydrology, sediment transport, and sediment deposition along a selected reach of Long Branch Creek in Macon County, Missouri. The study was designed to investigate spatial and temporal characteristics of sediment deposition in a remnant forested riparian area and compare these factors by magnitude of discharge events both within and outside the measured range of flood magnitudes. The two-dimensional finite-element numerical models RMA2-WES and SED2D-WES were used in conjunction with measured data to simulate streamflow and sediment transport/deposition characteristics during 2-, 5-, 10-, and 25-year recurrence interval floods. Spatial analysis of simulated sediment deposition results indicated that mean deposition in oxbows and secondary channels exceeded that of the remaining floodplain areas during the 2-, 5-, 10-, and 25-year recurrence interval floods. The simulated mass deposition per area for oxbows and secondary channels was 1.1 to 1.4 centimeters per square meter compared with 0.1 to 0.60 centimeters per square meter for the remaining floodplain. The temporal variability of total incremental floodplain deposition during a flood was found to be strongly tied to sediment inflow concentrations. Most floodplain deposition, therefore, occurred at the beginning of the streamflow events and corresponded to peaks in sediment discharge. Simulated total sediment deposition in oxbows and secondary channels increased in the 2-year through 10-year floods and decreased in the 25- year flood while remaining floodplain deposition was highest for the 25-year flood. Despite increases in sediment inflows from the 2-year through 25-year floods, the retention ratio of sediments (the ratio of floodplain deposition to inflow load) was greatest for the 5-year flood and least for the 25-year flood. The decrease in retention ratio at greater flows is likely the result of higher velocities on the floodplain, resulting in higher bed shear stress, greater suspension time of deposited material, and greater sediment transport through the system. Simulated sediment deposition was most sensitive to sediment inflow concentrations and modification of floodplain roughness—factors that can be controlled through management practices. The increase in floodplain sediment deposition resulting from a simulated increase in vegetation density (increase in floodplain roughness from a Manning's n of 0.11 to 0.12) was 142,000 kilograms, or 6.5 percent for a 10-year recurrence interval flood. This increase was comparable to total oxbow and secondary channel deposition mass in the simulations, but would result in a mean increase in floodplain deposition thickness of only 0.025 centimeter. The hydrodynamic model results show the importance of the secondary channels and meander cutoff channels in this system because these areas quickly bring floodwaters and sediment to areas not close to the main channel. The meander cutoff channels in the simulation also effectively decrease flow and velocities in some main channel sections thereby affecting sediment deposition in the vicinity of these features.

Missouri↗